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  • 04. Solid Earth::04.01. Earth Interior::04.01.02. Geological and geophysical evidences of deep processes
  • 04. Solid Earth::04.02. Exploration geophysics::04.02.01. Geochemical exploration
  • Elsevier  (27)
  • AGU Geochemical Society  (1)
  • American Association for the Advancement of Science  (1)
  • American Institute of Physics (AIP)
  • Public Library of Science
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Keywords
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Years
  • 1
    Publication Date: 2021-01-07
    Description: The CO2 degassing process from a large area on the Tyrrhenian side of central Italy, probably related to the input into the upper crust of mantle fluids, was investigated in detail through the geochemical study of gas emissions and groundwater. Mass-balance calculations and carbon isotopes show that over 50% of the inorganic carbon in regional groundwater is derived from a deep source highlighting gas−liquid separation processes at depth. The deep carbonate−evaporite regional aquifer acts as the main CO2 reservoir and when total pressure of the reservoir fluid exceeds hydrostatic pressure, a free gas phase separates from the parent liquid and escapes toward the surface generating gas emissions which characterise the study area. The distribution of the CO2 flux anomalies and the location of high PCO2 springs and gas emissions suggest that the storage and the expulsion of the CO2 toward the atmosphere are controlled by the geological and structural setting of the shallow crust. The average CO2 flux and the total amount of CO2 discharged by the study area were computed using surface heat flow, enthalpy and CO2 molality of the liquid phase circulating in the deep carbonate−evaporite aquifer. The results show that the CO2 flux varies from 1×104 mol y−1 km−2 to 5×107 mol y−1 km−2, with an average value of 4.8×106 mol y−1 km−2, about five times higher than the value of 1×106 mol y−1 derived by Kerrick et al. [Kerrick, D.M., McKibben, M.A., Seward, T.M., Caldeira, K., 1995. Convective hydrothermal CO2 emission from high heat flow regions. Chem. Geol. 121, 285–293] as baseline for terrestrial CO2 emissions. The total CO2 discharged from the study area is 0.9×1011 mol y−1, confirming that Earth degassing from Tyrrhenian central Italy is a globally relevant carbon source
    Description: Published
    Description: 89–102
    Description: 2.4. TTC - Laboratori di geochimica dei fluidi
    Description: 4.5. Degassamento naturale
    Description: JCR Journal
    Description: reserved
    Keywords: Earth degassing ; carbon dioxide ; CO2 flux ; groundwater ; 04. Solid Earth::04.02. Exploration geophysics::04.02.01. Geochemical exploration ; 04. Solid Earth::04.04. Geology::04.04.12. Fluid Geochemistry ; 04. Solid Earth::04.08. Volcanology::04.08.01. Gases ; 04. Solid Earth::04.08. Volcanology::04.08.06. Volcano monitoring
    Repository Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
    Type: article
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  • 2
    Publication Date: 2020-11-26
    Description: The complexity of volcano-hosted hydrothermal systems is such that thorough characterization requires extensive and interdisciplinary work. We use here an integrated multidisciplinary approach, combining geological investigations with hydrogeochemical and soil degassing prospecting, and resistivity surveys, to provide a comprehensive characterization of the shallow structure of the southwestern Ischia's hydrothermal system. We show that the investigated area is characterized by a structural setting that, although very complex, can be schematized in three sectors, namely, the extra caldera sector (ECS), caldera floor sector (CFS), and resurgent caldera sector (RCS). This contrasted structural setting governs fluid circulation. Geochemical prospecting shows, in fact, that the caldera floor sector, a structural and topographic low, is the area where CO2-rich (〉40 cm3/l) hydrothermally mature (log Mg/Na ratios 〈 −3) waters, of prevalently meteoric origin (δ18O 〈 −5.5‰), preferentially flow and accumulate. This pervasive hydrothermal circulation within the caldera floor sector, being also the source of significant CO2 soil degassing (〉150 g m−2 d−1), is clearly captured by electrical resistivity tomography (ERT) and transient electromagnetic (TEM) surveys as a highly conductive (resistivity 〈 3 Ω·m) layer from depths of ~100 m, and therefore within the Mount Epomeo Green Tuff (MEGT) formation. Our observations indicate, instead, that less-thermalized fluids prevail in the extra caldera and resurgent caldera sectors, where highly conductive seawater-like (total dissolved solid, TDS 〉 10,000 mg/l) and poorly conductive meteoric-derived (TDS 〈 4,000 mg/l) waters are observed, respectively. We finally integrate our observations to build a general model for fluid circulation in the shallowest (〈0.5 km) part of Ischia's hydrothermal system.
    Description: Published
    Description: Q07017
    Description: 1.2. TTC - Sorveglianza geochimica delle aree vulcaniche attive
    Description: JCR Journal
    Description: restricted
    Keywords: ERT ; TEM ; Ischia ; fluid geochemistry ; hydrothermal systems ; resurgent caldera ; 03. Hydrosphere::03.02. Hydrology::03.02.03. Groundwater processes ; 03. Hydrosphere::03.02. Hydrology::03.02.05. Models and Forecasts ; 03. Hydrosphere::03.04. Chemical and biological::03.04.06. Hydrothermal systems ; 04. Solid Earth::04.01. Earth Interior::04.01.02. Geological and geophysical evidences of deep processes ; 04. Solid Earth::04.02. Exploration geophysics::04.02.01. Geochemical exploration ; 04. Solid Earth::04.04. Geology::04.04.09. Structural geology ; 04. Solid Earth::04.04. Geology::04.04.12. Fluid Geochemistry
    Repository Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
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  • 3
    Publication Date: 2021-05-11
    Description: The CO2 laser-based lidar ATLAS has been used to study the Stromboli volcano plume. ATLAS measured water vapor concentration in cross-sections of the plume and wind speed at the crater. Water vapor concentration and wind speed were retrieved by differential absorption lidar and correlation technique, respectively. Lidar returns were obtained up to a range of 3 km. The spatial resolution was 15 mand the temporal resolution was 20 s. By combining these measurements, the water vapor flux in the Stromboli volcano plume was found. To our knowledge, it is the first time that lidar retrieves water vapor concentrations in a volcanic plume.
    Description: Published
    Description: 1295–1298
    Description: 1.10. TTC - Telerilevamento
    Description: JCR Journal
    Description: reserved
    Keywords: Lidar ; Volcanic plume ; DIAL ; Water vapor ; 04. Solid Earth::04.02. Exploration geophysics::04.02.01. Geochemical exploration ; 04. Solid Earth::04.08. Volcanology::04.08.01. Gases ; 04. Solid Earth::04.08. Volcanology::04.08.06. Volcano monitoring
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  • 4
    Publication Date: 2017-04-04
    Description: The continuous volcanic and seismic activity at Mount Etna makes this volcano an important laboratory for seismological and geophysical studies. We used repeated three-dimensional tomography to detect variations in elastic parameters during different volcanic cycles, before and during the October 2002–January 2003 flank eruption. Well-defined anomalous low P- to S-wave velocity ratio volumes were revealed. Absent during the pre-eruptive period, the anomalies trace the intrusion of volatile-rich (Q4 weight percent) basaltic magma, most of which rose up only a few months before the onset of eruption. The observed time changes of velocity anomalies suggest that four-dimensional tomography provides a basis for more efficient volcano monitoring and shortand midterm eruption forecasting of explosive activity.
    Description: Published
    Description: 821-823
    Description: reserved
    Keywords: NONE ; 04. Solid Earth::04.01. Earth Interior::04.01.02. Geological and geophysical evidences of deep processes ; 04. Solid Earth::04.06. Seismology::04.06.07. Tomography and anisotropy ; 04. Solid Earth::04.08. Volcanology::04.08.06. Volcano monitoring
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  • 5
    Publication Date: 2017-04-04
    Description: In this paper we present a collection of good quality shear wave splitting measurements in Southern Italy. In addition to a large amount of previous splitting measurements, we present new data from 15 teleseisms recorded from 2003 to 2006 at the 40 stations of the CAT/SCAN temporary network. These new measurements provide additional constraints on the anisotropic behaviour of the study region and better define the fast directions in the southern part of the Apulian Platform. For our analysis we have selected wellrecorded SKS phases and we have used the method of Silver and Chan to obtain the splitting parameters: the azimuth of the fast polarized shear wave (φ) and delay time (δt). Shear wave splitting results reveal the presence of a strong seismic anisotropy in the subduction system below the region. Three different geological and geodynamic regions are characterized by different anisotropic parameters. The Calabrian Arc domain has fast directions oriented NNE–SSW and the Southern Apennines domain has fast directions oriented NNW–SSE. This rotation of fast axes, following the arcuate shape of the slab, is marked by a lack of resolved measurements which occurs at the transition zone between those two domains. The third domain is identified in the Apulian Platform: here fast directions are oriented almost N–S in the northern part and NNE–SSW to ENE–WSW in the southern one. The large number of splitting parameters evaluated for events coming from different back-azimuth allows us to hypothesize the presence of a depth-dependent anisotropic structure which should be more complicated than a simple 2 layer model below the Southern Apennines and the Calabrian Arc domains and to constrain at 50 km depth the upper limit of the anisotropic layer, at least at the edge of Southern Apennines and Apulian Platform. We interpret the variability in fast directions as related to the fragmented subduction system in the mantle of this region. The trench-parallel φ observed in Calabrian Arc and in Southern Apennines has its main source in the asthenospheric flow below the slab likely due to the pressure induced by the retrograde motion of the slab itself. The pattern of φ in the Apulian Platform does not appear to be the direct result of the rollback motion of the slab, whose influence is limited to about 100 km from the slab. The anisotropy in the Apulian Platform may be related to an asthenospheric flow deflected by the complicated structure of the Adriatic microplate or may also be explained as frozen-in lithospheric anisotropy.
