ALBERT

Description: Ghana is urbanising rapidly, and over half of the country’s population have lived in urban areas since 2010. Although research has proliferated to explore Ghana’s urbanisation, there is a dearth of research that holistically explores the wider sustainability implications of urbanisation, offers comparative perspectives in the context of large and smaller urban areas, and provides a perspective of local level urbanisation in the context of resource extraction (mining). This study comparatively assesses two urban areas in Ghana (Kumasi and Obuasi), by conducting a spatio-temporal analysis of land cover change through remote sensing and by analysing demographic change through a synthesis of published population data, in order to highlight the sustainability implications of urbanisation. The results show that urbanisation has been rapid, and has resulted in changes in land cover and demography in Kumasi and Obuasi. The sustainability implications of urbanisation are identified to include limited economic opportunities, socio-spatial segregation, and destruction of natural vegetation. The evidence in this study provides insights into urbanisation in Ghana, and suggests that the positive sustainability impacts of urbanisation may be eroded by how factors such as market forces and land tenure interact at the local level.

Description: The optimization of ecological resource allocation is increasingly seen as a potential solution for urban revitalization and sustainable land use planning, and the key point is to assess and simulate the spatial arrangement of the ecological land. In this study, we proposed a conceptual framework with the aim of reoccupying ecological resources for rust belt cities from the perspective of eco-economic trade-offs. The ecological security pattern, the urban development pattern, and the ecological quality of cropland were constructed and evaluated to measure the development level of an ecological system and a socio-economic system. Furthermore, the results were used as the constraints that influenced land use distribution to simulate the ecological land reoccupation pattern. The suitable area, the preservation area, the configurable area, and the unsuitable area in the reoccupation pattern accounted for 6.94%, 49.97%, 28.17%, and 0.69%, respectively. Significantly, under strict cropland protection policies, the available space for ecological land expansion was heavily compressed. Therefore, the emphasis on agricultural production should be reexamined to release more space for ecological resources. This method could be an effective pathway to alleviate the pressures on urban and natural space caused by the competition between land-use activities, such as economic development, agricultural production, and ecological conservation. The findings are expected to promote urban revitalization, green agriculture, and sustainable social development in rust belt cities, and provide certain references for the utilization of land resources and regional policy making.

Description: As acidic deposition has decreased across Eastern North America, forest soils at some sites are beginning to show reversal of soil acidification. However, the degree of recovery appears to vary and is not fully explained by deposition declines alone. To assess if other site and soil factors can help to explain degree of recovery from acid deposition, soil resampling chemistry data (8- to 24-year time interval) from 23 sites in the United States and Canada, located across 25° longitude from Eastern Maine to Western Ontario, were explored. Site and soil factors included recovery years, sulfate (SO42−) deposition history, SO42− reduction rate, C horizon pH and exchangeable calcium (Ca), O and B horizon pH, base saturation, and exchangeable Ca and aluminum (Al) at the time of the initial sampling. We found that O and B horizons that were initially acidified to a greater degree showed greater recovery and B horizon recovery was further associated with an increase in recovery years and lower initial SO42− deposition. Forest soils that seemingly have low buffering capacity and a reduced potential for recovery have the resilience to recover from the effects of previous high levels of acidic deposition. This suggests, that predictions of where forest soils acidification reversal will occur across the landscape should be refined to acknowledge the importance of upper soil profile horizon chemistry rather than the more traditional approach using only parent material characteristics.

Description: The genus Thujopsis (Cupressaceae) comprises monoecious coniferous trees endemic to Japan. This genus includes two varieties: Thujopsis dolabrata (L.f.) Siebold et Zucc. var. dolabrata (southern variety, Td) and Thujopsis dolabrata (L.f.) Siebold et Zucc. var. hondae Makino (northern variety, Th). The aim of this study is to understand the phylogeographic and genetic population relationships of the genus Thujopsis for the conservation of genetic resources and future breeding. A total of 609 trees from 22 populations were sampled, including six populations from the Td distribution range and 16 populations from the Th distribution range. The genotyping results for 19 expressed sequence tag (EST)-based simple sequence repeat (SSR) markers, followed by a structure analysis, neighbor-joining tree creation, an analysis of molecular variance (AMOVA), and hierarchical F statistics, supported the existence of two genetic clusters related to the distribution regions of the Td and Th varieties. The two variants, Td and Th, could be defined by their provenance, in spite of the ambiguous morphological differences between the varieties. The distribution ranges of both variants, which have been defined from their morphology, was confirmed by genetic analysis. The Th populations exhibited relatively uniform genetic diversity, most likely because Th refugia in the glacial period were scattered throughout their current distribution area. On the other hand, there was a tendency for Td’s genetic diversity to decrease from central to southern Honshu island. Notably, the structure analysis and neighbor-joining tree suggest the hybridization of the two varieties in the contact zone. More detailed studies of the genetic structure of Td are required in future analyses.

Description: Ice accretion is a phenomenon whereby super-cooled water droplets impinge and accrete on wall surfaces. It is well known that the icing may cause severe accidents via the deformation of airfoil shape and the shedding of the growing adhered ice. To prevent ice accretion, electro-thermal heaters have recently been implemented as a de- and anti-icing device for aircraft wings. In this study, an icing simulation method for a two-dimensional airfoil with a heating surface was developed by modifying the extended Messinger model. The main modification is the computation of heat transfer from the airfoil wall and the run-back water temperature achieved by the heater. A numerical simulation is conducted based on an Euler–Lagrange method: a flow field around the airfoil is computed by an Eulerian method and droplet trajectories are computed by a Lagrangian method. The wall temperature distribution was validated by experiment. The results of the numerical and practical experiments were in reasonable agreement. The ice shape and aerodynamic performance of a NACA 0012 airfoil with a heater on the leading-edge surface were computed. The heating area changed from 1% to 10% of the chord length with a four-degree angle of attack. The simulation results reveal that the lift coefficient varies significantly with the heating area: when the heating area was 1.0% of the chord length, the lift coefficient was improved by up to 15%, owing to the flow separation instigated by the ice edge; increasing the heating area, the lift coefficient deteriorated, because the suction peak on the suction surface was attenuated by the ice formed. When the heating area exceeded 4.0% of the chord length, the lift coefficient recovered by up to 4%, because the large ice near the heater vanished. In contrast, the drag coefficient gradually decreased as the heating area increased. The present simulation method using the modified extended Messinger model is more suitable for de-icing simulations of both rime and glaze ice conditions, because it reproduces the thin ice layer formed behind the heater due to the runback phenomenon.

Description: In agricultural science, the establishment of a given cropping system in mountainous areas is often understood from the relationship between differences of altitude-specific, agroecological conditions and crop cultivation characteristics. However, social factors can also play a role. We aimed to clarify how the cropping system is maintained through examining sociocultural factors, specifically land tenure and marriage systems, in an agricultural community in rural mountainous Africa. Several surveys based on participatory observation accompanied by home stays were conducted to determine people who participated in cropping systems and to understand which social system maintained the cropping system. We found that around 70% of target households in Kiboguwa village cultivated three staple crops (maize, cassava and rice) using the same cropping system and almost no farmers outside the village used the village’s sloped fields, meaning that the villagers maintained the cropping system. Households acquired nearby sloped fields by various means such as inheriting land through maternal lineage of household heads or wives. We observed virilocal and uxorilocal residence at similar degrees—and if either the husband or wife was from outside the village, that household would also have fields outside the village. However, nearly 80% of marriages were intravillage and villagers predominantly used fields located within the village limits regardless of the residence type, which helped maintain the cropping system.

Description: Failures of marine propulsion components or systems can lead to serious consequences for a vessel, cargo and the people onboard a ship. These consequences can be financial losses, delay in delivery time or a threat to safety of the people onboard. This is why it is necessary to learn about marine propulsion failures in order to prevent worst-case scenarios. This paper aims to provide a review of experimental, analytical and numerical methods used in the failure analysis of ship propulsion systems. In order to achieve that, the main causes and failure mechanisms are described and summarized. Commonly used experimental, numerical and analytical tools for failure analysis are given. Most indicative case studies of ship failures describe where the origin of failure lies in the ship propulsion failures (i.e., shaft lines, crankshaft, bearings, foundations). In order to learn from such failures, a holistic engineering approach is inevitable. This paper tries to give suggestions to improve existing design procedures with a goal of producing more reliable propulsion systems and taking care of operational conditions.

Description: In this study, the environmental impacts of various alternative ship fuels for a coastal ferry were assessed by the life cycle assessment (LCA) analysis. The comparative study was performed with marine gas oil (MGO), natural gas, and hydrogen with various energy sources for a 12,000 gross tonne (GT) coastal ferry operating in the Republic of Korea (ROK). Considering the energy imports of ROK, i.e., MGO from Saudi Arabia and natural gas from Qatar, these countries were chosen to provide the MGO and the natural gas for the LCA. The hydrogen is considered to be produced by steam methane reforming (SMR) from natural gas with hard coal, nuclear energy, renewable energy, and electricity in the ROK model. The lifecycles of the fuels were analyzed in classifications of Well-to- Tank, Tank-to-Wake, and Well-to-Wake phases. The environmental impacts were provided in terms of global warming potential (GWP), acidification potential (AP), photochemical potential (POCP), eutrophication potential (EP), and particulate matter (PM). The results showed that MGO and natural gas cannot be used for ships to meet the International Maritime Organization’s (IMO) 2050 GHG regulation. Moreover, it was pointed out that the energy sources in SMR are important contributing factors to emission levels. The paper concludes with suggestions for a hydrogen application plan for ships from small, nearshore ships in order to truly achieve a ship with zero emissions based on the results of this study.

Description: We compared the catalytic effects of two polymers (soluble starch and apple pectin) on the flocculation of kaolinite suspension. Moreover, the relationship between the zeta potential value and the time when kaolin particle sedimentation occurred was verified, and the mechanism of flocculation was analyzed. Additionally, a constitutive model was proposed to simulate the non-ideal sedimentation of clay particles in an aqueous system under constant gravity. This model not only considers the inhomogeneity of the solute but also simulates the change in clay concentration with time during the deposition process. This model proposes a decay constant (α) and sedimentation coefficient (s). The model can also be used to calculate the instantaneous sedimentation rate of the clay suspensions at any time and any depth for the settling cylinder. These sedimentary characteristics were simulated by adopting the established deposition model. The results show that the model is capable of predicting the time required for the complete sedimentation of particles in the aqueous system, suggesting the feasibility of engineering wastewater treatment, site dredging, etc.

Description: Dense β-SiC coating with 3C-structure was utilized as a dry cold forging punch and core-die. Pure titanium T328H wires of industrial grade II were employed as a work material. No adhesion or galling of metallic titanium was detected on the contact interface between this β-SiC die and titanium work, even after this continuous forging process, up to a reduction in thickness by 70%. SEM (Scanning Electron Microscopy) and EDX (Electron Dispersive X-ray spectroscopy) were utilized to analyze this contact interface. A very thin titanium oxide layer was in situ formed in the radial direction from the center of the contact interface. Isolated carbon from β-SiC agglomerated and distributed in dots at the center of the initial contact interface. Raman spectroscopy was utilized, yielding the discovery that this carbon is unbound as a free carbon or not bound in SiC or TiC and that intermediate titanium oxides are formed with TiO2 as a tribofilm.

Description: The manufacturing of parts from nickel-based superalloy Alloy 247LC by laser powder bed fusion (L-PBF) is challenging, primarily owing to the alloy’s susceptibility to cracks. Apart from the cracks, voids created during the L-PBF process should also be minimized to produce dense parts. In this study, samples of Alloy 247LC were manufactured by L-PBF, several of which could be produced with voids and crack density close to zero. A statistical design of experiments was used to evaluate the influence of the process parameters, namely laser power, scanning speed, and hatch distance (inherent to the volumetric energy density) on void formation, crack density, and microhardness of the samples. The window of process parameters, in which minimum voids and/or cracks were present, was predicted. It was shown that the void content increased steeply at a volumetric energy density threshold below 81 J/mm3. The crack density, on the other hand, increased steeply at a volumetric energy density threshold above 163 J/mm3. The microhardness displayed a relatively low value in three samples which displayed the lowest volumetric energy density and highest void content. It was also observed that two samples, which displayed the highest volumetric energy density and crack density, demonstrated a relatively high microhardness; which could be a vital evidence in future investigations to determine the fundamental mechanism of cracking. The laser power was concluded to be the strongest and statistically most significant process parameter that influenced void formation and microhardness. The interaction of laser power and hatch distance was the strongest and most significant factor that influenced the crack density.

Description: Laser-based technologies are extensively used for polymer surface patterning and/or texturing. Different micro- and nanostructures can be obtained thanks to a wide range of laser types and beam parameters. Cell behavior on various types of materials is an extensively investigated phenomenon in biomedical applications. Polymer topography such as height, diameter, and spacing of the patterning will cause different cell responses, which can also vary depending on the utilized cell types. Structurization can highly improve the biological performance of the material without any need for chemical modification. The aim of the study was to evaluate the effect of CO2 laser irradiation of poly(L-lactide) (PLLA) thin films on the surface microhardness, roughness, wettability, and cytocompatibility. The conducted testing showed that CO2 laser texturing of PLLA provides the ability to adjust the structural and physical properties of the PLLA surface to the requirements of the cells despite significant changes in the mechanical properties of the laser-treated surface polymer.

