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  • 1
    Call number: (DE-599)GBV03709842X
    Type of Medium: Monograph available for loan
    Language: German
    Location: MOP - must be ordered
    Branch Library: GFZ Library
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  • 2
    Monograph available for loan
    Monograph available for loan
    Stuttgart : Schweizerbart Science Publishers ; Volume 1, number 1 (1978)-
    Call number: M 18.91571
    Type of Medium: Monograph available for loan
    Pages: 134 Seiten
    ISSN: 2363-7196
    Series Statement: Global tectonics and metallogeny : special issue Vol. 10/2-4
    Classification:
    Tectonics
    Parallel Title: Erscheint auch als Global tectonics and metallogeny
    Language: English
    Location: Upper compact magazine
    Branch Library: GFZ Library
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  • 3
    Call number: AWI A3-20-93434-2
    In: Meteorologische Abhandlungen / Institut für Meteorologie und Geophysik der Freien Universität Berlin, Band XXXII, Heft 2
    Type of Medium: Series available for loan
    Pages: 218 Seiten , Illustrationen
    Series Statement: Meteorologische Abhandlungen / Institut für Meteorologie und Geophysik der Freien Universität Berlin 32,2
    Language: German
    Note: Zugleich: Dissertation, Freie Unversität Berlin, [ca. 1963] , INHALTSVERZEICHNIS PROBLEMSTELLUNG UND ZIELSETZUNG 1. BEMERKUNGEN ZUM BEOBACHTUNGSGELÄNDE UND ZUM BEOBACHTUNGSMATERIAL 1.1 Das Beobachtungsgelände 1.2 Das Beobachtungsmaterial 2. HOMOGENITÄTSBETRACHTUNGEN 2.1 Temperatur 2.2 Niederschlag 2.3 Wind 2.4 Sonnenschein und Bewölkung 3. TEMPERATURVERHÄLTNISSE 3.1 Monats- und Jahreswerte 3.2 Tageswerte 3.3 Pentadenwerte 3.4 Häufigkeitsbetrachtungen 3.5 Interdiurne Veränderlichkeit 3.6 Der tägliche Gang 3.7 Vorkommen bestimmter Schwellenwerte 3.71 Frost- und Eistage 3.72 Sommer- und Tropentage 4. DER WASSERGEHALT DER LUFT 4.1 Monats- und Jahreswerte 4.2 Tageswerte 4.3 Häufigkeitsbetrachtungen 4.4 Interdiurne Veränderlichkeit 4.5 Der tägliche Gang 5. BEWÖLKUNGSVERHÄLTNISSE 5.1 Monats- und Jahreswerte 5.2 Tageswerte 5.3 Häufigkeitsbetrachtungen 5.4 Der tägliche Gang 5.5 Heitere und trübe Tage 5.6 Nebel 6. SONNENSCHEIN 6.1 Monats- und Jahreswerte 6.2 Tageswerte 6.3 Der tägliche Gang 7. NIEDERSCHLAGSVERHÄLTNISSE 7.1 Monats- und Jahreswerte 7.2 Niederschlagsbereitschaft 7.3 Tageswerte 7.4 Der tägliche Gang 7.5 Häufigkeitsbetrachtungen 7.6 Niederschlags- und Trockenperioden 7.7 Niederschlag und Wind· 7.8 Schneeverhältnisse 7.81 Schneefall und Schneedecke 7.82 Schneehöhe 7.9 Gewitter 8. WINDVERHÄLTNISSE 8.1 Windrichtung 8.2 Windgeschwindigkeit 8.21 Der jährliche Gang 8.22 Häufigkeitsbetrachtungen 8.23 Sturmtage und Windstillen 8.24 Der tägliche Gang 9.ZUSAMMENFASSUNG VERZEICHNIS DER TEXTTABELLEN VERZEICHNIS DER ABBILDUNGEN LITERATURVERZEICHNIS TABELLENANHANG
    Location: AWI Reading room
    Branch Library: AWI Library
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  • 4
    Monograph available for loan
    Monograph available for loan
    [Edgecumbe, N.Z.] : A. Muller
    Call number: M 15.89146
    Description / Table of Contents: An account of the results of the 2 March 1987 earthquake in the eastern Bay of Plenty and the aftermath's effects on the people and places on the Rangitaiki Plains
    Type of Medium: Monograph available for loan
    Pages: 223 S., , Ill.
    Language: English
    Branch Library: GFZ Library
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  • 5
    Call number: MOP 19538/1d-6d
    Type of Medium: Monograph available for loan
    Pages: 111 S.
    ISSN: 0486-2287
    Language: Russian
    Note: In kyrill. Schr.
    Location: MOP - must be ordered
    Branch Library: GFZ Library
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  • 6
    Monograph available for loan
    Monograph available for loan
    Garmisch-Partenkirchen : Institut für atmosphärische Umweltforschung der Fraunhofer- Gesellschaft
    Call number: MOP 44829 / Mitte
    Type of Medium: Monograph available for loan
    Pages: 25 S. , graph. Darst.
    Language: English
    Location: MOP - must be ordered
    Branch Library: GFZ Library
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  • 7
    Call number: AWI A3-20-93434
    In: Meteorologische Abhandlungen / Institut für Meteorologie und Geophysik der Freien Universität Berlin, Band XXXII, Heft 1
    Type of Medium: Series available for loan
    Pages: 121 Seiten , Illustrationen
    Series Statement: Meteorologische Abhandlungen / Institut für Meteorologie und Geophysik der Freien Universität Berlin 32,1
    Language: German
    Note: Zugleich: Dissertation, Freie Unversität Berlin, [ca. 1963] , INHALTSVERZEICHNIS PROBLEMSTELLUNG UND ZIELSETZUNG 1. BEMERKUNGEN ZUM BEOBACHTUNGSGELÄNDE UND ZUM BEOBACHTUNGSMATERIAL 1.1 Das Beobachtungsgelände 1.2 Das Beobachtungsmaterial 2. HOMOGENITÄTSBETRACHTUNGEN 2.1 Temperatur 2.2 Niederschlag 2.3 Wind 2.4 Sonnenschein und Bewölkung 3. TEMPERATURVERHÄLTNISSE 3.1 Monats- und Jahreswerte 3.2 Tageswerte 3.3 Pentadenwerte 3.4 Häufigkeitsbetrachtungen 3.5 Interdiurne Veränderlichkeit 3.6 Der tägliche Gang 3.7 Vorkommen bestimmter Schwellenwerte 3.71 Frost- und Eistage 3.72 Sommer- und Tropentage 4. DER WASSERGEHALT DER LUFT 4.1 Monats- und Jahreswerte 4.2 Tageswerte 4.3 Häufigkeitsbetrachtungen 4.4 Interdiurne Veränderlichkeit 4.5 Der tägliche Gang 5. BEWÖLKUNGSVERHÄLTNISSE 5.1 Monats- und Jahreswerte 5.2 Tageswerte 5.3 Häufigkeitsbetrachtungen 5.4 Der tägliche Gang 5.5 Heitere und trübe Tage 5.6 Nebel 6. SONNENSCHEIN 6.1 Monats- und Jahreswerte 6.2 Tageswerte 6.3 Der tägliche Gang 7. NIEDERSCHLAGSVERHÄLTNISSE 7.1 Monats- und Jahreswerte 7.2 Niederschlagsbereitschaft 7.3 Tageswerte 7.4 Der tägliche Gang 7.5 Häufigkeitsbetrachtungen 7.6 Niederschlags- und Trockenperioden 7.7 Niederschlag und Wind· 7.8 Schneeverhältnisse 7.81 Schneefall und Schneedecke 7.82 Schneehöhe 7.9 Gewitter 8. WINDVERHÄLTNISSE 8.1 Windrichtung 8.2 Windgeschwindigkeit 8.21 Der jährliche Gang 8.22 Häufigkeitsbetrachtungen 8.23 Sturmtage und Windstillen 8.24 Der tägliche Gang 9.ZUSAMMENFASSUNG VERZEICHNIS DER TEXTTABELLEN VERZEICHNIS DER ABBILDUNGEN LITERATURVERZEICHNIS TABELLENANHANG
    Location: AWI Reading room
    Branch Library: AWI Library
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  • 8
    Call number: IASS 15.89494
    Type of Medium: Monograph available for loan
    Pages: Losebl.-Ausg.
    Edition: Stand: Oktober 2010
    ISBN: 9783768501828
    Language: German
    Branch Library: RIFS Library
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  • 9
    Monograph available for loan
    Monograph available for loan
    Madrid : Secc
    Call number: PIK N 456-17-90913
    Type of Medium: Monograph available for loan
    Pages: 536 Seiten
    Series Statement: Ministerio de Transportes Turismo Y Comunicaciones : Publicación Serie A 114
    Parallel Title: 1,1=6; 2,1=13 von Publicaciones / D / Ministerio del Aire, Subsecretaria de Aviación Civil, Servicio Meteorológico Nacional
    Language: Spanish
    Location: A 18 - must be ordered
    Branch Library: PIK Library
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  • 10
    Monograph available for loan
    Monograph available for loan
    Leningrad : Gidrometeorolog. Izd.
    Call number: MOP 33767
    Type of Medium: Monograph available for loan
    Pages: 663 S.
    Language: Russian
    Note: In kyrill. Schr., russ.
    Location: MOP - must be ordered
    Branch Library: GFZ Library
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  • 11
    Journal available for loan
    Journal available for loan
    Tübingen : Mohr Siebeck ; 1.1884 - 48.1931; N.F. 1.1932/33 - 10.1943/44(1945),3; 11.1948/49(1949) -
    Call number: ZS 22.95039
    Type of Medium: Journal available for loan
    Pages: Online-Ressource
    ISSN: 1614-0974 , 0015-2218 , 0015-2218
    Language: German , English
    Note: N.F. entfällt ab 57.2000. - Volltext auch als Teil einer Datenbank verfügbar , Ersch. ab 2000 in engl. Sprache mit dt. Hauptsacht.
