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  • 03. Hydrosphere::03.04. Chemical and biological::03.04.03. Chemistry of waters  (6)
  • Mount Etna  (6)
  • Elsevier  (11)
  • Essen : Verl. Glückauf
  • Krefeld : Geologischer Dienst Nordhein-Westfalen
  • 2005-2009  (11)
  • 2005  (11)
Collection
Publisher
Years
  • 2005-2009  (11)
Year
  • 1
    Publication Date: 2021-06-25
    Description: We report in this paper a systematic investigation of the chemical and isotopic composition of groundwaters flowing in the volcanic aquifer of Mt. Vesuvius during its current phase of dormancy, including the first data on dissolved helium isotope composition and tritium content. The relevant results on dissolved He and C presented in this paper reveal that an extensive interaction between rising magmatic volatiles and groundwaters currently takes place at Vesuvius. Vesuvius groundwaters are dilute (mean TDS 2800 mg/L) hypothermal fluids (mean T 17.7°C) with a prevalent alkaline-bicarbonate composition. Calcium-bicarbonate groundwaters normally occur on the surrounding Campanian Plain, likely recharged from the Apennines. D and 18O data evidence an essentially meteoric origin of Vesuvius groundwaters, the contribution from either Tyrrhenian seawater or 18O-enriched thermal water appearing to be small or negligible. However, the dissolution of CO2-rich gases at depth promotes acid alteration and isochemical leaching of the permeable volcanic rocks, which explains the generally low pH and high total carbon content of waters. Attainment of chemical equilibrium between the rock and the weathering solutions is prevented by commonly low temperature (10 to 28°C) and acid-reducing conditions. The chemical and isotope (C and He) composition of dissolved gases highlights the magmatic origin of the gas phase feeding the aquifer. We show that although the pristine magmatic composition may vary upon gas ascent because of either dilution by a soil-atmospheric component or fractionation processes during interaction with the aquifer, both 13C/12C and 3He/4He measurements indicate the contribution of a magmatic component with a 13C 0‰ and R/Ra of 2.7, which is consistent with data from Vesuvius fumaroles and phenocryst melt inclusions in olivine phenocrysts. A main control of tectonics on gas ascent is revealed by data presented in this paper. For example, two areas of high CO2 release and enhanced rock leaching are recognized on the western (Torre del Greco) and southwestern (Torre Annunziata–Pompeii) flanks of Vesuvius, where important NE-SW and NW-SE tectonic structures are recognized. In contrast, waters flowing through the northern sector of the volcano are generally colder, less saline, and CO2 depleted, despite in some cases containing significant concentrations of magmaderived helium. The remarkable differences among the various sectors of the volcano are reconciled in a geochemical interpretative model, which is consistent with recent structural and geophysical evidences on the structure of Somma-Vesuvius volcanic complex.
    Description: -European Union, -Ministero dell’Universita’ e della Ricerca Scientifica e Tecnologica; -CNR–Gruppo Nazionale per la Vulcanologia.
