ALBERT

Description: Research is reported on the development of sensors for gas turbine combustor applications that measure real-time gas temperature using near-infrared water vapor absorption and concentration in the combustor exhaust of trace quantities of pollutant NO and CO using mid-infrared absorption. Gas temperature is extracted from the relative absorption strength of two near-infrared transitions of water vapor. From a survey of the water vapor absorption spectrum, two overtone transitions near 1800 nm were selected that can be rapidly scanned in wavelength by injection current tuning a single DFB diode laser. From the ratio of the absorbances on these selected transitions, a path-integrated gas temperature can be extracted in near-real time. Demonstration measurements with this new temperature sensor showed that combustor instabilities could be identified in the power spectrum of the temperature versus time record. These results suggest that this strategy is extremely promising for gas turbine combustor control applications. Measurements of the concentration of NO and CO in the combustor exhaust are demonstrated with mid-infrared transitions using thermo-electrically cooled, quantum cascade lasers operating near 5.26 and 4.62 microns respectively. Measurements of NO are performed in an insulated exhaust duct of a C2H4-air flame at temperatures of approximately 600 K. CO measurements are performed above a rich H2-air flame seeded with CO2 and cooled with excess N2 to 1150 K. Using a balanced ratiometric detection technique a sensitivity of 0.36 ppm-m was achieved for NO and 0.21 ppm-m for CO. Comparisons between measured and predicted water-vapor and CO2 interference are discussed. The mid-infrared laser quantum cascade laser technology is in its infancy; however, these measurements demonstrate the potential for pollutant monitoring in exhaust gases with mid-IR laser absorption.