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  • 12
    Call number: IASS 22.95033
    Type of Medium: Monograph available for loan
    Pages: 378 S , 225 mm x 135 mm
    ISBN: 3899421876 , 978-3-89942-187-3
    Series Statement: Edition panta rei
    Language: German
    Note: Zugl.: Marburg (Lahn), Univ., Habil.-Schr., 2004 u.d.T.: Gutmann, Mathias: Die Medialität des Erfahrens
    Branch Library: RIFS Library
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  • 13
  • 14
    Electronic Resource
    Electronic Resource
    Amsterdam : Elsevier
    Physics Letters B 294 (1992), S. 466-478 
    ISSN: 0370-2693
    Source: Elsevier Journal Backfiles on ScienceDirect 1907 - 2002
    Topics: Physics
    Type of Medium: Electronic Resource
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  • 15
    Electronic Resource
    Electronic Resource
    Amsterdam : Elsevier
    Physics Letters B 317 (1993), S. 474-484 
    ISSN: 0370-2693
    Source: Elsevier Journal Backfiles on ScienceDirect 1907 - 2002
    Topics: Physics
    Type of Medium: Electronic Resource
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  • 16
    Publication Date: 2022-12-05
    Description: The EUREF Permanent GNSS Network (EPN) provides a unique atmospheric dataset over Europe in the form of Zenith Total Delay (ZTD) time series. These ZTD time series are estimated independently by different analysis centers, but a combined solution is also provided. Previous studies showed that changes in the processing strategy do not affect trends and seasonal amplitudes. However, its effect on the temporal and spatial variations of the stochastic component of ZTD time series has not yet been investigated. This study analyses the temporal and spatial correlations of the ZTD residuals obtained from four different datasets: one solution provided by ASI (Agenzia Spaziale Italiana Centro di Geodesia Spaziale, Italy), two solutions provided by GOP (Geodetic Observatory Pecny, Czech Republic), and one combined solution resulting from the EPN’s second reprocessing campaign. We find that the ZTD residuals obtained from the three individual solutions can be modeled using a first-order autoregressive stochastic process, which is less significant and must be completed by an additional white noise process in the combined solution. Although the combination procedure changes the temporal correlation in the ZTD residuals, it neither affects its spatial correlation structure nor its time-variability, for which an annual modulation is observed for stations up to 1,000 km apart. The main spatial patterns in the ZTD residuals also remain identical. Finally, we compare two GOP solutions, one of which only differs in the modeling of non-tidal atmospheric loading at the observation level, and conclude that its modeling has a negligible effect on ZTD values.
    Language: English
    Type: info:eu-repo/semantics/article
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  • 17
    Publication Date: 2022-12-02
    Description: Temporal aliasing errors resulting from the undersampling of non-tidal atmospheric as well as oceanic mass variations constitute the largest limitation towards the retrieval of monthly gravity solutions based on GRACE and GRACE-FO satellite gravity missions. Their mitigation is thus a primary goal of current research. Unfortunately, the two-step co-parametrization approach proposed for application in Bender-type gravity retrieval scenario in Wiese et al. yields no added value for a single satellite pair. A detailed study of this parametrization strategy is carried out and it is shown that the reason for this is the flawed central assumption of the proposed method, that is that signals of different spatial wavelengths can be perfectly captured and separated with respect to their temporal extent. Based on this finding, we derive a multi-step self-de-aliasing approach (DMD) which aims to rectify the shortcoming of the Wiese et al. method specifically for the single-pair case while retaining its independence from background-model-based de-aliasing of non-tidal atmosphere and ocean (AO) signal components. The functionality and added value of this novel approach is validated within a set of numerical closed-loop simulations as well as in real GRACE and GRACE-FO data processing. The simulation results show that the DMD may improve the gravity retrieval performance in the high-degree spectrum by more than one order of magnitude if one aims to retrieve the full AOHIS (i.e. atmosphere, ocean, hydrology, ice, solid earth) signal, and by at least a factor 5 if a priori AO de-aliasing is applied. Simultaneously, the DMD is shown to degrade the retrieval of the low degrees, but it is also demonstrated that this issue can be mitigated by introducing a constraint into the processing scheme. The simulation results are widely confirmed by results obtained from applying the DMD to real GRACE/GRACE-FO data of the test years 2007, 2014 and 2019. The applicability of the DMD is further shown for Bender-type gravity retrieval. It is demonstrated that in case of a double-pair-based gravity retrieval this approach is at least equivalent to the Wiese et al. method.
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  • 18
    Publication Date: 2022-11-14
    Description: The Pan-African belts of Malawi contain a largely unexplored endowment of gem bearing pegmatites. We present U–Pb in zircon (LA-ICPMS) and Rb–Sr mineral isochron geochronological and isotope data from pegmatites across Malawi. The pegmatites contain tourmaline, beryl, aquamarine, zircon, amethyst and sunstone as gemstone species. Two zircon bearing pegmatites in southern Malawi intruded early in the Pan-African orogenic cycle at 719 ± 5 Ma and 729 ± 4 Ma and are associated with the emplacement of alkaline rocks that formed during an intra-continental rifting episode in the eastern part of former Rodinia. One further zircon pegmatite containing inherited zircon of a similar age (746 ± 44 Ma) was emplaced at 598 ± 15 Ma, after the assembly of Western and Eastern Gondwana and the formation of the East African Orogen (EAO). The majority of the analysed pegmatites, however, are significantly younger. The ∼550 Ma pegmatites were emplaced during the Kuunga Orogeny, correlating with the collision of northern and southern Gondwana cratonic entities. During a prolonged post-collisional period, possibly related to crustal collapse and extension, further gem-mineralised pegmatites formed at ∼520 ± 6 Ma and ∼500–485 Ma. The youngest pegmatite intruded in the southern Malawian Ntcheu area in the Middle Ordovician at ∼460 Ma. A large spread in 87Sr/86Sr initial isotopic ratios between 0.70556 and 0.79018 suggests a variety of magma sources for the Kuunga-related pegmatites with a variably strong crustal affinity.
    Language: English
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  • 19
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    In:  Marine Analytical Chemistry
    Publication Date: 2022-11-17
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  • 20
    Publication Date: 2022-12-14
    Description: Ilmenite and olivine megacrysts from the 89 Ma Monastery kimberlite (Kaapvaal Craton, South Africa) captured abundant and large melt inclusions containing quenched Si-Mg-rich melt, calcite, spinel, perovskite, phlogopite, and serpentine. Textural observations and 3D X-ray tomography of ilmenite and olivine megacrysts show melt inclusion shapes, sizes and distribution patterns indicative of melt capture during primary crystal growth near the base of the subcontinental lithospheric mantle (SCLM). Patterns supporting secondary melt injection along fractures or veins, such as planar arrays of melt inclusions, are absent. Melt inclusions in olivine, in some examples reaching the dimension of centimetres, likely were captured in skeletal voids forming in fast growing, up to decimetre-sized olivine megacrysts. These large melt inclusions commonly decrepitated, forming apophyses, radial fractures, and veins, along which residual volatile- and Si-Mg-rich melt was extracted. We attribute the decrepitation of melt inclusions in olivine to the rapidly increasing difference between the melt pressure in the inclusions, captured at mantle depth, and the decreasing confining stress to which the host olivines were exposed during magma ascent and after emplacement. In ilmenite, melt inclusions up to ∼ 6 mm in diameter remained commonly intact during the kimberlite ascent from its mantle source to the shallow crust. The quenched silicate melt in olivine- and ilmenite-hosted melt inclusions, in some places preserved as unaltered hydrous and CO3-bearing glass, shows systematic major element compositional variations that suggest that this melt formed by similar fractionation and depletion processes, irrespective of the hosting megacryst phase. Apparent modal variations in quenched silicate melt, calcite, and oxide contents suggest that the melt batches captured as inclusions in ilmenite and olivine either record different evolution stages in the megacryst magma, or document compositional heterogeneities in this magma at the time of megacryst growth.
    Language: English
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  • 21
    Publication Date: 2022-08-15
    Description: Ocean acidification (OA) has been identified as one of the major climate-change related threats, mainly due to its significant impacts on marine calcifiers. Among those are the calcareous green algae of the genus Halimeda that are known to be major carbonate producers in shallow tropical and subtropical seas. Hence, any negative OA impacts on these organisms may translate into significant declines in regional and global carbonate production. In this study, we compiled the available information regarding Halimeda spp. responses to OA (experimental, in situ), with special focus on the calcification responses, one of the most studied response parameters in this group. Furthermore, among the compiled studies (n = 31), we selected those reporting quantitative data of OA effects on algal net calcification in an attempt to identify potential general patterns of species- and/or regional-specific OA responses and hence, impacts on carbonate production. While obtaining general patterns was largely hampered by the often scarce number of studies on individual species and/or regions, the currently available information indicates species-specific susceptibility to OA, seemingly unrelated to evolutionary lineages (and associated differences in morphology), that is often accompanied by differences in a species� response across different regions. Thus, for projections of future declines in Halimeda-associated carbonate production, we used available regional reports of species-specific carbonate production in conjunction with experimental OA responses for the respective species and regions. Based on the available information, declines can be expected worldwide, though some regions harbouring more sensitive species might be more impacted than others.
    Repository Name: EPIC Alfred Wegener Institut
    Type: Article , NonPeerReviewed
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  • 22
    Publication Date: 2022-12-22
    Description: This chapter aims at introducing the reader to general concepts about the main forcings of the Mediterranean Sea, in terms of exchanges through the Strait of Gibraltar, and air-sea exchanges of heat, freshwater, and momentum. These forcings are also responsible for the peculiar characteristics of Mediterranean water masses. Therefore, the chapter continues with giving a general explanation on water mass analysis, and then it describes the properties and vertical and horizontal distributions of the main Mediterranean water masses. To conclude, the reader is introduced to the use of other (biogeochemical, and chemical) tracers of water masses, with a focus on the Mediterranean Sea.
