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  • 101
    Publication Date: 2015-09-05
    Description: Magnetic minerals acquire a remanent magnetization when cooled or warmed in an applied field H through a phase transition. This paper reports the first observations of transition cooling and warming remanent magnetizations (TrCRM and TrWRM) in pyrrhotite (Fe 7 S 8 ) and hematite (αFe 2 O 3 ), with phase transitions at 32 K (Besnus transition) and 250 K (Morin transition). TrWRM was produced by warming in a 2 mT field from 10 to 300 K and TrCRM by cooling in 2 mT from 300 to 10 K. In both experiments, magnetization M was measured at 5 K intervals. The largest changes in M occurred over a 20 K interval flanking the Besnus or Morin transition but substantial changes also occurred away from any transition, presumably due to continuous changes in anisotropy. The triclinic low-temperature phase of pyrrhotite has high remanence efficiency compared to the room-temperature monoclinic phase. When H was zeroed at 300 K, only 35–40% of M survived as TrWRM, but in TrCRM experiments when H was zeroed at 10 K, practically 100% of M was preserved. After zero-field cooling to 10 K, 50–60% of TrWRM was retained but 〈15% of TrCRM survived zero-field warming to 300 K. In hematite, both TrWRM of the room-temperature spin-canted phase and TrCRM of the low-temperature defect phase exist, as shown by net remanence production following complete warming–cooling or cooling–warming cycles between 10 and 300 K. Details of remanence acquisition/demagnetization in crossing the Morin transition could not be resolved, however. Symmetries were observed for both minerals. Single-domain size pyrrhotite crystals had mirror-image field-off and field-on warming curves below 32 K, during TrWRM production/TrCRM loss at the 32 K transition, and up to 150 K. Submicron single-domain hematite had almost complete symmetry between field-off and field-on curves during cooling as well as warming, both below and above the Morin transition but not in the transition region itself. This is the first time that mirror-image symmetries, observed previously for pseudo-single-domain and multidomain magnetite, have been documented for mineral grains in a single-domain state.
    Keywords: Geomagnetism, Rock Magnetism and Palaeomagnetism
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    Topics: Geosciences
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  • 102
    Publication Date: 2015-07-27
    Description: A computational method is given for solving the forward modelling problem for transient electromagnetic exploration. Its key features are the discretization of the quasi-static Maxwell's equations in space using the first-kind family of curl-conforming Nédélec elements combined with time integration using rational Krylov methods. We show how rational Krylov methods can also be used to solve the same problem in the frequency domain followed by a synthesis of the transient solution using the fast Hankel transform, and we argue that the pure time-domain solution is more efficient. We also propose a new surrogate optimization approach for selecting the pole parameters of the rational Krylov method which leads to convergence within an a priori determined number of iterations independent of mesh size and conductivity structure. These poles are repeated in a cyclic fashion, which, in combination with direct solvers for the discrete problem, results in significantly faster solution times than previously proposed schemes.
    Keywords: Geomagnetism, Rock Magnetism and Palaeomagnetism
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  • 103
    Publication Date: 2015-11-05
    Description: In 2010, a wide-angle seismic reflection/refraction profile was acquired along the Hecataeus Rise, an area of shallow seabed immediately south of Cyprus in the eastern Mediterranean. The profile crossed from the Hecataeus Rise, through the Cyprus Arc to the Levantine Basin beyond. Due to the short length of the profile and the corresponding lack of deep ray coverage, velocity modelling was complemented by gravity modelling to gain constraints on deep crustal structure. The resultant model reveals velocities for the Hecataeus Rise that show no evidence of shallow ophiolites like those seen on mainland Cyprus, and the velocities are not diagnostic of a unique crustal affinity. Low-velocity sediments make up at least 7 km of the upper structure of Hecataeus Rise and these sediments overlie a two-layered crust. From the gravity modelling, the combined sediments and crust of Hecataeus Rise appear to be thinner than the Eratosthenes Seamount block to the southwest. A high-velocity lower crustal block is modelled under the seaward edge of Hecataeus Rise and, based on the gravity modelling, is inferred to extend landwards beneath the Rise. Similar high-velocity blocks were identified on the southwestern edge of Hecataeus Rise along nearby refraction lines and were interpreted as remnant Tethyan oceanic crust, foundered in the Cyprus Arc, along which subduction has ceased in this area. Given the thin two-layered crust beneath a thick accumulation of sediments modelled for Hecataeus Rise, we interpret that Hecataeus Rise represents a collage of oceanic fragments, accreted together within the failed subduction zone. Outboard of the crust of Hecataeus Rise, a 5-km deep low-velocity basin, possibly an accretionary wedge, is imaged that appears to correspond with the Cyprus Arc deformation zone imaged on both coincident and along-strike seismic reflection lines. A similar and wider feature is observed on seismic refraction lines to the west and combined, these may be revealing an eastward tapering zone of crustal deformation. To the south of the profile, the Levantine Basin appears undisturbed by the collision to the north and exhibits a uniform and homogeneous velocity structure.
    Keywords: Geomagnetism, Rock Magnetism and Palaeomagnetism
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  • 104
    Publication Date: 2015-09-05
    Description: The Rogaland Igneous Complex (RIC) in southern Norway intruded into post-Sveconorwegian granulite facies crust ~930 Ma. It includes three massif anorthosites, several small leuconorite bodies and the ~7 km thick norite-quartz mangerite layered Bjerkreim-Sokndal (BKS) intrusion. The intrusion consists of five rhythmic megaunits created by repeated magma influxes topped by a transition zone and more evolved mangerites and quartz mangerites. Over 70 palaeomagnetic sites have been collected in the BKS, sampling all the megacyclic subunits and overlying mangerites. Remanence within the BKS is held in hemo-ilmenite-only rocks (lower parts of the megacyclic units), mixed hemo-ilmenite and magnetite rocks (upper parts of the lower megacyclic units) and magnetite only rocks in the upper highest megacyclic unit and overlying mangerites. Due to the different oxides present magnetic susceptibility varies over four orders of magnitude with a bimodal distribution (mean susceptibility of 6.4 x 10 –3 SI for hemo-ilmenite rocks, and 8.7 x 10 –2 SI for magnetite rocks). NRM values do not show a strong bimodal distribution as many of the rocks lacking magnetite have hemo-ilmenite with strong lamellar magnetism; average NRM for the entire suite is 8.83 A m –1 . All sites within the cyclic part of the intrusion have stable remanence and produce well-clustered site means. Samples from the upper mangerite rocks, dominated by MD magnetite, are commonly unstable and not all sites provide acceptable data. Mean directions for 66 sites spanning the entire intrusion are I = –73.5°, D = 303.4°, with α 95 = 3.7° and k = 24. The resulting pole position is at 35.9°S and 217.9°E, with a palaeolatitude for this part of Baltica of –59.4°. Examination of the magnetic mineralogy combined with geochronology for RIC rocks and cooling rates for the region yields an age of magnetization of 916 Ma. Metamorphic country rocks yield similar directions at least 10 km from the contact, confirming the presence of a contact aureole around the intrusion. Comparison to other early Neoproterozoic palaeomagnetic poles from southern Scandinavia confirms the high southern latitude position of Baltica at this time, and combined with the few other ~900 Ma poles from Baltica affirm the presence of the Rodinia supercontinent at this time.
    Keywords: Geomagnetism, Rock Magnetism and Palaeomagnetism
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  • 105
    Publication Date: 2015-03-18
    Description: The Internal Sierras (IS) in the southern margin of the Western and Central Axial Zone (Southern Pyrenees) are affected by a syn-orogenic remagnetization that provides information to reconstruct deformation geometries at the time of acquisition of magnetization. Furthermore, the IS structure changes strike along its structural trend, from ~N120 to 130°E in the western and eastern margins to ~N070–090°E in the central part. Palaeomagnetic techniques have been used to (i) accurately define the timing of remagnetization with regard to deformation and (ii) determine if the along-strike trend variation in the IS was induced by deformation and thrust emplacement during the Pyrenean compression or, on the contrary, was the result of a primary orientation controlled by structures inherited from pre-orogenic times. From 23 new palaeomagnetic sites, collected in Upper Cretaceous marls and marly limestones, two meaningful and stable palaeomagnetic components were resolved, principally carried by magnetite: (1) a lower-temperature component (B) that unblocks between 200 °C and 325–400 °C and (2) a higher-temperature component (C) that has been successfully isolated by means of combined thermal (up to 400 °C) and AF demagnetization (generally up to 50–100 mT). The B component is a late remagnetization that post-dates folding and emplacement of basement thrust sheets in the IS (mainly the Gavarnie thrust). It supports small but statistically significant clockwise rotations in the western part of the IS (from +18 to +26°). These rotations can be attributed to the westwards shortening decrease in the thrust system below the Gavarnie unit that results from its along-strike structural change, with a higher number of basement thrusts to the east. The C component has been interpreted as an early remagnetization, based on the results of conglomerate and fold tests. This component predates basement thrusting and is diachronous across the study area: reverse and normal polarities dominate in the eastern and western margins of the IS, respectively. New and previous palaeomagnetic data point out that curvature in the IS is probably a primary feature and the along-strike change in their trend could be interpreted as the result of basement geometrical features inherited from Variscan, Late Variscan or Mesozoic times. A complex, multi-episodic remagnetization probably related to burial and deformation processes occurred during Eocene times.
    Keywords: Geomagnetism, Rock Magnetism and Palaeomagnetism
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  • 106
    Publication Date: 2015-02-06
    Description: A comprehensive magnetic field model named CM5 has been derived from CHAMP, Ørsted and SAC-C satellite and observatory hourly-means data from 2000 August to 2013 January using the Swarm Level-2 Comprehensive Inversion (CI) algorithm. Swarm is a recently launched constellation of three satellites to map the Earth's magnetic field. The CI technique includes several interesting features such as the bias mitigation scheme known as Selective Infinite Variance Weighting (SIVW), a new treatment for attitude error in satellite vector measurements, and the inclusion of 3-D conductivity for ionospheric induction. SIVW has allowed for a much improved lithospheric field recovery over CM4 by exploiting CHAMP along-track difference data yielding resolution levels up to spherical harmonic degree 107, and has allowed for the successful extraction of the oceanic M 2 tidal magnetic field from quiet, nightside data. The 3-D induction now captures anomalous Solar-quiet features in coastal observatory daily records. CM5 provides a satisfactory, continuous description of the major magnetic fields in the near-Earth region over this time span, and its lithospheric, ionospheric and oceanic M 2 tidal constituents may be used as validation tools for future Swarm Level-2 products coming from the CI algorithm and other dedicated product algorithms.
    Keywords: Geomagnetism, Rock Magnetism and Palaeomagnetism
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  • 107
    Publication Date: 2015-03-01
    Description: The observation of electromagnetic signals by ocean bottom electromagnetometers in association with the Tohoku tsunami of 2011 March 11 has raised the opportunity to re-examine the physics of motional induction due to oceanic long waves in the framework of 1-D magnetotellurics (MT). Although a propagating tsunami has a complex structure, the induced electromagnetic field can be simply approximated as a plane wave (though a simple thin-sheet approximation is not valid at higher frequencies). We found that the MT impedance due to a surface gravity wave (or the ‘motional impedance’) is influenced largely by the dispersion of the wave if the period is sufficiently short or the electrical conductivity of the seabed is low. The tipper due to the motional induction (or the ‘motional tipper’) and motional impedance are essentially identical if the underneath structure is 1-D. It would be possible to estimate the motional impedance and tipper from the observed ocean bottom electromagnetic field at the time of passing of a tsunami. The wave amplitude must be much greater than several tens of centimetres for the motional impedance and tipper estimation to be free from the effects of external sources. However, the obtained motional impedance and tipper will mostly represent the property of the wave and use of them may not be suitable to discuss the subseafloor conductivity structure.
    Keywords: Geomagnetism, Rock Magnetism and Palaeomagnetism
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  • 108
    Publication Date: 2015-03-01
    Description: The lacustrine deposits in Heqing basin provide an excellent archive for long-term high-resolution palaeoclimate studies in the monsoon-dominated southeastern Tibetan Plateau region. In this study, we investigate the climatic significance of magnetic parameters for analysing the variability of the past climate. For this, we performed comprehensive time-series and statistical analysis on previously published proxy data from a 168-m-long drill core (Core-HQ) that spans ~900–30 ka, comprising mainly magnetic parameters and carbonate content (CC). Moreover, we investigated magnetic properties of modern soil in the catchment that predominantly formed on limestone bedrock. Key findings are: (1) modern soils and sediments of Core-HQ both contain a mixture of magnetite (Mt), maghemite (Mgh) and hematite (Ht), but magnetic concentration of the soils is one order higher; (2) a superparamagnetic (SP) fraction of Mt/Mgh dominates in the soils whereas in Core-HQ the SP contribution is generally very low; (3) a larger grain-size fraction of Mt/Mgh and Ht is also present in the soils. We explain variations of magnetic concentration and CC in Core-HQ by an increased wind transport of soil and a decreased surface water transport of carbonate and soil in less humid periods. Low-temperature oxidation of magnetite in the catchment is as another crucial process that reflects weathering conditions and is likely sensitive to humidity; the degree of LTO can be semi-quantified by the magnetic parameters ARM/SIRM and S -ratio. Combining CC, ARM/SIRM and S -ratio values, we derive a weathering intensity (WI). The WI index variation along Core-HQ shows strong fluctuations on a 100-kyr eccentricity scale in the lower part, especially during ~630–380 ka, followed by a long period (~320–80 ka) of persistently weaker weathering (drier?) conditions with low variability, and a rapid return of much stronger weathering (wetter?) conditions at ~80 ka. We suggest that a reduced influence of the Indian summer monsoon accounts for less moisture supply to the region and lower climatic variability.
    Keywords: Geomagnetism, Rock Magnetism and Palaeomagnetism
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  • 109
    Publication Date: 2015-03-05
    Description: Magnetic mineralogy of crustal rocks has important implications for understanding continental crustal evolution and origin of regional magnetic anomalies. However, magnetic properties of the deep continental crust are still poorly understood. In this paper, measurements of density ( ), mass-specific magnetic susceptibility ( ), natural remanent magnetization (NRM) and magnetic hysteresis loops, temperature-dependent magnetic susceptibility ( – T ), chemical and mineral analyses were conducted on Archean gneiss samples from the Jixian petrophysical section in the Precambrian terrain, northeastern North China Craton, with the aim of refining understanding of magnetic phase transformations in the deep crustal rocks. Results show that density and rock magnetic properties change distinctly with metamorphic facies. The dominant magnetic mineral is magnetite, while a little hematite is present in a few samples. Together with geochemical and mineralogical compositions, it is inferred that progressive increase in metamorphic grade from east to west is the major cause for magnetic enhancement of the lower crust in the studied section. Therefore, we conclude that study of magnetic phases of deep crustal rocks can offer important insights into the history of high metamorphic grade terranes.
    Keywords: Geomagnetism, Rock Magnetism and Palaeomagnetism
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  • 110
    Publication Date: 2015-02-27
    Description: The C -response is a conventional transfer function in global electromagnetic induction research and is traditionally determined from observations of magnetic variations in the vertical and horizontal components. Its interpretation relies on the assumption that the source of the variations is well approximated by a large-scale symmetric (magnetospheric) ring current, described by a single spherical harmonic. However, there is growing evidence for a more complex structure of this source. In this paper, we investigate the variability of C -responses due to sources different from the dominating large-scale symmetric ring current. We show that the effect is significant and persists at all periods. Describing the magnetospheric source by a single spherical harmonic coefficient thus injects substantial errors into the estimated responses. To overcome the problem, we introduce arrays of alternative transfer functions that relate the components of the magnetic variation to different spherical harmonic coefficients. These transfer functions can handle a complex spatial structure of the magnetospheric source. Compared to C -responses, we observe a significant increase in the coherencies relating input and output quantities of the new transfer functions, especially at high latitudes. This increases the usability of observatory magnetic data for the recovery of global 3-D mantle conductivity structure.
    Keywords: Geomagnetism, Rock Magnetism and Palaeomagnetism
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  • 111
    Publication Date: 2015-03-04
    Description: Magnetic mineralogy of crustal rocks has important implications for understanding continental crustal evolution and origin of regional magnetic anomalies. However, magnetic properties of the deep continental crust are still poorly understood. In this paper, measurements of density ( ), mass-specific magnetic susceptibility ( ), natural remanent magnetization (NRM) and magnetic hysteresis loops, temperature-dependent magnetic susceptibility ( – T ), chemical and mineral analyses were conducted on Archean gneiss samples from the Jixian petrophysical section in the Precambrian terrain, northeastern North China Craton, with the aim of refining understanding of magnetic phase transformations in the deep crustal rocks. Results show that density and rock magnetic properties change distinctly with metamorphic facies. The dominant magnetic mineral is magnetite, while a little hematite is present in a few samples. Together with geochemical and mineralogical compositions, it is inferred that progressive increase in metamorphic grade from east to west is the major cause for magnetic enhancement of the lower crust in the studied section. Therefore, we conclude that study of magnetic phases of deep crustal rocks can offer important insights into the history of high metamorphic grade terranes.
    Keywords: Geomagnetism, Rock Magnetism and Palaeomagnetism
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  • 112
    Publication Date: 2014-12-17
    Description: Surface nuclear magnetic resonance (surface-NMR) is a promising technique for exploring shallow subsurface aquifer structures. Surface-NMR can be applied in environments that are characterized as a 1-D layered Earth. The technique utilizes a single loop and is referred to as magnetic resonance sounding. The technique referred to as magnetic resonance tomography (MRT) allows complex 2-D aquifer structures to be explored. Currently, MRT requires multiple loops and a roll along measurement scheme, which causes long survey time. We propose a loop layout using an elongated transmitter and an in-loop receiver arrays (ETRA) to conduct a 2-D survey with just one measurement. We present a comprehensive comparison between the new layout and the common approaches based on sensitivity and resolution analyses and show synthetic and field data. The results show that ETRA generates subsurface images at sufficient resolution with significantly lower survey times than other loop layouts.
