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  • Chemistry  (2,639)
  • 1980-1984
  • 1955-1959  (2,639)
  • 1957  (2,639)
  • 1
    Electronic Resource
    Electronic Resource
    Hoboken, NJ : Wiley-Blackwell
    AIChE Journal 3 (1957), S. 213-222 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: Data were obtained in flat-plate continuous-flow thermogravitational columns to check the theory developed by Furry, Jones, and Onsaer and a modification of this theory proposed by the authors. Separations of ethyl alcohol-water and benzene-n-heptane mixtures were measured, flow rate, column length, temperature difference, spacing between plates, and inclination of the plates being varied in the experiments. Theory and data are in qualitative agreement for the range of variables studied. Quantitative agreement exists between theory and experiment in the region of practical design for liquid-thermal-diffusion plants.Equations to aid in the design of thermal-diffusion plants are developed, and a plant to treat 1,000 bbl./day of a liquid aromatic-aliphatic mixture is designed and costs are estimated.
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  • 2
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    Hoboken, NJ : Wiley-Blackwell
    AIChE Journal 3 (1957), S. 198-207 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: A solution to the Stefan-Maxwell diffusion equations for equimolal countercurrent diffusion in a three-component gas mixture is obtained which is similar in form to Gilliland's equation for diffusion of two gases through a third inert gas. The important features of both types of diffusion are investigated and the conditions under which the following phenomena occur are determined: (1) diffusion barrier (the rate of diffusion of a component is zero even though its concentration gradient is not zero); (2) osmotic diffusion (the rate of diffusion of a component is not zero even though its concentration gradient is zero); (3) reverse diffusion (a component diffuses against the gradient of its concentration).A generalized driving force which describes these phenomena is introduced, and approximate equations are developed which give the individual rates of diffusion directly.
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  • 3
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    Hoboken, NJ : Wiley-Blackwell
    AIChE Journal 3 (1957), S. 208-212 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: The effective correlations of turbulent velocities and friction losses for tubes and parallel plates recently published have been analyzed further in order to simplify their use and to extend the range of Reynolds number.Working diagrams have been developed from which turbulent friction losses and local velocities for tubes and parallel plates can be calculated without interpolation or trial-and-error procedures. Tentative values of parallel-plate friction factors and average-to-maximum velocity ratios in the transition region are also included, and new experimental values of the velocity ratio in smooth tubes are reported. The working diagrams permit more rapid, accurate, and consistent calculations of fluid behavior to be made over a wider range of operating conditions than was previously possible.
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  • 4
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    Hoboken, NJ : Wiley-Blackwell
    AIChE Journal 3 (1957), S. 230-235 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: Reaction kinetics for the catalytic dehydrogenation of sec-butyl alcohol to methyl ethyl ketone has been investigated at atmospheric pressure and temperatures ranging from 650° to 750°F. in the presence of solid brass spheres, 1/8 in. in diameter. The nature of this catalyst permitted a direct evaluation of the surface involved in this reaction and allowed the definition of a surface-feed ratio to be expressed as S/F in place of the conventional weightfeed ratio W/F commonly used in catalytic studies. Feed compositions ranged from secbutyl alcohol to mixtures containing high percentages of methyl ethyl ketone and hydrogen.In these studies mass transfer effects were found to be significant and, for a proper representation of conditiated at the catalyst surface, must be taken into account. The effect of feed compositions on the initial rates of reaction showed that the rate-controlling step was the desorption of hydrogen involving a single-site mechanism.In addition, the results of these studies have been used to produce values of height of reactor unit HRU which have been found to correlate with mass velocity and temperature. The HRU provides a simple means of calculating the depth of catalyst necessary to effect a designated conversion.
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  • 5
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    Hoboken, NJ : Wiley-Blackwell
    AIChE Journal 3 (1957), S. 242-248 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: Heat transfer and friction measurements were made for air flow through a smooth copper pipe and six other commercial pipes, with a ratio of diameter to equivalent sand roughness varying from 640 to 64. The Reynolds number range was 10,000 to 80,000. Though some increase in heat transfer coefficients with roughness was found, the heat transmission per unit power loss always decreased.The momentum-heat-transfer anlogies of Reynolds and Colburn are shown to be inadequate for handling the experimental data. Those of Prandtl and Taylor, von Kármán, and Pinkel fail to show a required Reynolds number dependence of jh when friction factor has become independent of Reynolds number for a rough pipe. Martinelli's equation shows such dependence and, even in approximate form, gives good prediction of the experimental results.
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  • 6
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    Hoboken, NJ : Wiley-Blackwell
    AIChE Journal 3 (1957), S. 248-256 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
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  • 7
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    Hoboken, NJ : Wiley-Blackwell
    AIChE Journal 3 (1957), S. 325-329 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: The surface tensions against air of acetone-water solutions have been measured over the entire composition range from 20°C. to generally within 1° to 10°C. of the normal boiling points. The capillary-height method was employed and the results are thought to be accurate to better than ±0.5%.
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  • 8
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    Hoboken, NJ : Wiley-Blackwell
    AIChE Journal 3 (1957), S. 329-330 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: With stationary isotropic turbulence postulated, the rate of decrease in concentration fluctuations of a scalar contaminant is estimated in terms of the turbulence scale and the power input to the system.
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  • 9
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    Hoboken, NJ : Wiley-Blackwell
    AIChE Journal 3 (1957), S. 331-335 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: Extension of the kinetics of the catalytic oxidation of nitric oxide on activated carbon and silica gel confirms the rate-controlling step postulated by previous workers. The effect of variables including water vapor on the reaction rate is expressed by an equation containing the constants a, b, c, and w, which have been evaluated for both catalysts at 30°, 45°, and 60°C. The effect of water vapor is to reduce the reaction by reversible adsorption on the active sites of the catalyst. The value of w is dependent on temperature but independent of water-vapor concentration up to a relative humidity of 20%. Above 20% the value of w for activated carbon increases greatly with relative humidity, in agreement with the effect of capillary adsorption at high water contents.
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  • 10
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    AIChE Journal 3 (1957), S. 343-347 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: Constant layer moisture at the hot surface is found to exist during the constant-rate period of drying of sand on a hot surface in still air. It accounts not only for the constantrate period of drying itself but also largely for the length of the period.Temperature of the air-surface interface usually has minor effects on the rate of vaporization because equilibrium between vapor and the bed is not established during periods of rapid vaporization.Numerical relationships have not been established.
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  • 11
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    AIChE Journal 3 (1957), S. 336-342 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: Plate efficiencies measured on 18-in.-diam. sieve plates are reported for the acetic acid-water system and for the methyl isobutyl ketone-water system at atmospheric pressure. In the former system the major resistance to mass transfer is in the gas phase; liquid-phase resistance to mass transfer is controlling in the latter. Efficiencies are also reported for the aniline-nitrobenzene system (gas-phase resistance controlling) at 5 mm. Hg absolute on 6-in.-diam. sieve plates. Pure gas- and liquid-phase efficiencies for both plate designs were determined by the adiabatic humidification of air and the desorption of oxygen from water into air. Predicted values of plate efficiency for each of the binary systems studied were computed from the pure phase efficiencies according to the procedure outlined by Gerster et al. A comparison between measured and predicted efficiencies is presented as a guide for future research in this field.
