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  • Articles  (811)
  • Physics  (310)
  • Chemistry  (233)
  • Geomagnetism, Rock Magnetism and Palaeomagnetism  (159)
  • geostatistics  (109)
  • Analytical Chemistry and Spectroscopy
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  • Geosciences  (811)
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  • 1
    Electronic Resource
    Electronic Resource
    Springer
    Stochastic environmental research and risk assessment 6 (1992), S. 209-221 
    ISSN: 1436-3259
    Keywords: geostatistics ; precipitation ; water balance models ; semivariogram ; kriging ; spatial variation
    Source: Springer Online Journal Archives 1860-2000
    Topics: Architecture, Civil Engineering, Surveying , Energy, Environment Protection, Nuclear Power Engineering , Geography , Geosciences
    Notes: Abstract Daily precipitation amounts show spatial variation over sub-continential regions. Point measurements, representative for regions of land, have to be interpolated towards unobserved locations. In this study four days in 1984 were selected to investigate the spatial variability of daily precipitation amount in North-western Europe in relation to the meteorological conditions. Data were interpolated using Kriging. Crossvalidation was used to compare interpolated values with measured values. Large differences in the spatial structure of daily precipitation amount are obsered as a result of different meterological conditions. Stratification of the study area into a coastal, a mountainous and an interior stratum proved to be successful, reducing the Mean Squared Error of Prediction with up to 55%.
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  • 2
    Electronic Resource
    Electronic Resource
    Springer
    Stochastic environmental research and risk assessment 6 (1992), S. 304-320 
    ISSN: 1436-3259
    Keywords: geostatistics ; precipitation ; water balance models ; semivariogram ; kriging ; spatial variation
    Source: Springer Online Journal Archives 1860-2000
    Topics: Architecture, Civil Engineering, Surveying , Energy, Environment Protection, Nuclear Power Engineering , Geography , Geosciences
    Notes: Abstract Daily precipitation amounts show spatial variation over sub-continential regions. Point measurements, represntative for regions of land, have to be interpolated towards unobserved locations. In this study four days in 1984 were selected to investigate the spatial variability of daily precipitation amount in north-western Europe in relation to the meteorological conditions. Data were interpolated using kriging. Crossvalidation was used to compare interpolated values with measured values. Large differences in the spatial structure of daily precipitation amount are observed as a result of different meteorological conditions. Stratification of the study area into a coast, a mountain and an interior stratum proved to be successful, reducing the Mean Squared Error of Prediction with up to 55%.
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  • 3
    ISSN: 1432-0975
    Keywords: Key words Otolith ; Chemistry ; ICP-MS ; Stock discrimination ; Epinephelus striatus
    Source: Springer Online Journal Archives 1860-2000
    Topics: Biology , Geosciences
    Notes: Abstract  We examined the utility of otolith minor and trace element chemistry, assayed with inductively coupled plasma mass spectrometry (ICP-MS), as a means of delineating population structure in the Nassau grouper (Epinephelus striatus). We characterized the elemental composition of otoliths collected in 1993 from three locations in Exuma Sound, Bahamas and from Glover Reef, Belize in 1995. A single location in Exuma Sound was sampled in 1994 to test temporal variability in otolith composition. Five elements (Ca, Zn, Sr, Ba and Pb) were routinely detected, at levels significantly above background, by solution-based ICP-MS. Results from analysis of variance of elemental data, expressed as a ratio to Ca, indicated that there were no significant differences among the Exuma locations for any element, but significant variability was found between Glover Reef and the pooled Exuma localities for Zn/Ca, Sr/Ca and Ba/Ca ratios. Significant inter-annual differences at one Exuma Sound location was restricted to Ba/Ca ratios. Discriminant function analysis correctly classified 86% and 95% of the Belize and pooled Exuma sites, respectively. Otoliths from Belize were characterized by low Zn/Ca and high Ba/Ca and Pb/Ca ratios compared to otoliths from fish collected in Exuma Sound. Although differences in Ba levels may be related to upwelling at Glover Reef, more data are needed to definitely link otolith composition with regional differences in water chemistry.
