ALBERT

Notes: Microstructures in slate belt rocks at the Elura Mine, near Cobar, south-eastern Australia, indicate that volume loss by syntectonic dissolution is coupled with mass accretion by reprecipitation of the dissolved material in dilational sites. The mass accretion is sustained primarily by repetitive tensile microfracturing at high pore-fluid pressures. Oriented growth in the inter- and intragranular microcracks is locally host-controlled, creating lattice- and shape-preferred orientations. The grain-scale crack-seal features throughout the rock reflect rhythmic fluid pressure fluctuations; a balance is achieved between the fracture-induced permeability (and consequent flushing rates), and the rate of fluid build-up in a relatively sealed environment.Instability in the balancing factors can lead to localization and intensification of tensile failure (and hence, tension vein formation) in the grain aggregate. Growth of veins by crack-seal also reflects a steady state, but with more localized fluctuations of fluid flow on the aggregate scale. Still larger imbalances between flushing and fluid accumulation (i.e. pressure variations) induce breccia veining. The larger pressure gradients over greater distances, associated with dilation localization (from pervasive microfracturing to spaced breccia domains), allow fluid channelling with an increased potential for chemical fluid/rock disequilibrium. Therefore, large breccia vein systems tend to be sites of extensive fluid/rock interaction and replacement, as spectacularly illustrated by the syntectonic sulphide orebodies at Elura. The huge amounts of silicate, carbonate and sulphide accumulated during folding at Elura illustrate the large scale of source and sink couples possible in solute mass transfer.

Notes: The Internal Zone of the Betic Cordilleras consists of several superimposed major thrust sheets with different P-T-t evolutions. On the basis of an integrated field, microscopic and laboratory study, the tectono-metamorphic history of the Mulhacen Complex and Almanzora Unit has been reconstructed in detail. The Mulhacen Complex has been affected by at least five phases of penetrative deformation, which have been labelled Dx-1, Dx, Dx+1, Dx+2 and Dx+3. Dx-1, and Dx are related to continent-continent collision, which is indicated by high pressure-low temperature (HP/LT) and subsequent intermediate P/T metamorphic conditions. Dx+1 is related to crustal thinning and heterogeneous extension. During this event the Almanzora Unit was juxtaposed against the Mulhacen Complex. This phase was succeeded by the establishment of low pressure-high temperature (LP/HT) conditions and at least two phases of folding and overthrusting. The Almanzora Unit shows a comparable tectono-metamorphic evolution post Dx+1. However, the P/T conditions prior to Dx+1 indicate a higher crustal position with respect to the Mulhacen Complex during the collisional event.

Notes: Following the Middle Devonian Acadian deformation an extensive belt of high grade metamorphism was formed in New England. In south-western Maine, at the northern end of this belt, there occurs a transition along the strike from regional low-pressure/high-temperature metamorphism to contact metamorphism in low-grade rocks. Petrological studies indicate that this transition occurs along a surface plunging to the north-east at about 3.5°, with respect to the Middle-to-Late Devonian erosion surface. In addition, detailed petrological mapping has defined a history of temporally separate, localized metamorphic events associated with plutonism and occurring at increasingly deeper levels to the south-west. Geochronological studies constrain ambient temperatures in the transition zone at the time of metamorphism to be less than 300° C in the north-east and between 350° C and 500° C in the south-west. They also establish a pattern of diachronous cooling due to differential uplift and erosion, with cooling occurring later and most rapidly to the south-west. Geophysical evidence suggests that along with this spatial variation in metamorphic style the shapes of the plutons in Maine undergo a transition from laterally extensive sheet-like bodies in the high grade terrane to more equant-shaped bodies in the low-grade terrane. Using the results of these petrological, geochronological and geophysical studies, as well as those of stratigraphical and structural studies we construct a thermal model for the transition zone. The model suggests that the Acadian metamorphism in south-western Maine is a result of deep-level contact metamorphism near laterally extensive granitic sills dipping to the north-east with respect to the present erosion surface. The plutons themselves are interpreted to be a result of lower crustal melting in response to crustal thickening in the presence of normal or slightly augmented mantle heat flux.

Notes: All along the Himalayan chain an axis of crystalline rocks has been preserved, made of the Higher Himalaya crystalline and the crystalline nappes of the Lesser Himalaya. The salient points of the metamorphism, as deduced from data collected in central Himalaya (central Nepal and Kumaun), are:〈list xml:id="l1" style="custom"〉1The Higher Himalaya crystalline, also called the Tibetan Slab, displays a polymetamorphic history with a first stage of Barrovian type overprinted by a lower pressure and/or higher temperature type metamorphism. The metamorphism is due to quick and quasi-adiabatic uplift of the Tibetan Slab by transport along an MCT ramp, accompanied by thermal refraction effects in the contact zone between the gneisses and their sedimentary cover. The resulting metamorphic pattern is an apparent (diachronic) inverse zonation, with the sillimanite zone above the kyanite zone.2Conversely, the famous inverted zonation of the Lesser Himalaya is basically a primary pattern, acquired during a one-stage prograde metamorphism. Its origin must be related to the thrusting along the MCT, with heat supplied from the overlying hot Tibetan Slab, as shown by synmetamorphic microstructures and the close geometrical relationships between the metamorphic isograds and the thrust.3Thermal equilibrium is reached between units above and below the MCT. Far behind the thrust tip there is good agreement between the maximum temperature attained in the hanging wall and the temperature of the Tibetan Slab during the second metamorphic stage; but closer to the MCT front, the thermal accordance between both sides of the thrust is due to a retrogressive metamorphic episode in the basal part of the Tibetan Slab.

Notes: South of the Main Mantle Thrust in north Pakistan, rocks of the northern edge of the Indian plate were deformed and metamorphosed during the main southward thrusting phase of the Himalayan orogeny. In the Hazara region, between the Indus and Kaghan Valleys, metamorphic grade increases northwards from chlorite zone to sillimanite zone rocks in a typically Barrovian sequence. Metamorphism was largely synchronous with early phases of the deformation. The metamorphic rocks were subsequently imbricated by late north-dipping thrusts, each with higher grade rocks in the hanging wall than in the footwall, such that the metamorphic profile shows an overall tectonic inversion. The rocks of the Hazara region form one of a number of internally imbricated metamorphic blocks stacked, after the metamorphic peak, on top of each other during the late thrusting. This imbrication and stacking represents an early period of post-Himalayan uplift.

Notes: Crustal thickening along the northern margin of the Indian plate, following the 50 Ma collision along the Indus Suture Zone in Ladakh, caused widespread high-temperature, medium-pressure Barrovian facies series metamorphism and anatexis. In the Zanskar Himalaya metamorphic isograds are inverted and structurally telescoped along the Main Central Thrust (MCT) Zone at the base of the High Himalayan slab. Along the Zanskar valley at the top of the slab, isograds are the right way-up and are also telescoped along northeast-dipping normal faults of the Zanskar Shear Zone (ZSZ), which are related to culmination collapse behind the Miocene Himalayan thrust front. Between the MCT and the ZSZ a metamorphic-anatectic core within sillimanite grade rocks contains abundant leucogranite-granite crustal melts of probable Himalayan age. A thermal model based on a crustal-scale cross-section across the Zanskar Himalaya suggests that M1 isograds, developed during early Himalayan Barrovian metamorphism, were overprinted during high-grade MCT-related anatexis and folded around a large-scale recumbent fold developed in the hanging wall of the MCT.

Notes: Experiments up to water pressures of 21 kbar have been undertaken to bracket the reactions chlorite + quartz = talc + kyanite + H2O, chlorite + quartz = talc + cordierite + H2O, and talc + kyanite + quartz = cordierite ± H2O by reversed runs in the system MgO-Al2O3-SiO2-H2O (MASH). These reaction curves intersect at an invariant point (IP1) at PH2O = 6.4 ± 0.2 kbar and a temperature of 624 ± 4°C. The curve of the chlorite + quartz breakdown to talc + kyanite + H2O at water pressures above 6.4 kbar shows a negative dP/dT, with the slope decreasing with rising pressure, whereas the slope of the breakdown curve to talc + cordierite + H2O at water pressures is clearly positive.The composition of the chlorite solid solution reacting with quartz has been estimated to be approximately Mg4.85Al1.15[Al1.15Si2.85O10](OH)8 over the entire pressure range investigated. The composition of the talc solid solution forming by the breakdown of chlorite + quartz appears to be Mg2.94Al0.06[Al0.06Si3.94O10](OH)2 at PH2O = 2kbar. With increasing pressure, the Al content of talc decreases, reaching a value of about 0.06 atoms per formula unit at P,H2O = 21 kbar.As a consequence of the new experimental data, the existing phase topologies of the MASH-system and K2O-MASH-system have been revised. For example, the invariant point IP1 and the univariant reaction curve kyanite + talc + H2O = chlorite + cordierite are stable. For this reason, the development of medium- to high-temperature metamorphic rocks compositionally approximating the MASH-system must be reconsidered. The whiteschists from Sar e Sang, Afghanistan, are treated as an example. The application of the present experimental data to metamorphic rocks of more normal composition requires the examination of the influence of further components. This leads to the conclusion that the introduction of Fe2+ into magnesian chlorite extends its stability field in the presence of quartz by 10°-15°C in comparison with pure Mg-chlorite.

Notes: A reaction producing jadeitic pyroxene in metagreywackes of the northern Diablo Range has been identified on the basis of mineral distribution, isograd patterns and composition of coexisting minerals. The appearance of jadeitic pyroxene (∼Jd80) is closely followed by the disappearance of pumpellyite, which indicates that pumpellyite plays a major role in the pyroxene-producing reaction. A new projection from hematite, lawsonite, chlorite, quartz and H2O on to the NaAlO2-FeO-MgO ternary confirms the role of pumpellyite in pyroxene production and suggests a reaction of the form: 1.00 pumpellyite + 0.31 chlorite + 8.71 albite + 0.70 hematite + 2.00 H2O = 8.54 jadeite + 0.57 glaucophane + 3.09 lawsonite + 5.26 quartz. Metagreywackes of the northern Diablo Range were metamorphosed under conditions of PH2O=Ptotal at 200-300 °C and 7.5-10.0 kbar. Despite the low temperatures attained during metamorphism, the assumption of equilibrium yields results consistent with field observations and phase relations.

Notes: Metabasites and metagreywackes from the Pelona and Rand Schists of southern California were analysed using three different electron microprobes. For all three instruments, the estimated Fe3+ contents of calcic amphibole, chlorite and epidote are positively correlated. For some samples, there is an additional correlation between high estimated Fe3+ and the presence of magnetite. These results imply that microprobe analyses can be used to discern relative differences in Fe3+. However, microprobe data and calculations on the sensitivity of the correction procedures to systematic analytical errors indicate that estimated values of Fe3+ are not significant in an absolute sense. Thus, estimates of Fe3+ are meaningful when comparing samples analysed with a single microprobe, but must be used with caution when comparing analyses obtained on more than one probe.