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  • 12
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    AIChE Journal 3 (1957), S. 353-360 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: Linear partial-differential eqations are often encountered when thermal or material diffusion in flowing systems is considered. Analytic solutions of such equations are known for only the simplest situations. In two examples a graphical method of solution is presented and demonstrated which makes feasible, without excessive labor or special computing facilities, the use of available knowledge concerning turbulent flow in the prediction of thermal or material transfers in complex situations involving linear steady flow.
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  • 13
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    Hoboken, NJ : Wiley-Blackwell
    AIChE Journal 3 (1957), S. 348-352 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: The behavior of the film coefficient of heat transfer for the condensation of organic vapor mixtures was investigated experimentally to establish a satisfactory basis for applying the Nusselt equation to binary systems. Five ideal and nonideal pairs, all of which gave miscible condensates, were studied; the work was carried out under conditions of almost total condensation on a horizontal condensing surface designed to comply as rigidly as possible with the conditions for which Nusselt's equation is valid.The same behavior was observed for all systems and all concentrations studied: the experimental coefficients fell between those for the pure components and followed the behavior pattern for pure components when the temperature difference was taken as that between the bubble point of the condensate and the surface temperature, rather than between the dew point or the measured vapor temperature and the surface temperature, Correlation of the film coefficient showed it to vary approximately linearly with composition if the coefficients were compared at a constant value of the temperature difference, defined as above. This permits determination of the coefficient for a mixture by interpolation between the coefficients for the pure components, which are easily obtained, in preference to making the calculations with the properties of the mixture obtained by laborious and uncertain weighting of the corresponding properties of the pure components.When results are interpreted in the light of the theories of Colburn and Drew, the presence of a vapor-phase resistance to heat and mass transfer, as postulated by them, is indicated.
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  • 14
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    Hoboken, NJ : Wiley-Blackwell
    AIChE Journal 3 (1957), S. 361-365 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: Two-phase critical flow of steam-water mixtures has been investigated over a pressure range from 4 to 43 1b./sq.in. abs. and a quality range from saturated vapor to 1% (weight) vapor. Discharges were measured from 1/4-,1/2-, 3/4-, and 1-in. pipes and from annuli of intermediate cross-sectional areas. The experimental mass flow rates are always grteater than the values calculated on the basis of a homogeneous flow model. Several empirical methods for correlating the data were determined, and comparisons are presented of the predictions of several analytical flow models.
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  • 15
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    AIChE Journal 3 (1957), S. 366-372 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: Kinetic studies were made in a differential flow reactor of the hydogenation of α-methyl-styrene with the liquid trickling over a bed of catalyst pellets countercurrent to a stream of hydrogen. The catalysts consisted of palladium, platinum, rhodium, ruthenium, and nickel supported on the external surfaces of aluminal pellets.With palladium at pressures above 3 atm. the apparent rate-controlling step was a surface reaction between dissociated hydrogen and α-methylstyrene both adsorbed on different type of active sites. Below 3 atm. pressure the reactants competed for similar active sites. With platinum the apparent rate-controlling step was a surface reaction between dissociated hydrogen and α-methylstyrene on similar active sites. Rhodium and nickel catalyzed the polymerization α-methylstyrene together with slow hydrogenation. Ruthenium had negligible activity for catalyzing the hydrogenation under the moderate conditions used in this work.In all cases mass transfer resistances were negligible.
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  • 16
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    Hoboken, NJ : Wiley-Blackwell
    AIChE Journal 3 (1957), S. 373-381 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: Applying both their own assumptions and the mechanism of lateral mixing proposed by Ranz (20), the authors obtained theoretical formulas for effective thermal conductivities ke in packed beds. Previously reported experimental data were analyzed with these equations, and the usable data for predicition of ke were shown.In order to see the influence of both packing characteristics and temperature on the effective thermal conductivities, experimental data were obtained with air for beds with various kinds of packing, i.e., iron spheres, porcelain packings, cement clinker, insulating fire brick, and Raschig rings. Correlation of these data with Equation (15) showed that this equation adequately expressed the heat transfer mechanisms in packed beds with motionless gases, especially at hight temperatures.
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  • 17
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    AIChE Journal 3 (1957), S. 381-385 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: Heat and mass transfer and coagulation are considered as related to the mean-square relative velocity between particle and fluid uR2 and eddy diffusion as described by the mean-square particle displacement, Xp2. The mathematical methods used are similar to those employed in the early calculations of the Brownian motion.The mean-square relative velocity is obtained as a function of particle characteristics, intensity of turbulence, and a fluid correlation coefficient. In the limiting case of equal particle and fluid density uR2 = 0, and for very heavy particles uR2 → uF2.A general expression for the eddy diffusivity is obtained is obtained which reduces to the same form as that of the fluid for the stationary state. However, the correlation coefficient to be used in the calculations depends on uR2. As a first approximation, it can be assumed that at a sufficiently long time from the introduction of the particles, fluid and particle diffusivities are equal.For short times after injection, the particle spread may be much less than that of the fluid. An illustrative calculation for the initial spreading of a jet of suspended particles is offered. In all cases an effort is made to organize the available experimental data within the framework of the theory.
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  • 18
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    AIChE Journal 3 (1957), S. 386-390 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: The bulk chemical properties of an impregnated chromia-alumina catalyst with respect to several gases, CO, CO2, C3H6, were determined as a function of the degree of oxidation of the surface of the catalyst. The importance of the results lies in the demonstration that a simple method described herein can be used to obtain significant data on catalytic surfaces. Briefly, the prior adsorption of oxygen by the catalyst tended to promote the adsorption of carbon monoxide and to prohibit the adsorption of carbon dioxide. Far more carbon monoxide was adsorbed by the highly oxidized surface than could be accounted for on the basis of adsorbed carbon dioxide. The quantity of propylene adsorbed also increased with an increase in the oxidation of the surface. The results are explained on the basis of two types of adsorbed oxygen atoms.
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  • 19
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    AIChE Journal 3 (1957), S. 391-394 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: A rigorous method is presented for the evaluation of the heat requirements in binary batch fractionations which involve negligible column hold up. The method, in which the additional variables of the discontinuous process are taken into account, is a modification of the methods of Ponchon and Savarit for continuous operation. Two examples, one for a fractionation in which the composition of the product is constant and the other in which the reflux ratio is constant, are given as illustrations of the method.The application of the method permits more accurate evaluation of reboiler and condenser heat loads and, in turn, better design.
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  • 20
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    AIChE Journal 3 (1957), S. 395-404 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
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  • 21
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    AIChE Journal 3 (1957), S. 411-417 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: In the hydrogenation of α-methylstyrene by means of a suspended palladium-alumina catalyst in a stirred reactor the mass transfer of hydrogen through the liquid is the rate-controlling step and the resistance to chemical reaction at the catalyst surface is negligible except at extremely rapid rates of stirring. This system therefore provides an excellent means of establishing the effects of operating variables and mechanical construction on mass transfer coefficients in liquids in stirred reactors. It is convenient to consider the total resistance to mass transfer as consisting of two separate resistaces: in the liquid adjoining the bubbles and in the liquid adjoining the suspended solid particles; thus R = Rb + Rs.A general equation was evaluated from experimental data based upon unit volume of liquid.