    Description: Published
    Description: 49-67
    Description: 3.3. Geodinamica e struttura dell'interno della Terra
    Description: JCR Journal
    Description: partially_open
    Keywords: Shear wave splitting ; Subduction ; Mantle flow ; Southern Italy ; 04. Solid Earth::04.01. Earth Interior::04.01.02. Geological and geophysical evidences of deep processes ; 04. Solid Earth::04.01. Earth Interior::04.01.03. Mantle and Core dynamics ; 04. Solid Earth::04.06. Seismology::04.06.07. Tomography and anisotropy ; 04. Solid Earth::04.07. Tectonophysics::04.07.02. Geodynamics ; 04. Solid Earth::04.07. Tectonophysics::04.07.06. Subduction related processes
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  • 6
    Publication Date: 2017-04-04
    Description: The first geochemical data showing the existence of an active degassing activity over a large seismically active sector of the Southern Alps (Friuli Region, NE Italy) are presented. The dissolved gases, helium and carbon isotopic systematics of 46 water samples taken from 13 sites running along E–W and NE–SW faults besides the natural degassing of a 5000 km2 wide area are investigated. The chemical composition of the dissolved gases revealed that a CO2-rich gas phase feeds the local groundwaters. 3He/4He ratios (R) normalized to the atmospheric 3He/4He ratio (Ra=1.39×10−6) and corrected for the atmospheric contamination (R/Rac), range from 0.29 to 1 as a result of a two component (radiogenic and atmospheric) mixing. The δ13C values of total dissolved inorganic carbon (TDIC) ranging from −15.28 to −0.75‰ vs. PDB, show the occurrence of multiple gas–water interactions. The mixing between the atmospheric air and a crustal source and the gas–water interactions occurring at various extents appears to be the main control on the observed He–C systematics. The natural CO2 degassing was evaluated by a soil gas survey carried out by a grid of about 100 measuring sites located over the area that generated destructive seismic sequences (e.g. the Gemona sequence of 1976; main shocks M6.4 of 6th May and M6.1 of 11th and 15th September). The results obtained show that a significant amount of crustal-originated gases are released over the continental area of Eastern Southern Alps. The evidence that carbon dioxide is associated with radiogenic-type helium denotes the lack of the mantle as primary energy and degassing source, highlighting the possibility that CO2 is produced by thermo-mechanical processes occurring at seismogenic depth. The information provided here may be used to start up a long-term geochemical monitoring of this seismically active area and could be able to detect the modifications occurring to the circulating fluids to gain a better insight on the relationships between the fluids' geochemistry and the activity of the local seismogenic faults.
    Description: Published
    Description: 76–85
    Description: 3.2. Tettonica attiva
    Description: JCR Journal
    Description: reserved
    Keywords: Fluids ; Faults ; geochemistry ; isotopes ; 04. Solid Earth::04.02. Exploration geophysics::04.02.01. Geochemical exploration
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  • 7
    Publication Date: 2017-04-04
    Description: Geological sequestration of anthropogenic CO2 appears to be a promising method for reducing the amount of greenhouse gases released to the atmosphere. Geochemical modelling of the storage capacity for CO2 in saline aquifers, sandstones and/or carbonates should be based on natural analogues both in situ and in the laboratory. The main focus of this paper has been to study natural gas emissions representing extremely attractive surrogates for the study and prediction of the possible consequences of leakage from geological sequestration sites of anthropogenic CO2 (i.e., the return to surface, potentially causing localised environmental problems). These include a comparison among 3 different Italian case histories: i) the Solfatara crater (Phlegraean Fields caldera, southern Italy) is an ancient Roman spa. The area is characterized by intense and diffuse hydrothermal activity, testified by hot acidic mud pools, thermal springs and a large fumarolic field.. Soil gas flux measurements show that the entire area discharges between 1200 and 1500 tons of CO2 a day; ii) the Panarea island (Aeolian islands, southern Italy) where a huge submarine volcanic-hydrothermal gas burst occurred in November, 2002. The submarine gas emissions chemically modified seawater causing a strong modification of the marine ecosystem. All of the collected gases are CO2-dominant (maximum value: 98.43 vol. %); iii) the Tor Caldara area (Central Italy), located in a peripheral sector of the quiescent Alban Hills volcano, along the faults of the Ardea Basin transfer structure. The area is characterized by huge CO2 degassing both from water and soil. Although the above mentioned areas do not represent a storage scenario, these sites do provide many opportunities to study near-surface processes and to test monitoring methodologies.
    Description: Published
    Description: 1339-1346
    Description: 4.5. Studi sul degassamento naturale e sui gas petroliferi
    Description: JCR Journal
    Description: reserved
    Keywords: gas emission ; natural analogue ; 04. Solid Earth::04.02. Exploration geophysics::04.02.01. Geochemical exploration
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  • 8
    Publication Date: 2017-04-04
    Description: Hydrothermal systems and related vents can exhibit dramatic changes in their physico-chemical conditions over time as a response to varying activity in the feeding magmatic systems. Massive steam condensation and gas scrubbing processes of thermal fluids during their ascent and cooling cause further compositional changes that mask information regarding the conditions evolving at depth in the hydrothermal system. Here we propose a new stability diagram based on the CO2-CH4-CO-H2 concentrations in vapor, which aims at calculating the temperatures and pressures in hydrothermal reservoirs. To filter gas scrubbing effects, we have also developed a model for selective dissolution of CO2-H2S-N2-CH4-He-Ne mixtures in fresh and/or air-saturated seawater. This methodology has been applied to the recent (November 2002) crisis that affected the geothermal field off the island of Panarea (Italy), where the fluid composition and fluxes have been monitored for the past two decades. The chemical and isotopic compositions of the gases suggest that the volatile elements originate from an active magma, which feeds a boiling saline solution having temperatures of up to 350 C and containing 12 mol CO2 in vapor. The thermal fluids undergo cooling and re-equilibration processes on account of gas-water-rock interactions during their ascent along fracture networks. Furthermore, steam condensation and removal of acidic species, partial dissolution in cold air-saturated seawater and stripping of atmospheric components, affect the composition of the geothermal gases at shallow levels. The observed geochemical variations are consistent with a new input of magmatic fluids that perturbed the geothermal system and caused the unrest event. The present-state evolution shows that this dramatic input of fluids is probably over, and that the system is now tending towards steady-state conditions on a time scale of months.
    Description: Published
    Description: 3045-3059
    Description: partially_open
    Keywords: Submarine degassing ; geothermal system ; gas-water interaction ; gas geothermometry ; 04. Solid Earth::04.01. Earth Interior::04.01.02. Geological and geophysical evidences of deep processes ; 04. Solid Earth::04.08. Volcanology::04.08.01. Gases ; 04. Solid Earth::04.08. Volcanology::04.08.04. Thermodynamics ; 04. Solid Earth::04.08. Volcanology::04.08.06. Volcano monitoring ; 05. General::05.02. Data dissemination::05.02.01. Geochemical data
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  • 9
    Publication Date: 2017-04-04
    Description: The northwestern flank of the Colli Albani, a Quaternary volcanic complex near Rome, is characterised by high CO2 values and Rn activities in the groundwater and by the presence of zones with strong emission of gas from the soil. The most significant of these zones is Cava dei Selci where many houses are located very near to the gas emission site. The emitted gas consists mainly of CO2 (up to 98 vol) with an appreciable content of H2S (0.8). The He and C isotopic composition indicates, as for all fluids associated with the Quaternary Roman and Tuscany volcanic provinces, the presence of an upper mantle component contaminated by crustal fluids associated with subducted sediments and carbonates. An advective CO2 flux of 37 tons/day has been estimated from the gas bubbles rising to the surface in a small drainage ditch and through a stagnant water pool, present in the rainy season in a topographically low central part of the area. A CO2 soil flux survey with an accumulation chamber, carried out in February-March 2000 over a 12 000 m2 surface with 242 measurement points, gave a total (mostly conductive) flux of 61 tons/day. CO2 soil flux values vary by four orders of magnitude over a 160-m distance and by one order of magnitude over several metres. A fixed network of 114 points over 6350 m2 has been installed in order to investigate temporal flux variations. Six surveys carried out from May 2000 to June 2001 have shown large variations of the total CO2 soil flux (8/25 tons/day). The strong emission of CO2 and H2S, which are gases denser than air, produces dangerous accumulations in low areas which have caused a series of lethal accidents to animals and one to a man. The gas hazard near the houses has been assessed by continuously monitoring the CO2 and H2S concentration in the air at 75 cm from the ground by means of two automatic stations. Certain environmental parameters (wind direction and speed; atm P, T, humidity and rainfall) were also continuously recorded. At both stations, H2S and CO2 exceeded by several times the recommended concentration thresholds. The highest CO2 and H2S values were recorded always with wind speeds less than 1.5 m/s, mostly in the night hours. Our results indicate that there is a severe gas hazard for people living near the gas emission site of Cava dei Selci, and appropriate precautionary and prevention measures have been recommended both to residents and local authorities.
