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Exciting frequencies and depolarization ratios for resonance Raman effectsResearch supported by NRCC Grant A 2843. (1974)

Koningstein, J. A. ; Jakubinek, B. G.

Chichester [u.a.] : Wiley-Blackwell

Journal of Raman Spectroscopy 2 (1974), S. 317-324

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ISSN: 0377-0486

Keywords: Chemistry ; Analytical Chemistry and Spectroscopy

Source: Wiley InterScience Backfile Collection 1832-2000

Topics: Chemistry and Pharmacology , Physics

Notes: The behaviour of an element of the Raman scattering tensor is considered as the exciting frequency is tuned through the vibronic absorption spectrum of the scattering molecule. Certain observed features of Raman excitation profiles are explained, and some predictions made. Using some simplifying assumptions, we examine the limiting form of the scattering tensor in certain resonance situations. On the basis of symmetry considerations, we then outline expected variations in (and limits on) the depolarization ratio near resonance.

Additional Material: 1 Ill.

Type of Medium: Electronic Resource

URL: http://dx.doi.org/10.1002/jrs.1250020310

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