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  • Cambridge University Press
  • 2000-2004  (7,846)
  • 1985-1989  (10,902)
  • 1950-1954  (1,787)
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  • 1
    Unknown
    Cambridge, UK ; New York : Cambridge University Press
    Keywords: Distributive justice. ; Economics, Moral and ethical aspects. ; Income distribution. ; Poverty. ; Wealth.
    Pages: vi, 537 p.
    ISBN: 0-511-08215-0
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  • 2
    facet.materialart.
    Unknown
    Cambridge University Press
    In:  Cambridge, 264 pp., Cambridge University Press, vol. 42, no. 3, pp. 632 pp., (ISBN 052)
    Publication Date: 2004
    Keywords: Textbook of geophysics ; Seismology ; Wave propagation ; Ray seismics ; Anisotropy ; Acoustics ; Elasticity ; Layers ; Cagniard ; Inversion ; WKBJ ; Maslov ; Born ; Kirchhoff ; Migration of earthquakes ; Inhomogeneity ; more ; advanced ; than ; Aki ; and ; Richards ; MATLAB
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  • 3
    Publication Date: 2004-01-01
    Description: We investigated Csípo-halom, one of the kurgans that served as a burial place in the Hortobágy area of the Hungarian Great Plain. For pedological description and other studies of the protected mound and its surroundings, only a few monitoring drillings were permitted to get soil samples. On the basis of morphological and visual studies, the structure and layers of the mound were reconstructed. The Laboratory of Environmental Studies of the Institute of Nuclear Research at the Hungarian Academy of Sciences (INR/HAS) performed radiocarbon measurements of soil samples, applying a bulk combustion pretreatment method. The measured 14C ages of soil samples from reference points, such as the top layer of the mound, the center of mound body, the base layer of the mound, the near surroundings, and the distant surroundings, are in good agreement with the preliminary archaeological concept for this field and give substantial information about the rate of soil generation processes in this area.
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  • 4
    Publication Date: 2004-01-01
    Description: We assessed the evidence for variations in the marine radiocarbon reservoir effect (MRE) at coastal, archaeological Iron Age sites in north and west Scotland by comparing AMS measurements of paired marine and terrestrial materials (4 pairs per context). ΔR values were calculated from measurements on material from 3 sites using 6 sets of samples, all of which were deposited around 2000 BP. The weighted mean of the ΔR determinations was −79 ± 17 14C yr, which indicates a consistent, reduced offset between atmospheric and surface ocean 14C specific activity for these sites during this period, relative to the present day (ΔR = ∼0 14C yr). We discuss the significance of this revised ΔR correction by using the example of wheelhouse chronologies at Hornish Point and their development in relation to brochs. In addition, we assess the importance of using the concepts of MRE correction and ΔR variations when constructing chronologies using 14C measurements made on materials that contain marine-derived carbon.
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  • 5
    Publication Date: 2004-12-01
    Description: This paper compares the economic efficiency of firm-agency governance structures for pollution reduction using transaction costs economics. Two governance structures are analyzed with the transaction costs approach: command and control regulation (CCR) and negotiated agreements (NAs). We propose that the choice of governance structure depends on the strategies firms pursue given the attributes of their transactions and their market opportunities. The application of transaction cost economics analysis leads to different choices of regulatory instruments. Firms in more mature, stable industries are likely to choose command and control, while firms in new, dynamic sectors are more likely to opt for negotiated agreements. Frequency of transactions is a key factor in firm choice.
    Print ISSN: 1369-5258
    Electronic ISSN: 1469-3569
    Topics: Political Science , Economics
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  • 6
    Publication Date: 2004-08-01
    Description: The battle between the recording industry and those illegal sharing music over the Internet has gripped headlines over the last few years like few others related to the digital age. At its core, it is a battle about the meaning of property and thus a battle over the heart of the emerging information economy. This article critically examines the double punch of law and technology – the simultaneous and interwoven deployment of legal and electronic measures to protect digital content – and asks whether it is merely a defense strategy against piracy, as the industry asserts, or rather an attempt to fundamentally redefine the producer-consumer relationship. Based on some initial evidence for the latter proposition, the article analyzes reasons for concern, outlines the current politics of copyright policymaking that have given producers the upper hand, and sketches elements of a strategy to fight music piracy that does not infringe on basic consumer rights.
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  • 7
    Publication Date: 2004-12-01
    Description: This paper analyzes congressional voting on tobacco issues over two decades. Contrary to existing claims, the analysis shows that the tobacco industry's legislative success is more a function of representatives' regulatory and pro-business ideologies than of tobacco PAC money or a geographically-based tobacco voting bloc. In most cases, the tobacco voting bloc—representatives and senators from major tobacco producing districts and states—is not strong enough to protect and sustain the tobacco price support system, let alone affect the outcome of commercial issues such as cigarette taxes and regulation. The industry's campaign contributions also have sporadic and limited impact on commercial issues affecting tobacco. Only on agricultural issues do tobacco PAC contributions exhibit any influence.
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  • 8
    Publication Date: 2004-04-01
    Description: ASEAN countries perceive the possible formation of the FTAA as a potential threat on the grounds that it may divert export markets and foreign direct investment (FDI) capital to the FTAA region. This effect, together with the “China factor” and the hangover from the 1997 financial crisis, posts a concern to the ASEAN countries' economic growth. We show that, with Singapore as an exception, ASEAN countries are afflicted with state activism, poor property rights protection, and under-developed corporate governance. We argue that a poor institutional environment may exacerbate the effects of an external shock – such as that of FTAA – and thus we need to explicitly incorporate the role of institutional environments in our analysis. We further argue that while FDI flows to locations with market opportunities, a location's institutional environment affects the composition of FDI. Due to ASEAN countries' institutional weakness, its substantial inward FDI has mainly substituted, rather than complemented, local entrepreneurship. As FTAA may divert FDI flows into ASEAN countries, their appropriate response is to improve institutional quality so that the share of the more productive complementary FDI will increase in the total FDI inflows.
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  • 9
    Publication Date: 2004-12-01
    Description: The conventional view of private campaign contributions is that they distort policy to the detriment of society. Formal models consistent with such views, however, are based on restrictive assumptions about the nature of campaigns, interest groups and policy dimensionality. This paper relaxes those assumptions and allows for informative campaigns, multiple interest groups and multiple issue dimensions. It uses analytical and computational methods to demonstrate that private campaign contributions from societally unrepresentative contributors can, under reasonable conditions, improve social welfare. Multidimensionality is important because politicians need to be responsive on salient issues to prevent opponents from raising money based on less salient issues and using the money to publicize positions on salient issues.
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  • 10
    Publication Date: 2004-04-01
    Description: The current level and future evolution of trans-Pacific business linkages are tightly linked to domestic politics in Latin American countries. Where the structure of a nation's political institutions offer credible checks and balances against discretionary policymaking, external linkages including those with Pacific partners are stronger. Future liberalization including the formation of an FTAA is more likely when new policymakers arrive in office or when existing policymakers feel strong internal or external pressure to shift the course of their trade policy. A given liberalization is more likely to be sustained when coupled with short-term observable improvement in social and economic indicators. Countries with political institutions that fail to limit policymakers' discretion are particularly sensitive to a failure to demonstrate clear and immediate results. An analysis of the potential of an FTAA to influence trans-Pacific business linkages based on these arguments suggests that adoption is far from certain and that northern and southern countries alike will have to design an agreement with particular attention to social and economic consequences in Latin American countries.
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  • 11
    Publication Date: 2004-12-01
    Description: China's industrial policy for high-technology industries combines key features of the policies pursued elsewhere in East Asia such as opening to foreign investors and supporting domestic firms. Leveraging its large market size, China has gone further than other developing countries by promoting standards for products that compete in China with products controlled by major electronics companies. This paper analyzes the experience to date of this Chinese policy in the consumer optical storage industry in the context of China's evolving national innovation system. China's standard-setting policy is politicized but ultimately pragmatic, which avoids imposing excessive costs on the economy. It may also have dynamic learning benefits for Chinese firms who are starting to compete in global markets.
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  • 12
    Publication Date: 2004-04-01
    Description: Over the past decade, multinationals (MNCs) have followed three main objectives while entering Latin America: efficiency seeking, growth seeking, and resource seeking. Efficiency seeking MNCs aim to reduce costs in their global production process through access to cheaper labor, and proximity to destination markets such as the United States. Growth seeking firms enter Latin American markets to grow and/or acquire new markets. They are by nature more dependent on the macroeconomic conditions in local markets for their success. Resource seeking firms enter Latin America in the search of minerals, metals, and hydrocarbons. This paper introduces the concept of “natural markets” to explain the relative successes of MNCs from different regions – Europe (mainly Iberian), USA, and Asia. ‘Natural markets’ for a MNC are defined as those markets sharing a common history or language or having a high level of physical proximity with the country of origin of the MNC. This paper proposes that a firm focusing on natural markets has a comparative advantage, and thus increases the probability of its success. The paper also draws upon the experiences of successful MNCs in Latin America to infer some lessons for East Asian MNCs wishing to operate in the region.
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  • 13
    Publication Date: 2004-01-01
    Description: In the framework of the Worldwide Marine Radioactivity Studies (WOMARS) project, water profile samples for radiocarbon measurements were taken during the IAEA'97 cruise at 10 stations in the southwestern North Pacific Ocean. While 14C concentrations were rapidly decreasing from the surface (Δ14C about 100‰) down to about 800 m at all visited stations (Δ14C about −200‰), the concentrations below 1000 m were almost constant. Some stations were in proximity to the GEOSECS stations sampled in 1973; thus, 14C profiles could be compared after a 24-yr interval. Generally, 14C concentrations had decreased in surface waters (by 50–80‰) and increased (by about the same amount) in intermediate waters when compared with GEOSECS data. In deep waters (below 1000 m), the observed 14C concentrations were similar to GEOSECS values. The bomb-produced 14C inventory had increased by more than 20% over the 24 yr from 1973 to 1997 and was estimated to be about (32 ± 5) 1012 atom m-2, with an annual 14C flux of (1.3 ± 0.3) 1012 atom m-2 yr-1. The results suggest that bomb-produced 14C has been advected northwards by the Kuroshio Current and the Kuroshio Extension and stored in the intermediate layer as North Pacific Intermediate Water.
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  • 14
    Publication Date: 2004-01-01
    Description: While it is customary to use solid samples for measuring the 14C/12C ratio, it is sometimes necessary to handle liquid or gas samples. Motivated by a scientific purpose to count radiocarbon yields in deuterated acetone irradiated with energetic neutrons, we developed a new combustion system to treat liquid or gas samples. In contrast with the typical combustion system using CuO for solid samples, the new combustion system uses high-purity O2 (99.999%) gas. As an initial investigation, we combusted deuterated acetone (acetone-d6, certified 100.0 atm % D) to make CO2 under the ambient O2 pressure. The resulting CO2 gas then went through the reduction process to form graphite for further accelerator mass spectrometry (AMS) measurement.