    Keywords: Geomagnetism, Rock Magnetism and Palaeomagnetism
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  • 113
    Publication Date: 2014-11-09
    Description: We studied ionospheric responses to the 2012 April 11 M w 8.6 North Sumatra earthquake using total electron content (TEC) measurements with the regional Global Navigation Satellite System network. This earthquake ruptured the oceanic lithosphere off the Indian Ocean coast of North Sumatra, and is known as the largest strike-slip earthquake ever recorded. Coseismic ionospheric disturbances (CIDs) with rapid TEC enhancement of a few TEC units propagated northward with a speed of acoustic waves (~1 km s –1 ). Resonant atmospheric oscillation with a frequency ~4 mHz have been found as monochromatic oscillation of TEC lasting for an hour after the main shock and the largest aftershock. We compared CID amplitudes of 21 earthquakes world-wide with moment magnitudes ( M w ) 6.6–9.2. They roughly obeyed a law such that CID amplitude increases by two orders of magnitude for the M w increase of three. The 2012 North Sumatra earthquakes slightly deviated negatively from the trend possibly reflecting their strike-slip mechanisms, that is small vertical crustal movements for their magnitudes.
    Keywords: Geomagnetism, Rock Magnetism and Palaeomagnetism
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  • 114
    Publication Date: 2014-09-03
    Description: Broad-band magnetic susceptibility (MS) measurement, a novel magnetic method capable of quantifying a narrow grain size distribution (GSD) of superparamagnetic (SP) particles by measuring low-field MS at a number of frequency steps spanning four orders of magnitude, has been tested in a loess/palaeosol section at Luochuan in the Chinese Loess Plateau. The studied succession consists of sequences from the latest palaeosol unit (S0) to the upper part of the loess unit (L2), spanning the last glacial–interglacial cycle. Reconstructed GSDs consist of volume fractions on the order of 10 –24 m 3 , and the mean GSDs are modal but with distinctive skewness among the loess, the weakly developed palaeosols (weak palaeosols), and the mature palaeosols. This indicates that the mean volume of SP particles in this loess/palaeosol sequence tends to increase during the transition from loess -〉 weak palaeosol -〉 palaeosol, an indication of grain growth as pedogenesis progresses. Total frequency dependence, or TFD(per cent), the difference between 130 at the lowest (130 Hz) and 500k at the highest (500 kHz) frequencies normalized to 130 , is judged to be a more suitable index than previous frequency dependence parameters for the concentration of SP particles. TFD(per cent) has a strong correlation with 130 , showing a continuous ‘growth curve’ with the rate of increase being highest for the loess, moderate for the weak palaeosols, and saturated for the palaeosols. The characteristic curve suggests that smaller SP particles are preferentially formed in the earlier stage of pedogenesis rather than the later phase when even larger particles are formed in mature palaeosols. These results demonstrate that the broad-band MS measurement method will be useful for the quantitative assessment of magnetic nanoparticles in soils and sediments.
    Keywords: Geomagnetism, Rock Magnetism and Palaeomagnetism
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  • 115
    Publication Date: 2014-10-08
    Description: Environmental magnetism can provide simple and fast methods to semi-quantify the contamination levels by heavy metals in urban areas from the relationships between the magnetic properties and the heavy metal concentrations. The aim of this study is to explore the interpretation of selected magnetic parameters as proxies for the evaluation of heavy metal contamination in urban dusts. Dust samples were collected from different districts of Nanjing, Southeast China. The magnetic properties of dusts were analysed and heavy metal (Fe, Al, As, Ba, Cd, Cr, Co, Cu, Hg, Mn, Mo, Ni, Pb, Sr, V and Zn) concentrations were measured. Magnetic minerals, mainly from anthropogenic activities, are dominated by coarse stable single domain-grained ferrimagnetic minerals. The – T curves indicated that the main magnetic minerals are magnetite and hematite. Magnetic properties exhibited similar spatial distribution and significant positive correlations with the concentrations of most metals and with the pollution load index. Magnetic properties had a strong link with the abundance of heavy metals derived from industrial emission and traffic activities, whereas there was a poor correlation with the concentrations of metals from multi-sources such as commercial/domestic sources and natural processes. Besides the low-frequency magnetic susceptibility ( LF ) and the saturation isothermal remanent magnetization, other magnetic parameters can be considered as efficient indicators in the assessment of heavy metal contamination. The linkage between the magnetic properties and heavy metal concentrations in street dusts depends on the sources and nature of their magnetic fraction. Environmental magnetism analyses may provide simple and rapid methods for the assessment of heavy metal contamination in urban street dusts.
    Keywords: Geomagnetism, Rock Magnetism and Palaeomagnetism
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  • 116
    Publication Date: 2014-10-08
    Description: We present in this paper an alternative approach to modelling and inversion of surface nuclear magnetic resonance (sNMR) data that has numerous attractive characteristics. By considering the forward and inverse problem in the frequency-domain (FD) it is possible to heavily truncate the band-limited data set with no appreciable loss of information. Furthermore, it introduces a natural method of signal demodulating and sidesteps the rotating frame transformation, which can be difficult to apply to large volumes. By instead remaining in the laboratory frame, phase shifts due to off-resonance transmission and static variation in the Larmor frequencies become simpler to account for. For these reasons, we present the first practical scheme for comprehensively inverting the complex sNMR data set. The use of complex data allows for improved depth and decay constant resolution. However, it requires the knowledge of subsurface electrical conductivity, and by corollary the ability to accurately model those effects in the sNMR record. Finally, the complex FD signal is sensitive to dephasing of the sNMR record due to static magnetic field inhomogeneity. We illustrate the ability to detect dephasing in synthetic and field data and demonstrate an effective inversion which is able to solve for static dephasing effects. This results in better estimation of meaningful decay constants as well as reduced error in extrapolated initial signal amplitude. Both of these parameters are critical for using sNMR in applications requiring estimation of hydraulic parameters.
    Keywords: Geomagnetism, Rock Magnetism and Palaeomagnetism
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  • 117
    Publication Date: 2014-09-20
    Description: We report a palaeomagnetic investigation of the last full geomagnetic field reversal, the Matuyama-Brunhes (M-B) transition, as preserved in a continuous sequence of exposed lacustrine sediments in the Apennines of Central Italy. The palaeomagnetic record provides the most direct evidence for the tempo of transitional field behaviour yet obtained for the M-B transition. 40 Ar/ 39 Ar dating of tephra layers bracketing the M-B transition provides high-accuracy age constraints and indicates a mean sediment accumulation rate of about 0.2 mm yr –1 during the transition. Two relative palaeointensity (RPI) minima are present in the M-B transition. During the terminus of the upper RPI minimum, a directional change of about 180 ° occurred at an extremely fast rate, estimated to be less than 2 ° per year, with no intermediate virtual geomagnetic poles (VGPs) documented during the transit from the southern to northern hemisphere. Thus, the entry into the Brunhes Normal Chron as represented by the palaeomagnetic directions and VGPs developed in a time interval comparable to the duration of an average human life, which is an order of magnitude more rapid than suggested by current models. The reported investigation therefore provides high-resolution integrated palaeomagnetic and radioisotopic data that document the fine details of the anatomy and tempo of the M-B transition in Central Italy that in turn are crucial for a better understanding of Earth's magnetic field, and for the development of more sophisticated models that are able to describe its global structure and behaviour.
    Keywords: Geomagnetism, Rock Magnetism and Palaeomagnetism
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  • 118
    Publication Date: 2014-09-27
    Description: The anisotropy of magnetic susceptibility (AMS) of soft rocks was measured in order to distinguish between the effect of remote and local strain fields, determine the size of the related inelastic damage zone and resolve the fault-plane solutions of past earthquakes. The AMS fabrics were explored next to late Pleistocene syndepositional normal faults (total displacement up to ~3.5 m) that cross soft lacustrine rocks within the seismically active Dead Sea basin. ‘Deposition fabrics’ prevail meters away from the fault planes and are characterized by scattered maximum and intermediate principal AMS axes. ‘Deformation fabrics’ are detected up to tens of centimetres from the fault planes and are characterized by well-grouped AMS axes, in which one of the principal axes is parallel to the strike of the nearby fault. Variations in the AMS fabrics and magnetic lineations define the size of the inelastic damage zone around the faults. The results demonstrate that the deformation-driven magnetic fabrics and the associated inelastic damage zones are compatible with coseismic dynamic faulting and the effects of the local strain field during earthquakes. Most of the AMS fabrics show a conspicuous similarity to that of the fault-plane solutions, i.e., the principal AMS axes and instantaneous strain ellipsoids are coaxial. These results suggest a novel application of the AMS method for defining the shape and size of the damage zones surrounding dynamic faults and determining the full tensor of the local strain field.
    Keywords: Geomagnetism, Rock Magnetism and Palaeomagnetism
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  • 119
    Publication Date: 2014-09-25
    Description: Very low frequency (VLF) electromagnetic waves that penetrate conductive magma-filled dykes generate secondary fields on the surface that can be used to invert for dyke properties. The model used for the interpretation calculates currents induced in a conductive strip by an inducing field that decays exponentially with depth due to the conductivity of the surrounding medium. The differential equations are integrated to give an inhomogeneous Fredholm equation of the second kind with a kernel consisting of a modified Bessel function of the second kind. Numerical methods are typically used to solve for the induced currents in the strip. In this paper, we apply a modified Galerkin–Chebyshev method, which involves separating the kernel into source and field spectra and integrating the source terms to obtain a matrix equation for the unknown coefficients. The incident wave is expressed as a Chebyshev series. The modified Bessel function is separated into a logarithmic singularity and a non-singular remainder, both of which are expanded in complex Chebyshev polynomials. The Chebyshev coefficients for the remainder are evaluated using a fast Fourier transform, while the logarithmic term and incident field have analytic series. The deconvolution then involves a matrix inversion. The results depend on the ratio of strip-size to skin-depth. For infinite skin-depth and a singular conductivity distribution given by $\tau _0 a/\sqrt{a^2 - z^2 }$ (where 0 is the conductance, a is the half-length and z the distance from the centre), Parker gives an analytic solution. We present a similar analytic series solution for the finite skin-depth case, where the size to skin depth ratio is small. Results are presented for different ratios of size to skin depth that can be compared with numerical solutions. We compare full-space and half-space solutions. A fit of the model to VLF data taken above a magma filled dykes in Hawaii and Mt Etna demonstrates that while properties such as depth to top, conductivity ratio, tilt and dip can be determined, the depth to bottom is indeterminate due to the exponential decay of the inducing field.
    Keywords: Geomagnetism, Rock Magnetism and Palaeomagnetism
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  • 120
    Publication Date: 2014-09-25
    Description: Correlated data errors (noise) are common in magnetotelluric (MT) data, but MT inversions typically neglect error correlations without investigating the impact of this simplification on inversion results. This paper examines effects of neglecting frequency- and spatially correlated noise on MT inversion, based on a nonlinear Bayesian formulation which quantifies the uncertainties of inversion results in terms of marginal posterior probability densities and credibility intervals. To do so, data with frequency- and spatially correlated noise of differing degrees are generated for several layered (1-D) synthetic cases. Bayesian MT inversions are carried out for these data sets with and without accounting for error correlation (i.e. applying full and diagonal covariance matrices, respectively, in the inversion), and the results are compared. For cases with noise that is strongly correlated over frequency or space, parameter uncertainties estimated using the diagonal-covariance simplification (neglecting error correlations) are found to often be significantly underestimated compared with results computed using the full covariance matrix.
    Keywords: Geomagnetism, Rock Magnetism and Palaeomagnetism
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  • 121
    Publication Date: 2014-09-11
    Description: We report a new method to infer continuous time-series of the declination, inclination and intensity of the magnetic field from archaeomagnetic data. Adopting a Bayesian perspective, we need to specify a priori knowledge about the time evolution of the magnetic field. It consists in a time correlation function that we choose to be compatible with present knowledge about the geomagnetic time spectra. The results are presented as distributions of possible values for the declination, inclination or intensity. We find that the methodology can be adapted to account for the age uncertainties of archaeological artefacts and we use Markov chain Monte Carlo to explore the possible dates of observations. We apply the method to intensity data sets from Mari, Syria and to intensity and directional data sets from Paris, France. Our reconstructions display more rapid variations than previous studies and we find that the possible values of geomagnetic field elements are not necessarily normally distributed. Another output of the model is better age estimates of archaeological artefacts.
    Keywords: Geomagnetism, Rock Magnetism and Palaeomagnetism
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  • 122
    Publication Date: 2014-12-12
    Description: We present a rigorous method for interpolation of electric and magnetic fields close to an interface with a conductivity contrast. The method takes into account not only a well-known discontinuity in the normal electric field, but also discontinuity in all the normal derivatives of electric and magnetic tangential fields. The proposed method is applied to marine 3-D controlled-source electromagnetic modelling (CSEM) where sources and receivers are located close to the seafloor separating conductive seawater and resistive formation. For the finite-difference scheme based on the Yee grid, the new interpolation is demonstrated to be much more accurate than alternative methods (interpolation using nodes on one side of the interface or interpolation using nodes on both sides, but ignoring the derivative jumps). The rigorous interpolation can handle arbitrary orientation of interface with respect to the grid, which is demonstrated on a marine CSEM example with a dipping seafloor. The interpolation coefficients are computed by minimizing a misfit between values at the nearest nodes and linear expansions of the continuous field components in the coordinate system aligned with the interface. The proposed interpolation operators can handle either uniform or non-uniform grids and can be applied to interpolation for both sources and receivers.
    Keywords: Geomagnetism, Rock Magnetism and Palaeomagnetism
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  • 123
    Publication Date: 2014-12-17
    Description: According to field observations, electromagnetic (EM) signals accompanying seismic waves can be recorded. The orders of magnitude of observed coseismic electric and magnetic signals associated with earthquakes are usually around 1 to 10 1 mV km –1 and 10 –2 to 1 nT, respectively. In this paper, we carry out numerical simulation of coseismic EM signals associated with seismic waves due to electrokinetic effect and compare with field observations. The seismic source is represented by a finite fault measuring 15 x 9 km 2 with a max slip displacement 1.5 m, corresponding to a M w 5.9 earthquake. While using the EM surface boundary condition of continuous horizontal EM components, the magnetic signals only accompany the late-arriving S waves at receiver near the ground surface. This is obviously different from field observations. Thus, we adopt another EM surface boundary condition which assumes the ground surface carries surface charge. For the used half-space model, a surface-charge density magnitude | Q sc | in excess of 10 –4 C m –2 is sufficient to make horizontal magnetic components clearly show up at the whole time duration of seismic waves. When | Q sc | increases, the contribution of surface-charge density to coseismic EM signals becomes more and more dominant comparing with that of the seismically induced streaming-current. We estimate the Q sc expected at the Earth's surface might be a value between –5 x 10 –4 and –0.1 C m –2 by the comparison between numerical results and field observations. The vertical magnetic signals only accompany the late-arriving seismic waves, because they are theoretically only induced by SH wave. The field observation results of vertical magnetic signals may be resulted from the scattering effect or the seismic dynamo effect. We conclude that electrokinetic effect combined with surface-charge assumption is one possible generation mechanism of the observed coseismic EM signals.
    Keywords: Geomagnetism, Rock Magnetism and Palaeomagnetism
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  • 124
    Publication Date: 2014-12-21
    Description: Fifteen sites of lava flows from Martinique Island (FWI) have been selected to document the geomagnetic field in the Caribbean area over the past 2.5 Ma and further constrain the time-averaged field during this period. Identical characteristic directions were isolated using both AF and thermal stepwise demagnetization techniques in all flows. Nine mean-site directions have a normal polarity, while three others are reversed. The mean geomagnetic pole position obtained after reducing all directions to the same polarity is indistinguishable from the present north geographic pole. The dispersion is at least 8° larger than the values derived from the time-averaged field models and remains unexplained otherwise than resulting from the relatively small number of directions. The other three flows are characterized by large deviations from the expected north–south direction. One lava flow dated at 1.69 Ma (±0.02 Ma) is likely associated with a transitional field during the Gilsà subchron. The lava flow dated at 770 ka (±11 ka) coincides with the age of the Brunhes-Matuyama geomagnetic reversal and is also coeval with another intermediate flow of the same age found at Guadeloupe Island. The 617 ka (±52 ka) old unit is characterized by reversed directions that are evidently not related to the last reversal, but with other reversed polarity and transitional lava flows of the same age recorded, respectively at Mexico and La Palma island. We infer that the presence of reversed directions with the same age at distinct localities confirms that a short episode of reversed polarity has occurred during this period.
    Keywords: Geomagnetism, Rock Magnetism and Palaeomagnetism
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  • 125
    Publication Date: 2014-10-12
    Description: Presently, most loess/palaeosol magnetic susceptibility records are interpreted as following either the wind-vigour model or the pedogenic enhancement model. However redoxomorphic processes induced by waterlogging, often referred to gleying in the loess literature, are also known to alter loess deposits but their impact on loess/palaeosol magnetic susceptibility records has received little attention. The reported rock magnetic study aims to characterize the mineral magnetic response of loess to waterlogging-induced redoxomorphic processes, thus improving our understanding of mineral magnetic changes within loess deposits with respect to environmental and climate conditions. The Nussloch loess-palaeosol deposit (Rhine Valley, Germany) was targeted because it is one of the best-studied Pleniglacial deposits for Western Europe in which numerous tundra gley intervals have been identified. Moreover, a comprehensive high-resolution environmental magnetism study has never been undertaken for this site. Various rock magnetism experiments were conducted at both room and low temperatures to characterise the composition, concentration and relative magnetic grain size of the mineral magnetic assemblage. The relative changes in magnetic parameters within the investigated loess interval are primarily controlled by (1) varying concentrations of coarse-grained ferrimagnetic particles of detrital (aeolian) origin and (2) dissolution of fine-grained ferrimagnetic particles related to in situ post-depositional alteration promoted by waterlogging-induced redoxomorphic processes. Goethite is found to be ubiquitous throughout the studied interval and is argued to have both a primary (aeolian) and secondary ( in situ ) origin. We conclude, that redoxomorphic processes induced by waterlogging, if present, will hinder the interpretation of magnetic susceptibility variations within loess and palaeosol deposits following the expected relationships dictated by the wind-vigour and the pedogenic enhancement magnetism models.