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  • 22
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    AIChE Journal 3 (1957), S. 405-410 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: Local convective thermal transfer is difficult to predict for nonuniform three-dimensional boundary flows. Direct measurements of local transfer from objects of practical interest are therefore useful in the prediction of thermal transfer and in an understanding of multidimensional boundary flows.Measurements of the gross and local transfer were made upon a silver sphere 0.5 in. in diameter and a ceramic porous sphere of the same size from which n-heptane was permitted to evaporate. The air stream had a level of turbulence of approximately 5.4% and only small variation in velocity with position. Temperature distributions in the boundary flows around these spheres were determined, and from these distributions local transfer coefficients were established for the forward hemisphere. The gross transfers were established from the electrical energy added to the silver sphere and from the quantity of n-heptane evaporated from the porous sphere.The local thermal transfers were in reasonable agreement with some of the theoretical analyses based upon a three-dimensional laminar-boundary layer. Satisfactory agreement was obtained between spatial integration of the local transfer and the simultaneously measured over-all values. These, in turn, were in fair agreement with correlated values of the gross thermal and material transfer from spheres.
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  • 23
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    AIChE Journal 3 (1957), S. 418-427 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: The effects of the physical properties and volume flow rate of liquids on the surface area of sprays produced by a pressure type of atomizing nozzle were determined experimentally. the specific surface area of the sprays is correlated by an equation of two dimensionless groups in terms of the variables surface tension to the -1.0 power, kinematic viscosity to the -0.4 power, and volume flow rate to the 2.4 power. The volume flow rate is correlated by an equation of two dimensionless groups containing the variables viscosity to the 0.17 power, density to the -0.58 power, and spray pressure to the 0.42 power. The conversion of compression energy to surface-area energy appears to be constant at approximately 0.1%.
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  • 24
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    AIChE Journal 3 (1957), S. 12S 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
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  • 25
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    AIChE Journal 3 (1957), S. 9S 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
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    AIChE Journal 3 (1957), S. 428 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: Following an approach similar to that presented for the aliphatic (6, 7) and naphthenic (8) hydrocarbons, methyl-group contributions have been developed that now make possible the calculation of van der Waals' constants for aromatic hydrocarbons of considerable size and complexity. These constants are then utilized to calculate the critical temperatures, pressures, and volumes for these aromatic hydrocarbons.In addition, simple relationships have been developed that permit the evaluation of both van der Waals' constants for the unsubstituted linearly fused aromatic hydrocarbons.Comparisons of calculated critical constants with values presented in the literature for over twenty aromatic hydrocarbons produced average absolute deviations of 0.70% for the critical temperature and 2.14% for the critical pressure.
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    AIChE Journal 3 (1957), S. 7S 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
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    AIChE Journal 3 (1957) 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
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    AIChE Journal 3 (1957), S. 431-431 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
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  • 30
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    AIChE Journal 3 (1957), S. 513-516 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: A new solution is presented of the differential equations describing unsteady state heat transfer in stationary beds of small granular solid particles through which a fluid is flowing. Arbitrary initial solid temperature distribution and arbitrary variation of inlet gas temperature are allowed. The solution presented appears easier to apply in practice than those previously published and affords an example of the versatility of Fourier integrals and series. An application of the solution to the regeneration of Dow type-B butylene dehydrogenation catalyst is described.
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    AIChE Journal 3 (1957), S. 517-522 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: Vapor-liquid equilibria of the systems n-octane-Cellosolve, ethylbenzene-Cellosolve, and n-octane-ethylbenzene-Cellosolve were determined at 760 mm. Hg. The activity coefficient data of Yang and Van Winkle (23) for the system n-octane-ethylbenzene and the data of this work on other systems were expressed by Wohl's three-suffix Margules equations. The ternary data are predicted satisfactorily from the binary constants and no noticeable ternary effects seem to exist for this ternary system.
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    AIChE Journal 3 (1957), S. 523-527 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: By experimental means a relation is obtained between the thermal resistance of an eddy and its angular momentum. The eddy is stationary, and no extraneous motion is present. The secondary motion which may develop in the annulus between concentric rotating cylinders is used to obtain the eddies. The fluid motion is well defined at all times and at all points of space. Heat is passed through the eddies, and the Nusselt number is obtained, which varies linearly with the angular momentum. Both Nusselt number and angular momentum vary linearly with the peripheral velocity of the inner rotating cylinder, which can be interpreted in terms of a Reynolds number associated with fluid flow perpendicular to a cylinder.
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    AIChE Journal 3 (1957), S. 11-15 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
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    Notes: Experimental studies of the mixing of coaxial streams of a natural gas and air at atmospheric pressure were made at Reynolds numbers of 44,000 and 79,000 under conditions where the turbulent-velocity profile of nearly uniform flow was altered as little as feasible by the blending of the two streams.Total diffusivities of natural gas in air for the region near the center of the conduit were computed from the data for turbulent, steady, nonuniform flow. The total diffusivities were found to be rather complicated functions of the conditions of flow. Limitations in the configuration of the apparatus did not permit a study of the behavior of the total diffusivities to be made over as wide a range of flow rates as would be necessary to investigate the large-scale trends indicated by this study.
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    AIChE Journal 3 (1957), S. 29-32 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
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    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: A phase-behavior approach to the prediction of the performance characteristics of a dissolved-gas-drive reservoir is unique in that the problem of choosing flash, differential, or composite-solution gas-oil ratios and formation-volume factors has been circumvented. Data required are a compositional analysis of the reservoir fluid, the bubble point of this fluid, and the relative-permeability curves for the reservoir rock.Gas-oil ratios and formation-volume factors were calculated under conditions duplicating the performance of the reservoir. A comparison was then made between these results and those obtained by calculations involving a differential, a flash, and a composite process. A vital factor in the solution of the problem is the accuracy of the calculated equilibrium constant. Agreement within 3% was obtained when a calculated differential formation-volume curve was compared with an experimentally determined curve.
