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  • heavy metals  (53)
  • Springer  (53)
  • Blackwell Publishing Ltd
  • 1995-1999  (53)
  • 1999  (53)
Collection
Publisher
  • Springer  (53)
  • Blackwell Publishing Ltd
Years
  • 1995-1999  (53)
Year
  • 1
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    Electronic Resource
    Springer
    World journal of microbiology and biotechnology 15 (1999), S. 179-184 
    ISSN: 1573-0972
    Keywords: 14CO2 ; heavy metals ; MICs ; sediment communities ; Vmax ; water communities
    Source: Springer Online Journal Archives 1860-2000
    Topics: Biology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: Abstract The effects of Cd2+, Cr3+ and Zn2+ on the microbial activity of water and sediment samples from a contaminated stream were studied. The maximum [14C]glucose uptake (Vmax) and the mineralization (14CO2) rates were determined. A 10% reduction in Vmax was obtained at lower metal concentrations in water samples than in sediment ones. Moreover, a 10% decrease in 14CO2 was observed at significantly minor metal levels, so 14CO2 was more sensitive to evaluated heavy metal pollution. On the basis of MICs obtained for both communities, they were more sensitive to Cd2+ than to Cr3+ and Zn2+. Zinc was less inhibitory to Vmax and 14CO2 rates; Cr3+ showed an intermediate toxicity, and Cd2+ was 10–100 times more inhibitory than the other metals.
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  • 2
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    International journal of salt lake research 8 (1999), S. 75-92 
    ISSN: 1573-8590
    Keywords: alkaline lakes ; heavy metals ; microbial mats ; Wadi El Natrun
    Source: Springer Online Journal Archives 1860-2000
    Topics: Biology , Geography
    Notes: Abstract Heavy metal concentrations of Wadi El Natrun saline lakes were investigated. Pb, Zn, Mn, Cu, Cd, Ni, Fe and Al were measured in surficial sediments. The heavy metal concentrations largely indicate the influence of weathering of terrigenous sources on land. In comparison with the average in sedimentary rocks, the concentrations of the heavy metals studied are higher than the global average sandstone. This is also reflected in the high enrichment factors. The heavy metal concentration in lakes II and III decrease in the order Pb 〉 Zn 〉 Cu, while in lake I the decreasing order is Cu 〉 Zn 〉 Pb. Sediments with microbial mats were found to concentrate heavy metals above background sediment values.
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  • 3
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    International journal of salt lake research 8 (1999), S. 75-92 
    ISSN: 1573-8590
    Keywords: alkaline lakes ; heavy metals ; microbial mats ; Wadi El Natrun
    Source: Springer Online Journal Archives 1860-2000
    Topics: Biology , Geography
    Notes: Abstract Heavy metal concentrations of Wadi El Natrun saline lakes were investigated. Pb, Zn, Mn, Cu, Cd, Ni, Fe and Al were measured in surficial sediments. The heavy metal concentrations largely indicate the influence of weathering of terrigenous sources on land. In comparison with the average in sedimentary rocks, the concentrations of the heavy metals studied are higher than the global average sandstone. This is also reflected in the high enrichment factors. The heavy metal concentration in lakes II and III decrease in the order Pb〉Zn 〉Cu, while in lake I the decreasing order is Cu〉Zn〉Pb. Sediments with microbial mats were found to concentrate heavy metals above background sediment values.
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  • 4
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    Biologia plantarum 42 (1999), S. 119-123 
    ISSN: 1573-8264
    Keywords: anatomy ; epidermis ; heavy metals ; mesophyll ; Triticum aestivum ; vascular bundles
    Source: Springer Online Journal Archives 1860-2000
    Topics: Biology
    Notes: Abstract The effects of 1 mM cadmium, lead and nickel on dry mass, Cd, Pb, and Ni contents, and changes in leaf structure in young wheat plants were studied. In leaves, Cd content was highest, followed by Pb and Ni, in roots Cd content was also highest, but followed by Ni and Pb. Roots accumulated considerably larger amounts of the three heavy metals than leaves. Largest reductions of leaf and root mass were obtained with Cd. Pb and Ni effects were almost equal. Ni excess had a strong negative effect on mesophyll thickness, while Cd mostly reduced the number and size of vascular bundles and vessel diameter. High Pb reduced the diameter of vessels causing their different deformations.
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  • 5
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    Journal of applied electrochemistry 29 (1999), S. 1129-1132 
    ISSN: 1572-8838
    Keywords: chrome plating ; heavy metals ; membranes ; porous ceramic diaphragm ; porous pot
    Source: Springer Online Journal Archives 1860-2000
    Topics: Chemistry and Pharmacology , Electrical Engineering, Measurement and Control Technology
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  • 6
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    Journal of applied electrochemistry 29 (1999), S. 411-419 
    ISSN: 1572-8838
    Keywords: chromate ; gas diffusion electrode ; heavy metals ; mass transfer ; packed bed electrode
    Source: Springer Online Journal Archives 1860-2000
    Topics: Chemistry and Pharmacology , Electrical Engineering, Measurement and Control Technology
    Notes: Abstract Reduction of chromate in very low concentration (20 ppm) has been carried out in a GBC reactor. Final concentrations below 0.5 ppm have been achieved at reasonable reaction rates. Spontaneous reduction of chromate by hydrogen in a GBC reactor without an external power source requires careful selection of cathode material. Chemically stable materials such as titanium and RVC tend to passivate when in contact with chromate solution and are unsuitable for use as cathode materials. Graphite, active carbon and graphite felt show no obvious passivation. Reduction of oxidized groups and oxygen are the major side reactions. These occur significantly, especially when using an activated carbon bed as a cathode.
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  • 7
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    BioMetals 12 (1999), S. 241-246 
    ISSN: 1572-8773
    Keywords: Aspergillus niger ; heavy metals ; chemical modification ; Langmuir
    Source: Springer Online Journal Archives 1860-2000
    Topics: Biology , Chemistry and Pharmacology
    Notes: Abstract The metal-binding ability of Aspergillus niger mycelial waste was improved by chemical modification. The latter was performed by introducing additional carboxy groups using oxidation methods or the introduction of the ethyldiamino group first by chlorination of A. niger using mesyl chloride and subsequent reaction of the product with ethylene diamine. Metal binding abilities of the products for Cd2+, Co2+, Ni2+ and Zn2+ were determined according to the Langmuir model, whereby pK D * -values of 3.88 up to 5.02 were revealed. Maximum capacities for the metals were found to be in the range 172 to 1064 mmol/kg.
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  • 8
    ISSN: 1573-0867
    Keywords: compensatory fertilization ; deposition ; heavy metals ; liming ; Pinus sylvestris ; soil pollution
    Source: Springer Online Journal Archives 1860-2000
    Topics: Agriculture, Forestry, Horticulture, Fishery, Domestic Science, Nutrition
    Notes: Abstract The results from four compensatory fertilization experiments located at different distances (0.5, 2, 4 and 8 km) along a heavy metal deposition gradient extending from the Harjavalta Cu-Ni smelter in SW Finland are presented. The experiments were established in middle-age Scots pine stands growing on dryish sites of sorted glaciofluvial sediments. The soil type in all the experiments is ferric podsol. The treatments in the experiments consisted of liming, a powdered slow-release mineral mixture and stand-specific fertilization which comprised at least methylene urea and ammonium nitrate. Monitoring of deposition and soil solution and studies on soil chemical and microbiological properties, on the nutrient status of trees and needle litterfall, on fine root dynamics and on the growth of the tree stands were carried out during a 5-year period. There was a severe shortage of exchangeable Ca and Mg in the organic layer of the most polluted stands. Although the uppermost mineral soil layer had relatively high exchangeable Ca and Mg concentrations, the trees were not able to utilize these nutrient reserves presumably due to the toxic effects of Cu and Ni on the plant roots and mycorrhizas. The treatments that included limestone markedly decreased the Cu and Ni concentrations in the soil solution and soil organic layer, presumably due to immobilisation through precipitation or absorption. The Ca and Mg concentrations correspondingly increased, which certainly contributed to the partial recovery of fine root and stand growth. The powdered mineral mixture and the combination of methylene urea and ammonium nitrate had no short-term effect on the microbial biomass and activity. All the fertilizer treatments increased volume growth in the most polluted stand. The stand-specific fertilization increased needle mass in heavily polluted stands, but the response of the needle mass to fertilizer treatments was low in the less polluted stands. No clear evidence was found to support the role of nutrient status in tree resistance.
