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Raman and infrared spectra of transition metal halide hexahydrates (1987)

Agulló-Rueda, F. ; Calleja, J. M. ; Martini, M. ; [et al.]

Chichester [u.a.] : Wiley-Blackwell

Journal of Raman Spectroscopy 18 (1987), S. 485-491

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ISSN: 0377-0486

Keywords: Chemistry ; Analytical Chemistry and Spectroscopy

Source: Wiley InterScience Backfile Collection 1832-2000

Topics: Chemistry and Pharmacology , Physics

Notes: The Raman and infrared spectra of NiCl2·6H2O, NiCl2·6D2O, CoCl2·6H2O, CoCl2·6D2O and CoBr2·6H2O single crystals have been measured in the range 3600-30 cm-1 (Raman) and 3800-400 cm-1 (IR). The water internal modes have been best assigned for NiCl2·6H2O, including Fermi resonance effects. The corresponding Raman intensities have been interpreted in terms of the free molecule Raman tensors. Among the lattice vibrations, the metal halide and metal-water stretchings, and also the librations of the MX2·4H2O octahedra, have been identified and assigned.

Additional Material: 6 Ill.

Type of Medium: Electronic Resource

URL: http://dx.doi.org/10.1002/jrs.1250180707

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