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  • 4
    ISSN: 1573-0581
    Keywords: Bathymetry ; gravity ; magnetics ; satellite data ; Gondwana breakup ; geostatistics ; geophysical inverse theory
    Source: Springer Online Journal Archives 1860-2000
    Topics: Geosciences , Physics
    Notes: Abstract Bathymetric, gravity, and magnetic data from Antarctic expeditions with RV POLARSTERN and satellite altimeter data from the Geosat Geodetic Mission are analysed using methods from geostatistics and geophysical inverse theory. The Explora Escarpment represents the edge between the Antarctic Continental Shelf and the Weddell Abyssal Plain. It is an important link in the reconstruction of Gondwana breakup, but a feature as large as the 2000 m deep Wegener Canyon was only discovered in 1984, when extensive bathymetric, gravimetric, and magnetic surveys with RV POLARSTERN began. Geostatistics, the theory of regionalized variables, is applied to integrate dense surveys of Wegener Canyon and sparse observations in adjacent areas into maps with full coverage of the 230 km by 330 km area at 10°–20° W/70°–72° S. The resultant highresolution bathymetric and gravity maps reveal detailed structures of the Explora Escarpment. Using geophysical inversion, the gravity terrain effect is calculated. Satellite data are used for their better coverage, but have much lower resolution. Nevertheless, the structures of Wegener Canyon and other more prominent features appear with surprisingly good correlation also in the Geosat altimeter data. While it was initially supposed that Wegener Canyon is purely an erosional structure, the magnetic map now provides evidence of the ‘canyon's’ tectonic origin.
    Type of Medium: Electronic Resource
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  • 5
    Electronic Resource
    Electronic Resource
    Springer
    Pure and applied geophysics 118 (1980), S. 128-151 
    ISSN: 1420-9136
    Keywords: Galactic cosmic rays ; Solar proton events ; Particle precipitation ; Chemistry
    Source: Springer Online Journal Archives 1860-2000
    Topics: Geosciences , Physics
    Notes: Abstract An assessment is made of the relative contribution of certain classes of energetic particle precipitation to the chemical composition of the middle atmosphere with emphasis placed on the production of odd nitrogen and odd hydrogen species and their subsequent role in the catalytic removal of ozone. Galactic cosmic radiation is an important source of odd nitrogen in the lower stratosphere but since the peak energy deposition occurs below the region where catalytic removal of O3 is most effective, it is questionable whether this mechanism is important in the overall terrestrial ozone budget. The precipitation of energetic solar protons can periodically produce dramatic enhancement in upper stratospheric NO. The long residence time of NO in this region of the atmosphere, where catalytic interaction with O3 is also most effective, mandates that this mechanism be included in future modelling of the global distribution of O3. Throughout the mesosphere the precipitation of energetic electrons from the outer radiation belt (60°≲Λ≲70°) can sporadically act as a major local source of odd hydrogen and odd nitrogen leading to observable O3 depletion. Future satellite studies should be directed at simultaneously measuring the precipitation flux and the concomitant atmosphere modification, and these results should be employed to develop more sophisticated models of this important coupling.
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  • 6
    Electronic Resource
    Electronic Resource
    Springer
    Boundary layer meteorology 85 (1997), S. 197-222 
    ISSN: 1573-1472
    Keywords: Turbulence ; Chemistry ; Closure ; Convective boundary layer
    Source: Springer Online Journal Archives 1860-2000
    Topics: Geosciences , Physics
    Notes: Abstract We study the interactions of chemistry and turbulent mixing of tracersin the convective boundary layer with a second-order closure model,including higher order chemistry terms. In order to limit the number of predictive equations we prescribe the profiles for ¯w¯Θ, ¯w¯θ ¯θ and the lengthscale l. However, for model validation we treat temperature and humidity asinert tracers, and compare the results with profiles observed during theAir Mass Transformation Experiment, and with similarity expressions for thesurface layer. We find good agreement of the mean profiles, but the (co-)variances are slightly underpredicted. Furthermore, the model usesdiagnostic equations expressing third moments of concentration in terms ofsecond moments and their vertical derivatives. They are compared withlarge-eddy model results, showing good agreement and, therefore, thesimplifications are justified. The model is applied to the transport of two gases subject to one bimolecular reaction. The importance of concentration correlations on themean transformation rate is studied. For two gases diffusing in oppositedirections we find for moderate and fast chemistry a 50% and90% decreased transformation rate due to the negatively correlatedconcentrations. These values are similar to large-eddy results of Schumannand Sykes et al. For two bottom-up tracers we find that the covariance ofboth reactive species is either positive or negative, increasing or reducingthe effective transformation rate depending on the Damköhler number (the ratio of the turbulent and the chemistry timescale). A significantdirect influence of chemistry on the flux divergence is found in bothcases. According to the model the effective transport to mid-levels of theboundary layer is increased when two reactive tracers diffuse in oppositedirections, and decreased in the case of two bottom-up tracers.
