ISSN:
0935-6304
Keywords:
Fischer-Tropsch waters
;
Alcohols in water
;
Carboxylic acids in water
;
Aldehydes in water
;
Ketones in water
;
Chemistry
;
Analytical Chemistry and Spectroscopy
Source:
Wiley InterScience Backfile Collection 1832-2000
Topics:
Chemistry and Pharmacology
Notes:
This paper describes a quantitative technique for the determination of organic constituents in Fischer-Tropsch by-product waters. Temperature-programmed gas chromatography on derivatized bonded polar capillary columns provides the required separation that permits reliable quantitation of individual compounds. A preliminary combined gas chromatographic-mass spectrometric survey to identify the components present in Fischer-Tropsch by-product waters is presented. The elution order of 58 identified components is tabulated. Components identified in a typical Fischer-Tropsch by-product water include C1-C9 linear and branched alcohols, C3—C8 ketones, C2—C6 carboxylic acids, and C2—C4 linear aldehydes.
Additional Material:
3 Ill.
Type of Medium:
Electronic Resource
URL:
http://dx.doi.org/10.1002/jhrc.1240170410