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  • 9
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    Hydrobiologia 398-399 (1999), S. 375-383 
    ISSN: 1573-5117
    Keywords: coastal pollution ; copper pollution ; heavy metals ; macroalgae ; Lessonia ; L. nigrescens ; L. trabeculata ; ultrastructure
    Source: Springer Online Journal Archives 1860-2000
    Topics: Biology
    Notes: Abstract Plants of Lessonia trabeculata and L. nigrescens were studied by transmission electron microscopy in order to evaluate ultrastructural level changes in response to copper exposure. Samples of fronds, stipes, and holdfasts were collected from areas with and without copper mining discharges. Changes in cell ultrastructure observed in Lessonia trabeculata were related to copper concentrations in seawater, seaweeds and extracted alginates. The results strongly suggest that tolerance or adaptation of Lessonia to high concentrations of copper is the capacity of different plant tissues to accumulate copper as precipitates, primarily at two levels: the cell wall and periplasmalemmal space, with the vacuolar system being a third site.
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  • 10
    ISSN: 1573-5117
    Keywords: Rare earth elements ; estuarine sediments ; east coast of India ; heavy metals
    Source: Springer Online Journal Archives 1860-2000
    Topics: Biology
    Notes: Abstract Bed sediment samples collected from the Hoogly, Godavari, Krishna and Cauvery estuaries on the east coast of India were analyzed for rare earth elements (REEs), mainly lanthanides (La–Lu), Y, a number of metals (V, Cr, Co, Ni, Zn, Ag, Cd and Pb), using Thermal Ionization Mass Spectrometry. Continental weathering plays an important role in the distribution of REEs and metals. However, metals showed wide variation in concentration among estuaries, mainly due to varying salinity, which controls complex estuarine processes, and partly to anthropogenic inputs. Factor analysis of elemental data identified two major groups of elements: (i) LREEs, HREEs, Cd, Pb and Ag, revealing an association with detritals brought in by the rivers; and (ii) V, Cr , Co, Ni and Zn, indicating complex estuarine processes and human input. LREEs are more enriched than HREEs (LREE/HREE ratio varied between 12 and 40) reflecting silicate weathering of crustal materials, and a resultant increase in LREEs in detritals. We conclude that the estuarine system constitutes 70% of LREEs and 30% of HREE flux to the Bay of Bengal.
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  • 11
    ISSN: 1573-5117
    Keywords: heavy metals ; accumulation ; physiological fitness ; survival ; HSP 70 ; Mytilus ; Baltic Sea
    Source: Springer Online Journal Archives 1860-2000
    Topics: Biology
    Notes: Abstract Earlier studies demonstrate that blue mussels (Mytilus edulis) from the Baltic population are more sensitive, in terms of physiological response and survival when exposed to toxic substances, compared to mussels from a more marine environment. The question whether this can be explained by environmental factors or genetic differences in the ability to synthesise a common stress-inducible protein (HSP 70) was addressed in two experiments. In the first experiment mussels from the North and Baltic Seas were acclimatised to an intermediate salinity of 15‰ S in the laboratory. The physiological performance was studied when the heavy metal cadmium was added and accumulated by the animals during a one week exposure. Tissue concentration was measured and related to physiological response. The level of expression of HSP 70 was analysed by densitometry on Western blots. North Sea mussels rapidly induced high levels and multiple forms of HSP 70, reached a comparatively low tissue concentration of cadmium, and showed only a minor physiological response and low mortality rates. Baltic Sea mussels had low levels of HSP 70, induced at slow rate, reached higher tissue concentrations of cadmium, and showed a more pronounced physiological response and higher mortality rates. High levels of stress proteins and a rapid induction corresponded well with physiological fitness, and the mussels from the North Sea thus seem to have a more efficient detoxification system, probably including stress-inducible proteins. In the second experiment, juvenile mussels from the Baltic population were acclimatised for a month to North Sea conditions in a field transplant. The mussels were then exposed to low-dose copper in the laboratory and the accumulation, physiological response and synthesis of stress inducible proteins were assessed. The results indicate that the physiological differences described between the populations are to a large extent explained by environmental factors. However, some differences can still be observed between the populations, e.g., a lower rate of induction of a major stress protein in Baltic than in North Sea mussels. It can thus be suggested that a reduced ability to stress protein induction, in their natural low saline habitat, might be a contributing factor to the higher pollution sensitivity earlier demonstrated for Baltic blue mussels.
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  • 12
    ISSN: 1573-515X
    Keywords: phytoplankton ; nutrients ; heavy metals ; colloids ; ultrafiltration ; river
    Source: Springer Online Journal Archives 1860-2000
    Topics: Chemistry and Pharmacology , Geosciences
    Notes: Abstract The impact of the spring phytoplanktonic blooms on the partition of nutrients and metals between the dissolved and particulate phases was studied over two years in the river Marne, upstream of its confluence with the river Seine. Particular attention was devoted to copper and manganese, determined in the dissolved phase (〈 0.22 μm), subdivided into the colloidal phase and the 'truly dissolved' phase (〈 10 KDaltons) obtained by tangential ultrafiltration. During the algal growth peaks, a sharp reduction of nutrients was observed in the dissolved phase: in 1994, consumption of 70% of silica, 50% of ammonium and 40% of soluble phosphorus present before the phytoplanktonic bloom. The water concentration peaks of suspended matter (SM) and of particulate metals, phosphorus and carbon coincide with those of chlorophyll. The highly significant correlations between pH and chlorophyll (r = 0.92, P 〈 0.001), pH and SM (r = 0.97, P 〈 0.001) and chlorophyll and SM (r = 0.93, P 〈 0.001) confirmed the phytoplanktonic nature of SM and the determining role of pH in the partition of metals, its increase being responsible for the coprecipitation of metal. As a corollary to the increase in the particulate phase, a decrease of 55% was observed for copper and manganese in the 'truly dissolved' phase compared to the concentrations outside bloom periods. The importance of the colloidal fraction was also shown. During the strong algal growth periods, the proportion of 'colloidal metal' in the dissolved phase (〈 0.22 μm) reached 60% and the increase in the colloidal fraction was 4 times stronger for copper than for manganese. While manganese seemed to be more associated with macroparticles, copper was more associated with fine colloidal biological particles intrinsic to the phytoplankton.
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  • 13
    ISSN: 1573-515X
    Keywords: phytoplankton ; nutrients ; heavy metals ; colloids ; Ultrafiltration ; river
    Source: Springer Online Journal Archives 1860-2000
    Topics: Chemistry and Pharmacology , Geosciences
    Notes: Abstract The impact of the spring phytoplanktonic blooms on the partition of nutrients and metals between the dissolved and particulate phases was studied over two years in the river Marne, upstream of its confluence with the river Seine. Particular attention was devoted to copper and manganese, determined in the dissolved phase (〈 0.22μm), subdivided into the colloidal phase and the ‘truly dissolved’ phase (〈 10 KDaltons) obtained by tangential Ultrafiltration. During the algal growth peaks, a sharp reduction of nutrients was observed in the dissolved phase: in 1994, consumption of 70% of silica, 50% of ammonium and 40% of soluble phosphorus present before the phytoplanktonic bloom. The water concentration peaks of suspended matter (SM) and of particulate metals, phosphorus and carbon coincide with those of chlorophyll. The highly significant correlations between pH and chlorophyll (r=0.92,P 〈 0.001), pH and SM (r=0.97,P 〈 0.001) and chlorophyll and SM (r=0.93,P 〈 0.001) confirmed the phytoplanktonic nature of SM and the determining role of pH in the partition of metals, its increase being responsible for the coprecipitation of metal. As a corollary to the increase in the particulate phase, a decrease of 55% was observed for copper and manganese in the ‘truly dissolved’ phase compared to the concentrations outside bloom periods. The importance of the colloidal fraction was also shown. During the strong algal growth periods, the proportion of ‘colloidal metal’ in the dissolved phase (〈 0.22μm) reached 60% and the increase in the colloidal fraction was 4 times stronger for copper than for manganese. While manganese seemed to be more associated with macroparticles, copper was more associated with fine colloidal biological particles intrinsic to the phytoplankton.
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  • 14
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    Plant and soil 212 (1999), S. 35-43 
    ISSN: 1573-5036
    Keywords: heavy metals ; plant microelements ; soil pollution ; soil nematode communities ; Maturity Index
    Source: Springer Online Journal Archives 1860-2000
    Topics: Agriculture, Forestry, Horticulture, Fishery, Domestic Science, Nutrition
    Notes: Abstract Heavy metal pollution in soils constitutes an acute problem threatening various groups of living organisms. Nematode samples were taken in the framework of a complex food-chain experiment which is being carried out after artificially contaminating a part of an agrobiotope. The 13 heavy metals and microelements involved in the study are the following: Al, As, Ba, Cd, Cr, Cu, Hg, Mo, Ni, Pb, Se, Sr, and Zn. Parallel plots receiving maximum concentrations equal to approx. 270 ppm were sampled twice during a complete vegetation period of winter wheat. Nematode abundance and richness as well as Maturity Index data revealed that Se and Cr had significantly negative effects on assemblages, while Zn appeared to have a generally positive influence on these parameters. Impacts by the other elements are less obvious or quite neutral (like that of Al). Favorable soil conditions and time elapsed (over 5 years) since the contamination, both resulting in a decrease of available element concentrations, may account for the not very pronounced effects.