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  • 15
    Publication Date: 2004-01-01
    Description: A vacuum sample processing line was set up and methods were developed for the determination of radiocarbon in small-volume seawater and biota samples. Seawater samples (500 mL per borosilicate glass bottle and poisoned with HgCl2) were acidified with 5 mL concentrated hydrochloric acid. Pure N2 was used as a carrier gas to strip CO2 from the samples for 10 min in a circulation mode. After purification through several water traps, the CO2 was isolated cryogenically. Using Na2CO3 standard solutions, recovery yields were calculated superior to 95 ± 5%. Freeze-dried marine biota samples were thoroughly mixed with Cu(II)O and combusted at 900°. The CO2 was purified by passing through Ag wool and Cu granules at 450° before reduction to graphite. Finally, graphite was synthesized using Zn dust heated to 450° in the presence of an Fe catalyst at 550°. Although this method takes about 8 hr (synthesis done overnight), the advantage is that no water vapor by-product is formed to hinder the reaction. The graphite yields, measured both by gravimetric methods and by pressure readings, were 95 ± 5%. Accelerator mass spectrometry (AMS) measurements were carried out at the NSF-Arizona AMS Facility. Results for water samples from the northwest Pacific Ocean are reported which are in agreement with data reported elsewhere.
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  • 16
    Publication Date: 2004-01-01
    Description: Confidence in the precisions of accelerator mass spectrometry (AMS) and decay measurements must be comparable for the application of the radiocarbon calibration to age determinations using both technologies. We confirmed the random nature of the temporal distribution of 14C ions in an AMS spectrometer for a number of sample counting rates and properties of the sputtering process. The temporal distribution of ion counts was also measured to confirm the applicability of traditional counting statistics.
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  • 17
    Publication Date: 2004-01-01
    Description: We have measured the radiocarbon concentrations in single-yr tree rings of old wood by accelerated mass spectrometry (AMS) using a multicathode. The 14C concentrations of 10 single-yr tree rings were measured in 100 tree rings at intervals of 10. For each single-yr tree-ring sample, typically 80 measurements of the 14C concentrations were carried out using multicathodes. The sample standard deviations indicated that there are other fluctuations of typically 1.5%, in addition to the fluctuation of the Poisson counting statistics which is typically 3% for each measurement. The average 14C date of the tree rings was 22,130 ± 306 BP for all 624 data of single-yr tree-ring samples measured by the multicathodes. From the calibration data of Lake Suigetsu, the calendar dates of these 100 tree rings were located between 25,400 cal BP and 26,150 cal BP. The 14C dates changed between 21,979 BP and 22,272 BP, with an error of approximately 50 BP, corresponding to a precision of approximately 0.5%. There was a step with a change of approximately 144 BP for each 10 yr in the time profile.
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  • 18
    Publication Date: 2004-01-01
    Description: New results of radiocarbon concentration in tree rings from the Kraków region covering a growth period of 20 yr have been analyzed, and the relationship between them and 14C concentrations in the atmospheric CO2 are described. This enabled assessment of the uptake period for pine trees at the regional climatic conditions. Both sets of data show lower 14C concentrations than reported for “clean air” at the reference station, indicating a remarkable input of “dead” CO2 of fossil fuel origin. Using data of carbon dioxide and 14C concentrations from Schauinsland, summer values of the fossil component (Cf) in carbon dioxide were calculated for the Kraków area. Fitting exponential and linear functions to experimental data, the exchange time was calculated, and expected future 14C concentration in the atmosphere was estimated.
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  • 19
    Publication Date: 2004-01-01
    Description: Some of the most valuable paleoclimate archives yet recovered are the multi-proxy records from the Greenland GISP2 and GRIP ice cores. The crucial importance of these data arises in part from the strong correlations that exist between the Greenland δ18O records and isotopic or other proxies in numerous other Northern Hemisphere paleoclimate sequences. These correlations could, in principle, allow layer-counted ice-core chronologies to be transferred to radiocarbon-dated paleoclimate archives, thus providing a 14C calibration for the Last Glacial Maximum and Isotope Stage 3, back to the instrumental limits of the 14C technique. However, this possibility is confounded by the existence of numerous different chronologies, as opposed to a single (or even a “best”) ice-core time scale. This paper reviews how the various chronologies were developed, summarizes the differences between them, and examines ways in which further research may allow a 14C calibration to be established.
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  • 20
    Publication Date: 2004-01-01
    Description: One problem in preparing iron for radiocarbon dating is the low carbon content which makes the sample size needed too large for some sample combustion systems. Also, the metallic character of the samples complicates sample combustion or oxidation. The Erlangen accelerator mass spectrometry group uses an elemental analyzer for the sample combustion, directly followed by a reduction facility. As the carbon content and sample size for iron samples are unsuitable for combustion in an elemental analyzer, 2 alternative approaches are to (a) avoid oxidation and reduction, or (b) extract the carbon from the iron, prior to combustion. Therefore, 2 different pathways were explored. One is direct sputtering of the unprocessed iron sample in the ion source. The other is the complete chemical extraction of carbon from the iron sample and dating of the carbonaceous residue. Also, different methods for cleaning samples and removing contamination were tested. In Erlangen, a Soxhlet extraction is employed for this purpose. Also, the sampling of the iron sample by drilling or cutting can be a source of contamination. Thus, the measurement of iron drill shavings yielded ages that were far too high. The first results for iron samples of known age from 2 archaeological sites in Germany are presented and discussed.
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  • 21
    Publication Date: 2004-01-01
    Description: Radiocarbon (Δ14C) measurements of monthly samples from a Galapagos surface coral are among the first data sets from the new Keck Carbon Cycle Accelerator Mass Spectrometry laboratory at the University of California, Irvine. An average Δ14C value of −62 is obtained for 144 measurements of samples from monthly coral bands that lived from about AD 1760–1771 (±6 yr). High Δ14C values were found during January through March, when upwelling was weak or absent at the Galapagos Islands. Low Δ14C values were obtained mid-year during strong upwelling. The average seasonal variability of Δ14C was 15–25, which is greater than that at other tropical and subtropical locations in the Pacific Ocean because of intense seasonal upwelling at this site. Periods of sustained high Δ14C values were found during 1762–1763 and 1766. A spectral analysis revealed that the spectral density for the Δ14C data displays most of its variance at the 5-yr cycle, which is reflective of El Niño periodicity during the 20th century.
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  • 22
    Publication Date: 2004-01-01
    Description: Lake sediments have the potential to preserve proxy records of past climate change. Organic material suitable for radiocarbon dating often provides age control of such proxy records. Six shallow freshwater lakes on the sub-Antarctic island of South Georgia were investigated for carbon reservoir effects that may influence age-depth profiles from lake sediment records in this important region. Paired samples of particulate organic matter (POM) from the water column and surface sediment (bulk organic carbon) were analyzed by accelerator mass spectrometry 14C. POM in 4 lakes was found to be in equilibrium with the atmosphere (~107% modern), whereas 2 lakes showed significant depletion of 14C. In each lake, the surface sediment ages were older than the paired POM age. Surface sediment ages showed a much greater range of ages compared to the equivalent POM ages, even for lakes located in close proximity. We conclude that sediment disturbance during coring, bioturbation, and periodic resuspension of sediments are likely factors causing the difference in the apparent age of surface sediments.
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  • 23
    Publication Date: 2004-01-01
    Description: Paired radiocarbon and 230Th/U dating was performed on 13 surface corals from submerged reefs in the Marquesas and from raised terraces in Vanuatu. The absolute ages of the corals analyzed ranged from 3000 to 15,000 cal yr. Estimates of the difference between the absolute and 14C ages of these corals are in agreement with previous determinations up until 11,500 cal yr. The resulting mean sea surface reservoir age R is determined at 390 ± 60 yr for the Marquesas region (9°S), which is slightly higher than the R value at 280 ± 50 yr for the Tahiti Islands (18°S). Multiple 14C analyses of 2 corals from the Marquesas present scattered 14C ages at ~12,000 and ~15,100 cal yr. This could be attributed to rapid changes of the 14C content of surface waters around the Marquesas Islands or to a subtle submarine diagenesis.
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  • 24
    Publication Date: 2004-01-01
    Description: Radiocarbon is produced within minerals at the earth's surface (in situ production) by a number of spallation reactions. Its relatively short half-life of 5730 yr provides us with a unique cosmogenic nuclide tool for the measurement of rapid erosion rates (〉10−3 cm yr−1) and events occurring over the past 25 kyr. At SUERC, we have designed and built a vacuum system to extract 14C from quartz which is based on a system developed at the University of Arizona. This system uses resistance heating of samples to a temperature of approximately 1100° in the presence of lithium metaborate (LiBO2) to dissolve the quartz and liberate any carbon present. During extraction, the carbon is oxidized to CO2 in an O2 atmosphere so that it may be collected cryogenically. The CO2 is subsequently purified and converted to graphite for accelerator mass spectrometry (AMS) measurement. One of the biggest problems in measuring in situ 14C is establishing a low and reproducible system blank and efficient extraction of the in situ 14C component. Here, we present initial data for 14C-free CO2, derived from geological carbonate and added to the vacuum system to determine the system blank. Shielded quartz samples (which should be 14C free) and a surface quartz sample routinely analyzed at the University of Arizona were also analyzed at SUERC, and the data compared with values derived from the University of Arizona system.
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  • 25
    Publication Date: 2004-01-01
    Description: The injection of 10BeF- instead of 10BeO- into a compact accelerator mass spectrometry system with a terminal voltage of 0.58 MV was investigated, because BF- molecules are unstable and isobaric interference of 10B with 10Be can thus be significantly reduced. We describe the method we developed to prepare BeF2 samples. 10Be was measured in a segmented gas ionization detector. Separation of 10Be from 10B could be achieved both for ions in the 1+ charge state with an energy of 0.8 MeV and in the 2+ charge state with an energy of 1.4 MeV. The 2+ ions are better separated, whereas the 1+ charge state has a higher transmission. 10Be/9Be ratios (~10-12) in a suite of rock samples were successfully determined for exposure dating in either charge state and compared with measurements made on the 6MV tandem.