Notes: All the Mesozoic and Cenozoic volcanic rocks of the Central Andes (from southern Ecuador to central Chile), except Recent ones, have been affected by episodes of regional metamorphism, without change in texture and structure. The metamorphism, which ranges from low zeolite to greenschist facies, can be classified as burial metamorphism because there is an overall increase in metamorphic grade with stratigraphic depth in the individual volcanic sequences separated by regional unconformities. Some sequences display metamorphic patterns transitional to ocean-floor and to geothermal field types, reflecting variations along and across the Andes in tectonic setting and thermal gradients.Volcanism was closely followed by metamorphism during each cycle characterizing the geological history of the Central Andes. The episodic nature of the metamorphism has led to breaks in metamorphic grade at regional unconformities and repetition of facies series, where strata of higher grade may even overlie those of lower grade. The existence of permeability-controlled distribution patterns of secondary minerals within individual flows shows that gradients of chemical activity, rate of reaction and Pfluid were acting, in addition to temperature and P,tot overall gradients, during the regional metamorphism. The alteration is accompanied by chemical changes and disturbances of the K-Ar and Rb-Sr isotope systems. Similarities between Mesozoic facies series in the western and eastern flanks of the Andes are consistent with a mechanism of ensialic spreading-subsidence.

Notes: An analytical study to evaluate quantitatively weak zoning of a garnet from a high-grade kinzigite has been performed with an electron microprobe. The technique consists of the reconstruction of a profile step-by-step by successive analyses performed during relatively long counting times (30 s), along a radial profile of 2,500 μm length. The successive analytical data along this profile are statistically treated by Fisher's test and compared with the χ2 values (Pearson's law). These statistical tests were applied to assess microprobe stability and analysis homogeneity, and as a consequence to assure high credibility of the radial variations of the garnet. From core to rim, and for each element, zoning appears as the radial juxtaposition of stationary Poissonian samples. These samples being associated, the garnet appears to be constituted of successive concentric domains with stationary compositions. Different substitutions between Mg, Fe, Mn and Ca are evidenced. Such an analytical approach to chemical zoning can be useful for understanding growth mechanisms, and the possible diffusion reactions with the environment at each growth step. In addition, such a procedure can be used to evaluate accurately the fluid content of cordierite, and to appreciate the nature of the fluids concerned. As an example, the fluid content of a cordierite from a similar high-grade kinzigite has been evaluated.

Notes: P-T conditions inferred from fluid inclusions in metamorphic rocks often disagree with the values predicted from mineral equilibria calculations. These observations suggest that inclusions formed during early stages of regional metamorphism continue to re-equilibrate during burial and subsequent uplift in response to differential pressure. P-T conditions accompanying burial and uplift were experimentally simulated by initially forming pure H2O inclusions in quartz at elevated temperatures and pressures, and then re-equilibrating the inclusions in the presence of a 20 wt% NaCl solution such that final confining pressures ranged from 5 kbar above to 4 kbar below the initial internal pressure of the inclusions at the temperature of re-equilibration.In all samples re-equilibrated at confining pressures below the internal pressure, some inclusions were formed that had compositions of 20 wt% NaCl and densities in accord with the final P-T conditions. Additionally, some inclusions were observed to contain fluids of intermediate salinities (between 0 and 20 wt% NaCl). Densities of these inclusions were also consistent with formation at the re-equilibration P-T conditions. The remainder of the fluid inclusions observed in these samples contained pure H2O and their homogenization temperatures corresponded to densities intermediate between the initial and final P-T conditions. In short-term experiments (7 days) where the initial internal overpressure exceeded 1 kbar, no inclusions were found that contained the original density and none were found to have totally re-equilibrated. Instead, most H2O inclusions re-equilibrated until their internal pressures were between ∼750 and 1500 bars above the confining pressure, regardless of the initial pressure differential. In a long-term experiment (52 days), inclusions re-equilibrated at a lower confining pressure than the initial internal pressure displayed homogenization temperatures corresponding to a range in final internal pressures between 0 kbar (i.e. total re-equilibration) and 1.2 kbar above the confining pressure.In experiments where the confining pressure during re-equilibration exceeded the initial internal pressure, densities of pure H2O inclusions increased to values intermediate between the initial and final P-T conditions. Additionally, these inclusions were generally surrounded by a three-dimensional halo of smaller inclusions, also of intermediate density, resulting in a texture similar to that previously ascribed to decrepitation from internal overpressure. In extreme cases where confining pressures were 4–5 kbar above the initial pressure, the parent inclusion almost completely closed leaving only the three-dimensional array of small (〈inlineGraphic alt="leqslant R: less-than-or-eq, slant" extraInfo="nonStandardEntity" href="urn:x-wiley:02634929:JMG243:les" location="les.gif"/〉5 μm) inclusions, the outline of which may be several times the volume of the original inclusion. Groups of such inclusions closely resemble textures commonly observed in medium- to high-grade metamorphic rocks.Inclusions containing 10 and 42 wt% NaCl solutions trapped at 600 °c and 3 kbar were re-equilibrated at 600 °c and 1 kbar for 5 days in dry argon to evaluate the importance of H2O diffusion as a mechanism of lowering the inclusion bulk density. Salinities of re-equilibrated inclusions obtained from freezing point depressions and halite dissolution temperatures indicate that original compositions were preserved. Density changes similar to those previously described were noted in these experiments, in inclusions showing no visible microfractures. Therefore, density variations observed in inclusions in this study, re-equilibrated under rapid deformation conditions, are considered to result from a change in the inclusion volume, without significant loss of contents by diffusion or leakage.

Notes: In the main Himalayan range in the Ladakh-Zanskar area, domal structures have been observed at structurally deeper levels in the tectonic unit of the Higher Himalayan Crystalline. Their formation occurred during a second, temperature-dominated phase (M2) of high-grade regional metamorphism, characterized by the semipelitic paragenesis of sillimanite-K-feldspar and incipient anatexis. The doming event reveals a local system of synmetamorphic uplift superimposed on a regional system of northeast-southwest trending compression. In the main Himalayan range the development of the dominant S2 foliation is related to deformation during the doming phase, which started early in the M2 event. The deformation propagated continuously north-east and south-west with time. In the north-east, on the northern slopes of the main Himalayan range, this deformation is expressed by extensional shear movements of the upper tectonic levels finally leading to the late- to postmetamorphic normal fault system of the Zanskar shear zone. Towards the south-west, deformation is expressed by compressional movements, e.g. at the Main Central Thrust (MCT) in the Kishtwar window area. The observed compression and extension is inferred to relate to an increased uplift of the domal bulges of the tectonic Kishtwar window and of the whole main Himalayan range.

Notes: The pressure-temperature and temperature-time paths derived for rocks in the Kohistan arc and adjacent Nanga Parbat-Haramosh massif record the dynamics of the collision between the island arc and the Indian plate. Studies of P-T-t paths show that the Kohistan arc was thrust over the Nanga Parbat-Haramosh massif at least 25 Ma ago, but not more than 30–35 Ma ago. Rocks in the Kohistan arc followed decreasing pressure paths, with the early metamorphism beginning at high pressures (9.5 kbar) and later metamorphism occurring at 8.0 kbar. In contrast, rocks in the Nanga Parbat-Haramosh massif (Indian plate) experienced increasing pressure and temperature paths. Prior to thrusting, the massif was at low pressures (4.0 kbar) and low temperatures (450°c). Later, the pressure and temperature increased to 8 kbar and 580°c. The authors interpret the convergence (to approximately the same pressure and temperature) of the P-T paths in the two terranes as being the result of thrusting and thermal equilibration between the thrust sheets. 40Ar/39Ar cooling ages of hornblendes and other geochronological data suggest that the time of peak metamorphism and hence the completion of thickening was approximately 30–35 Ma ago.Temperature-time paths show that after thrusting, during the period 25–10 Ma, the Kohistan arc and Nanga Parbat-Haramosh massif were uplifted at similar rates (0.5 km Ma). However, in the past 10 Ma the Nanga Parbat-Haramosh massif has been uplifted more rapidly than the adjacent Kohistan arc. Rapid uplift has been accommodated by late faults along the edge of the massif.

Notes: The Kanskaya formation in the Yenisey range, Eastern Siberia is a newly studied example of retrogression of granulite facies rocks. The formation consists of two stratigraphical units: the lower Kuzeevskaya group and the upper Atamanovskaya group. Rocks from both of these units show rare reaction textures such as replacement of cordierite by garnet, sillimanite and quartz, silimanite coronas around spinel and corundum, and garnet rims around plagioclase in metabasites, while plagioclase rims around garnet can be seen in associated metapelites. The paragenesis quartz + orthopyroxene + sillimanite is a feature of the Kuzeevskaya group. In many samples, chemical zoning of garnet and cordierite shows an increase in Mg from core to rim as well as the reverse.Biotite-garnet-cordierite-sillimanite-quartz as well as spinel±biotite-garnet°Cordierite±sillimanite-quartz assemblages were studied using geothermometers and geobarometers based on both exchange and net-transfer reactions (Perchuk & Lavrent'eva, 1983; Aranovich & Podlesskii, 1983; Gerya & Perchuk, 1989). Detailed investigation of 10 samples including 1000 microprobe analyses revealed decompression (first stage) followed by the near isobaric cooling of the granulites. From geological studies, the 7 km total thickness of the sequence closely corresponds to the pressure difference (∼ 2.2kbar) measured by geobarometers in the samples taken from different levels in the sequence. Individual samples yield P-T paths ranging from 100°C/kbar to 140°C/kbar depending on their locations with respect to the large Tarakskiy granite pluton. In places the 100°C/kbar path changed to the 140°C/kbar due to the influence of the intrusion. In a P-T diagram these trajectories are subparallel lines, whose P-T maxima define the Archaean geotherm between 3.1 and 2.7 Ga, determined isotopically. A petrological model for P-T evolution of the Kanskaya formation is proposed.

Notes: A method is proposed for adjusting the mass balance to characterize quantitatively the behaviour of minerals in anatexis. The method is based on an unconstrained simple mixing model that can be expressed as: 〈displayedItem type="mathematics" xml:id="mu1" numbered="no"〉〈mediaResource alt="image" href="urn:x-wiley:02634929:JMG619:JMG_619_mu1"/〉 where B, A0, and A1-n, are compositional vectors of segregate, source rock and source minerals, respectively. The most important concepts are: (1) degree of partial fusion: FMM= 1/a0; (2) mineral fractionation index: 〈displayedItem type="mathematics" xml:id="mu2" numbered="no"〉〈mediaResource alt="image" href="urn:x-wiley:02634929:JMG619:JMG_619_mu2"/〉 and (3) plagioclase differentiation index: 〈displayedItem type="mathematics" xml:id="mu3" numbered="no"〉〈mediaResource alt="image" href="urn:x-wiley:02634929:JMG619:JMG_619_mu3"/〉 .For a given mineral, the MFI values have the following meaning: (a) MFI 〈0: residual phase originated, at least partly, as a product of incongruent melting; (b) 0 〉 MFI 〈1: preferential retention in the residue; (c) MFI= 1: identical modal fraction in source and melt; (d) a0 〉 MFI 〉 1: preferential incorporation into the segregate, and (e) MFI 〉 a0: external contribution to the anatectic system defined by a0A0. To test the method and illustrate its use, it was applied to two real problems of partial melting in the Peña Negra Anatectic Complex (Central Spain). The first is a very simple case of segregation of a diktyonitic neosome from an orthogneiss through partial melting located in vertical shear zones. This process is characterized by: (1) FMM= 0.51; (2) active incorporation of K-feldspar, plagioclase and biotite into the segregate; (3) disequilibrium melting of plagioclase; (4) residual behaviour of quartz and ilmenite. The second case concerns the formation of a cordierite-bearing granite from granodioritoid diatexites through an anatectic process, whose most salient characteristics are: (1) FMM= 0.45; (2) incongruent melting of biotite; (3) residual behaviour of plagioclase, which melted with a PDI of 1.22; (4) preferential incorporation of quartz into the segregate; (5) total extraction of K-feldspar from the residue.

