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Photoenolization of 4-Naphthoyl[2.2]paracyclophanes (1994)

Hopf, Henning ; Laue, Thomas ; Zander, Maximilian

Weinheim : Wiley-Blackwell

Berichte der deutschen chemischen Gesellschaft 127 (1994), S. 965-966

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ISSN: 0009-2940

Keywords: Cyclophanes ; Photochemistry ; Triplet states ; Enolization ; Chemistry ; Inorganic Chemistry

Source: Wiley InterScience Backfile Collection 1832-2000

Topics: Chemistry and Pharmacology

Notes: When ethanolic solutions of 4-(1-naphthoyl)[2.2]paracyclophane (3) and 4-(2-naphthoyl)[2.2]paracyclophane (4) are subjected to UV irradiation at low temperature, 1,5-hydrogen migration of the 2-H bridge proton to the carbonyl group takes place, leading to the enol of type 2. In the context of mechanistic considerations the triplet spectroscopic properties of 3 and 4 are discussed.

Additional Material: 1 Ill.

Type of Medium: Electronic Resource

URL: http://dx.doi.org/10.1002/cber.19941270527

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