Description: The research presented in the paper intends to overcome an information gap on the evolution of urbanized surfaces in Italy which in the studies carried out so far have never been available. The only historical data on this form of land use date back to the 1950s, and were extracted from a national cartography created by the Military Geographic Institute. The next chronological section available was then that of the noughties, already digital. However, much more frequent data were processed by the ten-year censuses by the National Institute of Statistics, but concerning buildings and not urbanized areas. By processing building census data, this study has put together some novel information on land take dynamics between the end of World War II and the year 2000, highlighting the more intensive processes that occurred at an extraordinary rate in the ‘70′s and ‘80′s, obtaining unprecedented information on the speed of transformation of the territory in these decades of economic boom. Through this method, we were able to obtain numerous geographical indications previously lacking on a national scale, highlight the yet significant vigor of this phenomenon and develop an inferential scenario.

Description: Access and use of seed of improved varieties of groundnut among farmers can improve farmers’ livelihoods and contribute to the potential of crop production in Tanzania. This paper analyzes factors underpinning the adoption of improved groundnut varieties among farmers to pave the way for upscaling quality seed used for increased production and commodity business in farming communities. A four-stage stratified sampling was used to collect data from 300 groundnut farmers in seven agro-ecological zones through individual interviews. Secondary data were collected from the literature and the Tanzania Agricultural Research Institute at Naliendele centre (TARI–Naliendele). Descriptive statistics and Probit regression model were used for data analysis. The empirical results showed that Johari 1985, Pendo 1998, Naliendele 2009, Mnanje 2009, Mangaka 2009 and Nachi 2015, are the main six improved groundnut varieties used by farmers, with Pendo 1998 having the highest adoption rate (17.1%). In the grain market, four varieties, namely Pendo 1998, Mnanje 2009, Nachi 2015 and Johari 1985, were observed to be highly preferred by grain off-takers. Furthermore, among the adopted improved varieties, Nachi 2015, is observed to be the most consistent high yielding variety, ranging from 1100 kg/ha to 1500 kg/ha in all agro-ecological zones. A farmer’s decision to adopt new varieties is affected by age and gender, farmer group membership, availability of improved seed and seed cost. Overall, male farmers are more likely to adopt improved varieties of groundnut than female farmers. The implications of these findings are also discussed, in particular in the area of policy support.

Description: This study presents an integrated examination of both the ecosystem services (ES) and ecosystem disservices (EDS) associated with smallholder animal husbandry in rural livelihoods in three villages in southeast South Africa. It recognises the contribution of ES supporting and resulting from smallholder livestock and poultry production, but also details the limiting factors or EDS, such as tick-borne disease, birds of prey or unpalatable rangeland, produced by the same system. Using a mixed-methods approach, including focus group discussions with various Participatory Learning and Action (PLA) activities, key informant interviews, household surveys and land-use change mapping on GIS, we consider the relative value and benefits from ES after the effects of EDS, as well as the management and strategies that households adopt to minimise EDS. The effects of ES and EDS were expressed in economic terms to provide a common framework to assess the magnitude of their contribution or effect. Although animal husbandry made measurable contributions to households, with an average gross value of between R2605–R9753 across villages, EDS undermined the meaningful production of livestock and poultry goods and services. The average EDS-induced economic loss in households was between R8289–R22,426 per annum. Despite active management, often at substantial cost to the household, EDS undermined the health of livestock which resulted in a loss of the animal or potential goods and services produced. We emphasise the need to recognise both the positive and negative contributions of ecosystems to identify the complex feedbacks between ES and EDS which interact to determine local ways of doing things.

Description: Species with wide geographical ranges exhibit specific adaptations to local climates, which may result in diverging responses among populations to changing conditions. Climate change has advanced spring phenology worldwide, but questions of whether and how the phenological responses to warming differ among individuals across the natural range of a species remain. We conducted two experiments in January and April 2019, and performed daily observations of the timings of bud break in 1-year-old seedlings of sugar maple (Acer saccharum Marshall) from 25 Canadian provenances at two thermal conditions (14/10 and 18/14 °C day/night temperature) in a controlled environment. Overall, bud break started 6 days from the beginning of the experiments and finished after 125 days. The earlier events were observed in seedlings originating from the colder sites. Bud break was delayed by 4.8 days per additional degree Celsius in the mean annual temperature at the origin site. Warming advanced the timing of bud break by 17–27 days in January and by 3–8 days in April. Similar advancements in bud break were observed among provenances under warming conditions, which rejected our hypothesis that sugar maple populations have different phenological responses to warming. Our findings confirm the differentiation in ecotypes for the process of bud break in sugar maple. In cases of homogenous spring warming across the native range of sugar maple, similar advancements in bud phenology can be expected in different populations.

Description: This case study from Stockholm County, Sweden, explores practitioners’ experiences of barriers and bridges in municipal planning practices to support actions for ecosystem services. This qualitative study is based on information gathered from a focus group, workshops, and semi-structured interviews, which aided in identifying key factors for integrating ecosystem services in municipal planning. We identified 10 key factors divided into three themes: (i) regulatory framework and political support, (ii) local organizational capacity, and (iii) local adaptation of tools and practices. In particular, the practitioners pointed to the need for the development of legal support and regulations for ecosystem services on the national and EU policy levels. Furthermore, the need for local capacity building and understanding of ecosystem services as well as increased regional support to enhance local knowledge exchange and learning was emphasized. Also, in a decentralized local governance system such as in Sweden, to fully implement ecosystem services in urban planning for sustainable development, locally adapted practical tools and monitoring procedures were considered important.

Description: Sugarcane is an important industrial crop because it is the major source of white sugar. It is also one of the crops for the alcohol and biofuel industries. Disease-causing organisms can significantly decrease the productivity of sugarcane plants and sugar quality. Among the disease-causing organisms, Colletotrichum falcatum Went causes the most significant economic loss (5–50%) in the sugarcane production due to red rot disease. This loss results in only 31% sugar recovery. It is reported that C. falcatum can kill sugarcane plants. Currently, there is no sustainable way of preventing red rot disease from spreading in sugarcane plantations. Many popular sugarcane varieties are no longer used in sugarcane cultivation because of their susceptibility to C. falcatum. The objectives of this manuscript were to: (i) summarize existing approaches for the early detection of red rot disease and controlling techniques of red rot disease in the field and laboratory and (ii) assess red rot disease control effectiveness so as to propose better methods for mitigating the spread C. falcatum. If our proposition is adopted or practiced, it could significantly contribute to the mitigation of C. falcatum infection in the sugarcane industry. This could enable achieving sustainable cultivation of sugarcanes to guarantee the sustainability of the sugar industry in the tropics and the subtropics.

Description: The transition from intensive conventional agriculture to sustainable agriculture has become a global priority. This is due to the need for environmentally friendly agriculture to ensure sufficient food for a rapidly growing population. The bioeconomy is essential to progress in the field of sustainable agriculture. It contributes to the conservation of biological resources through circular and comprehensive management. The bioeconomy prioritizes the reduction and reuse of materials and products. The focus of this study is the use of biodegradable/compostable raffia in protected horticultural crops in the Province of Almería (Spain). The analysis and evaluations, based on an extensive literature review and information given by stakeholders, determined that biodegradable raffia use significantly improves the management of residual biomass in Almería. However, biodegradable raffia is only used in a small percentage of crops even though it is a sustainable alternative and profitable for farmers. The economic analysis incorporates the higher cost of recycling non-biodegradable raffia.

Description: Sustainable agricultural production is endangered by several ecological factors, such as drought, extreme temperatures, excessive salts, parasitic ailments, and insect pest infestation. These challenging environmental factors may have adverse effects on future agriculture production in many countries. In modern agriculture, conventional crop-breeding techniques alone are inadequate for achieving the increasing population’s food demand on a sustainable basis. The advancement of molecular genetics and related technologies are promising tools for the selection of new crop species. Gene pyramiding through marker-assisted selection (MAS) and other techniques have accelerated the development of durable resistant/tolerant lines with high accuracy in the shortest period of time for agricultural sustainability. Gene stacking has not been fully utilized for biotic stress resistance development and quality improvement in most of the major cultivated crops. This review emphasizes on gene pyramiding techniques that are being successfully deployed in modern agriculture for improving crop tolerance to biotic and abiotic stresses for sustainable crop improvement.

Description: Research Highlights: The informed decisions on land use require assessment of the impacts of these decisions on the supply of different ecosystem services. Background and Objectives: Scenario modeling can be used to provide harmonized and quantitative information on the impacts of various zoning decisions on the provision of various ecosystem services. In this study, we explored the effects of land-use zoning decisions on the provision of roundwood and energy wood, carbon stock of living tree components, berry yields, scenic beauty and recreation. Materials and Methods: Three alternative forest scenarios were formulated in terms of restrictions on forest management for already established land-use zones by the provinces in Finland. These data were integrated with the National Forest Inventory (NFI) plot data for forest dynamics modeling. Results: In Finland, 9% of the forest land was protected and 9% was under restricted forest management due to legislative decisions, forest owners’ decisions, or regional land use plans in 2016. These established zoning decisions resulted in an estimated 17% smaller roundwood and energy wood removals per year in 2016–2025 compared to the estimated wood removals in the scenario without any restrictions. The decrease in annual gross stumpage earnings was EUR 775 million per year. The carbon stock of living tree components in 2025 was 12% larger than in the scenario without any restrictions. Bilberry yield increased due to the restrictions considered in our study, while the restrictions had only a slight effect on cowberry yield at province and country levels. The restrictions increased the recreation value, particularly in Lapland, but only slightly affected scenic beauty at province and country levels. Conclusions: Scenario analyses support informed decision making and the balancing of different forest uses. Harmonized translation of restrictions and the use of standard indicators to model the impacts also support comparisons between the regions.

Description: In this study, dynamic hardness tests on solid and engineered wood flooring specimens of Eucalyptus globulus Labill. and Eucalyptus grandis W. Hill ex Maiden hardwoods were performed because nowadays, these fast-growing hardwoods are still scarcely employed for this use. Furthermore, another two examples of hardwood commonly applied on wood flooring, Quercus robur L. and Hymenaea courbaril L., were also tested. To compare their properties, a dynamic impact hardness test based on the impact of steel balls, with several diameters, and drop heights was developed. Accordingly, 120 solid wood flooring specimens and 120 engineering wood flooring specimens were producing with these four hardwood species. Dynamic impact tests were made with three steel balls of different diameters (30–40–50 mm), and they were carried out from five different drop heights (0.60–0.75–0.90–1.05–1.20 m). The impact of the steel ball drew the size of the footprint on the surface and this mark was measured with a digital caliper for both dimensions, diameter and depth, as footprint diameter (FD) and indentation depth (ID). Data from 3000 samples, corresponding to 120 different individual groups (4 species × 3 ball diameters × 5 drop height × 2 floor type) were analyzed. Results indicated that the variability of ID (CV between 19.25–25.61%) is much greater than the values achieved for FD (CV between 6.72–7.91%). Regarding the fast-growing hardwood species tested, E. globulus showed a similar behavior to traditional hardwood applied on wood flooring in Europe, Q. robur, and it could be a promising growth in the flooring industry. However, E. grandis showed the worst values compared to traditional hardwood in all test configurations.

Description: Highly controlled biomineralization of calcium carbonate is via non-classical mesocrystallization of amorphous precursors. In the present study, a simple in vitro assay was developed to mimic the biological process, which involved stabilized amorphous calcium carbonate and a single crystal substrate of calcite. The microcoating layer formed on the calcite substrate displayed mesocrystalline characteristics, and the layers near the substrate were strongly influenced by the epitaxy to the substrate. This behavior was preserved even when the morphology of the coating layer was modified with poly(acrylic acid), a model anionic macromolecule. Interestingly, the extent of the epitaxy increased substantially with poly(ethylene imine), which barely affected the crystal morphology. The in vitro assay in the present study will be useful in the investigations of the biomineralization and bioinspired crystallization of calcium carbonate in general.

Description: Ti6Al4V alloy is still attracting great interest because of its application as an implant material for hard tissue repair. This research aims to produce and investigate in-situ chitosan/hydroxyapatite (CS/HA) nanocomposite coatings based on different amounts of HA (10, 50 and 60 wt.%) on alkali-treated Ti6Al4V substrate through the sol-gel process to enhance in vitro bioactivity. The influence of different contents of HA on the morphology, contact angle, roughness, adhesion strength, and in vitro bioactivity of the CS/HA coatings was studied. Results confirmed that, with increasing the HA content, the surface morphology of crack-free CS/HA coatings changed for nucleation modification and HA nanocrystals growth, and consequently, the surface roughness of the coatings increased. Furthermore, the bioactivity of the CS/HA nanocomposite coatings enhanced bone-like apatite layer formation on the material surface with increasing HA content. Moreover, CS/HA nanocomposite coatings were biocompatible and, in particular, CS/10 wt.% HA composition significantly promoted human mesenchymal stem cells (hMSCs) proliferation. In particular, these results demonstrate that the treatment strategy used during the bioprocess was able to improve in vitro properties enough to meet the clinical performance. Indeed, it is predicted that the dense and crack-free CS/HA nanocomposite coatings suggest good potential application as dental implants.

