ALBERT

Beschreibung / Inhaltsverzeichnis: Geochemistry is a science that is based on an understanding of chemical processes in the earth. One of the principal tools available to the chemist for understanding systems at equilibrium is thermodynamics. The awareness and application of thermodynamic techniques has increased at a very fast pace in geosciences; in fact, one may be so bold as to say that thermodynamics in geology has reached the "mature" stage, although much future thermodynamic research is certainly needed. However, the natural processes in the earth are often sluggish enough that a particular system may not reach equilibrium. This observation is being supported constantly by new experimental and field data available to the geochemist e.g. the non-applicability of the phase rule in some assemblages, the compositional inhomogeneities of mineral grains, the partial reaction rims surrounding original minerals, the lack of isotopic equilibration or the absence of minerals (e.g. dolomite), which should be present according to thermodynamics. The need to apply kinetics has produced a large number of papers dealing with kinetics in geochemistry. As an initial response to this growing field, a conference on geochemical transport and kinetics was conducted at Airlie House, VA, in 1973, sponsored by the Carnegie Institution of Washington. The papers there dealt with several kinetic topics including diffusion, exsolution, metasomatism and metamorphic layering. Since 1973 the number of kinetic papers has continued to increase greatly. Therefore, the time is ripe for a Short Course in Kinetics, which brings together the fundamentals needed to explain field observations using kinetic data. It is hoped that this book may serve, not only as a reference for researchers dealing with the rates of geochemical processes, but also as a text in courses on geochemical kinetics. One of us has found this need of a text in teaching a graduate course on geochemical kinetics at Harvard and at Penn State during the past several years. Finally, it is our hope that the book may itself further even more research into the rates of geochemical processes and into the quantification of geochemical observations. The book is organized with a rough temperature gradient in mind, i.e. low temperature kinetics at the beginning and igneous kinetics at the end (no prejudices are intended with this scheme!). However, the topics in each chapter are general enough that they can be applied often to any geochemical domain: sedimentary, metamorphic or igneous. The theory of kinetics operates at two complementary levels: the phenomenological and the atomistic. The former relies on macroscopic variables (e.g. temperature or concentrations) to describe the rates of reactions or the rates of transport; the latter relates the rates to the basic forces operating between the particular atomic or molecular species of any system. This book deals with both descriptions of the kinetics of geochemical processes. Chapter one sets the framework for the phenomenological theory of reaction rates. If any geochemical reaction is to be described quantitatively, the rate law must be experimentally obtained in a kinetically sound manner and the reaction mechanism must be understood. This applies to heterogeneous fluid-rock reactions such as those occurring during metamorphism, hydrothermal alteration or weathering as well as to homogeneous reactions. Chapter 2 extends the theory to the global kinetics of geochemical cycles. This enables the kinetic concepts of stability and feedback to be applied to the cycling of elements in the many reservoirs of the earth. Chapter 3 applies the phenomenological treatment of chapter 1 to diagenesis and weathering. The rate of dissolution of minerals as well as the chemical evolution of pore waters are discussed. The atomistic basis of rates of reaction, transition state theory, is introduced in Chapter 4. Transition state theory can be applied to relate the rate constants of geochemical reactions to the atomic processes taking place. This includes not only homogeneous reactions but also reactions that occur at the surface of minerals. Chapter 5 discusses the theory of irreversible thermodynamics and its application to petrology. The use of the second law of thermodynamics along with the expressions for the rate of entropy production in a system have been used successfully since 1935 to describe kinetic phenomena. The chapter applies the concepts to the growth of minerals during metamorphism as well as to the formation of differentiated layers (banding) in petrology. Chapter 6 describes the phenomenological theory of diffusion both in aqueous solutions and in minerals. In particular, the multicomponent nature of diffusion and its consequence in natural systems is elaborated. Chapter 7 provides the atomistic basis for the rates of reactions in minerals. Understanding of the rates of diffusion, conduction, order-disorder reactions or exsolution in minerals depends on proper description of the defects in the various mineral structures. Chapter 8 provides the kinetic theory of crystal nucleation and growth. While many of the concepts in the chapter can be applied to aqueous systems, the emphasis is on igneous processes occurring during crystallization of a melt. To fully understand both the mineral composition as well as the texture of igneous rocks, the processes whereby new crystals form and grow must be quantified by using kinetic theory. Due to space and time limitations (kinetics!) some topics have not been covered in detail. In particular, the mathematical solution of diffusion or conduction equations is discussed very well by Crank in his book, Mathematics of Diffusion, and so is not covered to a great extent here. The treatment of fluid flow (e.g. convection) is also not covered in the text.

