ISSN:
1436-5073
Schlagwort(e):
hexaisothiocyanatomanganate(II)
;
X-ray structure analysis
;
magnetic susceptibility
;
dehydration reactions
Quelle:
Springer Online Journal Archives 1860-2000
Thema:
Chemie und Pharmazie
Notizen:
Abstract Na4[Mn(NCS)6] · 13H2O was prepared and characterized by chemical analysis, magnetic susceptibility, thermal dehydration reactions, and single crystal X-ray structure analysis. The crystals are triclinic with a=9.310(1)Å, b=9.367(1)Å, c=9.730(2)Å, α= 89.89(1)°,β=75.33(1)°, γ=70.72(1)°, space group P¯I.Z=1. The structure is built up from Na(H2O)5 S, Na(H2O)6, and Mn(NCS)6, octahedra. All water molecules are coordinated to Na+ -ions in terminal as well as bridging fashion. They form O-H···O as well as O-H···S hydrogen bonds.
Materialart:
Digitale Medien
URL:
http://dx.doi.org/10.1007/BF01246178