    Description: - GNV funded research project Gas Hazard of Colli Albani
    Description: Published
    Description: 81^94
    Description: partially_open
    Keywords: Colli Albani ; CO2 flux ; H2S ; gas hazard ; 01. Atmosphere::01.01. Atmosphere::01.01.07. Volcanic effects ; 04. Solid Earth::04.01. Earth Interior::04.01.02. Geological and geophysical evidences of deep processes ; 04. Solid Earth::04.03. Geodesy::04.03.06. Measurements and monitoring ; 04. Solid Earth::04.04. Geology::04.04.12. Fluid Geochemistry ; 04. Solid Earth::04.08. Volcanology::04.08.01. Gases ; 04. Solid Earth::04.08. Volcanology::04.08.02. Experimental volcanism ; 04. Solid Earth::04.08. Volcanology::04.08.06. Volcano monitoring ; 05. General::05.02. Data dissemination::05.02.01. Geochemical data ; 04. Solid Earth::04.08. Volcanology::04.08.08. Volcanic risk
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  • 10
    Publication Date: 2017-04-04
    Description: Shear-wave splitting estimates from recordings of 10 portable seismographic stations during the first year of the RETREAT seismic deployment, in combination with broadband data from the Italian national seismic network, are associated with seismic anisotropy within the upper mantle beneath the Northern Apennines. Anisotropic parameters derived from both shear-wave splitting and P travel-time residuals vary geographically and depend on event back-azimuth, reflecting complexity in the underlying mantle strain field. Variations of the splitting time delays and fast polarization seem to exclude a 2-D sublithosphere corner flow, associated with the Apennines subduction, as the main source of the inferred anisotropy. The anisotropic signal may be generated by a frozen-in fabric of the Adriatic and Tyrrhenian lithosphere domains, or by flow variations induced by episodic and fragmentary slab rollback.
    Description: Published
    Description: 157-170
    Description: JCR Journal
    Description: reserved
    Keywords: birefringence; ; Apennines ; 04. Solid Earth::04.01. Earth Interior::04.01.02. Geological and geophysical evidences of deep processes
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  • 11
    Publication Date: 2017-04-04
    Description: The sustained and uninterrupted plume degassing at Mount Etna volcano, Southern Italy, represents the troposphere’s most prominent natural source of fluorine. Of the ~ 200 Mg of fluorine (as HFg) emitted daily by the volcano, 1.6±2.7 Mg are deposited by wet and dry deposition. Fluorine-deposition via volcanic ash, here characterised for the first time, can be quite significant during volcanic eruptions (i.e. 60 Mg of fluorine were deposited during the 2001 eruption through volcanic ash, corresponding to ~ 85% of the total fluorine deposition). Despite the fact that these depositions are huge, the fate of the deposited fluorine and its impact on the environment are poorly understood. We herein present original data on fluorine abundance in vegetation (Castanea Sativa and Pinus Nigra) and andosoils from the volcano’s flank, in the attempt to reveal the potential impact of volcanogenic fluorine emissions. Fluorine contents in chestnut leaves and pine needles are in the range 1.8-35 µg/g and 2.1-74 µg/g respectively; they exceed the typical background concentrations in plants growing in rural areas, but fall within the lower range of typical concentrations in plants growing near high fluorine anthropogenic emission sources. The rare plume fumigations on the lower flanks of Mt Etna (distance 〉 4 km from summit craters) are probably the cause of the “undisturbed” nature of Etnean vegetation: climatic conditions, which limit the growth of vegetation on the upper regione deserta, are a natural limit to the development of more severe impacts. High fluorine contents, associated with visible symptoms, were only measured in pine needles at three sites, located near recently-active (2001 to 2003) lateral eruptive fractures. Total fluorine contents (FTOT) in the Etnean soils have a range of 112-341 µg/g, and fall within the typical range of undisturbed soils; fluorine extracted with distilled water (FH2O) have a range of 5.1 to 61 µg/g and accounts for 2-40 % of FTOT. FH2O is higher in topsoils from the eastern flank (downwind), while it decreases with depth in soil profiles and on increasing soil grain size (thereby testifying to its association with clay-mineral-rich, fine soil fractions). The fluorine adsorption capacity of the andosoils acts as a natural barrier that protects the groundwater system.
    Description: Published
    Description: 87-101
    Description: 1.2. TTC - Sorveglianza geochimica delle aree vulcaniche attive
    Description: 4.5. Degassamento naturale
    Description: JCR Journal
    Description: reserved
    Keywords: Mt. Etna ; Fluorine ; environmental volcanology ; impact of volcanic F ; soils ; vegetation ; volcanic ash ; 01. Atmosphere::01.01. Atmosphere::01.01.07. Volcanic effects ; 03. Hydrosphere::03.03. Physical::03.03.01. Air/water/earth interactions ; 04. Solid Earth::04.02. Exploration geophysics::04.02.01. Geochemical exploration ; 04. Solid Earth::04.04. Geology::04.04.12. Fluid Geochemistry ; 04. Solid Earth::04.08. Volcanology::04.08.01. Gases ; 05. General::05.08. Risk::05.08.01. Environmental risk
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  • 12
    Publication Date: 2017-04-04
    Description: Metamorphic and magmatic garnets are known to fractionate REE, with generally HREE-enriched patterns, and high Lu/ Hf and Sm/Nd ratios, making them very useful as geochemical tracers and in geochronological studies. However, these garnets are typically Al-rich (pyrope, almandine, spessartine, and grossular) and little is known about garnets with a more andraditic (Fe3+) composition, as frequently found in skarn systems. This paper presents LA-ICP-MS data for garnets from the Crown Jewel Au-skarn deposit (USA), discusses the factors controlling incorporation of REE into garnets, and strengthens the potential of garnet REE geochemistry as a tool to help understand the evolution of metasomatic fluids. Garnets from the Crown Jewel deposit range from Adr30Grs70 to almost pure andradite (Adr〉99). Fe-rich garnets (Adr〉90) are isotropic, whereas Al-rich garnets deviate from cubic symmetry and are anisotropic, often showing sectorial dodecahedral twinning. All garnets are extremely LILE-depleted, Ta, Hf, and Th and reveal a positive correlation of RREE3+ with Al content. The Al-rich garnets are relatively enriched in Y, Zr, and Sc and show ‘‘typical’’ HREE-enriched and LREE-depleted patterns with small Eu anomalies. Fe-rich garnets (Adr〉90) have much lower RREE and exhibit LREE-enriched and HREE-depleted patterns, with a strong positive Eu anomaly. Incorporation of REE into garnet is in part controlled by its crystal chemistry, with REE3+ following a coupled, YAG-type substitution mechanism ð½ X2þ VIII 1 ½REE3þ VIII þ1 ½ Si4þ IV 1½Z3þ IV þ1Þ, whereas Eu2+ substitutes for X2+ cations. Thermodynamic data (e.g., Hmixing) in grossular– andradite mixtures suggest preferential incorporation of HREE in grossular and LREE in more andraditic compositions. Variations in textural and optical features and in garnet geochemistry are largely controlled by external factors, such as fluid composition, W/R ratios, mineral growth kinetics, and metasomatism dynamics, suggesting an overall system that shifts dynamically between internally and externally buffered fluid chemistry driven by fracturing. Al-rich garnets formed by diffusive metasomatism, at low W/R ratios, from host-rock buffered metasomatic fluids. Fe-rich garnets grow rapidly by advective metasomatism, at higher W/R ratios, from magmatic-derived fluids, consistent with an increase in porosity by fracturing.