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  • 26
    Publication Date: 2004-01-01
    Description: Cosmic background and its variation have been removed in the Gran Sasso National Laboratory (National Institute of Nuclear Physics) by its 1400-m rock overburden. Stable, high-performance liquid scintillation counting conditions are obtained when any remaining variable components of the environmental background, such as radon, are eliminated. The ultra low-level liquid scintillation spectrometer Quantulus™ has an anti-Compton guard detector (guard for short) that allows monitoring of gamma radiation in the background. The guard detector efficiency in radiocarbon background reduction is 8% in the Gran Sasso National Laboratory, while 80% is observed in surface laboratories. Thus, atmospheric pressure variations in surface laboratories cause variation in cosmic radiation flux. The Quantulus anti-Compton detector is highly efficient in detecting cosmic radiation, and the sample count rate remains stable in long-term counting. Also, correlation of sample backgrounds with environmental gamma radiation in various laboratories is examined.
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  • 27
    Publication Date: 2004-01-01
    Description: The Holocene Dead Sea and the late Pleistocene Lake Lisan were characterized by varying radiocarbon reservoir ages ranging between 6 and 2 ka in the Dead Sea and between 2 ka and zero in Lake Lisan. These changes reflect the hydrological conditions in the drainage system as well as residence time of 14C in the mixed surface layer of the lake and its lower brine. Long-term isolation of the lower brine led to 14C decay and an increase in the reservoir age. Yet, enhanced runoff input with atmospheric 14C brings the reservoir age down. The highest reservoir age of 6 ka was recorded after the sharp fall of the Dead Sea at ~8.1 ka cal BP. The lower reservoir age of zero was recorded between 36 and 32 ka cal BP, when the Lake Lisan mixed layer was frequently replenished by runoff.
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  • 28
    Publication Date: 2004-01-01
    Description: In this study, we aim to characterize the main processes controlling 14CDIC concentrations in porewater at the shallow shelf (water depth less than 120 m) off the Mediterranean coast of Israel. At these water depths, we expected to find evidence for seawater penetration toward the coast, since this area was flooded by seawater only some 18,000 yr ago (the end of the Last Glacial period).Measurements of the chemical composition (14CDIC) and stable carbon isotopic composition (δ13CDIC) were performed in several sediment cores (40–250 cm long) at water depths between 6 and 115 m. At water depths of 60 m, represented by a 2.5-m-long sediment core, the porewater 14CDIC levels (85–87 pMC) were lower than the corresponding sediment values in each layer (92–95 pMC), mainly due to the oxidation of relatively old organic matter (about 70 pMC) with no evidence to advection. In contrast, sediment cores from water depths shallower than 50 m showed only slight anaerobic oxidation and high 14CDIC values of approximately 100 pMC, indicating possible downward advection. These geochemical observations support the perception that the penetration of seawater into the coastal aquifer occurs at the shallow water zone (
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  • 29
    Publication Date: 2004-01-01
    Description: A simulation study for the separation of rare isotopes such as beryllium and aluminum was performed for a new beam line to be attached to the 3MV Tandetron accelerator at the accelerator mass spectrometry (AMS) facility of Seoul National University in Korea. The new beam line will also be used for other scientific applications, namely, ion implantations, Rutherford backscattering, and nuclear astrophysics experiments. It mainly consists of 30° and 100° deflection dipole magnets and drift spaces. A transfer matrix for the beam line was determined by the TRANSPORT code. Simulation of the rare isotope separation was performed by a ray tracing method using the TURTLE code. The simulation results, including the effect of the energy degrader, provide feasibility for the separation of isobars with small mass differences in 10Be-10B and 26Al-26Mg.
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  • 30
    Publication Date: 2004-01-01
    Description: A total of 294 beachrock samples were collected from 116 sites on 15 islands in the Nansei Islands chain, southwestern Japan, and were radiocarbon dated. The beachrocks began to form at about 6900 BP and some are still under development in the islands. Values of isotope fractionations of different materials making up the beachrocks ranged between +9.4‰ and −5.7‰. Isotope fractionations outside the range of 0 ± 2‰ suggest that these beachrocks were strongly influenced by underground water and running freshwater when they were cemented. The sea level during the late Holocene has remained the same for at least the past 5000 yr, except for several uplifted coasts.
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  • 31
    Publication Date: 2004-01-01
    Description: The requests to measure many samples, and samples with very low carbon masses, make it necessary to develop new techniques in sample handling to accelerate sample preparation and to eliminate carbon contamination. Our 40 MC-SNICS was recently modified to a hybrid ion source. To run the hybrid ion source with a gas parameter, settings were studied and a gas handling system for the direct coupling of an elemental analyzer and a gas ion source was developed.
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  • 32
    facet.materialart.
    Unknown
    Cambridge University Press
    Publication Date: 2004-01-01
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  • 33
    Publication Date: 2004-01-01
    Description: Known-age corals from the Cocos (Keeling) Islands, Indian Ocean, have been analyzed by accelerator mass spectrometry (AMS) for radiocarbon to determine marine reservoir age corrections. The ΔR value for the Cocos (Keeling) Islands is 66 ± 12 yr based on the analyses undertaken for this study. When our AMS and previously published dates for Cocos are averaged, they yield a ΔR of 64 ± 15 yr. This is a significant revision of an earlier estimate of the ΔR value for the Cocos (Keeling) Islands of 186 ± 66 yr (Toggweiler et al. 1991). The (revised) lower ΔR for the Cocos (Keeling) Islands is consistent with GEOSECS 14C data for the Indian Ocean, and previously published bomb 14C data for the Red Sea, Gulf of Aden, and Cocos Islands. The revised ΔR is also close to values for the eastern Indian Ocean and adjacent seas. These suggest surface waters that reach the Cocos Islands might be partly derived from the far western Pacific, via the Indonesian throughflow, and might not be influenced by the southeast flow from the Arabian Sea.
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  • 34
    Publication Date: 2004-01-01
    Description: International radiocarbon intercalibration studies have revealed that radiometric laboratories using liquid scintillation (LS) spectrometry of benzene reported, on average, younger ages for near-background standards than either gas proportional counter (GPC) or accelerator mass spectrometry (AMS) laboratories. These studies suggested that the younger LS ages are probably related to the use of spectrophotometric benzene as a background standard. An analysis of successive 110-ka subfossil wood (Airedale Reef Ancient Wood: ARAW) standards shows that vacuum line memory effects occur in LS spectrometry and, consequently, must be corrected to obtain accurate 14C dates. ARAW standards, measured at monthly intervals in the Waikato laboratory, are used to provide blank corrections for both research and routine dating applications. The strong correlation between the ARAW δ14C data and the sample activities that preceded the standards may provide an opportunity to obtain sample-specific blank corrections. Lithium carbide synthesis is likely to prove a source of contamination. This work suggests that reproducible background levels for routine dating of less than 0.1 pMC (55 ka 14C yr) are achievable.
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  • 35
    Publication Date: 2004-01-01
    Description: The Keck Carbon Cycle accelerator mass spectrometry facility at the University of California, Irvine, operates a National Electronics Corporation 40-sample MC-SNICS ion source. We describe modifications that have increased beam current output, improved reliability, and made the source easier to service.
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  • 36
    Publication Date: 2004-01-01
    Description: Following the passing of Prof Cheikh Anta Diop in 1986, the radiocarbon laboratory (LC14) he created 20 yr earlier at the Institut Francophone d'Afrique Noire (IFAN), Dakar, Senegal, fell into a long hibernation. It took nearly 3 yr to renovate the laboratory and reinstall new equipment in order to return LC14 to full functionality and resume its activity. A new dating system has been implemented around a super low-level liquid scintillation spectrometer from Packard, the Tri-Carb 3170TR/LS, located in an underground room.In this paper, we assess the performance of the dating setup (background level and figure of merit) using known samples from Paris 6 and international standards from the International Atomic Energy Agency (IAEA). After the calibration, the setup was used to study bolé seashells from the Khant area in the northern part of Senegal (West Africa). The aim is to present evidence of the correlation between the transgression of the Nouakchottan (5500 BP) and a few industries in the Khant area. The corresponding ages are difficult to assess and the dates available for this cultural site are randomly distributed, ranging from 4500 to 1500 BP, i.e., a chronological period spanning from the Neolithic to the Iron Age.
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  • 37
    Publication Date: 2004-01-01
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  • 38
    Publication Date: 2004-01-01
    Description: Sequential injection or bouncing has a number of properties which can lead to a reduction of the analysis accuracy if no appropriate measures are taken. A special injection system has been developed in order to eliminate these shortcomings. The influence of source glitches or instabilities on the measured isotopic ratio is substantially reduced by a high cycling frequency. A fast beam-blanking unit guarantees the needed accuracy of the injection periods. Background currents are avoided by synchronizing the current measurement for the stable isotopes with their injection periods. To achieve the required speed and precision of the gated measurement, new instrumentation was developed. The elimination of background contributions allows an efficiency for radiocarbon counting as high as 95% at a cycling frequency of 100 Hz.
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  • 39
    Publication Date: 2004-01-01
    Description: The National Electrostatics Corporation has built and tested a prototype low energy, open-air, single stage carbon accelerator mass spectrometry (AMS) system (patent pending). The configuration tested has a standard 40-sample, multi-cathode SNICS source on a 300-kV deck. The beam is mass analyzed before acceleration to a gas stripper located at ground. The 14C+ ions are separated from 13C+ and 12C+ arising from the molecular breakup by a 90° analyzing magnet immediately after the gas stripper which acts as a molecular dissociator. The 14C+ beam passes through an electrostatic spherical analyzer before entering the particle detector. The observed 14C/12C precision is better than 5% with a sensitivity of better than 0.05 dpm/gmC. A first single stage AMS system has been ordered. The configuration of this system will be discussed.
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  • 40
    Publication Date: 2004-01-01
    Description: Five radiocarbon analyses were performed on 5 different sources within Soreq Cave, which was used as a model for the Judea Group Aquifer of Israel (pMCq0). The transit time of rainwater through the roof of the cave to sources within it had been determined with tritium. From this information, the year of deposition of rain on the roof of the cave, which later appeared in one of the sources, was estimated and the atmospheric 14C concentration at that time was ascertained (pMCa0). The parameter Q = pMCq0 / pMCa0 was found to be Q = 0.60 ± 0.04. This makes it possible to calculate the age of water in any well in the Judea Group Aquifer of Israel by measuring its 14C concentration (pMCqt) by use of the decay equation and applying Q.
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  • 41
    Publication Date: 2004-01-01
    Description: The new accelerator mass spectrometry (AMS) Radiocarbon Analysis Laboratory in Jena is described. The laboratory developed a combustion system for solid samples and a CO2 extraction system for air samples. Thus far, sample preparation, including graphitization, was performed in the laboratory, and the samples were measured subsequently by other AMS facilities. Currently, the laboratory owns a 3MV AMS system from HVEE (Netherlands) that has passed the acceptance tests and will be used for routine 14C determinations in the near future. The AMS system is equipped with 2 ion sources, one suitable for graphite targets and the second for both graphite and CO2 targets.