Description: This paper presents the studies of the development of a high-performance epoxy coating for steel substrates. To this end, it investigated the synergistic effect of incorporating zinc oxide (ZnO) nanoparticles into nanosilica containing epoxy formulations. The mechanical properties of the epoxy coating formulations were improved by modifying the surfaces of the silica nanoparticles (5 wt.%) with 3-glycidoxypropyl trimethoxysilane, which ensured their dispersal through the material. Next, the ZnO nanoparticles (1, 2, or 3 wt.%) were incorporated to improve the corrosion performance of the formulations. The anticorrosive properties of the coatings were examined by electrochemical impedance spectroscopy (EIS) of coated mild steel specimens immersed in 3.5% NaCl solution over different time intervals (1 h to 30 days). Incorporation of the ZnO nanoparticles and the nanosilica into the coating formulation improved the corrosion resistance of the epoxy coating even after long-term exposure to saline test solutions. Finally, to evaluate how the nanoparticles affected the chemical and morphological properties of the prepared coatings, the coatings were characterized by scanning electron microscopy (SEM), Fourier transform infrared (FTIR) spectroscopy, and X-ray diffraction (XRD).

Description: The aim of the study was to evaluate the changes in glomalin-related soil proteins (GRSP) content, microbial diversity and soil physical quality depending on the type of soil measures of soil improvement and changes in soil health. The study was based on a 100-year stationary field microplot experiment where the soil profiles were collected with preserving the natural soil horizons. The microplot experiment was carried out on eight different soil types: Brunic Arenosol (Dystric I), Rendzic Leptosol, Fluvic Cambisol, Haplic Cambisol (Eutric), Gleyic Phaeozem, Brunic Arenosol (Dystric II), Haplic Cambisol (Eutric II) and Haplic Cambisol (Dystric). These soils are the most common types of agricultural soils in Poland. Relatively significant correlations with the soil quality, physical parameters and the glomalin-related soil proteins have been found. The study determined the total GRSP (T-GRSP) and easily extractable GRSP (EE-GRSP) levels in soils as well as the soil physical quality index and soil’s microbial biodiversity. The GRSP depended on the type of soil and correlated with S-Index and also was responsible for the unique chemical and physical properties of soils. Soils characterized by the highest T-GRSP content belonged to the group of very good and good soil physical quality characterized also by high biological activity, for which there were strong correlations with such parameters as dehydrogenase activity (DHA), microbial biomass content (MBC), microbial nitrogen content (MBN) and total bacteria number (B). The highest T-GRSP content and higher microbial diversity were found in Gleyic Phaeozem, Rendzic Leptosol and Fluvic Cambisol. The T-GRSP and EE-GRSP content were additionally correlated with the number of AMF spores. Very poor and poor soil physical quality according to S-Index characterized Brunic Arenosol (Dystric I) and Haplic Cambisol (Dystric). This research indicates that a specific edaphone of soil microorganisms and GRSP content may be of great importance when assessing a soil’s quality and improvements in soil health. The abundance of glomalin-producing fungi significantly affects the quality of the soil. This effect is particularly important for agricultural soils are threatened by ongoing land degradation.

Description: In the present paper, the identification of the material parameters of a masonry lighthouse is discussed. A fully non-invasive method was selected, in which the material properties were determined via numerical model validation applied to the first pair of natural frequencies and their related mode shapes, determined experimentally. The exact structural model was built by means of the finite element method. To obtain experimental data for the inverse analysis, operational modal analysis was applied to the structure. Three methods were considered: peak picking (PP), eigensystem realization algorithm (ERA) and natural excitation technique with ERA (NExT-ERA). The acceleration’s responses to environmental excitations, enhanced in some periods of time by sheet piling hammering or by sudden interruptions like wind stroke, were assumed within the analysis input. Different combinations of the input were considered in the PP and NExT-ERA analysis to find the most reasonable modal forms. A number of time periods of a free-decay character were considered in the ERA technique to finally calculate the averaged modal forms. Finally, the elastic modulus, Poisson’s ratio and material density of brick, sandstone and granite masonry were determined. The obtained values supplement the state of the art database concerning historic building materials. In addition, the numerical model obtained in the analysis may be used in further cases of structural analysis.

Description: Land-based sources are the key sources of plastic debris, and mismanaged plastic debris can eventually enter the ocean via marine beaches. In this study, the spatial distribution and amount of plastic debris in the land-based source input zone of First Long Beach (FLB), China, which is a major tourist attraction, were first investigated. By using field investigation, sand samples were collected from two sections on FLB adjacent to land-based sources in December 2019, and the plastic debris in the sand samples was quantified and characterized in the laboratory. The amount of plastic debris ranged from 2 to 82 particles/m2 on this marine sand beach. There was a significant difference in plastic debris amount between the transects along the land-based source input zone (p 〈 0.05) due to the impacts of wind, ocean currents, and waves. The most abundant size of plastics was 0.5–2.5 cm (44.4%). Moreover, the most common color was white (60.9%). The most abundant shape of plastic debris fell into the fragment category (76.2%). The plastic debris amounts were significantly correlated with multiple sizes. Our results show that land-based wastewater discharge is a large plastic debris source on FLB under coastal water tide variation. Reduction strategies should be carried out by tracing the various land-based sources of plastic debris.

Description: Some special conditions are important for chemical syntheses, such as high temperature and the medium used; unfortunately, uncontrollable influences are introduced during the process, resulting in unexpectedly low repeatability. Herein, we report a facile, environmentally friendly, stable, and repeatable methodology for synthesizing silver nanoplates (SNPs) at 0 °C that overcomes these issues and dramatically increases the yield. This method mainly employs sodium dodecyl sulfate (SDS) and sodium alginate (SA) as the surface stabilizer and assistant, respectively. Consequently, we produced hexagonal nanoplates and tailed nanoplates, and the characterization showed that SA dominates the clear and regular profiles of nanoplates at 0 °C. The tailed nanoplates, over time, showed the growth of heads and the dissolving of tails, and inclined to the nanoplates without tails. The synthesis method for SNPs used in this study—0 °C without media—showed high repeatability. We confirmed that these special conditions are not required for the synthesis of silver nanostructures (SNSs). Furthermore, we constructed a new method for preparing noble metal nanostructures and proved the possibility of preparing metal nanostructures at 0 °C.

Description: Eucalyptus grandis and E. dunnii have high productive potential in the South of Brazil, Uruguay, and central Argentina. This is based on the similarity of the climate and soil of these areas, which form an eco-region called Campos. However, previous results show that these species have differences in their distribution caused by the prioritization of Uruguayan soils for forestry, explained by the particular conditions of each site. In this study, the site variables (climate, soil, and topography) that better explain the distribution of both species were identified, and prediction models of current and future distribution were adjusted for different climate change scenarios (years 2050 and 2070). The distribution of E. grandis was associated with soil parameters, whereas for E. dunnii a greater effect of the climatic variables was observed. The ensemble biomod2 model was the most precise with regard to predicting the habitat for both species with respect to the simple models evaluated. For E. dunnii, the average values of the AUC, Kappa, and TSS index were 0.98, 0.88, and 0.77, respectively. For E. grandis, their values were 0.97, 0.86, and 0.80, respectively. In the projections of climatic change, the distribution of E. grandis occurrence remains practically unchanged, even in the scenarios of temperature increase. However, current distribution of E. dunnii shows high susceptibility in a scenario of increased temperature, to the point that most of the area currently planted may be at risk. Our results might be useful to political government and foresters for decision making in terms of future planted areas.

Description: This research group has recently used the new technology Distributed Acoustic Sensing (DAS) for the monitoring and the measurement of airplane flutter. To the authors’ knowledge, this is the first such use for this new technology. Traditionally, the measurement of airplane flutter requires the mounting of a very large number of sensors on the wing being monitored, and extensive wiring must be connected to all these sensors. The new system and technology introduced in this paper dramatically reduces the hardware requirements in such an application: all the traditional sensors and wiring are replaced with one fiber optic cable with a diameter of 2 mm. An electro-optical system with the size of a desktop PC monitors simultaneously one or more of such fiber optic cables and detects/characterizes any mechanical disturbances on the cables. Theoretical and experimental results are given.

Description: Landscape connectivity is increasingly promoted as a conservation tool to combat the negative effects of habitat loss, fragmentation, and climate change. Given its importance as a key conservation strategy, connectivity science is a rapidly growing discipline. However, most landscape connectivity models consider connectivity for only a single snapshot in time, despite the widespread recognition that landscapes and ecological processes are dynamic. In this paper, we discuss the emergence of dynamic connectivity and the importance of including dynamism in connectivity models and assessments. We outline dynamic processes for both structural and functional connectivity at multiple spatiotemporal scales and provide examples of modeling approaches at each of these scales. We highlight the unique challenges that accompany the adoption of dynamic connectivity for conservation management and planning in the context of traditional conservation prioritization approaches. With the increased availability of time series and species movement data, computational capacity, and an expanding number of empirical examples in the literature, incorporating dynamic processes into connectivity models is more feasible than ever. Here, we articulate how dynamism is an intrinsic component of connectivity and integral to the future of connectivity science.

Description: Although compacted soil can be recovered through root development of planted seedlings, the relationship between root morphologies and soil physical properties remain unclear. We investigated the impacts of soil compaction on planted hybrid larch F1 (Larix gmelinii var. japonica×L. kaempferi, hereafter F1) seedlings with/without N loading. We assumed that N loading might increase the fine root proportion of F1 seedlings under soil compaction, resulting in less effects of root development on soil recovery. We established experimental site with different levels of soil compaction and N loading, where two-year-old F1 seedlings were planted. We used a hardness change index (HCI) to quantify a degree of soil hardness change at each depth. We evaluated root morphological responses to soil compaction and N loading, focusing on ectomycorrhizal symbiosis. High soil hardness reduced the total dry mass of F1 seedlings by more than 30%. Significant positive correlations were found between HCI and root proportion, which indicated that F1 seedling could enhance soil recovery via root development. The reduction of fine root density and its proportion due to soil compaction was observed, while these responses were contrasting under N loading. Nevertheless, the relationships between HCI and root proportion were not changed by N loading. The relative abundance of the larch-specific ectomycorrhizal fungi under soil compaction was increased by N loading. We concluded that the root development of F1 seedling accelerates soil recovery, where N loading could induce root morphological changes under soil compaction, resulting in the persistent relationship between root development and soil recovery.

Description: Leaf rust (LR) and stem rust (SR) pose serious challenges to wheat production in Kazakhstan. In recent years, the susceptibility of local wheat cultivars has substantially decreased grain yield and quality. Therefore, local breeding projects must be adjusted toward the improvement of LR and SR disease resistances, including genetic approaches. In this study, a spring wheat segregating population of Pamyati Azieva (PA) × Paragon (Par), consisting of 98 recombinant inbred lines (RILs), was analyzed for the resistance to LR and SR at the seedling and adult plant-growth stages. In total, 24 quantitative trait loci (QTLs) for resistance to rust diseases at the seedling and adult plant stages were identified, including 11 QTLs for LR and 13 QTLs for SR resistances. Fourteen QTLs were in similar locations to QTLs and major genes detected in previous linkage mapping and genome-wide association studies. The remaining 10 QTLs are potentially new genetic factors for LR and SR resistance in wheat. Overall, the QTLs revealed in this study may play an important role in the improvement of wheat resistance to LR and SR per the marker-assisted selection approach.

Description: Chili pepper (Capsicum spp.) is one of the most economically important horticultural crops in the world; its production for the food and pharmaceutical industries has been increasing worldwide. The economic importance of this crop is due, in part, to the nutraceutical properties derived from its secondary metabolism. Drought is the main environmental factor that affects crop production. Nevertheless, studies involving water deficit have considered short-term responses to sharp water deficit rather than long-term acclimation processes through moderate and gradually increasing water deficits, which omitted the dynamics and profile of the secondary metabolism that are part of the plant’s defence system against this stress factor. The present study aimed to identify the different mechanisms that chili pepper plants use to cope with drought stress using a progressive decrease and increase of water availability, conditions that commonly occur for crops in open fields. Four treatments were applied as follows: gradual water deficit (GWD), initial waterlogging with gradual water deficit (IWGD), sudden water deficit with gradual recovery (SWDR), and no deficit of water (NDW). These conditions should represent a more real situation similar to that faced by plants in the agricultural environment. In order to evaluate the response mechanisms associated with these water deficits, changes in phenological variables, proline accumulation, and the gene expression of phenylalanine ammonia-lyase (PAL), chalcone synthase (CHS), peroxidase (POD), and superoxide dismutase (SOD) were measured in chili pepper plants growing on land under different irrigation regimes in two contrasting soil types in areas where chili pepper plants are cultivated in central Mexico. The variables evaluated showed a differentiated response of the mechanisms in plants growing under different levels of water deficit. Given the differential response observed for the gene expression and morphological and biochemical variables studied in chili pepper plants against different water regimes, in this work, this may have implications for more efficient use of water in crops with high nutraceutical content, in addition to prospects for using products derived from secondary metabolism in the pharmaceutical industry.

Description: Climate change has the potential to disrupt ecosystem services and further exacerbate the effects of human activities on natural resources. This has significant implications for educational institutions and the populations they serve. As the current crop of landscape architecture students struggles to define its role within the climate crisis and its related social and political underpinnings, a core mission of colleges and universities moving forward should be to provide students with applied knowledge about how climate change affects the landscape. This goes beyond coursework in climate science or policy; for landscape architecture students to be leaders in the response to climate change, they need applied, practical skills. An ever-growing body of the literature focuses on landscape design strategies for climate change adaptation; however, few frameworks integrate these strategies with the hands-on experience students will need to face real-world challenges after graduation. Educational institutions have the potential to utilize their campuses as demonstration sites for applied ecosystem research programs and actively engage students with the design, implementation, politics, and ongoing stewardship of these landscapes. This paper uses a case study methodology to understand how experiential and public-engaged learning pedagogies contribute to student preparedness to address climate change. It examines three cases of engaged learning at the University of California, Davis campus and attributes their impact to intentional connections with research, to the delegation of responsibility; to the openness of spaces for experimentation, and to self-reflection that connects climate with everyday behavior. By promoting experiential learning programs that require students to actively use their heads and their hands to construct and sustainably manage their own campus landscapes, service-learning studios and internships can provide opportunities for students to address the real scenarios of climate crisis and resilience.