Notes: Graphitic metapelites from the Howard Ridge area, British Columbia, have been studied to estimate the pressure, temperature and fluid composition attending amphibolite facies metamorphism. Results from thermobarometric calculations indicate that P-T conditions of 610–625°C and 6.7kbar were reached during metamorphism. The equilibrium paragonite-quartz-albite-kyanite-H2O gives significantly different estimates of XH2O in the metamorphic fluid using different paragonite solution models. Estimates of XH2O range from a maximum of 0.93 (Eugster et al., 1972) to a minimum of 0.29 (Chatterjee & Flux, 1986). H2O estimates obtained using the Eugster et al. (1972) and Chatterjee & Froese (1975) solution models give similar results (i.e. 0.8 ± 0.1 versus 0.7 ± 0.1, respectively). Non-ideal mixing in the C-O-H system provides an XH2O estimate of 0.74 at H2O maximum conditions, 0.5 log units below the QFM buffer. The Chatterjee & Flux (1986) paragonite solution model provides unrealistically low estimates of XH2O relative to other paragonite solution models, C-O-H equilibria, and published fluid inclusion and mineral equilibria data. Consistent estimates of fluid composition between C-O-H and mineral equilibria suggest that a H2O-rich fluid attended metamorphism of graphitic metapelites at Howard Ridge.

Notes: Rocks from the metamorphic basement of the Azuero and Sona peninsulas, Panama, consist of schistose amphibolites and minor amounts of metasediment. In the Sona peninsula, strongly zoned amphiboles indicate that the amphibolites followed a progressive anticlockwsie P-T path prograde from low T/low P to medium T/high P, and are retrograded into the greenschist facies. In contrast, the amphibolites of the Azuero peninsula are affected by a low to medium T/low P metamorphism.The metamorphic events of the Sona amphibolites occurred prior to the intra-Senonian tectonic phase which affects the Mesozoic formations along the Pacific coast of Costa Rica and Panama. The regional significance of such a basement in Isthmian Central America is discussed.

Notes: Microstructural and petrological data from the Jumping Brook metamorphic suite, western Cape Breton Highlands, suggest that a single episode of syntectonic prograde metamorphism, followed by uplift, cooling and associated retrogression, affected these rocks during mid-Palaeozoic times. Microstructures indicative of progressive crenulation foliation development can be traced from low-grade (chlorite zone) through high-grade (kyanite zone) rocks, allowing a clear sequence of porphyroblast growth to be established. Metamorphic reactions and P-T calculations suggest metamorphic conditions of 700-750°C at 8-10 kbar were achieved in kyanite zone rocks. Although a complete P-T-t path was not defined, combined petrological and geochronological data can be used to constrain computed P-T-t models. These models suggest that a component of post-metamorphic tectonic exhumation is required to explain the observed times of cooling and uplift. The microstructural and petrological data to not support the interpretation that the high-grade rocks represent pre-existing crystalline basement. Indeed, the metamorphic history, geochronology and computed tectonic models all point to a single, short-lived episode of Silurian-Devonian volcanism, intrusion, convergence, regional metamorphism and uplift, probably resulting from collision tectonics at an irregular continental margin.

Notes: Dissolution and solution transfer during deformation/metamorphism are controlled by the partitioning of deformation into progressive shearing and shortening components. Progressive shearing is readily accommodated by slip on the planar crystal structure of phyllosilicates and graphite without accumulating dislocation density gradients across grain boundaries.Progressive shortening is accommodated by the cores of most other minerals (including sulphides). These minerals develop strain, and hence dislocation density gradients, on their rims due to progressive shearing along grain boundaries. These gradients are particularly large when the mineral abuts phyllosilicate or graphite. The resulting chemical potential gradients between the core and rim drive dissolution, causing removal of the highly strained grain margins.Removal of dissolved material by solution transfer is aided by the geometry of shearing of phyllosilicates and graphite around other grains in an active anastomosing foliation. Interlayers and interfaces on boundaries lying at a low angle to the direction of shearing, and oriented relative to the sense of shear such that they can open, gape by small amounts. Water present in these interlayer spaces becomes destructured, considerably enhancing diffusion rates along the foliation.Penetrative volume loss, especially in deforming/metamorphosing pelitic rocks, is large at all metamorphic grades, increasing and becoming more penetrative with depth to at least the transition into granulite and eclogite facies. Transference of material by fluid flow from deep to high levels in the earth's crust is precluded because thousands to tens of thousands of rock volumes of fluid are required, necessitating continual recirculation of fluid from shallow to deep crustal levels in one large or several small sets of cells, unless some extremely large-scale form of fluid channelling is possible. Reassessment of diffusion mechanisms, and hence rates, during deformation and pervasive foliation generation in large volumes of rock where fluid channeling cannot provide enough fluid, indicates that diffusion can proceed with sufficient rapidity that massive recirculation of fluid is no longer required. The amount of fluid can be reduced sufficiently to allow large volume losses by a one-way flow of fluid to the earth's surface, in deforming/metamorphosing environments where the fluid pressure equals or exceeds the hydrostatic pressure.Deformation partitioning-controlled dissolution progressively changes the bulk chemistry of a rock containing phyllosilicates or graphite during deformation/metamorphism because matrix minerals, other than phyllosilicates and graphite, are preferentially removed. The large size of porphyroblasts, if present, tends to preserve them from dissolution. Hence, the bulk chemistry operative during subsequent porphyroblast growth can have changed considerably from that operative when the first porphyroblasts grew, in rocks in which bedding is still well preserved.

Notes: Low-pressure granulite facies metasedimentary gneisses exposed in MacRobertson Land, east Antarctica, include hercynitic spinel-bearing metapelitic gneisses. Peak metamorphic mineral assemblages include spinel + rutile + ilmenite + sillimanite + garnet, spinel + ilmenite + sillimanite + garnet + cordierite, ortho-pyroxene + magnetite + ilmenite + garnet, spinel + cordierite + biotite + ilmenite and orthopyroxene + cordierite + biotite, each with quartz, K-feldspar and melt. The presence of garnet + biotite- and cordierite + orthopyroxene-bearing assemblages implies crossing tie-lines in AFM projection for the K2O-FeO-MgO-Al2O3-SiO2-H2O (KFMASH) system. This apparent contradiction, and the presence of spinel, rutile and ilmenite in the assemblages, is acounted for by using the KFMASH-TiO2-O2 system, i.e. AFM + TiO2+ Fe2O3. We derive a petrogenetic grid for this system, applicable to low-pressure granulite facies metamorphic conditions. Retrograde assemblages are interpreted from corona textures on hercynitic spinel and Fe-Ti oxides. The relative positions of the peak and retrograde metamorphic assemblages on the petrogenetic grid suggest that corona development occurred during essentially isobaric cooling.

Notes: Sequential reaction textures in Archaean garnet-corundum-sapphirine granulites from the Central Zone of the Limpopo Belt document a progression from early, coarse-grained, high-pressure (P 〉 9.5 kbar) granulite-facies assemblages (M1) to late, low-pressure (P 〈6 kbar) granulite-facies sub-assemblages (M2).The stable M1 assemblage was garnet (57% pyrope; Mg/(Mg + Fe) = 62) + sapphirine + corundum + gedrite + phlogopite + rutile. Late-M1 boron-free kornerupine grew at the expense of garnet and corundum, and coexisted with garnet, sapphirine and gedrite. Partial or complete breakdown of coarse garnet and kornerupine during M2 resulted in the development of pseudomorphs and coronas consisting of fine-grained symplectic intergrowths of cordierite, gedrite and sapphirine (later, spinel).The majority of reaction textures can be explained in terms of a stable reaction sequence, and a model time-sequence of mineral facies can be constructed. When compared with a qualitative petrogenetic grid of (Fe, Mg)-discontinuous reactions in the FMASH multisystem sapphirine-garnet-corundum-spinel-cordierite-gedrite-kornerupine, the facies-sequence indicates decompression at essentially constant T assuming constant a(H2O).Exhumation of M1 corundum inclusions during M2 breakdown of kornerupine resulted in production of metastable spinel by a disequilibrium reaction with gedrite. A second disequilibrium reaction of the spinel with cordierite produced sapphirine. The operation of such reaction while pressure was decreasing (the opposite dP from that implied by the texture if assumed to be the product of an equilibrium reaction) has serious implications for the use of reaction textures in the construction of P-T vectors.Garnet-biotite thermometry on garnet interiors and phlogopite inclusions in corundum yields temperatures of ca. 850°C for the M1 stage. A minimum late-M1 pressure of ca. 7 kbar is indicated by the former association of kornerupine and corundum. Relict M1 kyanites reported by other workers indicate a minumum early-M1 pressure of 9.5 kbar, implying metamorphism at depths of at least 33 km (probably 〈inlineGraphic alt="geqslant R: gt-or-equal, slanted" extraInfo="nonStandardEntity" href="urn:x-wiley:02634929:JMG383:ges" location="ges.gif"/〉 38km). The high-pressure granulite-facies metamorphism was followed by an almost isothermal pressure decrease of 〉 5 kbar, indicative of rapid uplift. The P-T path is interpreted as the product of a single metamorphic cycle which probably took place in response to tectonic thickening of the crust. Such a process contrasts with the extensional origin recently proposed for isobarically cooled granulite-facies terranes.

Notes: The early metamorphic history of high-grade exotic blocks in the Franciscan Complex may be more complicated than previously supposed. The different assemblages of high-grade glaucophane schist, eclogite, amphibolite and hornblende schist are commonly considered to have formed at the same time from essentially unmetamorphosed oceanic crust. However, new textural and mineralogical data presented here suggest that high-grade glaucophane schist and eclogite have replaced an earlier epidote-amphibolite facies assemblage that is identical to the primary assemblages in many of the hornblende-rich blocks. At least some of the hornblende-rich blocks may therefore be well-preserved remnants of the earlier metamorphism. Comparison of the mineral assemblages and element partitioning in the mixed-assemblage blocks suggests that the glaucophane schist and eclogite metamorphism took place at slightly lower temperatures but at the same or higher pressures than the earlier, hornblende-forming stage.

Notes: The High Himalayan Crystallines (HHC) of SE Zanskar consist of biotite paragneisses, of orthogneisses that derive from early-Palaeozoic granitoids, of minor metabasics and of post-metamorphic leucogranites of Miocene age.Two main metamorphic events have been documented in the HHC. The first event occurred at P= 12.0 ± 0.5 kbar and T= 750 ± 50° C in rare metabasics intruded by early-Palaeozoic granitoids. In the biotite paragneisses, thermobarometric estimates of the first event point to comparable T at P 4–5 kbar lower. The first event is followed by a pervasive syn-tectonic crystallization characterized by lower P and T. On the basis of the cooling ages of the metamorphic minerals and on the geological evidence, the second event is referred to the Tertiary Himalayan crystallization. Further petrological and geochronological studies are necessary to prove whether a few mineral relics ascribed to the first event define a polyphase Himalayan evolution or if they record the incomplete obliteration of an older history during the Himalayan event.The HHC of SE Zanskar show a decrease in metamorphic grade from the middle structural levels upward, close to the Kade unit, and downward, close to the Lesser Himalaya (from sillimanite-K-feldspar-biotite-bearing assemblages to kyanite-staurolite-muscovite-bearing assemblages). This metamorphic zonation is probably a consequence of the polyphase history of intracontinental thrusts and of the tectonic emplacement of hot crustal slabs within shallower and colder thrust sheets at relatively late stages of the continental collision between India and Eurasia.