    Description: Published
    Description: 963–981
    Description: partially_open
    Keywords: isotopes ; water chemistry ; dissolved gases ; 03. Hydrosphere::03.02. Hydrology::03.02.03. Groundwater processes ; 03. Hydrosphere::03.04. Chemical and biological::03.04.03. Chemistry of waters ; 03. Hydrosphere::03.04. Chemical and biological::03.04.05. Gases ; 03. Hydrosphere::03.04. Chemical and biological::03.04.06. Hydrothermal systems ; 03. Hydrosphere::03.04. Chemical and biological::03.04.07. Radioactivity and isotopes ; 04. Solid Earth::04.08. Volcanology::04.08.01. Gases ; 04. Solid Earth::04.08. Volcanology::04.08.06. Volcano monitoring
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  • 2
    Publication Date: 2017-04-04
    Description: This work presents the results of hydrogeochemical studies carried out at Vesuvius during the period May 1998 - December 2001, mostly focusing on compositional time variations observed during this time. Based on their chemistry, groundwater samples are distinguished into two groups, 1 and 2, representative of water circulation in the southern and northern sectors of the volcano, respectively. Waters from group 1 are typically more acidic, warmer,and more saline than those of group 2. They also have higher CO2 and CH4 contents, attributed to enhanced input of deep-rising volatiles and prolonged water-rock interactions. Time-series highlight the fairly constant chemical composition of the entire aquifer. Groundwater temperature, pH, bicarbonate content and dissolved CO2 display quite stable values in the study period, particularly in deep wells (piezometric level more than 100 m deep). Shallower water bodies present more evident temporal variations, related to seasonal and anthropogenic effects. This paper also describes some important variations in water chemistry which had occurred by the time of the seismic event in early October 1999, particularly in the Olivella spring located on the northern flank of the volcano. At this site, a great decrease in water pH and redox potential, and increased dissolved CO2 contents and 3He/4He ratios were observed. These changes in chemical and isotope composition support the hypothesis of an input of magma-derived helium and carbon dioxide into the aquifer feeding the Olivella spring by the time of the earthquake.
    Description: Published
    Description: 81-104
    Description: partially_open
    Keywords: Vesuvius ; volcanic surveillance ; groundwater ; hydro-geochemistry ; oxygen-18 ; 03. Hydrosphere::03.04. Chemical and biological::03.04.03. Chemistry of waters ; 03. Hydrosphere::03.04. Chemical and biological::03.04.05. Gases ; 03. Hydrosphere::03.04. Chemical and biological::03.04.06. Hydrothermal systems ; 04. Solid Earth::04.08. Volcanology::04.08.06. Volcano monitoring
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  • 3
    Publication Date: 2017-04-04
    Description: The properties of volcanic tremor wavefield at Mt. Etna Volcano, Italy, are investigated using data from two dense, smallaperture arrays of short-period seismometers deployed on the North and South flank of the volcano. Spectral analysis shows that most of the seismic energy is associated to several, narrow spectral peaks spanning the 1–5 Hz frequency band. Analysis of simultaneous recordings evidences that most of these peaks are common to different sites, thus suggesting a source effect as the origin of this energy. Frequency-slowness analyses evidence a complex wavefield, where body- and surface-waves alternatively dominate depending on the frequency band and component of motion taken into account. Surface waves are found to dominate at frequencies below 1 Hz and above 3 Hz. Conversely, the 0.8–2.3 Hz vertical- and radial-component wavefields at both arrays exhibit a nondispersive nature, with apparent velocities spanning the 1–2 s/km range. Particle motion analysis suggests these arrivals are associated to both P- and SV-waves inciding at shallow angles. At the northern array, back-azimuths of these waves encompass the whole summit crater area. At the southern array, back-azimuths are instead clustered around a direction pointing about 500 m east of the SE crater. At frequency around 4 Hz, the dominant direction of wave propagation at the southern site shifts about 30jW, pointing to the Bocca-Nuova/Voragine craters, and concordance of location is found with the source imaged by the northern array. The 0.8–2.3 Hz transverse-component of motion depicts velocities of about 0.5 km/s, a value which is about three times lower than those associated to the vertical and radial components. Results from polarization analyses at the two array sites depict the dominance of horizontal, linear particle motion oriented transversally with respect to the source direction. Polarization ellipsoids at the stations of the sparse network all depict a quasi-horizontal setting. With two exceptions, the direction of particle motion is always oriented tangentially to the summit volcanic edifice. The origin of the large transverse motion observed at the two array sites is thus attributed to SH waves generated by free-surface interaction of waves impinging the concave topography. The correlation method is used to derive the dispersion properties of short-period (0.5–5 Hz) Rayleigh waves, from which the shallow shear-wave velocity structures are derived for beneath the two semicircular arrays. Using a probabilistic approach, we invert slowness data measured at the two dense arrays for retrieving source location and extent. The joint inversion of slowness data from the two arrays point to different sources. This observation is interpreted in terms of ray bending associated to lateral heterogeneity and/or strong topographic effects on wave propagation. Once the propagation effects are taken into account, the most probable source locations are associated to a shallow region encompassing the summit craters and the eruptive fissures active at the time of the experiment (September 1999).