Description: The objective of our research is to improve the properties of calcium-sulphate hemihydrate parts printed by binder jetting. In this paper, we show the thermal treatment results when using temperature time ramps on binder-jetted ceramic parts without infiltrating. The results show that the mechanical properties of printed parts are improved substantially. Two different thermal cycles were investigated for their effect on the dehydration process of CaSO4·½H2O using infrared analysis. The thermal-treated samples were compared with respect to porosity, surface roughness, compression strength and dimensional and weight variation. The proposed thermal treatment significantly improves the compression strength in a short time, guaranteeing dimensional stability while providing a good surface. This improvement in mechanical properties offers a great chance for using binder-jetted parts as functional components, for example, in the casting field or the medical sector (scaffolds).

Description: As the use of continuous fiber polymer matrix composites expands into new fields, there is a growing need for more sustainable manufacturing processes. An integrated computational material design framework has been developed, which enables the design of tailored manufacturing systems for polymer matrix composite materials as a sustainable alternative to achieving high-quality components in high-rate production. Trapped rubber processing achieves high pressures during polymer matrix composite processing, utilizing the thermally induced volume change of a nearly incompressible material inside a closed cavity mold. In this interdisciplinary study, the structural analysis, material science and manufacturing engineering perspectives are all combined to determine the mold mechanics, and the manufacturing process in a cohesive and iterative design loop. This study performs the coupled thermo-mechanical analysis required to simulate the transients involved in composite manufacturing and the results are compared with a previously developed test method. The internal surface pressure and temperatures are computed, compared with the experimental results, and the resulting design process is simulated. Overall, this approach maintains high-quality consolidation during curing while allowing for the possibility for custom distributions of pressures and temperatures. This can lead to more sustainable manufacturing by reducing energy consumption and improving throughput.

Description: The aim of this study was to investigate the impact of distributed propulsion systems used on inland and coastal navigation in shallow water. Five layouts were assessed by computational fluid dynamics (CFD) simulation. The hull/propulsion layout cases have been analyzed for discrete flow speed values in the range 0–6 m/s. All cases have been examined under restricted draft conditions in shallow water with a minimum of 0.3 m under keel clearance (UKC) and under unrestricted draft conditions in deep water. The results show that distributed propulsion consisting of 6 or 8 (in some cases, even more) units produces noticeable higher thrust effects in shallow water than the traditional layout. Under restricted conditions, the thrust increase between two distributed layouts with different numbers of propulsors is higher, in contrast to deep water, where differences in performance are not so significant.

Description: Xenogenic collagen-based matrices represent an alternative to subepithelial palatal connective tissue autografts in periodontal and peri-implant soft tissue reconstructions. In the present study, we aimed to investigate the migratory, adhesive, proliferative, and wound-healing potential of primary human oral fibroblasts (hOF) and periodontal ligament cells (hPDL) in response to four commercially available collagen matrices. Non-crosslinked collagen matrix (NCM), crosslinked collagen matrix (CCM), dried acellular dermal matrix (DADM), and hydrated acellular dermal matrix (HADM) were all able to significantly enhance the ability of hPDL and hOF cells to directionally migrate toward the matrices as well as to efficiently repopulate an artificially generated wound gap covered by the matrices. Compared to NCM and DADM, CCM and HADM triggered stronger migratory response. Cells grown on CCM and HADM demonstrated significantly higher proliferative rates compared to cells grown on cell culture plastic, NCM, or DADM. The pro-proliferative effect of the matrices was supported by expression analysis of proliferative markers regulating cell cycle progression. Upregulated expression of genes encoding the adhesive molecules fibronectin, vinculin, CD44 antigen, and the intracellular adhesive molecule-1 was detected in hPDL and hOF cells cultured on each of the four matrices. This may be considered as a prerequisite for good adhesive properties of the four scaffolds ensuring proper cell–matrix and cell–cell interactions. Upregulated expression of genes encoding TGF-β1 and EGF growth factors as well as MMPs in cells grown on each of the four matrices provided support for their pro-proliferative and pro-migratory abilities. The expression of genes encoding the angiogenic factors FGF-2 and VEGF-A was dramatically increased in cells grown on DADM and HADM only, suggesting a good basis for accelerated vascularization of the latter. Altogether, our results support favorable influence of the investigated collagen matrices on the recruitment, attachment, and growth of cell types implicated in oral soft tissue regeneration. Among the four matrices, HADM has consistently exhibited stronger positive effects on the oral cellular behavior. Our data provide solid basis for future investigations on the clinical application of the collagen-based matrices in surgical periodontal therapy.

Description: We evaluated surface-based analysis for assessing the possible relationship between the microstructural properties and particulate matter (i.e., two size fractions of PM2.5 and PM10) adsorption efficiencies of their leaf surfaces on ten woody species. We focused on the effect of PM adsorption capacity between micro-morphological features on leaf surfaces using a scanning electron microscope and a non-contact surface profiler as an example. The species with higher adsorption of PM10 on leaf surfaces were Korean boxwood (Buxus koreana Nakai ex Chung & al.) and evergreen spindle (Euonymus japonicus Thunb.), followed by yulan magnolia (Magnolia denudata Desr.), Japanese yew (Taxus cuspidata Siebold & Zucc.), Japanese horse chestnut (Aesculus turbinata Blume), retusa fringetree (Chionanthus retusus Lindl. & Paxton), maidenhair tree (Ginkgo biloba L.), and royal azalea (Rhododendron schlippenbachii Maxim.). There was a higher capacity for the adsorption of PM2.5 on the leaf surfaces of B. koreana and T. cuspidata, followed by A. turbinata, C. retusus, E. japonicus, G. biloba, and M. denudata. In wax layer tests, T. cuspidata, A. turbinata, R. schlippenbachii, and C. retusus showed a statistically higher PM2.5 capturing capacity than the other species. Different types of trichomes were distributed on the adaxial and abaxial leaves of A. turbinata, C. retusus, M. denudata, pagoda tree (Styphnolobium japonicum (L.) Schott), B. koreana, and R. schlippenbachii; however, these trichomes were absent on both sides of the leaves of G. biloba, tuliptree (Liriodendron tulipifera L.), E. japonicus, and T. cuspidata. Importantly, leaf surfaces of G. biloba and S. japonicum with dense or thick epicuticular leaf waxes and deeper roughness revealed lower PM adsorption. Based on the overall performance of airborne PM capture efficiency, evergreen species such as B. koreana, T. cuspidata, and E. japonicus showed the best results, whereas S. japonicum and L. tulipifera had the lowest capture. In particular, evergreen shrub species showed higher PM2.5 depositions inside the inner wall of stomata or the periphery of guard cells. Therefore, in leaf microstructural factors, stomatal size may be related to notably high PM2.5 holding capacities on leaf surfaces, but stomatal density, trichome density, and roughness had a limited effect on PM adsorption. Finally, our findings indicate that surface-based microstructures are necessarily not a correlation for corresponding estimates with leaf PM adsorption.

Description: Concrete wastewater infrastructures are important to modern society but are susceptible to sulfuric acid attack when exposed to an aggressive environment. Fibre-reinforced mortar has been adopted as a promising coating and lining material for degraded reinforced concrete structures due to its unique crack control and excellent anti-corrosion ability. This paper aims to evaluate the performance of polyethylene (PE) fibre-reinforced calcium aluminate cement (CAC)–ground granulated blast furnace slag (GGBFS) blended strain-hardening mortar after sulfuric acid immersion, which represented the aggressive sewer environment. Specimens were exposed to 3% sulfuric acid solution for up to 112 days. Visual, physical and mechanical performance such as water absorption ability, sorptivity, compressive and direct tensile strength were evaluated before and after sulfuric acid attack. In addition, micro-structure changes to the samples after sulfuric acid attack were also assessed by X-Ray Diffraction (XRD) and Scanning Electron Microscopy (SEM) to further understand the deterioration mechanism. The results show that overall fibre-reinforced calcium aluminate cement (CAC)-based samples performed significantly better than fibre-reinforced ordinary Portland cement (OPC)-based samples as well as mortar samples in sulfuric acid solution in regard to visual observations, penetration depth, direct tensile strength and compressive reduction. Gypsum generation in the cementitious matrix of both CAC and OPC-based systems was the main reason behind the deterioration mechanism after acid attack exposure. Moreover, laboratory sulfuric acid testing has been proven for successfully screening the cementitious material against an acidic environment. This method can be considered to design the service life of concrete wastewater pipes.

Description: The most massive and fast-eroding thaw slump of the Northern Hemisphere located in the Yana Uplands of Northern Yakutia was investigated to assess in detail the cryogenic inventory and carbon pools of two distinctive Ice Complex stratigraphic units and the uppermost cover deposits. Differentiating into modern and Holocene near-surface layers (active layer and shielding layer), highest total carbon contents were found in the active layer (18.72 kg m−2), while the shielding layer yielded a much lower carbon content of 1.81 kg m−2. The late Pleistocene upper Ice Complex contained 10.34 kg m−2 total carbon, and the mid-Pleistocene lower Ice Complex 17.66 kg m−2. The proportion of organic carbon from total carbon content is well above 70% in all studied units with 94% in the active layer, 73% in the shielding layer, 83% in the upper Ice Complex and 79% in the lower Ice Complex. Inorganic carbon is low in the overall structure of the deposits.

Description: Incorporating various industrial waste materials into concrete has recently gained attention for sustainable construction. This paper, for the first time, studies the effects of silica stone waste (SSW) powder on concrete. The cement of concrete was replaced with 5, 10, 15, and 20% of the SSW powder. The mechanical properties of concrete, such as compressive and tensile strength, were studied. Furthermore, the microstructure of concrete was studied by scanning electron microscopy (SEM), energy-dispersive X-ray spectroscopy analysis (EDX), Fourier transformed infrared spectroscopy (FTIR), and X-Ray diffraction (XRD) tests. Compressive and tensile strength of samples with 5% SSW powder was improved up to 18.8% and 10.46%, respectively. As can be observed in the SEM images, a reduced number of pores and higher density in the matrix can explain the better compressive strength of samples with 5% SSW powder.

Description: This paper presents a study of the Ti-6Al-4V alloy milling under different lubrication conditions, using the minimum quantity lubrication approach. The chosen material is widely used in the industry due to its properties, although they present difficulties in terms of their machinability. A minimum quantity lubrication (MQL) prototype valve was built for this purpose, and machining followed a previously defined experimental design with three lubrication strategies. Speed, feed rate, and the depth of cut were considered as independent variables. As design-dependent variables, cutting forces, torque, and roughness were considered. The desirability optimization function was used in order to obtain the best input data indications, in order to minimize cutting and roughness efforts. Supervised artificial neural networks of the multilayer perceptron type were created and tested, and their responses were compared statistically to the results of the factorial design. It was noted that the variables that most influenced the machining-dependent variables were the feed rate and the depth of cut. A lower roughness value was achieved with MQL only with the use of cutting fluid with graphite. Statistical analysis demonstrated that artificial neural network and the experimental design predict similar results.

Description: BiFeO3 nanocrystals were applied as the sensing material to isopropanol. The isopropanol sensor based on BiFeO3 nanocrystals shows excellent gas-sensing properties at the optimum working temperature of 240 °C. The sensitivity of as-prepared sensor to 100 ppm isopropanol is 31 and its response and recovery time is as fast as 6 and 17 s. The logarithmic curves of the sensitivity and concentration of BiFeO3 sensors are a very good linear in the low detection range of 2–100 ppm. In addition, the gas sensing mechanism is also discussed. The results suggest that the BiFeO3 nanomaterial can be potentially applied in isopropanol gas detection.

Description: For the first time, an original compound belonging to the heptazine family has been deposited in the form of thin layers, both by thermal evaporation under vacuum and spin-coating techniques. In both cases, smooth and homogeneous layers have been obtained, and their properties evaluated for eventual applications in the field of organic electronics. The layers have been fully characterized by several concordant techniques, namely UV-visible spectroscopy, steady-state and transient fluorescence in the solid-state, as well as topographic and conductive atomic force microscopy (AFM) used in Kelvin probe force mode (KPFM). Consequently, the afferent energy levels, including Fermi level, have been determined, and show that these new heptazines are promising materials for tailoring the electronic properties of interfaces associated with printed electronic devices. A test experiment showing an improved electron transfer rate from a tris-(8-hydroxyquinoline) aluminum (Alq3) photo-active layer in presence of a heptazine interlayer is finally presented.