Notes: Blueschists occur along the Indus Suture Zone in Ladakh as tectonic thrust slices, as isolated blocks within mélange units and as pebbles within continental detrital series. In the Shergol-Baltikar section high-pressure rocks within the Mélange unit lie between the Dras-Naktul-Nindam nappes in the north and the Lamayuru units in the south. The blueschists are imbricated with mélange formation of probably upper Cretaceous age. They are overlain discordantly by the Shergol conglomerate of post Eocene (Oligo-Miocene ?) age. Blueschist lithologies are dominated by volcanoclastic rock sequences of basic material with subordinate interbedding of cherts and minor carbonates. Mineral assemblages in metabasic rocks are characterized by lawsonite-glaucophane/crossite-Na-pyroxene-chlorite-phengite-titanite ± albite ± stilpnomelane. In the quartz bearing assemblages garnet is present but omphacite absent. P-T estimates indicate temperatures of 350 to 420°c and pressures around 9–11 kbar. Geochemical investigations show the primary alkaline character of the blueschist, which suggests an oceanic island or a transitional MORB type primary geotectonic setting. K/Ar isotopic investigations yield middle Cretaceous ages for both whole rocks and minerals. Subduction related HP-metamorphism affecting the Mesozoic Tethyan oceanic crust developed contemporaneously with magmatism in the Dras volcanic are and the Ladakh batholith. Subsequent collision of India with Asia obducted relics of subduction zone material which later became involved in nappe emplacement during the Himalayan mountain building.

Notes: Mineral assemblages in pelitic, mafic, calcareous and ultramafic rocks within a metamorphosed tectonic mélange indicate that the Marble Mountain terrane and adjacent Western Hayfork subterrane (northern California) underwent regional low- to medium-pressure amphibolite facies metamorphism. Metamorphic conditions estimated by comparison of observed assemblages with experimentally-determined reaction boundaries and by geothermometry constrain metamorphic temperatures between about 500° and 570°C. The occurrence of andalusite in regionally metamorphosed pelites indicates pressures below about 370 MPa. Metabasite amphibole compositions also suggest low to intermediate metamorphic pressures.Metaserpentinites containing the upper amphibolite facies assemblage (olivine + enstatite + anthophyllite) are found locally within the study area and have been reported previously by other workers elsewhere in the Marble Mountain terrane. These assemblages may reflect higher temperatures of recrystallization than assemblages in surrounding rocks and may represent vestiges of an earlier high-temperature metamorphic event undergone by the ultramafic rocks prior to incorporation in the mélange.Although the age of the low- to intermediate-pressure metamorphism is poorly constrained, cross-cutting plutons indicate that metamorphism must be older than about 162 Ma. Therefore this regional metamorphic event, which probably marks the accretion of these terranes to the North American continental margin, is older than the currently accepted 151–147 Ma age of the Nevadan event in the Klamath Mountains. The inferred low to intermediate pressures of metamorphism and the lithologies of the protoliths suggest a near-arc tectonic setting and refute a subduction zone model for this event.

Notes: In regionally metamorphosed pelites of the Mount Raleigh pendant, the fibrolite isograd occurs 5km downgrade from the sillimanite isograd. Fibrolite formed from the decomposition of biotite, a reaction that probably resulted from the late-stage influx of acidic volatiles. In contrast, sillimanite formed by the direct,‘volume-for-volume’replacement of andalusite. Andalusite and sillimanite coexist in a 3 km-wide zone above the sillimanite isograd. Electron probe analyses of these phases reveal low minor element contents and yield KD[=X] values close to unity; the low Fe2O3 contents are compatible with reducing conditions implied by the ubiquity of graphite. Because KD→ 1.0, the zone of coexisting andalusite + sillimanite cannot be attributed to multivariancy resulting from partitioning of minor elements between these phases. Rather, the metastable persistence of andalusite into the sillimanite P-T stability field is suggested. The modal proportions of sillimanite versus andalusite imply that minimal (〈5%) and alusitesillimanite reaction occurred in a zone 1.5km above the sillimanite isograd; in contrast, there was a marked increase in reaction progress immediately above this zone. With an estimated thermal gradient (in the plane of exposure) of approximately 20°C/km, the 1.5 km-wide zone of nil reaction suggests that the andalusite-sillimanite equilibrium boundary was overstepped by about 30 °C before significant reaction occurred. Inclusion-rich areas in andalusite provided favourable sites for sillimanite nucleation; however, the growth of sillimanite may have been impeded by‘pinning’of sillimanite grain boundaries by inclusions.

Notes: Thermobarometric studies on various granulite facies areas along the Prydz Bay coast, East Antarctica (73°-79°E, 68°-70°S), show that, at around 1100 Ma, during a late Proterozoic orogeny, the rocks of the Larsemann Hills suffered a lower pressure metamorphic peak than the surrounding areas. Along the Prydz Bay coast, the rocks affected by this event include parts of the Vestfold Hills block plus all of the Rauer Group, the Larsemann Hills and the Munro Kerr Mountains. The dykes in the south-west corner of the Vestfold Hills were recrystallized during this event with little deformation at temperatures not quite as high as in the areas further south-west (650°C, 6.5 kbar) (Collerson et al., 1983), the Rauer Group was metamorphosed at 800°C and 7.5 kbar (Harley, 1987a), the Larsemann Hills at 750°C and 4.5 kbar, and the Munro Kerr Mountains probably at around 850°C and 5 kbar. Retrograde equilibration in the different areas occurred during decompression to about 10 km depth in all areas, followed by isobaric cooling at this depth.This paper shows that the peak metamorphism in the Larsemann Hills occurred at a pressure which is too low to have been the consequence of thermal relaxation of overthickened crust with normal mantle heat flow. Although other areas in Prydz Bay were metamorphosed at sufficiently high pressures so that their decompression paths are not inconsistent with a continental collision model, the inferred pre-metamorphic peak histories and the requirement of consistency with the Larsemann Hills, make it unlikely that collision followed by erosion-driven decompression is an appropriate model. We suggest that the thermal regime of the crust in the Larsemann Hills region was controlled by a perturbation in the asthenosphere, with magma invasion of the crust. We suggest that the 500 Ma event, represented in Prydz Bay by granitic outcrops at Landing Bluff and by several K/Ar ages from the Larsemann Hills area, was responsible for the final excavation of the terrane.

Notes: Detailed microstructural analysis of inclusion trails in hundreds of garnet porphyroblasts from rocks where spiral-shaped inclusion trails are common indicates that spiral-shaped trails did not form by rotation of the growing porphyroblasts relative to geographic coordinates. They formed instead by progressive growth by porphyroblasts over several sets of near-orthogonal foliations that successively overprint one another. The orientations of these near-orthogonal foliations are alternately near-vertical and near-horizontal in all porphyroblasts examined. This provides very strong evidence for lack of porphyroblast rotation.The deformation path recorded by these porphyroblasts indicates that the process of orogenesis involves a multiply repeated two-stage cycle of: (1) crustal shortening and thickening, with the development of a near-vertical foliation with a steep stretching lineation; followed by (2) gravitational instability and collapse of this uplifted pile with the development of a near-horizontal foliation, gravitational spreading, near-coaxial vertical shortening and consequent thrusting on the orogen margins. Correlation of inclusion trail overprinting relationships and asymmetry in porphyroblasts with foliation overprinting relationships observed in the field allows determination of where the rocks studied lie and have moved within an orogen. This information, combined with information about chemical zoning in porphyroblasts, provides details about the structural/metamorphic (P-T-t) paths the rocks have followed.The ductile deformation environment in which a porphyroblast can rotate relative to geographic coordinates during orogenesis is spatially restricted in continental crust to vertical, ductile tear/transcurrent faults across which there is no component of bulk shortening or transpression.

Notes: The western metamorphic belt of the Coast Plutonic Complex, south-east Alaska and adjacent British Columbia, contains strongly deformed rocks and a prominent topographic low: the Coast Range megalineament. Near Holkham Bay, south-east Alaska, the lineament separates the western metamorphic belt into: a western low-grade (greenschist facies) terrane, and an eastern medium-grade (amphibolite facies) terrane.Sphalerite compositions of grains in direct contact with pyrite and pyrrhotite in chlorite-muscovite zone rocks in the low-grade terrane give pressures of about 8 kbar; compatible with pressures of 8-10 kbar at 500°C calculated from plagioclase-biotite-garnet-muscovite assemblages adjacent to the Windham Bay pluton about 15 km away. A pressure of 4.8 ± 0.7 kbar was calculated from sphalerite compositions in staurolite zone rocks east of the Coast Range megalineament. This is indistinguishable from pressures of 4.8 ± 1 kbar at 585°C and 5.1 ± 1 kbar at 680°C (plagioclase-garnet-aluminum silicate-quartz equilibria), and 4.1 ± 1 kbar at 585°C (plagioclase-biotite-garnet-muscovite equilibrium) determined for the medium-grade terrane. An identical pressure of 4.8 ± 0.7 kbar was calculated from sphalerite compositions in biotite zone rocks adjacent to the lineament; this is considerably higher than a pressure of 3.1 ± 1 kbar at 525°C obtained using plagioclase-biotite-garnet-muscovite geobarometry from shear zones within the lineament. The discrepancy may be explained by later equilibration of mineral phases within the shear zones.The geothermobarometry suggests relatively low temperatures and high pressures for the low-grade terrane (6-10 kbar), and intermediate temperatures and pressures for the medium-grade terrane to the east (4-6 kbar). Comparison of the barometers indicate that sphalerite can be used to estimate metamorphic pressures, similar to those estimated from silicate mineral chemistry when pyrrhotite-sphalerite-pyrite assemblages are used.

Notes: Metabasalts and metasedimentary rocks of the Devonian Central Metamorphic Belt comprise the lower plate of the east-dipping Trinity thrust system in the Klamath province. An inverted metamorphic gradient is preserved in the Central Metamorphic Belt; metamorphic conditions decrease from amphibolite facies adjacent to the Trinity thrust, through albite-epidote amphibolite facies, to upper greenschist facies at the base of the Central Metamorphic Belt. Mineral chemistry, mineral assemblages and limited geothermometry suggest that peak metamorphic conditions decrease structurally downward from 650 ± 50° C at the Trinity thrust to 500 ± 50° C at the base of the Central Metamorphic Belt, under pressures of 5 ± 3 kbar. Synmetamorphic Ab + Qtz veins, up to 1 m thick, increase in abundance towards the Trinity thrust. Infiltration of H2O-CO2 fluids derived from prograde devolatilization reactions in the Central Metamorphic Belt caused extensive hydration and metasomatism of the Trinity peridotite; the hanging wall block of the Trinity thrust zone.Geological relationships and the preserved inverted metamorphic gradient suggest that the Central Metamorphic Belt formed in an east-dipping Devonian subduction zone in an oceanic environment. The Central Metamorphic Belt appears to represent a discrete slice of accreted oceanic crust several km thick, rather than progressively accreted material. Metamorphic pressures recorded by the Central Metamorphic Belt are intermediate between the ∼2 kbar pressures recorded in dynamothermal aureoles beneath obducted ophiolites and the 7–10 kbar preserved in subduction-related inverted metamorphic gradients. The lack of blueschist facies mineral assemblages in the Central Metamorphic Belt may possibly be explained by an anomalously warm geotherm prior to subduction or early shear heating prior to the arrival of wet rocks at depth.