    Description: Published
    Description: 185-205
    Description: 3.6. Fisica del vulcanismo
    Description: 3.8. Geofisica per l'ambiente
    Description: JCR Journal
    Description: reserved
    Keywords: A LA-ICP-MS ; Crown Jewel ; 04. Solid Earth::04.01. Earth Interior::04.01.04. Mineral physics and properties of rocks ; 04. Solid Earth::04.02. Exploration geophysics::04.02.01. Geochemical exploration ; 04. Solid Earth::04.04. Geology::04.04.05. Mineralogy and petrology ; 04. Solid Earth::04.04. Geology::04.04.12. Fluid Geochemistry ; 04. Solid Earth::04.08. Volcanology::04.08.06. Volcano monitoring
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  • 13
    Publication Date: 2017-04-04
    Description: The 2001 eruption represents one of the most studied events both from volcanological and geophysical point of view on Mt. Etna. This eruption was a crucial event in the recent dynamic of the volcano, marking the passage from a period (March 1993 – June 2001) of moderate stability with slow, continuous flank sliding and contemporaneous summit eruptions, to a period (July 2001 to present) of dramatically increased flank deformations and flank eruptions. We show new GPS data and high precision relocation of seismicity in order to demonstrate the role of the 2001 intrusive phase in this change of the dynamic regime of the volcano. GPS data consist of two kinematic surveys carried out on 12 July, a few hours before the beginning of the seismic swarm, and on 17 July, just after the onset of eruptive activity. A picture of the spatial distribution of the sin-eruptive seismicity has been obtained using the HypoDD relocation algorithm based on the double-difference (DD) technique. Modeling of GPS measurements reveal a southward motion of the upper southern part of the volcano, driven by a NNW-SSE structure showing mainly left-lateral kinematics. Precise hypocenter location evidences an aseismic zone at about sea level, where the magma upraise was characterized by a much higher velocity and an abrupt westward shift, revealing the existence of a weakened or ductile zone. These results reveal how an intrusion of a dike can severely modify the shallow stress field, triggering significant flank failure. In 2001, the intrusion was driven by a weakened surface, which might correspond to a decollement plane of the portion of the volcano affected by flank instability, inducing an additional stress testified by GPS measurements and seismic data, which led to an acceleration of the sliding flanks.
    Description: In press
    Description: 1.1. TTC - Monitoraggio sismico del territorio nazionale
    Description: 1.3. TTC - Sorveglianza geodetica delle aree vulcaniche attive
    Description: 1.4. TTC - Sorveglianza sismologica delle aree vulcaniche attive
    Description: 1.5. TTC - Sorveglianza dell'attività eruttiva dei vulcani
    Description: 3.2. Tettonica attiva
    Description: 3.5. Geologia e storia dei sistemi vulcanici
    Description: 3.6. Fisica del vulcanismo
    Description: 4.2. TTC - Scenari e mappe di pericolosità sismica
    Description: 4.3. TTC - Scenari di pericolosità vulcanica
    Description: 4.4. Scenari e mitigazione del rischio ambientale
    Description: JCR Journal
    Description: reserved
    Keywords: Stress release ; Dike ; Volcano-tectonics ; Flank instability ; Mount Etna ; Instrumental monitoring ; 04. Solid Earth::04.01. Earth Interior::04.01.99. General or miscellaneous ; 04. Solid Earth::04.01. Earth Interior::04.01.02. Geological and geophysical evidences of deep processes ; 04. Solid Earth::04.02. Exploration geophysics::04.02.99. General or miscellaneous ; 04. Solid Earth::04.03. Geodesy::04.03.99. General or miscellaneous ; 04. Solid Earth::04.03. Geodesy::04.03.06. Measurements and monitoring ; 04. Solid Earth::04.03. Geodesy::04.03.07. Satellite geodesy ; 04. Solid Earth::04.04. Geology::04.04.99. General or miscellaneous ; 04. Solid Earth::04.04. Geology::04.04.01. Earthquake geology and paleoseismology ; 04. Solid Earth::04.04. Geology::04.04.09. Structural geology ; 04. Solid Earth::04.06. Seismology::04.06.99. General or miscellaneous ; 04. Solid Earth::04.06. Seismology::04.06.03. Earthquake source and dynamics ; 04. Solid Earth::04.06. Seismology::04.06.04. Ground motion ; 04. Solid Earth::04.06. Seismology::04.06.08. Volcano seismology ; 04. Solid Earth::04.07. Tectonophysics::04.07.99. General or miscellaneous ; 04. Solid Earth::04.07. Tectonophysics::04.07.02. Geodynamics ; 04. Solid Earth::04.07. Tectonophysics::04.07.05. Stress ; 04. Solid Earth::04.07. Tectonophysics::04.07.07. Tectonics ; 04. Solid Earth::04.08. Volcanology::04.08.99. General or miscellaneous ; 04. Solid Earth::04.08. Volcanology::04.08.06. Volcano monitoring ; 04. Solid Earth::04.08. Volcanology::04.08.07. Instruments and techniques ; 04. Solid Earth::04.08. Volcanology::04.08.08. Volcanic risk ; 05. General::05.02. Data dissemination::05.02.03. Volcanic eruptions
    Repository Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
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  • 14
    Publication Date: 2017-04-04
    Description: Three different methodologies were used to measure Radon (222Rn) in soil, based on both passive and active detection system. The first technique consisted of Solid State Nuclear Track Detectors (SSNTD), CR-39 type, and allowed integrated measurements. The second one consisted of a portable device for short time measurements. The last consisted of a continuous measurement device for extended monitoring, placed in selected sites. Soil 222Rn activity was measured together with soil Thoron (220Rn) and soil carbon dioxide (CO2) efflux, and it was compared with the content of radionuclides in the rocks. Two different soil gas horizontal transects were investigated across the Pernicana fault system (NE flank of Mount Etna), from November 2006 to April 2007. The results obtained with the three methodologies are in a general agreement with each other and reflect the tectonic settings of the investigated study area. The lowest 222Rn values were recorded just on the fault plane, and relatively higher values were recorded a few tens of meters from the fault axis on both of its sides. This pattern could be explained as a dilution effect resulting from high rates of soil CO2 efflux. Time variations of 222Rn activity were mostly linked to atmospheric influences, whereas no significant correlation with the volcanic activity was observed. In order to further investigate regional radon distributions, spot measurements were made to identify sites having high Rn emissions that could subsequently be monitored for temporal radon variations.. SSNTD measurements allow for extended-duration monitoring of a relatively large number of sites, although with some loss of temporal resolution due to their long integration time. Continuous monitoring probes are optimal for detailed time monitoring, but because of their expense, they can best be used to complement the information acquired with SSNTD in a network of monitored sites.
    Description: In press
    Description: 1.2. TTC - Sorveglianza geochimica delle aree vulcaniche attive
    Description: 1.5. TTC - Sorveglianza dell'attività eruttiva dei vulcani
    Description: 3.2. Tettonica attiva
    Description: 4.4. Scenari e mitigazione del rischio ambientale
    Description: 4.5. Degassamento naturale
    Description: JCR Journal
    Description: reserved
    Keywords: Soil Radon and Thoron activity ; soil CO2 efflux ; Pernicana fault system ; Mount Etna ; volcano-tectonic monitoring ; 03. Hydrosphere::03.04. Chemical and biological::03.04.07. Radioactivity and isotopes ; 03. Hydrosphere::03.04. Chemical and biological::03.04.08. Instruments and techniques ; 04. Solid Earth::04.01. Earth Interior::04.01.99. General or miscellaneous ; 04. Solid Earth::04.02. Exploration geophysics::04.02.01. Geochemical exploration ; 04. Solid Earth::04.02. Exploration geophysics::04.02.05. Downhole, radioactivity, remote sensing, and other methods ; 04. Solid Earth::04.04. Geology::04.04.99. General or miscellaneous ; 04. Solid Earth::04.04. Geology::04.04.06. Rheology, friction, and structure of fault zones ; 04. Solid Earth::04.04. Geology::04.04.09. Structural geology ; 04. Solid Earth::04.06. Seismology::04.06.99. General or miscellaneous ; 04. Solid Earth::04.07. Tectonophysics::04.07.99. General or miscellaneous ; 04. Solid Earth::04.07. Tectonophysics::04.07.07. Tectonics ; 04. Solid Earth::04.08. Volcanology::04.08.99. General or miscellaneous ; 04. Solid Earth::04.08. Volcanology::04.08.06. Volcano monitoring ; 04. Solid Earth::04.08. Volcanology::04.08.07. Instruments and techniques
    Repository Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
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  • 15
    Publication Date: 2017-04-04
    Description: Dynamic accumulation chamber methods have been extensively used to estimate the total output of CO2 released from active volcanic area. In order to asses the performance and reliability of a closed dynamic system several tests were carried out with different soil permeabilities and soil CO2 fluxes. A special device was used to create a constant one-dimensional CO2 flux through a soil column with a known permeability. Three permeabilities were investigated, ranging between 3.6 × 10− 2 and 3.5 × 10 μm2, as were several CO2 fluxes (ranging between 1.1 × 10− 6 and 6.3 × 10− 5 kg m− 2 s− 1). The results highlight that the accuracy of soil CO2 flux measurements strictly depends on the soil gas permeability and the soil CO2 flux regimen. Generally chamber measurements underestimate CO2 fluxes at low soil permeability and low soil CO2 fluxes, whereas appreciable overestimations occur for high permeability soil, especially for high soil CO2 fluxes. Other tests carried out with different settings for the measurement device, such as the chamber volume and the flux of the pump used to recirculate air through the chamber and the gas analyzer (recirculation flux), revealed a strong dependence of the closed dynamic chamber measurements on the recirculation flux. Low recirculation fluxes (0.2–0.4 l min− 1) decreased the performance of the measurement system, causing underestimations of the actual soil CO2 flux, whereas higher values (0.6–1.0 l min− 1) resulted in overestimations, especially for elevated soil CO2 fluxes. An empirical equation was deduced to allow accumulation chamber fluxes to be calculated very accurately based on soil gas permeabilities measured in the field.