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  • 15
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    Plant growth regulation 29 (1999), S. 151-160 
    ISSN: 1573-5087
    Keywords: heavy metals ; kinetin ; lupin ; Lupinus termis ; metallothionein
    Source: Springer Online Journal Archives 1860-2000
    Topics: Agriculture, Forestry, Horticulture, Fishery, Domestic Science, Nutrition
    Notes: Abstract The effect of exogenous kinetin application on the growth and some physiological processes of Lupinus termis plants growing in metal containing solutions with excess concentrations of Cu and Zn ion were studied. Generally, plants growing in these solutions had a lower chlorophyll (Chl.) content, leaf relative water content (RWC) and produced less biomass than the control plants. Proline content was higher in metal-treated plants than in untreated controls. Chromatography of cell-free-extracts of roots and shoots indicated three main protein peaks with molecular weights about 170, 75--70 and 5--45 kDa. These peaks were coincident with Cu or Zn maxima. Addition of kinetin reduced the decline in Chl. content in metal-treated plants, improved water status of the plants and enhanced growth of the shoots and roots. The Cu or Zn content expressed on a per mg protein basis was raised when kinetin was applied to the growing shoots. Kinetin (Kin), Cu and Zn, singly and in the presence of kinetin (Cu × Kin and Zn × Kin), significantly affected the parameters tested. Only the effects of Cu × Kin and Zn × Kin interactions on shoot fresh weight and Cu × Kin on root length were statistically insignificant. Based on the calculated coefficient of determination (η 2) the roles of Cu and Zn in affecting Chl. content and growth were dominant in comparison to kinetin. Kinetin effect was dominant for root length and proline content, but the role of the interaction was subdominant. The results of this study indicate that kinetin can alleviate the harmful effects of Cu and Zn on the growth of lupin plants through stimulation of Cu and Zn incorporation into metal-binding proteins.
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  • 16
    ISSN: 1573-5036
    Keywords: fertilization ; fine roots ; heavy metals ; liming ; nutrients
    Source: Springer Online Journal Archives 1860-2000
    Topics: Agriculture, Forestry, Horticulture, Fishery, Domestic Science, Nutrition
    Notes: Abstract This study was conducted to assess 1) the growth of fine roots into ingrowth cores and fine root mortality, 2) the effects of liming and correction fertilization on fine-root growth and mortality, and 3) the concentrations of heavy metals in fine roots in control, limed or fertilized Scots pine stands at different distances from a copper-nickel smelter. Fine-root biomass in the ingrowth cores in the control plots varied between 1 (at 0.5 km from the smelter) and 252 and 271 g/m2 (at 4 and 8 km, respectively). In the most polluted stand at 0.5 km, 98% of the fine roots that had grown into the ingrowth cores had died before sampling. Corresponding values for the other stands (4 and 8 km) were only 13-18%. At 0.5 km, liming increased the growth and survival of fine roots. The concentrations of Cu and Ni were also smaller in fine roots from the limed plot than those from the control plot. In the correction fertilization treatment at 0.5 km the total ingrowth of fine roots was at the same level as in the control, but less fine roots had died. Thus, the correction fertilizer treatment increased the survival but not the growth of fine roots. At 4 or 8 km, there were no significant differences in the fine-root biomass or necromass or element concentrations between the treatments.
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  • 17
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    Environmental monitoring and assessment 56 (1999), S. 177-193 
    ISSN: 1573-2959
    Keywords: accumulation ; bioindicators ; concentrations ; heavy metals ; Karelia ; wildlife
    Source: Springer Online Journal Archives 1860-2000
    Topics: Energy, Environment Protection, Nuclear Power Engineering
    Notes: Abstract The levels of mercury, cadmium, lead, copper, nickel, zinc and iron were determined in samples of liver, kidney, skeletal muscle, heart, lungs and hair of moose (N = 67), reindeer (N = 45), brown bear (N = 18), wild boar (N = 10) and squirrel (N = 18) shot in Karelia from 1989 to 1991 during regular hunting. The highest heavy-metal concentrations were found in livers, kidney, lungs and hair samples. The samples of muscle contained lowest levels of these elements. The tissues of moose, reindeer and brown bear were contaminated with heavy metals to a greatest extent. Lowest levels of toxicants were recorded in wild boar. Results indicate a widespread presence of heavy metal in the environment and in wildlife, which may be linked to acid precipitation. There was no evidence of these elements accumulated to toxic levels, but Karelian public have been informed that the eating of moose liver and kidney would probably result in their exceeding WHO standard weekly intake limit for cadmium.
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  • 18
    ISSN: 1573-2959
    Keywords: heavy metals ; organochlorines ; red fox
    Source: Springer Online Journal Archives 1860-2000
    Topics: Energy, Environment Protection, Nuclear Power Engineering
    Notes: Abstract Heavy metals and organochlorine contamination were analyzed in tissues of red foxes (Vulpes vulpes) from the Province of Siena (central Italy). Mercury (Hg), cadmium (Cd) and lead (Pb) concentrations were assessed in liver tissues and the data were analyzed for differences in relation to sex and age. Overall Hg, Cd and Pb mean values were 0.16, 0.62 and 0.64 μg g_1 d.w., respectively. HCB, DDT and PCB concentrations were assayed in fatty tissues and muscle. The highest levels of those pollutants were found in muscle (0.47, 1.16 and 20.2 μg g_1 lipid basis of HCB, DDTs and PCBs respectively), rather than in fat (0.23, 0.49 and 7.2 μg g_1 l.b. of HCB, DDTs and PCBs respectively). Pollutant accumulation was analyzed in relation to sex, age and sexual maturity of females.
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  • 19
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    Environmental monitoring and assessment 54 (1999), S. 229-237 
    ISSN: 1573-2959
    Keywords: coastal index ; discriminant analysis ; fishing areas ; heavy metals
    Source: Springer Online Journal Archives 1860-2000
    Topics: Energy, Environment Protection, Nuclear Power Engineering
    Notes: Abstract The quality assessment of fishing areas on the basis of the levels of heavy metals in clams ( Chamelea gallina) was attempted by using discriminant analysis. Five metals, Hg, Pb, Cd, Cu and Zn, were analyzed in the soft edible parts of clams from three fishing areas. The descriptive methods applied to data obtained do not show enough differences between sampling stations for management purposes. Only discriminant analysis is successful in the differentiation between all fishing areas. Through the first discriminant function, the group centroids are proposed as index of different source of clams. These values standardized are proposed as coastal quality index.
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  • 20
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    Environmental monitoring and assessment 55 (1999), S. 389-399 
    ISSN: 1573-2959
    Keywords: accumulation ; heavy metals ; mine spoils ; vegetation ; soil-plant relationships
    Source: Springer Online Journal Archives 1860-2000
    Topics: Energy, Environment Protection, Nuclear Power Engineering
    Notes: Abstract The presence of heavy metals (Cr, Ni and Fe) in soil and accumulated by herbs, shrubs and trees regenerated naturally on the minewaste-dumps of Sukinda chromite mines (TISCO sector) were investigated. There was significant correlationship between Cr and Fe in the soil where a tree species (Catunaregam spinosa) occurred. Guazuma ulmifolia and Diospyros montana also did show significant correlation between leaf, stem and soil for Cr, Ni and Fe. Among the shrubs (Calotropis gigantea, Chromolaena odorata, Phyllanthus reticulatus and Woodfordia fruticosa) significant and positive correlations were obtained for Cr and Ni in soil and iron and nickel in leaf and chromium and nickel in stem. Among the annual herbs, whole plant of tephrosia purpurea and Borrevia articularis showed significant and positive correlation with chromium and nickel with the maximum correlation coefficient value. It was concluded that the above information would be useful in revegetation programmes in subtropical regions having seasonal rainfall.
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  • 21
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    Environmental monitoring and assessment 59 (1999), S. 321-330 
    ISSN: 1573-2959
    Keywords: agar diffusion assay ; Arabian Gulf ; chromogenic bacteria ; heavy metals ; toxicity
    Source: Springer Online Journal Archives 1860-2000
    Topics: Energy, Environment Protection, Nuclear Power Engineering
    Notes: Abstract A simple method – direct agar diffusion assay – was optimised for rapid assessment of heavy metal toxicity to marine chromogenic and non-chromogenic bacteria. The procedure involved spotting of a 10 microliter test solution on the seeded agar plate and incubation of the plates at 30°C to accelerate bacterial growth. Under optimum conditions, test results were obtainable within 12–18 hr instead of 96 hr incubation time generally required for a marine bacterial assay by conventional agar plate methods. A range of sixteen heavy metals, each at 5 different concentrations was tested. Toxicity was demonstrated by the formation of a clear zone of growth inhibition around the point of application. Toxicity of tested chemicals could be easily demonstrated at concentrations as low as 0.1 μg per spot on the agar plate. A dose dependent relation between metal concentration (μg/spot) and the diameter of the clear zone on agar plate was observed, suggesting potential of this method as an easy and economical tool in quantitative toxicology studies.