Notes: The Bunger Hills, East Antarctica, experienced a low-pressure granulite facies orogenic event during the Proterozoic. The stable coexistence of the S1 foliation-parallel M1 assemblages, garnet-cordierite-spinel-ilmenite and garnet-sillimanite-spinel-ilmenite-rutile, in quartz-bearing pelitic gneisses is evidence for metamorphic peak pressures of around 4 kbar during M1, at temperatures of about 800°C. The growth of massive reaction coronas of garnet and cordierite around hercynitic spinel and iron-titanium oxides during M2 is evidence for the destabilization of the M1 assemblages during compression. Thermodynamic calculations on the M2 assemblages indicate formation pressures of 6–7 kbar at temperatures of about 750°C. Thus, the gneisses from the Bunger Hills indicate about 2 kbar or more of compression during minimal cooling. Such a P-T path is different from that of many other Proterozoic terranes which are characterized by isobaric cooling or decompression. A large charnockite body, which is undeformed, was intruded at ∼950°C, towards the end of compression.The low pressures during M1 can be best explained by metamorphism at mid-crustal levels in thin continental crust in thin lithosphere above a thermal perturbation in the underlying asthenosphere. We suggest that the compression during cooling was a result of gravitational backflow in which the action of body forces between adjacent normal thickness crust and the thin crust of the Bunger Hills is 'switched on’by the thermal perturbation. Within such a model, the timing of intrusion of the charnockite exposed in the Bunger Hills is consistent with its generation by partial melting during the metamorphic maximum of the lowermost crust.

Notes: There is no significant difference in the diffusion profiles across albite-adularia bicrystals that were simultaneously deformed at a strain rate of 10-6S-1 and those from hydrostatic experiments at the same conditions (1500 MPa and 1000°C for 156 h). This indicates that the bulk alkali diffusion rate, which is the sum of lattice diffusion (D, 1) and dislocation pipe diffusion (Dp), is not significantly enhanced by dislocations at these conditions, and that the maximum value for the ratio of Dp/D1 is about 105. This is equal to the value previously reported for‘oxygen’diffusion in albite. If this ratio is independent of temperature, the contribution of either static (pre-deformed) or moving (syn-deformed) dislocations to the bulk diffusion rate of alkalis is probably minor at all metamorphic conditions. For Al and Si diffusion the ratio of Dp/D1 may be larger if D1 is lower. Thus a significant contribution from dislocations to bulk diffusion cannot be ruled out, especially during simultaneous deformation.

Notes: In the Woodroffe Thrust mylonite zone, central Australia, recrystallization in plagioclase and K-feldspar involved subgrain rotation, assisted by grain-boundary or kink band boundary bulging, without contribution from a change in the chemical composition from host grains to new grains. The size of subgrains and new grains changes across the mylonite zone, apparently as a function of the strain rate and the H2O content of the rock.The partitioning of deformation into zones of progressive shearing and progressive shortening controls the sites of recovery and recrystallization in feldspar during mylonitization. The size of feldspar porphyroclasts in well developed mylonites is governed by the scale of deformation partitioning reached in the earlier stages of mylonitization, before the formation of a large proportion of fine-grained matrix that can accommodate the progressive shearing component of the deformation.Recrystallization occurs in microcline, apparently without involving a translation to a monoclinic structure, as microcline-twinned new grains are common adjacent to microcline-twinned host grains. K-feldspar triclinicity values calculated from XRD traces increase from the margins to the interior of the mylonite zone, in conjunction with deformation intensity. K-feldspar host grains locally have cores of orthoclase or untwinned microcline, surrounded by mantles of twinned microcline, suggesting a relationship between the presence of microcline twinning and the degree of K-feldspar triclinicity.

Notes: The decrepitation behaviour of fluid inclusions in quartz at one atmosphere confining pressure has been evaluated using pure H2O synthetic inclusions formed by healing fractures in natural quartz. Three different modes of non-elastic deformation, referred to as stretching, leakage or partial decrepitation, and total decrepitation have been observed. The internal pressure required to initiate non-elastic deformation is inversely related to inclusion size according to the equation:internal pressure (kbar) = 4.26 D-0.423where D is the inclusion diameter in microns. Regularly shaped inclusions require a higher internal pressure to initiate non-elastic deformation than do irregularly shaped inclusions of similar size. Heating inclusions through the α/β quartz inversion results in mechanical instability in the quartz crystal and leads to mass decrepitation of inclusions owing to structural mismatches generated by pressure gradients in the quartz around each inclusion.Long-term heating experiments (∼2 years) suggest that the internal pressure required to initiate non-elastic deformation does not decrease significantly with time and indicates that short-lived thermal fluctuations in natural systems should not alter the inclusion density and homogenization temperature. Inclusions that do exhibit decreased density (higher homogenization temperature) are, however, always accompanied by a change in shape from irregular to that of a negative crystal.Observations of this study are consistent with elasticity theory related to fracture generation and propagation around inclusions in minerals. These results indicate that an inclusion will not be influenced by a neighbouring inclusion, or other defect in the host phase, as long as the distance between the two is 〉2–4 diameters of the larger of the two inclusions.

Notes: Sapphirine has been found in two types of magnesian, metabasic lenses from tectonite zones within the Central Gneiss Belt of the south-west Grenville Province, Canada. The first type (association I) comes from a lenticular mafic lens within highly tectonized anorthosite, the second type (association II) comes from meta-eclogitic pods with foliated amphibolite rims. In each case the sapphirine-bearing assemblages record a wealth of reaction textures. The primary mineralogy in association II is represented by high alumina clinopyroxene, garnet and kyanite ± plagioclase and records pressures of around 14-16 kbar; in association I the primary mineralogy is represented by plagioclase, two pyroxenes and possibly olivine but here the equilibrium pressure is unknown.The host gneisses equilibrated at approximately 8 to 10 kbar and 700-750°C by continuous cation exchange reactions during and after the culmination of the Grenvillian orogeny at 1.16-1.0 Ga. It is unlikely that the higher pressures recorded in the meta-eclogitic pods represent an earlier high-pressure metamorphism as the pods are restricted to shear zones. A tectonic mode of emplacement into a crust undergoing granulite facies metamorphism is more likely. Sapphirine formed by discontinuous decompression reactions; in association II this involved a reaction between garnet and kyanite and resulted in the formation of magnesian granulite facies assemblages. At the same time primary clinopyroxene became much less aluminous by evolving plagioclase. Pressures and temperatures from coexisting phases, that are believed to have equilibrated at the same time as sapphirine formation, are estimated as 11 to 12 kbar and 750°C. These probably represent the peak conditions for granulite facies metamorphism in the south-west Grenville Province.

Notes: Several examples of deformation-induced myrmekite have been found in two amphibolite facies mylonites derived from granitic protoliths, namely a muscovite-poor S-C mylonite and a single foliation, muscovite-poor mylonitic gneiss. Back-scattered SEM and conventional optical microscopy show that in both rock types, syntectonic myrmekitic intergrowths of oligoclase and quartz formed on the two sides of K-feldspar grains that faced the local inferred incremental shortening direction for the mylonite. Myrmekite does not occur on the two ends of the grain that faced the incremental stretching direction.The replacement of K-feldspar by plagioclase and quartz results in a volume decrease and is favoured on high normal stress sites around the grains. We suggest that the ambient temperature, pressure and chemical activities were such that the replacement reaction was favoured, but the addition of extra strain energy along the high-pressure sides of the grains localized the reaction at these sites. This energy could arise from elastic strain, or strain associated with tangled dislocations or twin boundaries. The relative roles of stress and strain energy concentrations in driving the replacement reaction are not known, but both were probably important.

Notes: The Main Central Thrust (MCT) south of Mt Everest in eastern Nepal is a 3 to 5km thick shear zone separating chlorite-bearing schist in the lower plate from sillimanite-bearing migmatitic gneiss in the overlying Tibetan Slab. The metamorphic grade increases through the MCT zone toward structurally higher levels. Previous workers have suggested that either post- or synmetamorphic thrust movement has caused this inversion of metamorphic isograds. In an effort to quantify the increase in grade and to constrain proposed structural relations between metamorphism and slip on the fault, four well-calibrated thermobarometers were applied to pelitic samples collected along two cross-strike transects through the MCT zone and Tibetan Slab. Results show an increase in apparent temperature up-section in the MCT zone from 778 K to 990 K and a decrease in temperature to ∼850 K in the lower Tibetan Slab, which is consistent with synmetamorphic thrust movement. A trend in calculated pressures across this section is less well-defined but, on average, decreases up-section with a gradient of ∼28MPa/km, resembling a lithostatic gradient. Pressure-temperature paths for zoned garnets from samples within the MCT zone, modelled using the Gibbs' Method, show a significant decrease in temperature and a slight decrease in pressure from core to rim, which might be expected for upper plate rocks during synmetamorphic thrust movement. Samples from the uppermost Tibetan Slab yield higher temperatures and pressures than those from the lower Tibetan Slab, which may be evidence for later‘resetting’ of thermobarometers by intrusion of the large amounts of leucogranite at that structural level.

Notes: Along a cross-section through the Lesser and Higher Himalayan units at the Kishtwar window area (north-west India), a polyphase, Barrovian-type metamorphism has been delineated in relation to the development of the Main Central Thrust (MCT). In the metapelitic mineral assemblages, three metamorphic phases have been distinguished:〈list xml:id="l1" style="custom"〉(a)conditions up to amphibolite grade at moderate to high pressures (alm + rut + ilm + kya + qtz) characterize the M1 phase;(b)pressure release and/or temperature increase as a result of movement along the MCT and the formation of gneiss domes in the Higher Himalaya, as expressed by oriented (N70°-100° E) fibrolite, defines the M2 phase; and,(c)finally during uplift of the Kishtwar window area, a retrogressive M3 phase is characterized by the assemblage quartz-muscovite-chlorite.Both optically zoned and single-stage garnets have been examined with the electron microprobe to determine their element partitioning. Normal zoning has been found in samples below the MCT in the Lesser Himalaya, indicating prograde growth during the M2 phase, whereas tectonically above, in the Higher Himalaya unit, the garnets reveal double-stage growth with a complex zoning pattern due to reaction-partitioning during M1 and M2 and reverse-zoning at their rims during the retrogressive M3 phase. Geothermometry on metapelites along a cross-section through the MCT zone and the Higher Himalaya imply distinct readjustments of garnet-biotite exchange equilibria and indicate isothermal conditions (500-600° C) throughout the section during the M3 retrogression. Pressure calculations (gro-an-kya-qtz and alm-rut-ilm-kya-qtz) suggest a decrease in pressure towards the top of the section (6-7.5 to 4.5-5 kbar), as corroborated by fibrolite replacing kyanite. The spatially inverse metamorphism exposed within the Lesser Himalaya of the Kishtwar window is regarded as a product of polyphase metamorphism combined with ongoing thrusting and shearing and is reflected by condensed M2 isograds around the Kishtwar window.