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  • 42
    Publication Date: 2004-01-01
    Description: Two independent 14C data sets of 10 tree-ring samples from the longest master chronology of the Pazyryk cultural complex were obtained and wiggle-matched to the absolute timescale. The results show very good agreement, within 10–15 calendar yr. The Ulandryk-4 burial ground (mound 1) was dated to about 320–310 cal BC, and this is consistent with wiggle-matching of the Pazyryk burial ground date series.
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  • 43
    Publication Date: 2004-01-01
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  • 44
    Publication Date: 2004-01-01
    Description: Radiocarbon is produced in all types of nuclear reactors. Most of the 14C released into the environment is in the form of gaseous emissions. Recent data on the 14C concentration found in terrestrial samples taken in the vicinity of nuclear power plants in Romania and Lithuania are presented. We found increased 14C levels in the surroundings of both power plants. At the Romanian power plant Cernavoda, we found excess levels of 14C in grass within a distance of about 1000 m, the highest 14C specific activity being 311 Bq/kg C (approximately 28% above the contemporary 14C background) found at a distance of 200 m from the point of release (nearest sampling location). At the Lithuanian power plant Ignalina, samples of willow, pine, and spruce showed a 14C excess of similar magnitude, while significantly higher values were found in moss samples. The samples were analyzed at the accelerator mass spectrometry facility in Lund, Sweden.
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  • 45
    Publication Date: 2004-01-01
    Description: The first radiocarbon dates from the unique early Scythian monument Arzhan-2, discovered in 2001, are presented. The monument contained a royal burial (grave nr 5). Unfortunately, precise dating is hampered by the Hallstatt plateau in the calibration curve. However, using both accelerator mass spectrometry measurements from buried materials and conventional dates for floating tree rings from the burial chamber, we were able to date the construction of the monument to the 7th century BC. This is consistent with archaeological expectations. Other graves located inside the barrow were also dated. Grave nr 11, located on the edge of the barrow, is younger, showing that the monument was a place of burial ritual for many years for this ancient population.
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  • 46
    Publication Date: 2004-01-01
    Description: We have AMS dated samples of Pacific rat (Rattus exulans) bone “collagen” and filtered gelatin samples from the prehistoric site of Shag River Mouth, New Zealand. The age of occupation of this site has previously been determined based on 50 radiocarbon measurements. The site dates to the late Archaic phase of southern New Zealand prehistory (about 650–500 BP; 14th–15th century AD). The results of rat bones which we have dated produce a range in ages, from about 980–480 BP, a difference we attribute to a combination of effects. Pretreatment appears to be an important variable, with results showing differences in 14C age between the progressive “collagen” and filtered gelatin chemical treatment stages. Amino acid profiles suggest there is a proteinaceous but non-collagenous contaminant which is removed by the more rigorous pretreatment. Stable isotopes vary between pretreatments, supporting the removal of a contaminant, or contaminants. Variation in δ15N values imply a range in uptake of dietary protein, and might suggest a potential influence from the local aquatic environment or the consumption of marine-derived protein. Rats are opportunistic, omnivorous mammals, and, therefore, obtain carbon from a variety of reservoirs and so we ought to expect that in environments where there is a variety of reservoirs, these will be exploited. Taken together, the results show that rat bone AMS 14C determinations vary in comparison with the established age of the site, but are in notably better agreement with non-collagenous data than in previously published determinations (Anderson 1996).
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  • 47
    Publication Date: 2004-01-01
    Description: A representative selection of Roman and Coptic textiles is used to compare the radiocarbon dating results with the chronology proposed by art historians. In some cases, the comparison was made on individual objects, but in other cases, groups of stylistically and/or technologically related textiles were compared. In the case of the latter, the interquartile range was calculated. The results of this comparison show that some individual samples and groups are dated older than expected, while for another group the opposite is the case. One group was matching well with the presumed period as a whole, but not on the basis of the individual pieces. The analyses showed the necessity of 14C dating to obtain a more accurate dating of Coptic textiles.
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  • 48
    Publication Date: 2004-01-01
    Description: New radiocarbon dates obtained from Late Pleistocene and Holocene deposits of the southern, eastern, and northern shores of Lake Baikal in 1995–2001 are presented, and the most important results of paleoenvironmental studies based on C data are discussed. The following paleogeographic events were verified with the help of C dating: 1) first Late Pleistocene glaciation (Early Zyryan); 2) Middle Zyryan interstadial; 3) loess formation during the Late Zyryan (Sartan) deglaciation; 4) warm and cold events in the Late Glacial; and 5) vegetation changes and forest successions during the Late Glacial and Holocene.
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  • 49
    Publication Date: 2004-01-01
    Description: Eleven woolly mammoth bone samples from Lugovskoe (central West Siberian Plain, Russia) were radiocarbon dated in 3 laboratories: Institute of Geology, Novosibirsk; Oxford University, Oxford; and Christian Albrechts University, Kiel. Each laboratory used its own protocol for collagen extraction. Parallel dating was carried out on 3 samples in Novosibirsk and Oxford. Two results are in good agreement. However, there is a major discrepancy between 2 dates obtained for the third sample. The dates obtained so far on the Lugovskoe mammoths range from about 18,250 BP to about 10,210 BP. The Lugovskoe results thus far confirm the possibility of woolly mammoth survival south of Arctic Siberia in the Late Glacial after about 12,000 BP, which has important implications for interpreting the process of mammoth extinction. The site has also produced the first reliable traces of human occupation from central Western Siberia at the Late Glacial, including unique direct evidence of mammoth hunting.
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  • 50
    Publication Date: 2004-01-01
    Description: A high-resolution atmospheric radiocarbon record has been obtained for the interval of 17–36 kyr from U/Th-dated aragonite sediment of Lake Lisan. Reservoir age corrections were applied with reservoir ages of 200, 1250, and 2000 yr, which correlate with the different water levels of the lake. The present 14C record for Lake Lisan shows near resemblance with that of Lake Suigetsu: both converge to the value of Δ14C ∼0‰ at 32 kyr cal BP. Both also show significant differences compared to other reported high-resolution 14C records (e.g. Iceland Sea, Cariaco basin, and Bahamas speleothem). This inconsistency should be addressed by re-assessment of the basic assumptions behind the determination of calendar ages of the various records.
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  • 51
    Publication Date: 2004-01-01
    Description: We review the reasons for change in paleoecological conditions and their effects on different cultures at the beginning and during the Holocene period in western Hungary using radiocarbon data combined with paleoecological and paleolimnological results. Two sites were investigated in the southern and northern part of the ancient bay of Balaton Lake: Keszthely-Úsztatómajor and Főnyed I. 14C dating of 2 core samples represented a chronology from 11,000 cal BC to 2000 cal BC (10,700 BP to 3700 BP) and from 6200 cal BC to 1200 cal BC (7300 BP to 3000 BP), respectively. A relatively constant inverse sediment accumulation rate was observed in both cases (23 yr/cm and 33 yr/cm, respectively). In the case of Főnyed I, a sharp break was observed in the sedimentation curve around 6000–4800 cal BC (6000 BP). Changes in the vegetation due to human activity were observed in a larger extent only at the end of Late Neolithic, with the most significant changes detected in the landscape coinciding with the presence of Lengyel III culture in the region. The appearance of higher amounts of pollen of cereals at the sites proved the presence of crop cultivation. However, the role of plant cultivation may have been limited for the ancient inhabitants of the Kis-Balaton region due to a limited amount of soil suitable for agriculture and due to the extensive water table. Further changes in vegetation were observed during the Late Copper Age (Baden culture) and the period of Early and Middle Bronze Age, respectively. Signs of forest clearing during the period have not been detected and the increased peak of Fagus indicates climatic change. The low intensity of anthropogenic activity should not be attributed to geographic isolation.
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  • 52
    Publication Date: 2004-01-01
    Description: Radiocarbon measurements of different lipid fractions and individual compounds, isolated from soil samples collected on 2 different agricultural long-term study sites, located in the rural area of Rotthalmünster (Germany) and in the city of Halle/Saale (Germany), were analyzed to obtain information about sources and the stability of soil organic matter (SOM). Different lipid compound classes were isolated by automated solvent extraction and subsequent medium-pressure liquid chromatography. Generally, 14C contents of lipid compound classes from topsoil samples of maize plots at Rotthalmünster are close to the modern atmospheric 14C content. Lower 14C values of aliphatic and aromatic hydrocarbons isolated from neutral lipids suggest a contribution of old carbon to these fractions. In contrast, 14C values of bulk soil (52 pMC) as well as isolated lipid classes from Halle are highly depleted. This can be attributed to a significant contribution of fossil carbon at this site. Extremely low 14C contents of aromatic (7 pMC) and aliphatic hydrocarbons (19 pMC) reflect the admixture of fossil hydrocarbons at the Halle site. Individual phospholipid fatty acids (PLFA), which are used as a proxy for viable microbial biomass, were isolated by preparative capillary gas chromatography (PCGC) from topsoils at Rotthalmünster and Halle. PLFA 14C values are close to atmospheric 14C values and, thus, indicate a clear microbial preference for relatively young SOM. At Rotthalmünster, the 14C concentration of short-chain unsaturated PLFAs is not significantly different from that of the atmosphere, while the saturated PLFAs show a contribution of sub-recent SOM extending over the last decades. At Halle, up to 14% fossil carbon is incorporated in PLFAs n-C17:0 and cy-C18:0, which suggests the use of fossil carbon by soil microorganisms. Moreover, it can be concluded that the 14C age of soil carbon is not indicative of its stability.
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  • 53
    Publication Date: 2004-01-01
    Description: A technique of accelerator mass spectrometry (AMS) has made it possible to directly measure radiocarbon ages of pottery by isolating organic materials sealed in the pottery when the pottery was formed. We analyzed the carbon contents and 14C ages for “black pottery” from the Philippines and “fiber pottery” from Japan using the relevant carbonaceous materials extracted from the pottery samples, i.e., adhered chaff or grass fibers that were incorporated in the pottery matrix, respectively. The carbon yield of the pottery sample varied largely depending on the pottery types, the preservation conditions, as well as the chemical pretreatment methods to purify carbonaceous materials for 14C dating. We will discuss criteria for sample selection of well-preserved pottery, and a modified method, instead of the standard alkali treatment, to obtain sufficient material for precise 14C dating.