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    AIChE Journal 3 (1957), S. 16-28 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: One of the important factors affecting the efficiency of vapor-liquid contacting operations is the relationship between available interfacial area and contact time.Because of the difficulties in measuring these quantities, little information has heretofore been made available on them. Previous studies have been confined to extreme over-simplifications of the turbulent type of contacting taking place in fractionation devices. The present investigation consisted of the determination of interfacial area and contact time for the formation of air bubbles submerged in water and aqueous solutions. The bubbles were produced at single vertical slots and rose through a flowing liquid. In order to complete the study on physical contacting, a companion study is concerned with vapor-liquid behavior in the forth and entrainment zones. The experimental technique in this study involved taking high-speed motion pictures of the bubbling action. Measurements of the area and volume of bubbles were made at intervals during the course of their growth, and values of total contact time and average interfacial area per unit volume of vapor are presented.It was found that both the average interfacial area per unit volume of vapor a and the total contact time tm were primarily affected by the head of flowing liquid on the slot. Below slot submergence of approximately 2.5 in. of liquid, interfacial area was shown to decrease with increasing slot submergence and increasing slot area. Above 2.5 in. of liquid, interfacial area was a function of skirt clearance, liquid viscosity, and surface tension.Total contact time was found to increase with increasing slot submergence and to decrease with increasing vapor rate and skirt clearance.Through the use of an integrated mass transfer-rate equation, the terms a and tm can be used in conjunction with the appropriate mass transfer coefficient for predicting the point efficiencies on bubble-cap plates.
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    AIChE Journal 3 (1957), S. 33-36 
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    Notes: Experimental equilibrium vapor and liquid compositions are reported for the hydrogen-methane system at -150°, -200°, and -250°F. and at pressures of 500 to 4,000 lb./sq. in. The ternary system hydrogen-methane-propane was studied at 0°, -100°, and -200°F. at 500 and 1,000 lb./sq. in. Phase compositions were determined for a limited number of similar conditions for the hydrogen-methane-propylene and hydrogen-methane-ethylene-ethane-propylene-propane systems.
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    AIChE Journal 3 (1957), S. 37-42 
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    Keywords: Chemistry ; Chemical Engineering
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    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: Data are reported for the evaporation of spheres of naphthalene into air, helium, carbon dioxide, and Freon-12, and of liquid diethyl adipate into air at pressures from 0.1 to 3,000μ Hg and at Reynolds numbers from 0 to 1.37. By use of suitable values of the surface-evaporation coefficient and the assumption of additivity of surface evaporation and diffusional resistances, the data are well correlated. The results lend semiquantitative support to the theory of sublimation of crystals developed by Stranski.
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    AIChE Journal 3 (1957), S. 43-48 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
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    Notes: Rates of mass and heat transfer to single spheres and cylinders at low Reynolds numbers are predicted from boundary-layer theory. The velocity distributions which are assumed to exist are those derived from the linearized Navier-Stokes equations by Tomotika and Aoi.In the case of the sphere the Nusselt number is found to be a function only of the Peclet group when the Stokes streamline function is assumed to apply. Experimental data for mass and heat transfer to singel spheres fall 10 to 40% higher than predicted from the theory. Experimental data for heat and mass transfer to single cylinders at large NPe check the theory.Curves are also plotted for the efficiency of removal of colloidal particles by combined direct interception and diffusion for both spheres and cylinders.
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    AIChE Journal 3 (1957), S. 56-62 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
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    Notes: Liquid extractions of benzoic acid-toluene solutions by means of water were studied under varying flow rates of both solvents in a 2-in. perforated-plate column to which pulsations of different frequencies and amplitudes were applied. Studies on reversal of the phase of the dispersion were made. With fixed flow rates of both solvents, the rate of extraction increased much more rapidly when the flow through the perforation became turbulent. The results are correlated by means of Reynolds number based on the flow through the perforations and are calculated from the product of the frequency and amplitude of the pulsations.
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    AIChE Journal 3 (1957), S. 101-110 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
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    Notes: This paper describes further research on a 4-in. I.D. by 8-ft. spray tower of Elgin design. Previous work concerned limiting flow and holdup in this tower. Owing to its high capacity and low cost, the spray tower would have much greater commercial application in liquid-liquid extraction if its conditions of transient operation could be predicted and if it could be operated to yield low Ht values. This research attempts to show that transient conditions can be predicted and that low Ht values for both mass and heat transfer can be realized near the limiting flow conditions.Theroretical equations for rate of approach to steady state derived and tested for the systems ethylene dichloride-water-propionic acid and ethylene dichloride-water-acetic acid show that the approach depends on the ratio of the phase flow rates. This study is important for the prediction of start-up time for industrial towers.With the same systems the extraction capacity of the spray tower was investigated up to the condition of rejection. The results were correlated as KEa and Ht, OE vs. a function of the ratio of the phase flow rates. The dispersed-phase flow rate was found to have primary significance.The heat transfer rates between water as continuous phase and solvents of various denisties were correlated as Ht′ values plotted against a function of the ratio of the phase flow rates. The advantages of operation near rejection were demonstrated, and the effect of direction of heat transfer was found to be significant.
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    AIChE Journal 3 (1957), S. 293-296 
    ISSN: 0001-1541
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    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: Data are presented in support of an expression describing the relation between the sedimenting velocity or the fluidizing velocity and the fraction voids. This expression which contains no empirical constants may be obtained by considering a particle in a fluid having the average properties of the suspension. Stokes's law is used to calculate the force on the particle, and an equation derived by Vand is used to describe the viscosity of the suspension. The equation based on this model is valid for particle Reynolds numbers less than 0.07. The model may be used as an approximation of bed behavior at higher Reynolds numbers by application of a correction to Stokes's law.
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    AIChE Journal 3 (1957), S. 8J 
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    AIChE Journal 3 (1957) 
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    AIChE Journal 3 (1957), S. 297-297 
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    AIChE Journal 3 (1957), S. 321-324 
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    Keywords: Chemistry ; Chemical Engineering
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    AIChE Journal 3 (1957), S. 433-438 
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    Keywords: Chemistry ; Chemical Engineering
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    Notes: This paper proposes a theory of filter-cake washing on continous filtration equipment based upon the assumption that mixing of the strong liquor and wash fluid is controlling. The theory can be conventiently applied to experimental filtration leaf tests for determining wash efficiency and is easily extrapolated to full-scale results with the normally experienced uneven cake thickness and wash-fluid distribution taken into account.To obtain the necessary wash-fluid volume for proper soluble removal, a correlation method of wash time as a function of wash ratio with parameters of cake-formation time has been derived from commonly accepted filtration theory. Experimental and plant data indicate a close agreement with the theory, and the method can be employed to predict filtration rate as a function of wash ratio. A typical illustration has been given to determine filtration requirements for recovering soluble uranium after leaching of the ore by continuous filtration. Washing rate was proved to be conrolling, and this design based only on cake-formation rate would yield insufficient wash ratios and excessive soluble uranium loss. Final filter and flow-sheet design must be based on uranium recovery which can be predicted by the proposed methods.
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    AIChE Journal 3 (1957), S. 454-461 
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    Keywords: Chemistry ; Chemical Engineering
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    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: The fragmentary thermal-conductivity data for argon available in the literature have been correlated by use of a residual thermal conductivity k - k* vs. density ρ relationship. This correlation produced a unique continuous curve which was found to be singularly independent of temperature and pressure for both gaseous- and liquid-state data. From low-pressure thermal-conductivity values k* and the relationship given above, it is possible to determine thermal conductivities at any condition of temperature and pressure for which a corresponding density is available. This procedure was used to calculate reliable thermal conductivities k for high-pressure regions where experimental data were lacking.In a similar manner the critical thermal conductivity kc for argon was established directly from the critical density and the quantity kTc*. The kc value permitted the calculation of reduced thermal conductivities kR and made possible the construction of an extensive reduced-state chart. Although this correlation was developed mainly from data for argon, it was found to apply equally as well to the other inert gases as postulated from the theory of corresponding states.A comparison of thermal conductivities calculated from the reduced-state plot with over 200 experimental points produced an average deviation of 1.8% for all the inert gases. This chart was also found applicable to the diatomic gases and their mixtures but produced significant deviations for substances having more than two atoms per molecule.