    Description: Published
    Description: 223-245
    Description: partially_open
    Keywords: Mount Etna ; Volcanic tremor ; Volcanic seismicity ; Seismic monitoring ; 04. Solid Earth::04.06. Seismology::04.06.08. Volcano seismology
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  • 4
    Publication Date: 2017-04-04
    Description: While the eruptive record of Mount Etna is reasonably complete for the past 400 years, the activity of the early and late 1960s, which took place at the summit, is poorly documented in the scientific literature. From 1955 to 1971, the Central and Northeast Craters were the sites of long-lived mild Strombolian and effusive activity, and numerous brief episodes of vigorous eruptive activity, which led to repeated overflows of lava onto the external flanks of the volcano. A reconstruction of the sequence of the more important of these events based on research in largely obscure and nearly inaccessible sources permits a better understanding of the eruption dynamics and rough estimates of erupted volumes and of the changes to the morphology of the summit area. During the first half of 1964, the activity culminated in a series of highly dynamic events at the Central Crater including the opening of a fissure on the E flank of the central summit cone, lava fountains, voluminous tephra emission, prolonged strong activity with continuous lava overflows, and growth of large pyroclastic intracrater cones. Among the most notable processes during this eruption was the breaching of a section of the crater wall, which was caused by lateral pressure of lava ponding within the crater. Comparison with the apparently similar summit activity of 1999 allows us to state that (a) lava overflows from large pit craters at the summit are often accompanied by breaching of the crater walls, which represents a significant hazard to nearby observers, and that (b) eruptive activity in 1999 was much more complex and voluminous than in 1964. For 1960s standards however, the 1964 activity was the most important summit eruption in terms of intensity and output rates for about 100 years, causing profound changes to the summit morphology and obliterating definitively the former Central Crater.
    Description: Published
    Description: 203-218
    Description: partially_open
    Keywords: Mount Etna ; Summit eruption ; Crater morphology and Lava overflows ; 04. Solid Earth::04.08. Volcanology::04.08.03. Magmas ; 04. Solid Earth::04.08. Volcanology::04.08.06. Volcano monitoring ; 05. General::05.02. Data dissemination::05.02.03. Volcanic eruptions
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  • 5
    Publication Date: 2017-04-04
    Description: This paper discusses the abundance, speciation and mobility of As in groundwater systems from active volcanic areas in Italy. Using literature data and new additional determinations, the main geochemical processes controlling the fate of As during gas–water–rock interaction in these systems are examined. Arsenic concentrations in the fluids range from 0.1 to 6940 mg/l, with wide differences observed among the different volcanoes and within each area. The dependence of As content on water temperature, pH, redox potential and major ions is investigated. Results demonstrate that As concentrations are highest where active hydrothermal circulation takes place at shallow levels, i.e. at Vulcano Island and the Phlegrean Fields. In both areas the dissolution of As-bearing sulphides is likely to be the main source of As. Mature Cl-rich groundwaters, representative of the discharge from the deep thermal reservoirs, are typically enriched in As with respect to SO4-rich ‘‘steam heated groundwaters’’. In the HCO3 groundwaters recovered at Vesuvius and Etna, aqueous As cycling is limited by the absence of high-temperature interactions and by high-Fe content of the host rocks, resulting in oxidative As adsorption. Thermodynamic modelling suggests that reducing H2S-rich groundwaters are in equilibrium with realgar, whereas in oxidising environments over-saturation with respect to Fe oxyhydroxides is indicated. Under these oxidising conditions, As solubility decreases controlled by As co-precipitation with, or adsorption on, Fe oxy-hydroxides. Consistent with thermodynamic considerations, As mobility in the studied areas is enhanced in intermediate redox environments, where both sulphides and Fe hydroxides are unstable.