Description: A possible approach for providing new properties for textiles is the insertion of natural ingredients into the textile product during the process of its manufacture. Myrrh has long been used in medicine as an antibacterial and antifungal material. Polylactide (PLA) is a thermoplastic synthetic biopolymer obtained from renewable resources—and due its biodegradability, is also widely used in medicine. In this study, films and multifilament yarns from modified biodegradable PLA granules with ethanolic and aqueous myrrh extracts were developed and characterized. Optical microscopy was used to determine the surface morphology of PLA/myrrh multifilament yarns. Tensile tests, ultraviolet-visible (UV-vis), differential scanning calorimetry (DSC) were applied to determine, consequently, mechanical, optical properties and degree of crystallinity of PLA/myrrh films and multifilament yarns. The chemical composition of PLA/myrrh multifilament yarns was estimated by Fourier-transform infrared (FTIR) spectroscopy method. The results showed that it is possible to form PLA melt-spun multifilament yarns with myrrh extract. The type of myrrh extract (ethanolic or aqueous) has a significant influence on the mechanical and optical properties of the PLA films and melt-spun yarns. The mechanical properties of PLA films and melt-spun multifilament yarns formed from PLA granules with aqueous myrrh extract decreased 19% and 21% more than PLA with ethanolic extract, respectively. Analysis of UV-vis spectra showed that, due to the yellow hue, the reflectance of PLA films and melt-spun PLA multifilament yarns modified with myrrh extracts decreased exponentially. The DSC test showed that multifilament yarns from PLA modified with aqueous extract had the highest degree of crystallization.

Description: Organic amendments can reportedly sustain and increase lowland rice productivity in smallholder systems. Few studies have assessed locally-available substrates in hydrologically variable floodplain environments. We investigated the effects of green and farmyard manures on rice yields, and total soil C and N in the Kilombero floodplain, Tanzania. At both the fringe and the middle positions, five treatments were applied in 2016 and 2017, comprising (1) non-amended control, (2) farmyard manure, (3) pre-rice legumes, (4) post-rice legumes and (5) a combination of green and farmyard manures. Residual treatment effects were assessed in 2018 when rice plots were uniformly non-amended. Depending on the year and the position, organic amendments increased rice grain yields by 0.7–3.1 Mg ha–1 above the non-amended control. Sole green and farmyard manure applications had similar effects on grain yield, while a combination of green and farmyard manure led to a significant increase in grain yield above both the control and sole applications of organic amendments in both years. The contribution from biological N2 fixation by legumes ranged from 4 to 61 kg N ha–1. Despite partial N balances being mostly negative, we observed positive residual effects on the yield of the non-amended rice in the third year. Such effects reached up to 4 Mg ha−1 and were largest with post-rice legumes, sole or combined with farmyard manure. Irrespective of the position in the floodplain, manures significantly increased soil C and N contents after two years, hence enhancing soil fertility and resulting in increased rice grain yields. Comparable benefits may be obtained along the hydrological gradients of other large river floodplains of the region and beyond.

Description: This paper primarily assesses the scale of adverse changes to the compressive strength of different types of silicates due to the influence of moisture. The study covers three groups of silicate units of different strength classes—15, 20 and 25—obtained from three different manufacturers. It was demonstrated that in all studied groups, moisture significantly decreased the compressive strength by about 30–40%. In addition, microstructural studies were conducted to analyze the relationship between the specific porosity structure of each group of silicate bricks and their compressive strength. On the basis of SEM (Scanning Electron Microscopy) and EDS (Electron Dispersive Spectroscopy) analysis, the elemental composition of individual silicates was determined and the contact zone between the aggregate and the binder was determined, which largely influenced the obtained compressive strength of each silicates. Next, the study referred to the utility of the normative procedure used to determine the strength class of samples with different geometries and at different moisture concentrations. The results of the calculations showed the high accuracy of the normative-based assessment of strength class, regardless of the manufacturer and the moisture values during examination.

Description: Additive manufacturing (AM) is the term for a number of processes for joining materials to build physical components from a digital 3D model. AM has multiple advantages over other construction techniques, such as freeform, customization, and waste reduction. However, AM components have been evaluated by destructive and non-destructive testing and have shown mechanical issues, such as reduced resistance, anisotropy and voids. The build direction affects the mechanical properties of the built part, including voids of different characteristics. The aim of this work is an extended analysis of void shape by means of X-ray computed tomography (CT) applied to fused deposition modeling (FDM) samples. Furthermore, a relation between the tensile mechanical properties and digital void measurements is established. The results of this work demonstrate that void characteristics such as quantity, size, sphericity and compactness show no obvious variations between the samples. However, the angle between the main void axis and the mechanical load axis α shows a relation for FDM components: when its mean value μ(α) is around 80 (degrees) the yield strength and Young’s modulus are reduced. These results lead to the formulation of a novel criterion that predicts the mechanical behavior of AM components.

Description: The aim of this study was to analyse the genetic and phenotypic differentiation of bacteria isolated from root nodules of Trifolium rubens, a rare clover species. The symbiotic compatibility of selected isolates was investigated using two agronomically important plants, red clover (Trifolium pratense L.) and pea (Pisum sativum L.). A high genetic diversity of analysed strains was shown using the Enterobacterial Repetitive Intergenic Consensus Polymerase Chain Reaction (ERIC-PCR) method. Most of the strains showed a high similarity to R. leguminosarum in the 16S rRNA sequence. Two strains were identified as Agrobacterium spp. There was a strong positive correlation between fresh clover weight and the number of root nodules and a statistically significant increase in the number of the root nodules in selected strains compared to the negative control. Phenotypic tests and BIOLOG analysis showed the ability of the analysed strains to grow in different experimental conditions (pH = 6–10, 0.5–3% NaCl, different carbon and nitrogen sources), which makes them suitable for application as an agronomically important factor.

Description: The objective of this work is to study the geometric properties of surface topographies of hot-work tool steel created by electric discharge machining (EDM) using motif and multiscale analysis. The richness of these analyses is tested through calculating the strengths of the correlations between discharge energies and resulting surface characterization parameters, focusing on the most representative surface features—craters, and how they change with scale. Surfaces were created by EDM using estimated energies from 150 to 9468 µJ and measured by focus variation microscope. The measured topographies consist of overlapping microcraters, of which the geometry was characterized using three different analysis: conventional with ISO parameters, and motif and multiscale curvature tensor analysis. Motif analysis uses watershed segmentation which allows extraction and geometrically characterization of each crater. Curvature tensor analysis focuses on the characterization of principal curvatures and their function and their evolution with scale. Strong correlations (R2 〉 0.9) were observed between craters height, diameter, area and curvature using linear and logarithmic regressions. Conventional areal parameter related to heights dispersion were found to correlate stronger using logarithmic regression. Geometric characterization of process-specific topographic formations is considered to be a natural and intuitive way of analyzing the complexity of studied surfaces. The presented approach allows extraction of information directly relating to the shape and size of topographic features of interest. In the tested conditions, the surface finish is mostly affected and potentially controlled by discharge energy at larger scales which is associated with sizes of fabricated craters.

Description: Ecuador Andean purple corn (Zea mays L.) was subjected to a germination process at 15–40 °C for 24–168 incubation hours. Purple corn protein concentrates (PCPCs) were obtained by alkaline extraction at pH 8.0 and pH 10.0, followed by an isoelectric precipitation process at pH 4.0, pH 5.0 and pH 6.0. Proteins and phenolic content of PCPCs was calculated. PCPC antioxidant properties were determined by the ferric-reducing antioxidant power (FRAP) in vitro method and by the 2,2-azinobis, 3-ethyl-benzothiazoline-6-sulfonic acid, (ABTS) in vitro method. Andean purple corn seeds were able to germinate under the germination conditions tested in this study. The higher percentage of germination was of 63.33% at 168 h/25 °C. The PCPCs protein profile was characterized for the presence of six bands with molecular weights of 14.50 kDa, 20.12 kDa, 25.18 kDa, 41.85 kDa, 59.59 kDa, and 65.87 kDa. Germinated PCPC presented a high TPC content with ranges of 605.71–1820.00 mg gallic acid equivalents (GAE)/g PCPC dry weight (DW), germinated PCPC/72 h/25 °C presented a higher value of 1820.00 mg GAE/g PCPC, DW. All germinated PCPCs samples assayed presented strong antioxidant activity when measured by the ABTS and FRAP methods. Germinated PCPC/144 h/35 °C presented high antioxidant activity by ABTS with 804.35 µmol Trolox equivalents (TE)/g PCPC DW and germinated PCPC/144 h/30 °C presented a high value by the FRAP method, 987.83 µmol TE/g PCPC DW.

Description: Weedy rice is one of the most common weeds in rice cultivation in many rice areas throughout the world and it is able to cause significant yield reductions. Weedy rice is characterized by a high biological diversity that permits different populations to be identified on the basis of their morphological and physiological traits. This variability contributes to its success in different environments and allows different abiotic stresses, which are intensified by climate change, to be faced. Taller plants, enhanced tillering, seed shattering and the presence of red pericarp, variable hull coloration and awn morphology, linked to a deeper seed dormancy, are some of the traits that help weedy rice to spread in changing environments. The higher phenotypic plasticity and genetic variability of weedy rice make it more able to cope with temperature variations, intermittent water availability, soil salinity, drought conditions and increased CO2 concentrations than cultivated rice. As these abiotic stresses will become more frequent in the future, weedy rice competitiveness may be higher, with a spread of infestations. Thus, the control of weedy rice should be based on an integration of different preventive and agronomic techniques, a sensible use of herbicides and the use of suitable rice varieties.

Description: Laser irradiation is a popular method to produce microtextures on metal surfaces. However, the common laser-produced microtextures were hierarchical (multiscale), which may limit their applicability. In this paper, a method of two-step laser irradiation, combining first-step strong ablation and sequentially second-step gentle ablation, was presented to produce micron-rough surface with single-scale microtextures. The effect of laser fluence on the Ti–6Al–4V surface morphology and wettability were investigated in detail. The morphology results revealed that the microtextures produced using this method gradually evolved from multiscale to single-scale meanwhile from microprotrusions to microholes with increasing the second-step laser fluence from 0.0 to 2.4 J/cm2. The wettability and EDS/XPS results indicated that attributing to the rich TiO2 content and micron roughness produced by laser irradiation, all the two-step laser-irradiated surfaces exhibited superhydrophilicity. In addition, after silanization, all these superhydrophilic surfaces immediately turned to be superhydrophobic with close water contact angles of 155–162°. However, due to the absence of nanotextures, the water-rolling angle on the superhydrophobic surfaces with single-scale microtextures distinctly larger than those with multiscale ones. Finally, using the two-step laser-irradiation method and assisted with silanization, multifunctional superhydrophobic Ti–6Al–4V surfaces were achieved, including self-cleaning, guiding of the water-rolling direction and anisotropic water-rolling angles (like the rice-leaf), etc.

Description: The ultrasonic modulation technique, developed by inspecting the nonlinearity from the interactions of crack surfaces, has been considered very effective in detecting fatigue cracks in the early stage of the crack development due to its high sensitivity. The wave modulation is the frequency shift of a wave passing through a crack and does not occur in intact specimens. Various parameters affect the modulation of the wave, but quantitative analysis for each variable has not been comprehensively conducted due to the complicated interaction of irregular crack surfaces. In this study, specimens with a constant crack width are manufactured, and the effects of various excitation parameters on modulated wave generation are analyzed. Based on the analysis, an effective crack detection algorithm is proposed and verified by applying the algorithm to fatigue cracks. For the quantitative analysis, tests are repeatedly conducted by varying parameters. As a result, the excitation intensity shows a strong linear relationship with the amount of modulated waves, and the increase of modulated wave is expected as crack length increases. However, the change in the dynamic characteristics of the specimen with the crack length is more dominant in the results. The excitation frequency is the most dominant variable to generate the modulated waves, but a direct correlation is not observed as it is difficult to measure the interaction of crack surfaces. A numerical analysis technique is developed to accurately simulate the movement and interaction of the crack surface. The crack detection algorithm, improved by using the observations from the quantitative analyses, can distinguish the occurrence of modulated waves from the ambient noises, and the state of the specimens is determined by using two nonlinear indexes.

Description: This study aimed to develop series analytical solutions based on the Mindlin plate theory for the free vibrations of functionally graded material (FGM) rectangular plates. The material properties of FGM rectangular plates are assumed to vary along their thickness, and the volume fractions of the plate constituents are defined by a simple power-law function. The series solutions consist of the Fourier cosine series and auxiliary functions of polynomials. The series solutions were established by satisfying governing equations and boundary conditions in the expanded space of the Fourier cosine series. The proposed solutions were validated through comprehensive convergence studies on the first six vibration frequencies of square plates under four combinations of boundary conditions and through comparison of the obtained convergent results with those in the literature. The convergence studies indicated that the solutions obtained for different modes could converge from the upper or lower bounds to the exact values or in an oscillatory manner. The present solutions were further employed to determine the first six vibration frequencies of FGM rectangular plates with various aspect ratios, thickness-to-width ratios, distributions of material properties and combinations of boundary conditions.

Description: Conventional technologies for ureteral stent fabrication suffer from major inconveniences such as the development of encrustations and bacteria biofilm formation. These drawbacks typically lead to the failure of the device, significant patient discomfort and an additional surgery to remove and replace the stent in the worst cases. This work focuses on the preparation of a new nanocomposite material able to show drug elution properties, biodegradation and eventually potential antibacterial activity. Poly(2-hydroxyethyl methacrylate) or the crosslinked poly(2-hydroxyethyl methacrylate)-co-poly(acrylic acid) hydrogels were prepared by the radical polymerization method and combined with a biodegradable and antibacterial filling agent, i.e., flower-like Zinc Oxide (ZnO) micropowders obtained via the hydrothermal route. The physico-chemical analyses revealed the correct incorporation of ZnO within the hydrogel matrix and its highly mesoporous structure and surface area, ideal for drug incorporation. Two different anti-inflammatory drugs (Ibuprofen and Diclofenac) were loaded within each composite and the release profile was monitored up to two weeks in artificial urine (AU) and even at different pH values in AU to simulate pathological conditions. The addition of mesoporous ZnO micropowders to the hydrogel did not negatively affect the drug loading properties of the hydrogel and it was successfully allowed to mitigate undesirable burst-release effects. Furthermore, the sustained release of the drugs over time was observed at neutral pH, with kinetic constants (k) as low as 0.05 h−1. By exploiting the pH-tunable swelling properties of the hydrogel, an even more sustained release was achieved in acidic and alkaline conditions especially at short release times, with a further reduction of burst effects (k ≈ 0.01–0.02 h−1). The nanocomposite system herein proposed represents a new material formulation for preparing innovative drug eluting stents with intrinsic antibacterial properties.