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  • 54
    Publication Date: 2004-01-01
    Description: Sub-fossil sections from a Florida wetland were accelerator mass spectrometry (AMS) dated and the sedimentological conditions were determined. 14C data were calibrated using a combined wiggle-match and 14C bomb-pulse approach. Repeatable results were obtained providing accurate peat chronologies for the last 130 calendar yr. Assessment of the different errors involved led to age models with 3–5 yr precision. This allows direct calibration of paleoenvironmental proxies with meteorological data. The time frame in which 14C dating is commonly applied can possibly be extended to include the 20th century.
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  • 55
    Publication Date: 2004-01-01
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  • 56
    Publication Date: 2004-01-01
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  • 57
    Publication Date: 2004-01-01
    Description: Estimation of the magmatic contribution to soil air at Unzen Volcano, SW Japan, was carried out using carbon isotopes, both 14C and 13C, and a mixing model of isotopic mass balance in order to assess the spatial variation of magmatic influence from the volcano. The advantage of using soil air samples is that a wide range of gas sampling sites can be selected. Magmatic CO2 contributed mostly in the eastern region from Unzen Volcano. The high magmatic contribution to soil air appeared along the Akamatsudani fault zone located southeast of the volcano. Our observations across the fault also showed remarkable peaks of CO2 concentration and δ13C values, suggesting that magmatic fluid comes up along the fracture zone as for the normal fault system of the graben.
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  • 58
    Publication Date: 2004-01-01
    Description: Radiocarbon age determinations and stratigraphy suggest that the deposits in Black Creek Swamp on Kangaroo Island record 3 phases of deposition and associated soil development which spanned at least the last 20,000 yr. Four new 14C age determinations on bulk soil organic matter and their stratigraphic context are presented in this paper. Three of these age determinations (FP6: 15,687 ± 110 BP [WK11487]; FP7: 16,326 ± 385 BP [WK11488]; and FP8: 17,618 ± 447 BP [WK11489]), are from the organic-rich fossil layer located 45–75 cm below the current floodplain surface. The fourth, a much younger date, FP5: 5589 ± 259 BP (WK11486), was obtained from the base of the overlying modern soil. The dates for the fossil layer increase systematically with depth and correlate well with 5 previous 14C dates (Hope et al., unpublished), ranging between 15,040 ± 120 BP and 19,000 ± 310 BP. This suggests that the data set represents a possible minimum age of the bulk organic matter, and considering the high organic matter contents of approximately 8%, has implications for the age of the megafauna buried in this layer. The overlying modern soil, with its much younger date, contains lower levels of organic matter (3–7%) and gastropods not seen in the fossil layer. This suggests a substantial change in environmental conditions probably due to an alteration in the floodplain drainage conditions. This chronological and sedimentalogical discontinuity indicates that 2 distinct depositional regimes existed and were separated by up to 10,000 14C yr. A calcareous, sandy silt deposit underlying the fossil layer is a calcarenite deposit with low total organic content and is considered the base of the section; it suggests a third separate depositional episode. As such, the Black Creek Swamp in the southwest corner of Kangaroo Island formed intermittently over at least the last 20,000 yr during 3 distinct depositional phases, one of which was the formation of the fossil-laden, organic-rich floodplain surface, which has a possible minimum age of approximately 15,000 to 19,000 BP.
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  • 59
    Publication Date: 2004-01-01
    Description: A kohitsugire is a paper fragment from an old manuscript written mainly in the Heian and Kamakura periods. Although they contain significant information for historical, literary, and paleographical study, because of their antique handwriting and description of historical incidents, there are many copies and counterfeits written several centuries later. In this study, radiocarbon ages of kohitsugire were measured by accelerator mass spectrometry (AMS). On the kohitsugire attributed to the famous calligraphists in the Kamakura period (Fujiwara no Sadaie and Prince Munetaka), 14C dating indicated that they were not genuine and should be excluded from the materials for study of the calligraphists. Calibrated 14C ages of the kohitsugire attributed to Fujiwara no Yukinari indicated the middle Heian period. This calligraphy was written on Tobikumogami paper, which has a billowing cloud pattern decorated with indigo-blue-dyed fiber. Although it was commonly accepted that the Tobikumogami is peculiar to the middle 11th to early 12th century, the results from 14C dating also suggested that the origin of the Tobikumogami would date back to the last of the 10th or the early 11th century, when Fujiwara no Yukinari flourished as a calligraphist. Calibrated 14C ages of the kohitsugire attributed to Nijo Tameuji and Reizei Tamesuke showed that they are fragments of old manuscripts describing lost tales and were written in the 13th–14th century. Consequently, 14C dating clarified the existence of ancient tales which had been unknown and indicated their worth as a material for the study of classical Japanese literature.
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  • 60
    Publication Date: 2004-01-01
    Description: The dating of the settlement of Iceland has been debated for many years. According to written sources (sagas) from the early 12th century, the first Norwegian settlers arrived in Iceland in AD 874. However, some 14C dates from the earliest archaeological sites in Iceland, invariably from samples of birch and other indigenous wood species, have yielded surprisingly old ages, older by 100–150 yr than the historical date, suggesting that the settlement took place in the 7th or 8th century. In this paper, we report 16 new 14C dates of pairs of barley grain and wood samples from an excavation in Reykjavík in 2001. The new results show that the wood samples tend to be older than the grain samples by up to about 100 yr. We argue that the barley grains give the true date (AD 890), whereas the wood dates are too old. The grain dates are in close agreement with the settlement year quoted in the written sources. In particular, our new data eliminate the need of any of the ad hoc theories introduced up to now to explain the suspiciously high 14C ages of wood samples from the settlement of Iceland, namely, 1) the island effect, 2) the volcanic or geothermal effect, or 3) that settlement actually took place significantly before the time recorded in the sagas.
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  • 61
    facet.materialart.
    Unknown
    Cambridge University Press
    Publication Date: 2004-01-01
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  • 62
    Publication Date: 2004-01-01
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  • 63
    Publication Date: 2004-01-01
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  • 64
    Publication Date: 2004-01-01
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  • 65
    Publication Date: 2004-01-01
    Description: The influence of the calibration curve on the statistical inference of time intervals was investigated. For this purpose, the calculation of the summed probability density function was used. Computer simulations were done for batches of 11 samples, each time uniformly covering 200-yr time intervals. The results show that the calibration curve causes the summed probability density function of a group to cover a wider interval than the real-time interval of the phenomenon. Moreover, the estimated time interval may be often shifted in relation to the real-time interval.
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  • 66
    Publication Date: 2004-01-01
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  • 67
    Publication Date: 2004-01-01
    Description: The intertidal biota from Parton beach, close to the Sellafield nuclear fuel reprocessing plant, were all found to be enriched in radiocarbon relative to ambient background. The degree of enrichment appears to reflect the positions of the biota in the food chain once the dilution in seaweed from atmospheric uptake is taken into account. Close to the low-water mark, the order was mussels 〉 limpets 〉 anemones winkles 〉 seaweed. The same order was observed close to the high-water mark, except that anemones were absent from this area. The activities in the biogeochemical fractions of the water column reflect the fact that discharges are primarily in the form of dissolved inorganic carbon (DIC), which is subsequently transferred to the particulate organic carbon (POC) and, to a lesser extent, the dissolved organic carbon (DOC), and finally, the particulate inorganic carbon (PIC). Analysis of intertidal sediment suggests that there is likely to be a gradual increase in the specific activity of 14C in the inorganic component of this material as Sellafield contaminated organisms die and their shells are ground down by natural processes.
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  • 68
    Publication Date: 2004-01-01
    Description: The density (BSG) of bone increases, at the osteon scale, during lifetime aging within the bone. In addition, post-mortem diagenetic change due to microbial attack produces denser bioapatite. Thus, fractionation of finely powdered bone on the basis of density should not only enable younger and older populations of osteons to be separated but also make it possible to separate out a less diagenetically altered component. We show that the density fractionation method can be used as a tool to investigate the isotopic history within an individual's lifetime, both in recent and archaeological contexts, and we use the bomb 14C atmospheric pulse for validating the method.
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  • 69
    Publication Date: 2004-01-01
    Description: The evolution of the outer lake of Hwajinpo Lagoon in Korea has been reconstructed using environmental proxies (lithologic, geochemical, and fossil data) with a chronology established using 7 accelerator mass spectrometry (AMS) radiocarbon dates. Grain size, water content, and X-ray analyses from the core of outer coastal lakes (HJ99) were used to reconstruct sedimentary environments by using total organic carbon, C/N, S, and C/S chemical proxies. Assemblages of mollusc remains also provided paleoenvironmental information. The environmental changes of the outer lake of Hwajinpo Lagoon can be divided into 6 depositional phases. The basin of the Hwajinpo was exposed and underwent a weathering process before the Holocene period. The muddy sand layer on the weathered bedrock indicated an estuarine system about 6000 BP. The laminated layer implies that the lagoonal system was anoxic between about 5500–2800 BP. The marl layer implies a relatively oxic lagoonal condition with mollusc presence about 2500 B P. The layer of very low sulfur content indicates a freshwater lake system isolated by a sand barrier about 1700 BP. Beginning about 1000 B P, the river system deposits progress progradation on the marl layer. Two erosional landforms could be related with a high standing sea level span during Holocene. These high-stands are dated at 5700 BP and 2200 BP and are supposed to have formed erosional landforms of about 1.6 amsl and 0.8 amsl, respectively. Environmental changes of the outer lake of Hwajinpo Lagoon are considered due mainly to the lake- and sea-level fluctuation during Holocene.
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  • 70
    Publication Date: 2004-01-01
    Description: Radiocarbon measurements on a partially articulated female human skeleton, recovered from the foreshore of the river Thames in London, raised interesting questions of interpretation when the body did not produce the anticipated Neolithic date. A relatively recent 14C age and a strong marine component to the individual's diet, identified by stable isotope measurements, means that the date of death is difficult to estimate accurately, although the body probably does not constitute a forensic case.
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  • 71
    Publication Date: 2004-01-01
    Description: We reconstructed climate change during the second half of the Holocene for the Minusinsk (southern Siberia) and the Uyuk (Central Asia) valleys in the Eurasian steppe zone. Sediment cores from 2 lakes and a soil profile from the Arzhan-2 burial mount were investigated. We combined pollen and geochemical analyses and radiocarbon dating with the archaeological record. A sharp increase of human population density occurred at the transition from the Bronze Age to Iron Age (about 2700 cal BP). The most representative Scythian culture started in the Uyuk and the Minusinsk valleys after increased humidity and occupation capacity of the steppe zone during the 9th century BC.