    Description: Published
    Description: 1283–1296
    Description: partially_open
    Keywords: Hydrogeochemistry ; Arsenic ; volcanic groundwaters ; speciation ; 03. Hydrosphere::03.01. General::03.01.01. Analytical and numerical modeling ; 03. Hydrosphere::03.02. Hydrology::03.02.02. Hydrological processes: interaction, transport, dynamics ; 03. Hydrosphere::03.02. Hydrology::03.02.03. Groundwater processes ; 03. Hydrosphere::03.04. Chemical and biological::03.04.03. Chemistry of waters ; 03. Hydrosphere::03.04. Chemical and biological::03.04.06. Hydrothermal systems
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  • 6
    Publication Date: 2017-04-04
    Description: A number of tumuli formed on the aa-dominated lava fan complex which developed in the medial zone of the 1983 flow-field of Mount Etna during the later stages of the eruption. This complex flow-field formed on shallow sloping ground below a scarp between 1900 and 1700 m asl. A major tube system fed a branching tube network in the fan complex. Numerous tumuli and break-outs of lava formed in the fan. Three main types of tumulus are identified: (1) Focal tumuli, which are formed from the break-up and uplift of `old´, thick lava crust and themselves become sustained sites for the distribution of lava both as flows and within distributary tubes. These focal tumuli are significant centres associated with major tubes. (2) Satellite tumuli, which are typically elongate, whale-back shaped features that branch out from focal tumuli. These satellite tumuli were initially lava flows erupted from a focal tumulus. The crust of the flow slowed or came to a halt and the rigid crust became uplifted and fractured, forming a dome-shaped ridge feature. These satellite tumuli continued to be fed from the focal tumulus and became sites of lava emission with numerous break-outs. (3) Distributary tumuli formed on the fan associated with short-lived break-outs from tubes and are relatively simple structures formed from limited effusion of toey lobes and pahoehoe lava. The major tumuli on the fan complex show distinct dilation fractures. The fracture surfaces provide good exposure of the crust and three distinct zones are recognised – an upper zone showing columnar jointing, a middle zone consisting of planar fracture surfaces and a basal zone with distinctive banded planar fracture surfaces showing evidence of both brittle and ductile formation. Using these data a model is proposed for tumulus growth. Field analysis of the fan complex shows how it was fed by a branching tube system, leading to flow thickening, formation of tumuli and numerous ephemeral boccas.
    Description: Published
    Description: partially_open
    Keywords: aa lava flow-field ; Mount Etna ; tumulus ; lava crust and lava tubes. ; 04. Solid Earth::04.08. Volcanology::04.08.02. Experimental volcanism ; 04. Solid Earth::04.08. Volcanology::04.08.03. Magmas ; 04. Solid Earth::04.08. Volcanology::04.08.06. Volcano monitoring
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  • 7
    Publication Date: 2017-04-04
    Description: Radon levels were measured in 119 groundwater samples collected throughout the active volcanic area of Mt. Etna by means of a portable Lucas-type scintillation chamber. The measured activity values range from 1.8 to 52.7 Bq l 1. About 40% of the samples exceed the maximum contaminant level of 11 Bq l 1 proposed by the USEPA in 1991. The highest radon levels are measured in the eastern sector of the volcano, which is the seismically most active zone of the volcano. On the contrary the south-western sector, which is both seismically active and a site of intense magmatic degassing, display lower radon levels. This is probably due to the formation of a free gas phase (oversaturation of CO2) that strips the radon from the water. Comparison of the data gathered at Mt. Etna with those of other areas indicates that 222Rn activity in groundwater is positively correlated with both the content of parent elements in the aquifer rocks and the temperature of the geothermal systems that interacts with the sampled aquifers.
