ISSN:
1600-5759
Quelle:
Crystallography Journals Online : IUCR Backfile Archive 1948-2001
Thema:
Chemie und Pharmazie
,
Geologie und Paläontologie
,
Physik
Notizen:
In the title compound, [Co(C2H6NS)(C2H8N2)2](NO3)2, the CoIII atom has a slightly distorted octahedral geometry, coordinated by one 2-aminoethanethiolate and two ethylenediamine ligands. The three five-membered chelate rings adopt a gauche conformation with the unfavoured (lel)2(ob) form, which is ascribed to hydrogen bonds between the amine groups in the complex cation and the nitrate counter-anions [N...O 2.900 (3)–3.378 (3) Å].
Materialart:
Digitale Medien
URL:
http://dx.doi.org/10.1107/S0108270101002773
