Publication Date:
2020-11-25
Description:
Over the past few decades, substantial progress has been made to overcome the technical difficulties of continuously measuring volcanic SO2 emissions. However, measurements of CO2 emissions still present many difficulties, partly due to the lack of instruments that can directly measure CO2 emissions and partly due to its strong atmospheric background. In order to overcome these difficulties, a commonly taken approach is to combine differential optical absorption spectroscopy (DOAS) by using NOVAC scan-DOAS instruments for continuous measurements of crateric SO2 emissions, and electrochemical/NDIR multi-component gas analyser system (multi-GAS) instruments for measuring CO2/SO2 ratios of excerpts of the volcanic plume. This study aims to quantify the representativeness of excerpts of CO2/SO2 ratios measured by Multi-GAS as a fraction of the whole plume composition, by comparison with simultaneously measured CO2/SO2 ratios using cross-crater Fourier transform infrared spectroscopy (FTIR). Two study cases are presented: Telica volcano (Nicaragua), with a homogenous plume, quiescent degassing from a deep source and ambient temperature, and Turrialba volcano (Costa Rica), which has a non-homogeneous plume from three main sources with different compositions and temperatures. Our comparison shows that in our “easier case” (Telica), FTIR and Multi-GAS CO2/SO2 ratios agree within a factor about 3 %. In our “complicated case” (Turrialba), Multi-GAS and FTIR yield CO2/SO2 ratios differing by approximately 13–25 % at most. These results suggest that a fair estimation of volcanic CO2 emissions can be provided by the combination of DOAS and Multi-GAS instruments for volcanoes with similar degassing conditions as Telica or Turrialba. Based on the results of this comparison, we report that by the time our measurements were made, Telica and Turrialba were emitting approximately 100 and 1,000 t day−1 of CO2, respectively.
Description:
This work was supported by the Swedish International Development Agency (SIDA), and the DECADE initiative in coordination with OVSICORI-UNA and INETER. The research leading to these results received funding from the European Research Council under the European Union’s Seventh Framework Programme (FP7/2007/2013)/ERC grant agreement n1305377 (PI Aiuppa)
Description:
Published
Description:
2335–2347
Description:
4V. Processi pre-eruttivi
Description:
JCR Journal
Keywords:
volcanic degassing
;
Multi-GAS
;
UV spectroscopy
;
FTIR
Repository Name:
Istituto Nazionale di Geofisica e Vulcanologia (INGV)
Type:
article
