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Stationary-phase swelling and its consequences in capillary gas-liquid chromatography (1986)

Pretorius, V. ; Lawson, K.

Weinheim : Wiley-Blackwell

Journal of High Resolution Chromatography 9 (1986), S. 335-340

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ISSN: 0935-6304

Keywords: Capillary gas-liquid chromatography ; Stationary-phase focusing ; Swelling ; Chemistry ; Analytical Chemistry and Spectroscopy

Source: Wiley InterScience Backfile Collection 1832-2000

Topics: Chemistry and Pharmacology

Notes: Sample introduction using the solvent effect can lead to significant swelling of the stationary phase. The phenomenon has been studied theoretically and experimentally. The longitudinal profile of the swollen phase has been established. Swelling can affect the retention time of solutes, the shape of solute bands emerging from the inlet, and the maximum permissible sample size.

Additional Material: 8 Ill.

Type of Medium: Electronic Resource

URL: http://dx.doi.org/10.1002/jhrc.1240090604

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