    Description: Published
    Description: 387-393
    Description: 1.2. TTC - Sorveglianza geochimica delle aree vulcaniche attive
    Description: 4.5. Studi sul degassamento naturale e sui gas petroliferi
    Description: JCR Journal
    Description: reserved
    Keywords: Soil CO2 flux measuraments ; Closed dynamic chamber ; soil gas permeability ; 04. Solid Earth::04.02. Exploration geophysics::04.02.01. Geochemical exploration ; 04. Solid Earth::04.04. Geology::04.04.12. Fluid Geochemistry ; 04. Solid Earth::04.08. Volcanology::04.08.01. Gases ; 04. Solid Earth::04.08. Volcanology::04.08.06. Volcano monitoring ; 04. Solid Earth::04.08. Volcanology::04.08.07. Instruments and techniques
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  • 16
    Publication Date: 2017-04-04
    Description: This survey proposes a new approach to identify buried caldera boundaries of a volcanic cone, combining (1) a systematic elliptic Fourier functions (EFF) analysis on the contour lines based on the external shape of the edifice with (2) self-potential (SP) measurements on volcano flanks. The methodology of this approach is to investigate the relationships between (1) vertical morphological changes inferred from EFF analysis and (2) lateral lithological transition inside the edifice inferred from SP/elevation gradients. The application of these methods on Misti volcano in southern Peru displays a very good correlation. The three main boundaries evidenced by hierarchical cluster analysis on the contour lines coincide with the two main boundaries characterised by SP signal and with a secondary SP signature related with a summit caldera. In order to explain these results showing a very good correlation between morphologic and lithologic changes as function of elevation, caldera boundaries have been suggested. The latter would be located at an average elevation of (1) 4350–4400 m, (2) 4950–5000 m, and (3) 5500– 5550 m. For the lowest boundary in elevation, the coincidence with the lateral extension of the hydrothermal system inferred from SP measurements suggests that caldera walls act as a barrier for lateral extension of hydrothermal systems. In the summit area, the highest boundary has been related with the summit caldera, inferred by a secondary SP minimum and geological evidence.
    Description: - Institut de Recherche pour le Développement (IRD) - Instituto Geofisico del Peru´ (IGP).
    Description: Published
    Description: 283– 297
    Description: partially_open
    Keywords: caldera ; elliptic Fourier functions ; geomorphology ; self-potential ; Misti volcano ; Peru ; 03. Hydrosphere::03.02. Hydrology::03.02.02. Hydrological processes: interaction, transport, dynamics ; 03. Hydrosphere::03.02. Hydrology::03.02.03. Groundwater processes ; 03. Hydrosphere::03.02. Hydrology::03.02.04. Measurements and monitoring ; 03. Hydrosphere::03.04. Chemical and biological::03.04.05. Gases ; 03. Hydrosphere::03.04. Chemical and biological::03.04.06. Hydrothermal systems ; 04. Solid Earth::04.01. Earth Interior::04.01.02. Geological and geophysical evidences of deep processes ; 04. Solid Earth::04.02. Exploration geophysics::04.02.04. Magnetic and electrical methods ; 04. Solid Earth::04.04. Geology::04.04.03. Geomorphology ; 04. Solid Earth::04.04. Geology::04.04.09. Structural geology ; 04. Solid Earth::04.04. Geology::04.04.11. Instruments and techniques ; 04. Solid Earth::04.08. Volcanology::04.08.05. Volcanic rocks ; 05. General::05.02. Data dissemination::05.02.04. Hydrogeological data ; 05. General::05.05. Mathematical geophysics::05.05.99. General or miscellaneous ; 05. General::05.08. Risk::05.08.99. General or miscellaneous ; 04. Solid Earth::04.08. Volcanology::04.08.08. Volcanic risk
    Repository Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
    Type: article
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  • 17
    Publication Date: 2017-04-04
    Description: Volcanism at Mount Etna (Italy) has been observed for millennia and inspired ancient mythologies as well as scientific thought through countless generations.Yetmuch of our understanding of the way this volcano works stems fromstudies of the past 20 years, and in particular from strengthened monitoring since the late 1980s. In addition, the eruptive activity of Etna has undergone significant changes during the past 13 years, and these have led to an improved understanding of the relationship between the plumbing system of the volcano and instability of its eastern to southern f lanks. Following the end of the 1991–1993 eruption, a new eruptive cycle began, which so far has produced about 0.23 km3 of lavas and pyroclastics (dense-rock equivalent). The cycle evolved frominitial recharging of the plumbing system and inf lation, followed by powerful summit eruptions and slow spreading of the eastern to southern f lanks, to a sequence of f lank eruptions accompanied by accelerated f lank displacement. Structurally, the volcanic system has become increasingly unstable during this period. Volcanological, geophysical and geochemical data allow the cause–effect and feedback relationships between magma accumulation below the volcano, f lank instability, and the shift from continuous summit activity to episodic f lank eruptions to be investigated. In this scenario, the growth of magma storage areas at a depth of 3–5 km below sea level exerts pressure against those f lank sectors prone to displacement, causing them to detach from the stable portions of the volcanic edifice. Geochemical data indicate that magma remains stored belowthe volcano, even during phases of intense eruptive activity, thus causing a net volumetric increase that is accommodated by f lank displacement. Instability can be enhanced by the forceful uprise ofmagma through the f lanks, as in 2001, when the f irst f lank eruption of the current eruptive cycle took place. Subsequent f lank eruptions in 2002–2003 and 2004– 2004, on the other hand, were, at least in part, facilitated by the opening of fractures at the head of moving f lank sector, although the eruptions were significantly dissimilar from one another. Renewed inflation of the volcano after the 2004–2005 eruption, continued displacement of the unstable f lank sector, and gradual resumption of summit activity in late-2005, demonstrate that the same feedback mechanisms continue to be active, and the Etna system remains highly unstable. The evolution of earlier eruptive cycles shows that a return to a state of relative stability is only possible once a voluminous f lank eruption effectively drains the magmatic plumbing system.
    Description: Published
    Description: 85–114
    Description: reserved
    Keywords: Mount Etna ; eruptive cycle ; volcano monitoring ; seismicity ; deformation ; geochemistry ; structural geology ; magma storage ; 03. Hydrosphere::03.04. Chemical and biological::03.04.05. Gases ; 04. Solid Earth::04.01. Earth Interior::04.01.02. Geological and geophysical evidences of deep processes ; 04. Solid Earth::04.03. Geodesy::04.03.06. Measurements and monitoring
    Repository Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
    Type: article
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  • 18
    Publication Date: 2017-04-04
    Description: A physical model based on the advective–diffusion theory was developed in order to describe the mixing between a deep gas source and the atmosphere. The model was used to predict the isotopic fractionation of carbon in soil CO2. Gas samples were collected at different depths in areas characterized by different geological settings and CO2 fluxes. The relative theoretical and experimental isotopic profiles were compared and a good agreement was found. These profiles show how the isotopic composition of CO2 changes through the upper few decimeters of soil and how the amount of the isotopic fractionation is strongly influenced by soil CO2 flux. Finally, the model was used to derive the carbon isotopic composition of unfractioned deep CO2 source for all the investigated sites
    Description: Published
    Description: 3016–3027
    Description: 1.2. TTC - Sorveglianza geochimica delle aree vulcaniche attive
    Description: 2.4. TTC - Laboratori di geochimica dei fluidi
    Description: 4.5. Degassamento naturale
    Description: JCR Journal
    Description: reserved
    Keywords: Carbon isotope fractionation ; soil degassing ; gas transport ; D13C(CO2) ; 04. Solid Earth::04.02. Exploration geophysics::04.02.01. Geochemical exploration ; 04. Solid Earth::04.04. Geology::04.04.12. Fluid Geochemistry ; 04. Solid Earth::04.08. Volcanology::04.08.01. Gases
    Repository Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
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  • 19
    Publication Date: 2017-04-04
    Description: An extensive geochemical survey of the fluids released by the volcanic/geothermal system of Methana was undertaken. Gases were characterized based on the chemical and isotopic [helium (He) and carbon (C)] analysis of 27 samples. Carbon dioxide soil gas concentration and fluxes were measured at 179 sampling sites throughout the peninsula. Forty samples of thermal and cold groundwaters were also sampled and analysed to characterize the geochemistry of the aquifers. Gases of hydrothermal origin gave a preliminary geothermometric estimate of about 210 °C. The He-isotope composition indicated mantle contributions of up to 40%, and the C-isotope composition of CO2 indicated that it predominantly (〉90%) originated from limestone decomposition. The groundwater composition was suggestive of mixing between meteoric and hydrothermally modified sea-water endmembers and water–rock interaction processes limited to simple rock dissolution driven by an increased endogenous CO2 content. All of the thermal manifestations and anomalous degassing areas, although of limited extent, were spatially correlated with the main active tectonic system of the area. The total CO2 output of the volcanic system has been preliminary estimated to be less than 0.05 kg s–1. Although this value is very low compared to those of other volcanic systems, anomalous CO2 degassing at Methana – which is currently restricted to limited areas and at present is the only volcanic risk of the peninsula – is a potential gas hazard that warrants further assessment in future studies.