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  • 22
    ISSN: 1573-5117
    Keywords: coastal pollution ; copper pollution ; iron pollution ; heavy metals ; macroalgae ; macroinvertebrates ; Lessonia ; L. trabeculata
    Source: Springer Online Journal Archives 1860-2000
    Topics: Biology
    Notes: Abstract In 1996/97, a study was carried out to evaluate several variables related to the potential ecological effects of soluble copper and iron released as the result of direct dumping of mine tailing into the littoral zone of the Pacific Ocean off northern Chile. Variables studied included: 1. content of copper and iron in mining discharges; 2. distribution of Cu and Fe in seawater at study sites; 3. distribution of Cu and Fe in the seaweed Lessonia trabeculata and in its alginates (obtained from frond, stipe and holdfast); 4. alterations in Lessonia morphology; and 5. variability in the macroinvertebrate community associated with Lessonia holdfasts and the inter-plant subtidal community. The variables were evaluated for different depths and distance from discharge sources, as well as for control areas far from any mining activity. It was observed that tailings from copper mining caused more ecological perturbation than those from iron mining; however, the lack of organisms very close to tailing discharges could be caused by stress produced by loading of fine sediments rather than by the presence of heavy metals. This work shows that the concentrations of heavy metals in seawater, plants, and alginates of Lessonia in contaminated and control sites were highly variable, decreasing with depth and distance from the contamination source. What were originally considered as control areas far from anthropogenic metal release, showed high concentration of heavy metal due to natural orogenetic processes occurring along the Chilean coast.
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  • 23
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    Water, air & soil pollution 109 (1999), S. 1-15 
    ISSN: 1573-2932
    Keywords: EDTA ; heavy metals ; leaching ; lead ; soil remediation
    Source: Springer Online Journal Archives 1860-2000
    Topics: Energy, Environment Protection, Nuclear Power Engineering
    Notes: Abstract The performance of EDTA for the treatment of calcareous soils contaminated with heavy metals from mining and smelting activities was evaluated in this study. Soil samples containing variable levels of contamination, from 500 to 35 000 mg kg-1 Pb and 700 to 20 000 mg kg-1 Zn, were subjected to EDTA treatment and the extraction of heavy metals was found to vary, ranging between 50 and 98% for Pb and 50 to 100% for Zn. Total residual concentrations were above the limits set by regulatory authorities; leachable metals, however, were efficiently removed and treated soils were all acceptable in terms of toxicity. The effect of EDTA concentration and pulp density was studied on a soil sample containing 12 000 mg kg-1 Pb and 10 000 mg kg-1 Zn. Heavy metals removal was improved at low pulp densities and when EDTA concentration was increased from 0.025 to 0.25 M. The tetrasodium salt Na4-EDTA was found to be less effective for metals removal compared to the disodium salt Na2-EDTA, though applied at higher concentrations. This experimental work has also demonstrated the great importance of soil matrix for the overall evaluation of the EDTA leaching as a cost effective remedial option. The simultaneous dissolution of calcite was found to consume approximately 90% of the available EDTA. It was thus concluded that for the treatment of calcareous soils the design criteria and cost estimations should be based on the calcite content of the soil.
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  • 24
    ISSN: 1573-2932
    Keywords: heavy metals ; polycyclic aromatic compounds ; sewage sludge
    Source: Springer Online Journal Archives 1860-2000
    Topics: Energy, Environment Protection, Nuclear Power Engineering
    Notes: Abstract The total contents of PAHs, organic polar fractions and 14 major hydrocarbons containing 3–6 aromatic rings as well as heavy metal contents were determined in sewage sludges from highly industrialized (Upper Silesia), agricultural and recreational regions of Poland. Sludges from the industrial region showed markedly increased concentrations of all the organic micropollutants and 2–10 times higher levels of the following heavy metals: Pb, Cd, Cr, Cu, Fe, Zn, Ni, Mn and Co. The levels, however, did not exceed the Polish as well as European Economic Community limit values, which renders all the sludges applicable to land and some of them suitable for utilization on agricultural soils.
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  • 25
    ISSN: 1573-2932
    Keywords: bootstrapping ; heavy metals ; Norway ; palaeolimnology ; partition coefficients ; pH ; redundancy analysis ; surface sediments
    Source: Springer Online Journal Archives 1860-2000
    Topics: Energy, Environment Protection, Nuclear Power Engineering
    Notes: Abstract Data from 96 headwater lakes from Norway are used to model heavy metal concentrations in surficial lake sediments in relation to atmospheric deposition. The study evaluates the application of sediment-water partitioning models at the field scale and finds optimum values for the partition coefficients. The impact of environment (sediment type, lake water pH, etc.) on KDvalues is explored directly by comparing KDestimates with environmental variables. KDvalues for each metal are found by optimising the fit between predicted and observed surface-sediment concentrations. The sensitivity of the KDestimates to data structure is examined by bootstrapping. KDvalues of 105.8and 106.2were calculated for cadmium (Cd) and lead (Pb), respectively, comparable to recent direct observations. Biogenic silica influenced KDvalues for Cd, Pb and Zn, whereas lake depth influenced Pb. pH did not have any detectable effect. KDfor zinc (Zn) was less well defined, but higher than indicated by published experimental measurements. The results suggest that sediment-water partitioning models have an important contribution to make to field-scale lake studies of sediment heavy metals, and have important implications for palaeolimnological evaluations of heavy metal deposition.
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  • 26
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    Water, air & soil pollution 109 (1999), S. 397-406 
    ISSN: 1573-2932
    Keywords: chicory ; fly ash pH ; heavy metals
    Source: Springer Online Journal Archives 1860-2000
    Topics: Energy, Environment Protection, Nuclear Power Engineering
    Notes: Abstract Chicory was cultivated in a pot experiment using two soils of different pH. Treatments were NPK, fly ash (pH 8) + NP and fly ash (pH 12) + NP, respectively. Another series of pots received heavy metals in soluble form additionally to the described treatments. It was observed that fly ash causes generally a decrease in Zn, Cd, Ni and Cu concentrations of chicory. The reduction occurs both for the metals naturally present in the soil and, to a greater extent, for those added as salts. This effect is more evident when fly ash at pH 12, rather than that at pH 8, was used. The increase of soil-pH through the fly ash addition is the major factor decreasing heavy metal availability. It was observed that potassium originating from fly ash is not available for crop uptake.
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  • 27
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    Water, air & soil pollution 111 (1999), S. 159-170 
    ISSN: 1573-2932
    Keywords: composting ; heavy metals ; municipal solid wastes ; sequential extraction ; speciation
    Source: Springer Online Journal Archives 1860-2000
    Topics: Energy, Environment Protection, Nuclear Power Engineering
    Notes: Abstract The organic fraction of municipal wastes has been composted on the laboratory scale. In the obtained compost the content of cadmium, cobalt, copper, manganese, nickel, lead and zinc were determined, as well as the speciation i.e, the form of their occurrence, making use of Rudd's method of sequential extraction. The investigations also concerned the way of removing these metals from the compost by means of leaching with solutions of sulphuric and nitric acid, as well as by electrochemically separating the metals from the solution after the compost had been leached with sulphuric acid. It has been found that the application of the electrochemical method with varying pH values of the leaching solution within the range of 6.8–2.8 allows for the separation of 83.5% Cd, 55.0% Co, 65.4% Cu, 59.4% Mn, 70.3% Ni, 90.5% Pb and 56.2% Zn.
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  • 28
    ISSN: 1573-2932
    Keywords: anions ; cations ; chemical composition ; heavy metals ; rain
    Source: Springer Online Journal Archives 1860-2000
    Topics: Energy, Environment Protection, Nuclear Power Engineering
    Notes: Abstract Precipitation events were collected during the period from October 1996 to April 1997 from two sites in the city of Amman, Jordan. The samples were analyzed for major cations (Na+, K+, Ca2+, Mg2+ and NH4+), major anions (F-, Cl-, NO3- and SO42-), in addition to heavy metals (Cu2+, Cd2+, Zn2+, and Pb2+). High levels of Ca2+ and SO42- were observed. The results were comparable with some regional values and they indicate that about 58% of Na+ and Cl- are of marine origin, while Ca2+, K+ and a large fraction of SO42- are of soil dust origin. Heavy metals were detectable in most of the samples, zinc showed the highest concentrations. Significant correlation was obtained between zinc and lead, which may indicate automobile emission source.