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  • 72
    Publication Date: 2004-01-01
    Description: Hawke's Bay is a region of New Zealand where earliest settlement of indigenous people may have occurred. A sedimentological and palynological study of lake sediments from a small catchment was undertaken to reconstruct erosion, vegetation, and fire histories to determine human environmental impact, and thus add to knowledge of the timing of initial settlement of New Zealand. Precise dating was an essential facet of the research because of the short time span of human occupation in New Zealand. A chronology is proposed based on accelerator mass spectrometry (AMS) radiocarbon dating of palynomorph concentrates. Known-age tephras were used as a check on the validity of the 14C ages obtained using this technique, which is being developed at Rafter Radiocarbon Laboratory. Two episodes of sustained erosion occurred between about 1500 and 1050 BC with a period of ~50 yr at about 1300 BC when no erosion occurred. Five episodes of erosion of very short duration occurred at about 625 BC, 450 BC, 100 BC, AD 950, and AD 1400. Erosion probably resulted from landslides induced by earthquakes or severe storms, with the exception of the last event which coincides with local burning and is probably a consequence of this. A conifer/broadleaved forest surrounded the lake until soon after AD 1075–1300, when a dramatic decline in pollen of forest plants and an increase in charcoal occurred. Forest was replaced by fire-induced scrub, interpreted as a result of anthropogenic burning by prehistoric Polynesians. A further decline in woody vegetation occurred when European-introduced plants appear in the pollen record and extensive pasture was established.
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  • 73
    Publication Date: 2004-01-01
    Description: This paper examines if an erosive hiatus found in the peat stratigraphy and marsh-accumulation record from northwest Hammock River Marsh (HRM), Connecticut (CT) can be attributed to a 14th or a 15th century hurricane, each documented by a radiocarbon-dated overwash fan in Succotash Marsh (SM) (Rhode Island) about 90 km to the east. Given that (i) the best estimate age range for the 15th century overwash deposit in SM (1400–1440 cal AD, 2 σ) overlaps entirely with that for first plant growth after erosion at HRM (1390–1450 cal AD, 2 σ), while the best estimate age range for the 14th century overwash deposit (1290–1410 cal AD, 2 σ) overlaps just 10 yr, and (ii) interpretation of the available stratigraphic and sedimentary evidence from HRM suggests that a high-energy event offers the simplest explanation for the observed marsh erosion, we conclude that a plausible link exists between the 15th century hurricane and the marsh erosion in HRM. The best estimate age range for the 14th century hurricane appears to overlap for 91% with the age range for the first plant growth (1290–1400 cal AD, 2 σ) following marsh erosion in East River Marsh (CT), located about 12 km west of HRM. These results imply that erosive boundaries in salt-marsh peat deposits have potential as markers of past hurricane activity.
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  • 74
    Publication Date: 2004-01-01
    Description: High precision for radiocarbon cannot be reached without profound insight into the various sources of uncertainty which only can be obtained from systematic investigations. In this paper, we present a whole series of investigations where in some cases 16O:17O:18O served as a substitute for 12C:13C:14C. This circumvents the disadvantages of event counting, providing more precise results in a much shorter time. As expected, not a single effect but a combination of many effects of similar importance were found to be limiting the precision.We will discuss the influence of machine tuning and stability, isotope fractionation, beam current, space charge effects, sputter target geometry, and cratering. Refined measurement and data evaluation procedures allow one to overcome several of these limitations. Systematic measurements on FIRI-D wood show that a measurement precision of ±20 14C yr (1 σ) can be achieved for single-sputter targets.
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  • 75
    Publication Date: 2004-08-01
    Description: Trade-related investment measures (TRIMs) have been a key issue in regional and multilateral trade negotiations, but they have received little attention in theoretical work to date. This article analyzes the political economy of TRIMs to illuminate why regional arrangements have been a popular framework for eliminating them. The main argument is that multinational firms often demand safeguards when TRIMs are being liberalized, particularly if they have large sunk costs due to asset specificity. In general, regional arrangements are better equipped than multilateral rules to incorporate the safeguards these firms demand: regionalism requires governments to make binding commitments, and it creates opportunities to discriminate against outsiders. A case study of lobbying by U.S. companies with FDI in Canada from the early twentieth century to the negotiation of the Canada-United States Free Trade Agreement illustrates these points. The article concludes that regional arrangements are likely to remain more active, and more successful, than multilateral discussions in managing the commitment problems inherent in liberalizing TRIMs.
    Print ISSN: 1369-5258
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  • 76
    Publication Date: 2004-08-01
    Description: Restrictive policies aimed at reducing the likelihood of bank failure during recessions tend to increase the probability of a credit crunch. In this paper we infer governments' policy responses to this dilemma by studying the cyclical behavior of bank capital in 1369 banks from 28 OECD countries during the period 1992–98. We find significant differences across countries. In the US and Japan, bank capital is counter-cyclical, that is, the typical bank strengthens its capital base during periods of weak economic activity. In the other countries, there is no relationship between the level of macroeconomic activity and bank capital. From these findings we infer that severe banking crises in the US and Japan may have made policymakers there more vigilant towards “unhealthy” banks, even when this implies an increase in the risk of a credit crunch. In countries without such crisis experience, policymakers seem to be less concerned about future banking crises. Our results suggest that the strong push by the US for the 1988 Basle Accord may have been a reflection of this increased sensitivity. They also suggest that, to the extent business cycles do not develop in synchronicity across countries and policymakers respond differently to the banking crisis-credit crunch dilemma, current reforms of the Basle Accord, which are designed to tighten regulatory requirements, may encounter difficulties.
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  • 77
    Publication Date: 2004-04-01
    Description: The paper focuses on how the Free Trade Area of the Americas (FTAA), which will include both high-income developed and developing countries, will affect the options and investment strategies of multinational firms outside the region. Preliminary sections discuss the strategies open to both insider firms (headquartered with the Americas) and outsider firms, and the characteristics of technologies and countries that determine equilibrium location choices. Then I turn more explicitly to the question at hand, and suggest that a free-trade area of the Americas can be conceptually decomposed into (a) integration among the southern developing countries and (b) integration between the south and NAFTA. The first will give third-country multinationals horizontal investment opportunities to serve the effectively larger southern market with local production to serve the local southern market. The second gives third-country multinationals the opportunity to exploit low labor costs in the south to produce for export to North America (export-platform FDI). While this all sounds attractive for third-country firms, the theory emphasizes that the same advantages of integration are conferred upon U.S. and Canadian firms who have the additional advantage of supplying services and intermediate goods to southern affiliates at lower cost than the third country firms. This competitive effect from insider firms leads the theory to suggest weaker benefits to third-country firms than a simpler approach might predict.
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  • 78
    Publication Date: 2004-04-01
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  • 79
    Publication Date: 2004-04-01
    Description: This paper discusses how MNCs reacted to NAFTA and MERCOSUR in terms of their investment and operations patterns in three sectors - automotive, electronics, and apparel - and assesses the likely impact of the upcoming Free Trade Agreement of the Americas (FTAA). It shows that NAFTA functioned – at least in its first years - as an investment relocation engine, while MNCs' reaction to MERCOSUR was significant only in the automotive sector. The emergence of China and other Asian economies, with their low cost and vast markets, and the progressive enlargement in the scope of MNCs operations, seem to diminish the economic relevance of NAFTA and MERCOSUR. FTAA may provide a new impetus to the integration of the automotive industry in the Americas, and a stronger rationale for a slowdown of plant relocation to Asia in light industries such as electronics and garments. But it is unlikely that it will reverse current trends which point to Asia – with China at the epicenter – as the global magnet for manufacturing and exports.
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  • 80
    Publication Date: 2004-08-01
    Description: We discuss the political and legal environment surrounding Internet wine sales, and consider the arguments in the debate over direct shipment bans on wine by investigating the wine market in the Northern Virginia suburbs of Washington, DC. Using a sample of wines identified by Wine and Spirits magazine's annual restaurant poll, we find that 15 percent of wines available online were not available from retail wine stores within 10 miles of McLean, Virginia during the month the data were collected. Our results also indicate that Virginia's direct shipment ban, which was in place until 2003, prevented consumers from purchasing some premium wines at lower prices online. Aggregate cost savings depends on the consumer's shopping strategy, the price per bottle, the quantity of wine ordered, and the shipping method chosen. For the entire sample, online purchase could result in an average savings of as much as 3.6 percent or an average premium of as much as 48 percent. A comparison shopper who considers both online and offline retailers could save an average of 1.6-9.7 percent. These results help explain why consumers and producers have found it worthwhile to challenge interstate direct shipment bans, which tend to benefit wine wholesalers.
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  • 81
    Publication Date: 2004-12-25
    Description: The dynamics of gravity currents are believed to be strongly influenced by dissipation due to turbulence and mixing between the current and the surrounding ambient fluid. This paper describes new theory and experiments on gravity currents produced by lock exchange which suggest that dissipation is unimportant when the Reynolds number is sufficiently high. Although there is mixing, the amount of energy dissipated is small, reducing the current speed by a few percent from the energy-conserving value. Benjamin (J. Fluid Mech. vol. 31, 1968, p. 209) suggests that dissipation is an essential ingredient in gravity current dynamics. We show that dissipation is not important at high Reynolds number, and provide an alternative theory that predicts the current speed and depth based on energy-conserving flow that is in good agreement with experiments. We predict that in a deep ambient the front Fronde number is 1, rather than the previously accepted value of √ 2. New experiments are reported for this case that support the new theoretical value. © 2004 Cambridge University Press.
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  • 82
    Publication Date: 2004-12-10
    Description: Experimental results on sediment erosion (scour) by a plane turbulent wall jet, issuing from a sluice gate, are presented which show clearly - it seems for the first time - that the turbulent wall layer is destabilized by the concave curvature of the water/sediment interface. The streamwise Görtler vortices which emerge create sediment streaks or longitudinal sediment ridges. The analysis of the results in terms of Görtler instability of the wall layer indicates that the strength of these curvature-excited streamwise vortices is such that the sediment transport is primarily due to turbulence created by these vortices. Their contribution to the wall shear stress is taken to be of the same form as the normal turbulent wall shear stress. For this reason, the model developed by Hogg et al. (J. Fluid Mech. Vol. 338, 1997, p. 317) remains valid; only the numerical coefficients are affected. The logarithmic dependency of the time evolution of the scour-hole depth predicted by this model is shown to be in good agreement with experiments. New scaling laws for the quasi-steady state depth and the associated time, inspired by the Hogg et al. (1997) model are proposed. Furthermore, it is emphasized that at least two scouring regimes must be distinguished: a short-time regime after which a quasi-steady state is reached, followed by a long-time regime, leading to an asymptotic state of virtually no sediment transport. © 2004 Cambridge University Press.