    Description: Published
    Description: 818-828
    Description: 1.2. TTC - Sorveglianza geochimica delle aree vulcaniche attive
    Description: JCR Journal
    Description: reserved
    Keywords: Methana ; south Aegean volcanic arc ; fluids geochemistry ; soil gases ; groundwaters ; 03. Hydrosphere::03.04. Chemical and biological::03.04.03. Chemistry of waters ; 03. Hydrosphere::03.04. Chemical and biological::03.04.05. Gases ; 03. Hydrosphere::03.04. Chemical and biological::03.04.06. Hydrothermal systems ; 04. Solid Earth::04.02. Exploration geophysics::04.02.01. Geochemical exploration ; 04. Solid Earth::04.04. Geology::04.04.12. Fluid Geochemistry ; 04. Solid Earth::04.08. Volcanology::04.08.01. Gases ; 04. Solid Earth::04.08. Volcanology::04.08.06. Volcano monitoring ; 04. Solid Earth::04.08. Volcanology::04.08.08. Volcanic risk
    Repository Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
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  • 20
    Publication Date: 2017-04-04
    Description: The 2001 eruption represents one of the most studied events both from volcanological and geophysical point of view on Mt. Etna. This eruption was a crucial event in the recent dynamics of the volcano, marking the passage from a period (March 1993–June 2001) of moderate stability with slow, continuous flank sliding and contemporaneous summit eruptions, to a period (July 2001 to present) of dramatically increased flank deformations and flank eruptions. We show new GPS data and high precision relocation of seismicity in order to demonstrate the role of the 2001 intrusive phase in this change of the dynamic regime of the volcano. GPS data consist of two kinematic surveys carried out on 12 July, a few hours before the beginning of the seismic swarm, and on 17 July, just after the onset of eruptive activity. A picture of the spatial distribution of the sin-eruptive seismicity has been obtained using the HypoDD relocation algorithm based on the double-difference (DD) technique. Modeling of GPS measurements reveals a southward motion of the upper southern part of the volcano, driven by a NNW–SSE structure showing mainly left-lateral kinematics. Precise hypocenter location evidences an aseismic zone at about sea level, where the magma upraise was characterized by a much higher velocity and an abrupt westward shift, revealing the existence of a weakened or ductile zone. These results reveal how an intrusion of a dike can severely modify the shallow stress field, triggering significant flank failure. In 2001, the intrusion was driven by a weakened surface, which might correspond to a decollement plane of the portion of the volcano affected by flank instability, inducing an additional stress testified by GPS measurements and seismic data, which led to an acceleration of the sliding flanks.
    Description: This work was funded by the Istituto Nazionale di Geofisica e Vulcanologia and by the Dipartimento per la Protezione Civile (Italy).
    Description: Published
    Description: 78–86
    Description: 1.3. TTC - Sorveglianza geodetica delle aree vulcaniche attive
    Description: 1.4. TTC - Sorveglianza sismologica delle aree vulcaniche attive
    Description: 1.5. TTC - Sorveglianza dell'attività eruttiva dei vulcani
    Description: 3.2. Tettonica attiva
    Description: 3.6. Fisica del vulcanismo
    Description: 4.3. TTC - Scenari di pericolosità vulcanica
    Description: JCR Journal
    Description: reserved
    Keywords: stress release ; dike ; volcano-tectonics ; flank instability ; Mt. Etna ; instrumental monitoring ; 04. Solid Earth::04.01. Earth Interior::04.01.99. General or miscellaneous ; 04. Solid Earth::04.01. Earth Interior::04.01.02. Geological and geophysical evidences of deep processes ; 04. Solid Earth::04.02. Exploration geophysics::04.02.99. General or miscellaneous ; 04. Solid Earth::04.03. Geodesy::04.03.99. General or miscellaneous ; 04. Solid Earth::04.03. Geodesy::04.03.07. Satellite geodesy ; 04. Solid Earth::04.04. Geology::04.04.99. General or miscellaneous ; 04. Solid Earth::04.04. Geology::04.04.09. Structural geology ; 04. Solid Earth::04.06. Seismology::04.06.99. General or miscellaneous ; 04. Solid Earth::04.06. Seismology::04.06.08. Volcano seismology ; 04. Solid Earth::04.07. Tectonophysics::04.07.99. General or miscellaneous ; 04. Solid Earth::04.07. Tectonophysics::04.07.05. Stress ; 04. Solid Earth::04.07. Tectonophysics::04.07.07. Tectonics ; 04. Solid Earth::04.08. Volcanology::04.08.99. General or miscellaneous ; 04. Solid Earth::04.08. Volcanology::04.08.03. Magmas ; 04. Solid Earth::04.08. Volcanology::04.08.06. Volcano monitoring ; 04. Solid Earth::04.08. Volcanology::04.08.08. Volcanic risk ; 05. General::05.02. Data dissemination::05.02.99. General or miscellaneous ; 05. General::05.02. Data dissemination::05.02.02. Seismological data ; 05. General::05.02. Data dissemination::05.02.03. Volcanic eruptions
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  • 21
    Publication Date: 2017-04-04
    Description: The study of syntectonic basins, generated at the hanging-wall of regional low-angle detachments, can help to gain a better knowledge of these important and mechanically controversial extensional structures, constraining their kinematics and timing of activity. Seismic reflection images constrain the geometry and internal structure of the Sansepolcro Basin (the northernmost portion of the High Tiber Valley). This basin was generated at the hangingwall of the Altotiberina Fault (AtF), an E-dipping low-angle normal fault, active at least since Late Pliocene, affecting the upper crust of this portion of the Northern Apennines. The dataset analysed consists of 5 seismic reflection lines acquired in the 80s’ by ENI-Agip for oil exploration and a portion of the NVR deep CROP03 profile. The interpretation of the seismic profiles provides a 3-D reconstruction of the basin’s shape and of the sedimentary succession infilling the basin. This consisting of up to 1200 m of fluvial and lacustrine sediments: this succession is much thicker and possibly older than previously hypothesised. The seismic data also image the geometry at depth of the faults driving the basin onset and evolution. The western flank is bordered by a set of E-dipping normal faults, producing the uplifting and tilting of Early to Middle Pleistocene succession along the Anghiari ridge. Along the eastern flank, the sediments are markedly dragged along the SW-dipping Sansepolcro fault. Both NE- and SW-dipping faults splay out from the NE-dipping, low-angle Altotiberina fault. Both AtF and its high-angle splays are still active, as suggested by combined geological and geomorphological evidences: the historical seismicity of the area can be reasonably associated to these faults, however the available data do not constrain a unambiguous association between the single structural elements and the major earthquakes.
    Description: Published
    Description: 285-293
    Description: 3.2. Tettonica attiva
    Description: JCR Journal
    Description: open
    Keywords: Sansepolcro basin; ; seismic reflection profiles; ; extensional basin; ; Central Italy ; 04. Solid Earth::04.01. Earth Interior::04.01.02. Geological and geophysical evidences of deep processes
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  • 22
    Publication Date: 2017-04-04
    Description: We present here the new observations of seismic anisotropy obtained from SKS birefringence analysis. We studied 27 teleseismic earthquakes recorded by the temporary seismic network of RETREAT project in the Northern Apennines region. For each station–event couple we calculate the anisotropic parameters (delay time and fast-polarization direction) by minimizing the energy in the transverse component. Our measurements confirm the existence of two domains. The Tuscany domain, on the south-west with respect to the Apennines, shows mostly NW–SE fast axes directions, with a rotation toward E–W direction moving toward the Tyrrhenian Sea. The Adria domain, north-east of the Apennines orogen, shows more scattered measurements, with prevailing N–S to NNE–SSW directions; also with back-azimuthal dependence. The transition between the two domains is abrupt in the nothern part of the study region but more gradual in the southern part. Measured delay times (1.8 s on average) suggest that the detected anisotropy is located principally in the asthenosphere. Beneath the Adria domain, where the presence of a double-layer structure seems consistent, a lithospheric contribution is plausible. An interpretation in terms of ongoing mantle deformation suggests a differential evolution of the trench-retreat process along the Northern Apennines orogen. The orogen-parallel anisotropy in the study region is beneath the inner part of the belt instead of beneath its crest and no orogen-normal measurements are found in the Tuscany side. Compared to the anisotropy pattern of the typical slab retreat seen in southern part of the Northern Apennines, in the northernmost one the anisotropy suggests that an oblique trench-retreat has occurred, possibly linked to Northern Apennines retreat since 5 Ma.