    Keywords: Geomagnetism, Rock Magnetism and Palaeomagnetism
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  • 126
    Publication Date: 2014-10-12
    Description: Palaeosecular variation (PSV), as estimated from the scatter of remanent magnetization directions or poles, can be used to shed light to processes in the geodynamo, and potentially, to model the growth of the solid inner core. To understand the temporal aspects of the geomagnetic field behavior in the far past, we have calculated the scatter of palaeomagnetic poles (S) from a set of 55 high-quality observations derived from a new Precambrian paleomagnetic data compilation. Our analysis supports former Phanerozoic and Precambrian analyses of PSV, which favour a lower reversal rate, a higher stability of the geodynamo and a substantially smaller size of the inner core prior to 1.5 billion years ago.
    Keywords: Geomagnetism, Rock Magnetism and Palaeomagnetism
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  • 127
    Publication Date: 2014-10-12
    Description: A palaeomagnetic study has been carried out in 29 cores drilled at six different sites from the volcanic products of Lomo Negro eruption (El Hierro, Canary Islands, Spain). Systematic thermal and alternating field demagnetization of the samples’ natural remanent magnetization revealed a northward, stable palaeomagnetic direction similar in all the samples. Rock magnetic experiments indicate that this palaeomagnetic component is carried by a mixture of high-Ti and low-Ti titanomagnetite crystals typical of basaltic lithologies that have experienced a significant degree of oxyexsolution during subaerial cooling. The well constrained palaeomagnetic direction of Lomo Negro lavas was used to perform a palaeomagnetic dating of the volcanic event, using the SHA.DIF.14k global geomagnetic model restricted for the last 3000 yr. It can be unambiguously concluded that Lomo Negro eruption occurred well before the previously proposed date of 1793 AD, with three different age ranges being statistically possible during the last 3 ka: 115 BC-7 AD, 410–626 AD and 1499–1602 AD. The calibration of a previously published non-calibrated 14 C dating suggests a XVI c. date for Lomo Negro eruption. This conclusion leaves open the possibility that the seismic crisis occurred at El Hierro in 1793 AD was related to an intrusive magmatic event that either did not reach the surface or either culminated in an unregistered submarine eruption similar to the one occurred in 2011–2012 at the southern off-shore ridge of the island.
    Keywords: Geomagnetism, Rock Magnetism and Palaeomagnetism
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  • 128
    Publication Date: 2014-10-16
    Description: We have performed an extended palaeomagnetic study of the Oslo Graben volcanics, compared to the study of half a century ago by van Everdingen, using modern techniques and a four times larger amount of sites, plus additional rock magnetic experiments. We conclude that the average direction ( D = 204.0, I = –37.9, k = 46.9, α 95 = 2.0) and associated palaeomagnetic pole ( = 48.3, = 155.5, K = 52.2, A 95 = 1.9) of the Krokskogen and Vestfold volcanics together are statistically identical to those of the earlier study. This gives confidence in the fact that older palaeomagnetic studies can be reliable and robust, even though methods have improved. Our larger number of samples, and better age constraints, enable us to separate the data into two major intervals: the younger, on average, Krokskogen area and the older Vestfold area. The results show firstly that palaeolatitudes are slightly higher than predicted by the latest apparent polar wander path (APWP) for Eurasia by Torsvik et al. These data support an early Permian Pangaea A configuration and do not necessitate a Pangaea B configuration. The larger data set also allows us to assess the distribution of the characteristic remanent magnetization directions of the Oslo Graben in terms of geomagnetic field behaviour, which were acquired during a long period of dominantly single polarity the Permo-Carboniferous Reversed Superchron (PCRS). The distributions show a significantly lower virtual geomagnetic pole (VGP) scatter at the observed (low) latitudes than expected from a compilation from lavas of the last 5 Myr. The data do however show excellent agreement with the scatter observed both during the Cretaceous Normal Superchron and the PCRS. A comparison of the directional distributions in terms of elongation is less discriminating, since the large errors in all cases allow a fit to the predicted elongation/inclination behaviour of the TK03.GAD model.
    Keywords: Geomagnetism, Rock Magnetism and Palaeomagnetism
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  • 129
    Publication Date: 2014-10-17
    Description: We illustrate a new imaging method to estimate the depth to the sources of potential fields and the structural index. The method consists of applying the Depth from EXtreme Point (DEXP) transformation to the ratio (R) between two different-order partial derivatives of the field. While the scaling function of the potential field depends on the structural index, we show that the scaling function of R merely depends on the difference between the two used orders of differentiation. This allows three main features to be established for the DEXP transformation of R: (1) it is independent from the structural index; (2) the estimation of the source depths is fully automatic, simply consisting in the search of position of the extreme points of the DEXP image and (3) the structural index of each source is finally determined from the scaling function or the extreme points using the estimated depth. Besides the well-known characteristics of the DEXP transformation, such as high-resolution and stability, the DEXP transformation of R enjoys one more relevant feature: it can be applied to multisource cases, yielding simultaneously correct estimations of structural index and depth for each source in the same image. However, while the DEXP transformation is a linear transformation of the field, the DEXP transformation of R is non-linear, and a procedure is described to circumvent the non-linear effects. The method is tested with synthetic examples and the estimated source parameters show a good agreement with the true values. The method was applied also to real magnetic data from the Pima copper mine, Arizona, USA, Hamrawien area, Egypt and Cataldere, Bala district of Turkey. The results are consistent with the known information about the causative sources.
    Keywords: Geomagnetism, Rock Magnetism and Palaeomagnetism
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  • 130
    Publication Date: 2014-10-17
    Description: Variational data assimilation (4DVar) is a powerful technique for tuning dynamic models to observations, in order not only to forecast future time evolution of the system, but to make inferences about quantities that are otherwise unconstrained by observation. We apply this technique, well-grounded in meteorology and oceanography, to the Earth's core where incompressible fluid motions in an electrically conducting medium are responsible for magnetic field generation. Our dynamic model's momentum equation neglects inertia such that the entire evolution depends only on the structure of the initial magnetic field; time evolution of the system is solely governed by the equation of magnetic induction. Nevertheless the dynamic system encompasses the effects of rotation, Lorentz forces and viscosity and aims to mimic a reasonable force-balance in the Earth's core. Building on the work of Li et al. , in order to optimize the data-fit subject to the dynamics, we further develop the mathematical structure of the adjoint equations of the system. We address the feasibility of recovering 3-D spatial properties of the system using only time-varying 2-D observations of different character. Using closed-loop testing, we demonstrate the retrievability of the initial state (and thus the entire trajectory) of the system over convective timescales, when sampling in regions in which magnetic induction dominates over diffusion. The results suggest the possibility of retrieving the entire trajectory of the dynamo system of the Earth using the 400-yr model of secular variation gufm1 .
    Keywords: Geomagnetism, Rock Magnetism and Palaeomagnetism
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  • 131
    Publication Date: 2014-10-19
    Description: We investigate polarity reversals in the geodynamo using a rotating, convection-driven dynamo model. As the flow in rapidly rotating convection is dominated by columns aligned with the axis of rotation, the focus is on the dynamics of columnar vortices. By studying the growth of a seed magnetic field to a stable axial dipole field, we show that the magnetic field acts in ways that significantly enhance the relative helicity between cyclonic and anticyclonic vortices. This flow asymmetry is the hallmark of a dipolar dynamo. Strong buoyancy, on the other hand, offsets the effect of the magnetic field, establishing parity between positive and negative vortices. As the dipole field is deprived of the helicity required to support itself, the dynamo is pushed into a reversing state. This is a likely regime for polarity reversals in the Earth's core. The integral lengthscale at which buoyancy injects energy is not significantly different from the convective flow lengthscale, which implies that buoyancy does not feed vortices at the small scales where non-linear inertia is present. The lengthscale at which the Lorentz force acts in the reversing dynamo is small, which may allow the passive presence of non-linear inertia in the small scales.
    Keywords: Geomagnetism, Rock Magnetism and Palaeomagnetism
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  • 132
    Publication Date: 2014-06-21
    Description: A new methodology to estimate magnetotelluric (MT) tensor relationships, called Estimation of Local transfer-functIons by Combining Interstation Transfer-functions (ELICIT), is proposed whereby the MT tensor relationships of the local site are derived using only interstation transfer functions. The MT impedance tensor and the geomagnetic transfer function at the local site are characterised by combining interstation tensor relationships between electric and magnetic fields at the local site with the horizontal magnetic fields acquired at a neighbouring site. The main property of the proposed method is that the employed interstation transfer functions are independently constrained, without the need to acquire the electric and the magnetic fields at the local site simultaneously to recover the local MT tensor relationships. Due to this property, the ELICIT method offers new possibilities for MT data acquisition and processing, providing significant improvements when the magnetic time-series at the local site are affected by local noise or are truncated. Error analysis shows that, even when magnetic fields are truncated, the quality of the results obtained following the ELICIT method are similar to those we would obtain if the magnetic fields had not been truncated. Another important property is that different neighbouring sites can be used to recover the tensor relationships at the local site. Averaging of results obtained using different neighbouring sites can be performed to improve the statistics. For our example data, when the ELICIT method is used to improve the statistics, errors of the estimates for periods between 1000 and 20 000 s periodicities are clearly reduced. All interstation transfer functions are calculated doing remote reference and the bootstrap method is used to compute the errors, when necessary. Long period magnetotelluric data acquired in the Pyrenees and in the Atlas Mountains in Morocco, and magnetic data provided by Fürstenfeldbruck magnetic observatory have been used to test the proposed ELICIT method, with positive results. Due to the lack of requirement that the electric and the magnetic fields of the local site be acquired simultaneously, the proposed method also offers new possibilities for MT data acquisition, optimizing the available instrumentation.
    Keywords: Geomagnetism, Rock Magnetism and Palaeomagnetism
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  • 133
    Publication Date: 2014-06-21
    Description: The robust statistical model of a Gaussian core contaminated by outlying data that underlies robust estimation of the magnetotelluric (MT) response function has been re-examined. The residuals from robust estimators are systematically long tailed compared to a distribution based on the Gaussian, and hence are inconsistent with the robust model. Instead, MT data are pervasively described by the alpha stable distribution family whose variance and sometimes mean are undefined. A maximum likelihood estimator (MLE) that exploits the stable nature of MT data is formulated, and its two-stage implementation in which stable parameters are first fit to the data and then the MT responses are solved for is described. The MLE is shown to be inherently robust, but differs from the conventional robust estimator because it is based on a model derived from the data, while robust estimators are ad hoc , being based on the robust model that is inconsistent with actual data. Propriety versus impropriety of the complex MT response was investigated, and a likelihood ratio test for propriety and its null distribution was established. The Cramér-Rao lower bounds for the covariance matrix of proper and improper MT responses were specified. The MLE was applied to exemplar long period and broad-band data sets from South Africa. Both are shown to be significantly stably distributed using the Kolmogorov–Smirnov goodness of fit and Ansari-Bradley non-parametric dispersion tests. Impropriety of the MT responses at both sites is pervasive, hence the improper Cramér-Rao bound was used to estimate the MLE covariance. The MLE is shown to be nearly unbiased and well described by a Gaussian distribution based on bootstrap simulation. The MLE was compared to a conventional robust estimator, establishing that the standard errors of the former are systematically smaller than for the latter and that the standardized differences between them exhibit excursions that are both too frequent and too large to be described by a Gaussian model. This is ascribed to pervasive bias of the robust estimator that is to some degree obscured by their systematically large confidence bounds. Finally, a series of topics for further investigation is proposed.
    Keywords: Geomagnetism, Rock Magnetism and Palaeomagnetism
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  • 134
    Publication Date: 2014-06-22
    Description: Broad-band and long period magnetotelluric (MT) data were acquired at 39 stations along five NNW-SSE profiles crossing the Iapetus Suture Zone (ISZ) in Ireland. Regional strike analyses indicate that the vast majority of the MT data is consistent with an assumption of a 2-D geo-electric strike direction. Strike is N52°E for the three easternmost profiles and N75°E for the two westernmost profiles; these directions correlate well with the observed predominant geological strike of the study region. 2-D inversions of the galvanic distortion-corrected TE and TM mode data from each profile are shown and discussed. As mapped geological variations between the neighbouring profiles suggest a heterogeneous subsurface, it is important to verify the robustness of the presence and geometries of prominent conductivity anomalies by employing 3-D forward and inverse modelling. A high conductivity layer (resistivity of 1–10 m), found at middle to lower crustal depths and presumed to be indicative of metamorphosed graphitic sediments rich in sulphides deposited during the convergence of the Laurentian and Avalonian continents, essentially constitutes the electrical signature of the ISZ. Shallow conductors observed are probably due to black shales that were widely deposited within the sedimentary accretionary wedge during Ordovician time. We interpret the moderately low resistivity at shallow depths from west to east across Ireland as indicative of an increase in maturity of the black shales in the easterly direction. From our conductivity models the southern extent of the ISZ is inferred to lie between the Navan Silvermines Fault and the Navan Tipperary Line, and shows clear resistivity contrast along all the profiles at the southern MT stations. The change in resistivity deduced from the 2-D models is spatially related to the composition of Lower Palaeozoic Ordovician, Silurian, Devonian and Carboniferous rocks. At upper mantle depths of about 60 km, a high conductivity block below the central MT stations is found to lie within the accretionary wedge of the Iapetus suture, and the location of the conductive anomaly corroborates reasonably well with the inferred spreading head of the putative Iceland plume-related magmatic intrusion. The low resistivity upper crust beneath the ISZ is indeed rich in Ordovician rocks with black shale content in the eastern as well as the central part; the western part is largely underlain by a highly resistive block of volcanic and metamorphosed rocks forming crystalline basement.
    Keywords: Geomagnetism, Rock Magnetism and Palaeomagnetism
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  • 135
    Publication Date: 2014-07-03
    Description: This paper presents new directional archeomagnetic data from nine Meso-/Neolithic fireplaces, sampled in a cave shelter, at Arconciel, in western Switzerland. Rock magnetic measurements indicate a homogenous magnetic mineralogy in all fireplaces, with magnetite as the main magnetic carrier. The remanent magnetization is stable and generally shows one characteristic directional component. Nine new directions, which were obtained from Arconciel, are combined with 356 other archeomagnetic data from a circular area with a radius of 700 km around this site, to obtain a penalized least square spline fit for the past 9000 yr. We found in general good agreement with other local compilations, such as the Balkan curve, the regional SCHA.DIF.8k model and with lake sediments from UK, Fennoscandia and Switzerland. Nevertheless, a time lag of several centuries is observed for a declination maximum between the archeomagnetic spline fit and the other European data records around 5900 BC. This time lag is also observed in the Swiss lake sediment record; therefore we interpret this shift as a local feature of the Earth's magnetic field.
    Keywords: Geomagnetism, Rock Magnetism and Palaeomagnetism
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  • 136
    Publication Date: 2014-06-21
    Description: In Christian religion the sunrise is of great symbolic importance. Therefore, many churches constructed in the Middle Ages point towards geographic East. Although ‘easting’ of churches actually refers to the alignment towards the azimuth of sunrise on the individual churches’ patron's day, deviation of nave alignment from the geographic East direction is often assumed to be caused by the use of magnetic compasses. Therefore, the church alignment could provide information about historical magnetic declination. We investigate 124 churches in Lower Austria and 68 in northern Germany to clarify this question as well as the ‘easting’ hypothesis. Church orientations are determined from georeferenced satellite images. Metadata such as the construction year, possible reconstructions and the church patron are gathered to determine the date when current church direction was appointed, and to perform sunrise calculations. However, due to uncertainties of construction years and the declining importance of orientation tradition after the 15th century several churches are excluded from the study. Thus, 32 churches with reliable metadata remain for evaluation in each region. The analysis reveals a preferred alignment of naves towards geographic East in Lower Austria and northern Germany. The construction and alignment of churches was often affected by the pre-existing buildings and streets or topography and natural surroundings. Therefore, deviations from geographic East are more likely caused by town or landscape. The mean deviations from magnetic East in both regions are large compared to the mean deviations from geographic East and sunrise azimuths. Hence, the use of compasses cannot be confirmed. Despite a few churches indicating orientation according to their patron's day, a general trend cannot be observed in the data reviewed.
    Keywords: Geomagnetism, Rock Magnetism and Palaeomagnetism
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  • 137
    Publication Date: 2014-06-21
    Description: A new finite difference solution to the global geomagnetic induction problem is developed and tested, based on a modified Lorenz gauge of the magnetic vector and electric scalar potentials and implementing a novel, overset ‘Yin-Yang’ grid that avoids unnecessary mesh refinement at the geographic poles. Previously used in whole-earth mantle convection models, the overset grid is built from a pair of partially overlapping mid-latitude latitude–longitude (lat/lon) grids, one of which is rotated with respect to the other for complete coverage of the sphere. Because of this symmetry, only one set of finite difference templates is required for global discretization of the governing Maxwell equations, a redundancy that is exploited for computational efficiency and multithreaded parallelization. Comparisons between solutions obtained by the proposed method show excellent agreement with those obtained by independent integral equation methods for 1-D, 2-D and 3-D problem geometries. The computational footprint of the method is minimized through a (non-symmetric) matrix-free BiCG-STAB iterative solver which computes finite difference matrix coefficients ‘on the fly’ as needed, rather than pulling stored values from memory. Scaling of the matrix-free BiCG-STAB algorithm with problem size shows behaviour similar to that seen with the (symmetric) QMR algorithm used in the Cartesian case from which the present algorithm is based. The proposed method may therefore provide a competitive addition to the existing body of global-scale geomagnetic induction modelling algorithms, allowing for resource-efficient forward modelling as the kernel for large-scale computing such as inversion of geomagnetic response functions, computational hypothesis testing and parametric studies of mantle geodynamics and physiochemical state.