    Type: Book chapter , PeerReviewed
    Format: text
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  • 23
    Publication Date: 2022-03-09
    Description: Strike-slip faults are classically associated with pull-apart basins where continental crust is thinned between two laterally offset fault segments. We propose a subsidence mechanism to explain the formation of a new type of basin where no substantial segment offset or syn-strike-slip thinning is observed. Such “flexural strike-slip basins” form due to a sediment load creating accommodation space by bending the lithosphere. We use a two-way coupling between the geodynamic code ASPECT and surface-processes code FastScape to show that flexural strike-slip basins emerge if sediment is deposited on thin lithosphere close to a strike-slip fault. These conditions were met at the Andaman Basin Central fault (Andaman Sea, Indian Ocean), where seismic reflection data provide evidence of a laterally extensive flexural basin with a depocenter located parallel to the strike-slip fault trace.
    Language: English
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  • 24
    Publication Date: 2022-03-09
    Description: Carbonatites host some unique ore deposits, especially REE, and fractional crystallization might be a potentially powerful mechanism for control enrichment of carbonatitic magmas by these metals to economically significant levels. At present, data on distribution coefficients of REE during fractional crystallization of carbonatitic melts at volcanic conditions are extremely scarce. Here we present an experimental study of REE partitioning between carbonatitic melts and calcite in the system CaCO3-Na2CO3 with varying amounts of P2O5, F, Cl, SiO2, SO3 at 650–900 °C and 100 MPa using cold-seal pressure vessels and LA-ICP-MS. The presence of phosphorus in the system generally increases the distribution coefficients but its effect decreases with increasing concentration. The temperature factor is high: at 770–900 °C DREE ≥ 1, while at lower temperatures DREE become below unity. Silicon also promotes the fractionation of REE into calcite, while sulfur contributes to retention of REE in the melt. Our results imply that calcite may impose significant control upon REE fractionation at the early stages of crystallization of carbonatitic magmas and might be a closest proxy for monitoring the REE content in initial melt.
    Language: English
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  • 25
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    In:  Earth and Planetary Science Letters
    Publication Date: 2022-03-09
    Description: The birth and expansion of continental plateaus exert a strong control on our planet's climate and the distribution and evolution of its biodiversity. It has been proposed that the Tibetan Plateau has been steadily growing by southward expansion. Here we demonstrate that the shape of the southeastern margin of the plateau has remained unchanged for the last 10 Myr despite vast amounts of exhumation. Our finding is based on a new, high-resolution thermochronological dataset from the deep gorges of the Salween and Mekong rivers, which we interpret using a physics-based model combined with an optimization method. We show that our scenario also agrees with a wide range of other, independent geological and geophysical data. This finding demonstrates that plateau margins can reach large-scale topographic steady-state between outward growth and surface erosion, which has important implications for our understanding of the evolution of Earth's climate and biodiversity in the recent geological past.
    Language: English
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  • 26
    Publication Date: 2022-03-09
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  • 27
    Publication Date: 2022-03-09
    Description: Sulfidated nanoscale zerovalent iron (S-nZVI) exhibits low anoxic oxidation and high reactivity towards many chlorinated hydrocarbons (CHCs). However, nothing is known about S-nZVI reactivity once exposed to complex CHC mixtures, a common feature of CHC plumes in the environment. Here, three S-nZVI materials with varying iron sulfide (mackinawite, FeSm) shell thickness and crystallinity were exposed to groundwater containing a complex mixture of chlorinated ethenes, ethanes, and methanes. CHC removal trends yielded pseudo-first order rate constants (kobs) that decreased in the order: trichloroethene 〉 trans-dicloroethene 〉 1,1-dichlorethene 〉 trichloromethane 〉 tetrachloroethene 〉 cis-dichloroethene 〉 1,1,2-trichloroethane, for all S-nZVI materials. These kobs trends showed no correlation with CHC reduction potentials based on their lowest unoccupied molecular orbital energies (ELUMO) but absolute values were affected by the FeSm shell thickness and crystallinity. In comparison, nZVI reacted with the same CHCs groundwater, yielded kobs that linearly correlated with CHC ELUMO values (R2 = 0.94) and that were lower than S-nZVI kobs. The CHC selectivity induced by sulfidation treatment is explained by FeSm surface sites having specific binding affinities towards some CHCs, while others require access to the metallic iron core. These new insights help advance S-nZVI synthesis strategies to fit specific CHC treatment scenarios.
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  • 28
    Publication Date: 2022-03-09
    Description: The LArge-scale Reservoir Simulator (LARS) has been previously developed to study hydrate dissociation in hydrate-bearing systems under in-situ conditions. In the present study, a numerical framework of equations of state describing hydrate formation at equilibrium conditions has been elaborated and integrated with a numerical flow and transport simulator to investigate a multi-stage hydrate formation experiment undertaken in LARS. A verification of the implemented modeling framework has been carried out by benchmarking it against another established numerical code. Three-dimensional (3D) model calibration has been performed based on laboratory data available from temperature sensors, fluid sampling, and electrical resistivity tomography. The simulation results demonstrate that temperature profiles, spatial hydrate distribution, and bulk hydrate saturation are consistent with the observations. Furthermore, our numerical framework can be applied to calibrate geophysical measurements, optimize post-processing workflows for monitoring data, improve the design of hydrate formation experiments, and investigate the temporal evolution of sub-permafrost methane hydrate reservoirs.
    Language: English
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  • 29
    Publication Date: 2022-03-09
    Description: Wuhan (China) is facing severe consolidation subsidence of soft soil and karst collapse hazards. To quantitatively explore the extent and causes of land subsidence in Wuhan, we performed multitemporal interferometry (MTI) analysis using synthetic aperture radar (SAR) data from the TerraSAR-X satellite from 2013 to 2017 and the Sentinel-1A satellite from 2015 to 2017. MTI results reveal four major subsidence zones in Wuhan, namely, Hankou (exceeding −6 cm/yr), Xudong-Qingshan (−3 cm/yr), Baishazhou-Jiangdi (−3 cm/yr), and Jianshe-Yangluo (−2 cm/yr). Accuracy assessment using 106 levelling benchmarks and cross-validation between the two InSAR-based results indicate an overall root-mean-square error (RMSE) of 2.5 and 3.1 mm/yr, respectively. Geophysical and geological analyses suggest that among the four major subsiding zones, Hankou, Xudong-Qingshan, and Jianshe-Yangluo are located in non-karstic soft soil areas, where shallow groundwater (〈 30 m) declines driven by engineering dewatering and industrial water depletion contribute directly to soft soil compaction. Subsidence in the Baishazhou-Jiangdi zone develops in the karst terrain with abundant underground caves and fissures, which are major natural factors for gradual subsidence and karst collapse. Spatial variation analysis of the geological conditions indicates that the stage of karst development plays the most important role in influencing kart subsidence, followed by municipal construction, proximity to major rivers, and overlying soil structure. Moreover, land subsidence in this zone is affected more via coupling effects from multiple factors. Risk zoning analysis integrating subsidence horizontal gradient, InSAR deformation rates, and municipal construction density show that the high-risk areas in Wuhan are mainly distributed in the Tianxingzhou and Baishazhou-Jiangdi zone, and generally spread along the metro lines.
    Language: English
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  • 30
    Publication Date: 2022-03-09
    Description: Climate change and rapid expansion of urban areas are expected to increase pluvial flood hazard and risk in the near future, and particularly so in large developed areas and cities. Therefore, large-scale and high-resolution pluvial flood hazard mapping is required to identify hotspots where mitigation measures may be applied to reduce flood risk. Depressions or low points in urban areas where runoff volumes can be stored are prone to pluvial flooding. The standard approach based on estimating synthetic design hyetographs assumes, in a given depression, that the T-year design storm generates the T-year pluvial flood. In addition, urban areas usually include several depressions even linked or nested that would require distinct design hyetographs instead of using a unique synthetic design storm. In this paper, a stochastic methodology is proposed to address the limitations of this standard approach, developing large-scale ∼ 2 m-resolution pluvial flood hazard maps in urban areas with multiple depressions. The authors present an application of the proposed approach to the city of Pamplona in Spain (68.26 km2). The Safer_RAIN fast-processing algorithm based on digital elevation models (DEMs) is compared with the IBER 2D hydrodynamic model in four real storms by using 10-min precipitation fields. Precipitation recorded at rainfall-gauging stations was merged with continuous fields obtained from a meteorological radar station. Given the hydrostatic limitations of Safer_RAIN, the benchmarking results are adequate in terms of water depths in depressions. A long set of 10 000 synthetic storms that maintain the statistical properties of observations in Pamplona is generated. Safer_RAIN is used to simulate runoff response, and filling and spilling processes, in depressions for the 10 000 synthetic storms, obtaining the probability distribution of water depths in each cell. Maps of pluvial flood hazards are developed in the Pamplona metropolitan area for 10 return periods in the range from two to 500 years from such pixel-based series of simulated water depths. Bivariate return-period curves are estimated in a set of cells, showing that several storms can generate a given T-year pluvial flood with an increasing precipitation with storm duration that depends on the draining catchment soil characteristics. The methodology proposed is useful to develop maps of pluvial flood hazards in large multi-depression urban areas in reasonable computation times, identifying the main pluvial flood hotspots.
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  • 31
    Publication Date: 2022-04-08
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  • 32
    Publication Date: 2022-04-08
    Description: The real-time Earth orientation parameters (EOP) estimation is needed for many applications, including precise tracking and navigation of interplanetary spacecraft, climate forecasting, and disaster prevention. However, the complexity and time-consuming data processing always lead to time delays. Accordingly, several methods were developed and applied for the EOP prediction. However, the accuracy of EOP prediction is still not satisfactory even for prediction of just a few days in the future. Therefore, new methods or a combination of the existing approaches can be investigated to improve the predicted EOP. To assess the various EOP prediction capabilities, the international Earth rotation and reference systems service (IERS) established the working group on the 2nd Earth Orientation Parameters Prediction Comparison Campaign (2nd EOP PCC). Our EOP prediction team provides the full set of EOP predictions weekly for one year ahead. In this campaign, we used the SSA+Copula method and the empirical free core nutation (FCN) model (named B16) for Earth rotation parameters and celestial pole offsets (CPO) prediction, respectively. Additionally, we investigated new prediction techniques and different input data set; as an example, the Convolutional Neural Networks (CNN) is introduced to model and predict the short-term EOP. Our preliminary results illustrate an improvement in EOP prediction compared to the current EOP prediction methods, especially on CPO.
