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Anion selectivities of membranes based on HgII complexes of calix[4]arene derivatives (1996)

Wróblewski, Wojciech ; Malinowska, Elżbieta ; Brzózka, Zbigniew

Weinheim : Wiley-Blackwell

Electroanalysis 8 (1996), S. 75-78

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ISSN: 1040-0397

Keywords: Potentiometry ; Anions ; Calix[4]arene ; Chemistry ; Polymer and Materials Science

Source: Wiley InterScience Backfile Collection 1832-2000

Topics: Chemistry and Pharmacology

Notes: Anion selectivities of membranes based on cationic complexes of thioamide calix[4]arene derivatives are presented for the first time. HgII complexes of thioamide derivatives of calix[4]arene were applied to design perchlorate-selective ISEs which show linear responses in the range 1-5 of pClO4 with a slope of 56.5mV decade -1. The highest selectivity over other anions (except iodides) and optimum performances of electrodes were obtained for a 0.01 M solution of HgII as an internal electrolyte.

Additional Material: 6 Ill.

Type of Medium: Electronic Resource

URL: http://dx.doi.org/10.1002/elan.1140080115

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