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Investigations of vibronic transitions by resonance CARS (1990)

Kircheva, P. P. ; Simeonov, S. D.

Chichester [u.a.] : Wiley-Blackwell

Journal of Raman Spectroscopy 21 (1990), S. 55-63

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ISSN: 0377-0486

Keywords: Chemistry ; Analytical Chemistry and Spectroscopy

Source: Wiley InterScience Backfile Collection 1832-2000

Topics: Chemistry and Pharmacology , Physics

Notes: The influence of thermally excited vibrations on vibronic spectra (absorption, CARS excitation profile and resonance background) has been modelled for polyatomic molecules in solution. It is shown that for a model describing some polymethine compounds, the spectra depend only slightly on temperature except in the case of a resonance background and an excitation profile of vibrations with a relatively high value of the origin shift parameter (Δ 〉 1). The investigations of low-frequency vibrations by resonance CARS to giving information about some molecular parameters is proposed.

Additional Material: 11 Ill.

Type of Medium: Electronic Resource

URL: http://dx.doi.org/10.1002/jrs.1250210111

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