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  • 33
    Publication Date: 2022-04-08
    Description: Despite its high seismogenic potential, the details of the seismogenic processes of Zagros Simply Folded Belt (SFB) remains debated. Three large earthquakes (Mw 7.3, 5.9, and 6.3) struck in the Lurestan arc of the Zagros SFB in 2017 and 2018. The sequence was recorded by seismic stations at regional, and teleseismic distances. Coseismic surface displacements, measured by Sentinel-1A/B satellites, provide additional data and a unique opportunity to study these earthquakes in detail. Here, we complement previous studies of the coseismic slip distribution of the 12 November 2017 Mw 7.3 Ezgeleh earthquake by a detailed analysis of its aftershocks, and we analyzed the rupture process of the two interrelated earthquakes (25 August 2018 Mw 5.9 Tazehabad and the 25 November 2018 Mw 6.3 Sarpol-e Zahab earthquakes). We model the surface displacements obtained from Interferometric Synthetic Aperture Radar (InSAR) measurements and seismic records. We conduct non-linear probabilistic optimizations based on joint InSAR and seismic data to obtain finite-fault rupture of these earthquakes. The Lurestan arc earthquakes were followed by a sustained aftershock activity, with 133 aftershocks exceeding Mn 4.0 until December 30, 2019. We rely on the permanent seismic networks of Iran and Iraq to relocate ∼700 Mn 3 + events and estimate moment tensor solutions for 85 aftershocks down to Mw 4.0. The 2017 Ezgeleh earthquake has been considered to activate a low-angle (∼17°) dextral-thrust fault at the depth of 10–20 km. However, most of its aftershocks have shallow centroid depths (8–12 km). The joint interpretation of finite source models, moment tensor, and hypocentral location indicate that the 2018 Tazehabad and Sarpol-e Zahab earthquakes ruptured different strike-slip structures, providing evidence for the activation of the sinistral and dextral strike-slip faults, respectively. The deformation in the Lurestan arc is seismically accommodated by a complex fault system involving both thrust and strike-slip faults. Knowledge about the deformation characteristics is important for the understanding of crustal shortening, faulting, and hazard and risk assessment in this region.
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  • 34
    Publication Date: 2022-04-08
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  • 35
    Publication Date: 2022-04-08
    Description: Elliptical sulfate-rich features, stained red by the presence of iron oxides, are set within permafrost and carbonate rock at Borup Fiord Pass in the Canadian High Arctic. These features, which vary in diameter from ∼0.5 to 3 m, exhibit the co-localization of sulfur (S) and iron (Fe) minerals, with S and Fe both preserved in multiple oxidation states. Through application of x-ray diffraction (XRD) and Raman microspectroscopy, we find that these features appear to encapsulate central cores with abundant pyrite while S0, gypsum, and iron-bearing secondary minerals such as jarosite, goethite, and hematite have formed from oxidative weathering of the pyrite. These features appear similar to terrestrial gossans, mineral features representative of weathered sulfide ores in the near-surface. We use Raman microspectroscopy and scanning transmission x-ray microscopy (STXM) to show that organic carbon is associated with the minerals within these features. The origin of this carbon remains enigmatic; however, we consider the possibility that this carbon, along with etching of the pyrite grains and accumulation of encrusted filaments detected in the features, may be indicative of preserved biological activity during alteration of the pyrite. We also consider how such geological sulfide emplacements and their weathered surface expressions may provide a target for future surface and remote sensing studies of Mars and in the search for extraterrestrial life.
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  • 36
    Publication Date: 2022-04-08
    Description: The Pan-Eurasian Experiment (PEEX) Science Plan, released in 2015, addressed a need for a holistic system understanding and outlined the most urgent research needs for the rapidly changing Arctic-boreal region. Air quality in China, together with the long-range transport of atmospheric pollutants, was also indicated as one of the most crucial topics of the research agenda. These two geographical regions, the northern Eurasian Arctic-boreal region and China, especially the megacities in China, were identified as a “PEEX region”. It is also important to recognize that the PEEX geographical region is an area where science-based policy actions would have significant impacts on the global climate. This paper summarizes results obtained during the last 5 years in the northern Eurasian region, together with recent observations of the air quality in the urban environments in China, in the context of the PEEX programme. The main regions of interest are the Russian Arctic, northern Eurasian boreal forests (Siberia) and peatlands, and the megacities in China. We frame our analysis against research themes introduced in the PEEX Science Plan in 2015. We summarize recent progress towards an enhanced holistic understanding of the land–atmosphere–ocean systems feedbacks. We conclude that although the scientific knowledge in these regions has increased, the new results are in many cases insufficient, and there are still gaps in our understanding of large-scale climate–Earth surface interactions and feedbacks. This arises from limitations in research infrastructures, especially the lack of coordinated, continuous and comprehensive in situ observations of the study region as well as integrative data analyses, hindering a comprehensive system analysis. The fast-changing environment and ecosystem changes driven by climate change, socio-economic activities like the China Silk Road Initiative, and the global trends like urbanization further complicate such analyses. We recognize new topics with an increasing importance in the near future, especially “the enhancing biological sequestration capacity of greenhouse gases into forests and soils to mitigate climate change” and the “socio-economic development to tackle air quality issues”.
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  • 37
    Publication Date: 2022-03-24
    Description: Glacial isostatic adjustment is largely governed by the rheological properties of the Earth's mantle. Large mass redistributions in the ocean–cryosphere system and the subsequent response of the viscoelastic Earth have led to dramatic sea level changes in the past. This process is ongoing, and in order to understand and predict current and future sea level changes, the knowledge of mantle properties such as viscosity is essential. In this study, we present a method to obtain estimates of mantle viscosities by the assimilation of relative sea level rates of change into a viscoelastic model of the lithosphere and mantle. We set up a particle filter with probabilistic resampling. In an identical twin experiment, we show that mantle viscosities can be recovered in a glacial isostatic adjustment model of a simple three-layer Earth structure consisting of an elastic lithosphere and two mantle layers of different viscosity. We investigate the ensemble behaviour on different parameters in the following three set-ups: (1) global observations data set since last glacial maximum with different ensemble initialisations and observation uncertainties, (2) regional observations from Fennoscandia or Laurentide/Greenland only, and (3) limiting the observation period to 10 ka until the present. We show that the recovery is successful in all cases if the target parameter values are properly sampled by the initial ensemble probability distribution. This even includes cases in which the target viscosity values are located far in the tail of the initial ensemble probability distribution. Experiments show that the method is successful if enough near-field observations are available. This makes it work best for a period after substantial deglaciation until the present when the number of sea level indicators is relatively high.
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  • 38
    Publication Date: 2022-03-21
    Description: Mantle metasomatism is an important process in subduction zones in which fluids from the dehydrating oceanic slab interact with the overlying upper mantle resulting in a chemical alteration of the mantle. Consequently, this fluid-rock interaction may influence the mantle rock's physical properties such as the deformation behavior. In order to study element redistribution during mantle metasomatism in the laboratory, we used the simplified model reaction olivine + quartz = orthopyroxene, where olivine acts as representative for the upper mantle and quartz as proxy for the metasomatizing agent. We conducted piston-cylinder experiments at 1.5 GPa and 950 to 1400 °C, lasting between 48 and 288 h, on samples containing a mixture of quartz and one set of synthesized forsterite samples doped with either Co, Ni, Mn, or Zn. Additionally, we tested the influence of either nominally anhydrous or hydrous experimental conditions on the chemical distribution of the respective dopant element by using either crushable alumina or natural CaF2 as pressure medium. Results of the chemical analyses of the recovered samples show dopant specific partitioning between doped forsterite and orthopyroxene independent of the confining pressure medium; except for the runs in which Ni-doped forsterite samples were used. The observed Ni- and Co-enrichment in forsterite samples may be used to identify mantle rocks that underwent mantle metasomatism in nature.
    Language: English
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  • 39
    Publication Date: 2022-03-29
    Description: To mark the 20th anniversary of Natural Hazards and Earth System Sciences (NHESS), an interdisciplinary and international journal dedicated to the public discussion and open-access publication of high-quality studies and original research on natural hazards and their consequences, we highlight 11 key publications covering major subject areas of NHESS that stood out within the past 20 years. The papers cover all the topics contemplated in the European Geosciences Union (EGU) Division on Natural Hazards including dissemination, education, outreach and teaching. The selected articles thus represent excellent scientific contributions in the major areas of natural hazards and risks and helped NHESS to become an exceptionally strong journal representing interdisciplinary areas of natural hazards and risks. At its 20th anniversary, we are proud that NHESS is not only used by scientists to disseminate research results and novel ideas but also by practitioners and decision-makers to present effective solutions and strategies for sustainable disaster risk reduction.
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  • 40
    Publication Date: 2022-03-29
    Description: With the completion of Chinese BeiDou Navigation Satellite System (BDS), the world has begun to enjoy the Positioning, Navigation, and Timing (PNT) services of four Global Navigation Satellite Systems (GNSS). In order to improve the GNSS performance and expand its applications, Low Earth Orbit (LEO) Enhanced Global Navigation Satellite System (LeGNSS) is being vigorously advocated. Combined with high-, medium-, and low- earth orbit satellites, it can improve GNSS performance in terms of orbit determination, Precise Point Positioning (PPP) convergence time, etc. This paper comprehensively reviews the current status of LeGNSS, focusing on analyzing its advantages and challenges for precise orbit and clock determination, PPP convergence, earth rotation parameter estimation, and global ionosphere modeling. Thanks to the fast geometric change brought by LEO satellites, LeGNSS is expected to fundamentally solve the problem of the long convergence time of PPP without any augmentation. The convergence time can be shortened within 1 minute if appropriate LEO constellations are deployed. However, there are still some issues to overcome, such as the optimization of LEO constellation as well as the real time LEO precise orbit and clock determination.
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  • 41
    Publication Date: 2022-03-27
    Description: Raw, SEGY and other supplementary data are presented from the seismic refraction / wide-angle reflection profile, TTZ-South, in Poland and Ukraine. The purpose of this 550 km long seismic profile was to reveal the lithospheric structure along the Teisseyre-Tornquist Zone (TTZ), a major geophysical boundary in Europe.