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    AIChE Journal 3 (1957), S. 467-472 
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    Keywords: Chemistry ; Chemical Engineering
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    Notes: Previous papers have reported equilibrium data for the binary systems cyclohexaneheptane, heptane-toluene, and cyclohexane-toluene. This present study gives similar data for the ternary system cyclohexane-heptane-toluene and compares the activity coefficients with those predicted from the three limiting binaries.The ternary activity coefficients fall well in line between the limiting-binary data. Distribution is about as would be predicted by the ternary Margules equations. As an approximation, if the coefficients are plotted as a function of the aromatic concentration only, without consideration of the ratio of naphthenes to paraffins, reasonably good correlation is observed.
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    AIChE Journal 3 (1957), S. 473-479 
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    Notes: A new method is proposed for the calculation of the heat of vaporization of hydroxylated compounds to an accuracy of about ±0.5 kcal./mole from no more data than the molecular structure and a boiling point. The older methods, by comparison, achieved an accuracy of about ±1 kcal./mole with a far greater computational effort, since they required the (usually hypothetical) critical temperature and critical pressure in addition to a boiling point.The method is here applied to aliphatic and aromatic alcohols, to ether-alcohols (e.g., the cellosolves), and to alcohols conaining keto or aldehyde groups (e.g., salicylaldehyde) and supersedes previous correlations covering the heats of vaporization of these compounds. The method can also be used to assess the quality of vapor-pressure data of the compounds covered by it.The method is based on the assumption that the heat of vaporization consists of two terms, the dispersion energy and the hydrogen-bond increment (close but not equal to the hydrogen-bond strength). The first term is calculated from a knowledge of the heat of vaporization of the equistructural hydrocarbon, now easily available from the Tables of A.P.I. Research Project 44. The hydrogen-bond term is calculated from a set of rules given in the report.The application of the increment method of this report to other properties and other functional groups is the subject of a continuing investigation.
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    AIChE Journal 3 (1957), S. 535-538 
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    Keywords: Chemistry ; Chemical Engineering
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    Notes: The problem of diffusion in a moving medium with given motion of the boundaries is considered. The method presented yields the analytical solution to any desired degree of accuracy provided that solutions for certain associated problems of diffusion in a medium at rest with boundaries at rest are known. The method is applied to the analysis of partial and approximate solutions previously presented for the one-dimensional case of a spherical cavity in a liquid with radial boundary motion induced by evaporation.
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    AIChE Journal 3 (1957), S. 528-534 
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    Notes: Flow equations have been proposed for hydroextractor cakes wherein the pores are filled with moving liquid. These equations have been confirmed for the effect of each variable by use of different experimental techniques. The critical wetting rate has provided the most informative steady state, in which the cake is fed with liquid to maintain the inner surface of the liquid at radius rL coincident with that of the cake at radius rc. Transient techniques have also been used wither with a probe to time the movement of a liquid level between two radii less than rc, or with a photoelectric detector to observe the coincidence of rL = rc. The tests have proved the validity of the hydrodynamic assumptions involved in the equations and have provided both precise methods for research and practical methods for industrial purposes.
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    AIChE Journal 3 (1957), S. 9D-9D 
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    AIChE Journal 3 (1957), S. 10D-11D 
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    AIChE Journal 3 (1957), S. 11D-11D 
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    AIChE Journal 3 (1957), S. 12D-12D 
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    AIChE Journal 3 (1957), S. 69-74 
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    Notes: Carbon tetrachloride was evaporated into a stream of air over ranges of gas concentration from 0 to 0.70 mole fraction carbon tetrachloride, Reynolds number from 600 to 15,000, and Schmidt number from 0.23 to 1.17. The data were correlated by an equation and also by a computer solution to the differential equation describing mass transfer from values of eddy viscosity and eddy diffusivity obtained from the literature.
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    AIChE Journal 3 (1957), S. 92-100 
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    Notes: This paper presents the first theoretical analyses combined with an experimental study of the variables controlling heat transfer rates to non-Newtonian fluids in the streamline-flow region. The theoretical analyses, for the limiting types of non-Newtonian materials, were related to the intermediate case of Newtonian behavior to form a coherent theory applicable to Newtonian and non-Newtonian fluids alike.The experimental data covered Graetz numbers between 100 and 2,000 and were correlated with a mean deviation of 13.5%. The flow-behavior indexes of the three non-Newtonian fluids used varied form 0.18 to 0.70.Some preliminary non-Newtonian results are presented on the problems of nonisothermal fluid-flow pressure losses and heat transfer outside the laminar-flow region. Further theoretical work is recommended in both these areas. Additional experimental data would be of value in all of the problems discussed.
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    AIChE Journal 3 (1957), S. 83-91 
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    Notes: Measurements are reported on axial mixing of binary gas mixtures at room temperature and atmospheric pressure in a random bed of spherical particles. By means of the Fick's Law equation for diffusion an axial Peclet number, dp U/Ez (where dp is particle diameter, U is interstitial velocity, and Ez is axial eddy diffusivity), was computed in terms of the ratio of the amplitudes of a sinusoidal concentration wave at the inlet and outlet of the bed. An experimental method was devised to eliminate end effects in the system. For the gas systems H2—N2 and C2H4—N2 and for Reynolds numbers between 100 and 400 the mean of twenty-one determinations of axial Peclet number was 1.88 ± 0.15. This value is in excellent agreement with a value of 2.0 predicted theoretically on the assumption that the bed acts as a series of n perfect mixers, where n is the number of particles traversed between inlet and outlet.Axial diffusivity for turbulent flow of gases among particles is about sixfold larger than radial diffusivity, previously determined. It is suggested that axial diffusivity may not, perhaps, be neglected in contacting devices, such as adsorbers and catalytic reactors.
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    AIChE Journal 3 (1957), S. 117-120 
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    AIChE Journal 3 (1957), S. 111-116 
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    Notes: The viscosity of a suspension is related to the properties of the suspending liquid and the suspended particles by measuring the viscosity of suspensions made up of closely sized materials such as glass spheres, plastic Zeolite spheres, blasting sand, and salt cubes in a wide range of concentrations in liquids of varying properties made up of castor oil, tetrabromoethane and carbon tetrachloride, or corn syrup and water. The measurements were made under carefully controlled conditions by means of a Brookfield viscometer, and the reproducibility of results was demonstrated by repetitive runs.Equations are derived to describe the viscosities of these various suspensions in terms of the viscosity and density of the suspending liquid and of the shape, size distribution, density, and concentration of solid particles. The range of concentration covered is from infinite dilution to near infinite viscosity.The results obtained can best be explained by postulating nonuniform distribution of particles in a suspension in a network of tetrahedral and simple cubical packings.