    Keywords: Geomagnetism, Rock Magnetism and Palaeomagnetism
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  • 138
    Publication Date: 2014-06-21
    Description: We present a robust and scalable solver for time-harmonic Maxwell's equations for problems with large conductivity contrasts, wide range of frequencies, stretched grids and locally refined meshes. The solver is part of the fully distributed adaptive 3-D electromagnetic modelling scheme which employs the finite element method and unstructured non-conforming hexahedral meshes for spatial discretization using the open-source software deal.II. We use the complex-valued electric field formulation and split it into two real-valued equations for which we utilize an optimal block-diagonal pre-conditioner. Application of this pre-conditioner requires the solution of two smaller real-valued symmetric problems. We solve them by using either a direct solver or the conjugate gradient method pre-conditioned with the recently introduced auxiliary space technique. The auxiliary space pre-conditioner reformulates the original problem in form of several simpler ones, which are then solved using highly efficient algebraic multigrid methods. In this paper, we consider the magnetotelluric case and verify our numerical scheme by using COMMEMI 3-D models. Afterwards, we run a series of numerical experiments and demonstrate that the solver converges in a small number of iterations for a wide frequency range and variable problem sizes. The number of iterations is independent of the problem size, but exhibits a mild dependency on frequency. To test the stability of the method on locally refined meshes, we have implemented a residual-based a posteriori error estimator and compared it with uniform mesh refinement for problems up to 200 million unknowns. We test the scalability of the most time consuming parts of our code and show that they fulfill the strong scaling assumption as long as each MPI process possesses enough degrees of freedom to alleviate communication overburden. Finally, we refer back to a direct solver-based pre-conditioner and analyse its complexity in time. The results show that for multiple right-hand sides the direct solver-based pre-conditioner can still be faster for problems of medium size. On the other hand, it also shows non-linear growth in memory, whereas the auxiliary space method increases only linearly.
    Keywords: Geomagnetism, Rock Magnetism and Palaeomagnetism
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  • 139
    Publication Date: 2014-06-21
    Description: The configuration of the Pangea supercontinent has been a topic of intense debate for almost half a century, a controversy that stems from discrepancies between the geology-based Pangea-A and the palaeomagnetically based Pangea-B. Recent palaeomagnetic compilations aimed at resolving this controversy have identified the poor quality of palaeomagnetic data from Gondwana for Permian times as a major obstacle. Specifically, the vast majority of Gondwanan poles come from sedimentary rocks that are prone to biases from compaction or are poorly dated. Here, we present a new palaeomagnetic pole for cratonic South America based on impact melts from the 254.7 ± 2.5 Ma Araguainha impact structure (AIS). The granite basement, the impact-generated melt sheet and veins were sampled at 28 sites (169 specimens) and provided a reliable palaeomagnetic record similar to that of volcanic rocks. Alternating field and thermal demagnetization indicate a stable characteristic remanent magnetization carried by both magnetite and haematite. All sites but one show a single palaeomagnetic direction of normal polarity with a mean direction of Dec = 357.4°; Inc = –38.9°; N  = 28; k  = 62.35; α 95  = 3.5°, yielding a palaeomagnetic pole (AIS) at Lat = –84.2; Lon = 326.6; K  = 83.5; A 95  = 3.6°; S B  = 9.6°. The new pole provides a firm constraint on the position of Gondwana which is consistent with the Pangea A configuration.
    Keywords: Geomagnetism, Rock Magnetism and Palaeomagnetism
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  • 140
    Publication Date: 2014-06-21
    Description: Reconstructions of the Holocene geomagnetic field and how it varies on millennial timescales are important for understanding processes in the core but may also be used to study long-term solar-terrestrial relationships and as relative dating tools for geological and archaeological archives. Here, we present a new family of spherical harmonic geomagnetic field models spanning the past 9000 yr based on magnetic field directions and intensity stored in archaeological artefacts, igneous rocks and sediment records. A new modelling strategy introduces alternative data treatments with a focus on extracting more information from sedimentary data. To reduce the influence of a few individual records all sedimentary data are resampled in 50-yr bins, which also means that more weight is given to archaeomagnetic data during the inversion. The sedimentary declination data are treated as relative values and adjusted iteratively based on prior information. Finally, an alternative way of treating the sediment data chronologies has enabled us to both assess the likely range of age uncertainties, often up to and possibly exceeding 500 yr and adjust the timescale of each record based on comparisons with predictions from a preliminary model. As a result of the data adjustments, power has been shifted from quadrupole and octupole to higher degrees compared with previous Holocene geomagnetic field models. We find evidence for dominantly westward drift of northern high latitude high intensity flux patches at the core mantle boundary for the last 4000 yr. The new models also show intermittent occurrence of reversed flux at the edge of or inside the inner core tangent cylinder, possibly originating from the equator.
    Keywords: Geomagnetism, Rock Magnetism and Palaeomagnetism
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  • 141
    Publication Date: 2014-06-21
    Description: Several recent studies have used palaeomagnetic estimates of the virtual axial dipole moment to construct a quantitative stochastic model for fluctuations and reversals in the Earth's dipole field. We investigate the physical significance of the terms in a standard stochastic (Langevin) model using output from a numerical geodynamo model. The first term, known as the drift term, characterizes the slow adjustment of the dipole field toward a time-averaged state. We find that the timescale for this slow adjustment is set by the magnetic decay time of dipole fluctuations. These fluctuations are typically be represented by the first few decay modes. The second term is often called the noise term because it characterizes the influence of short-period convective fluctuations in the core. We establish a connection between the noise term and the rms variation in magnetic induction. Applying these results to the palaeomagnetic field suggests that the rms variation in dipole generation exceeds the mean rate of generation. Such large fluctuations may be necessary to permit magnetic reversals. Palaeomagnetic estimates of the drift term favour a high electrical conductivity in the core. A lower bound on electrical conductivity is 0.6 x 10 6 S m –1 . Similarly, we establish an upper bound on turbulent magnetic diffusivity (0.8 m 2 s –1 ), although realistic estimates may be much less.
    Keywords: Geomagnetism, Rock Magnetism and Palaeomagnetism
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  • 142
    Publication Date: 2014-12-19
    Description: We demonstrate that first differences of polar orbiting satellite magnetic data in the along-track direction can be used to obtain high resolution models of the lithospheric field. Along-track differences approximate the north–south magnetic field gradients for non-polar latitudes. In a test case, using 2 yr of low altitude data from the CHAMP satellite, we show that use of along-track differences of vector field data results in an enhanced recovery of the small scale lithospheric field, compared to the use of the vector field data themselves. We show that the along-track technique performs especially well in the estimation of near zonal spherical harmonic coefficients. Moreover, lithospheric field models determined using along-track differences are found to be less sensitive to the presence of unmodelled external field contributions and problems associated with the polar gap are ameliorated. Experiments in modelling the Earth's lithospheric magnetic field with along-track differences are presented here as a proof of concept. We anticipate that use of such along-track differences in combination with east–west field differences, as are now provided by the Swarm satellite constellation, will be important in building the next generation of lithospheric field models.
    Keywords: Geomagnetism, Rock Magnetism and Palaeomagnetism
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  • 143
    Publication Date: 2014-12-23
    Description: We develop an singular value decomposition-based compression of the Green's function matrix of an electromagnetic integral equation forward solver for global geomagnetic induction, on top of an fast Fourier transform reduction of the system to a block-diagonal form. With this approach, the memory usage and CPU time of Krylov subspace iterative solutions are significantly reduced at a very small cost of accuracy, making the accelerated forward solver well suited for 3-D inversions as well as forward simulations with multiple sources.
    Keywords: Geomagnetism, Rock Magnetism and Palaeomagnetism
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  • 144
    Publication Date: 2014-12-25
    Description: The Fisher distribution is central to palaeomagnetism but presents several problems when used to characterize geomagnetic field directions as observed in sequences of volcanic rocks. First, it introduces a shallowing effect when used to define the mean of any group of directional unit vectors. This is problematic because it can suggest the presence of persistent non-axial dipole components when none are present. More importantly, it fails to capture the observed ‘long tail’ in distributions of both directions and associated virtual geomagnetic poles in terms of angular distance from a central direction. To achieve a good fit to data, it therefore requires the introduction of a second distribution (and therefore the estimation of additional parameters) or the arbitrary removal of data. Here we present a new distribution to describe palaeomagnetic directions and demonstrate that it overcomes both of these problems, generating robust indicators of both the central direction (or pole position) and the spread of palaeomagnetic data as defined by unit vectors. Starting from the assumption that poles (or directions) have an expected colatitude, rather than a mean location, we derive the spherical exponential distribution. We demonstrate that this new distribution provides a good fit to palaeomagnetic data sets from seven large igneous provinces between 15 and 65 Ma and also those produced by numerical dynamo models. We also use it to derive a new shape parameter which may be used as a diagnostic tool for testing goodness of fit of models to data and use this to argue for a shift in geomagnetic behaviour between 5 and 15 Ma. Furthermore, we point out that this new statistic can be used to determine the most appropriate distribution to be used when constructing confidence limits for poles.
    Keywords: Geomagnetism, Rock Magnetism and Palaeomagnetism
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  • 145
    Publication Date: 2014-08-30
    Description: Haematite pigment is a common constituent of sedimentary rocks, but its contribution to the natural remanent magnetization of rocks is poorly understood. Here, we describe magnetic properties of two distinct pigment types that produce a characteristic decorative ‘print stone’ found in the ~2.5 Ga Mount McRae Shale Formation, Hamersley Province, Western Australia. Distinct magnetic remanence directions observed in the Print Stone can be correlated to each pigment type. By comparison with the Australian apparent polar wander path, the remanence carried by uniformly distributed pigment can be dated to ~15–25 Ma, while two age options, the Mesoproterozoic (~1.5 Ga) or the middle Carboniferous (~320–310 Ma), are permissible for the remanence carried by the pigment responsible for the distinctive ‘newsprint’ pattern. Magnetic properties and demagnetization characteristics of the different pigment types overlap significantly, and thus are not predictive of the dominant remanence carrier. Magnetic characteristics of the uniformly distributed pigment vary significantly on short spatial scales. Strong local control on pigment formation raises the possibility that a primary remanent magnetization may survive locally in pockets within sedimentary red bed formations.
    Keywords: Geomagnetism, Rock Magnetism and Palaeomagnetism
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  • 146
    Publication Date: 2014-09-01
    Description: Remanent magnetizations of magnetites between single-domain (SD) threshold size (0.1 μm) and 20 μm have SD-like intensities and coercivities. This paper shows for the first time that magnetite's induced magnetization also has pseudo-single-domain behaviour. The first part of the paper reports temperature-dependent initial susceptibility data, k 0 ( T ), of sized magnetites and assesses their granulometric potential. The second part transforms coercive force data, H c ( T ), for the same magnetites into simulated k 0 ( T ) curves. The third part considers k 0 ( T ) results of coarse-grained mafic rocks as candidate sources of deep-seated magnetic anomalies. High-temperature susceptibility k 0 measured with a Kappabridge for eight fractions of crushed natural magnetites (median sizes of 0.6, 1, 3, 6, 9, 14, 110 and 135 μm) shows a progressive increase in the height of the Hopkinson peak below the Curie point as grain size decreases. The trend is systematic and has granulometric potential in the 1–14 μm range. Self-demagnetization should produce almost flat k 0 ( T ) in grains larger than SD size but experimentally, well-defined Hopkinson peaks are not limited to the finest grains. 1-μm magnetites have a peak 1.5 times k 0 at 20 °C and 14-μm grains have a peak of 1.25. Only 110 and 135 μm grains have T -independent k 0 . Using an empirical relationship between coercive force H c and k 0 , H c ( T ) data for the sized magnetites were used to simulate k 0 ( T ) results. A hump in the k 0 heating curve around 250 °C was traced to annealing out internal strains, evident in H c data measured in first heatings. For sizes ≤6 μm, observed Hopkinson peaks were smaller than predicted, possibly because of a previously unrecognized grain-size dependence of the empirical constant relating H c and k 0 . Two crystalline rocks, a gabbro and a diabase, combine SD-like Hopkinson peaks and multidomain (MD) flat ramps in their k 0 ( T ) data. In the diabase, a Hopkinson peak is prominent in separated plagioclase grains containing submicron magnetite, but is masked in whole-rock data. The gabbro has a clear superposition of SD and MD k 0 ( T ) functions in its whole-rock data, with a Hopkinson peak of 1.35. If oceanic layer-3 gabbros have similar susceptibility enhancement above 500 °C, they could be more important magnetic anomaly sources than room-temperature k 0 measurements on dredged or fault-uplifted samples would suggest.
    Keywords: Geomagnetism, Rock Magnetism and Palaeomagnetism
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  • 147
    Publication Date: 2014-08-20
    Description: We investigate the influence of different thermal and velocity boundary conditions on numerical geodynamo models. We concentrate on the implications for magnetic field morphology, heat transport scaling laws, force balances and generation mechanisms. The field morphology most strongly depends on the local Rossby number, but there is some variation in the dipolarity of the field with boundary condition. Scaling laws also depend on the boundary conditions, but a diffusivity-free scaling is a good first order approximation for all our dipolar models. Our multipolar models, however, obey different scaling laws from dipolar models implying a different force balance in these models. We find that our dipolar models have a stronger degree of Lorentz–Coriolis balance compared to our multipolar models which have a stronger degree of Lorentz-inertial balance.The models with a stronger Lorentz–Coriolis dominance can be generated by either α, α 2 or α 2 mechanisms whereas the models with a stronger Lorentz-inertial balance are all α 2 dynamos. These results imply that some caution is necessary when extrapolating results from dynamo models to Earth-like parameters since the choice of boundary conditions can have important effects.
    Keywords: Geomagnetism, Rock Magnetism and Palaeomagnetism
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  • 148
    Publication Date: 2014-07-20
    Keywords: Geomagnetism, Rock Magnetism and Palaeomagnetism
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  • 149
    Publication Date: 2014-06-22
    Description: Lake sediments are excellent sources of palaeoenvironmental and palaeoclimatic information because they provide continuous and high-resolution records. South America is of particular interest because it is the only landmass that stretches southward into the Pacific and Atlantic Oceans towards Antarctica. The aim of this study is to explore the relationship of magnetic parameters with elemental and palaeobiological data of Laguna Potrok Aike to develop a model of lake-level changes and related hydrological and climatic fluctuations. Magnetic measurements were performed on subsamples from 15 500 cal. BP to the present, and associated rock magnetic parameters were calculated to infer magnetic mineralogy, concentration and grain size. According to the model, parameters dependent on magnetic concentration and grain size are directly related to lake-level changes. During dry periods, the remanent coercivity displays high values, whereas the proportion of magnetite is relatively low. Low percentages of greigite are observed, indicating that the water of the lake was stratified at least four times during the studied period, at approximately 10 300, 8900, 8500 and 8300 cal. BP. The preservation of greigite by inhibiting its complete transformation into pyrite is associated with a rapid burial that occurs with high sedimentation rates. Thermal stratification could be caused by a slight cooling in the area triggered by a weakening of the Westerlies and/or low activity of the sun, sum to the effect of a flood of melt water in the North Atlantic.
    Keywords: Geomagnetism, Rock Magnetism and Palaeomagnetism
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  • 150
    Publication Date: 2014-06-28
    Description: Measurement of magnetic vector or tensor quantities, namely of field or field gradient, delivers more details of the underlying geological setting in geomagnetic prospection than a scalar measurement of a single component or of the scalar total magnetic intensity. Currently, highest measurement resolutions are achievable with superconducting quantum interference device (SQUID)-based systems. Due to technological limitations, it is necessary to suppress the parasitic magnetic field response from the SQUID gradiometer signals, which are a superposition of one tensor component and all three orthogonal magnetic field components. This in turn requires an accurate estimation of the local magnetic field. Such a measurement can itself be achieved via three additional orthogonal SQUID reference magnetometers. It is the calibration of such a SQUID reference vector magnetometer system that is the subject of this paper. A number of vector magnetometer calibration methods are described in the literature. We present two methods that we have implemented and compared, for their suitability of rapid data processing and integration into a full tensor magnetic gradiometry, SQUID-based, system. We conclude that the calibration routines must necessarily model fabrication misalignments, field offset and scale factors, and include comparison with a reference magnetic field. In order to enable fast processing on site, the software must be able to function as a stand-alone toolbox.
    Keywords: Geomagnetism, Rock Magnetism and Palaeomagnetism
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  • 151
    Publication Date: 2014-06-28
    Description: Motional induction in the ocean by tides has long been observed by both land and satellite measurements of magnetic fields. While these signals are weak (~10 nT) when compared to the main magnetic field, their persistent nature makes them important for consideration during geomagnetic field modelling. Previous studies have reported several discrepancies between observations and numerical predictions of the tidal magnetic signals and those studies were inconclusive of the source of the error. We address this issue by (1) analysing magnetometer data from ocean-bottom stations, where the low-noise and high-signal environment is most suitable for detecting the weak tidal magnetic signals, (2) by numerically predicting the magnetic field with a spatial resolution that is 16 times higher than the previous studies and (3) by using four different models of upper-mantle conductivity. We use vector magnetic data from six ocean-bottom electromagnetic (OBEM) stations located in the Northwestern Pacific Ocean. The OBEM tidal amplitudes were derived using an iteratively re-weighted least-squares (IRLS) method and by limiting the analysis of lunar semidiurnal (M2), lunar elliptic semidinurnal (N2) and diurnal (O1) tidal modes to the night-time. Using a 3-D electromagnetic induction solver and the TPX07.2 tidal model, we predict the tidal magnetic signal. We use earth models with non-uniform oceans and four 1-D mantle sections underneath taken from Kuvshinov and Olsen, Shimizu et al. and Baba et al. to compare the effect of upper-mantle conductivity. We find that in general, the predictions and observations match within 10–70 per cent across all the stations for each of the tidal modes. The median normalized percent difference (NPD) between observed and predicted amplitudes for the tidal modes M2, N2 and O1 were 15 per cent, 47 per cent and 98 per cent, respectively, for all the stations and models. At the majority of stations, and for each of the tidal modes, the higher resolution (0.25° 0.25°) modelling gave amplitudes consistently closer to the observations than the lower resolution (1° 1°) modelling. The difference in lithospheric resistance east and west of the Izu–Bonin trench system seems to be affecting the model response and observations in the O1 tidal mode. This response is not seen in the M2 and N2 modes, thereby indicating that the O1 mode is more sensitive to lithospheric resistance.