    Language: English
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  • 42
    Publication Date: 2022-03-30
    Language: English
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  • 43
    Publication Date: 2022-03-30
    Language: English
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  • 44
    Publication Date: 2022-04-13
    Description: The Pacific Northwest (PNW) has substantial earthquake risk, both due to the offshore Cascadia megathrust fault but also other fault systems that produce earthquakes under the region's population centers. Forecasts of aftershocks following large earthquakes are thus highly desirable and require statistical models of a catalog of the PNW’s past earthquakes and aftershock sequences. This is complicated by the fact that the PNW contains multiple tectonic regimes hypothesized to have different aftershock dynamics as well as two types of earthquake clustering (aftershock sequences and swarms). The Epidemic-Type Aftershock Sequence (ETAS) model is a top-performing spatiotemporal point process model which describes the dynamics of earthquakes and aftershocks in a seismic region using a set of parameters. Typically, maximum likelihood estimation is used to fit ETAS to an earthquake catalog; however, the ETAS likelihood suffers from flatness near its optima, parameter correlation and numerical instability, making likelihood-based estimates less reliable. We present a Bayesian procedure for ETAS estimation, such that parameter estimates and uncertainty can be robustly quantified, even for small and complex catalogs like the PNW. The procedure is conditional on knowing which earthquakes triggered which aftershocks; this latent structure and the ETAS parameters are estimated iteratively. The procedure uses a Gibbs sampler to conditionally estimate the posterior distributions of each part of the model. We simulate several synthetic catalogs and test the modelling procedure, showing well-mixed posterior distributions centered on true parameter values. We also use the procedure to model the continental PNW, using a new catalog formed by algorthmically combining US and Canadian data sources and then, identifying and removing earthquake swarms. While MLEs are unstable and depend on both the optimization procedure and its initial values, Bayesian estimates are insensitive to these choices. Bayesian estimates also fit the catalog better than do MLEs. We use the Bayesian method to quantify the uncertainty in ETAS estimates when including swarms in the model or modelling across different tectonic regimes, as well as from catalog measurement error. Seismicity rate estimates and the earthquake forecasts they yield vary spatially and are usually represented as heat maps. While the visualization literature suggests that displaying forecast uncertainty improves understanding in users of forecast maps, research on uncertainty visualization (UV) is missing from earthquake science. In a pre-registered online experiment, we test the effectiveness of three UV techniques for displaying uncertainty in aftershock forecasts. Participants completed two map-reading tasks and a comparative judgment task, which demonstrated how successful a visualization was in reaching two key communication goals: indicating where many aftershocks and no aftershocks are likely (sure bets) and where the forecast is low but the uncertainty is high enough to imply potential risk (surprises). All visualizations performed equally well in the goal of communicating sure bet situations. But the visualization mapping the lower and upper bounds of an uncertainty interval was substantially better than the other map designs at communicating potential surprises. We discuss the implications of these experimental results for the communication of uncertainty in aftershock forecast maps.
    Language: English
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  • 45
    Publication Date: 2022-02-16
    Description: Carbonate has often been identified in aqueous carbonic inclusions in spodumene-bearing and other pegmatites, but its origin remains unclear. Here, the conditions at which carbonate and hydrogen carbonate can be generated from spodumene, CO2 and H2O, were studied using a hydrothermal diamond-anvil cell (HDAC) and Raman spectroscopy. In all experiments, spodumene persisted in aqueous carbonic solution up to the maximum temperature (600 to 800 °C). Heating of hydrogen carbonate/oxalate solutions produced CO2- and HCO−3-rich peralkaline fluids, which resulted in strong corrosion of spodumene (and polylithionite-trilithionite) and, in one run, formation of zabuyelite [Li2(CO3)] crystals at low temperatures. The experiments indicate that the reaction of spodumene with CO2 and H2O requires a peralkaline fluid to proceed rapidly. In addition, they show that spodumene crystallizes upon the heating of quartz, muscovite, and aqueous lithium carbonate solution. We conclude that if the aqueous fluid was rich in alkali hydrogen carbonate, zabuyelite in fluid inclusions in pegmatites can form both via a subsolidus reaction of CO2-bearing fluid inclusion with the spodumene host or by trapping a peralkaline fluid early in the evolution of simple or complex pegmatites. The results of our experimental study strengthen the conclusion that, although counterintuitive, hydrogen carbonate-rich peralkaline fluids may be involved in the evolution of peraluminous granitic pegmatites, in which peralkaline minerals are normally absent or very rare.
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  • 46
    Publication Date: 2022-02-16
    Description: Knowledge of groundwater flow is of high relevance for groundwater management and the planning of different subsurface utilizations such as deep geothermal facilities. While numerical models can help to understand the hydrodynamics of the targeted reservoir, their predictive capabilities are limited by the assumptions made in their set up. Among others, the choice of appropriate hydraulic boundary conditions, adopted to represent the regional to local flow dynamics in the simulation run, is of crucial importance for the final modelling result. In this publication we present the hydrogeological models to obtain results to quantify how and to which degree different upper hydraulic boundary conditions and vertical cross boundary fluid movement influence the calculated deep fluid conditions Therefore, we take the central Upper Rhine Graben area as a natural laboratory. The presented three models are set up with different sets of boundary conditions. The Reference Model uses the topography as upper hydraulic pressure surface of 0 kPa. In model S1, a subdued replica of the topography, which was built on the base of hydraulic head measurements is applied as the upper hydraulic boundary condition and in model S2 vertical cross boundary flow is implemented. Based on our results, we illustrate in the landing paper that for the Upper Rhine Graben specific characteristics of the flow field are robust and insensitive to the choice of imposed hydraulic boundary conditions, while specific local characteristics are more sensitive. Accordingly, these robust features characterizing the first order groundwater flow dynamics in the Upper Rhine Graben include: (i) a regional groundwater flow component descending from the graben shoulders to rise at its centre; (ii) infiltration of fluids across the graben shoulders, which locally rise along the main border faults; (iii) the presence of heterogeneous hydraulic potentials at the rift shoulders. The configuration of the adopted boundary conditions influence primarily calculated flow velocities and the absolute position of the upflow axis within the graben sediments. In addition, the choice of upper hydraulic boundary conditions exerts a direct control on the evolving local flow dynamics, with the degree of influence gradually decreasing with increasing depth. With respect to regional flow modelling of basin hosted, deep water resources, the main conclusions derived from this study are: (i) the often considered water table as an exact replica of the model topography (Reference Model) likely introduces a source of error in the simulations in regional hydraulic modelling approaches. Here, we show that these errors can be minimized by making use of a water table as upper boundary condition derived from available hydraulic head measurements (model S1). If the study area is part of a supra-regional flow system - like the central Upper Rhine Graben is part of the whole Upper Rhine Graben - the in- and outflow across vertical boundaries need to be considered (model S2).
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  • 47
    Publication Date: 2022-02-16
    Description: The Younger Dryas (YD) is a roughly 1,100-year cold period marking the end of the last glaciation. Climate modelling for northern Europe indicates high summer temperatures and strong continentality. In eastern Europe, the scale of temperature variation and its influence on ecosystems is weakly recognised. Here, we present a multi-proxy reconstruction of YD conditions from Lake Gościąż (central Poland). The decadal-resolution analysis of its annually varved sediments indicates an initial decrease in Chironomidae-inferred mean July air temperature followed by steady warming. The pollen-inferred winter-to-summer temperature amplitude and annual precipitation is highest at the Allerød/YD transition and the early YD (ca. 12.7–12.4 ky cal BP) and YD/Holocene (11.7–11.4 ka cal BP) transition. Temperature and precipitation were the main reasons for lake level fluctuations as reflected in the planktonic/littoral Cladocera ratio. The lake’s diatom-inferred total phosphorus decreased with increasing summer temperature from about mid YD. Windy conditions in the early YD until ∼12.3 ka cal BP caused water mixing and a short-lived/temporary increase in nutrient availability for phytoplankton. The Chironomidae-inferred summer temperature and pollen inferred summer temperature, winter temperature and annual precipitation herein are one of only a few in eastern Europe conducted with such high resolution.
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  • 48
    Publication Date: 2022-02-16
    Description: Fluid inclusions in pegmatite minerals were studied using Raman spectroscopy to determine the carbon species. Carbon dioxide is very abundant in the aqueous liquid and vapor phases. Occasionally, CH4 was found in the vapor. In the aqueous liquid, HCO−3 was detected in fluid inclusions in tantalite-(Mn) from the Morrua Mine and in late-stage quartz from the Muiâne pegmatite and the Naipa Mine, all in the Alto Ligonha District, Mozambique. Moreover, we observed a carbonate (calcite group) in fluid inclusions in garnet from the Naipa Mine and in beryl from the Morrua Mine, both in the Alto Ligonha District, Mozambique, and a calcite-group carbonate and whewellite [CaC2O4∙H2O] in fluid inclusions in topaz from Khoroshiv, Ukraine. The occurrence of oxalate is interpreted to be due to a reaction of some form of carbon (possibly CO or bitumen) with a peralkaline fluid. Our results support the hypothesis that, although counterintuitive, hydrogen carbonate-rich peralkaline fluids may locally be involved in the evolution of peraluminous granitic pegmatites, in which peralkaline minerals are normally absent or very rare.
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  • 49
    Publication Date: 2022-02-16
    Description: One of the most fundamental questions in ecology is how many species inhabit the Earth. However, due to massive logistical and financial challenges and taxonomic difficulties connected to the species concept definition, the global numbers of species, including those of important and well-studied life forms such as trees, still remain largely unknown. Here, based on global ground-sourced data, we estimate the total tree species richness at global, continental, and biome levels. Our results indicate that there are ∼73,000 tree species globally, among which ∼9,000 tree species are yet to be discovered. Roughly 40% of undiscovered tree species are in South America. Moreover, almost one-third of all tree species to be discovered may be rare, with very low populations and limited spatial distribution (likely in remote tropical lowlands and mountains). These findings highlight the vulnerability of global forest biodiversity to anthropogenic changes in land use and climate, which disproportionately threaten rare species and thus, global tree richness.
