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  • Environmental sensing
  • Impedance spectroscopy
  • Lipids
  • Microspectroscopy Analysis
  • American Chemical Society  (3)
  • Biological and Chemical Oceanography Data Management Office (BCO-DMO). Contact: bco-dmo-data@whoi.edu  (1)
  • Kerch, Crimea  (1)
  • Periodicals Archive Online (PAO)
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  • 1
    Publication Date: 2017-04-04
    Description: Red Pompeian paintings, very famous for their deep intensity, are currently suffering from darkening. The origins of this darkening degradation are not clearly identified yet and remain a major issue for curators. In the specific case of cinnabar (HgS)-based red pigment, a photoinduced conversion into black metacinnabar is usually suspected. This work is focused on the blackening of red cinnabar paintings coated on a sparry calcite mortar. Different samples exhibiting different levels of degradation were selected upon visual observations and analyzed by synchrotron-based microanalytical techniques. Atomic and molecular compositions of the different debased regions revealed two possible degradation mechanisms. On one hand, micro X-ray fluorescence elemental maps show peculiar distributions of chlorine and sulfur. On the other hand, X-ray absorption spectroscopy performed at both Cl and S K-edges confirms the presence of characteristic degradation products: (i) Hg- Cl compounds (e.g., corderoite, calomel, and terlinguaite), which may result from the reaction with exogenous NaCl, in gray areas; (ii) gypsum, produced by the calcite sulfation, in black coatings. Metacinnabar is never detected. Finally, a cross section was analyzed to map the in-depth alteration gradient. Reduced and oxidized sulfur distributions reveal that the sulfated black coating consists of a 5-ím-thick layer covering intact cinnabar.
    Description: Published
    Description: 7484-7492
    Description: reserved
    Keywords: Microspectroscopy Analysis ; 05. General::05.09. Miscellaneous::05.09.99. General or miscellaneous
    Repository Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
    Type: article
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  • 2
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    Kerch Branch ("YugNIRO") of FSBSI "AzNIIRKH" | Kerch, Crimea
    Publication Date: 2021-05-19
    Description: Лаборатория технологии и механизации обработки рыбы начала свою деятельность в АзЧерНИРО в 1958 г., после завершения строительства нового здания института в Керчи по ул. Свердлова, 2. Следует отметить, что технологические исследования к тому времени велись в Доно-Кубанском отделении АзЧерНИРО (г. Ростов-на-Дону). Первой заведующей лабораторией стала Г.К. Ковальчук – высококвалифицированный специалист, которая организовала и сплотила коллектив технологов, определила основные направления научной деятельности. Исследования, проводимые лабораторией, были связаны прежде всего с сохранением свежести азово-черноморских рыб, определением сроков хранения рыбы-сырца и охлажденной рыбы на судах. Для Азово-Черноморского бассейна, где в летний период температура воздуха достигает 30 °С и выше, сохранение выловленной рыбы всегда имеет особо важное значение. В конце 1950-х гг. предлагалось решить проблему сохранения рыбы-сырца путем применения антибиотиков тетрациклиновой группы (биомицина). Сейчас применение антибиотиков при производстве пищевой продукции вызывает у нас неприятие, тогда же это было одно из актуальных направлений исследований, проводимых на всех рыбохозяйственных бассейнах. С 1956 г. в Канаде было официально разрешено обрабатывать рыбу льдом, содержащим биомицин. В 1959 г. в Ленинграде был проведен Всесоюзный коллоквиум по применению антибиотиков в рыбной промышленности, разработана методика проведения исследований. Технологической лабораторией АзЧерНИРО была подтверждена возможность использования биомицина для бычка и ставриды; для хамсы применение биомицина было нецелесообразным, поскольку при ее хранении при температуре от 3 до 5 °С процессы окисления протекали быстрее, чем бактериальная порча. С образованием лаборатории была начата работа по технологическому нормированию, которая проводилась совместно с производственными лабораториями. Требовался пересмотр действующих бассейновых норм, поскольку они не соответствовали современному уровню технологии и технической оснащенности предприятий. Технологические исследования неразрывно связаны со стандартизацией. Уже в 1959 г. Н.И. Горемыкиной были начаты работы по стандартизации. По заказу Госплана УССР разрабатывались республиканские технические условия на продукцию, требования к которой не были установлены в общесоюзных стандартах. Это были технические условия на мелкую рыбу-сырец, охлажденную, мороженую, холодного и горячего копчения; бычок охлажденный, мороженый и горячего копчения; на соленую продукцию, варено-мороженые раки, консервы из пеламиды, ставриды и др. При разработке нормативных документов в производственных условиях проверялись предложения от рыбопромышленных предприятий.