    Description: Published
    Description: 187–201
    Description: partially_open
    Keywords: Groundwater ; Radon ; Mount Etna ; Active volcanic areas ; 03. Hydrosphere::03.02. Hydrology::03.02.03. Groundwater processes ; 03. Hydrosphere::03.02. Hydrology::03.02.06. Water resources ; 03. Hydrosphere::03.04. Chemical and biological::03.04.03. Chemistry of waters ; 03. Hydrosphere::03.04. Chemical and biological::03.04.07. Radioactivity and isotopes ; 04. Solid Earth::04.08. Volcanology::04.08.06. Volcano monitoring ; 05. General::05.08. Risk::05.08.01. Environmental risk
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  • 8
    Publication Date: 2017-04-04
    Description: Large-scale flank instability on Mount Etna is associated with a distinct set of faults radiating generally from the summit area and restricted to the volcanic edifice itself. New observations and mapping of very recent and continuing deformation along these faults and related structures have been analysed in combination with published information, including recent seismic and eruption data, enabling the faults to be placed in three groups. Two of these, the Pernicana fault system (PFS) and the Ragalna fault system (RFS) bound, respectively, the northern and south-western margins of instability. Their activity responds to cycles of magma pressure associated with flank eruptions, together with subsequent deflation as gravity dominates. These cycles may operate at different depths, with the RFS bordering deep-seated instability. Their positions appear governed by the contact, in the substrate of the volcano, between relatively weak early Quaternary clays and stronger rocks of the Apennine–Maghrebian Chain that rise towards the north and west in the subsurface, buttressing the edifice in these directions. The unstable mass to the un-buttressed south and east is thus defined by its weak substrate and displays structures similar to those produced in model experiments. The third fault group, the Mascaluci–-Trecastagni fault system, borders a rather faster-moving zone of instability in the eastern part of the large unstable mass, outlining one element in a nested pattern in map view. Low-angle detachments below the unstable zones are thought to occur at different levels above a deep and laterally extensive detachment associated with the RFS, producing a nested pattern in section as well. This is illustrated by the PFS where the long-recognised western half of the fault borders a fast moving zone of instability riding above a detachment that daylights as a thrusted deformation front marked by recurring landsliding at an approximate mid-slope position on the volcano. Downslope, the newly recognised eastern extension of the PFS, exhibiting slip-rates an-order-of-magnitude lower than the western segment, is thought to border a deeper slow-moving detachment that daylights offshore. Windows of deformed sub-Etnean clays at anomalously high altitudes may indicate where similar detachments, no longer mechanically favoured and now inactive, have daylighted. As a result, the edifice can be considered, overall, as consisting of multiple unstable areas, nested in plan view and with basal detachments occurring at different levels in section. This model of edifice behaviour is regarded as an evolving one, with detachments waxing and waning in their activity as flank movement progresses.
    Description: Published
    Description: 137-153
    Description: partially_open
    Keywords: Mount Etna ; instability; flank faults ; volcano collapse models ; 04. Solid Earth::04.04. Geology::04.04.09. Structural geology ; 04. Solid Earth::04.08. Volcanology::04.08.06. Volcano monitoring
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  • 9
    Publication Date: 2017-04-04
    Description: New geochemical data on dissolved major and minor constituents in 276 groundwater samples from Etna aquifers reveal the main processes responsible for their geochemical evolution and mineralisation. This topic is of particular interest in the light of the progressive depletion of water resources and groundwater quality in the area. Multivariate statistical analysis reveal 3 sources of solutes: (a) the leaching of the host basalt, driven by the dissolution of magmaderived CO2; (b) mixing processes with saline brines rising from the sedimentary basement below Etna; (c) contamination from agricultural and urban wastewaters. The last process, highlighted by increased concentrations of SO4,NO3, Ca, F and PO4, is more pronounced on the lower slopes of the volcanic edifice, associated with areas of high population and intensive agriculture. However, this study demonstrates that natural processes (a) and (b) are also very effective in producing highly mineralised waters, which in turn results in many constituents (B, V, Mg) exceeding maximum admissible concentrations for drinking water.