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  • 50
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    In:  Protokoll über das 29. Schmucker-Weidelt-Kolloquium für Elektromagnetische Tiefenforschung: virtuell, 29. September - 1. Oktober 2021
    Publication Date: 2022-02-22
    Language: German
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  • 51
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    In:  Protokoll über das 29. Schmucker-Weidelt-Kolloquium für Elektromagnetische Tiefenforschung: virtuell, 29. September - 1. Oktober 2021
    Publication Date: 2022-02-22
    Description: We report a new improvement in self-organized maps for geological interpretation of geophysical data. By using a multi-geophysical dataset recorded in the mining area of Thuringia, Germany, we show the results of replacing the typical feature analysis by a principal component analysis. By performing a transformation of the dataset according to a few of the principal components, we obtain a more detailed representation of the local geology than previous works. Results also show a significant improvement in processing time, while also minimizing influence of user´s interpretation.
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  • 52
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    In:  Protokoll über das 29. Schmucker-Weidelt-Kolloquium für Elektromagnetische Tiefenforschung: virtuell, 29. September - 1. Oktober 2021
    Publication Date: 2022-02-22
    Description: The Songliao Block is located in the eastern part of the Central Asian Orogenic Belt. Its creation and evolution are believed to be related to the closure of the Paleo-Asian and Mongol-Okhotsk oceans, and to the subduction of the Paleo-Pacific Ocean. The deep seismic reflection profiles showed that there are sloping mantle reflections below the Songliao Block, which are suspected to be the result of the convergence of three tectonic domains. However, it is still not clear the current structural form of the Songliao Block is caused by the direct action or not of the tectonic systems. This work used 138 broadband magnetotelluric stations to obtain a three-dimensional electrical structural model of the northern Songliao Block. The results showed there are orthogonal network fault systems, faulted basins, igneous rocks. And the Lindian fault depression is the center of the asthenospheric upwelling, the shallowest up to 45 km. Combined with evidence from seismic studies, we proposed that the superposition of tectonic systems may have produced weak tectonic zones. These zones provided channels for the later upward movement of fluids and melt, likely due to hydrous upwellings caused by the subduction of the Paleo-Pacific system.
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  • 53
    facet.materialart.
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    In:  Protokoll über das 29. Schmucker-Weidelt-Kolloquium für Elektromagnetische Tiefenforschung: virtuell, 29. September - 1. Oktober 2021
    Publication Date: 2022-02-22
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  • 54
    facet.materialart.
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    In:  Protokoll über das 29. Schmucker-Weidelt-Kolloquium für Elektromagnetische Tiefenforschung: virtuell, 29. September - 1. Oktober 2021
    Publication Date: 2022-02-24
    Language: English
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  • 55
    facet.materialart.
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    In:  Protokoll über das 29. Schmucker-Weidelt-Kolloquium für Elektromagnetische Tiefenforschung: virtuell, 29. September - 1. Oktober 2021
    Publication Date: 2022-02-24
    Language: English
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  • 56
    Publication Date: 2022-04-11
    Description: The evolution of chemical bonding in ferropericlase, (Mg,Fe)O, with pressure may affect the physical and chemical properties of the Earth’s lower mantle. Here, we report highpressure optical absorption spectra of single-crystalline ferropericlase ((Mg0.87Fe0.13)O) up to 135 GPa. Combined with a re-evaluation of published partial fluorescence yield X-ray absorption spectroscopy data, we show that the covalency of the Fe−O bond increases with pressure, but the iron spin transition at 57−76.5 GPa reverses this trend. The qualitative crossover in chemical bonding suggests that the spin-pairing transition weakens the Fe−O bond in ferropericlase. We find, that the spin transition in ferropericlase is caused by both the increase of the ligand field-splitting energy and the decrease in the spin-pairing energy of high-spin Fe2+.
    Language: English
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  • 57
    Publication Date: 2022-04-11
    Description: he competition between the impact of inherited weaknesses and plate kinematics determines the location and style of deformation during rifting, yet the relative impacts of these ‘internal’ and ‘external’ factors remain poorly understood, especially in 3D. In this study, we used brittle-viscous analogue models to assess how multiphase rifting, that is changes in plate divergence rate or direction, and the presence and orientation of weaknesses in the competent mantle and crust, influences rift evolution. We find that the combined reactivation of mantle and crustal weaknesses without any kinematic changes already creates complex rift structures. Divergence rates affect the strength of the weak lower crustal layer and hence the degree of mantle-crustal coupling; slow rifting decreases coupling, so that crustal weaknesses can dominate deformation localisation and surface structures, whereas fast rifting increases coupling and deformation related to mantle weaknesses can have a dominant surface expression. Through a change from slow to fast rifting mantle-related deformation can overprint structures that previously formed along (differently oriented) crustal weaknesses. Conversely, a change from fast to slow rifting may shift deformation from mantle-controlled towards crust-controlled. When changing divergence directions, structures from the first rifting phase may control where subsequent deformation occurs, but only when they are sufficiently well developed. We furthermore place our results in a larger framework of brittle-viscous rift modelling results from previous experimental studies, showing the importance of general lithospheric layering, divergence rate, the type of deformation in the mantle, and finally upper crustal structural inheritance. The interaction between these parameters can produce a variety of deformation styles that may, however, lead to comparable end products. Therefore, careful investigation of the distribution of strain localisation, and to an equal extent of basin depocenter locations over time is required to properly determine the evolution of complex rift systems, providing an incentive to revisit various natural examples.
    Language: English
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  • 58
    Publication Date: 2022-04-11
    Description: The Kiaka orogenic gold deposit (Burkina Faso), located in the Paleoproterozoic domain of the West African Craton, is characterized by a two-stage gold mineralization hosted in volcano-sedimentary metamorphic rocks that was formed during the Eoeburnean (2.20–2.13 Ga) and Eburnean (2.13–2.05 Ga) orogenic cycles. These two stages include an early disseminated low-grade gold mineralization and a late vein-hosted high-grade gold mineralization. Paragenetic studies indicate that the first gold stage was coeval with the deposition of hydrothermal tourmaline. The aim of this paper is twofold: (i) to determine the processes responsible for deposition of the economic disseminated gold mineralization and (ii) to identify the source of the mineralizing fluids. For this purpose, we performed an in situ study on tourmaline by combining electron probe microanalysis and secondary ion mass spectrometry measurements of boron isotopes. Hydrothermal tourmaline hosted in metamafic volcanic rocks and metagreywackes has a dravite composition but shows different δ11B values falling within the two intervals of − 25.1 to − 22.0‰ and − 19.6 to − 15.1‰, respectively. Our results suggest that tourmaline formed from a distal, high-temperature (ca. 400 °C), reduced, and low-salinity hydrothermal fluid that interacted with the local host rocks. Based on the modeling of tourmaline–fluid boron isotope fractionation, we propose a metamorphic fluid origin derived from devolatilization of deeply buried muscovite schists during the regional prograde to peak metamorphism prior ca. 2.13 Ga. This metamorphic fluid–rock interaction model may possibly extend to other orogenic gold deposits in the West African Craton.
    Language: English
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  • 59
    facet.materialart.
    Unknown
    In:  GMIT - Geowissenschaftliche Mitteilungen
    Publication Date: 2022-04-11
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  • 60
    facet.materialart.
    Unknown
    In:  Journal of Geophysical Research: Solid Earth
    Publication Date: 2022-04-11
    Description: Fluvial deposits offer Earth’s best-preserved geomorphic record of past climate change over geological timescales. Quantitatively extracting this information remains challenging in part due to the complexity of erosion, sediment transport and deposition processes and how each of them responds to climate. Furthermore, sedimentary basins have the potential to temporarily store sediments, and rivers subsequently rework those sediments. This may introduce time lags into sedimentary signals and obscure any direct correlation with climate forcing. Here, using a numerical model that combines all three processes—and a new analytical solution—we show that the thickness of fluvial deposits at the outlet of a mountain river can be linked to the amplitude and period of rainfall oscillations but is modulated by the mountain uplift rate. For typical uplift rates of a few mm/yr, climate oscillations at Milankovitch periods lead to alluvial sediment thickness of tens of meters as observed in nature. We also explain the time lag of the order of 20–25% of the forcing period that is commonly observed between the timing of maximum rainfall and erosion. By comparing to field datasets, our predictions for the thickness and time lag of fluvial deposits are broadly consistent with observations despite the simplicity of our modeling approach. These findings provide a new theoretical framework for quantitatively extracting information on past rainfall variations from fluvial deposits.
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  • 61
    facet.materialart.
    Unknown
    In:  Journal of Geophysical Research: Earth Surface
    Publication Date: 2022-04-11
    Description: Physical weathering in cold, steep bedrock hillslopes occurs at rates that are thought to depend on temperature, but our ability to quantify the temperature-dependence of erosion remains limited when integrating over geomorphic timescales. Here, we present results from a 1D numerical model of in-situ cosmogenic 10Be, 14C, and 3He concentrations that evolve as a function of erosion rate, erosion style, and ground surface temperature. We used the model to explore the suitability of these nuclides for quantifying erosion rates in areas undergoing non-steady state erosion, as well as the relationship between bedrock temperature, erosion rate, and erosional stochasticity. Our results suggest that even in stochastically-eroding settings, 10Be-derived erosion rates of amalgamated samples can be used to estimate long-term erosion rates, but infrequent large events can lead to bias. The ratio of 14C to 10Be can be used to evaluate erosional stochasticity, and to determine the offset between an apparent 10Be-derived erosion rate and the long-term rate. Finally, the concentration of 3He relative to that of 10Be, and the paleothermometric interpretations derived from it, are unaffected by erosional stochasticity. These findings, discussed in the context of bedrock hillslopes in mountainous regions, indicate that the 10Be-14C-3He system in quartz offers a method to evaluate the temperature-sensitivity of bedrock erosion rates in cold, high-alpine environments.