    Description: Published
    Keywords: Canned food ; Fish processing ; Biotechnologies ; Smoked fish ; Patents ; Lipids ; Standards ; Live feeds
    Repository Name: AquaDocs
    Type: Conference Material , Non Refereed
    Format: pp.241-246
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  • 3
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    Biological and Chemical Oceanography Data Management Office (BCO-DMO). Contact: bco-dmo-data@whoi.edu
    Publication Date: 2022-10-31
    Description: Dataset: Coral physiological and δ15N isotopic measurements.
    Description: Experimental coral physiological and δ15N isotopic measurements in October 2012 at Reef Systems Coral Farm, Ohio. For a complete list of measurements, refer to the full dataset description in the supplemental file 'Dataset_description.pdf'. The most current version of this dataset is available at: https://www.bco-dmo.org/dataset/839920
    Description: NSF Emerging Frontiers Division (NSF EF) EF-1041124
    Keywords: Coral calcification ; Photosynthesis ; Carbon budgets ; Chlorophyll a ; Protein ; Carbohydrates ; Lipids ; Energy reserves ; Nitrogen isotopes
    Repository Name: Woods Hole Open Access Server
    Type: Dataset
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  • 4
    Publication Date: 2022-05-27
    Description: © The Author(s), 2021. This article is distributed under the terms of the Creative Commons Attribution License. The definitive version was published in Gosselin, K. M., Nelson, R. K., Spivak, A. C., Sylva, S. P., Van Mooy, B. A. S., Aeppli, C., Sharpless, C. M., O’Neil, G. W., Arrington, E. C., Reddy, C. M., & Valentine, D. L. Production of two highly abundant 2-methyl-branched fatty acids by blooms of the globally significant marine cyanobacteria Trichodesmium erythraeum. ACS Omega, 6(35), (2021): 22803–22810, https://doi.org/10.1021/acsomega.1c03196.
    Description: The bloom-forming cyanobacteria Trichodesmium contribute up to 30% to the total fixed nitrogen in the global oceans and thereby drive substantial productivity. On an expedition in the Gulf of Mexico, we observed and sampled surface slicks, some of which included dense blooms of Trichodesmium erythraeum. These bloom samples contained abundant and atypical free fatty acids, identified here as 2-methyldecanoic acid and 2-methyldodecanoic acid. The high abundance and unusual branching pattern of these compounds suggest that they may play a specific role in this globally important organism.
    Description: This work was funded with grants from the National Science Foundation grants OCE-1333148, OCE-1333162, and OCE-1756254 and the Woods Hole Oceanographic Institution (IR&D). GCxGC analysis made possible by WHOI’s Investment in Science Fund.
    Keywords: Lipids ; Alkyls ; Bacteria ; Genetics ; Chromatography
    Repository Name: Woods Hole Open Access Server
    Type: Article
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  • 5
    Publication Date: 2022-10-21
    Description: © The Author(s), 2021. This article is distributed under the terms of the Creative Commons Attribution License. The definitive version was published in Colson, B. C., & Michel, A. P. M. Flow-through quantification of microplastics using impedance spectroscopy. ACS Sensors, 6(1), (2021): 238–244, doi:10.1021/acssensors.0c02223.
    Description: Understanding the sources, impacts, and fate of microplastics in the environment is critical for assessing the potential risks of these anthropogenic particles. However, our ability to quantify and identify microplastics in aquatic ecosystems is limited by the lack of rapid techniques that do not require visual sorting or preprocessing. Here, we demonstrate the use of impedance spectroscopy for high-throughput flow-through microplastic quantification, with the goal of rapid measurement of microplastic concentration and size. Impedance spectroscopy characterizes the electrical properties of individual particles directly in the flow of water, allowing for simultaneous sizing and material identification. To demonstrate the technique, spike and recovery experiments were conducted in tap water with 212–1000 μm polyethylene beads in six size ranges and a variety of similarly sized biological materials. Microplastics were reliably detected, sized, and differentiated from biological materials via their electrical properties at an average flow rate of 103 ± 8 mL/min. The recovery rate was ≥90% for microplastics in the 300–1000 μm size range, and the false positive rate for the misidentification of the biological material as plastic was 1%. Impedance spectroscopy allowed for the identification of microplastics directly in water without visual sorting or filtration, demonstrating its use for flow-through sensing.
    Description: The authors thank the Richard Saltonstall Charitable Foundation and the National Academies Keck Futures Initiative (NAKFI DBS13) for their funding support.
    Keywords: Microplastics ; Plastics ; Impedance spectroscopy ; Dielectric properties ; Instrumentation ; Particle detection ; Flow-through ; Environmental sensing
    Repository Name: Woods Hole Open Access Server
    Type: Article
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