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    AIChE Journal 3 (1957), S. 121-126 
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    Notes: Values of thermal conductivity and temperature coefficients for thirty-five pure organic liquids, in addition to those previously reported, obtained with a previously described apparatus (Part I), are presented. Values of thermal conductivity or temperature coefficients for twenty-eight of these liquids have not been reported before. The experimentally determined maximum error is ±1.0%.The two methods for predicting the thermal conductivity of liquids previously proposed (Parts I and II) are extended to cover the types of compounds studied in this investigation, in particular ring compounds.The temperature coefficient of thermal conductivity was observed to decrease rapidly, approaching zero as the freezing point is approached. The existence of a transition temperature or region within the liquid state is shown and identified with the onset of molecular rotation.
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    AIChE Journal 3 (1957), S. 143 
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    AIChE Journal 3 (1957), S. 127-136 
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    Keywords: Chemistry ; Chemical Engineering
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    Notes: Mass and heat transfer rates in extraction are studied theoretically and experimentally for the practical range of the variables involved. For the particular but typical case of liquid drops moving through another liquid a simple correlation for the over-all mass transfer coefficient is presented, which holds with a probable error of 20%.Included are systems in which the rate is limited by either coefficient, as well as systems in which both coefficients are significant. The correlation, valid for both directions of transfer with either phase dispersed, is useful for the extrapolation of performance from system to system in a given piece of equipment. Also, together with correlations for transfer area and effective driving force, it is part of the information needed for design.
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    AIChE Journal 3 (1957), S. 144 
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    Keywords: Chemistry ; Chemical Engineering
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    AIChE Journal 3 (1957), S. 144 
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    AIChE Journal 3 (1957), S. 136-142 
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    Keywords: Chemistry ; Chemical Engineering
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    Notes: The pressure-drop characteristics associated with one liquid and one gaseous phase flowing concurrently in a pipe or tube have yet to be understood. The operation of evaporators, boilers, and condensers has long stimulated interest in the pressure drop of steamwater mixtures, and more recently this specialized case of one-component, two-phase flow has received even greater attention from the applications in cooling nuclear reactors. The two-phase-flow problems have not been amenable to through theoretical analyses, and therefore empirical and semiempirical correlations have attained unusual prominence in practical applications. The present investigation employs a new research tool for the study of two-phase-flow structure.A variety of geometric flow patterns is possible. Bergelin, Alves, and others have classified these patterns according to visual appearance; whereas the Martinelli classifications were based upon whether the flow in each phase was termed viscous or turbulent. The distinction between viscous and turbulent flow in either phase is rather arbitrary, and if the Reynolds number for one phase, calculated on the basis of the total tube diameter, is greater than 2,000, the flow in the phase is called turbulent. This investigation is confined to the study of annular flow, in which most of the liquid is found in an annular ring surrounding the central vapor core and the flow in each phase is turbulent.Boiling or flashing occurs when superheated water rises in an insulated vertical tube at atmospheric pressure. For a separated two-phase flow geometry, the mean linear steam velocity may exceed that of the water. The fraction of the tube occupied by the steam (void fraction) at a given cross section cannot be obtained directly from a determination of the thermodynamic quality. Void fractions, however, must be known for the estimation of the pressure drops due to head and momentum changes.Void fractions and pressure drops for steam-water flows were measured in an 0.872-in. I.D. vertical tube at atmospheric pressure over a quality range of 0 to 4%. The test section was the hot leg of a natural-circulation loop, and the inlet liquid flow rate ranged from 1 to 3 ft./sec. A new technique for measuring void fractions was used, and the method utilizes the difference between the gamma-ray absorption coefficients of water and steam.
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    AIChE Journal 3 (1957), S. 10M 
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    AIChE Journal 3 (1957) 
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    AIChE Journal 3 (1957), S. 145-145 
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    AIChE Journal 3 (1957), S. 153-156 
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    Keywords: Chemistry ; Chemical Engineering
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    AIChE Journal 3 (1957), S. 147-152 
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    Notes: Experimental data are presented for the heats of mixing of liquids at 25°C. and 1 atm. pressure for ten binary and five ternary systems. For nonpolar binary systems a two-constant equation has been developed which correlates the data within experimental accuracy. Several equations which have been proposed for the calculation of ternary heats of mixing from binary data are tested for the systems studied. The method of Jost and Röck (4) for determining the constants in power-series functions from experimental data is considered.
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    AIChE Journal 3 (1957), S. 157-161 
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    Notes: To test the applicability, over a wide range of temperatures, pressures, and gas physical properties, of the mass transfer correlation presented earlier, 0.5-in. naphthalene Berl saddles were vaporized into air, carbon dioxide, and Freon-12 in a 4.0-in. column. Temperatures from 15° to 73°C. and pressures from 0.26 to 1 atm. were covered.The correlation was found to represent all the experimental data when the surface temperature of the naphthalene was used to evaluate the correct driving force.This correlation, when combined with effective interfacial areas presented previously, makes it possible to estimate the volumetric mass transfer coefficeint, kGa, for any gas-liquid-solute system.
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    AIChE Journal 3 (1957), S. 161-164 
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    Notes: The densities of acetone-water liquid solutions have been measured over the entire composition range from 20°C. to within 3° to 7°C. of the normal boiling point of the mixture. The density was measured with a Robertson pycnometer (13), which was modified slightly. The density values are thought to be accurate to within ±0.00005 density units. The technique for determining density values of the volatile mixture near the boiling temperature is given in some detail. The refractive index (nD25) of pure acetone has been redetermined and equals 1.35596 ± 0.00003.
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    AIChE Journal 3 (1957), S. 165-171 
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    Notes: New absorption- and stripping-factor functions have been developed for use in computing multicomponent separations in fractionators, reboiled absorbers, refluxed strippers, and columns with side-stream strippers. Charts of fraction not absorbed vs. A factor and fraction not stripped vs. S factor are included with the equations for these operations.These functions and procedures are of particular advantage in computing complex columns, i.e., two or more feeds and three or more products, where the proposed A and S factor equations provide a method for converging on a solution.
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    AIChE Journal 3 (1957), S. 172-175 
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    Notes: The general problem of heat transfer to fluids in laminar flow in tubes is discussed, a new procedure for the measurement of local laminar-flow heat transfer coefficients is described, and an empirical equation is presented for the correlation of data for local heat transfer rates to liquids flowing upward in laminar flow in vertical tubes under conditions of constant heat flux at the tube wall.
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    AIChE Journal 3 (1957), S. 187-190 
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    Notes: Equilibrium isotherms are presented for the cation exchange of copper and sodium on Dowex-50 resin in solutions from 0.01 to 4N in chloride content, and the equilibrium data are correlated on the basis of the Donnan equilibrium. Data are also given on the water content of the resin and the diffusible ions present in this water.