    Keywords: Geomagnetism, Rock Magnetism and Palaeomagnetism
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  • 152
    Publication Date: 2014-07-23
    Description: Magnetotelluric observations over one or 2-D structures that are distorted by 3-D electro-galvanic effects, need to be corrected for their proper conversion into reliable images of the subsurface electrical resistivity distribution. One of the most widely used approaches for correcting the data is the Groom–Bailey decomposition of the impedance tensor in terms of the unknown parameters of strike, twist and shear, along with the also unknown 2-D impedances. The standard approach for recovering the 2-D impedances is to solve numerically for all the unknowns as a non-linear inverse problem. In this work, we pose the recovery of the undistorted impedances in terms of a quadratic equation whose solutions filter out the distortions after a final tune for the appropriate shear parameter. The formula relies on two known invariants of the impedance tensor, the series and parallel invariants that have special immunity to some of the distorting parameters. Compared with the standard numerical recovery, the analytical solution provides more accurate results; they are clear-cut for both amplitudes and phases. The recovered amplitudes of the impedance are independent of strike, twist and shear, and the phases, in addition, of static effects. The recovery formula is transparent to random noise; hence the data preserve the original uncertainties. The applications to individual soundings of the COPROD2S1 data set and to a profile over a seismogenic region in Baja California, illustrate the effectiveness of the approach.
    Keywords: Geomagnetism, Rock Magnetism and Palaeomagnetism
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  • 153
    Publication Date: 2014-07-29
    Description: Great progress has been made in the numerical simulation of planetary dynamos, though these numerical experiments still operate in a regime very far from the planets. For example, it seems unlikely that viscous forces are at all significant in planetary interiors, yet some of the simulations display a significant dependence on viscosity, and indeed in some of the simulations the dynamo mechanism is itself viscously driven, taking the form of helical Ekman pumping within columnar convection rolls. Given the similarity of the external magnetic fields observed in the terrestrial planets and gas giants, and the extremely small value of the Ekman number in all such cases, it seems natural to suppose that the underlying dynamo mechanism in these planets is simple, robust, independent of viscosity and insensitive to mechanical boundary conditions. A key step to identifying this mechanism is to determine the source of helicity in planetary cores, which itself should be robust, independent of viscosity and insensitive to boundary conditions. In this paper, we explore the possibility that the helicity in the core of the Earth arises from the spontaneous emission of inertial waves, driven by the equatorial heat flux in the outer core. We also ask if a similar mechanism might operate in other planets, and perhaps act to supplement the helicity driven by Ekman pumping in the (viscous) numerical simulations. We demonstrate that such waves do indeed produce the required helicity distribution outside the tangent cylinder. Moreover, we show that these waves inevitably propagate along the axis of the columnar vortices, and indeed they are the very mechanism by which the columnar vortices form in the first place and the means by which the columns subsequently evolve. We also calculate the emf induced by such axially propagating inertial waves and show that, in principle, this emf is sufficient to support a self-sustaining dynamo of the α 2 type. Finally, we derive the scaling laws for this kind of inertial-wave dynamo. We compare these predictions with the (imperfect) simulations, and also with what little we know about the Earth's core. The numerical experiments fall into two categories; the slowly rotating simulations which cannot sustain inertial waves at the small scales and the rapidly rotating (planet-like) ones which can. Our scaling laws are consistent with the latter class of simulations, and also with what we know about the Earth.
    Keywords: Geomagnetism, Rock Magnetism and Palaeomagnetism
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  • 154
    Publication Date: 2014-07-26
    Description: The main sources of magnetic minerals in soils unaffected by anthropogenic pollution are iron oxides and hydroxides derived from parent materials through soil formation processes. Soil magnetic minerals can be used as indicators of environmental factors including soil forming processes, degree of pedogenesis, weathering processes and biological activities. In this study measurements of magnetic susceptibility are used to detect the presence and the concentration of soil magnetic minerals in topsoil and bulk samples in a small cultivated field, which forms a hydrological unit that can be considered to be representative of the rainfed agroecosystems of Mediterranean mountain environments. Additional magnetic studies such as isothermal remanent magnetization (IRM), anhysteretic remanent magnetization (ARM) and thermomagnetic measurements are used to identify and characterize the magnetic mineralogy of soil minerals. The objectives were to analyse the spatial variability of the magnetic parameters to assess whether topographic factors, soil redistribution processes, and soil properties such as soil texture, organic matter and carbonate contents analysed in this study, are related to the spatial distribution pattern of magnetic properties. The medians of mass specific magnetic susceptibility at low frequency ( lf ) were 36.0 and 31.1 10 –8 m 3 kg –1 in bulk and topsoil samples respectively. High correlation coefficients were found between the lf in topsoil and bulk core samples ( r  = 0.951, p  〈 0.01). In addition, volumetric magnetic susceptibility was measured in situ in the field ( is ) and values varied from 13.3 to 64.0 10 –5 SI. High correlation coefficients were found between lf in topsoil measured in the laboratory and volumetric magnetic susceptibility field measurements ( r  = 0.894, p  〈 0.01). The results obtained from magnetic studies such as IRM, ARM and thermomagnetic measurements show the presence of magnetite, which is the predominant magnetic carrier, and hematite. The predominance of superparamagnetic minerals in upper soil layers suggests enrichment in pedogenic minerals. The finer soil particles, the organic matter content and the magnetic susceptibility values are statistically correlated and their spatial variability is related to similar physical processes. Runoff redistributes soil components including magnetic minerals and exports fine particles out the field. This research contributed to further knowledge on the application of soil magnetic properties to derive useful information on soil processes in Mediterranean cultivated soils.
    Keywords: Geomagnetism, Rock Magnetism and Palaeomagnetism
    Print ISSN: 0956-540X
    Electronic ISSN: 1365-246X
    Topics: Geosciences
    Published by Oxford University Press on behalf of The Deutsche Geophysikalische Gesellschaft (DGG) and the Royal Astronomical Society (RAS).
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  • 155
    Publication Date: 2014-06-28
    Description: State of the art numerical models of the Geodynamo are still performed in a parameter regime extremely remote from the values relevant to the physics of the Earth's core. In order to establish a connection between dynamo modelling and the geophysical motivation, it is necessary to use scaling laws. Such scaling laws establish the dependence of essential quantities (such as the magnetic field strength) on measured or controlled quantities. They allow for a direct confrontation of advanced models with geophysical constraints. We combine a numerical approach, based on a multiple linear regression method in the form of power laws, applied to a database of 102 direct numerical simulations (courtesy of U. Christensen), and a physical approach, based on energetics and forces balances. We show that previous empirical scaling laws for the magnetic field strength essentially reflect the statistical balance between energy production and dissipation for saturated dynamos. Such power based scaling laws are thus necessarily valid for any dynamo in statistical equilibrium and applicable to any numerical model, irrespectively of the dynamo mechanism. We show that direct numerical fits can provide contradictory results owing to biases in the parameters space covered in the numerics and to the role of a priori hypothesis on the fraction of ohmic dissipation. We introduce predictive scaling laws, that is relations involving input parameters of the governing equations only. We guide our reasoning on physical considerations. We show that our predictive scaling laws can properly describe the numerical database and reflect the dominant forces balance at work in these numerical simulations. We highlight the dependence of the magnetic field strength on the rotation rate. Finally, our results stress that available numerical models operate in a viscous dynamical regime, which is not relevant to the Earth's core.
    Keywords: Geomagnetism, Rock Magnetism and Palaeomagnetism
    Print ISSN: 0956-540X
    Electronic ISSN: 1365-246X
    Topics: Geosciences
    Published by Oxford University Press on behalf of The Deutsche Geophysikalische Gesellschaft (DGG) and the Royal Astronomical Society (RAS).
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  • 156
    Publication Date: 2014-06-28
    Description: High-quality palaeomagnetic data for the early Carboniferous of Central Asia are scarce and the palaeogeographic evolution of this area prior to final amalgamation of the region east of the Ural mountains is still rather obscure. Here, we present palaeomagnetic data for early Carboniferous deposits from two areas in the Kyrgyz North Tianshan (NTS). Detailed rock-magnetic analysis indicates the presence of magnetite and haematite as magnetic carriers in these red sediments. In the Kazakh basin section (KEL), we identify a high-temperature component (HTC) of magnetization during stepwise thermal demagnetization at temperatures of up to ~680 °C yielding a site mean direction of D  = 176.2°, I  = –36.4°, k  = 57.4 and α 95  = 8.9° after tilt correction. Two HTCs of magnetization were identified in samples from the Sonkul Basin (DUN) with maximum blocking temperatures of ~600 °C (magnetite) and ~680 °C (haematite). The magnetite component was also identified with alternating field demagnetization. The resulting site mean directions for these two components identified in 16 and 14 sites, respectively, are D  = 149.3°, I  = –50.3°, k  = 73.6 and α 95  = 4.3° for the magnetite and D  = 139.6°, I  = –35.1°, k  = 71.6 and α 95  = 4.7° for the haematite component. All three mean directions show a significant increase of the precision parameter k after tilt correction indicating acquisition of the high-temperature magnetization prior to the main folding event in the Jurassic. We explain the difference of the two components of DUN by a process of inclination bias due to compaction to which the platy haematite particles are more susceptible. Applying the elongation-inclination (E/I) method to directional data from over 100 individual samples from location DUN results in a negligible correction for the magnetite component (〈5°), whereas the inclination of the haematite component corrects from –35.0° to –50.3° ( f  = 0.6, error interval –41.4° to –57.9°), which is then equal to the uncorrected magnetite inclination. The small number of samples from section KEL does not allow application of the E/I technique and inclination correction based on high field anisotropy of isothermal remanent magnetization was applied, yielding a corrected inclination of –75.2° ± 4°. Assuming comparable degrees of compaction for both study areas and applying the flattening factor obtained in DUN on samples from KEL, however, would result in comparable inclinations. The identification of inclination shallowing at both sections indicates that the age of magnetization is close to the deposition age. Assuming a reversed polarity of the directions from both areas results in palaeolatitudes of ~30°N for section DUN and ~60°N for the anisotropy-based correction of section KEL. The large difference, however, is geologically very unlikely. The inclination of the magnetite component of DUN (unaffected by inclination shallowing) favours a palaeoposition of ~30°N. This is supported by the inclination shallowing corrected haematite component of DUN yielding a comparable inclination. Therefore, our results indicate that the NTS domain was situated at ~30°N in the early Carboniferous. Furthermore, the NTS zone was probably not connected to Baltica or Siberia prior to the late Palaeozoic.
    Keywords: Geomagnetism, Rock Magnetism and Palaeomagnetism
    Print ISSN: 0956-540X
    Electronic ISSN: 1365-246X
    Topics: Geosciences
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  • 157
    Publication Date: 2014-06-30
    Description: An exploratory 3-D model of the electrical conductivity structure of the Australian continent is presented. The model is derived from the inversion of vertical magnetic-field transfer functions from the Australia-wide Array of Geomagnetic Stations. Crustal conductivity anomalies evident in the model are consistent with those previously mapped by independent magnetometer array studies and new electrical structures are suggested in the upper mantle. The model represents a seamless continent-scale basis for further models likely to be derived from subsequent studies. The model reveals three upper-mantle enhanced-conductivity anomalies beneath Archaean cratonic regions and two upper-mantle anomalies beneath Phanerozoic terranes in eastern Australia. Two of these anomalies have been investigated by recent magnetotelluric (MT) surveys, one in the Yilgarn Craton–Officer Basin–Musgrave Block the other in the Gawler Craton region, and are consistent with the MT results. Across much of central Australia enhanced conductivity at depths of 50–100 km is observed in the model. This region corresponds well with a recognized seismic velocity gradient at 75–100 km. Conductivity differences are also observed beneath Archaean cratons in Western Australia. The Pilbara Craton is represented as an enhanced conductivity anomaly at about 100 km, corresponding well with the lower-velocity anomaly evident in surface wave tomography models. The Yilgarn Craton is imaged as a low-conductivity body, with conductivity two orders of magnitude lower than the Pilbara Craton, continuing to greater depths.
    Keywords: Geomagnetism, Rock Magnetism and Palaeomagnetism
    Print ISSN: 0956-540X
    Electronic ISSN: 1365-246X
    Topics: Geosciences
    Published by Oxford University Press on behalf of The Deutsche Geophysikalische Gesellschaft (DGG) and the Royal Astronomical Society (RAS).
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  • 158
    Publication Date: 2014-06-30
    Description: This paper presents new directional archeomagnetic data from nine Meso-/Neolithic fireplaces, sampled in a cave shelter, at Arconciel, in western Switzerland. Rock magnetic measurements indicate a homogenous magnetic mineralogy in all fireplaces, with magnetite as the main magnetic carrier. The remanent magnetization is stable and generally shows one characteristic directional component. Nine new directions, which were obtained from Arconciel, are combined with 356 other archeomagnetic data from a circular area with a radius of 700 km around this site, to obtain a penalized least square spline fit for the past 9000 yr. We found in general good agreement with other local compilations, such as the Balkan curve, the regional SCHA.DIF.8k model and with lake sediments from UK, Fennoscandia and Switzerland. Nevertheless, a time lag of several centuries is observed for a declination maximum between the archeomagnetic spline fit and the other European data records around 5900 BC. This time lag is also observed in the Swiss lake sediment record; therefore we interpret this shift as a local feature of the Earth's magnetic field.
    Keywords: Geomagnetism, Rock Magnetism and Palaeomagnetism
    Print ISSN: 0956-540X
    Electronic ISSN: 1365-246X
    Topics: Geosciences
    Published by Oxford University Press on behalf of The Deutsche Geophysikalische Gesellschaft (DGG) and the Royal Astronomical Society (RAS).
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  • 159
    facet.materialart.
    Unknown
    Oxford University Press
    Publication Date: 2014-06-30
    Description: We present a new approach for 2-D magnetotelluric forward numerical modelling in contrast to traditional numerical methods like finite elements or finite differences. The method used for solving the partial differential equations is based on a mesh-free technique which does not need an underlaying mesh or grid. We use the Meshless Local Petrov–Galerkin (MLPG) method in combination with radial basis functions to simulate the response of a given conductivity model to a plane-wave source. We compare the mesh-free solution with known simulation programs and simple analytical solutions. Furthermore, we discuss the new magnetotelluric modelling method in terms of implementation and stability. First, we study the convergence and discretization errors of the new method with a simple half-space conductivity model. Then we compare our mesh-free simulation results with simple 2-D conductivity models with the results of a well-known finite element program. In the end, we provide a smooth conductivity model calculated with the mesh-free approach. The modelling results, even with randomly distributed nodes, are in a good agreement with those obtained by the finite element method.
    Keywords: Geomagnetism, Rock Magnetism and Palaeomagnetism
    Print ISSN: 0956-540X
    Electronic ISSN: 1365-246X
    Topics: Geosciences
    Published by Oxford University Press on behalf of The Deutsche Geophysikalische Gesellschaft (DGG) and the Royal Astronomical Society (RAS).
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  • 160
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    Materialwissenschaft und Werkstofftechnik 29 (1998) 
    ISSN: 0933-5137
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics
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  • 161
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    Materialwissenschaft und Werkstofftechnik 29 (1998), S. 153-153 
    ISSN: 0933-5137
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics
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  • 162
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    Materialwissenschaft und Werkstofftechnik 29 (1998), S. A21 
    ISSN: 0933-5137
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics
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  • 163
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    Materialwissenschaft und Werkstofftechnik 29 (1998), S. 51-56 
    ISSN: 0933-5137
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics
    Description / Table of Contents: Application of Wear Resistant PACVD-Coatings in Aluminium Diecasting under Economical and Ecological AspectsAluminium pressure diecasting is a frequently applied manufacturing process for the near netshape production of precision parts. State of the art production techniques still demand considerable amounts of die lubricants. But the side effects of these lubricants include a decrease in surface quality of the cast part as well as a prolongation of the casting cycle time. The job quality decreases and the waste and exhaust disposal during production and application of lubricants is ecologically risky. In this study different wear resistant coating systems have been developed in order to minimize the use of die lubricants in the casting process while at the same time increasing the service life of the diecasting tools.Nitrides, carbides and borides of titanium were synthesized by means of DC-pulse-PACVD. The influence of the process parameters gas composition, pressure, voltage and pulse/pulse repetition ratio was investigated. Compositional analysis was performed by analytical methods such as XRD, EDS, WDS and SIMS. Hardness, adhesion and friction behaviour of the layers were determined in order to describe their mechanical properties. The wetting angle was determined and the corrosion resistance was evaluated in dip tests in aluminium melt. A selection of the best coatings was then compared in diecasting praxis tests under tightened-up conditions reducing the amount of lubricants.TiN, Ti(B,N), TiC and multilayers of the system Ti-C-N were deposited exhibiting a wide range of stoichiometry. The coatings reached hardness values of up to 4400 HK0.005 and the friction coefficient μ was in the range of 0.3. In the diecasting praxis test the amount of die lubricant could be reduced by 97%. Under most severe conditions all layer types led to a minimum increase in the lifetime of the tool of factor 60 compared to an untreated dummy. A strong dependence on the layer type and on its stoichiometry could be observed. Ti(B,N) as the most successful coating in this study has not yet shown any sign of failure and already achieved an increase in lifetime of 300 times.
    Notes: Der heutige Stand der Technik in Aluminiumdruckguß erfordert den Einsatz von Formtrennmitteln. Zu deren Nebenwirkungen gehört aber eine Verschlechterung der Oberflächenqualität des Gußteils. Formtrennmittel beeinträchtigen die Arbeitsplatzqualität und sind unter ökologischen Gesichtspunkten als bedenklich zu betrachten. Um den Einsatz von Trennmitteln zu vermeiden und gleichzeitig die Standzeit der Druckgußwerkzeuge zu erhöhen, wurden nitridische, karbidische und boridische Schichten auf Titanbasis mittels DC-Plus-PACVD abgeschieden und im Hinblick auf ihren Einsatz im Aluminiumdruckguß optimiert. Durch die Beschichtung konnte bei gleichzeitiger Steigerung der Qualität der abgegossenen Teile die notwendige Trennmittelmenge um 97% reduziert werden. Die Standzeit der beschichteten Druckgußkerne im Vergleich zu unbeschichteten erhöhte sich durch die Beschichtung um über das 300-fache.