    Description: Published
    Description: 863–882
    Description: partially_open
    Keywords: Hydrogeochemistry ; water quality ; Mt. Etna ; 03. Hydrosphere::03.02. Hydrology::03.02.03. Groundwater processes ; 03. Hydrosphere::03.02. Hydrology::03.02.04. Measurements and monitoring ; 03. Hydrosphere::03.02. Hydrology::03.02.06. Water resources ; 03. Hydrosphere::03.04. Chemical and biological::03.04.03. Chemistry of waters
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  • 10
    Publication Date: 2017-04-04
    Description: We describe the reactivation and the successive evolution of the shallow plumbing system of Mt. Etna between the end of the largest flank eruption of the last three centuries (1991–1993) and the subterminal eruption from South-East Crater (SEC), which occurred between February and mid-November 1999. Our analysis is based on observations of the volcanic activity and petrological studies of the erupted volcanics. Bulk rock, mineral and glass compositions have been determined for more than 80 samples erupted from the four summit craters between October 1995 and February 1999. These data allow us to recognise significant compositional variations among the products of different craters. In particular, volcanics produced between 1995 and 1999 by Bocca Nuova (BN), Voragine (VOR) and North-East Crater (NEC) show limited compositional variations and are similar to those observed during recent eruptions (e.g., 1991–93). More primitive magmas have been produced during the more vigorous fire fountains episodes. On the contrary, the South-East Crater produced slightly more differentiated volcanics than those of the other summit craters following its reactivation (November 1996) until the end of 1998. Whole rock compositions of products from this crater show low CaO/Al2O3, whereas interstitial glasses have lower MgO and higher alkali contents than those from the other craters. However, since the beginning of 1999, and just before the start of the subterminal eruption from SEC, the volcanics erupted from this crater progressively changed in composition, becoming similar to those of the other craters. This trend indicates that within the conduits of the summit craters, distinct thermal and fluid-dynamical regimes can evolve, controlling the cooling and crystallisation of Etna magmas.
    Description: Published
    Description: 55-71
    Description: partially_open
    Keywords: Mount Etna ; crystal fractionation ; petrologic monitoring and magmatic process ; 04. Solid Earth::04.04. Geology::04.04.05. Mineralogy and petrology ; 04. Solid Earth::04.08. Volcanology::04.08.03. Magmas ; 04. Solid Earth::04.08. Volcanology::04.08.05. Volcanic rocks
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  • 11
    Publication Date: 2022-05-24
    Description: Many studies have assessed the strong influence of volcanic activity on the surrounding environment. This is particularly true for strong gas emitters such as Mt. Etna and Stromboli volcanoes. Among volcanic gases, fluorine compounds are potentially very harmful. Fluorine cycling through rainwater in the above volcanic areas was studied analysing more than 400 monthly bulk samples. Data indicate that only approximately 1% of fluorine emission through the plume is deposited on the two volcanic areas by meteoric precipitations. Although measured bulk rainwater fluorine fluxes are comparable to and sometimes higher than in heavily polluted areas, their influence on the surrounding vegetation is limited. Only annual crops, in fact, show some damage that could be an effect of fluorine deposition, indicating that long-living endemic plant species or varieties have developed some kind of resistance.
    Description: Published
    Description: 175–185
    Description: partially_open
    Keywords: Fluorine ; Rainwater chemistry ; Volcanic activity ; Mt. Etna ; Stromboli Island ; 01. Atmosphere::01.01. Atmosphere::01.01.07. Volcanic effects ; 03. Hydrosphere::03.03. Physical::03.03.01. Air/water/earth interactions ; 03. Hydrosphere::03.04. Chemical and biological::03.04.03. Chemistry of waters ; 03. Hydrosphere::03.04. Chemical and biological::03.04.05. Gases ; 04. Solid Earth::04.08. Volcanology::04.08.01. Gases ; 05. General::05.02. Data dissemination::05.02.01. Geochemical data ; 05. General::05.08. Risk::05.08.01. Environmental risk
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