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Influence of pH on nickel electrodeposition at low nickel(II) concentrations (1995)

Proud, W. G. ; Gomez, E. ; Sarret, E. ; [et al.]

Springer

Journal of applied electrochemistry 25 (1995), S. 770-775

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ISSN: 1572-8838

Source: Springer Online Journal Archives 1860-2000

Topics: Chemistry and Pharmacology , Electrical Engineering, Measurement and Control Technology

Notes: Abstract The effect of pH on the nucleation stages of nickel electrodeposition on vitreous carbon has been analysed using low nickel concentrations, without additives. The experimental results indicated that there was a change in the electrochemical response of the system at 4 〈 pH 〈 4.5. A predischarge adsorption ascribed to nickel(II) species was observed with a different surface coverage depending on the pH. Moreover, different inhibition and 3D nucleation processes were detected in varying experimental conditions.

Type of Medium: Electronic Resource

URL: http://dx.doi.org/10.1007/BF00648632

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