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  • 164
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    Materialwissenschaft und Werkstofftechnik 29 (1998), S. 77-79 
    ISSN: 0933-5137
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics
    Description / Table of Contents: Über die Sinterung mit festen EinlagerungenDas Sintern von porösen Matrixwerkstoffen mit steifen, im speziellen nicht verdichtenden Einlagerungsphasen wird mit Hilfe des sphärischen Verbundwerkstoff-Modells von Scherer diskutiert. Ein neuer Zusammenhang zur Berechnung der Verdichtungsdichte des Verbundwerkstoffs unter Berücksichtigung der durch die nicht-verdichtenden Einlagerungen hervorgerufenen Eigenspannungen, wird vorgeschlagen. Drei Komponenten der Dehnungsrate werden betrachtet: (i) die freie, von den vorhandenen Spannungen unabhängige Verdichtungs-Dehnungsrate, (ii) die sich aus den mikroskopischen Spannungseffekten bei den Sintermechanismen ergebende Dehnungsrate und (iii) die aus der Spannung resultierende makroskopische Dehnungsrate. Die Ergebnisse deuten darauf hin, dass bei steifen Einlagerungen höhere innere Spannungen entstehen, als mit dem originalen Modell von Scherer berechnet.
    Notes: The sintering of porous matrices containing rigid, i.e. non-densifying, inclusions is discussed on the basis of the composite sphere model of Scherer. Recognizing that internal stresses are generated by the presence of the non-densifying inclusions, a new equation for the densification rate of the composite is proposed. It takes into account three contributions: (i) the free densification strain rate, which is independent of the stresses present, (ii) the strain rate due to the microscopic effect of the stresses on the sintering mechanism and (iii) the macroscopic deformation strain rate induced by the stresses. This result indicates that the presence of rigid inclusions may generate higher internal stresses in the densify ing compact than those calculated by the original Scherer's approach.
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  • 165
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    Materialwissenschaft und Werkstofftechnik 29 (1998), S. A38 
    ISSN: 0933-5137
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics
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  • 166
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    Materialwissenschaft und Werkstofftechnik 29 (1998), S. 97-130 
    ISSN: 0933-5137
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics
    Description / Table of Contents: Valve Materials for Combustion EnginesAn overview is being given on production numbers, requirements and properties of valve materials. Their development from the beginning till today's state of the art is reviewed with a focus on Chromium-Manganese-Nitrogen-alloys. Valve materials are grouped by the criteria of density - heavy, lightweight - and alloying elements. The multiple stresses of the material in the valve are being met with a few standardised grades and specific ways of manufacture. The path of the material from bar stock to the finished valve is being followed. Engine development in the past decades increased the load on the valves which could be met by continuously developing their structural strength. Also the strength of all valve materials could be raised to nominal strength above 1100 Mpa by applying specific methods. Higher strength at the surface is being effectuated by work hardening effects. The technology to increase reliability of hollow valves and new aspects of valve seat facing including residual stress is explicitly discussed. General aspects of alloy utilisation is followed by a discussion of lightweight valve materials as Titanium alloys, intermetallic Titaniumaluminide alloys and ceramic materials, spec. Silicon Nitride, which all have a potential as forthcoming valve materials capable of reducing fuel consumption of the engines.
    Notes: Nach einem Überblick über Produktionszahlen, allgemeine Anforderungen und Eigenschaften von Ventilen für Verbrennungsmotoren, wird in einem Rückblick die Werkstoffentwicklung für die Ventilstähle von den ersten Anfängen bis zum heutigen Stand aufgezeigt. Schwerpunktmäßig wird die Gruppe der Chrom-Mangan-Stickstoff-Stähle behandelt. Daneben werden die Ventilwerkstoffe geordnet nach schweren und leichten und innerhalb dieser Gruppen nach Legierungsmerkmalen beschrieben. Es wird über die vielfältigen Werkstoffanstrengungen am Ventil informiert, die mit wenigen genormten Werkstoffgüten und speziellen Fertigungsverfahren problemlos mit niedrigsten Fehlerraten beherrscht werden. Der Weg des Werkstoffes vom Halbzeug bis zum fertigen Ventil wird in allen Schritten verfolgt. Die in den letzten Dekaden forcierte Motorenentwicklung führte zu verschärften Betriebsbedingungen auch für die Ventile, die mit einer kontinuierlichen Weiterentwicklung bestehender Werkstoffgüten und Verbesserungen der Gestaltsfestigkeit der Ventile aufgefangen wurden. In diesem Zusammenhang werden spezielle Lösungen zur Festigkeitssteigerung aller Ventilwerkstoffe bis in den Bereich von über 1100 MPa erläutert, die nach bekannten metallkundlichen Gesetzen ermöglicht wurden. Als wesentliches Prinzip werden ortsabhängig, besonders an der Oberfläche, erhöhte Festigkeits- und Verschleißeigenschaften zur Optimierung der Gestalts- und Betriebsfestigkeit eingesetzt. Über Entwicklungen zur Technologie der Hohlventile und von erweiterten Lösungen beim Auftragschweißen von Ventilsitzen im Zusammenhang mit Eigenspannungen wird ausführlich berichtet. Einer kurzen allgemeinen Betrachtung zum Legierungsaufwand der wichtigsten Ventilwerkstoffe folgt ein Kapitel über Titan, Intermetallische Verbindungen und Keramik, die möglicherweise als zukünftige leichte Ventilwerkstoffe Verwendung finden können.
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  • 167
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    Materialwissenschaft und Werkstofftechnik 29 (1998), S. 141-152 
    ISSN: 0933-5137
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics
    Description / Table of Contents: Hartstoffschichten auf Leichtmetall-Komponenten unter mechanischer OberflächenbeanspruchungIn der vorliegenden Studie wurde das Verhalten von hartstoffbeschichteten Leichtmetallkomponenten unter mechanischer Oberflächenbeanspruchung untersucht. Hierzu wurden drei Leichtmetallegierungen (Ti-6Al-4V, A1Si7Mg und AlMgSi0.5) sowie 100Cr6 - Stahl (als Vergleichsmaterial) mit zwei unterschiedlichen PVD-Verfahren beschichtet: radio frequency magnetron sputtering und electron beam evaporation. Als Schichtmaterialien wurden CrN und TiN verwendet. Um die verschiedenen Substrat/Schicht-Kombinationen hinsichtlich ihres Belastungsvermögens zu beurteilen, wurden Standard-Testmethoden angewendet, die jeweils eine andere Lastsituation simulieren: der Härtetest (der eine statische Normalkraft aufbringt), der Ritztest (der eine statische Normalkraft mit einer statischen Tangentialkraft überlagert) und der Impacttest (der eine dynamische Normalkraft aufbringt).Es wurde beobachtet, daß das Belastungsvermögen beschichteter Materialien von der vorherrschenden Lastsituation abhängt. Die beschichteten Aluminiumlegierungen wiesen unter allen getesteten Lastsituationen ein geringes Belastungsvermögen auf. Allerdings zeigten sie eine höhere Oberflächenhärte als unbeschichteter Stahl. Beschichtetes Ti-6Al-4V wies ein hohes Belastungsvermögen auf, vergleichbar mit beschichtetem Stahl. Bei sämtlichen beschichteten Leichtmetallsubstraten war eine signifikante Verbesserung des Belastungsvermögens mit zunehmender Schichtdicke zu erkennen.An den Ergebnissen des Ritztests, welcher weitverbreitet zur Untersuchung der Haftung dünner Schichten eingesetzt wird, war auf den Aluminiumsubstraten ein sofortiger Durchbruch des Prüfdiamanten durch die Schichten zu beobachten. Es traten keinerlei Abplatzungen auf. Aufgrund dieses Verhaltens erscheint der Ritztest nicht geeignet, um die Schichthaftung auf Leichtmetallsubstraten zu untersuchen. Im Gegensatz dazu wies das Schadensbild des Impacttests auch auf den Aluminiumsubstraten Schichtabplatzungen auf, was auf dessen Eignung zur Beurteilung des Haftungsvermögens dünner Schichten auf sehr weichen Substraten schließen läßt.Die Studie zeigt, daß in bestimmten Anwendungsgebieten eine Substitution des Stahls durch hartstoffbeschichtete Leichtmetallegierungen möglich ist.
    Notes: In this work the behaviour of hard coated light-metal components was investigated when they are mechanically loaded. Three lightmetal alloys, Ti-6Al-4V, AlSi7Mg and AlMgSi0.5 and 100Cr6 steel (as a reference material) were coated by two different physical vapour deposition processes: radio frequency magnetron sputtering and electron beam evaporation. The coating materials utilised were CrN and TiN. Standard test methods with different loading conditions were used to evaluate the substrate/coating-combinations: the hardness test (applying a static normal load), the scratch test (applying a combination of a static normal and a static tangential force) and the impact test (applying a dynamic normal load).It was observed that the load support of coated materials depends on the loading conditions. The coated aluminium alloys showed poor load support under all loading test conditions but produced a higher surface hardness than uncoated steel. Coated Ti-6Al-4V showed very good load support properties, similar to coated steel. All coated light-metal substrates demonstrated significant improvement in load support behaviour with an increase in coating thickness.The results of the scratch test, which is commonly used to asses adhesion properties of thin coatings, showed an immediate indenter-breakthrough on the aluminium alloy substrates, but causing no coating delamination. Due to this behaviour, the scratch test is not suitable to evaluate adhesion properties on coated soft light-metals. Yet the impact test allowed assessment of coating delamination on the aluminium alloys, proving its usefulness for adhesion measurement even on soft substrates.The study indicates that substitution of steel with coated lightmetal alloys is a viable proposition for certain applications.
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    Materialwissenschaft und Werkstofftechnik 29 (1998), S. 154-162 
    ISSN: 0933-5137
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics
    Description / Table of Contents: A concept to describe the fatigue lifetime by using statistical methodsIn order to spend time and money, cyclic loading tests have been usually undertaken with a relative small number of specimens. On the other hand, it is well established that fatigue life data, i.e. the cycle number of crack initiation Ni as well as the cycle number of total failure Nf show a scatter for a given load level. Therefore, fatigue live predictions must be undertaken using statistical methods. In this case it has to be taken into account that the quantity Nf consists of two parts, i.e. crack initiation and propagation. The first one has to be calculated in a statistical manner, whereas the second one with deterministic methods. Therefore, a superposition of statistical and deterministic parts has to be taken into account. Up to now it was estimated that in all cases the failure results from the same damage mechanism. In this case a scatter of fatigue life may be described by the Weibull distribution and characterised by the location parameter and the Weibull exponent. By using the correct density function, all fatigue life data Ni can be plotted in a failure probability Pv(Ni) vs. Ni plot. In case of some Al-alloys no linear dependence between Pv and Ni has been found, indicating that more than one type of defect spectrum may initiate the failure. Indeed, in AlMgSi cold worked specimens two types of cracks, e.g. surface as well as corner cracks, have been found that initiate the failure of the specimens. If was possible to correlate each type of crack with an individual Weibull distribution. By using this procedure, fatigue life can be estimated better than before.
    Notes: Zur experimentellen Lebensdauervorhersage an bauteilnahen Proben werden Schwingfestigkeitsuntersuchungen üblicherweise aus Zeit- und Kostengründen mit einer relativ kleinen Anzahl von Proben durchgeführt. Andererseits ist auf einem vorgegebenen Lastniveau grundsätzlich mit einer Streuung der Versuchsergebnisse, d. h. der Anrißlastspielzahl Ni bzw. der Lastspielzahl bis zum Bruch Nf, Zu rechnen. Um Lebensdauervorhersagen auf statistischer Grundlage durchführen zu können, muß beim Merkmalswert Nf in Betracht gezogen werden, daß die Rißausbreitung im Gegensatz zur Rißbildung in vielen Fällen deterministisch bestimmbar ist. Es ist daher abzuschätzen, in wie weit dieser Beitrag die Streuung der Gesamtlebensdauer beeinflußt. Desweiteren wurde bislang vorausgesetzt, daß der Versagensmechanismus immer auf dem selben Schädigungstyp beruht. In diesem Fall kann die Lebensdauer z. B. mit einer zweiparametrigen Weibull-Verteilung durch Angabe des Streu-und Lageparameters statistisch beschrieben werden. Bei der Verwendung einer geeigneten Dichtefunktion lassen sich die Schwingspielzahlen über die Ausfallwahrscheinlichkeiten auftragen. Im Fall von Al-Basislegierungen hat sich gezeigt, daß diese Auftragung keinen linearen Zusammenhang mehr aufweist, was dafür sprechen könnte, daß mindestens zwei unterschiedliche Defektsorten die Anrißbildung im Bauteil einleiten. Dies konnte für AlMgSi-Bleche anhand von Bruchflächenanalysen direkt nachgewiesen werden. Dazu wurden Ermüdungsrisse klassiert, die sich entweder an den Probenkanten oder direkt an Kratzern der Walzhaut bildeten. Die zwei Ereignisse ließen sich bei sonst gleichbleibenden Versuchsbedingungen in einzelne Weibull-Verteilungen zerlegen. Damit läßt sich im Fall von bauteilnahen Proben die Lebensdauer für kleine Ausfallwahrscheinlichkeiten genauer abschätzen als dies bislang der Fall ist.
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    Materialwissenschaft und Werkstofftechnik 29 (1998), S. 206-214 
    ISSN: 0933-5137
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics
    Description / Table of Contents: The size effect on the fatigue properties of weldmentsConstant amplitude fatigue tests (R = - 1 and 0)have been carried out in order to investigate the influence of specimen size and manufacturing conditions on the high-cycle fatigue behaviour of large welded I-beams (web height 500 mm, total length 12 and 7 m respectively). The specimens contained transverse butt welds and longitudinal fillet welds, mainly produced by manual metal arc welding. The Δs̰-concept, as proposed in international standards for fatigue related design is supported by the test results as far as transverse butt welds or longitudinal fillet welds in large sections are concerned. The HCF-behaviour of butt joints in large sections, welded under site conditions, are reasonably covered by Eurocode 3 category 90. EC 3-Category 100 does not conservatively cover the HCF-behaviour of longitudinal fillet joints in large sections.
    Notes: Der Einfluß von Bauteilgröße und Fertigungsbedingungen auf die Ermüdungsfestigkeit von Stumpfstößen und Längskehlnähten wurde anhand von Einstufen-Wöhlerversuchen (R = - 1 und 0) mit großen geschweißten I-Blechträgern (Stelghöhe 500 mm, Länge 12 m bzw. 7 m) untersucht. Die Mehrzahl der Schweißnähte wurde im Lichtbogenhandschweißverfahren hergestellt. Das Konzept der Mittelspannungsunabhängigkeit der zulässigen Spannungen, das in den neueren Stahlbauvorschriften propagiert wird, wird für die Nahtformen Stumpfstoß und Längsnaht durch die Ergebnisse der Großbauteilversuche gestüzt. Das HCF-Verhalten von unter Baustellenbedingungen geschweißten Stumpfstößen in großen Bauteilen wird durch die Kerbfallklasse 90 im Eurocode 3 hinreichend abgedeckt. Die im Eurocode 3 für Längskehlnähte vorgesehene Kerbfallklasse 100 deckt die Versuchsergebnisse nicht vollständig ab.
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    Materialwissenschaft und Werkstofftechnik 29 (1998), S. A61 
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    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics
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    Materialwissenschaft und Werkstofftechnik 29 (1998), S. 424-443 
    ISSN: 0933-5137
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics
    Description / Table of Contents: Deficiency and Surplus of Electrons, a Possibility to explain the most different Phenomenons of Materials Science?The dream to explain all phenomenons with a few principles is very old. It has been tried to explain the transformation and the process of destruction with the help of binding ratios between the atoms at the example of iron, iron-alloys and iron-compounds. The binding ratios depend on the mode, the motion and the distribution of the atoms of a material, on the temperature, on the pressure and on the surrounding (mode, distribution and state of aggregate of the surrounding atoms and particles, redox-potential, fields…).The system „Material and surrounding“ is characterized by deficiency and surplus of electrons in a disequilibrium (in the material as well as in the surrounding). Regardless whether a system is in equilibrium or in disequilibrium, there is a steady exchange of electrons (and also of other particles) between material and surrounding. The ratio of binding electrons to non-binding electrons should be suitable for the characterization of the binding ratios in the material.An universal material testing system for material testing corresponding to load is suggested with the aim of estimation of endurance.The UMTS should allow a better valuation of materials and constructional elements and also a better material sampling and constructing corresponding to load on the basis of Load-Energy-Occurence-Graphs and data files as well as the guarantee of endurance of constructional elements, machines, cars, aircrafts as well as constructions.
    Notes: Der Traum, alle Erscheinungen mit wenigen Prinzipien erklären zu können, ist schon recht alt.Am Beispiel von Eisen, Eisenlegierungen und Eisenverbindungen wird versucht, die Modifikationswechsel, Umwandlungsvorgänge und den Zerstörungsprozeß mit den Bindungsverhältnissen zwischen den Atomen zu erklären. Die Bindungsverhältnissen hängen von der Art, Bewegung und Verteilung der Atome eines Stoffes, von der Temperatur, vom Druck und von der Umgebung (Art, Verteilung und Aggregatzustand der umgebenden Atome und Teilchen, Red-Ox-Potential, Felder…) ab.Das System „Stoff und Umgebung“ ist im Ungleichgewicht (sowohl im Stoff als auch in der Umgebung) durch Elektronenmangel bzw. -überschuß gekennzeichnet. Unabhängig davon, ob sich ein System im Gleichgewicht oder im Ungleichgewicht befindet, findet ein ständiger Austausch von Elektronen (und mit Sicherheit auch von anderen Teilchen) zwischen Stoff und Umgebung statt. Zur Charakterisierung der Bindungsverhältnisse im Stoff sollte das Verhältnis „Bindungselektronen zu nicht an der Bindung beteiligten Elektronen“ beitragen können.Ein universelles Werkstoffprüfsystem zur beanspruchungsgerechten Werkstoffprüfung mit dem Ziel der Lebensdauerabschätzung wird vorgeschlagen. Das UMTS sollte eine bessere Werkstoff- und Bauteilbewertung, eine verbesserte Werkstoffauswahl und ein beanspruchungsgerechtes Konstruieren auf der Grundlage von Belastungs-Energie-Ereignis-Schaubildern und -Dateien sowie die Übernahme von Lebensdauergarantien für Bauteile, Maschinen, Fahr- und Flugzeuge sowie Konstruktionen ermöglichen.