    Description: Published
    Description: 68-82
    Description: 3.3. Geodinamica e struttura dell'interno della Terra
    Description: JCR Journal
    Description: reserved
    Keywords: seismic anisotropy ; mantle deformation ; Northern Apennines ; 04. Solid Earth::04.01. Earth Interior::04.01.02. Geological and geophysical evidences of deep processes
    Repository Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
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  • 23
    Publication Date: 2017-04-04
    Description: Society’s needs for a network of in situ ocean observing systems cross many areas of earth and marine science. Here we review the science themes that benefit from data supplied from ocean observatories. Understanding from existing studies is fragmented to the extent that it lacks the coherent long-term monitoring needed to address questions at the scales essential to understand climate change and improve geo-hazard early warning. Data sets from the deep sea are particularly rare with long-term data available from only a few locations worldwide. These science areas have impacts on societal health and well-being and our awareness of ocean function in a shifting climate. Substantial efforts are underway to realise a network of open-ocean observatories around European Seas that will operate over multiple decades. Some systems are already collecting high-resolution data from surface, water column, seafloor, and sub-seafloor sensors linked to shore by satellite or cable connection in real or near-real time, along with samples and other data collected in a delayed mode. We expect that such observatories will contribute to answering major ocean science questions including: How can monitoring of factors such as seismic activity, pore fluid chemistry and pressure, and gas hydrate stability improve seismic, slope failure, and tsunami warning? What aspects of physical oceanography, biogeochemical cycling, and ecosystems will be most sensitive to climatic and anthropogenic change? What are natural versus anthropogenic changes? Most fundamentally, how are marine processes that occur at differing scales related? The development of ocean observatories provides a substantial opportunity for ocean science to evolve in Europe. Here we also describe some basic attributes of network design. Observatory networks provide the means to coordinate and integrate the collection of standardised data capable of bridging measurement scales across a dispersed area in European Seas adding needed certainty to estimates of future oceanic conditions. Observatory data can be analysed along with other data such as those from satellites, drifting floats, autonomous underwater vehicles, model analysis, and the known distribution and abundances of marine fauna in order to address some of the questions posed above. Standardised methods for information management are also becoming established to ensure better accessibility and traceability of these data sets and ultimately to increase their use for societal benefit. The connection of ocean observatory effort into larger frameworks including the Global Earth Observation System of Systems (GEOSS) and the Global Monitoring of Environment and Security (GMES) is integral to its success. It is in a greater integrated framework that the full potential of the component systems will be realised.
    Description: Published
    Description: 1-33
    Description: 3.7. Dinamica del clima e dell'oceano
    Description: JCR Journal
    Description: reserved
    Keywords: Seafloor and water columnobservatories ; 01. Atmosphere::01.01. Atmosphere::01.01.02. Climate ; 01. Atmosphere::01.01. Atmosphere::01.01.04. Processes and Dynamics ; 01. Atmosphere::01.01. Atmosphere::01.01.08. Instruments and techniques ; 03. Hydrosphere::03.01. General::03.01.03. Global climate models ; 03. Hydrosphere::03.01. General::03.01.07. Physical and biogeochemical interactions ; 03. Hydrosphere::03.01. General::03.01.08. Instruments and techniques ; 03. Hydrosphere::03.03. Physical::03.03.01. Air/water/earth interactions ; 03. Hydrosphere::03.03. Physical::03.03.02. General circulation ; 03. Hydrosphere::03.03. Physical::03.03.03. Interannual-to-decadal ocean variability ; 03. Hydrosphere::03.03. Physical::03.03.05. Instruments and techniques ; 03. Hydrosphere::03.04. Chemical and biological::03.04.01. Biogeochemical cycles ; 03. Hydrosphere::03.04. Chemical and biological::03.04.02. Carbon cycling ; 03. Hydrosphere::03.04. Chemical and biological::03.04.03. Chemistry of waters ; 03. Hydrosphere::03.04. Chemical and biological::03.04.04. Ecosystems ; 03. Hydrosphere::03.04. Chemical and biological::03.04.05. Gases ; 03. Hydrosphere::03.04. Chemical and biological::03.04.06. Hydrothermal systems ; 03. Hydrosphere::03.04. Chemical and biological::03.04.08. Instruments and techniques ; 04. Solid Earth::04.01. Earth Interior::04.01.02. Geological and geophysical evidences of deep processes ; 04. Solid Earth::04.04. Geology::04.04.04. Marine geology ; 04. Solid Earth::04.04. Geology::04.04.11. Instruments and techniques ; 04. Solid Earth::04.04. Geology::04.04.12. Fluid Geochemistry ; 04. Solid Earth::04.05. Geomagnetism::04.05.05. Main geomagnetic field ; 04. Solid Earth::04.05. Geomagnetism::04.05.08. Instruments and techniques ; 04. Solid Earth::04.06. Seismology::04.06.06. Surveys, measurements, and monitoring ; 04. Solid Earth::04.06. Seismology::04.06.07. Tomography and anisotropy ; 04. Solid Earth::04.06. Seismology::04.06.08. Volcano seismology ; 04. Solid Earth::04.06. Seismology::04.06.10. Instruments and techniques ; 04. Solid Earth::04.07. Tectonophysics::04.07.02. Geodynamics ; 04. Solid Earth::04.07. Tectonophysics::04.07.03. Heat generation and transport ; 04. Solid Earth::04.07. Tectonophysics::04.07.04. Plate boundaries, motion, and tectonics ; 04. Solid Earth::04.07. Tectonophysics::04.07.07. Tectonics ; 04. Solid Earth::04.08. Volcanology::04.08.01. Gases ; 04. Solid Earth::04.08. Volcanology::04.08.02. Experimental volcanism ; 04. Solid Earth::04.08. Volcanology::04.08.06. Volcano monitoring ; 04. Solid Earth::04.08. Volcanology::04.08.07. Instruments and techniques ; 05. General::05.01. Computational geophysics::05.01.01. Data processing ; 05. General::05.02. Data dissemination::05.02.99. General or miscellaneous ; 05. General::05.02. Data dissemination::05.02.01. Geochemical data ; 05. General::05.02. Data dissemination::05.02.02. Seismological data ; 05. General::05.02. Data dissemination::05.02.03. Volcanic eruptions ; 05. General::05.02. Data dissemination::05.02.04. Hydrogeological data ; 05. General::05.08. Risk::05.08.01. Environmental risk ; 05. General::05.08. Risk::05.08.02. Hydrogeological risk
    Repository Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
    Type: article
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  • 24
    Publication Date: 2017-04-04
    Description: We model a fault cross-cutting the brittle upper crust and the ductile lower crust. In the brittle layer the fault is assumed to have stick-slip behaviour, whereas the lower ductile crust is inferred to deform in a steady-state shear. Therefore, the brittle-ductile transition (BDT) separates two layers with different strain rate and structural style. This contrasting behaviour determines a stress gradient at the BDT that is eventually dissipated during the earthquake. During the interseismic period, along a normal fault there should form a dilated hinge at and above the BDT. Conversely, an over-compressed volume should rather develop above a thrust plane at the BDT. On a normal fault the earthquake is associated with the coseismic closure of the dilated fractures generated in the stretched hangingwall during the interseismic period. In addition to the shear stress overcoming the friction of the fault, the brittle fault moves when the weight of the hangingwall exceeds the strength of the dilated band above the BDT. On a thrust fault, the seismic event is instead associated with the sudden dilation of the previously over-compressed volume in the hangingwall above the BDT, a mechanism requiring much more energy because it acts against gravity. In both casess, the deeper the BDT, the larger the involved volume, and the bigger the related magnitude. We tested two scenarios with two examples from L’Aquila 2009 (Italy) and Chi-Chi 1999 (Taiwan) events. GPS data, energy dissipation and strain rate analysis support these contrasting evolutions. Our model also predicts, consistently with data, that the interseismic strain rate is lower along the fault segment more prone to seismic activation.
    Description: This research has benefited from funding provided by the Italian Presidenza del Consiglio dei Ministri - Dipartimento della Protezione Civile (DPC) within the INGV-DPC 2007-2009 agreement (project S1), Sapienza University, CNR, Eurocores, TopoEurope.