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  • 62
    Publication Date: 2022-04-11
    Description: In seismic risk assessment, the sources of uncertainty associated with building exposure modelling have not received as much attention as other components related to hazard and vulnerability. Conventional practices such as assuming absolute portfolio compositions (i.e., proportions per building class) from expert-based assumptions over aggregated data crudely disregard the contribution of uncertainty of the exposure upon earthquake loss models. In this work, we introduce the concept that the degree of knowledge of a building stock can be described within a Bayesian probabilistic approach that integrates both expert-based prior distributions and data collection on individual buildings. We investigate the impact of the epistemic uncertainty in the portfolio composition on scenario-based earthquake loss models through an exposure-oriented logic tree arrangement based on synthetic building portfolios. For illustrative purposes, we consider the residential building stock of Valparaíso (Chile) subjected to seismic ground-shaking from one subduction earthquake. We have found that building class reconnaissance, either from prior assumptions by desktop studies with aggregated data (top–down approach), or from building-by-building data collection (bottom–up approach), plays a fundamental role in the statistical modelling of exposure. To model the vulnerability of such a heterogeneous building stock, we require that their associated set of structural fragility functions handle multiple spectral periods. Thereby, we also discuss the relevance and specific uncertainty upon generating either uncorrelated or spatially cross-correlated ground motion fields within this framework. We successively show how various epistemic uncertainties embedded within these probabilistic exposure models are differently propagated throughout the computed direct financial losses. This work calls for further efforts to redesign desktop exposure studies, while also highlighting the importance of exposure data collection with standardized and iterative approaches.
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  • 63
    Publication Date: 2022-04-11
    Description: Hydrodynamic interactions, i.e. the floodplain storage effects caused by inundations upstream on flood wave propagation, inundation areas, and flood damage downstream, are important but often ignored in large-scale flood risk assessments. Although new methods considering these effects sometimes emerge, they are often limited to a small or meso scale. In this study, we investigate the role of hydrodynamic interactions and floodplain storage on flood hazard and risk in the German part of the Rhine basin. To do so, we compare a new continuous 1D routing scheme within a flood risk model chain to the piece-wise routing scheme, which largely neglects floodplain storage. The results show that floodplain storage is significant, lowers water levels and discharges, and reduces risks by over 50%. Therefore, for accurate risk assessments, a system approach must be adopted, and floodplain storage and hydrodynamic interactions must carefully be considered.
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  • 64
    Publication Date: 2022-04-14
    Description: The permeability characteristics of natural fracture systems are crucial to the production potential of shale gas wells. To investigate the permeability behavior of a regional fault that is located within the Wufeng Formation, China, the gas permeability of shale samples with natural micro-fractures was measured at different confining pressures and complemented with helium pycnometry for porosity, computed micro-tomographic (µCT) imaging, and a comparison with well testing data. The cores originated from a shale gas well (HD-1) drilled at the Huayingshan anticline in the eastern Sichuan Basin. The measured Klinkenberg permeabilities are in the range between 0.059 and 5.9 mD, which roughly agrees with the permeability of the regional fault (0.96 mD) as estimated from well HD-1 productivity data. An extrapolation of the measured permeability to reservoir pressures in combination with the µCT images shows that the stress sensitivity of the permeability is closely correlated to the micro-fracture distribution and orientation. Here, the permeability of the samples in which the micro-fractures are predominantly oriented along the flow direction is the least stress sensitive. This implies that tectonic zones with a large fluid potential gradient can define favorable areas for shale gas exploitation, potentially even without requirements for hydraulic fracture treatments.
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  • 65
    Publication Date: 2022-04-20
    Description: Clathrate hydrates—also known as gas hydrates—are ice-like compounds consisting of gas and water molecules. They occur wherever elevated pressures and low temperatures prevail; and where enough water and hydrate-forming gas molecules are available. Therefore, natural gas hydrates occur at all active and passive continental margins, in permafrost regions, in some deep lakes, and under unfavorable circumstances, also, in pipelines. This article provides an overview of the (thermodynamic) requirements and various models for the nucleation and growth of gas hydrates and the different gas hydrate structures that may occur and which have been detected in nature. Furthermore, this study also shows the influence of the properties of the enclosed gas molecules such as size and shape on the structure and thermodynamic properties of the resulting hydrate phase. Finally, the complexity of a natural environment with regard to the various influences of sediments, microbial activity, and salinity of the pore fluid on hydrate formation is also discussed.
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  • 66
    Publication Date: 2022-06-24
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  • 67
    Publication Date: 2022-06-24
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  • 68
    Publication Date: 2022-06-24
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  • 69
    Publication Date: 2022-06-24
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  • 70
    Publication Date: 2022-06-24
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  • 71
    Publication Date: 2022-06-24
    Description: We believe that the transdisciplinary studies on water-related multi-hazards are innovative and critical research by the water community, thus answering the call of the recent Nature Sustainability Editorial ‘Too much and not enough’1 for water science ideas that are not derivative or stagnant. This domain of water studies focuses on the specific contexts where water-related hazardous events occur simultaneously, in cascade or cumulatively with other events. Characteristic of the field is the intensive collaboration of scientists and practitioners from different disciplines working together to better understand, assess and manage water-related multi-hazards. At the recent Asia Oceania Geosciences Society–European Geosciences Union Joint Conference on New Dimensions for Natural Hazards in Asia, we discussed the statement ‘Too much and not enough’1 and here suggest three reasons why transdisciplinary collaborations have led to many new ideas and notable advancements in the field of water-related multi-hazard research in recent years.
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  • 72
    Publication Date: 2022-06-24
    Description: A rockfall dataset for Germany is analysed with the objective of identifying the meteorological and hydrological (pre-)conditions that change the probability for such events in central Europe. The factors investigated in the analysis are precipitation amount and intensity, freeze–thaw cycles, and subsurface moisture. As there is no suitable observational dataset for all relevant subsurface moisture types (e.g. water in rock pores and cleft water) available, simulated soil moisture and a proxy for pore water are tested as substitutes. The potential triggering factors were analysed both for the day of the event and for the days leading up to it. A logistic regression model was built, which considers individual potential triggering factors and their interactions. It is found that the most important factor influencing rockfall probability in the research area is the precipitation amount at the day of the event, but the water content of the ground on that day and freeze–thaw cycles in the days prior to the event also influence the hazard probability. Comparing simulated soil moisture and the pore-water proxy as predictors for rockfall reveals that the proxy, calculated as accumulated precipitation minus potential evaporation, performs slightly better in the statistical model. Using the statistical model, the effects of meteorological conditions on rockfall probability in German low mountain ranges can be quantified. The model suggests that precipitation is most efficient when the pore-water content of the ground is high. An increase in daily precipitation from its local 50th percentile to its 90th percentile approximately doubles the probability for a rockfall event under median pore-water conditions. When the pore-water proxy is at its 95th percentile, the same increase in precipitation leads to a 4-fold increase in rockfall probability. The occurrence of a freeze–thaw cycle in the preceding days increases the rockfall hazard by about 50 %. The most critical combination can therefore be expected in winter and at the beginning of spring after a freeze–thaw transition, which is followed by a day with high precipitation amounts and takes place in a region preconditioned by a high level of subsurface moisture.
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  • 73
    Publication Date: 2022-06-24
    Description: Stibnite was mined until the end of the twentieth century in the Schlaining ore district, Austria, near the easternmost border of the Eastern Alps where windows of Penninic ophiolites and metasediments are exposed below Austroalpine tectonic units. In Early Miocene, structurally controlled small vein and metasomatic stibnite-quartz deposits were formed in Penninic Mesozoic calcareous marbles and calcite schists. Fluid inclusion studies identified two fluids involved in the mineralization: (i) a low-salinity, low-CO2 metamorphic fluid that precipitated quartz at approximately 240 °C and (ii) a stibnite-forming ore fluid that had a meteoric origin. There is no evidence of boiling or that the fluids mixed during mineralization. The ore components Sb and H2S were leached by fluid/rock interaction from buried rock units. Stibnite mineralization occurred by cooling the ore fluid to below 300 °C, at less than 2000 m depth. Quartz precipitated at slightly lower temperatures, approximately contemporaneous with stibnite. Fluid migration and ore deposition are probably related to high heat flow during the exhumation of the Rechnitz Window in response to Neogene extension and/or shallow Early Miocene andesitic magmatism. The study emphasizes that data obtained from the analyses of gangue minerals alone cannot routinely be used to infer the origin and depositional conditions of the associated ore minerals.
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  • 74
    Publication Date: 2022-06-24
    Description: Reconstructions of aeolian dust flux to West African margin sediments can be used to explore changing atmospheric circulation and hydroclimate over North Africa on millennial to orbital timescales. Here, we extend West African margin dust flux records back to 37 ka in a transect of sites from 19° to 27°N, and back to 67 ka at Ocean Drilling Program (ODP) Hole 658C, in order to explore the interplay of orbital and high-latitude forcings on North African climate and make quantitative estimates of dust flux during the core of the Last Glacial Maximum (LGM). The ODP 658C record shows a Green Sahara interval from 60 to 50 ka during a time of high Northern Hemisphere summer insolation, with dust fluxes similar to levels during the early Holocene African Humid Period, and an abrupt peak in flux during Heinrich event 5a (H5a). Dust fluxes increase from 50 to 35 ka while the high-latitude Northern Hemisphere cools, with peaks in dust flux associated with North Atlantic cool events. From 35 ka through the LGM dust deposition decreases in all cores, and little response is observed to low-latitude insolation changes. Dust fluxes at sites from 21° to 27°N were near late Holocene levels during the LGM time slice, suggesting a more muted LGM response than observed from mid-latitude dust sources. Records along the northwest African margin suggest important differences in wind responses during different stadials, with maximum dust flux anomalies centered south of 20°N during H1 and north of 20°N during the Younger Dryas.