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    Materialwissenschaft und Werkstofftechnik 29 (1998), S. 48-50 
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    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
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    Materialwissenschaft und Werkstofftechnik 29 (1998), S. 50-50 
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    Keywords: Chemistry ; Polymer and Materials Science
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    Materialwissenschaft und Werkstofftechnik 29 (1998), S. 338-338 
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    Keywords: Chemistry ; Polymer and Materials Science
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  • 175
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    Materialwissenschaft und Werkstofftechnik 29 (1998), S. 365-370 
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    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics
    Notes: The corrosion inhibition of mild steel by some naturally occuring substance was evaluated in absence and presence of 600 and 1200 mg H2S/l in 3% NaCl aqueous solution and pH of 3 and temperature of 25 °C. These naturally occurring substance included the water extracts, coumarines and fatty matters extracts of some Egyptian plants. These plants included:(1) Nigella Sativa (Family Ranunculacease) (Extract (1), 2) Coriandrum Sativum (Family Umbelliferea) (Extract II), 3) Ricinus communis (Family Euphorbiaceae) (Extract III). The galvanostatic anodic and cathodic polarization measurements were used for studying the corrosion behavior of mild steel and evaluation of the percentage inhibition of the undertesting extracts of these three plants and also preparation of fatty matters and coumarin fractions were mentioned.
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    Materialwissenschaft und Werkstofftechnik 29 (1998), S. 397-411 
    ISSN: 0933-5137
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics
    Description / Table of Contents: Mechanische und Physikalische Eigenschaften von Vermiculargraphit - Gußeisen GGV
    Notes: The mechanical and physical properties of compacted graphite iron (CGI) have been studied. While it is known that CGI provides at least 70% higher tensile strength, 35% higher elastic modulus and 80% higher fatigue limits than conventional grey cast iron, the objective of this paper was to determine how the properties change with varying nodularity (graphite shape) and pearlite content. Tensile properties, hardness, damping capacity and thermal conductivity were determined over the range 0-90% nodularity and 25-100% pearlite. Compressive properties, wear resistance and fatigue behaviour of CGI are also reported upon. Of greatest importance is the influence of patches of flake graphite in predominantly CGI microstructures. As soon as flake patches appear, which can occur with a loss of as little as 0.001% active magnesium, the mechanical properties of CGI abruptly decrease by 25-40%. Proper foundry control technology and quality procedures are therefore required to ensure the reliable production of this improved material.
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    Materialwissenschaft und Werkstofftechnik 29 (1998), S. A1 
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    Keywords: Chemistry ; Polymer and Materials Science
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    Materialwissenschaft und Werkstofftechnik 29 (1998), S. 1-8 
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    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics
    Description / Table of Contents: Protective coating systems for fasteners in contact with light weight metalsA review of the recent use of fasteners for light weight alloys in automotive car production is given. Mechanical design, materials selection and protective coating concepts for Magnesium- and Aluminum-alloys are presented. The specific problems caused by galvanic corrosion are discussed by the use of electrochemical data of the protective coating systems on fasteners for joining Magnesium. Experience from outdoor exposure in automotive applications up to date are considered.
    Notes: Es wird ein Überblick über die derzeit im Kraftfahrzeugbau verwendeten Verschraubungselemente für Leichtmetallegierungen gegeben. Dabei werden konstruktive Auslegungen, Werkstoffauswahl und Beschichtungskonzepte für Magnesium- und Aluminiumlegierungen vorgestellt. Die spezielle Problematik der Kontaktkorrosion wird anhand elektrochemischer Messungen f ür verschiedene Beschichtungssysteme im Verbau mit Magnesium diskutiert. Bisherige Felderfahrungen im Automobilbereich fließen jeweils in die Betrachtungen mit ein.
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    Materialwissenschaft und Werkstofftechnik 29 (1998), S. 16-22 
    ISSN: 0933-5137
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics
    Description / Table of Contents: Activation energy of repeated carbide precipitation processes in steelsDispersion microstructures in steels can be formed from the martensitic condition by repeated precipitation and coarsening of M3C (or M6C) particles. The precipitation stage comprehends the nucleation and the growth of one particle generation according to r ∝ t1/2 (r - particle radius, t - time), and already after some minutes it turns into the dominating coarsening according to r ∝ t1/3 (OSTWALD-ripening). The coarsening of the first precipitated particle generation is superposed with the following precipitation of further generations. They can be proved by the coercive field strength, the yield strength, microstructural mean values from scanning electron micrographs and by hardness tests. The occurring maxima of precipitation allow the evaluation of the activation energy for the effective volume diffusion in the α - Fe phase. By including the electronegativity (after L. Pauling ) the covalent bond in the M3C phase is considered. With that is possible to attach the estimated activation energy to the main alloying (and diffusing) element and also to the total composition of the steel.
    Notes: Dispersionsgefüge in Stählen werden aus dem martensitischen Zustand durch wiederholte Ausscheidung und Vergröberung von M3C-Partikeln (oder M6C) gebildet. Das Ausscheidungsstadium umfaßt gemäß r ∝ t1/2 (r - Partikelradius, t - Zeit) die Keimbildung und das Wachstum einer Partikelgeneration und geht schon nach wenigen Minuten in die dominierende Vergröberung gemäß der OSTWALD-Reifung r ∝ t1/3 über. Die Vergröberung zuerst ausgeschiedener Partikelgenerationen überlagert sich mit der nachfolgenden Ausscheidung und Vergröberung weiterer Partikelgenerationen. Sie können mit Hilfe der Koerzitivfeldstärke, der unteren Streckgrenze, mit Gefügemittelwertsdaten rasterelektronenmikroskopischer Abbildungen des Dispersionsgefüges und durch Kleinlasthärteprüfungen nachgewiesen werden. Die auftretenden Ausscheidungsmaxima gestatten die Abschätzung der Aktivierungsenergie für die effektive Volumendiffusion in der α - Fe - Phase. Durch Einbeziehung der Elektronegativitätswerte (hier nach L. PAULING) wird die vorliegende kovalente Bindung der M3C-Partikel berücksichtigt. Durch sie ergibt sich eine Zuordnung der abgeschätzten Aktivierungsenergie zu dem Hauptlegierungselement und darüber hinaus zur Gesamtzusammensetzung eines Stahles.
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    Materialwissenschaft und Werkstofftechnik 29 (1998), S. A24 
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    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics
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    Materialwissenschaft und Werkstofftechnik 29 (1998), S. 57-65 
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    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics
    Description / Table of Contents: With TiN particles lasermodified Al2O3 ceramic under oscillating sliding contact at different humidities and temperaturesA slightly porous, commercially available alumina ceramic was surface modified up to 170 μm thickness by adding TiN particles. The multiphase surface structure of this laser treated ceramic consisted of about 12 vol.% TiN, 16 vol.% grain boundary phase and 72 vol.% Al2O3. Tribological tests on the modified ceramic and for reference also on a highly dense alumina and titania were carried out in oscillating sliding contact against Al2O3 balls. In these tests, the temperature of the specimens was varied between 28°C and 500°C. At room temperature the relative humidity of the surrounding air was changed between 3% and 70% and additional tests were run by using distilled water as interfacial medium. The resulting multiphase microstructure showed substantially reduced friction and wear at different temperatures and also above relative humidities of about 35% at room temperature compared with the highly dense, commercially available alumina.
    Notes: Über einen zweistufigen Laserprozeß wurde eine handelsübliche Al2O3-Keramik in einer Randschicht von 170 μm Dicke durch Einlagerung von TiN-Partikeln modifiziert. Das entstandene mehrphasige Gefüge setzte sich aus ca 12 Vol.-% TiN, 16 Vol.-% Korngrenzenphase und 72 Vol.-% Aluminiumoxid zusammen. Die tribologische Charakterisierung erfolgte im reversierenden, ungeschmierten Gleitkontakt gegen Al2O3-Gegenkörper. Variiert wurde die Versuchstemperatur zwischen 28°C und 500°C und die relative Luftfeuchte bei Raumtemperatur zwischen 3% und 70%. Zusätzlich wurden Versuche in destilliertem Wasser unter Mischreibung durchgeführt. Als Referenzmaterialien wurden je eine handelsübliche, dichte Al2O3-und TiO2-Keramik mit in die Untersuchungen einbezogen.Die durch Oberflächenmodifizierung entstandenen, mehrphasigen Gefüge zeigten in verschiedenen Temperaturbereichen deutlich reduzierte Reibungszahlen und Verschleißbeträge im Vergleich mit der hochdichten, monolithischen Al2O3-Referenzkeramik. Aus den Untersuchungen zum Einfluß der relativen Luftfeuchte (rF) folgte, daß sich die mit TiN-Partikeln modifizierte Al2O3-Keramik oberhalb von 35 % rF durch niedrigere und von der Feuchte unabhängige Reibungszahlen und Verschleißbeträge auszeichnete.
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    Materialwissenschaft und Werkstofftechnik 29 (1998), S. 594-594 
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    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics
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    Materialwissenschaft und Werkstofftechnik 29 (1998), S. 605-608 
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    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics
    Description / Table of Contents: Das Grenzflächenverhalten eines mit Stahlkörnern verfestigten Kupfer-Basis-VerbundwerkstoffesEs wird ein neuer, mit Körnern verstärkter, Guß-Verbundwerkstoff vorgestellt. Zur Verstärkung [VZE]dienen grobe Stahlkörner mit einem Durchmesser von 0.6 bis 1 mm in einer Matrix aus Zinnbronze. Der Verschleißwiderstand dieses Verbundwerkstoffes ist zehnmal besser als der der Matrix, die Zugfestigkeit erreicht einen dreifach höheren Wert. In der vorliegenden Veröffentlichung wird schwerpunktmäßig das Grenzflächenverhalten zwischen den Körnern und der Matrix beschrieben. Als Ergebnis wird die Bildung der Grenzfläche durch Diffusion von Eisen und Kupfer, die zu einer Verfestigung führt, beschrieben.
    Notes: A new type of grain reinforcing cast composite is introduced. The reinforcing component is the coarse steel grain (0.6∼1.0mmφ) with the matrix of tin bronze. The wearing resistance of this material is 10 times as much as the matrix and regarding the tensile strength, 3 times. In this paper, the interface behaviour between grains and the matrix is emphasised. The results show the formation of an interface layer, caused by the diffusion of Fe and Cu, which strengthens the bonding.
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    Materialwissenschaft und Werkstofftechnik 29 (1998), S. 595-604 
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    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics
    Description / Table of Contents: Survival Rate and Reliability of Ceramic Femoral Heads for Total Hip ArthroplastyFemoral heads and sockets made of alumina ceramics are successfully used in total hip replacement. The in vivo fracture rate of Biolox heads is lower than 0.02%. An extremely high load (e. g. accident) can initiate subcritical crack growth causing fracturing.107 retrieved Biolox heads were investigated. When measuring their fracture load no fatigue was detected. This result can be explained by the relation between crack velocity and stress intensity (v-K-diagram). The stress intensity of ceramic heads when loaded with standard conditions (e. g. walking, max. load 3 kN) is in the order of 0.6 MPa m1/2. Stress intensities like that are below alumina's fatigue limit KIo which is in the order on 1 MPa m1/2.Biolox alumina heads are examples for engineering ceramics that are reliable despite tensile stress over very long periods of time.
    Notes: Der totale Ersatz eines Hüftgelenkes mit Kugelköpfen und Pfannen aus Aluminiumoxidkeramik ist klinisch bewährt. Die in vivo Bruchrate eines Biolox Kugelkopfes liegt unter 0,02 %. Ausgelöst durch eine extrem hohe Belastung (z. B. Unfall) kann der Bruch nach unterkritischem Rißwachstum erfolgen.An 107 Biolox Explantaten wurde die Restfestigkeit bestimmt. Es konnte keine Materialermüdung nachgewiesen werden. Dies kann mit Hilfe des Zusammenhanges zwischen der Geschwindigkeit des Rißfortschritts und der Spannungsintensität (v-K-Diagramm)b erklärt werden. Normal belastete keramische Kugelköpfe (z. B. beim Gehen max. 3 kN) haben in vivo Spannungsintensitäten K1 von ca. 0,6 MPa m1/2. Hiermit befindet man sich mit der Spannungsintensität im Bereich unter der Ermüdungsgrenze KIo, für die ca. 1 MPa m1/2 abgeschätzt werden kann.Biolox Kugelköpfe sind ein Beispiel für den Einsatz von Keramik, die trotz Zugspannungen als Dauerbelastung und mit hohen Anforderungen an die Sicherheit über large Zeiten sicher im Einsatz sind.
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    Topics: Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics
    Description / Table of Contents: Differences in the cyclic deformation behaviour of quenched and tempered steel 42 CrMo 4 (AISI 4140) due to stress- and strain-controlCyclic stress-strain-curves and Manson-Coffin-plots of quenched and tempered steel 42 CrMo 4 (AISI 4140) strongly depend on whether they are determined under stress- or total-strain-control. At total-strain-controlled experiments, this is caused on the one hand by comparatively high initial stress-amplitudes which lead to distinctive cyclic worksoftening. On the other hand, the occurring differences in the evolution of inhomogeneous deformation patterns at both types of loading, which can be recorded by means of photoelasticity and microscopy, lead to differently distributed plastic deformations and to different integral values of plastic strain.
    Notes: Die bei nennspannungs- und totaldehnungskontrollierter Zug-Druck-Wechselverformung von vergütetem 42 CrMo 4 erhaltenen Zyklischen Spannungs-Dehnungs-kurven und Manson-Coffin-Auftragungen hängen stark von der Versuchsführung ab. Ursachen dafür sind einerseits die bei Totaldehnungskontrolle vergleichsweise großen Anfangsspannungsamplituden, die zu ausgeprägten Wechselentfestigungen führen. Andererseits bilden sich bei beiden Beanspruchungsarten, wie sich spannungsoptisch und lichtmikroskopisch nachweisen läßt, unterschiedliche inhomogene Deformationserscheinungen aus, die voneinander abweichende plastische Dehnungsverteilungen und integrale Dehnungswerte ergeben.
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    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics
    Description / Table of Contents: Stress-strain hysteresis measurements of cyclically loaded unidirectional SiC-short-fiber reinforced alkali-lime-silicate-glassFor the technical application of fiber reinforced glasses, the knowledge of their fatigue behavior is important. Therefore, AR-glass specimens and SiC-short-fiber reinforced glass-compound specimens were produced by extrusion and investigated in stress controlled cyclic 3-point bending tests. The cyclic deformation behavior was characterized and the failure mechanisms were evaluated as a function of stress amplitude, number of cycles and fiber volume fraction by hysteresis measurements and microscopical investigations of the specimens surfaces. Selected results are presented and discussed.
    Notes: Im Hinblick auf die technische Anwendung faserverstärkter Gläser ist die Kenntnis des Ermüdungsverhaltens dieser Werkstoffe eine unabdingbare Voraussetzung. Hierzu wurden AR-Glasproben sowie SiC-kurzfaserverstärkte AR-Glas-Verbundproben durch Strangpressen hergestellt und in spannungskontrollierten 3-Punkt-Biegeversuchen im Schwellbereich schwingend beansprucht. Die Charakterisierung des zyklischen Verformungsverhaltens und die Bewertung der Versagensmechanismen in Abhängigkeit von Beanspruchungsamplitude, Beanspruchungsdauer und Faservolumengehalt erfolgte mit Hilfe des Hysteresismeßverfahrens sowie lichtmikroskopischer Strukturuntersuchungen an den Probenoberflächen. Ausgewählte Versuchsergebnisse werden vorgestellt und diskutiert.
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    Materialwissenschaft und Werkstofftechnik 29 (1998) 
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    Keywords: Chemistry ; Polymer and Materials Science
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    Materialwissenschaft und Werkstofftechnik 29 (1998), S. 339-344 
    ISSN: 0933-5137
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics
    Description / Table of Contents: Zerstörungsfreie Zustandsermittlung von GasturbinenschaufelnDie Restlebensdauer von sich in Einsatz befindenden Gasturbinenschaufeln wird durch die Bestimmung von Gefügeveränderungen des Grundwerkstoffes während der Betriebszeit ermittelt. Da man versucht Turbinenschaufelstufen in kompletten Sätzen zu halten, ist die Zerstörungsfreie Untersuchung (ZfU) sehr attraktiv. Ziel dieser Untersuchung war es deshalb, die Möglichkeiten eines ZfU Verfahrens zur Bestimmung von Strukturveränderungen im Basismaterial zu bewerten.Das einstufige Oberflächenabdruckverfahren (kombiniert mit REM-Untersuchungen) zeigt sich als relativ einfaches Verfahren, das allen Anforderungen entspricht. Auf unbeschichteten Turbinenschaufeln ist dieses Verfahren direkt anwendbar. Um es auf beschichteten Turbinenschaufeln anzuwenden, muß die Beschichtung lokal entfernt werden.
    Notes: In order to determine the remaining life of service exposed turbine blades it is necessary to characterize the degeneration of the microstructure of the base metal during service. Since turbine blades of industrial gas turbines are kept in complete stages, non-destructive inspection (NDI) is very attractive. Hence the goal of the investigation reported here was to evaluate a NDI technique able to detect microstructural changes of the base metal. It was found that single-stage replication (in combination with investigation in a Scanning Electron Microscope) is a relatively simple technique that fulfils all requirements. This technique can be used in-situ on uncoated buckets. For coated turbine blades local removal of the coating is necessary to perform base metal replication.