Beschreibung / Inhaltsverzeichnis: Although phyllosilicates are common in almost all types of rocks, their detailed study has not advanced in proportion to their importance. Books and reviews on this subject have been restricted primarily to the areas of clay mineralogy and soils. Such treatments understandably restrict coverage of the occurrences of the macroscopic-size species as well as much of their mineralogical and petrological nature. It was decided at the outset that not all phyllosilicates could be covered in a single book, and the size of this volume addressed only to the micas justifies the original decision. Kaolins, serpentines, chlorites, etc. will have to wait until some later date. This volume attempts to gather together much of our knowledge of micas, the most abundant phyllosilicate, and to indicate promising areas of future research. Chapters 1-3 lay the foundations of the classification, structures, and crystal chemistry of micas. Chapter 4 treats bonding and electrostatic modeling of micas. Chapters 5 and 6 cover spectroscopic and optical properties. Chapters 7-13, the bulk of the volume, are devoted to geochemistry and petrology. These include phase equilibria and the occurrences, chemistry, and petrology of micas in igneous, metamorphic, and sedimentary rocks, pegmatites, and certain ore deposits. Some treatments are exhaustive. All are at the forefront of our present knowledge, and indicate clearly the practical applications'of the study of micas to ascertaining various parameters of origin and crystallization history, as well as the many problems that still exist. The aim of this type of treatment is twofold -- to provide a handy reference volume for teachers and students and to enable researchers to pick more easily those directions and problems for which future research is most needed or is apt to be most productive or most challenging. X-ray powder patterns of micas in the literature are of surprisingly poor quality. The best are collated and supplemented with additional new patterns in the Appendix as an aid to identification.

Beschreibung / Inhaltsverzeichnis: Chapter 1: High-resolution Paleoclimatology - R. Bradley What is high-resolution paleoclimatology? What are its major achievements? What opportunities and challenges does it now face? What should dendroclimatology's role be in this? Chapter 2: Dendroclimatology in high-resolution Paleoclimatology - M. K. Hughes, H. F. Diaz and Th. W. Swetnam An overview of the development of dendroclimatology and an introduction to the questions posed in this book. Scientific bases of dendroclimatology Chapter 3: How well understood are the processes that create tree-ring records? - G. Vaganov Starting at the most basic level of the environmental control of tree-ring formation, do we have the necessary biological and ecophysiological understanding of this to support inferences about climate variability from tree rings? What are the weak points of this understanding and how might they be strengthened? Chapter 4: The state of the art of quantitative methods in dendroclimatology - E. Cook How sound are the quantitative techniques commonly used in dendroclimatology, in chronology building, identification and reconstruction of climate variables and the checking of these reconstructions? Are they appropriate to the material being analyzed and to the climatological problems being addressed? How might they be improved? Chapter 5: Detecting low-frequency change using tree rings - K. Briffa What limits the ability of tree-ring records to faithfully record climate variability at low frequencies (multi-centennial to millennial)? How might those limitations be overcome, if at all? What are the advantages and limitations of older and more novel approaches? What are the implications of these limitations? Reconstruction of climate patterns and values relative to today's climate Chapter 6: Dendroclimatology at regional and continental scales - R. Villalba What have been the major contributions of dendroclimatology to climatology so far? In what regions and for which climate problems is exciting progress now being made? What next? Chapter 7: Dendroclimatology at hemispheric and global scales - M. K. Hughes and M. Mann What are the achievements of dendroclimatology as applied at hemispheric and global scales climate patterns, circulation indices and large-scale means? What are the limitations of this approach? How might they be overcome? How might dendroclimatology contribute to the study of central pressing problems such as "How big is climate sensitivity? How has the last century, and especially recent decades, compared with earlier centuries? How faithful a representation of variability in recent centuries does the 20th century instrumental record give? Particular attention will be given to: a) identifying the most robust findings; and b) the most serious limitations. Chapter 8: Dendroclimatology, dendrohydrology and water resources management - C. Woodhouse and D. Meko How may dendroclimatology contribute to the study of water resources? How may it be used to inform modern public and decision-maker expectations of climate variability? Chapter 9: Dendroclimatology and the ecosystem impacts of climate - Th. W. SwetnamHow has dendroclimatology contributed to disturbance ecology? What is the significance of the recent changes in tree-growth-climate relationships observed in some regions, not only for dendroclimatology, but also for the understanding of the impacts of climate variability and change on ecosystems? Chapter 10: Dendroclimatology and the understanding of the interactions between climate variability and ancient human societies - D. Stahle and J. DeanHow has dendroclimatology contributed to understanding of the relationships between climate variability and societies in ancient times? Chapter 11: Tree rings and climate- sharpening the focus - M. K. Hughes, H. F. Diaz and Th. W. Swetnam What has been learned, using tree rings, about natural climate variability and its environmental and social impacts? What are the most significant strengths and weaknesses of dendroclimatology and the needs of, and opportunities for, future work.

Beschreibung / Inhaltsverzeichnis: This volume presents an overview of the current state of dendroclimatology, its contributions over the last 30 years, and its future potential. The material included is useful not only to those who generate tree-ring records of past climate-dendroclimatologists, but also to users of their results - climatologists, hydrologists, ecologists and archeologists.