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  • 29
    ISSN: 1573-2932
    Keywords: extraction ; heavy metals ; soil remediation
    Source: Springer Online Journal Archives 1860-2000
    Topics: Energy, Environment Protection, Nuclear Power Engineering
    Notes: Abstract A model was developed that allowed for the evaluation of a soil metal cleaning technique in a rapid and cost effective manner. Metal flow (Pb, Cu, Zn, and Cd) during a counter-current soil-acid extraction procedure, consisting of a decarbonation, solubilisation, and washing step, was determined. Required input data are total soil metal content and metal equilibrium distribution coefficients, derived from batch equilibration experiments. The model was calibrated and validated against experimentally obtained results. Model predictions adequately described metal behaviour and removal in each of the extraction steps. Based on the results, optimum operating conditions for the steps involved in the extraction procedure were determined and the feasibility of the counter-current extraction procedure for heavy metal removal from a contaminated soil evaluated.
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  • 30
    ISSN: 1573-2932
    Keywords: Arcachon Lagoon ; atmospheric fluxes ; Cd ; coastal zones ; Cu ; Gironde Estuary ; heavy metals ; high frequency variability ; ICP-MS ; Ni ; Pb ; Zn
    Source: Springer Online Journal Archives 1860-2000
    Topics: Energy, Environment Protection, Nuclear Power Engineering
    Notes: Abstract We report here the first data set on wet deposition of heavy metals in the southwestern French coastal zone. In this region, there are two major sensitive coastal ecosystems: the Gironde Estuary and the Arcachon Lagoon. Chemical analyses of heavy metals were carried out by ICP-MS. Annual mean concentrations of the dissolved fraction in precipitation were 0.2, 3.4, 4.3, 8.1 and 30 μg L-1for Cd, Ni, Cu, Pb and Zn, respectively. In terms of annual fluxes, these numbers are of the same order of magnitude as the fluxes measured in southeastern France, but are higher than those measured in western Brittany. When extrapolated to the entire Bay of Biscay, the annual wet dissolved fluxes of Cd, Ni, Cu, Pb and Zn are respectively 7, 110, 140 340 and 1440 t yr-1. According to available data in the literature, the regional Cd, Cu, Pb and Zn atmospheric fluxes for the Bay of Biscay are of the same order of magnitude as riverine inputs (Loire and Gironde). On a daily or weekly time scale, we observed a strong variability of elemental fluxes: up to 20% of the annual dissolved flux may occur in a rain event shorter than 3.5 days. Although elements display generally parallel variations with time, they sometimes follow independent behaviours (e.g. Pb and Cd), suggesting that they may derive from different geographical and/or pollution sources.
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  • 31
    ISSN: 1573-2932
    Keywords: arid-zone soils ; field capacity ; fractionation ; heavy metals ; kinetics ; redistribution ; transformation
    Source: Springer Online Journal Archives 1860-2000
    Topics: Energy, Environment Protection, Nuclear Power Engineering
    Notes: Abstract Solid-phase transformation of added Cd, Cu, Cr, Ni, Pb and Zn, in two arid-zone soils incubated in the field capacity moisture regime for one year, were studied. The heavy metals were fractionated into six empirically defined fractions using a selective sequential dissolution (SSD) protocol optimized for arid-zone soils. Each of these fractions was named based on the major soil component targeted for dissolution during the specific SSD step, but it is not assumed that they are mineralogically and chemically totally specific. The transformations of the metals in the two soils incubated at the field capacity regime were compared with those at the moisture saturation regime (Han and Banin, 1997). An initial fast stage of transformation of the soluble metals from the exchangeable (EXC) fraction to the less labile fractions (the carbonate (CARB) fraction for Cd, Pb, Zn, Ni and Cu, and the organic matter (OM) fraction for Cr, and to some extent Cu and Ni) occurred during the fractionation and within one hour after addition. This was followed by a second stage, involving long-term transformation processes of all metals: added Cd was transferred from the EXC into the CARB fraction; added Cr was transferred from the CARB to the OM fraction and Pb was transferred very slowly to the easily reducible oxide (ERO) fraction. Added Cu, Ni and Zn were transferred from the EXC and CARB fractions into the ERO fraction and to some extent OM and RO fractions. In Part I of this series, we reported that during incubation in the saturated moisture regime, Zn and Ni were transferred mainly into the RO and OM fractions. Cadmium, Cr and Pb underwent the same transformation pathways during the slow long-term process, with slightly different rates, in both water regimes. At low levels of addition, the incubated soils moved over one year towards a distribution similar to that of the native soil. At higher levels, the soils still remained removed from the quasi-equilibrium which characterized the native soil, even at the end of one year of incubation.
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  • 32
    ISSN: 1573-2932
    Keywords: critical load ; deposition ; heavy metals ; persistent organic pollutants ; soil quality ; water quality
    Source: Springer Online Journal Archives 1860-2000
    Topics: Energy, Environment Protection, Nuclear Power Engineering
    Notes: Abstract In the pilot study ESQUAD the impact of atmospheric deposition of three heavy metals (cadmium, copper and lead) and two persistent organic pollutants (benzo(a)-pyrene and lindane) on the quality of European soils and seawater has been calculated. Calculations have been made of atmospheric transport and deposition using a detailed emissions database for Europe. This enabled deposition maps to be produced to a resolution of approximately 50 km. The distribution of pollutant concentrations in forest soils was calculated for each grid cell using a database of soil property parameters in Europe. For the North Sea, a model was used to map long-term concentrations in water and sediment, which are due to atmospheric deposition and other, non-atmospheric sources. The model calculations allowed detailed comparisons of deposition fluxes and concentrations of the substances studied with critical loads and environmental quality threshold values, including critical loads. Although significant uncertainties were identified, the study gives insight in how threshold exceedance rates in Europe relate to pollutant type, threshold type, environmental compartment and chemophysical phase (adsorbed, dissolved). For all pollutants and for all compartments exceedances were calculated for at least some of the quality thresholds that were chosen.
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  • 33
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    Water, air & soil pollution 112 (1999), S. 21-40 
    ISSN: 1573-2932
    Keywords: China ; eutrophication ; heavy metals ; palaeolimnology ; spheroidal carbonaceous particles
    Source: Springer Online Journal Archives 1860-2000
    Topics: Energy, Environment Protection, Nuclear Power Engineering
    Notes: Abstract There is growing concern about the environmental impact of rapid economic growth in China. The problem is compounded by the scarcity of baseline data on the state of China's natural environment. As a step towards solving this problem, palaeolimnological methods have been applied to seven lakes in the Jianghan Plain, China, to evaluate recent changes in human impact. Lake sediment cores show enhanced concentrations of fossil fuel derived spheroidal carbonaceous particles (SCP) and Pb at all sites across the Jianghan Plain. The distribution of these industrial contaminants shows the overwhelming influence of the industrial cities. Wuhan dominates the fossil fuel derived pollution, while the copper smelter at Daye dominates the heavy metal pollution. Analysis of sediment diatom assemblages indicates mean total phosphorus concentrations of greater than 40 μg L-1 P in the lakes of the more intensely agricultural western part of the Jianghan Plain. The sediment concentration profiles for biogenic elements at these sites indicates a post-1960 eutrophication. Evidence for eutrophication in the eastern lakes is much weaker, though some evidence is present at all sites. The tracers of industrial pollution (Pb and SCP) correlate with Mn in the many of the lake sediments. This is compatible with both soil acidification, and soil gleyification due to intensified rice production.
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  • 34
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    Water, air & soil pollution 112 (1999), S. 349-363 
    ISSN: 1573-2932
    Keywords: aerosols ; heavy metals
    Source: Springer Online Journal Archives 1860-2000
    Topics: Energy, Environment Protection, Nuclear Power Engineering
    Notes: Abstract An extensive study of the different heavy metals (Fe, Mn Ni, Cr, Zn, Cd, Pb, Cu) present in the atmospheric aerosols collected at two stations in Mallorca located in the evirons of a new incinerator plant has been carried out. The aim of this study is to establish the quality of the air surrounding this new MSW (Municipal Solid Waste) incinerator on the island of Mallorca prior to its setting up. Besides, a study of the distribution of the analyzed metals in both the fine (diameter ≤1.5 μm) and coarse (diameter ≥1.5 μm) fractions of the aerosol has been performed. Concentrations of heavy metals in the atmospheric aerosols prior to the running of the new incinerator plant were found to be very low and similar to the values obtained at other Mediterranean stations.