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  • 83
    Publication Date: 2004-12-25
    Print ISSN: 0022-1120
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  • 84
    Publication Date: 2004-12-10
    Description: The effect of gravity modulation on the nonlinear evolution of long-wavelength disturbances at the free surface of a surfactant-covered thin liquid layer is studied. The surfactants, which are assumed to be insoluble, give rise to interfacial concentration gradients and associated Marangoni flow in the underlying liquid film. A coupled system of lubrication-theory-based evolution equations for the film height and surfactant concentration is solved numerically using spectral methods. Previous work using Floquet theory had determined that small-amplitude long-wavelength disturbances are destabilized by gravity modulation in the presence of surfactant; uncontaminated films were found to be linearly stable. Our numerical results indicate that uncontaminated free surfaces are destabilized by nonlinearities and exhibit a harmonic response. The interface exhibits complex dynamics during a forcing cycle, characterized by numerous coalescence events between thickened fluid ridges leading to coarsening. The presence of surfactant-induced Marangoni flow gives rise to a harmonic response, larger scale fluid structures of reduced amplitude, less frequent coalescence events, and less complicated film dynamics. © 2004 Cambridge University Press.
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  • 85
    Publication Date: 2004-12-10
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  • 86
    Publication Date: 2004-12-10
    Description: We present a model describing the evolution of the small-scale Navier-Stokes turbulence due to its stochastic distortion by much larger turbulent scales. This study is motivated by numerical findings (Laval et al. Phys. Fluids vol. 13, 2001, p. 1995) that such interactions of separated scales play an important role in turbulence intermittency. We introduce a description of turbulence in terms of the moments of k-space quantities using a method previously developed for the kinematic dynamo problem (Nazarenko et al. Phys. Rev. E vol. 68, 2003, 0266311). Working with the k-space moments allows us to introduce new useful measures of intermittency such as the mean polarization and the spectral flatness. Our study of the small-scale two-dimensional turbulence shows that the Fourier moments take their Gaussian values in the energy cascade range whereas the enstrophy cascade is intermittent. In three dimensions, we show that the statistics of turbulence wavepackets deviates from Gaussianity toward dominance of the plane polarizations. Such turbulence is formed by ellipsoids in the k-space centred at its origin and having one large, one neutral and one small axis with the velocity field pointing parallel to the smallest axis. © 2004 Cambridge University Press.
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  • 87
    Publication Date: 2004-12-10
    Description: Numerical solutions of stationary flow resulting from immersion of a single body in simple shear flow are reported for a range of Reynolds numbers. Flows are computed using finite-element methods. Comparisons to results of asymptotic low-Reynolds-number theory, experimental study, and other numerical techniques are provided. Results are presented primarily for isotropic bodies, i.e. the circular cylinder and sphere, for both of which the two conditions of a torque-free (freely-rotating) and fixed body are investigated. Conditions studied for the sphere are 0 〈 Re ≤ 100, and for the circular cylinder 0 〈 Re ≤ 500, with the shear-flow Reynolds number defined as Re = ∞dot;ca2 /ν; ∞dot;c is the shear rate of the Cartesian simple shear flow u = (∞dot;cy, 0, 0), a is the cylinder or sphere radius, and ν is the kinematic viscosity of the fluid. In the torque-free case, the rotation rate of the body decreases with increasing Re. Qualitative dependence, seen in the Re = 0 fluid flow field, upon whether the body is fixed against rotation or torque-free vanishes as Re increases and the fluid flow is more similar to that around the Re = 0 fixed body: the influence of rotation of the body and the associated closed streamlines are confined to a narrow layer about the body for Re 〉 0(1). Separation of the boundary layer is observed in the case of a fixed cylinder at Re ≈ 85, and for a fixed sphere at Re ≈ 100; similar separation phenomena are observed for a freely rotating cylinder. The surface stress and its symmetric first moment (the stresslet) are presented, with the latter providing information on the particle contribution to the mixture rheology at finite Re. Stationary flow results are also presented for elliptical cylinders and oblate spheroids, with observation of zero-torque inclinations relative to the flow direction which depend upon the aspect ratio, confirming and extending prior findings. © 2004 Cambridge University Press.
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  • 88
    Publication Date: 2004-11-25
    Description: We investigate the possibility of using proper orthogonal decomposition (POD) in reconstructing complete flow fields from gappy data. The incomplete fields are created from DNS snapshots of flow past a circular cylinder by randomly ommiting data points. We first examine the effectiveness of an existing method and subsequently introduce modifications that make the method robust and lead to the maximum possible resolution at a certain level of spatio-temporal gappiness. We simulate three levels of gappiness at approximately 20%, 50% and 80% in order to investigate the limits of applicability of the new procedure. We find that for the two lower levels of gappiness both the temporal and spatial POD modes can be recovered accurately leading to a very accurate representation of the velocity field. The resulting resolution is improved by more than five times compared to the existing method. However, for 80% gappiness only a few temporal modes are captured accurately while the corresponding spatial modes are noisy. We explain this breakdown of the method in terms of a simple perturbation analysis. This new methodology can be a building block in an effort to develop effective data assimilation techniques in fluid mechanics applications. © 2004 Cambridge University Press.
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  • 89
    Publication Date: 2004-11-25
    Description: We investigate the slow spreading of fluid mud over a gently sloped conical surface which may simulate a shallow basin or a hill. The mud is assumed to behave as a Bingham plastic possessing a finite yield stress and the lubrication approximation is used. Because of the finite yield stress, a variety of non-trivial equilibrium profiles can exist, corresponding to the state of deposit at the end of upward or downward motion. Analytical solutions are derived for axially symmetric deposits. It is shown that the front of the final profile in axisymmetric spreading is of a common form in dimensionless variables, independent of the total mud volume. Transient evolutions are then studied numerically by employing a finite-volume scheme for both axially symmetric and asymmetric spreading from a localized source. The characteristic features of the mud pile at different stages of spreading are examined. The final shape in asymmetric spreading is strongly affected by the total volume released and by the rate of discharge. © 2004 Cambridge University Press.
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  • 90
    Publication Date: 2004-11-25
    Description: Experiments are reported on the dynamics of a bed of particles sheared by a viscous Couette flow in an annular channel, with emphasis on the distributions of particle velocities, durations and lengths of the small saltation flights, and surface density of the moving particles. The velocity distributions are shown to decay approximately exponentially, with mean value, Up, equal to 0.1 γd, where γ is the shear rate and d is the particle diameter. The duration of the flights does not depend on the shear rate, and is equal to 15 times the settling time d/Vs, where Vs is the Stokes settling velocity. Starting from an initially loosely packed bed, the surface density of the moving particles, Np, was observed to decrease slowly over several days, unlike their velocity which remains constant with time. This decay is related to the increase of the threshold shear rate for particle motion, and corresponds to rearrangement of the particles near the bed surface (armouring). When the stationary state is reached, Np depends linearly on the shear rate, so that the particle flow rate, Qp = N p Up, is a quadratic function of the shear rate. Two theoretical models are proposed to account for these observations. In the first one, the erosion and deposition rates are modelled using the two hydrodynamic time scales: the inverse shear rate γ-1 for the erosion rate, and the settling time d/V s for the deposition rate. This model accounts for the linear dependence of Np on the shear rate. The second model was developed to capture the slow decrease of Np, by considering the trapping of moving particles into troughs of the bed. This trapping model does recover the main features observed experimentally, although the characteristic time for the decrease of N p still remains too short. Our observations are, finally, compared to existing numerical and experimental studies on turbulent flows. © 2004 Cambridge University Press.
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  • 91
    Publication Date: 2004-11-25
    Description: We consider miscible displacement between parallel plates in the absence of diffusion, with a concentration-dependent viscosity. By selecting a piecewise viscosity function, this can also be considered as 'three-fluid' flow in the same geometry. Assuming symmetry across the gap and based on the lubrication ('equilibrium') approximation, a description in terms of two quasi-linear hyperbolic equations is obtained. We find that the system is hyperbolic and can be solved analytically, when the mobility profile is monotonic, or when the mobility of the middle phase is smaller than its neighbours. When the mobility of the middle phase is larger, a change of type is displayed, an elliptic region developing in the composition space. Numerical solutions of Riemann problems of the hyperbolic system spanning the elliptic region, with small diffusion added, show good agreement with the analytical outside, but an unstable behaviour inside the elliptic region. In these problems, the elliptic region arises precisely at the displacement front. Crossing the elliptic region requires the solution of essentially an eigenvalue problem of the full higher-dimensional model, obtained here using lattice BGK simulations. The hyperbolic-to-elliptic change-of-type reflects the failing of the lubrication approximation, underlying the quasi-linear hyperbolic formalism, to describe the problem uniformly. The obtained solution is analogous to non-classical shocks recently suggested in problems with change of type. © 2004 Cambridge University Press.
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  • 92
    Publication Date: 2004-11-10
    Description: Rarefied gas flow through a thin orifice is studied on the basis of the direct simulation Monte Carlo method. The mass flow rate and the flow field are calculated over the whole range of the Knudsen number for various values of the pressure ratio. It is found that at all values of the pressure ratio a significant variation of the flow rate occurs in the transition regime between the free-molecular and hydrodynamic regimes. In the hydrodynamic regime the flow rate tends to a constant value. In the case of finite pressure ratio the flow field qualitatively differs from that for outflow into vacuum, namely vortices appear in the downflow container on approaching the hydrodynamic regime. Then, in the hydrodynamic regime the gas flow forms a strong jet. A comparison of the numerical results with experimental data available in the open literature has been performed. © 2004 Cambridge University Press.