Notes: The Darjeeling-Sikkim region provides a classic example of inverted Himalayan metamorphism. The different parageneses of pelitic rocks containing chlorite, biotite, garnet, staurolite, kyanite, sillimanite, plagioclase and K-feldspar are documented by a variety of textures resulting from continuous and discontinuous reactions in the different zones. Microprobe data of coexisting minerals show that XMg varies in the order: garnet 〈 staurolite 〈 biotite 〈 chlorite. White mica is a solid solution between muscovite and phengite. Garnet is mostly almandine-rich and shows normal growth zoning in the lower part of the Main Central Thrust (MCT) zone, and reverse zoning in the upper part of the zone. Chemographical relations and inferred reactions for different zones are portrayed in AFM space. In the low-grade zones oriented chlorites and micas and rolled garnets grew syntectonically, and were succeeded by cross-cutting chlorites and micas and garnet rims. In the upper zones sillimanite, kyanite and staurolite crystallized during a static inter-kinematic phase. P-T contitions of metamorphism, estimated through different models of geothermobarometry, are estimated to have been 580°c for the garnet zone to a maximum of 770°c for the sillimanite zone. The preferred values of pressure range from 5.0 kbar to 7.7 kbar. Models to explain the inverted metamorphism include overthrusting of a hot high Himalayan slab along a c. 5 km wide ductile MCT zone and the syn- or post-metamorphic folding of isograds.

Notes: Abstract. A model has been developed based on multiple regression which explains 95% of the variation in nitrate loading of the major rivers in the 4453 km2 Lough Neagh catchment for the years 1971–1987. The model relates loading of nitrate in the hydrological year to fertilizer usage, previous summer rainfall, summer temperature of the current year and December-May flow. It indicates that there is an increase in nitrate loading associated with fertilizer usage, and that the equivalent of 13% of nitrogen fertilizer that is lost as leachate comprises 50% of the river loadings.

Notes: Abstract. The loess plateau in China is the most developed region of loess in the world in terms of extent, thickness and depositional sequence. It is also the region with the most serious soil erosion in the world. This paper reviews the factors and reasons for soil erosion in this area. The loess is prone to vertical cleavage and its surface soils are soft and loose. Rainstorms are frequent with intense rain concentrated during the summer. Irrational land use and exploitive management have been carried out for thousands of years and express themselves through the loss of grassland and natural forests. Finally, some soil conservation schemes for use in the loess plateau are suggested.

Notes: Book reviews in this article: Land resources in the Loess Plateau of China Editor Professor Zhou Xianmo (S.M. Chou).

Notes: Abstract. The WOFOST simulation model is a tool for analysing the growth and production of field crops under a wide range of weather and soil conditions. Such an analysis is important first to assess to what extent crop production is limited by the factors of light, moisture and macro-nutrients, and second to estimate what improvements are possible. The theoretical concept of a production situation, as modelled by WOFOST, is explained, as is the hierarchy of potential production and water-limited and nutrient-limited production situations in the analysis. The organization of the computer files in the model, the structure of the FORTRAN source program and the available standard sets of data are described briefly.

Notes: Abstract. Assuming that other sources of error can be neglected, the reliability of a land suitability classification depends on the homogeneity of physiographically delineated map units with regard to land qualities. The map unit homogeneity of a small area in France was estimated using 64 observation points, arranged according to a nested sampling scheme, followed by nested analysis of variance.The analysis shows that in this area map units are too heterogeneous to accept the suitability classification as being completely reliable. However, alternative procedures using methods of optimal interpolation to map gradual change within the physiographic units are too expensive at a mapping scale of 1:25000 or smaller. It is not possible to produce completely accurate suitability maps at smaller scales. However, incorporating nested sampling and analysis of variance as standard procedures in land evaluation surveys costs little effort and yields at least an estimate of map accuracy and reliability of the suitability classification.

Notes: Abstract. The ultimate goal of resource monitoring is to analyse the spatial distribution of the balance between supply and demand of a certain resource. Remote sensing techniques are commonly used for the assessment of the supply of resources. By integrating remote sensing with the related techniques of geographical information systems and spatial modelling, the demand as well as the accessibility of resources can be analysed. The article gives an overview over methods for integrated resource monitoring. Examples from arid environments are also presented.

Notes: Abstract. Since 1981 information on land sales has been recorded in the Land Register for some counties in Scotland. Rural land sale data for areas of more than 10 hectares in Renfrewshire have been analysed to determine the extent to which land capability, elevation and slope have an influence on land value. Although many factors influence the price paid for rural land, the effect of land capability in particular is demonstrated, with altitude having a minor effect. Using a best fit curvilinear model price ranges are predicted on the basis of land capability classes.

Notes: Abstract. Experiments on the effects of stockpiling soil on an opencast coal mine in Derbyshire showed that there were significant changes in the microbial community. Numbers of aerobic bacteria in stored soils ranged from 0.5 to 12.8 ± 107 colony-forming-units (CFU)g-1 with the smallest values being in the deepest parts of the oldest stores, whereas an adjacent undisturbed soil contained 6.6 ± 107 CFU g-1. There was a greater effect on the numbers of fungal spores, which ranged from 0.1 to 6.7 ± 105 CFU g-1 soil, all less than the 10 ± 105 CFU g-1 recorded for the undisturbed control soil. The number of fungal spores in the deepest part of the older soil stores was only 1/100 of the number in the undisturbed soil. This was mirrored by the biomass values, as determined by adenosine triphosphate (ATP) assay. Values of ATP ranged from 0.38 to 13.13 nmol g-1 as compared to 5.8 nmol g-1 in the undisturbed soil. All three of these microbiological properties decreased in value with both age and depth of storage. Neither anaerobic nor spore-forming bacterial numbers were greatly affected by storage.The pH values tended toward neutrality in the deeper parts of the soil stores, and there was less organic matter in the older stores.

Notes: Abstract. Increasing the ploughing depth and ploughing in grassland has been common in Germany during the past 20 years. Incubation studies were conducted with topsoils from luvisols and gleysols at different times after change of management in order to assess its influence on nitrogen mineralization and its kinetic parameters.The results show that deep ploughing slows the mineralization of nitrogen. The difference between earlier (1967–72) and more recently (1980–82) deepened topsoil has become smaller after a further three years of cultivation, however. The preceding crops (wheat or sugar beet), the amount of N fertilizer as well as clay and nitrogen contents cause a variation in N mineralization. The results indicate a continuing approach of an‘equilibrium’organic matter and nitrogen content. The enrichment capacity of intensively managed soils may be replenished within 10 years.Gleysols formerly under grass mineralize more nitrogen than‘traditionally’ploughed soils, even 27 years after the ploughing-in. While nitrogen from easily decomposable materials decreases within the first 10 years, the resistant fraction is a long-lasting determinant for N mineralization. Both processes need to be considered when applying fertilizer to minimize nitrate leaching.

Notes: Abstract. A number of restored areas, a soil store and undisturbed areas on opencast coal mine sites, all of similar soil type, were sampled. The microbiological activity (dehydrogenase assay), nitrogen mineralization and nitrifying potentials and physico-chemical characteristics of the soils were determined. Dehydrogenase activities ranged from 140 to 580 μg TPF g-1 24 h-1 in undisturbed control soils, whereas the disturbed soils had activities of 10 to 220 μg g-1 24 h-1, with the smallest activities being recorded in the stored and most recently reinstated soil, indicating that disturbance has depressed microbial activity. Nitrogen mineralization potential was significantly affected by disturbance, with a value of 18 to 26 μg inorganic N g-1 21 d-1 in the soil store and 38 μg-1 21 d-1 in a soil reinstated for six months, although the values were less than this in soils reinstated for up to six years. Nitrifying potential was not significantly less in the stored soils, being within the range of 60 to 135 μg nitrate N formed g-1 soil 21 d-1, which was similar to that found in the undisturbed control soil.The water-holding capacity was less in the stored soil than the undisturbed controls, and was significantly less in soil reinstated for 1.5 to 2.5 years, being only 65% of the undisturbed value (0.66 g water g-1 soil). Ammonium content of the soil store was one hundred fold larger in the soil store than in the controls (0.6 to 1.7 μg ammonium N g-1). The carbon contents in the control soils ranged from 4.5 to 7.2%, whereas the stored and reinstated soils had generally less amounts ranging from 1.6 to 5.8%. There was a significant and positive correlation between water-holding capacity and nitrifying potential.The implications for long-term restoration are discussed.

Notes: Abstract. Water samples from ditches draining small upland areas in mid-Wales were collected before, during and after the improvement of the pasture using two different cultivation techniques. The samples were analysed for nitrogen, phosphorus, potassium and pH. The greatest release was associated with disc harrowing where nitrogen, in its nitrate form, exceeded European Economic Community maximum recommended concentrations for potable water supply for two weeks. Smaller losses of nitrogen, in the ammonium form, and of ortho-phosphate were observed following a minimum cultivation technique. It is concluded that, on a scale normally associated with upland Britain, pasture improvement is not likely to deteriorate significantly the quality of runoff within water supply catchments. This is confirmed by the results obtained from monitoring streamflow from catchments in which some degree of pasture improvement had been undertaken in the past.

Notes: Abstract. Direct drilling was compared with mouldboard ploughing on a sandy clay loam using winter wheat as the test crop for a period of four years (1978/79 to 1981/82). The effect of short- and long-term sequences of direct-drilling on grain yield from 1981/85 was also investigated and in 1983/84 and 1984/85 the effect of soil loosening by a slant-legged subsoiler, the‘Paraplow'. The range in annual mean yields was 7.19 to 9.32 t ha-1. There were no significant differences in grain yield between direct-drilling and ploughing except in 1979 when direct-drilled wheat yielded 0.60 t ha-1 more than wheat after ploughing. The number of years the land had been direct-drilled had no effect on grain yield.Using a slant-legged subsoiler on direct-drilled land significantly reduced cone resistance and increased root density, but these effects were variable across the working width of the implement. Subsoiling did not increase yield in 1983/84, and in 1984/85 it reduced yield by 0.45 t ha-1.Long-term direct drilling of winter wheat on the Tickenham soil series is unlikely to result in a loss of yield provided straw is burnt and grass weeds are controlled.

Notes: Abstract. Changes in aggregate stability, density, and porosity as well as the water retention and nutrient contents of different aggregate size fractions due to intensive tillage were investigated. Three soils from Vicarello, Fagna and Gambassi in North Central Italy which had been under permanent vegetation, minimum or conventional tillage for more than seven years were studied. The aggregates on conventionally tilled plots were slightly denser and less porous than those on the untilled or minimum-tilled plots. The aggregates were less stable under conventional tillage on all soils. Conventional tillage reduced the proportion or macro-aggregates by 22% at Vicarello and 35% at Gambassi. There were no differences in macro-aggregate proportions between minimum- and conventionally tilled plots at Fagna. The potential of the dry aggregates to distintegrate upon contact with water was greatest in the conventionally tilled and least in the untilled treatments. The proportions of dry macro-aggregates (〉 0.25 mm) in the untilled and tilled plots were 90 and 71%, respectively. The soil of the tilled plots contained less carbon and nitrogen than that of the untilled plots in all aggregate size fractions. The silt-plus-clay contents of the aggregates accounted for between 65 and 93% of variability in the water they retained at small potentials while organic carbon contents accounted for between 71 and 90% of variability in the stability of the aggregates irrespective of the tillage treatments.