Description: Testing Fusarium resistance to ear rots in maize requires a well-supported methodology and tests for toxin responses. In this study, commercial hybrids were tested for resistance to Fusarium graminearum, Fusarium culmorum, and Fusarium verticillioides (kernel and silk channel), as well as their toxin response. One third of the hybrids tested showed a similar resistance or susceptibility to the three pathogens and their toxin response, but there is no proof for their genetic background being the same or different. The performance of the remaining hybrids was highly variable and supports the idea of different genetic regulation. The mean ear rot severity of the kernel resistance was doubled compared with the silk channel resistance data. The ear rot and toxin tests displayed significant positive correlations, verifying the decisive role of resistance in toxin regulation. Several hybrids, termed toxigenic hybrids, showed significant extra toxin production, indicating an additional food safety risk. The toothpick method gave more reliable results and a better differentiation of genotypes. The resistance to different Fusarium spp. in a specific growing region should be analyzed separately in independent resistance tests. Through this, the food safety risks could be better identified. Susceptible hybrids should not be used for commercial production.

Description: The capture of a target spacecraft by a chaser is an on-orbit docking operation that requires an accurate, reliable, and robust object recognition algorithm. Vision-based guided spacecraft relative motion during close-proximity maneuvers has been consecutively applied using dynamic modeling as a spacecraft on-orbit service system. This research constructs a vision-based pose estimation model that performs image processing via a deep convolutional neural network. The pose estimation model was constructed by repurposing a modified pretrained GoogLeNet model with the available Unreal Engine 4 rendered dataset of the Soyuz spacecraft. In the implementation, the convolutional neural network learns from the data samples to create correlations between the images and the spacecraft’s six degrees-of-freedom parameters. The experiment has compared an exponential-based loss function and a weighted Euclidean-based loss function. Using the weighted Euclidean-based loss function, the implemented pose estimation model achieved moderately high performance with a position accuracy of 92.53 percent and an error of 1.2 m. The in-attitude prediction accuracy can reach 87.93 percent, and the errors in the three Euler angles do not exceed 7.6 degrees. This research can contribute to spacecraft detection and tracking problems. Although the finished vision-based model is specific to the environment of synthetic dataset, the model could be trained further to address actual docking operations in the future.

Description: The study’s objective was to evaluate the influence of thinning on the quality and regularity of yield of ‘Regina’ cherries grown on a dwarf Gisela 5 rootstock. The experiments were conducted in the years 2009–2012 in Western Poland. Trees were thinned using a chemical agent, ammonium thiosulphate (ATS), at doses of 20 g ATS L−1, 30 g ATS L−1 and 40 g ATS L−1, and by hand, and the results of chemical and hand thinning were compared with those obtained for unthinned trees. The course of weather conditions in winter and during flowering had a significant impact on yield. Chemical thinning is known to be an effective method to regulate fruiting of pome trees, but it can also be successful if applied to cherry trees, as reflected by the alternate bearing index, which was the lowest after applying ATS at a dose of 40 g. ATS treatment improved fruit quality in full crop years. Thinning resulted in, among other things, larger and darker fruit and higher content of total soluble solids and titratable acidity. Treatment with 40 g ATS L−1 significantly stimulated the vegetative growth of trees.

Description: Emerald ash borer is an invasive pest in North American forests. Ecological impacts of ash mortality from emerald ash borer are wide-ranging, including shifts in insect communities and wildlife behavior. Additionally, loss of ash from forests may have important implications regarding plant succession. Surveys of overstory, midstory, and understory trees within forests in northeastern Indiana, Lower Peninsula of Michigan, and northwestern Ohio were conducted to quantify the change in forest composition over a 10 year period. Interpolation of ash dominance illustrated inversion of live and dead ash values between 2007 and 2017. Even though more than 83% of overstory live ash basal area was lost across the study area, green ash was the most abundant midstory and understory species representing regeneration. Additionally, loss of ash from many of the sites resulted in compositional changes that were greater than merely the subtraction of ash. Due to the relatively large number of forest types with which ash species are associated, loss of ash will have broad ecological consequences, including on community composition.

Description: In view of the strong constraint zones of the concrete structure on the pile foundation, there are some differences between the calculation results of the isotropic equivalent pile foundation by the volume replacement ratio method and the actual engineering. In this paper, referring to the relevant algorithm of rock mass with anchor, the anchor and rock mass are, respectively, compared to pile and surrounding soil foundation. Eshelby equivalent inclusion theory is introduced into the equivalent mechanical model of soil foundation with pile, and a new equivalent pile foundation algorithm considering anisotropic elastic constant is compiled by Fortran. Three kinds of calculation methods are used to calculate the stress field of the concrete structure of the large pump station on the pile foundation during the construction period, and the stress in the strong constraint zones of the concrete structure are mainly analyzed. It is found that the calculation accuracy of Algorithm 3 is the highest, and the calculation results of Algorithm 2 can be modified by the coefficients to achieve the calculation accuracy of Algorithm 3 and the calculation efficiency is actually improved. Finally, the accuracy of the proposed method is verified by the engineering measured data.

Description: Aircrafts require a large amount of fuel in order to generate enough power to perform a flight. That consumption causes the emission of polluting particles such as carbon dioxide, which is implicated in global warming. This paper proposes an algorithm which can provide the 3D reference trajectory that minimizes the flight costs and the fuel consumption. The proposed algorithm was conceived using the Floyd–Warshall methodology as a reference. Weather was taken into account by using forecasts provided by Weather Canada. The search space was modeled as a directional weighted graph. Fuel burn was computed using the Base of Aircraft DAta (BADA) model developed by Eurocontrol. The trajectories delivered by the developed algorithm were compared to long-haul flight plans computed by a European airliner and to as-flown trajectories obtained from Flightradar24®. The results reveal that up to 2000 kg of fuel can be reduced per flight, and flight time can be also reduced by up to 11 min.

Description: Since 2006, an increasing number of French vineyards have chosen to convert to organic farming. One major change in vineyard practices includes replacing chemical pesticides with copper and sulfur-based products in line with Council Regulation (EC) No. 834/2007. This change can make overall management and pest and disease control more difficult and potentially lead to yield losses. From 2013 to 2016, a network of 48 vineyard plots, in southern France, under conventional management and in conversion to organic farming were monitored throughout the three-year conversion phase to investigate the grapevine phytosanitary management of four major pests and diseases and variations in control efficiency. The severity of downy and powdery mildew, grape berry moths, and Botrytis bunch rot were assessed and linked to the protection strategy. The findings showed that pests and diseases were controlled in the third year of conversion at similar efficiency levels as in conventional farming. However, the first two years of conversion were a transitional and less successful period during which higher incidences of cryptogamic diseases were observed. This demonstrates a need for winegrowers to receive more in-depth technical advice and support, especially on pest and disease control, during this critical transition period.

Description: Increasing demands on animal welfare and the higher temperatures in summer due to climate change make it necessary to adapt conventional pig husbandry systems. A cooled, solid lying area has the potential to increase lying comfort and reduce the heat stress, which improves animal welfare. In the present study, the effect of a cooled, solid lying area on lying and elimination behavior was investigated. In two fattening compartments, eight pens with 28 pigs each were rebuilt. Two pen designs, different in feeder place and type, were tested. The floor was cooled from 24.5 to 20 °C by cool water in half of the pens. A total of 672 fattening pigs were tested over three fattening periods. The lying behavior was recorded by video analysis three times per week and three times per day. In the pens with a cooled lying area, 14% (SED 2.9; p = 0.002), respectively 12% (SED 0.9; p = 0.0382) more pigs were lying on the solid lying area. Additionally, the fouling of the animals was reduced by the cooling in one pen design; the results were derived from weekly scores (0.42 vs. 0.67; SED 0.058 p = 0.0006). The fouling of the pen was not affected by the floor cooling, however, the fouling in all pens was very low.

Description: The sugarcane (Saccharum spp. L.) mechanical harvesting system leaves a large amount of straw mulch on the soil surface. The straw mulch may affect soil conditions, root regrowth, and sugarcane yield. Thus, this study assessed the response of sugarcane root system growth and stalk yield to different rates of straw removal. An experiment was conducted in a Rhodic Kandiudox with sand clay loam texture to test the impact of four rates of straw removal: no removal (18.9 Mg ha−1 of dry mass); moderate removal (8.7 Mg ha−1); high removal (4.2 Mg ha−1) and total removal on sugarcane root system and stalk yield. Higher concentrations of roots (60%) were found in the first 40 cm of soil. Moderate straw removal resulted in higher root mass (3.6 Mg ha−1) and stalk production (23 Mg ha−1 of dry mass). However, no straw removal reduced root mass by 20% (105 Mg ha−1). Through regression analysis, it was estimated that retaining between 8.5 and 13 Mg ha−1 of straw resulted in the highest root mass and stalk yield. Managing straw removal to retain a moderate amount enables producers to sustain suitable soil conditions for sugarcane root growth and stalk production while providing straw for industrial use.

Description: Proximal sensing techniques can potentially survey soil and crop variables responsible for variations in crop yield. The full potential of these precision agriculture technologies may be exploited in combination with innovative methods of data processing such as machine learning (ML) algorithms for the extraction of useful information responsible for controlling crop yield. Four ML algorithms, namely linear regression (LR), elastic net (EN), k-nearest neighbor (k-NN), and support vector regression (SVR), were used to predict potato (Solanum tuberosum) tuber yield from data of soil and crop properties collected through proximal sensing. Six fields in Atlantic Canada including three fields in Prince Edward Island (PE) and three fields in New Brunswick (NB) were sampled, over two (2017 and 2018) growing seasons, for soil electrical conductivity, soil moisture content, soil slope, normalized-difference vegetative index (NDVI), and soil chemistry. Data were collected from 39–40 30 × 30 m2 locations in each field, four times throughout the growing season, and yield samples were collected manually at the end of the growing season. Four datasets, namely PE-2017, PE-2018, NB-2017, and NB-2018, were then formed by combing data points from three fields to represent the province data for the respective years. Modeling techniques were employed to generate yield predictions assessed with different statistical parameters. The SVR models outperformed all other models for NB-2017, NB-2018, PE-2017, and PE-2018 dataset with RMSE of 5.97, 4.62, 6.60, and 6.17 t/ha, respectively. The performance of k-NN remained poor in three out of four datasets, namely NB-2017, NB-2018, and PE-2017 with RMSE of 6.93, 5.23, and 6.91 t/ha, respectively. The study also showed that large datasets are required to generate useful results using either model. This information is needed for creating site-specific management zones for potatoes, which form a significant component for food security initiatives across the globe.

Description: The bimodal-grain-size 7075 aluminium alloys containing varied ratios of large and small 7075 aluminium powders were prepared by spark plasma sintering (SPS). The large powder was 100 ± 15 μm in diameter and the small one was 10 ± 5 μm in diameter. The 7075 aluminium alloys was completely densified under the 500 °C sintering temperature and 60 MPa pressure. The large powders constituted coarse grain zone, and the small powders constituted fine grain zone in sintered 7075 aluminium alloys. The microstructural and microchemical difference between the large and small powders was remained in coarse and fine grain zones in bulk alloys after SPS sintering, which allowed for us to investigate the effects of microstructure and microchemistry on passive properties of oxide film formed on sintered alloys. The average diameter of intermetallic phases was 201.3 nm in coarse grain zone, while its vale was 79.8 nm in fine grain zone. The alloying element content in intermetallic phases in coarse grain zone was 33% to 48% higher than that on fine grain zone. The alloying element depletion zone surrounding intermetallic phases in coarse grain zone showed a bigger width and a more severe element depletion. The coarse grain zone in alloys showed a bigger electrochemical heterogeneity as compared to fine grain zone. The passive film formed on coarse grain zone had a thicker thickness and a point defect density of 2.4 × 1024 m−3, and the film on fine grain zone had a thinner thickness and a point defect density of 4.0 × 1023 m−3. The film resistance was 3.25 × 105 Ωcm2 on coarse grain zone, while it was 6.46 × 105 Ωcm2 on fine grain zone. The passive potential range of sintered alloys increased from 457 mV to 678 mV, while the corrosion current density decreased from 8.59 × 10−7 A/cm2 to 6.78 × 10−7 A/cm2 as fine grain zone increasing from 0% to 100%, which implied that the corrosion resistance of alloys increased with the increasing content of fine grains. The passive film on coarse grain zone exhibited bigger corrosion cavities after pitting initiation compared to that on fine grain zone. The passive film formed on fine grain zone showed a better corrosion resistance. The protectiveness of passive film was mainly determined by defect density rather than the thickness in this work.