    Description: In press
    Description: 3.1. Fisica dei terremoti
    Description: 3.2. Tettonica attiva
    Description: 4.3. TTC - Scenari di pericolosità vulcanica
    Description: JCR Journal
    Description: open
    Keywords: brittle-ductile transition ; thrust ; normal fault ; dilatancy ; seismic cycle ; L’Aquila Italy ; Chi-Chi Taiwan ; earthquake ; 04. Solid Earth::04.01. Earth Interior::04.01.02. Geological and geophysical evidences of deep processes ; 04. Solid Earth::04.01. Earth Interior::04.01.05. Rheology ; 04. Solid Earth::04.03. Geodesy::04.03.01. Crustal deformations
    Repository Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
    Type: article
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  • 25
    Publication Date: 2020-02-24
    Description: The physical properties of clay allow argillaceous formations to be considered geological barriers to radionuclide migration in high-level radioactive-waste isolation systems. As laboratory simulations are short term and numerical models always involve assumptions and simplifications of the natural system, natural analogues are extremely attractive surrogates for the study of long-term isolation. The clays of the Orciatico area (Tuscany, Central Italy), which were thermally altered via the intrusion of an alkali-trachyte laccolith, represent an interesting natural model of a heat source which acted on argillaceous materials. The study of this natural analogue was performed through detailed geoelectrical and soil–gas surveys to define both the geometry of the intrusive body and the gas permeability of a clay unit characterized by different degrees of thermal alteration. The results of this study show that gas permeability is increased in the clay sequences subjected to greater heat input from the emplacement of the Orciatico intrusion, despite the lack of apparent mineral and geotechnical variations. These results, which take into consideration long time periods in a natural, large-scale geological system, may have important implications for the long-term safety of underground storage of nuclear waste in clay formations.
    Description: Published
    Description: 1248-1256
    Description: 4.5. Studi sul degassamento naturale e sui gas petroliferi
    Description: JCR Journal
    Description: reserved
    Keywords: soil-gas geochemistry ; clay permeability ; 04. Solid Earth::04.02. Exploration geophysics::04.02.01. Geochemical exploration
    Repository Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
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  • 26
    Publication Date: 2017-04-04
    Description: The first comprehensive geochemical data-set of the fluids circulating over a 14,000 km2-wide seismicprone area of the Southern Apennines, Calabria Region (Italy), is presented here. The geochemical investigations were carried out with the twofold aim of constraining the origin and interactions of the circulating fluids and to investigate possible relationships with local faults. Sixty samples of both thermal and cold waters were collected, from which the dissolved gases were extracted. The geochemical features of the water samples display different types and degrees of water–rock interactions, irrespective of the outlet temperature. The calculated equilibrium temperatures of the thermal waters (60–160 C) and the low heat flow of thewhole study area, are consistent with a heating process due to deep water circulation and rapid upflow through lithospheric structures. The composition of the dissolved gases reveals that crustal-originating gases (N2 and CO2-dominated) feed all the groundwaters. The 3He/4He ratios of the dissolved He, in the range of 0.03–0.22Rac for the thermal waters and 0.05–0.63Rac for the cold waters (Rac = He isotope ratio corrected for atmospheric contamination), are mainly the result of a two-component (radiogenic and atmospheric) mixing, although indications of mantle-derived He are found in some cold waters. As the study area had been hit by 18 of the most destructive earthquakes (magnitude ranging from 5.9 to 7.2) occurring over a 280-a time span (1626–1908) in the Southern Apennines, the reported results on the circulating fluids may represent the reference for a better inside knowledge of the fault-fluid relationships and for the development of long-term geochemical monitoring strategies for the area.
    Description: Published
    Description: 540–554
    Description: 3.2. Tettonica attiva
    Description: JCR Journal
    Description: open
    Keywords: Fluids ; Geochemistry ; Faults ; Seismicity ; 04. Solid Earth::04.02. Exploration geophysics::04.02.01. Geochemical exploration
    Repository Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
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  • 27
    Publication Date: 2017-04-04
    Description: The Miano borehole, 1047 m deep, is located close to the river Parma in the Northern Apennines, Italy. A measuring station has been installed to observe the discharge of fluids continuously since November 2004. The upwelling fluid of this artesian well is a mixture of thermal water and CH4 as main components. In non-seismogenic areas, a relatively constant fluid emission would be expected, perhaps overlaid with long term variations from that kind of deep reservoir over time. However, the continuous record of the fluid emission, in particular the water discharge, the gas flow rate and the water temperature, show periods of stable values interrupted by anomalous periods of fluctuations in the recorded parameters. The anomalous variations of these parameters are of low amplitude in comparison to the total values but significant in their long-term trend. Meteorological effects due to rain and barometric pressure were not detected in recorded data probably due to reservoir depth and relatively high reservoir overpressure. Influences due to the ambient temperature after the discharge were evaluated by statistical analysis. Our results suggest that recorded changes in fluid emission parameters can be interpreted as a mixing process of different fluid components at depth by variations in pore pressure as a result of seismogenic stress variation. Local seismicity was analyzed in comparison to the fluid physico-chemical data. The analysis supports the idea that an influence on fluid transport conditions due to geodynamic processes exists. Water temperature data show frequent anomalies probably connected with possible precursory phenomena of local seismic events.
    Description: Published
    Description: 555–571
    Description: 3.2. Tettonica attiva
    Description: JCR Journal
    Description: open
    Keywords: Fluids ; Seismicity ; 04. Solid Earth::04.02. Exploration geophysics::04.02.01. Geochemical exploration
    Repository Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
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  • 28
    Publication Date: 2017-04-04
    Description: Co-injection of a conservative tracer during the geological sequestration of CO2 can imprint a marker to the injected gas that can be easily recognized during soil gas surveys in case of CO2 leakage from the reservoir toward the surface. In this work, an ultra-trace detection method, based on gas chromatography with electron capture detection for analyzing perfluorocarbon tracers (PFTs) in soil gas samples was optimized. Three totally fluorinated cycloalcane compounds consisting of five and six atom carbon rings were selected for this purpose. We evaluated the feasibility of collecting PFTs on adsorbent tube packed with a commercial graphitized carbon black (Carbotrap™ 100) sampling 2 L of soil gas. The sorbent tubes were then analyzed by using a two-stage thermal desorption process. The developed method allows to quickly determine these compounds at very low fL/L level, method identification limits ranged from 1.3 to 5.8 fL/L. Moreover, it shows good precision, evaluated by within-day and between-day studies. A preliminary survey of the PFT soil gas background concentrations, conducted by analyzing some soil gas samples collected in two different areas in Central Italy and in the Po Plain, ascertained the PFT background concentration lower than MIL.
    Description: Published
    Description: 60-64
    Description: 2.4. TTC - Laboratori di geochimica dei fluidi
    Description: JCR Journal
    Description: partially_open
    Keywords: Perfluorocarbon tracers; Soil gas; Carbon dioxide storage; Leakage monitoring; GC–ECD ; 04. Solid Earth::04.02. Exploration geophysics::04.02.01. Geochemical exploration
    Repository Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
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  • 29
    Publication Date: 2017-04-04
    Description: Two Italian areas, characterized by different seismological histories, were investigated to enhance the basic knowledge of gas migration mechanisms during earthquakes. Sharp variations occur in the movement and concentration of some gaseous species due to the evolution of the local stress regime. The first area (Colpasquale) is located in the central Italian region of Marche and provided a good location to study gas migration in a seismically active region. The area was devastated by a sequence of shallow earthquakes over a 3 month-long period (September–December, 1997). The occurrence of this catastrophic event, as well as the long duration of the ‘‘seismic sequence”, presented a unique opportunity to study gas migration in a zone undergoing active displacement. Soil gas surveys were performed 1 day, 1 week, 1 year and 2 years after the main shock (Ms 5.6) in the Colpasquale area. In particular, results highlight a change in the Rn distribution during the three monitoring years indicating a variation of gas migration that may be linked to the evolution of the stress regime. The second study area is located in the Campidano Graben (southern part of Sardinia Island). This area is characterized by seismic quiescence, displaying an almost complete lack of historical earthquakes and instrumentally recorded seismicity. The consistently low values observed for all analyzed gases suggest that the studied area is likely characterized by sealed, non-active faults that prevent significant gas migration. The comparison of data from both studied areas indicate that soil gas geochemistry is useful to locate tectonic discontinuities even when they intersect non-cohesive clastic rocks near the surface and thus are not visible (i.e., ‘‘blind faults”).
    Description: Published
    Description: 1206-1220
    Description: 4.5. Studi sul degassamento naturale e sui gas petroliferi
    Description: JCR Journal
    Description: reserved
    Keywords: gas geochemistry ; blind faults ; 04. Solid Earth::04.02. Exploration geophysics::04.02.01. Geochemical exploration
    Repository Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
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