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    AIChE Journal 3 (1957), S. 180-182 
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    Notes: Concentration relations between foams and their residual liquids (frothates) have been examined.Clean air streams of 88, 91, and 96% water saturation were bubbled into aqueous solutions of isobutyl alcohol. The concentration of the alcohol in the collected and collapsed foam was plotted against its concentration in the bulk liquid.Varying the saturation of the air stream resulted in both positive and negative enrichment of the foam with the surface-active alcohol. This suggests that where froth-frothate-concentration relations are unfavorable, a change in operating conditions may advantageously affect these relations and allow the mixture to be foam separated.
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    AIChE Journal 3 (1957), S. 183-186 
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    Notes: Ion exclusion is an operation in which an ion exchange resin is used to separate an electrolyte from a nonelectrolyte in a polar solvent. An ion exchange resin tends to absorb a nonelectrolyte and to exclude an electrolyte. This is described quantitatively by the equilibrium distribution of the electrolyte, the nonelectrolyte, and the solvent between the resin phase and the liquid phase surrounding the resin.As no ternary distribution data applicable to ion exclusion are available, and only a few binary data have been published, a principal purpose of this investigation was to determine the distribution data for a typical system: glycerol-sodium chloride-water-Dowex-50.
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    AIChE Journal 3 (1957), S. 176-180 
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    Notes: The dynamics of agitating single- and two-phase liquid mixtures in the absence of an air-liquid interface was compared with that of similar systems with an interface. Two geometrically similar cylindrical vessels, 12 and 18 in. in diameter respectively, were used, each fitted with a similar six-bladed, disk-turbine impeller.New general correlation curves of power number with Reynolds number are presented which show that elimination of the air-liquid interface makes it possible to attain dynamic similarity in scale-up in unbaffled vessels but makes little difference in baffled vessels.
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    AIChE Journal 3 (1957), S. 191-197 
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    Notes: Vapor-liquid equilibria of two binary systems, benzene-n-hexane and benzene-cyclohexane, were measured at pressures from 4 to 18 atm. The three-constant Redlich-Kister equation was found satisfactory for correlation.With the benzene-n-hexane system no azeotrope occurred; with the benzene-cyclohexane system an azeotrope appeared, and the mole fraction of cyclohexane in it diminished with increase in pressure. Lack of correction for fugacity in the vapor phase introduced a maximum error of 4% in activity coefficients at highest pressure.
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    AIChE Journal 3 (1957), S. 223-229 
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    Notes: A radioisotope technique has been utilized to study the point holdup of the dispersed phase and some operational flow characteristics in a packed countercurrent liquid-liquid extraction tower. The system used was toluene-water and the packing was Raschig rings. The toluene dispersed phase was tagged with gamma-radiating iodine-131.The study revealed that holdup experiences a hysteresis cycle with variations of the continuous-phase flow rate. Correlating equations are presented for “total” and permanent holdup, below loading, to account for this hysteresis. Entrance effects and flow maldistribution effects are readily determined by the method utilized. Displacement studies demonstrated that no simple “operational” dispersed-phase flow holdup exists, but rather a complex dispersed-phase movement, which involves all the “nonhysteresis” permanent holdup.
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    AIChE Journal 3 (1957), S. 236-241 
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    Notes: The decreasing solubility of hydrogen in hydrocarbons with decreasing temperature continues down to the freezing point of the hydrocarbons, around -300°F. This behavior is shown to be an enlargement of phenomena exhibited by normal hydrocarbon mixtures. Methods of predicting equilibrium-phase compositions are presented for hydrogen in ligh-hydrocarbon systems. The correlations are satisfactory for binary and certain ternary systems, but are not reliable for complex mixtures.
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    AIChE Journal 3 (1957), S. 262-267 
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    Notes: In spite of the importance of hydrogenation procesing operations in the refining of petroleum there are only limited experimental volumetric and phase equilibrium data concerning mixtures of hydrocarbons and hydrogen. An investigation of the volumetiric and phase behavior of the hydrogen-n-hexane system was therefore undertaken.The experimental study involved measurements of the specific volume of four mixtures of hydrogen and n-hexane at eight temperatures between 40° and 460°F. for pressures up to 10,000 lb./sq. in In addition, the composition of the gas phase in heterogeneous mixtures was determined at six temperatures within the interval mentioned above for pressures as high as 10,000 lb./sq. in.Little about this system was found to be qualitatively unusual except that the critical pressure exceeded 10,000 lb/sq. in. at all temperatures below 340°F. As would be expected, the dew-point gas was rather lean in n-hexane for temperatures below 220°F. and at pressures above 100 times the vapor pressure of n-hexane throughout the pressure range covered by this study.
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    AIChE Journal 3 (1957), S. 268-275 
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    Notes: Values of total pressure drop are presented for the flow of vaporizing water in an internally heated 1-in. I.D. by 1½-in. O.D. annulus at mass velocities of 270 to 1,440, lb./(sec.)(sq.ft.), pressures of 9 to 180 lb./sq. in., and up to 0.34 fraction by weight vaporized. The total heated length over which boiling took place was as large as 6 ft. There is no evidence of “sonic” pressure jumps at the outlet. The results for the annulus mentioned lie within +30 to -11% of the Lockhart-Martinelli curve at higher qualities and with ±45% of the correlation at lower qualities where the actual quality is more uncertain. A simplified correlation in terms of quality and volume fraction of liquid predicted the two-phase frictional pressure drops with an average error of 41%.It was found that the ratio of the two-phase pressure drop through a 0.3-in. orifice to the drop with no vaporization was approximately a linear function of the quality in the vena contracta but was only one tenth to one third as great as would be predicted if the mixture were to expand as a homogeneous fluid. Prediction of orifice presure drops is improved if slip between vapor and liquid is considered.
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    AIChE Journal 3 (1957), S. 276-279 
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    Notes: On the assumption of laminar Newtonian flow, flow profiles are developed for both the vertical plate and cylindrical column by use of classical equations. From the flow profiles the mass transport, vertical pressure gradient, and optimal design parameters are calculated. With the Reynolds-number criterion used to ascertain the maximum nonturbulent velocity, minimal values for the plate distance and column radius can be calculated. An example is included for each case.
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    AIChE Journal 3 (1957), S. 280-282 
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    Notes: It has been shown both theoretically and experimentally that the radial Peclet number in a packed bed approaches about 11. If it is assumed that the interstitial volume of the bed forms mixing cells, then a comparison of the solutions obtained from the mixing and turbulent diffusive mechanisms shows that the axial Peclet number for agreement of the two must be about 2, as a limiting case for high Reynolds numbers. This is substantiated by experiment.
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    AIChE Journal 3 (1957), S. 283-286 
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    Notes: Mass transfer coefficients have been determined for the dissolution of Na2S2O3·5H2O crystals in water under conditions of turbulent agitation in a mixing vessel. The dissolution was carried out in a steady-flow process in which the area of selt crystals and the concentration of the solution in the mixing vessel were constant during each run. A comparison is made with previously unpublished results for batch runs in a similar system, and a method is developed for calculating the surface area of salt particles suspended in the mixing vessel under steady-flow conditions.