    Type of Medium: Electronic Resource
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  • 7
    Electronic Resource
    Electronic Resource
    Springer
    Geotechnical and geological engineering 7 (1989), S. 227-237 
    ISSN: 1573-1529
    Keywords: Roof convergence ; longwall face ; geostatistics ; coal mining ; support advance
    Source: Springer Online Journal Archives 1860-2000
    Topics: Geosciences
    Notes: Summary Roof convergence and the rate of convergence are regionalized variables; the geostatistics can thus be applied to a set of underground observations. This investigation shows that the removal of a slice of coal induces roof movement. The rate of convergence is highest just after the coal removal and decreases with time. The immediate advance of a ‘rigid’ powered roof support decreases the total convergence for a complete production cycle. On the other hand, the timing of the advance of a relatively ‘soft’ support element has no influence on the total convergence for a complete production cycle.
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  • 8
    Electronic Resource
    Electronic Resource
    Springer
    Mathematical geology 20 (1988), S. 1001-1019 
    ISSN: 1573-8868
    Keywords: geostatistics ; change of support ; recoverable reserves ; selectivity ; normality index ; Cartier's formula ; affine correction ; discrete Gaussian model ; mosaic model
    Source: Springer Online Journal Archives 1860-2000
    Topics: Geosciences , Mathematics
    Notes: Abstract The practical problem considered here is: how can block distribution in an orebody be forecast from sample data? The task is arduous because information yielded by samples is too often insufficient to allow an accurate evaluation of blocks. In practice, necessary additional information is obtained via a model. Choosing that model is crucial; the value of results reflects the model, i.e., its adequacy to represent reality. In this paper, the importance of choosing the change of support model is illustrated with simulations and practical examples (especially deposits with a skewed sample distribution and a large spike at the origin). An attempt to quantify this importance is made also.
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  • 9
    Electronic Resource
    Electronic Resource
    Springer
    Mathematical geology 21 (1989), S. 285-308 
    ISSN: 1573-8868
    Keywords: Bayesian updating ; geostatistics ; Kriging ; linear inversion
    Source: Springer Online Journal Archives 1860-2000
    Topics: Geosciences , Mathematics
    Notes: Abstract Bayesian updating methods provide an alternate philosophy to the characterization of the input variables of a stochastic mathematical model. Here, a priori values of statistical parameters are assumed on subjective grounds or by analysis of a data base from a geologically similar area. As measurements become available during site investigations, updated estimates of parameters characterizing spatial variability are generated. However, in solving the traditional updating equations, an updated covariance matrix may be generated that is not positive-definite, particularly when observed data errors are small. In addition, measurements may indicate that initial estimates of the statistical parameters are poor. The traditional procedure does not have a facility to revise the parameter estimates before the update is carried out. alternatively, Bayesian updating can be viewed as a linear inverse problem that minimizes a weighted combination of solution simplicity and data misfit. Depending on the weight given to the a priori information, a different solution is generated. A Bayesian updating procedure for log-conductivity interpolation that uses a singular value decomposition (SVD) is presented. An efficient and stable algorithm is outlined that computes the updated log-conductivity field and the a posteriori covariance of the estimated values (estimation errors). In addition, an information density matrix is constructed that indicates how well predicted data match observations. Analysis of this matrix indicates the relative importance of the observed data. The SVD updating procedure is used to interpolate the log-conductivity fields of a series of hypothetical aquifers to demonstrate pitfalls and possibilities of the method.
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  • 10
    Electronic Resource
    Electronic Resource
    Springer
    Mathematical geology 21 (1989), S. 683-691 
    ISSN: 1573-8868
    Keywords: geostatistics ; factorial kriging analysis ; spectral analysis ; petroleum exploration
    Source: Springer Online Journal Archives 1860-2000
    Topics: Geosciences , Mathematics
    Notes: Abstract A regionalized variable, thickness of the reservoir layer, from a gas field is decomposed by factorial kriging analysis. Maps of the obtained components may be associated with depositional environments that are favorable for petroleum exploration.
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