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  • 35
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    Water, air & soil pollution 113 (1999), S. 115-125 
    ISSN: 1573-2932
    Keywords: adsorption ; clay ; desorption ; heavy metals
    Source: Springer Online Journal Archives 1860-2000
    Topics: Energy, Environment Protection, Nuclear Power Engineering
    Notes: Abstract This study evaluated the effect of competing copper, zinc, cadmium and nickel ions in 0.01 M Ca(NO3)2 on heavy metal sorption and desorption by soil clay fractions. Initial Cu addition levels varied from 99 mg kg-1 to 900 mg kg-1 and Zn, Cd and Ni levels were 94, 131 and 99 mg kg-1, respectively. Sorption of Cu conformed to a Freundlich equation. The amounts of metals not displaced by successive 48 h desorption cycles with 0.01 M Ca(NO3)2 were considered ‘specifically adsorbed’. Total sorption of Zn and Cd generally decreased in the order: Vertisol 〉 Gleyic Acrisol 〉 Planosol clay. More than 70% of the copper was specifically sorbed. Specific sorption of Zn was depressed by competition with Cu in the three clays investigated. At surface coverages higher than 200 mg Cu per kg of soil clay, zinc sorption in the Planosol and Gleyic Acrisol clays took place at low affinity sites. The exchangeable component of sorbed cadmium accounted for 〉:60% of the sorption in the Vertisol clay, 〉70% in the Gleyic Acrisol clay and was almost 100% in the Planosol clay. Nickel was not retained by the Planosol and Gleyic Acrisol clays and was ionexchangeably adsorbed by the Vertisol clay. At the conditions studied, Ni and Cd remain a ready source of pollution hazard.
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  • 36
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    Water, air & soil pollution 113 (1999), S. 261-272 
    ISSN: 1573-2932
    Keywords: coal fly ash ; heavy metals ; nutrient cycling ; sewage sludge ; soil enzymes
    Source: Springer Online Journal Archives 1860-2000
    Topics: Energy, Environment Protection, Nuclear Power Engineering
    Notes: Abstract Previous studies showed that coal fly ash could stabilize sewage sludge by reducing metal availability, but fly ash may cause an adverse effect on soil microbial activities. Therefore, an experiment was performed to evaluate the effects of amendment of soil with anaerobically digested dewatered sewage sludge, stabilised with alkaline coal fly ash, on soil enzyme activity and the implications for soil nutrient cycling. Sewage sludge was amended with 0, 5, 10, 35 and 50% w/w of fly ash, and then the ash-sludge mixtures were incubated with a sandy soil at 1:1 (v/v). Dehydrogenase activity decreased with an increase in fly ash amendment level and the time of incubation. Soil receiving 5% ash-sludge amendment had a higher dehydrogenase activity than other treatments. Soil receiving 10% ash-sludge mixture had the highest urease activity and in general, urease activity decreased with increasing incubation time. Phosphatase activity was the highest at 5% ash-sludge mixture amended soil and no general trend was observed with time. Water-soluble Zn, Mn and Cu contents were suppressed by the addition of fly ash. The present experiment indicated that addition of 10% ash-sludge mixture should have a positive benefit on the activity of soil microorganisms, N and P nutrient cycling, and reduce the availability of heavy metals.
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  • 37
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    Water, air & soil pollution 114 (1999), S. 251-276 
    ISSN: 1573-2932
    Keywords: canola meal ; energy dispersive X-ray ; heavy metals ; scanning electron microscopy ; sorption
    Source: Springer Online Journal Archives 1860-2000
    Topics: Energy, Environment Protection, Nuclear Power Engineering
    Notes: Abstract The results from this research indicate that canola meal (CM) can be used for adsorption of Zn2+, Cd2+, Cu2+, Pb2+and Ni2+from aqueous solutions. The order of sorption for these metals in single metal systems was as follows (molar basis): Zn2+〉 Cu2+〉 Cd2+〉 Ni2+〉 Pb2+. It was noted that a decrease in the concentration of CM caused a higher metal loading on the meal. Increases in the metal concentration, temperature or pH resulted in increased sorption of the metals by the meal. The systems with identical ratios of CM to Zn2+concentrations, regardless of their levels, resulted in the same amount of metal adsorbed per unit weight of meal. The Freundlich isotherm type model was used in this study and was found to fit the experimental equilibrium concentration data of Zn2+and Cd2+; however, the Langmuir isotherm model fit only the equilibrium data of Zn2+. Scanning Electron Microscopy (SEM) and Energy-Dispersive X-ray (EDX) microanalyses revealed that the metal ions were sorbed mainly at the cell wall and only small amounts of ions diffused into the cytoplasm of the CM cells. The Electron Spin Resonance (ESR) tests were inconclusive regarding the direct participation of free radicals in copper sorption.
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  • 38
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    Water, air & soil pollution 114 (1999), S. 339-346 
    ISSN: 1573-2932
    Keywords: biomonitoring indices ; germination ; heavy metals ; lead ; mercury ; rice ; seedling growth
    Source: Springer Online Journal Archives 1860-2000
    Topics: Energy, Environment Protection, Nuclear Power Engineering
    Notes: Abstract Treatment of seeds of two rice (Oryza sativa L.) cultivars (Ratna and IR36) separately with 10-5and 10-4M PbCl2and HgCl2decreased germination percentage, germination index (GI), shoot and root length, tolerance index (TI), vigour index (VI) and dry mass of shoot and root but increased percentage difference from control (% DFC) of germination and percentage phytotoxicity in both the cultivars. It was observed from these indices that the phytotoxic effect of mercury was greater than lead at identical concentrations and that IR36 appeared more tolerant than Ratna to these metals. Among the monitoring indices examined, TI, VI, and % phytotoxicity seemed to serve as good biological monitoring methods for evaluating the relative toxicity of lead and mercury to rice cultivars.
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  • 39
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    Water, air & soil pollution 115 (1999), S. 347-361 
    ISSN: 1573-2932
    Keywords: Bangladesh ; contamination ; heavy metals ; soils ; vegetation
    Source: Springer Online Journal Archives 1860-2000
    Topics: Energy, Environment Protection, Nuclear Power Engineering
    Notes: Abstract A study was conducted to investigate the heavy metal contamination of soil and vegetation in the vicinity of industries around Dhaka city in Bangladesh. Categorically soils, grass (Cynoden doctylon L), water hyacinth (Eichhornia crassipes L), rice (Oryza sative L), and arum (Alocasia esculenta L) were collected from tannery, ceramic, textile dying and sulphuric acid producing industrial sites. The concentrations of total Cd, Cu, Mn, Ni, Pb and Zn ranged from 0.1–1.8, 28–217, 106–577, 25–112, 17–99 and 53–477 mg kg−1 soil, respectively among the industrial sites. The concentrations of some heavy metals ranged from background levels to levels in excess of tolerable limits in agricultural soils. The concentrations of total Cu, Mn, Ni, Pb and Zn decreased with increasing distance from the disposal points of the tannery and the textile dying industries. Cadmium, Cu, Mn, Ni, Pb and Zn showed highly significant (p 〈 0.01) positive correlations with their total and DTPA-extractable contents in soils. The concentrations of most heavy metals were also higher in the vegetation samples of tannery area and the content of Pb (13–45 mg kg−1) in grass samples exceeded the toxic limit. In correlation matrix, plant concentrations of Cu, Mn, Pb and Zn were significantly correlated with their total and extractable contents in soils.
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  • 40
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    Water, air & soil pollution 115 (1999), S. 385-394 
    ISSN: 1573-2932
    Keywords: ferrite sludge ; heavy metals ; magnetic separation ; wastewater
    Source: Springer Online Journal Archives 1860-2000
    Topics: Energy, Environment Protection, Nuclear Power Engineering
    Notes: Abstract The purification of wastewater containing dissolved metal ions by in situ precipitation gives rise to a sludge composed mainly of ferrites MeXFe3-xO4 (where Me represents the existing metal ions in the wastewater). Oxides, iron oxy-hydroxides and other impurities are also present in the sludge in smaller proportion. The present investigation proposes magnetic separation of the sludge to recover the ferrites for their possible re-use. Under optimum operating conditions of the magnetic separator, a recovery efficiency of the magnetic fraction in excess of 99% and a high degree of selectivity were obtained.