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    AIChE Journal 3 (1957), S. 289-293 
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    Keywords: Chemistry ; Chemical Engineering
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    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: Approximations are suggested to extend the usefulness of operational calculus in solving boundary-value problems of interest to the chemical engineer. General approximations are outlined and specific ones illustrated. The use of computing machines with operational calculus is also considered.
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    Notes: The separation of 4.5 g. of americium from approximately a kilogram of light rare earths (primarily lanthanum) was achieved on a pilot plant scale by chromatographic displacement of the mixture from Dowex-50 resin with 0.1% ammonium citrate at pH 8 into hydrogen-form Dowex-50. The americium collected into a narrow band and was eluted free from lanthanum but contained an equal weight of cerium. A 6- and a 2-in.-diam. column were used in tandem. Use of a final column with a much smaller diameter would have permitted a cleaner separation from cerium, but this was left for a laboratory-scale separation by a different process. Precipitation, which was observed in the columns during the first runs, was later avoided entriely by use of high flow rates both initially and during the transfer between columns. No adverse effects were noted from ∼15 curies of alpha activity.
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    AIChE Journal 3 (1957), S. 305-312 
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    Notes: The design variables that affect the pressure drop across dry perforated plates were determined and correlated. Average orifice coefficients were calculated for the perforated plates by using a modified form of the single-orifice flow equation.The variables which affected the orifice coefficients were found to be the hole diameter, hole pitch, plate thickness, fraction of the plate covered by the perforated area, and a Reynolds number based on the hole diameter. The orifice coefficients have been correlated with these variables in dimensionless groupings.The correlation presented covers a practicable range of variables for which the pressure drop may be predicted in design.
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    AIChE Journal 3 (1957), S. 299-304 
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    Notes: The interaction between a turbulent air stream and a water film flowing parallel to it was studied. The variables explored were the liquid flow rate, the gas flow rate, and the film height. The data were correlated in terms of a liquid and a gas Reynolds number. Thinner films or films having a lower Reynolds number were more stable. For the experiments reported in this research the transition from a smooth surface to a surface possessing two-dimensional waves occurs at hUτρliquid/µliquid of about 520. Transition from two-dimensional waves to a “pebbled” surface occurs at a value of this parameter of about 600. Theories presented in the literature for the initiation of waves on a liquid surface do not adequately describe the experimental results.
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    AIChE Journal 3 (1957), S. 313-317 
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    Notes: A simple expression for estimating the turbulent forced-convection heat transfer performance of liquid metals flowing through noncircular ducts is presented. This equation requires the knowledge of the slug Nusselt number evaluated for the specific geometry and for the pertinent boundary conditions. Such Nusselt values are presented herein for a number of technically important geometries. One check on the heat transfer prediction given by Equation (4) is in the case of an annular duct with constant heat flow through the outer wall with the inner wall insulated, for which experimental data exist. The prediction agrees within 20% with the experimental data.Several possible boundary conditions that may exist in noncircular cross sections are throughly discussed, and it is hoped that as a result this paper may serve to clarify some of the confusion existing in the literature.
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    AIChE Journal 3 (1957), S. 318-320 
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    Notes: This paper presentes a correlation to predict the equilibrium ratios of hydrogen in hydrocarbon mixtures by use of the parameters of pressure and convergence pressure. Also a procedure to predict convergence pressures of hydrogen-containing mixtures was developed from a correlation of critical loci. With the predicted convergence pressure the measured values of hydrogen equilibrium ratios in binary hydrogen-paraffin mixtures were predicted with a statistical deviation of 8.1% for 237 measurements. Including hydrogen-olefin and multicomponent mixtures of hydrogen, paraffins, and olefins, the statistical deviation was found to be 11.3% for a total of 375 comparisons with measured values of hydrogen equilibrium ratios.
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    AIChE Journal 3 (1957), S. 439-442 
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    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: The problem of axial mixing in straight pipes is analyzed by a modification of G. I. Taylor's analysis. The treatment presented here includes the effect of both Schmidt and Reynolds numbers throughout the turbulent-flow range. All applicable data on flow of gases and liquids are found to confirm the validity of the method.The analysis indicates that axial mixing increases rapidly as the flow approaches the laminar region, especially for liquids, and that pipe roughness causes a relatively small increase in axial mixing. Turbulent eddy diffusion in the axial direction has a negligible effect.The results of the analysis are applicable to those systems wherein the kinematic viscosity of the flowing mixture does not vary greatly from one region to another and in which the concentration region of interest is spread out along a sufficient length of pipe. These limitations are broad enough to permit most practical problems to be treated by the method.
    Additional Material: 2 Ill.
    Type of Medium: Electronic Resource
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  • 98
    Electronic Resource
    Electronic Resource
    Hoboken, NJ : Wiley-Blackwell
    AIChE Journal 3 (1957), S. 443-448 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: A method is presented for the analysis of a reaction between a porous solid and a gaseous reactant where the kinetic expression is linear in the concentration and where appreciable concentration gradients are established in the pore system as a result of diffusive transport rate. Two cases are treated mathematically: a single cylindrical pore initially of uniform diameter and a porous solid initially containing uniform cylindrical pores with random intersections. The mathematical solutions to the latter case are used to interpret the experimental results reported in the literature on the gasification of graphite rods with carbon dioxide. Values of the computed effective diffusivity are an order of magnitude smaller than the bulk diffusivity at the same temperature and pressure.
    Additional Material: 11 Ill.
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  • 99
    Electronic Resource
    Electronic Resource
    Hoboken, NJ : Wiley-Blackwell
    AIChE Journal 3 (1957), S. 449-453 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: The production and refining of petroleum involve many processes in which conditions deviate markedly from equilibrium. For prediction of the behavior of such nonequilibrium systems, information concerning the molecular-transport characteristics of the paraffin hydrocarbons is of practical interest.Fick diffusion coefficients for methane were measured in the liquid phase of the methane-n-heptane system at temperatures between 40° and 340°F. at pressures up to 3,500 lb./sq. in., but the pressure range was limited at the higher temperatures by approach to the critical state of this binary system.The measurements obtained confirmed the fact that the Fick diffusion coefficients for methane decrease with an increase in the concentration of this component and increase rapidly with an increase in temperature for a constant composition. These data together with similar information for other binary paraffin hydrocarbon systems indicate that the Fick diffusion coefficients for methane decrease with an increase in the molecular weight of the less volatile component.
    Additional Material: 6 Ill.
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  • 100
    Electronic Resource
    Electronic Resource
    Hoboken, NJ : Wiley-Blackwell
    AIChE Journal 3 (1957), S. 462-466 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: A kinetic study of the catalytic vapor-phase hydrogenation of three aldehydes (acetaldehyde, propionaldehyde, and n-butyraldehyde) was made at low conversions with a commercial supported nickel catalyst. A simple initial rate equation was determined and found to agree with a mechanism suggested by the ideal kinetics of Hougen and known experimental evidence. By means of this equation the relative reactivities of the aldehydes were compared and found to agree with the predictions of organic theory. An improved reactor designed to ensure isothermal operation is described.
    Additional Material: 2 Ill.
    Type of Medium: Electronic Resource
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