Notes: Abstract. Between 1981 and 1987 field experiments were made on loam and sandy loam soils to test the effects of nitrogen, phosphorus and sulphur fertilizers on the yield and quality of linseed, and the uptake of S by the crop. In one experiment, all through the six years, the application of fertilizers up to 60 kg N, 40 kg P2O5 and 30 kg S ha-1 increased yields. In the second experiment, the same combination of N, P and S maximized crop yield, uptake of P and S, % oil and oil production. These balanced and optimum rates of fertilizers decreased the percentage of stearic, oleic and linoleic acids but increased that of linolenic acid by accelerating the metabolic pathway of linolenic acid synthesis. Applying P decreased the removal of native S in the soil but when more S was applied, more native S was taken up. Large dressings of P diminished crop yield and quality as well as the availability of native soil S.

Notes: Soil Management. A Practical Guide to the Use and Management of Soils. By T. Batey.

Notes: Abstract. The topsoil widely bought and sold for landscaping and similar schemes is intended to cover poor substrates and to provide improved growing conditions for plants. Two extensive surveys have shown that top soils at present being used are of very poor quality and rarely meet this requirement. Many of the substrates that the topsoils cover out-perform them, or can readily be improved to do so if modern land reclamation techniques are used.From this it follows that there could, and should, be (i) much more discretion in the use of topsoil, (ii) more attention paid to the improvement of existing substrates, (iii) more consideration given to the use of other materials as topsoil substitutes, and (iv) more care taken in the choice of top soil materials where these have to be used.It is suggested that the present British Standard for topsoil is inadequate and that is should be replaced by a three-tier system in which there would be separate specifications for; (i) high grade topsoil, (ii) lower grade topsoil, (iii) materials which can act as topsoil substitutes. In this way it should be possible to obtain a better and more reliable performance in landscaping schemes and lower costs.

Notes: Abstract. The performances of 16 different sand and sand-soil root zone constructions were examined during three seasons of simulated football-type wear. Water infiltration rates were controlled mainly by the percentage of sand in the rooting matrix although the type of sand also had a strong effect in the pure sand root zones. Even mixes with 91% sand had poor infiltration after two seasons of wear and suffered from occasional ponding after heavy rain. Pure sand root zones and high-specification sand-soil mixes had better grass retention and a firmer surface in wet weather than root zone material with sand contents 〈 90%. Traction values for the different root zone materials were similar, except for a pure sand construction based on a coarse 0.25–1.0 mm diameter sand. However, pure sand constructions can become unstable, particularly in dry conditions if the ground cover is less than 20%. Strategies for the use of sand amelioration and pure sand root zones are discussed in relation to the demands of particular user groups.

Notes: Abstract. Fertilizer application to sports turf has a significant effect on the playing characteristics of the surface as well as its aesthetic appearance. Nutrient availability affects leaf and root density, infestation by weed species, resistance to fungal pathogens, tolerance to wear, drought and cold in the turf grasses and surface hardness. The increasing use of high sand content, free-draining root zones for sports areas is leading to a larger demand for nitrogen and also to an increased interest in the use of slow-release nitrogen fertilizers. The optimum nutrient application rates are examined, particularly for nitrogen and the direction in which research on fertilization practice should take is considered.

Notes: Abstract. Techniques for restoring mineral workings to agriculture, forestry or amenity uses are described. An integrated scheme of working and restoration is vital, taking account of the soil resources available, appropriate methods of soil handling (usually by earthscraper or dump-truck and excavator) and a programme of aftercare including underdrainage. Changes in soil during storage are discussed. Some of the potential problems where the site is infilled with imported wastes are reviewed. The success of restoration can be judged by comparisons of soil properties, crop performance or the general acceptability of the restored site to the local residents.

Notes: Abstract. Graphs of soil pH against time were plotted for the Park Grass Experiment at Rothamsted Experimental Station, begun in 1856, and the Long-term Liming Experiments at Rothamsted and Woburn farms, begun in 1962. These showed that the magnitude and duration of the effect of lime applications varied with soil type, initial pH, fertilizer nitrogen application, and the crop grown. Simple equations for each situation were linked to form an empirical model which, with appropriate input data for soil type, crop, and initial and target pH, predicted the lime needed to reach that pH. Model predictions compared well with estimates from a Woodruff-type buffer method. The model forms a sound basis for a more comprehensive lime requirement model covering the whole of the United Kingdom.

Notes: Abstract. A spoil and vegetation survey was conducted of five fields reclaimed from coal mine spoils seeded in different years at the Whitewood mines of south-central Alberta, Canada. It aimed to understand the causes of visibly wide variations in ground cover of the seeded species which was mainly alfalfa. Sites were initially stratified into productivity classes: A (high), B (medium), and C (low) based on the seeded species, and then sampled. Cover and dry weight declined linearly with age of reclaimed field. The spoil at class-A sites contained more clay than that of class-C sites. It also contained more moisture and a better cover. Electrical conductivity (EC) and the concentrations of soluble B, Mg, Na, and K in the spoil were significantly greater at class-C sites. Cover and dry weight of the seeded species were negatively correlated with EC, B, Mg, and Na in the spoil, thus implicating these factors in poor vegetative productivity, particularly in the dry conditions that typify this part of Alberta.

Notes: Abstract. The measurement of the shear strength of the root plate/soil interface beneath mature trees is described. Results from this method are given for a total of 77 sample trees from crops of Sitka spruce aged between 24 and 35 years growing on a peaty gley, a deep peat and a brown earth. Shear strength was much higher for the brown earth than for either the peaty gley or the deep peat, mainly because there was a less clear-cut boundary to the rooting depth compared with the rooting boundary caused by the high water table on the peat sites. There was a slightly higher shear strength for the peaty gley than for the deep peat, but no apparent difference in shear strength between the peat and the underlying mineral soil in the peaty gley. The shear strength measurements were consistent with observed differences in tree stability and the method of measuring shear strength aids the assessment of susceptibility of trees to windthrow.

Notes: Abstract. The soil conditions both before and after restoring opencast sites and their effect on drainage and crop growth are discussed both in general and with specific reference to the site concerned. Both drainage treatments showed a benefit over the undrained control, although no extra benefit was observed from drains at 20-m spacing with mole drains and subsoiling compared to drains at 40-m spacing with mole drains. Subsoiling reduced bulk density and increased surface infiltration rates, but improvements to the soil brought about by subsoiling were short-lived.

Notes: Abstract. Comparisons of crop production on recently reinstated soil in Northumberland have shown that the reduced yield potential of such soil may not be inevitable. Storage of soil in bunds did not greatly reduce subsequent crop yields, but failure to drain the land did. Provided an effective drainage scheme was installed, arable and grass crops could be grown successfully, responding very well to additions of nitrogen fertilizer and other normal good husbandry practices. To date it seems that neither deep cultivation nor the use of grass leys were as effective in the restoration process as had been expected.

Notes: Abstract. Regression is frequently abused in soil research. Its proper use is for statistical prediction. It may also be used to calculate equations for calibration. A regression equation may be used to express a functional relation between two soil variables that are thought to be related by some simple mathematieal law but only where one of the variables is known exactly. In most other circumstances regression is inappropriate. Where departures from a functional relation are due to errors of measurement and sampling fluctuation it should be replaced by a structural analysis to find the best equation. Where the underlying relation is truly bivariate it should be described as such.

Notes: Abstract. Following removal of the upper 40 cm of soil, the physical properties of the exposed B horizon of a red-brown earth (Goulburn clay loam) were ameliorated using a combination of gypsum (5.4 ha−1) and rye grass. Phosphorus (P), nitrogen (N) and potassium (K) fertilizers were added to improve nutrient availability. The ameliorated properties of the exposed B horizon were compared with those of equivalent depths from an adjacent intact profile of Goulburn clay loam.Initially, during the establishment phase of the rye grass, the gypsum increased the electrolyte concentration in the 0–10 cm layer, and stabilized the soil surface against mechanical dispersion. After 18 months all the gypsum in the 0–10 cm layer had dissolved. However, in the presence of rye grass, the soil surface was no longer susceptible to dispersion by the mechanical impact of water. The rye grass improved soil physical properties mainly in the upper 20 cm of the exposed B horizon. Water-stable aggregation 〉 2000 μm and macroporosity increased, and bulk density and penetrometer resistance of the soil decreased.Continuous applications of P, N and K fertilizers resulted in a gradual improvement in the nutritional properties of the exposed B horizon. However, because of the large phosphorus adsorption by the exposed clay, 300 kg P ha−1 was required to provide sufficient available phosphorus in the 0–10 cm layer.

Notes: Abstract. This paper reviews research on sediment yields in British fresh waters affected by afforestation in their catchments. Soil erosion and sedimentation in fresh waters increase after afforestation in the uplands. In the long term a three-to tour-fold increase appears to be common in established upland forests, but much larger increases, some amounting to 50 times that before afforestation, have been recorded soon after ploughing, draining, roadmaking and harvesting. Some of the erosion has been exacerbated by environmental conditions such as steep slopes and storms. Improved silvicultural practices should reduce sediment output to fresh waters, but they might not prevent serious sedimentation following afforestation in the uplands. In contrast, afforestation of arable land under the Farm Woodland Scheme should result in decreased rates of erosion in the lowlands.

Notes: Abstract. The soil of amenity areas is important in the urban landscape. Some is natural, some is man-made. Both contribute greatly to the environment of our cities through the grass, shrubs and trees which they support. Results of research from agriculture and urban gardens have been extrapolated in this review to consider the significance of toxic metals in amenity soil. The metals of most concern for plant growth are zinc, copper and nickel as they are phytotoxic, but additionally lead, cadmium, arsenic, and mercury are of concern due to their effects on human health. The currently acceptable threshold values for metals in the soil of public open spaces, playing fields and parks are presented, and consideration is given to the toxic metal content of an assortment of materials likely to be used in constructing amenity soil.

Notes: Abstract. Assuming that there is no major chemical toxicity or deficiency, the major limitation in man-made soil is the loss of its natural structure, which, in turn, controls the air-water balance. Where such a soil has 〈 70% sand content this loss may adversely affect potential for use.Examples of man-made soils - sports turf and replaced opencast coal mining land - are used to illustrate principles of management. Two strategies exist: to encourage earthworms, thereby promoting effective site drainage by infiltration or, to limit their activity and rely mainly on surface shed. The implications of each of these soil options for wider management and use are discussed.

Notes: Abstract. Nitrogen deficiency is the major problem in the creation of new ecosystems on most derelict land. Initially there is insufficient nitrogen in the wastes to drive the new systems, and nitrogen accumulation is, therefore, required. The most cost-effective way of providing this nitrogen is to use leguminous species which fix nitrogen from the atmosphere. Once nitrogen starts to accumulate in the soil management should aim to promote efficient cycling. Maintaining a near-neutral soil pH and a sward with a small C:N ratio helps to increase the mineralization of nitrogen in dead plant residues, and grazing animals also reduce nitrogen accumulation in dead vegetation.