Description: Joint sealant is affected by various environmental factors in service, such as different temperatures, water soaking, ultraviolet and so on. In this paper, the VAE emulsion–cement compositejoint sealant was pretreated under multiple simulation environments. Thereafter, the degradation rules of fixed elongation and tensile properties of joint sealants at different mix proportions were systemically investigated under the action of external environments (temperature, water soaking and ultraviolet), and the influence mechanisms of diverse environmental factors were analyzed. The research results suggested that, under the action of external environments, the VAE emulsion–cement composite joint sealants exhibited degradation effects to varying degrees. After the addition of plasticizer, the joint sealants had reduced cohesion strength in low temperature environment and enhanced flexible deformability. The addition of water repellent improved the water resistance of joint sealants. Meanwhile, adding ultraviolet shield agent partially improved the ultraviolet radiation aging resistance. A greater powder–liquid ratio led to the lower flexibility of joint sealants, but superior water resistance and ultraviolet radiation aging resistance.

Description: Plasticity and functional diversity of macrophages play an important role in resisting pathogens invasion, tumor progression and tissue repair. At present, nanodrug formulations are becoming increasingly important to induce and control the functional diversity of macrophages. In this framework, the internalization process of nanodrugs is co-regulated by a complex interplay of biochemistry, cell physiology and cell mechanics. From a biophysical perspective, little is known about cellular mechanics’ modulation induced by the nanodrug carrier’s internalization. In this study, we used the polylactic-co-glycolic acid (PLGA)–polyethylene glycol (PEG) nanofibers as a model drug carrier, and we investigated their influence on macrophage mechanics. Interestingly, the nanofibers internalized in macrophages induced a local increase of stiffness detected by atomic force microscopy (AFM) nanomechanical investigation. Confocal laser scanning microscopy revealed a thickening of actin filaments around nanofibers during the internalization process. Following geometry and mechanical properties by AFM, indentation experiments are virtualized in a finite element model simulation. It turned out that it is necessary to include an additional actin wrapping layer around nanofiber in order to achieve similar reaction force of AFM experiments, consistent with confocal observation. The quantitative investigation of actin reconfiguration around internalized nanofibers can be exploited to develop novel strategies for drug delivery.

Description: Exsolved perovskites can be obtained from lanthanum ferrites, such as La0.6Sr0.4Fe0.8Co0.2O3, as result of Ni doping and thermal treatments. Ni can be simply added to the perovskite by an incipient wetness method. Thermal treatments that favor the exsolution process include calcination in air (e.g., 500 °C) and subsequent reduction in diluted H2 at 800 °C. These processes allow producing a two-phase material consisting of a Ruddlesden–Popper-type structure and a solid oxide solution e.g., α-Fe100-y-zCoyNizOx oxide. The formed electrocatalyst shows sufficient electronic conductivity under reducing environment at the Solid Oxide Fuel Cell (SOFC) anode. Outstanding catalytic properties are observed for the direct oxidation of dry fuels in SOFCs, including H2, methane, syngas, methanol, glycerol, and propane. This anode electrocatalyst can be combined with a full density electrolyte based on Gadolinia-doped ceria or with La0.8Sr0.2Ga0.8Mg0.2O3 (LSGM) or BaCe0.9Y0.1O3-δ (BYCO) to form a complete perovskite structure-based cell. Moreover, the exsolved perovskite can be used as a coating layer or catalytic pre-layer of a conventional Ni-YSZ anode. Beside the excellent catalytic activity, this material also shows proper durability and tolerance to sulfur poisoning. Research challenges and future directions are discussed. A new approach combining an exsolved perovskite and an NiCu alloy to further enhance the fuel flexibility of the composite catalyst is also considered. In this review, the preparation methods, physicochemical characteristics, and surface properties of exsoluted fine nanoparticles encapsulated on the metal-depleted perovskite, electrochemical properties for the direct oxidation of dry fuels, and related electrooxidation mechanisms are examined and discussed.

Description: The drilling of holes in CFRP/Ti (Carbon Fiber-Reinforced Plastic/Titanium alloy) alloy stacks is one of the frequently used mechanical operations during the manufacturing of fastening assemblies in temporary civil aircraft. A combination of inhomogeneous behavior and poor machinability of CFRP/Ti alloy stacks in one short drilling brought challenges to the manufacturing community. The impact of the drilling temperature and time delay factor under various cutting conditions on hole accuracy when machining CFRP/Ti alloy stacks is poorly studied. In this paper, the drilling temperature, the phenomenon of thermal expansion of the drill tool, and hole accuracy are investigated. An experimental study was carried out using thermocouples, the coordinate measuring machine method, and finite element analysis. The results showed that the time delay factor varied from 5 (s) to 120 (s), influences the thermal-dependent properties of CFRP, and leads to an increase in hole roundness. Additionally, the thermal expansion of the drill significantly contributes to the deviation of the hole diameter in Ti alloy.

Description: Community-based natural resource management (CBNRM) has grown in stature as a key component of many national natural resource and rural development governance systems. Despite their growth, the integrity of CBNRM governance systems has rarely been analysed in a national context. To enhance dialogue about how best to design and deploy such systems nationally, this paper analyses the Australian system in detail. The Australian system was selected because the nation has a globally recognised and strong history of CBNRM approaches. We first contextualise the international emergence of national CBRM governance systems before analysing the Australian system. We find that a theoretically informed approach recognising regions as the anchors in brokering multi-scale CBNRM was applied between 2000 and 2007. Subsequent policy, while strengthening indigenous roles, has tended to weaken regional brokering, Commonwealth–state cooperation and research collaboration. Our findings and consequent emerging lessons can inform Australian policy makers and other nations looking to establish (or to reform existing) CBNRM governance systems. Equally, the research approach taken represents the application of an emerging new theoretical framework for analysing complex governance systems.

Description: Targeted genome editing using CRISPR-Cas9 has been widely adopted as a genetic engineering tool in various biological systems. This editing technology has been in the limelight due to its simplicity and versatility compared to other previously known genome editing platforms. Several modifications of this editing system have been established for adoption in a variety of plants, as well as for its improved efficiency and portability, bringing new opportunities for the development of transgene-free improved varieties of economically important crops. This review presents an overview of CRISPR-Cas9 and its application in plant genome editing. A catalog of the current and emerging approaches for the implementation of the system in plants is also presented with details on the existing gaps and limitations. Strategies for the establishment of the CRISPR-Cas9 molecular construct such as the selection of sgRNAs, PAM compatibility, choice of promoters, vector architecture, and multiplexing approaches are emphasized. Progress in the delivery and transgene detection methods, together with optimization approaches for improved on-target efficiency are also detailed in this review. The information laid out here will provide options useful for the effective and efficient exploitation of the system for plant genome editing and will serve as a baseline for further developments of the system. Future combinations and fine-tuning of the known parameters or factors that contribute to the editing efficiency, fidelity, and portability of CRISPR-Cas9 will indeed open avenues for new technological advancements of the system for targeted gene editing in plants.

Description: The use of Light Emitting Diode (LED) lights in microscale vegetable production is more and more widespread. In this context, the effect of light spectrum on photosynthesis, growth, shoot yield, pigment content, and nutritional status of einkorn seedlings (Triticum monococcum L. ssp. monococcum), germinated and grown in a nutrient solution, was investigated. Plants were subjected to six different LED light treatments, all having a photon flux density (PFD) of 200 μmol m−2 s−1. Two light treatments were monochromatic (red or blue), three dichromatic (blue and red in the proportion), and one of a wider spectrum (selected as a control). All the light treatments affected the morphological, biochemical, and nutritional status of einkorn seedlings. Overall, the dichromatic treatments were the most effective in stimulating biomass production, CO2 assimilation, and evapotranspiration, as well as contents in chlorophyll a and b and carotenoids, and additionally nitrogen, phosphorous, manganese, iron, and zinc. These results are of relevance for the beneficial effects of dichromatic LED treatments in maximizing einkorn shoot yield and nutritional values, and in limiting energy consumption in indoor cultivation.

Description: Lentil (Lens culinaris Medikus) is one of the most important cool season food legume crops grown in many countries. Seeds are typically rich in protein, fiber, prebiotic carbohydrates and minerals, such as iron and zinc. With changing climate and variability, the lentil crop faces frequent droughts and heat stress of varying intensity in its major production zones. In the present study, a set of 162 lentil accessions selected through the Focused Identification of Germplasm Strategy (FIGS) were screened for tolerance to heat stress and combined heat-drought stresses under field conditions at two contrasting locations, namely Marchouch and Tessaout in Morocco. The results showed a significant genotypic variation for heat tolerance and combined heat-drought tolerance among the accessions at both locations. Based on the heat tolerance index (HTI), accessions, namely ILL 7833, ILL 6338 and ILL 6104, were selected as potential sources of heat tolerance at Marchouch, and ILL 7814 and ILL 8029 at Tessaout. Using the stress tolerance index (STI), ILL 7835, ILL 6075 and ILL 6362 were identified as the most tolerant lines (STI 〉 1) at Marchouch, and ILL 7814, ILL 7835 and ILL 7804 (STI 〉 1) at Tessaout, under the combined heat-drought stress conditions. Accession ILL 7835 was identified as a good source of stable tolerance to heat stress and combined heat-drought stress at both locations.

Description: Headland rips, sometimes referred to as boundary rips, are rip currents flowing against natural or artificial obstructions extending seaward from the beach, such as headland or groynes. They can be driven either by the deflection of the longshore current against the obstacle or by alongshore variation in breaking wave height due to wave shadowing in the lee of the obstacle. The driving mechanism therefore essentially depends on the angle of wave incidence with respect to the natural or artificial obstruction. We analyze 42 days of velocity profile measurements against a natural headland at the high-energy meso-macrotidal beach of Anglet, southwest France. Measurements were collected in 6.5–10.5-m depth as tide elevation varied, during the autumn–winter period with offshore significant wave height and period ranging 0.9–6 m and 8–16 s, respectively, and the angle of wave incidence ranging from −20 ∘ to 20 ∘ . Here we analyze deflection rip configurations, corresponding to approximately 24 days of measurements, for which the current meter was alternatively located in the rip neck, rip head or away from the rip as wave and tide conditions changed. Deflection rips were associated with large offshore-directed velocities (up to 0.6 m/s depth-averaged velocities) and tide modulation for low- to moderate-energy waves. The vertical profile of deflection rips was found to vary from depth-uniform in the rip neck to strongly depth-varying further offshore in the rip head with maximum velocities near the surface. Very low frequency motions of the rip were dramatic, ranging 10–60 min with a dominant peak period of approximately 40 min, i.e., with longer periods than commonly reported. The strong offshore-directed velocities measured well beyond the surf zone edge provide new insight into deflection rips as a dominant mechanism for water and sediment exchanges between embayed (or structurally-controlled) beaches and the inner-shelf and/or the adjacent embayments.

Description: In this work, piezoelectric (PZT) actuators were surface bonded on or embedded in a composite laminate and subjected to an electric voltage across the thickness, resulting in a bending effect on the composite laminate. An analytical expression of the deflection of a simply supported cross-ply composite laminate induced by distributed piezoelectric actuators was derived on the basis of classical plate theory and composite mechanics. The theoretical solution can be used to predict the deformation of the composite laminate. Series of parametric studies were performed to investigate the effects of location, size, and embedded depth of PZT actuators on the composite laminate deformation. The analytical predictions were verified with finite element results. A close agreement was achieved. It demonstrated that the present approach provided a simple solution to predict and control the deformed shape of a composite laminate induced by distributed PZT actuators.

Description: To optimize the mechanical performance of fused deposition modelling (FDM) fabricated parts, it is necessary to evaluate the influence of process parameters on the resulting mechanical performance. The main focus of the study was to characterize the influence of the initial process parameters on the mechanical performance of thermoplastic polyurethane under a quasi-static and high strain rate (~2500 s−1). The effects of infill percentage, layer height, and raster orientation on the mechanical properties of an FDM-fabricated part were evaluated. At a quasi-static rate of loading, layer height was found to be the most significant factor (36.5% enhancement in tensile strength). As the layer height of the sample increased from 0.1 to 0.4 mm, the resulting tensile strength sample was decreased by 36.5%. At a high-strain rate of loading, infill percentage was found to be the most critical factor influencing the mechanical strength of the sample (12.4% enhancement of compressive strength at 100% as compared to 80% infill). Furthermore, statistical analysis revealed the presence of significant interactions between the input parameters. Finally, using an artificial neural networking approach, we evaluated a regression model that related the process parameters (input factors) to the resulting strength of the samples.

Description: The complex failure mechanisms of glass laminates under in-plane loading conditions is modelled within the framework of phase-field strategy. Laminated glass is widely used for structural purposes due to its safe post-glass-breakage response. In fact, the combination of several glass plies bonded together with polymeric interlayers allows overcoming the brittleness of the glass and to reach a pseudo-ductile response. Moreover, the post-breakage behaviour of the laminate is strictly correlated by the mechanical properties of the constituents. Ruptures may appear as cracks within the layers or delamination of the bonding interface. The global response of a glass laminate, validated against experimental results taken from the literature, is carried out by investigating a simplified layup of two glass plies connected by cohesive interfaces through an interlayer. Delamination of the adhesive interface is described, and crack patterns within the materials are fully described. Finally, the proposed approach put the basis for future comparisons with results of experimental campaign and real-life applications.