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  • 93
    Publication Date: 2004-11-10
    Description: Thermal convection in rapidly rotating, self-gravitating Boussinesq fluid spheres is characterized by three parameters: the Rayleigh number R, the Prandtl number Pr and the Ekman number E. Two different asymptotic limits were considered in the previous studies of the linear problem. In the double limit E ≪ 1 and Pr/E ≫ 1, the local asymptotic theory showed that the convective motion is strongly non-axisymmetric, columnar, highly localized and described by the asymptotic scalings, (1/s)∂/∂Φ = O (E-1/3), ∂/∂z = 0(1), Rc = 0(E-1/3), where R c denotes the critical Rayleigh number and (s, Φ, z are cylindrical polar coordinates with the axis of rotation at s = 0. A global asymptotic theory with novel features for the limit E ≪ 1 and Pr/E ≫ 1, indicating the radial asymptotic scaling ∂/∂s = 0(E-1/3), was recently developed by Jones et al. (J. Fluid Mech. vol. 405, 2000, p. 157). In the different double limit E ≪ 1 and Pr/E ≫ 1, an asymptotic theory for the onset of convection building upon the theory of inertial waves was developed by Zhang (J. Fluid Mech. vol. 268, 1994 p. 211). It was shown that the convective motion at the leading-order approximation is represented by a single inertial-wave mode with a quadratic polynomial of s and z, obeying the asymptotic dependence ∂/∂s ∼ (1/s)∂/∂Φ = 0( 1 and Rc = 0(E) for stress-free spheres. There exist no simple asymptotic scalings for E 〈 1 appropriate to all values of PrIE. For an arbitrary small but non-zero E,the highly localized convection spreads out spatially with decreasing Pr, suggesting that the scaling laws such a∂/∂as = 0 (E-1/3) are no longer valid when Pr/E is not sufficiently large. This paper represents an attempt to develop a new asymptotic method for the analysis of convection in rapidly rotating spheres valid for asymptotically small E and for 0 〈 Pr/E ≤ ∞. The new method is based on the following three hypotheses. The first is that the leading-order velocity of convection for 0〈 Pr/E ≤ ∞ at E ≤ I is represented by either a single quasi-geostrophic-inertial-wave mode or by a combination of several quasi-geostrophic-inertial-wave modes convectively excited and sustained. Secondly, we assume that the convective motion for 0〈 Pr/E ≤ ∞ at E 〈 1 always has columnar structure, i.e. α/∂ az - 0(l), but without the general asymptotic scalings in the radial and azimuthal direction. Thirdly, we assume that there always exists a boundary flow that is non-zero only in the Ekman boundary layer on the bounding spherical surface and plays an important role even in the case of stress-free boundaries. Comparison between the result of the new method and the corresponding fully numerical simulation demonstrates a satisfactory quantitative agreement for all values of 0 ≤ Pr/ E ≤ 0 (106) when 0 (10-5) ≤ E ≤ 0 (10- 6). The new method is asymptotic in the sense that it is valid only for an asymptotically small E ≪ 1. In addition to the linear problem of thermal convection in rapidly rotating spheres, the corresponding weakly nonlinear problem is also solve to obtain an analytical expression for the convection-driven differential rotation generated by the nonlinear interaction of quasi-geostrophic-inertial-wave modes through the Reynolds stresses. The new method not only reveals the underlying nature of thermal convection in rapidly rotating spheres but also unites the two previously disjointed subjects in rotating fluids: the inertial-wave problem and the convective instability problem. © 2004 Cambridge University Press.
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  • 94
    Publication Date: 2004-11-10
    Description: This paper investigates the spatio-temporal instability of the natural-convection boundary-layer flow adjacent to a vertical heated flat plate immersed in a thermally stratified ambient medium. The temperature on the plate surface is distributed linearly. By introducing a temperature gradient radio a between the wall and the medium, we obtain a similarity solution which can describe in a smooth way the evolution between the states with isothermal and uniform-heat-flux boundary conditions. It is shown that the flow reversal in the basic flow vanishes when a is larger than a critical value. A new absolute-convective instability transition of this flow is identified in the context of the coupled Orr Sommerfeld and energy equations. Increasing a decreases the domain of absolute instability, and when a is large enough the absolute instability disappears. In particular, when a = 0 (isothermal surface), the interval of absolute instability becomes narrower for fluids of larger Prandtl numbers, and the absolute instability does not occur for Prandtl numbers greater than 70; when a = 1 (uniformheat-flux surface) the instability remains convective in a wide Prandtl number range. Analysis of the Rayleigh equations for this problem reveals that the basic flows supporting this new instability transition have inviscid origin of convective instability. Based on the steep global mode theory, the effects of a and Prandtl number on the global frequency are discussed as well. © 2004 Cambridge University Press.
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  • 95
    Publication Date: 2004-11-10
    Description: An analysis is made of steady-state flow of a compressible fluid in an infinite rapidly rotating pipe. Flow is induced by imposing a small azimuthally varying thermal forcing at the pipe wall. The Ekman number is small. Analyses are conducted to reveal both the axisymmetric-type and non-axisymmetric-type solutions. The axisymmetric solution is based on the azimuthally averaged wall boundary condition. The nonaxisymmetric solution stems from the azimuthally fluctuating part of the wall boundary condition. It is shown that the two-dimensional (uniform in the axial direction) non-axisymmetric solution exists for σ(γ - 1)M2 ≫ O(E1/3). However, an axially dependent solution is found if σ(γ - 1)M2≲ O(E1/3), in which E denotes the Ekman number, M the Mach number, γ the specific heat ratio and σ the Prandtl number. The axisymmetric solution prevails over the whole flow region; the two-dimensional non-axisymmetric solution is confined to the near-wall thermal layer of thickness O(E1/3). As a canonical example, a detailed description is given for the case of a highly conducting wall with differential heating. © 2004 Cambridge University Press.
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  • 96
    Publication Date: 2004-11-10
    Description: We present a study of the drag reduction induced by rigid fibres in a turbulent channel flow using direct numerical simulation. The extra stresses due to the fibres are calculated with the well-known constitutive equation involving the moments of the orientation vector. Drag reductions of up to 26% are calculated, with the largest drag reductions observed using non-Brownian fibres and semi-dilute concentrations. These findings suggest that elasticity is not necessary to achieve turbulent drag reduction. Flow statistics show trends similar to those observed in simulation of polymeric drag reduction: Reynolds stresses are reduced, velocity fluctuations in the wall-normal and spanwise directions are reduced while streamwise fluctuations are increased, and streamwise vorticity is reduced. We observe strong correlations between the fibre stresses and inter-vortex extensional flow regions. Based on these correlations and instantaneous visualizations of the flow field, we propose a mechanism for turbulent drag reduction by rigid fibre additives. © 2004 Cambridge University Press.
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  • 97
    Publication Date: 2004-10-25
    Description: This presents part 2 of a study of nonlinear convection in horizontal mushy layers during the solidification of binary alloys. Part 1 dealt with only the oscillatory modes of convection (Riahi, J. Fluid Mech. vol. 467, 2002, pp. 331-359). In the present paper we consider the particular range of parameters where the critical values of the scaled Rayleigh number R for the onset of oscillatory and stationary convection are close to each other, and we develop and analyse a nonlinear theory in such a parameter regime which takes into account those mixed stationary and oscillatory modes of convection with common wavenumber vectors. Under a near-eutectic approximation and in the limit of large far-field temperature, we first determine a number of weakly nonlinear solutions, and then the stability of these solutions is investigated. The most interesting result is the preference for a mixed solution composed of standing and stationary hexagonal modes over a relatively wide range of the parameter values and for R just above its lowest subcritical value where convection is possible. Such a preferred solution has properties mostly in agreement with the experimental results due to Tait et al. (Nature, vol. 359, 1992, pp. 406-408) in the sense that the flow is downward at the cell centres, upward at the cell boundaries and there is some tendency for channel formation at the cell nodes. © 2004 Cambridge University Press.
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  • 98
    Publication Date: 2004-10-10
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  • 99
    Publication Date: 2004-10-10
    Description: The dynamic response of an initially spherical capsule subject to different externally imposed flows is examined. The neo-Hookean and Skalak et al. (Biophys. J., vol. 13 (1973), pp. 245-264) constitutive laws are used for the description of the membrane mechanics, assuming negligible bending resistance. The viscosity ratio between the interior and exterior fluids of the capsule is taken to be unity and creeping-flow conditions are assumed to prevail. The capillary number ε is the basic dimensionless number of the problem, which measures the relative importance of viscous and elastic forces. The boundary-element method is used with bi-cubic B-splines as basis functions in order to discretize the capsule surface by a structured mesh. This guarantees continuity of second derivatives with respect to the position of the Lagrangian particles used for tracking the location of the interface at each time step and improves the accuracy of the method. For simple shear flow and hyperbolic flow, an interval in ε is identified within which stable equilibrium shapes are obtained. For smaller values of ε, steady shapes are briefly captured, but they soon become unstable owing to the development of compressive tensions in the membrane near the equator that cause the capsule to buckle. The post-buckling state of the capsule is conjectured to exhibit small folds around the equator similar to those reported by Walter et al. Colloid Polymer Sci. Vol. 278 (2001), pp. 123-132 for polysiloxane microcapsules. For large values of ε, beyond the interval of stability, the membrane has two tips along the direction of elongation where the deformation is most severe, and no equilibrium shapes could be identified. For both regions outside the interval of stability, the membrane model is not appropriate and bending resistance is essential to obtain realistic capsule shapes. This pattern persists for the two constitutive laws that were used, with the Skalak et al. law producing a wider stability interval than the neo-Hookean law owing to its strain hardening nature. © 2004 Cambridge University Press.
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  • 100
    Publication Date: 2004-09-25
    Description: We consider the effects of blade mean loading on the noise generated by the interaction between convected vorticity and a blade row. The blades are treated as flat plates aligned at a non-zero incidence angle, δ, to the oncoming stream, and we take harmonic components of the incident vorticity field with reduced frequency k, and use asymptotic analysis in the realistic limit k ≫ 1, δ ≪ 1 with kδ = 0 (1). In a previous paper (Peake & Kerschen, J. Fluid Mech., vol. 347 (1997), pp. 315-346) we have analysed the sound radiated back upstream, but the field in the blade passages and the sound radiated downstream are also of considerable practical interest, and are considered in this paper. The flow is seen to consist of inner regions around each leading edge, in which sound is generated by the local gust-airfoil and gust-flow interactions, and an outer region in which the incident gust and the acoustic radiation interact with the non-uniform mean flow and the other blades. It is shown that the complicated multiple interactions between the blades can be represented by images in potential-streamfunction space, yielding closed-form expressions for the phase distortion experienced by sound waves propagating down the blade passages. The acoustic radiation downstream of the cascade at O(1) distances is dominated by the duct-mode beams that emanate from the passages, while the far downstream field is generated by the diffraction of the duct modes by the trailing edges. The modal amplitudes of the radiation field far downstream tend to be largest when the mode direction is close to the propagation direction of the duct mode which generated it, corresponding to the way (in uniform flow) in which the radiation from a single blade passage tends to be beamed in the duct-mode directions. Although the diffraction coefficient for the scattering from a single trailing edge is singular in these directions, we show how uniformly valid expressions can be derived by combining the trailing-edge fields in an appropriate way, thereby describing the larger amplitude in the beam directions. The steady non-uniform flow downstream has the effect of tilting the directions of the beams by O(δ) angles away from the duct-mode directions, which are explicitly determined. Throughout this analysis it will be seen that the interaction with the non-uniform mean flow introduces phase corrections of size O(kδ), which, given the way in which interference effects between the multiple blades dominate unsteady cascade flow, proves to be highly significant. © 2004 Cambridge University Press.
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