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  • 41
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    Water, air & soil pollution 115 (1999), S. 465-479 
    ISSN: 1573-2932
    Keywords: gravel sludge ; heavy metals ; immobilization ; soil remediation
    Source: Springer Online Journal Archives 1860-2000
    Topics: Energy, Environment Protection, Nuclear Power Engineering
    Notes: Abstract Field plot studies were conducted on sandy loam soils in Dottikon, Rafz and Giornico contaminated by Zn, Cu and Cd to investigate the effectiveness of gravel sludge as an in situ immobilization additive. In addition to NaNO3-extractable heavy metal concentrations in the soil, metal concentrations in ryegrass (Lolium perenne L.) and lettuce (Lactuca sativa L.) were analyzed at two application doses of gravel sludge. Application of gravel sludge increased pH in all three topsoils by up to 0.6 units and reduced NaNO3-extractable Zn concentrations by more than 65%. No effect was seen for the NaNO3-extractable Cu concentrations in Rafz and even an increase resulted in Giornico. In Dottikon, gravel sludge additions decreased the NaNO3-extractable Cu concentrations from 0.97 to 0.7 mg kg−1 and reduced the concentrations of Zn and Cu by more than 35% in ryegrass. For lettuce grown in Giornico and Dottikon, we found reductions of Zn and Cd concentrations by 22 to 48%, whereas in Rafz, no significant variations were found. Immobilization by gravel sludge was most efficient in soils with high total/NaNO3-extractable heavy metal ratio and more effective for ryegrass than for lettuce. Part of the immobilization effect was due to a pH increase, caused by CaCO3 in gravel sludge.
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  • 42
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    Water, air & soil pollution 114 (1999), S. 413-421 
    ISSN: 1573-2932
    Keywords: heavy metals ; incineration ; medical waste ; Taiwan
    Source: Springer Online Journal Archives 1860-2000
    Topics: Energy, Environment Protection, Nuclear Power Engineering
    Notes: Abstract The purpose of this study was threefold: to investigate the types and amounts of medical waste from various hospitals in Taiwan; to analyze residues from incinerated medical waste for heavy metal content; and to measure the amount of infectious and general medical waste per bed per day and determine the ratio of infectious to general medical waste. Information was first obtained on the amounts of medical waste produced per bed per day and on waste handling and treatment. Next, residue samples were taken from incinerators and analyzed for heavy metal content. Third, daily records concerning waste content and weight from one hospital were kept over the period of one year. Chromium (Cr) and zinc (Zn) concentrations were significantly higher in medical waste than in general waste. Medical waste fluctuated significantly over the one-year period. Records showed that wastes containing dialysis material and wood/cotton materials were found to have the highest weight and wastes containing human organs had the lowest weight. Results of the present study underscore the need for all hospitals to effectively separate waste for proper treatment and disposal, particularly waste that produces residues which may be hazardous to the environment. In addition, hospitals also need to recycle or reuse certain materials in order to reduce waste production.
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  • 43
    ISSN: 1573-2932
    Keywords: bio-accumulation ; heavy metals ; Louisiana ; Parmotrema praesorediosum ; partitioning ; sulfur dioxide ; Tillandsia usneoides ; X-ray micro-probe analysis
    Source: Springer Online Journal Archives 1860-2000
    Topics: Energy, Environment Protection, Nuclear Power Engineering
    Notes: Abstract Samples of the epiphytic bromeliad Tillandsia usneoides L. (Bromeliaceae) and the lichen Parmotrema praesorediosum (Nyl.) Hale, growing on bald cypress trees in southern Louisiana, were chemically examined by means of X-ray micro-probe analysis to determine their comparative elemental content. The plants were found to effectively bio-accumulate heavy metals and sulfur from the atmosphere; the accumulatory capacities and implications are discussed. Partitioning occurs within the plants of T. usneoides and consequently any analytical procedure should standardise on precisely which parts are to be analysed. The bio- accumulation of certain heavy metals such as manganese, nickel and cadmium increases with age of the T. usneoides.
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  • 44
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    Water, air & soil pollution 114 (1999), S. 377-394 
    ISSN: 1573-2932
    Keywords: heavy metals ; snow quality ; urban snow
    Source: Springer Online Journal Archives 1860-2000
    Topics: Energy, Environment Protection, Nuclear Power Engineering
    Notes: Abstract The aim of the study was to investigate how the quality of snow varies within a city. The study area is situated in the Luleå municipality, in northern Sweden (lat. 65°35′N and long. 22°10′E). For this study, the city was divided into three different types of areas: housing areas, city centre and outskirts. In one area of each type, sampling sites were selected. Snow samples were taken at nine occasions, once every fourteenth day in the city centre and in the housing area. Analyses were carried out for pH, conductivity, suspended solids and both the total and dissolved concentration of phosphorus and selected metals. It was concluded that traffic or activities related to traffic were a major source of heavy metals and phosphorus in urban snow, both in the city centre and in the housing area. Also, the type of area and the design of the street were important for the quality of snow. A clear relation was found between the pH and the quantity of suspended solids in the snow. Higher pH values were found in snow samples from sites with higher traffic loads, and lower pH values at sites, which were the no-traffic sites, with small quantities of particles. The particulate and dissolved substances in the snow behaved in different ways.
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  • 45
    ISSN: 1573-3017
    Keywords: NOEC ; competition ; biodiversity ; nematodes ; heavy metals
    Source: Springer Online Journal Archives 1860-2000
    Topics: Energy, Environment Protection, Nuclear Power Engineering
    Notes: Abstract In estimating the effects of toxic substances on ecosystems we generally lack information on the sensitivity (expressed as a no-observed effect concentration, NOEC) of individual species in the field, and have to rely on information from laboratory test species, expressed as a frequency distribution of NOECs. In this case we can express toxic stress as the fraction of organisms that is exposed above its NOEC: the potentially affected fraction (PAF). This paper describes a model of the soil food web and the effect of toxic stress by persistent pollutants. The model predicts that in the absence of competition, individual species disappear from the foodweb at toxic concentrations 3–5 times their NOEC. With competition present, species affected by toxic stress are replaced by less sensitive ones. This has a twofold effect: species disappear from the foodweb at a lower concentration because loss of competitiveness occurs well before absolute extinction, but the replacement of disappearing species implies that the effect on total biomass and diversity becomes only noticeable at a PAF level near 100%. Model predictions are in good agreement with observations on nematode communities in experimental fields contaminated with copper and zinc. The model serves to illustrate why overall measures of ecosystem functioning (total biomass, production, diversity) are affected by toxic stress only at high levels of pollution, which is particularly true for systems with a high diversity. This apparent robustness masks a considerable genetic ‘erosion’, i.e. the disappearance of sensitive species or genotypes. The PAF is a good indicator of the latter effect.
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  • 46
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    Environmental geochemistry and health 21 (1999), S. 97-115 
    ISSN: 1573-2983
    Keywords: heavy metals ; particle size control ; polluted dusts and sediments
    Source: Springer Online Journal Archives 1860-2000
    Topics: Geosciences , Medicine
    Notes: Abstract Samples of urban dusts and sediments have been collected and categorised into three compartment those which act mainly as sources, those undergoing transport and those which have been deposited. The sediments were fractionated into 〈 63 μm to match similar sized lacustrine sediments and 〈 2 mm to represent natural and anthropogenic fluvially transported sediments. Preliminary results of total heavy metals analysis show that the 〈 2 mm fraction of the source group exhibits the greatest variabilty in metal concentrations. Overall, however, the 〈 63 μm fraction dominates regardless of compartment. Some heavy metal concentrations decrease through the source‐transport‐deposit process, possibly due to selective onward transport of finer material or other anthropogenic processes unique to the urban environment (e.g. street cleansing). Site‐specificity is indicated in a comparison with other similar studies.
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  • 47
    ISSN: 1573-2983
    Keywords: contaminated land ; in situ remediation ; heavy metals ; bioavailability ; zeolites
    Source: Springer Online Journal Archives 1860-2000
    Topics: Geosciences , Medicine
    Notes: Abstract The addition of synthetic zeolites and similar materials to metal contaminated soils has been shown to reduce soil phytotoxicity and to improve the quality of plant growth on such amended soils. To gain an understanding of the mechanism by which the phytotoxicity of contaminated soils is reduced when treated with synthetic zeolites, sequential extraction procedures and soil solution techniques have been used to identify changes associated with metal speciation in amended soils. Sequential extraction data and changes in soil solution composition are presented for three different contaminated soils, amended with three synthetic zeolites (P, 4A and Y) at concentrations of 0.5%, 1% and 5% w/w, or lime at 1%. The soils were collected from the site of a metal refinery, an old lead zinc mine spoil tip and from a field which had been treated with sewage sludge. After incubation of the zeolite treated soils for between one and three months, results showed a reduction in the metal content of the ammonium acetate fraction between 42% and 70%, depending on soil, zeolite and rate of addition, compared with the unamended soils. In addition, soil solution experiments indicated that synthetic zeolite amendments were more efficient at reducing metal content than comparable lime treatment. The mechanism by which synthetic zeolites reduce metal bioavailability in contaminated soils is discussed and compared to other amendments.