Notes: Abstract. Land evaluation involves the definition of the comparative marginal value of individual land areas for the uses being considered. For agricultural land evaluation crop yields are the most reliable estimates of comparative marginal values. Yield values can be obtained from field measurements, as well as from productivity indices and empirical and mechanistic crop growth models. This paper reviews the pros and cons of each approach. Mechanistic models of the summary type, that simulate only those processes that are critical to describe an agroecosystem, are the most realistic and practical tools for land evaluation. Criteria for these types of models are given.

Notes: Abstract. Good land management needs information about land resources and the processes taking place in the landscape. In practical land evaluation this information is often expressed in terms of land qualities. The original survey data are stored in geographical information systems where they can be used to estimate the values of appropriate land qualities. Land qualities are complex attributes of land used in planning that may be derived from the original attributes through empirical threshold or regression models, or from process-based deterministic or stochastic simulation models. In order to improve estimates of the distribution of land qualities in space and time, and hence to improve planning decisions, the models require data with a much better spatial resolution than is usually available. The problems and dangers associated with the ad hoc linkage of simulation models and GIS are discussed. Particular attention needs to be paid to the problems of error propagation and costs and benefits when using models.

Notes: Acoustic reverse-time finite-difference migration for zero-offset data is extended from two- to three-dimensional media. The formulation is based on the full three-dimensional acoustic wave equation and so has no dip restrictions and it involves extrapolation in a velocity distribution variable in three dimensions. The algorithm is demonstrated by successful migration of synthetic data sets for three models: a point diffractor, an oblique pinch-out, and a dome overlying a planar reflector.

Notes: Seismic attenuation introduces modifications in the wavelet shape in vertical seismic profiles. These modifications can be quantified by measuring particular signal attributes such as rise-time, period and shape index. Use of signal attributes leads to estimations of a seismic-attenuation log (Q-log).To obtain accurate signal attributes it is important to minimize noise influence and eliminate local interference between upgoing and downgoing waves at each probe location. When tube waves are present it is necessary to eliminate them before performing separation of upgoing and downgoing events. We used a trace-by-trace Wiener filter to minimize the influence of tube waves. The separation of upgoing and downgoing waves was then performed in the frequency domain using a trace-pair filter.We used three possible methods based on signal attribute measurements to obtain g-log from the extracted downgoing wavefield. The first one uses a minimum phasing filter and the arrival time of the first extremum. The two other methods determine the Q-factor from simple relations between the amplitudes of the first extrema and the pseudo-periods of the down-going wavelet.The relations determined between a signal attribute and traveltime over quality factor were then calibrated using field source signature and constant-Q models computed by Ganley's method. Q-logs thus obtained from real data are discussed and compared with geological information, specifically at reservoir level.Analysis of the tube wave arrivals at the level of the reservoir showed a tube wave attenuation that could not be explained by simple transmission effects. There was also a loss of signal coherence. This could be interpreted as tube wave diffusion in the porous reservoir, followed by dispersion. If this interpretation can be verified, tube wave analysis could lead to further characterization of porous permeable zones.

Notes: During the last couple of years there has been much research in the area of wavefield separation of borehole seismic data, and several articles have been published on various separation techniques. Methods involving the application of two-dimensional Fourier transformation, the Radon transformation, multi-level median filters or optimal filters, are all suggested as possible approaches to the wavefield separation problem.This paper compares some of these methods commonly used in the industry.The theories of the chosen methods are described to see how they are related. Using the different methods on synthetic and real data, we show how this theoretical relation is reflected in the relatively similar results obtained. We also show how the different filters treat coherent and random noise.

Notes: Matrix equations are derived to transform the resistivity sounding data obtained in one type of a four-electrode array to the corresponding resistivity sounding data that would be obtained using a different four-electrode array. These expressions are based primarily on recent work in which we have established a linear relation between the apparent resistivity and the kernel function by using a powerful exponential approximation for the kernel function. It is shown that the resistivity sounding data of two different four-electrode arrays have a linear relation through an essentially non-singular matrix operator and, as such, one is derivable from the other for a one-dimensional model and it can also be extended to two-dimensions.Some numerical examples considering synthetic data are presented which demonstrates the efficiency of the method in such transformations. Two published field examples are also considered for transformation giving a reliable interpretation.

Notes: Underground gravity observations in deep coal mines using the conventional gravity meters Worden (type Master) and LaCoste-Romberg (model D), both of which have been adapted to the fire damp regulations, can be accurate to ± 10 and ± 3 μgal, respectively. For underground determination of the vertical gradient of gravity the LaCoste-Romberg meter is used together with a specially designed measuring tower. Using this euipment an accuracy in tower gradient observations of ± 30 E was obtained.To apply the equipment to precision gravity observations in underground situations an additional correction, i.e. a gallery correction, is needed. High accuracy in correction is achieved by a new method of three-dimensional modelling. The gravity effect is computed for bodies with a surface approximated by triangular elements, which are generated from corner points of the body. The combination of gallery correction with tower gradient data leads to a new method for in situ density determination. It offers the possibility of horizontal instead of vertical density profiling.To demonstrate the effectiveness of the developments in underground observations the localization of a pump room is presented. Microgravity and tower gradient observations were carried out to detect the cavity. The horizontal gradient was also calculated to give a more reliable location.

Notes: Power spectrum analysis of the Bouger gravity values in the Eastern Alps suggests that the gravity field may be separated into long and short wavelength components. The long wavelength component is assumed to be caused by Alpine crustal thickening. This long wavelength component was subjected to a gravimetric single density-interface inversion procedure, giving a gravimetric Mohorovičić model which is generally in good agreement with Moho-depths derived by refraction and reflection seismology.The residual high-frequency gravity component correlates well with the main surface geological units in the Eastern Alps.Apparent density mapping by applying an inverse density deconvolution filter to the short wavelength gravity component gives density values for the upper crust which correspond well with averaged density values from rock samples.

Notes: Hydrogeological problems which involve the determination of lateral variations in structures or physical properties may be solved with electrical resistivity gradient profiling if there are significant variations in electrical resistivity, spatially or temporally. The method is explained, evaluated for sensitivity, compared with other methods, and applied to the location of volcanic dike zones that are impounding an anomalous water body near Schofield, Oahu, Hawaii. From the electrical soundings and other independent data, the lateral positions of the boundaries have been refined and their nature estimated.

Notes: 3D Kirchhoff migration and acoustic Born inversion of zero-offset seismic data in a constant-velocity medium can be uniformly factored as a cascade of two 2D diffraction integrals. The formal argument is based on a straightforward implementation of the original time-domain approach of Gibson, Larner and Levin. The factorization differs from the factorization described by Jakubowicz and Levin in omitting all time-dependent filters from the 2D operators in favour of ID filtrations performed as a preprocess and a postprocess.

Notes: Effective noise reduction of single-sweep recorded data is achieved by application of a velocity filter process on a decomposed vibrator pattern. This technique promises high resolution results with a minimum effect on signal characteristic. A comparison of the stacked section of records vertically stacked in the field with the stacked section of velocity-filtered receiver gathers shows a significant increase in resolution and signal-to-noise ratio.

Notes: In recent years, the use of wide source arrays in marine seismic surveys has been a topic of interest in the seismic industry. Although one motivation for wide arrays is to get more guns in a source array without increasing the in-line array dimension, wide arrays can also provide the benefit of suppressing side-scattered energy. Comparisons of common midpoint (CMP) stacks of data acquired offshore Washington and Alaska with wide and conventional-width source arrays, however, show only small and sometimes inconsistent differences. These data were acquired in areas where side-scattered energy is a problem. Comparisons of pre-stack data, however, show substantial differences between the wide and conventional source array data.The disparity between the stacked and prestack data is explained by analysing the effective suppression of back-scattered energy by CMP stacking. Energy reflected from scatterer positions broadside to a given CMP location has a lower stacking velocity than that of the primary reflection events. Thus, CMP stacking attenuates the side-scattered energy. In both survey areas the action of CMP stacking was so powerful in suppressing the broadside energy that the additional action of the wide array was inconsequential in the final stacked sections. In other areas, where the scattering velocity is comparable to the primary stacking velocity, wide arrays could provide considerable advantage.Even though CMP stacked data from wide and conventional-width arrays may appear similar, the reduced amount of side-scattered energy in wide-array prestack data may provide a benefit for data dependent processes such as predictive deconvolution and velocity analysis. However, wide arrays cannot be used indiscriminately because they can degrade cross-dipping primary events. They should be considered primarily as a special tool for attacking severe source-generated noise from back-scattered waves in areas where the action of CMP stacking is insufficient.

Notes: A new approximate method to calculate the space-time acoustic wave motion generated by an impulsive point source in a horizontally layered configuration is presented. The configuration consists of a stack of fluid layers between two acoustic half-spaces where the source and the receiver are located in the upper half-space. A distorted-wave Born approximation is introduced; the important feature of the method is the assumption of a background medium with vertical varying root-mean-square acoustic wave speed. A closed-form expression for the scattered field in space and time as a function of the contrast parameters is deduced. The result agrees closely with rigorously calculated synthetic seismograms. In the inverse scheme the wave speed and mass density can be reconstructed within a single trace. Results of the inversion scheme applied to synthetic data are shown.

Notes: A particular methodology adapted to crystalline formations with a thin weathered zone was developed for a village hydrological project, in Benin. A combination of electrical profiles, Schlumberger and square arrays, was able to locate the most fractured zones in the basement. We present some results obtained from theoretical models as well as from field data.The suggested methodology uses both measurements of resistivity and anisotropy. Strong anisotropy and low resistivity indicate the most productive hydrogeological areas.

Notes: Seismic data often contain traces that are dominated by noise; these traces should be removed (edited) before multichannel filtering or stacking. Noise bursts and spikes should be edited before single channel filtering. Spikes can be edited using a running median filter with a threshold; noise bursts can be edited by comparing the amplitudes of each trace to those of traces that are nearby in offset-common midpoint space. Relative amplitude decay rates of traces are diagnostic of their signal-to-noise (S/N) ratios and can be used to define trace editing criteria. The relative amplitude decay rate is calculated by comparing the time-gated trace amplitudes to a control function that is the median trace amplitude as a function of time, offset, and common midpoint. The editing threshold is set using a data-adaptive procedure that analyses a histogram of the amplitude decay rates.A performance evaluation shows that the algorithm makes slightly fewer incorrect trace editing decisions than human editors. The procedure for threshold setting achieves a good balance between preserving the fold of the data and removing the noisiest traces. Tests using a synthetic seismic line show that the relative amplitude decay rates are diagnostic of the traces’S/N ratios. However, the S/N ratios cannot be accurately usefully estimated at the start of processing, where noisy-trace editing is most needed; this is the fundamental limit to the accuracy of noisy trace editing.When trace equalization is omitted from the processing flow (as in amplitude-versus-offset analysis), precise noisy-trace editing is critical. The S/N ratio of the stack is more sensitive to type 2 errors (failing to reject noisy traces) than it is to type 1 errors (rejecting good traces). However, as the fold of the data decreases, the S/N ratio of the stack becomes increasingly sensitive to type 1 errors.