Description: The size of the fracture process zone (FPZ) has significance for studying the fracture mechanism and fracture characteristics of concrete. This paper presents the method of assessing the FPZ of Mixed-Mode I-II for quasi-static four-point shearing concrete beams with pre-notched by Lagrangian strain profiles from digital image correlation (DIC). Additionally, it explores the influences of volume rates of the coarse aggregate of 0%, 28%, 48%, and 68%, and the specific surface areas of 0.12 m2/kg, 0.15 m2/kg, and 0.26 m2/kg on the size of the FPZ. It shows that the size of FPZ in four-point shearing concrete beam can be characterized by the displacement field and strain field using DIC. The size of FPZ conforms to linear positive correlation with the volume rate of coarse aggregate, and linear negative correlation with the specific surface area of coarse aggregate. It presents that the crack initiation of the four-point shearing beam with the pre notch is dominated by mode I load, and the propagation and fracture of Mixed-Mode I-II cracks are caused by the combined effect of Mode I and Mode II loading.

Description: The structural, mechanical, and electronic properties, as well as stability, elastic anisotropy and effective mass of AlN/GaN/InN in the Pmn21 phase were determined using density functional theory (DFT). The phonon dispersion spectra and elastic constants certify the dynamic and mechanical stability at ambient pressure, and the relative enthalpies were lower than those of most proposed III-nitride polymorphs. The mechanical properties reveal that Pmn21-AlN and Pmn21-GaN possess a high Vickers hardness of 16.3 GPa and 12.8 GPa. Pmn21-AlN, Pmn21-GaN and Pmn21-InN are all direct semiconductor materials within the HSE06 hybrid functional, and their calculated energy band gaps are 5.17 eV, 2.77 eV and 0.47 eV, respectively. The calculated direct energy band gaps and mechanical properties of AlN/GaN/InN in the Pmn21 phase reveal that these three polymorphs may possess great potential for industrial applications in the future.

Description: Mesenchymal stem cells (MSCs) have been isolated from a variety of tissues using different methods. Active research have confirmed that the most accessible site to collect them is the adipose tissue; which has a significantly higher concentration of MSCs. Moreover; harvesting from adipose tissue is less invasive; there are no ethical limitations and a lower risk of severe complications. These adipose-derived stem cells (ASCs) are also able to increase at higher rates and showing telomerase activity, which acts by maintaining the DNA stability during cell divisions. Adipose-derived stem cells secret molecules that show important function in other cells vitality and mechanisms associated with the immune system, central nervous system, the heart and several muscles. They release cytokines involved in pro/anti-inflammatory, angiogenic and hematopoietic processes. Adipose-derived stem cells also have immunosuppressive properties and have been reported to be “immune privileged” since they show negative or low expression of human leukocyte antigens. Translational medicine and basic research projects can take advantage of bioprinting. This technology allows precise control for both scaffolds and cells. The properties of cell adhesion, migration, maturation, proliferation, mimicry of cell microenvironment, and differentiation should be promoted by the printed biomaterial used in tissue engineering. Self-renewal and potency are presented by MSCs, which implies in an open-source for 3D bioprinting and regenerative medicine. Considering these features and necessities, ASCs can be applied in the designing of tissue engineering products. Understanding the heterogeneity of ASCs and optimizing their properties can contribute to making the best therapeutic use of these cells and opening new paths to make tissue engineering even more useful.

Description: Tomato plants (Solanum lycopersicum L.) cv. Moperou, which possess gene Tm-2 for resistance against tomato mosaic virus (ToMV), were pre-inoculated with compatible pathotype P2 or incompatible pathotype P0 strains of ToMV and subsequently challenge infected with Pseudomonas syringae pv. tomato and Xanthomonas vesicatoria. It was found that both types of virus strains, compatible and incompatible, induced systemic acquired resistance (SAR), which protected plants from subsequent pathogen infection. The percentage of protection of the compatible ToMV pathotype P2 strain was 100% against both bacterial infections, while that of the incompatible ToMV pathotype P0 strain varied from 26 to 77% within the timeline and depended on the pathogen races. The SAR induced by ToMV was confirmed by the increased antioxidant defense and hydrogen peroxide content in the leaves of tomato plants inoculated with compatible and incompatible ToMV strains.

Description: Declining soil fertility is one of the major problems facing producers of field crops in most dryland areas of Sub-Saharan Africa. In response to the declining soil fertility, extensive participatory research has been undertaken by the World Agroforestry (ICRAF) and smallholder farmers in Dodoma region, Tanzania. The research has, amongst others, led to the development of Gliricidia agroforestry technology. The positive impact of Gliricidia intercropping on crop yields has been established. However, information on farmers’ willingness and ability to adopt the Gliricidia agroforestry technology on their farms is limited. This study predicts the adoption of Gliricidia agroforestry and conventional mineral fertilizer use technology. Focus Group Discussions (FGDs) were conducted with groups of farmers, purposively selected based on five sets of criteria: (i) at least 2 years of experience in either trying or using Gliricidia agroforestry technology, (ii) at least 1 year of experience in either trying or using the mineral fertilizer technology (iii) at least 10 years of living in the study villages, (iv) the age of 18 years and above, and (v) sex. The Adoption and Diffusion Outcome Prediction Tool (ADOPT) was used to predict the peak adoption levels and the respective time in years. A sensitivity analysis was conducted to assess the effect of change in adoption variables on predicted peak adoption levels and time to peak adoption. The results revealed variations in peak adoption levels with Gliricidia agroforestry technology exhibiting the highest peak of 67.6% in 12 years, and that the most influential variable to the peak adoption is the upfront cost of investing in Gliricidia agroforestry and fertilizer technologies. However, in Gliricidia agroforestry technology most production costs are incurred in the first year of project establishment but impact the long term biophysical and economic benefits. Moreover, farmers practicing agroforestry technology accrue environmental benefits, such as soil erosion control. Based on the results, it is plausible to argue that Gliricidia agroforestry technology has a high adoption potential and its adoption is influenced by investment costs. We recommend two actions to attract smallholder farmers investing in agroforestry technologies. First, enhancing farmers’ access to inputs at affordable prices. Second, raising farmers’ awareness of the long-term environmental benefits of Gliricidia agroforestry technology.

Description: In this paper, interactions of double parallel cracks were studied by performing experiments and numerical simulations. Fatigue crack propagation tests were carried out to measure crack growth rates in the specimens with double parallel cracks or a single crack. Finite element method was adopted to calculate stress intensity factors at the crack tips. Results show that the double parallel cracks at different positions present a shielding effect or enhancement effect on crack growth rates and stress intensity factors. When the double parallel cracks are offset, crack interactions mostly behave as enhancement effects. Empirical formulas were obtained to calculate the stress intensity factor at the “dangerous” crack tip of the double parallel cracks. By modifying the material parameters in Paris equation of the single crack, the double parallel cracks are simplified into a single crack with the same crack growth rates.

Description: The following article introduces technologies that build three dimensional (3D) objects by adding layer-upon-layer of material, also called additive manufacturing technologies. Furthermore, most important features supporting the conscious choice of 3D printing methods for applications in micro and nanomanufacturing are covered. The micromanufacturing method covers photopolymerization-based methods such as stereolithography (SLA), digital light processing (DLP), the liquid crystal display–DLP coupled method, two-photon polymerization (TPP), and inkjet-based methods. Functional photocurable materials, with magnetic, conductive, or specific optical applications in the 3D printing processes are also reviewed.

Description: This paper presents a series of dynamic simulations for a ship towed by kite. To ensure time efficient computations, seakeeping analysis with forward speed correction factors is carried out in the frequency domain and then transformed in the time domain by convolution. The seakeeping modeling is coupled with a zero-mass kite modeling assuming linear dependence of aerodynamic characteristics with respect to turning rate. Decoupled (segregated) and coupled (monolithic) approaches are assessed and compared in different environmental conditions. Results show that in regular beam waves, strong interactions between the kite and the ship motions are captured by the monolithic approach. Around the wave frequency, especially for the lower one tested (0.4 rad/s), a kite lock-in phenomenon is revealed. It is concluded that the mean kite towing force can be increased whereas the ship roll amplitude can even be decreased compared to a non-kite assisted ship propulsion configuration.

Description: One of the major issues faced when constructing various materials incorporating inorganic nanoparticles (NPs) is aggregation leading to loss of their final activity. In our work, cellulose acetate (CA) has been used to serve as matrix for the synthesis of UV-shielding and transparent films containing various amounts (1–5 wt.%) of cerium oxide (CeO2) NPs. In order to attain an improved dispersion and a better connectivity between NPs and the cellulose matrix, the surface of CeO2 NPs have been previously functionalized by the reaction with 3-aminopropyl(diethoxy)methylsilane (APDMS). The uniform dispersion of the NPs in the homogeneous thin films has been evidenced by using Transmission Electron Microscopy (TEM) and Fourier Transformation Infrared Spectroscopy (FTIR) characterization. The investigation of the optical properties for the hybrid films through UV-Vis spectroscopy revealed that the presence of CeO2 NPs in the CA matrix determined the appearance of strong UV absorption bands in the region 312–317 nm, which supports their use as efficient UV absorbers. This study has shown that UV shielding ability of the nanocomposites can be easily tuned by adjusting the numberof inorganic NPs in the CA template.

Description: In 1997, in front of the Pescara Harbour (Italy), a detached breakwater was constructed. In the successive years, the sediment transport due to the combined action of waves and coastal currents, in the area between the detached breakwater and the entrance of the Pescara Harbour, produced an accumulation of about 40,000   m 3 of sediment per year. In this paper, the causes of the accretion of the bottom elevation in front of the Pescara Harbour entrance and the effects produced by the existing detached breakwater are investigated. The effects on the sediment transport of the introduction of a new submerged breakwater designed to protect the entrance of the harbour from sediment siltation are investigated. In particular, the ability of the designed submerged breakwater, located orthogonally to the longshore current, to intercept the aforementioned solid material and to significantly reduce the accretion of the bottom in the area in front of the harbour entrance, was numerically verified. Numerical simulations were carried out by means of a model of the bottom-change composed of two sub-models: a two-dimensional phase resolving model that is used to calculate the fluid dynamic variables changing inside the wave period and a second sediment transport sub-model to simulate the bottom changes, in which the suspended sediment concentration is calculated by the wave-averaged advection–diffusion equation. The equations of motion, in which the vector and tensor quantities are expressed in Cartesian components, are written in a generalised curvilinear coordinate system. The fully nonlinear Boussinesq equations are written in an integral form and used to simulate the velocity fields.

Description: The aspects regarding the stiffness of the connections between the beams that support the storage pallets and the uprights is very important in the analysis of the displacements and stresses in the storage racking systems. The main purpose of this paper is to study the effects of both upright thickness and tab connector type on the rotational stiffness and on the capable bending moment of the connection. For this purpose, a number of 18 different groups of beam-connector-upright assemblies are prepared by combining three types of beams (different sizes of the box cross section), three kinds of uprights profiles (with a different thickness of the section walls), and two types of connectors (four-tab connectors and five-tab connectors). Flexural tests were carried out on 101 assemblies. For the assemblies containing the uprights having the thickness of 1.5 mm, the five-tab connector leads to a higher value of the capable moment and higher rotational stiffness than similar assemblies with four-tab connectors. A contrary phenomenon happens in case of the assemblies containing the upright profiles having a thickness of 2.0 mm regarding the capable design moment. It is shown how the safety coefficient of connection depends on both the rotational stiffness and capable bending moment.

Description: The objective of this study was to investigate the effect of light quality on the growth and contents of photosynthetic pigments and total flavonoids, the parameters of chlorophyll a fluorescence, antioxidant capacities, and enzyme activities. It was intended to preliminarily explore the internal mechanisms involved for the effect of light quality on the growth and physiology of Carpesium triste Maxim. Stem apex explants were cultured on the Murashige and Skoog (MS) medium under white (W), red (R), blue (B), or a 1:1 mixture of red and blue (RB) light-emitting diodes (LEDs) for four weeks. The RB induced sturdy plantlets and increased the contents of photosynthetic pigments and total flavonoids, photosynthetic electron transport and efficiency, 2-diphenyl-1-picrylhydrazyl (DPPH) free radical scavenging capacity, and activities of antioxidant enzymes in the plantlets. Taken together, combinations of monochromatic red and blue LEDs could be used for the best production of high-quality C. triste plantlets in vitro.

Description: In order to meet the growing global demand for bioproducts, areas of forests planted for productive purposes tend to increase worldwide. However, there are several controversies about the possible negative impacts of such forests, such as invasive potential, influence on water balance and biodiversity, and competition with other types of land use. As a result, there is a need to optimize land use, in order to achieve improvements in terms of sustainability in the broadest sense. In this study, the environmental and economic performances of pine and eucalyptus forest production systems for multiple purposes are compared aiming an optimized allocation of land use in the Center-West Region of Brazil. Life cycle assessment, life cycle cost and analysis of financial and economic indicators were used to assess potential environmental and economic impacts, covering the agricultural and industrial phases of pine and eucalyptus forest systems managed for the production of cellulose and sawn wood and, for pine, the production of rosin and turpentine from the extraction of gumresin and by applying the kraft process. Subsequently, the TOPSIS multicriteria decision-making method was applied to rank production systems in different combinations of phases and criteria, and multi-objective optimization was used to allocate land use according to different restrictions of areas and efficiency. The adoption of cleaner energy sources and the use of more efficient machines, equipment and vehicles are the main solutions to improve the environmental and economic performance of the forestry sector. The production systems of pine for cellulose and pine for sawn wood, rosin and turpentine were identified as the best solutions to optimize land use. For this reason, they must be considered as alternatives for the expansion and diversification of the Brazilian forest productive chain.