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  • 48
    ISSN: 1573-2959
    Keywords: birds ; environmental pollutants ; heavy metals
    Source: Springer Online Journal Archives 1860-2000
    Topics: Energy, Environment Protection, Nuclear Power Engineering
    Notes: Abstract Levels of environmental pollutants are usually higher in mainland and coastal areas than in offshore or oceanic islands due to higher inputs from agricultural and industrial sources. Levels of heavy metals are usually higher in adult than in young birds, because they have had longer to accumulate metals in their tissues, and/or because they may eat larger, more contaminated, prey. We examined the levels of arsenic, cadmium, chromium, lead, manganese, mercury, and selenium in the adults and young of Bonin petrel (Pterodroma hypoleuca), Christmas shearwater (Puffinus nativitatis) and red-tailed tropicbird (Phaethon rubricauda) on Midway Atoll, and adult wedge-tailed shearwater (Puffinus pacificus) on Midway Atoll and on Manana Island (off Oahu) in the northern Pacific. All birds were analyzed individually except for Christmas Shearwater chicks where samples were pooled to obtain sufficient quantities for analysis. Significant (p〈0.05) age-related differences were found for mercury, selenium, manganese and chromium in Bonin petrels, for selenium and mercury in Christmas shearwaters, and for chromium and mercury in Red-tailed Tropicbirds. Lead approached significance for all three species. Adults had higher levels than young except for chromium and manganese in the petrels and arsenic in all three species. There were significant interspecific differences in concentrations of all metals except arsenic for the adults nesting on Midway. Christmas shearwaters had the highest levels of all metals except mercury and chromium. Bonin petrels, the smallest species examined, had mercury levels that were over three times higher than any of the adults of the other three species. For wedge-tailed shearwaters, levels of chromium and lead were significantly higher, and manganese and selenium were lower on Midway than Manana. Knowledge of the foraging ranges and habits of these far-ranging seabirds is inadequately known, but does not currently explain the observed differences among species. We could not find a consistent pattern of differences between the burrow nesting species (Bonin petrel, Wedge-tailed shearwater) and the surface nesting tropicbirds. There was no consistent pairwise correlation between any metals across all species.
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  • 49
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    Springer
    Wetlands ecology and management 7 (1999), S. 13-23 
    ISSN: 1572-9834
    Keywords: altered hydrological regimes ; heavy metals ; nutrient enrichment ; pesticides ; salinization ; wetland degradation ; wetland loss
    Source: Springer Online Journal Archives 1860-2000
    Topics: Biology
    Notes: Abstract Many wetlands (estimated to be about 70%) have been lost in the coastal plain region of southwestern Australia since British settlement (in 1829), primarily as a result of infilling or drainage to create land for agricultural use or urban development. While further loss is almost universally acknowledged as undesirable, wetland degradation continues with little overt public recognition of the causes or consequences. Obvious and direct causes include nutrient enrichment, salinization, pollution with pesticides and heavy metals, the invasion of exotic flora and flora, loss of fringing vegetation and altered hydrological regimes occurring as a result of urbanization and agricultural practices. Underlying causes include a lack of understanding of wetland hydrology and ecology on behalf of both planning agencies and the private sector, and poor coordination of the many different agencies responsible for wetland management. Public and political awareness of wetland values continues to increase, but sectoral organization and responsibilities for wetland management lag behind. Sufficient scientific information now exists for improved management, protection and restoration of wetlands in southwestern Australia. However, this improvement cannot occur without the necessary political will and corresponding sectoral responses needed to implement coordinated wetland management policies and actions.
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  • 50
    ISSN: 1573-5117
    Keywords: Elbe ; heavy metals ; point and diffuse sources ; river loads ; retention
    Source: Springer Online Journal Archives 1860-2000
    Topics: Biology
    Notes: Abstract Two independent methods are presented to estimate point and diffuse source contributions in emissions and riverine loads. The first method uses emission factors and areal statistics of the Elbe catchment to estimate the emissions of the diffuse and point sources. The second method relies on relationships between load–discharge and concentration–discharge, using monitoring data from several water quality stations. These statistical relationships are then used to separate point and diffuse contributions to the total riverine load, after incorporating the point waste water flow discharges. Both methods are applied to the Elbe river for the period 1992–1995 to estimate the contribution of point and diffuse sources for six heavy metals. The results of the source apportionment estimates for the Elbe river show that there are regional differences in source strength and source origin. The main inputs of metals occur in the Czech Republic nowadays, whereas for Cd the Mulde catchment contributes large amounts. The comparison of both methods shows some differences, which are caused by retention in the river system and uncertainties in emissions.
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  • 51
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    Springer
    Photosynthetica 36 (1999), S. 321-331 
    ISSN: 1573-9058
    Keywords: Calvin cycle enzymes ; chlorophyll ; chloroplast structure ; heavy metals ; photosynthesis ; photosystems ; plant growth ; uptake of mineral elements
    Source: Springer Online Journal Archives 1860-2000
    Topics: Biology
    Notes: Abstract Cadmium is one of the most dangerous environmental pollutants, affecting, among other things, plant mineral composition. It easily interacts with iron, one of the most important elements for plant growth and metabolism. This interaction, including modifying effects of lowered or excessive Fe supply on Cd-exposed plants and its consequences for the photosynthetic apparatus is reviewed. The influence of modified Fe and Cd supply on the uptake of both metals, their distribution, plant growth, and photosynthesis is also explained. Moderate Fe excess has a beneficial influence on Cd-treated plants, resulting in more intensive growth, photosynthetic pigments accumulation, and more efficient light phase of photosynthesis. Nutrient-medium Fe deficiency increases plant susceptibility to Cd. The main open questions of Cd/Fe interaction are: (1) the strong Fe-dependency of Cd mobility within the plant, and (2) photosynthetic dark phase adaptation to Cd stress.
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  • 52
    ISSN: 1573-5125
    Keywords: accumulation ; bats ; Chironomidae ; Chiroptera ; food chain transfer ; heavy metals ; Myotis dasycneme ; PAHs ; PCBs ; pesticides ; sediment
    Source: Springer Online Journal Archives 1860-2000
    Topics: Biology
    Notes: Abstract Transfer ratios of metals, PCBs, pesticides and PAHs from the sediment to chironomid larvae and adults collected in a highly contaminated area, the Biesbosch, were studied. Metal concentrations in larvae were 0.28 (Cd), 0.02 (Cr), 0.52 (Cu), 0.06 (Hg), 0.03 (Pb), 0.32 (Zn) times those found in standard sediment, on a dry weight basis. Hg and Zn were well transported to the adult stage. Dry weight ratios of contaminant residues in adults and in larvae were 0.38 (Cd), 0.23 (Cr), 0.62 (Cu), 1.03 (Hg), 0.08 (Pb), 0.94 (Zn). For PCBs and pesticides, the concentration ratios of chironomid larvae fat to sediment (dry organic matter) varied around 3.3, which is consistent with laboratory studies. Organochlorine residues in adult fat were comparable to those in larvae lipids. However, the concentrations of non-ortho PCBs were 1.7 times higher in adults. For polycyclic aromatic hydrocarbons (PAH), larval fat:sediment (organic matter) concentration ratios ranged from 0.004 to 0.1. Adult: larvae ratios for PAHs varied between 0.2 and 0.6. For naphthalene a much higher transport ratio of 2 was found. Chironomid adults are the most important potential food source of the Pond bat, which lives in low densities in the Biesbosch. The contaminant concentrations measured in the chironomids do not exceed diet levels that are thought to be safe for mammals. However, Pond bats collected in less contaminated areas contained PCB-concentrations of 9, 33 and 76 mg kg−1 lipid weight, which are above concentrations that cause reproduction effects on Mink.
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  • 53
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    Journal of applied phycology 11 (1999), S. 79-87 
    ISSN: 1573-5176
    Keywords: biosorption ; seaweeds ; ion exchange ; pH ; ionic strength ; heavy metals
    Source: Springer Online Journal Archives 1860-2000
    Topics: Biology
    Notes: Abstract Biosorption, the passive accumulation of metal ions by biomass, can be used for purifying metal bearing wastewater. Seaweeds represent a readily available source of biosorbent material that possesses a high metal binding capacity. For example, Sargassum can accumulate 2 mequiv of Cd per gram of biomass i.e. 10% of its dry weight. Binding of Cd and Cu by Sargassum is an ion exchange process involving both covalent and ionic bonds. The amount of cations bound covalently or by complexation can be predicted using multi-component sorption isotherms involving 2 types of binding sites, carboxyl and sulphate. A Donnan model was used to account for the effect of ionic strength and electrostatic attraction. The use of a multi-component isotherm that included one term for Na binding was less appropriate than the Donnan model for modelling ionic strength effects. It was possible to predict metal and proton binding as a function of the pH value, metal concentration and ionic strength of the solution.
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