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Thermal desorption mass spectrometry of organic salts (1982)

Yergey, Alfred L. ; Cotter, Robert J.

Chichester : Wiley-Blackwell

Biological Mass Spectrometry 9 (1982), S. 286-292

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ISSN: 0306-042X

Keywords: Chemistry ; Analytical Chemistry and Spectroscopy

Source: Wiley InterScience Backfile Collection 1832-2000

Topics: Chemistry and Pharmacology

Notes: Mass spectra of a series of alkyl, alkyl/aryl and biologically important quaternary ammonium and phosphonium compounds have been obtained by a direct thermal process. No means of ionization other than the heating of a salt coated filament is used. The spectra consist primarily of even electron ions for which decomposition schemes involving four-center reactions are proposed. These spectra are similar to those obtained in fission fragment induced desorption, laser induced desorption and field desorption/collisional activation, but they are produced by a far simpler means.

Additional Material: 6 Ill.

Type of Medium: Electronic Resource

URL: http://dx.doi.org/10.1002/bms.1200090704

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