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  • 189
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    Materialwissenschaft und Werkstofftechnik 29 (1998), S. A97 
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    Keywords: Chemistry ; Polymer and Materials Science
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    Materialwissenschaft und Werkstofftechnik 29 (1998), S. A77 
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    Keywords: Chemistry ; Polymer and Materials Science
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  • 191
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    Materialwissenschaft und Werkstofftechnik 29 (1998), S. 389-396 
    ISSN: 0933-5137
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics
    Description / Table of Contents: Plasma Pretreatment and Coating of Polymer Films. Part 3: Analysis of the Experimental Results and DiscussionThe food packaging industry demands cheap polymer films possessing a high barrier against permeation of gases, moisture and flavour. Candidates for the most successful materials fulfilling these requirements are vacuum web coated biaxial oriented polypropylene (BOPP) films containing a thin inorganic barrier layer. For a good adhesion of the barrier layer on the BOPP films, the polymer film must be pretreated. The industry uses the Corona atmosphere plasma. This work is separated in three parts. The first part describes the experimental setup and the properties of vacuum web coated layers on polymer films[1] The next part contains the results of the systematic modification of polymer surface by atmosphere and low pressure plasmas[2]. The influence of the surface properties on the final functionality of the coated films is given. In the last part, the discussion of the results of the first and second part reveals systematic relations between the production parameters of the high barrier films and their final functionality. These results firstly reveal the adhesion mechanism of the inorganic barrier layers of the polymer films and the necessary surface properties of the polymer films, in order to get cheap high barrier films by vacuum web coating.
    Notes: Die lebensmittelverpackende Industrie verlangt nach immer billigeren Kunststoffolien mit immer höheren Barrieren gegenüber Gasen, Wasserdampf und Aromastoffen. Ein sehr erfolgreicher Schritt, um diese Anforderungen zu erfüllen, besteht in der vakuumtechnischen Beschichtung mit dünnen anorganischen Schichten von biaxial orientierten Polypropylenfolien (BOPP). UM gute Haftungen der aufgedampften Aluminiumschichten zu erzielen, müssen die BOPP-Folie vorbehandelt werden. Industriell steht dafür das Corona-Atmosphärendruckplasma zur Verfügung. In dieser Arbeit aufgeteilt in drei Abschnitte wird zuerst der Versuchsaufbau und die Eigenschaften beschichteter Kunststoffolien allgemein dargestellt[1]. Im nächsten Schritt erfolgt die systematische Modifikation der Folienoberfläche mittels verschiedener Atmosphärendruck- und Niederdruckplasmen [2]. Die Plasmen werden mittels Langmuir-Sonde und Quadrupolmassenspektrometer charakterisiert. Nach Beschichtung der mittels verschiedener Plasmen modifizierten Kunststoffolien zeigen Haftung und Permeabilitätsmessungen den Einfluß der Vorbehandlung auf die Funktionalität der Folie/Schicht-Systeme. Im letzten Abschnitt werden aus den Ergebnissen der Analysen der unbeschichteten und beschichteten Folien systematische Zusammenhänge zwischen Herstellungsparametern und funktionellen Eigenschaften der beschichteten Folien hergestellt. Daraus lassen sich erstmals die zu einer guten Schichthaftung führenden Mechanismen aufzeigen und die notwendigen Oberflächeneigenschaften der unbeschichteten Folie identifizieren, so daß durch die vakuumtechnische Beschichtung preisgünstige Hochbarrierefolien produziert werden können.
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    Materialwissenschaft und Werkstofftechnik 29 (1998), S. 336-338 
    ISSN: 0933-5137
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics
    Description / Table of Contents: Es wird die Präparation und die temperaturabhängige Lichtdurchlässigkeit thermotroper Gelnetzwerke in Abhängigkeit von ihrer Zusammensetzung auf der Basis von Polyvinylalkohol (PVA), ethoxyliertem Polydimethyl-siloxan (ePS) und Wasser beschrieben. Diese thermotropen Materialien sind für den Einsatz in sogenannten „intelligenten“ Fenstern geeignet.
    Notes: The aim of this study has been to examine the possibility of preparing thermotropic aqueous gel networks that exhibit multiphase transitions in connection with changing the transparency of the system depending on temperature variation. As polymers polyvinyl alcohol (PVA) and ethoxylated polydimethylsiloxane (ePS) were chosen. Thermotropic materials can be used as intelligent shadegivers.
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  • 193
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    Materialwissenschaft und Werkstofftechnik 29 (1998), S. 345-364 
    ISSN: 0933-5137
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics
    Description / Table of Contents: Plasma Pretreatement and Coating of Polymer Films. Part 2: Experimental Results of the Plasma Pretreatment of Polymer FilmsThe food packaging industry demands cheap polymer films possessing a high barrier against permeation of gases, moisture and flavor. Candidates for the most successful materials fulfilling these requirements are vacuum web coated biaxial oriented polypropylene (BOPP) films containing a thin inorganic barrier layer. For a good adhesion of the barrier layer on the BOPP films, the polymer film must be pretreated. The industry uses the Corona atmosphere plasma. This work is separated in three parts. The first part describes the experimental setup and the properties of vacuum web coated layers on polymer films [1]. The next part contains the results of the systematic modification of po } ymer surface by atmosphere and low pressure plasmas. The influence of the surface properties on the final functionality of the coated films is given. In the last part, the discussion of the results of the first and second part reveals systematic relations between the production parameters of the high barrier films and their final functionality. These results firstly reveal the adhesion mechanism of the inorganic barrier layers of the polymer films and the necessary surface properties of the polymer films, in order to get cheap high barrier films by vacuum web coating.
    Notes: Die lebensmittelverpackende Industrie verlangt nach immer billigeren Kunststoffolien mit immer höheren Barrieren gegenüber Gasen, Wasserdampf und Aromastoffen. Ein sehr erfolgreicher Schritt, um diese Anforderungen zu erfüllen, besteht in der vakuumtechnischen Beschichtung mit dünnen anorganischen Schichten von biaxial orientierten Polypropylenfolien (BOPP). Um gute Haftungen der aufgedampften Aluminiumschichten zu erzielen, müssen die BOPP-Folie vorbehandelt werden. Industriell steht dafür das Corona-Atmosphärendruckplasma zur Verfügung. In dieser Arbeit aufgeteilt in drei Abschnitte wird zuerst der Versuchsaufbau und die Eigenschaften beschichteter Kunststoffolien allgemein dargestellt [1]. Im nächsten Schritt erfolgt die systematische Modifikation der Folienoberfläche mittels verschiedener Atmosphärendruck- und Niederdruckplasmen. Die Plasmen werden mittels Langmuir-Sonde und Quadrupolmassenspektrometer charakterisiert. Nach Beschichtung der mittels verschiedener Plasmen modifizierten Kunststoffolien zeigen Haftung und Permeabilitätsmessungen den Einfluß der Vorbehandlung auf die Funktionalität der Folie/Schicht-Systeme. Im letzte Abschnitt werden aus den Ergebnissen der Analysen der unbeschichteten und beschichten Folien systematische Zusammenhänge zwischen Herstellungsparametern und funktionellen Eigenschaften der beschichteten Folien hergestellt. Daraus lassen sich erstmals die zu einer guten Schichthaftung führenden Mechanismen aufzeigen und die notwendigen Oberflächeneigenschaften der unbeschichteten Folie identifizieren, so daß durch die vakuumtechnischen Beschichtung preisgünstige Hochbarrierefolien produziert werden können.
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    Materialwissenschaft und Werkstofftechnik 29 (1998), S. 412-423 
    ISSN: 0933-5137
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics
    Description / Table of Contents: Weldability of Aluminium and Al AlloysAluminium is behind steel the most used metal. Advantages of Al-materials are the low weight, the favourable strength and deformation properties, the good corrosion resistance and the good electrical and thermal conductivity. Welding of aluminium encounters difficulties due to high melting oxide layer at the surface, the strong heat dissipation from the welding region, the tendency to form craters or pores and the high heat extension. This contribution describes the basic facts and special features of arc welding and weld properties of aluminium and Al-alloys during welding.
    Notes: Aluminium ist das nach dem Stahl am häufigsten eingesetzte Metall. Vorteile der Aluminiumwerkstoffe sind das geringe Gewicht, günstige Festigkeits- und Verformungseigenschaften, der hohe Korrosionswiderstand sowie die hohe elektrische und Wärmeleitfähigkeit. Beim Schweißen ergeben sich vielfach Schwierigkeiten, die u. a. durch die hochschmelzende Oxidhaut, die starke Wärmeableitung, die Neigung zur Riß- oder Porenbildung sowie durch die große Wärmedehnung verursacht werden. Im vorliegenden Beitrag werden die Grundlagen und Besonderheiten von Reinaluminium und unterschiedlicher Legierungen hinsichtlich der Lichtbogen-Schweißtechnologie und der Nahteigenschaften dargestellt.
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    Materialwissenschaft und Werkstofftechnik 29 (1998), S. 447-450 
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    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics
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    Materialwissenschaft und Werkstofftechnik 29 (1998), S. 451-451 
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    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
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    Materialwissenschaft und Werkstofftechnik 29 (1998), S. 466-475 
    ISSN: 0933-5137
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics
    Description / Table of Contents: Low energy IBAD: correlation between process parameters ans film properties for ion beam assisted evaporation and sputter depositionBinary nitride films with Al, Cr and Ti as metal components have been deposited with ion beam assisted evaporation and sputtering (IBAD) and the film properties are investigated in terms of the individual deposition parameters.In the case of ion beam assisted evaporation the flux ratio between the film forming metal atoms and the nitrogen ions from the ion source was shown to enable a quantitative control of the composition and the chemical phases of the films. Detailed studies for TiN reveal the possibilities to manipulate texture and stress, the average grain size and the morphology of the films. Such results are discussed with an extended structure zone model, introducing the energy input per film forming particle as the relevant parameter. Also, the structural film properties and the deposition parameters are quantitatively correlated with the hardness and the beginning of TiN deposition on stainless steel resulted in distinctly improved adhesion properties.For the deposition of TiN with a dual ion beam arrangement in which one beam bundle was directed onto a Ti-target and an other onto the substrate with the growing film, a strong influence of the particle energies and the incidence angles on the film texture and its directional orientation was found. Such effects are quantitatively related to the minimization of the free energy of the films and the influence of preferential re-sputtering effects. For ion beam sputter deposition without simultaneous ion bombardment of the growing film, the texture and the film stress are found to be controlled by energetic particles resulting from elastic backscattering at the target surface.
    Notes: Mittels ionenstrahlunterstütztem Aufdampfen und Aufsputtern (IBAD)wurden binäre Nitridschichten mit Al, Cr und Ti als Metallkomponente deponiert und hinsichtlich ihrer Eigenschaften in Abhängigkeit von den Depositionsparametern Charakterisiert.Beim ionenstrahlunterstützten Aufdampfen konnten durch Variation des Flußratenverhältnisses zwischen den schichtbildenden Metallatomen und den aus der Ionenquelle extrahierten Stickstoffionen die Schichtzusammensetzung und die chemischen Phasenverhältnisse kontrolliert eingestellt werden. Ausführliche Untersuchungen an den TiN-Schichten zeigen, daß auch Textur, Eigenspannungen, mittlere Korngröße und Morphologie der Schichten in weiten Grenzen manipuliert werden können. Ausgehend vom Energieeintrag pro schichtbildendem Teilchen werden die Ergebnisse anhand eines erweiterten Strukturzonenmodells diskutiert. Weiter lassen sich die strukturellen Schichteigenschaften und die Depositionsparameter mit der Härte und der Haftfestigkeit der Schichten quantitativ korrelieren. Durch dynamische Prozeßführung in der Anfangsphase des Schichtwachstums konnte eine deutliche Verbesserung der Haftung von TiN auf Werkzeugstahl erzielt werden.Für die Deposition von TiN mit einer Zweistrahlanordung, bei der ein Ionenstrahlbündel auf ein Ti-Target und ein weiteres auf das Substrat mit der aufwachsenden Schicht trifft, ergibt sich ein deutlicher Einfluß der Teilchenenergien und -auftreffwinkel auf die Schichttextur und deren Ausrichtung. Betrachtungen zur Minimierung der freien Energie in den Schichten und zum Einfluß von präferentiellen Rücksputtereffekten liefern ein quantitatives Verständnis der Effekte bei der Texturbildung. Bei der Ionenstrahl-Sputterdeposition ohne simultanem Substratbeschuß werden Textur und Schichtspannungen durch die vom Sputtertarget kommenden energiereichen Rückstreuteilchen bestimmt.
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    Materialwissenschaft und Werkstofftechnik 29 (1998), S. 518-524 
    ISSN: 0933-5137
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics
    Description / Table of Contents: Custom-Tailored Coating-Interface Systems by Means of lon Beam Assisted DepositionA coated sample represents in its most simple form a threefold junction consisting of substrate interface and top layer. In many cases the top layer consists again of several sublayers or the interface contains a modified substrate surface and an interconnection between top layer and interface. An ideal coating technique is evaporation under simultaneous ion bombardment with an ion source it is possible because of several free parameters to come close to an ideal system.For the coating Al/Al2O3 on steel it is shown that the width of a composition gradient between the sublayers Al and Al2O3 can be optimized with respect to excellent corrosion resistance.The example CrxN coating on steel or corrosion and wear resistence demonstrate the ability to optimize the corrosion and wear resistence by modifying the microstructure via variation of the parameters ion energy, ion impact angle, ion to atom ratio and process temperature.Finally, TiN layers on steel were chosen to show that the ion beam parameters influence the porosity and the crystal structure of the coatings. This fact can be used to optimize the corrosion protection or wear reduction obtained by the coating. Especially the multilayer Ti/TiO2/TiN exhibits very interesting properties.
    Notes: Ein beschichtetes Bauteil stellt in seiner einfachsten Form einen Dreierverbund aus Substrat, Interface und Schicht dar, in vielen Fällen kann die Schicht aus mehreren Untersystemen bzw. das Interface aus der modifizierten Substatrandschicht und einem Zwischenbereich zur Schicht bestehen. Eine ideale Beschichtungsmethode sollte es daher erlauben, alle diese Schichten bzw. Schichtbereiche in kontrollierter und aufeinander abgestimmter Form zu erzeugen.Mittels des IBAd-Verfahrens, bei dem Aufdampfschichten während ihrer Abscheidung mit Ionen aus einer Ionenquelle beschossen werden, ist es möglich, infolge der zahlreichen frei wählbaren Parameter sich an das ideale System heranzutasten.Anhand des Verbunds Stahl/Al/Al2O3 wird erlätert, wie durch einen in der Ausdehnung optimierten Zusammensetzungsgradienten das Interface zwischen den Subschichten Al und Al2O3 bezüglich des Korrosionsschutzvermögens der Schicht verbessert werden kann.An CrxN-Schichten wird demonstriert, daß durch die Wahl der Parameter Ionenenergie, Ioneneinfallswinkel, Ionen/Atom-Verhältnis und Prozeßtemperatur über die Mikrostruktur von Schicht und Oberfläche das Verschleiß-und Korrosionsverhalten sowie die Härte angepaßt werden können.Am Beispiel TIN auf Stahl zeigt sich, daß je nach Ionenstrahlparameter die Porosität und damit das Korrosionsverhalten bzw. die Kristallinität und damit Härte und Verschleißverhalten optimiert werden können. Besonders Mehrlagenschichten Ti/TiO2/TiN zeigen interessante Eigenschaften.
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    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics
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    ISSN: 0933-5137
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics
    Description / Table of Contents: Coatings in polymer processingCrxN coatings produced by PVD-magnetron sputtering (MSPVD) open unitsFor several years hard coatings have been used in plastic processing. The reduction of adhesion and contamination effects play a more and more important role besides the wear protection of injection moulds and extrusion tools. Applications of hard coatings in the field of highly stressed screws and barrels of plastification units are very seldom. In these cases the tribological effects are very intense so that the demanded wear resistance of hard coatings in the range 10μm is not sufficient. Different hard coatings based on titanium and chromium were tested according to their applicability for wear protection of screws in plastification units. Thickness, hardness, internal stresses and adhesion of the coatings were studied.Afterwards tribological tests in a model testing unit were investigated. Here the coatings were studied under tribological conditions, similar to those in a real plastification unit. The CrxN multilayer coatings showed extremely better wear resistance than the titanium based coatings. For this reason the CrxN coatings were optimized by help of the deposition parameters. These optimized coatings have been investigated according to their applicability for different polymers in comparison to other coating systems. First tests of CrCN/TiCN coated screw elements in practice showed very pleasing results. The test in practice with the optimized CrxN multilayer coating has yet to take place, but in the model tests the CrxN coatings showed excellent results.
    Notes: Hartstoffschichten werden bereits seit langem in der Kunststoffverarbeitung eingesetzt. Neben dem Verschleißschutz von Spritzguß-und Extrusionswerkzeugen stehen häufig auch die Verringerung von Klebneigungen und Formverschmutzungen im Vordergrund. Anwendungen im Bereich der hochbeanspruchten Schnecken und Zylinder von Plastifizieraggregaten sind noch selten. Die Verschleißeffekte sind hier so heftig, daß in der Praxis eine große Verschleißreserve gefordert wird, die Hartstoffschichten mit maximal 10 μm Schichtdicke naturgemäß nicht mitbringen. Verschiedene Hartstoffschichten auf Titan- und Chrombasis wurden hinsichtlich ihrer Eignung für den Verschleißschutz von Schnecken für Plastifizieraggregate untersucht. Schichtdicke, Härte, Eigenspannungen und Haftfestigkeit der Schichten wurden bestimmt.Anschließend wurden Verschleißversuche mit Hilfe einer Modellprüfapparatur, die die Schichten ähnlichen tribologischen Belastungen aussetzt, wie sie in einer Plastifiziereinheit auftreten, durchgeführt. Die CrxN-Mehrlagenschichten waren hierbei den auf Titan basierenden Schichten deutlich überlegen. Deshalb wurden für die CrxN-Schichten optimale Beschichtungsparameter bestimmt. Diese optimierten Schichten wurden mit verschiedenen anderen Schichtsystemen im Hinblick auf Ihre Eignung für unterschiedliche Kunststoffmaterialien verglichen. Erste Praxisversuche mit CrCN/TiCN-beschichteten Schneckenlementen sind sehr vielversprechend. Ein Praxistest der optimierten CrxN-Mehrlagenschichten steht zwar noch aus, jedoch konnten die guten Ergebnisse der CrxN-Schichten bei den Modellversuchen stets bestätigt werden.
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