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  • 75
    Publication Date: 2022-06-24
    Description: Using over-5-year EMFISIS wave measurements from Van Allen Probes, we present a detailed survey to identify the controlling factors among the geomagnetic indices and solar wind parameters for the 1-min root mean square amplitudes of lower band chorus (LBC) and upper band chorus (UBC). A set of important features are automatically determined by feature selection techniques, namely, Random Forest and Maximum Relevancy Minimum Redundancy. Our analysis results indicate the AE index with zero-time-delay dominates the intensity evolution of LBC and UBC, consistent with the evidence that chorus waves prefer to occur and amplify during enhanced substorm periods. Regarding solar wind parameters, solar wind speed and IMF Bz are identified as the controlling factors for chorus wave intensity. Using the combination of all these important features, a predictive neural network model of chorus wave intensity is established to reconstruct the temporal variations of chorus wave intensity, for which application of Random Forest produces the overall best performance.
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  • 76
    Publication Date: 2022-06-02
    Description: The upper crustal structure of the individual tectono-magmatic segments within the Main Ethiopian Rift is poorly understood. The Gedemsa tectono-magmatic segment (GTMS) is considered to be within an intermediate stage of rift development with magma-assisted rifting contributing to overall extension. The interpretation of gravity data from Global Gravity Model plus2013 has provided an insight on the nature and structure of the shallow upper crust beneath the GTMS within the Central Main Ethiopian Rift. A detailed investigation of the structure of the shallow upper crust based on 2D gravity models, 3D geologic interpretation maps, and residual and upward continued gravity anomaly maps indicate the occurrence of dense, mafic intrusions at depths between 10-20 km and 5–10 km beneath the Tullu Moye-Gedemsa and Boku volcanic centers, respectively. The gravity data indicate at deeper depths, the GTMS (25 km wide and 60 km long) is elongated parallel to the Main Ethiopian Rift axis. Our 2D gravity modeling indicates that the Quaternary faults within the Wonji Fault Belt are closely associated with the dense magmatic intrusions as the faults aid in transporting melt from the deeper crustal melt areas to the shallow magma chambers.
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  • 77
    Publication Date: 2022-06-03
    Description: A Cretaceous paleo-accretionary wedge, the Ashin Complex, now exposed along the Zagros suture zone in southern Iran, exhibits mafic, metasedimentary and ultramafic lithologies. Field, geochemical and petrological observations point to an anomalous high-temperature event that gave rise to the formation of peritectic (trondhjemitic) melts associated with restitic garnet-bearing amphibolites. Lu-Hf isotopic dating of centimetre-sized garnet in amphibolite-facies metasediments yielded a crystallization age of 113.10 ± 0.36 Ma, possibly representing the age of prograde to near-peak metamorphic conditions. SHRIMP U-Th-Pb zircon dating from trondhjemitic leucosomes yields crystallization ages of 104 ± 1 Ma, interpreted as the age of the temperature peak, which occurred in the upper amphibolite-facies (c. 650–680 °C at 1.1–1.3 GPa), according to thermodynamic modelling and Ti-in-zircon thermometry. Rutile crystals from two leucosomes yield Zr-in-rutile temperatures in the range of 580–640 °C and a LA-ICP-MS U-Pb age range from 85 to 112 Ma, interpreted as a consequence of partial re-equilibration during incipient cooling. A late static recrystallization event is indicated by the presence of sodic-calcic clinopyroxene, sodic amphibole, Si-rich phengite, titanite overgrowths after rutile and lawsonite within former leucosomes and late fractures. This mineral assemblage is a typical blueschist-facies (high pressure-low temperature) paragenesis and is interpreted as reflecting long-term isobaric cooling that occurred until the end of the Cretaceous as a consequence of increasing slab thermal age. This first report of a melting event in the Zagros paleo-accretionary wedge reveals the presence of a transient, abnormally high thermal gradient of c. 18 °C/km that occurred at c. 105–113 Ma. We speculate that this could be explained by the subduction of a thermal anomaly such as a seamount chain, a transform fault system or, more likely, a spreading ridge under the southern Iranian margin. Indeed, paleogeographic reconstructions of the Tethyan realm suggest the entrance of the Northern Tethyan basin ridge into the subduction zone shortly after 120 Ma.
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  • 78
    Publication Date: 2022-06-03
    Description: We present a comprehensive Li and B isotope study of granites, aplites, and igneous enclaves from the multi-phase Eibenstock granite in the Western Erzgebirge-Vogtland metallogenic province of Germany. The studied samples cover the entire compositional range of the granites from moderately to highly evolved and include variably altered types as obtained by magmatic fractionation, post-magmatic high- to medium-temperature and near-surface low-temperature alteration. Fractionation and alteration processes are unequivocally documented by the chemical variability of the rocks. Despite the marked imprint of these processes on bulk-rock compositions, our granite samples show only little variation in δ7Li (−0.52 to 0.75‰) and δ11B (−17.46 to −14.78‰), with surface samples defining the lower end of the δ7Li range. The narrow range in δ7Li suggests that magmatic fractionation and high-temperature overprint have a very minor effect on δ7Li. The B budget of the samples is dominated by tourmaline, which makes δ11B values insensitive for later high- to medium-temperature overprint or surficial low-temperature alteration. Depending on whether tourmaline crystallized before or after exsolution and loss of magmatic fluids, whole-rock samples have higher or lower δ11B values. Granite enclaves have δ7Li and δ11B values ranging from −1.51 to −0.81‰ and − 14.55 to −13.89‰, respectively. Some samples have chemical and mineralogical evidence for wall-rock interaction during emplacement or later overprint by external fluids. These samples show broader ranges in δ7Li (−2.61 to 2.21‰) and δ11B (−21.58 to −9.85‰). These values show that wall-rock interaction via assimilation and external fluids may affect δ7Li and δ11B to a larger extent than intra-magmatic processes, such as fractional crystallization, fluid-mediated autometasomatic overprinting, or exsolution of fluids from the melt. The offset of δ7Li and δ11B values towards the compositions of the wall rocks reflects the contrasting composition of granite and country rock and the addition of country-rock material to the granite. The magnitude of the offset reflects both the relative contribution of wall-rock derived Li and B to the granite and the magnitude of the difference in the Li and B isotopic compositions between them.
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  • 79
    Publication Date: 2022-06-08
    Description: The occurrence of felt earthquakes due to gas production in Groningen has initiated numerous studies and model attempts to understand and quantify induced seismicity in this region. The whole bandwidth of available models spans the range from fully deterministic models to purely empirical and stochastic models. In this article, we summarise the most important model approaches, describing their main achievements and limitations. In addition, we discuss remaining open questions and potential future directions of development.
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  • 80
    Publication Date: 2022-06-14
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  • 81
    Publication Date: 2022-06-14
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  • 82
    Publication Date: 2022-06-14
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  • 83
    Publication Date: 2022-06-14
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  • 84
    Publication Date: 2022-06-28
    Description: Py4HIP is an open-source software tool for Heat-In-Place calculations implemented as a self-explanatory Jupyter notebook written in Python (Py4HIP.ipynb) Calculating the Heat In Place (HIP) is a standard method for assessing the geothermal potential for a defined geological unit (e.g., Nathenson, 1975; Muffler and Cataldi, 1978; Garg and Combs, 2015). The respective implementation in Py4HIP is based on a volumetric quantification of contained energy after Muffler and Cataldi (1978), where the geological unit at hand is considered spatially variable in terms of its temperature, thickness, porosity, density and volumetric heat capacity of its solid and fluid (brine) components. The energy values
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  • 85
    Publication Date: 2022-06-28
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  • 86
    Publication Date: 2022-06-28
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  • 87
    Publication Date: 2022-06-27
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  • 88
    Publication Date: 2022-06-09
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  • 89
    Publication Date: 2022-06-09
    Description: Erosion by landslides is a common phenomenon in mountain regions around the globe, affecting all climatic zones. Landslides facilitate bedrock weathering, pedogenesis and ecological succession, being key drivers of biodiversity. Landslide chronosequences have long been used for studies of vegetation succession in initial ecosystems, but they further offer ideal model systems for studies of soil development and microbial community succession. In this review we synthesize the state of knowledge on the role of landslides in ecosystems, their influence on element cycles and interactions with biota. Further, we discuss feedback mechanisms between global warming, landslide activity and greenhouse gas emissions. In the view of increasing anthropogenic influence and climate change, soils are becoming a critical resource. Due to their ubiquity, landslide chronosequences have the potential to provide critical insights into soil development under different climates and thereby contribute to future soil restoration efforts.
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  • 90
    Publication Date: 2022-06-09
    Description: Llallagua is one of the world's biggest tin deposits and part of the metallogenic Bolivian Tin Belt, which occurs in the inner arc of the Central Andes. The Llallagua deposit formed through emplacement of a subvolcanic porphyry stock, of intermediate dacitic to rhyodacitic composition, metasomatism, and hydrothermal mineralization. The deposit is the subject of a well-established geochronologic controversy that includes contradictory ages (≈40 and 20 Ma) from multiple geochronometers. Geochronological characterization of phosphate minerals from the metasomatized igneous porphyry and hydrothermal vein assemblages, along with detailed petrography and chemical analyses, are used to reconcile the age controversy. The new interpretation is further supported by existing textural and geochemical data. The Usingle bondPb ages of unaltered igneous fluorapatite (e.g. 21.2 ± 2.9 Ma), monazite (e.g. 21.22 + 0.80/−0.66 Ma), and zircon (e.g. 21.15 ± 0.39 Ma) from the Llallagua porphyry are all equivalent within error at ≈20 Ma, and are interpreted to represent the age of porphyry stock emplacement. Ages determined from altered portions of these minerals (e.g. apatite, 18.8 ± 8.0 Ma) are within error the same as unaltered portions, suggesting alteration of the porphyry soon after emplacement. Usingle bondPb ages from unaltered fluorapatite (e.g. 21.4 ± 6.7 Ma), altered and unaltered monazite (e.g. 19.4 ± 1.4 Ma and 20.29 ± 0.30 Ma respectively), and unaltered xenotime (e.g. 19.32 ± 0.67 Ma) from the hydrothermal veins are also ≈20 Ma, indicating a very short hiatus or temporal continuity between stock emplacement and hydrothermal vein formation. The early Miocene age for tin mineralization at Llallagua is consistent with neighboring mineralization centers at the Morococala, Colquechaca, Japo, and Santa Fe mines, and with regional trends observed across the Bolivian Tin Belt, including stratigraphy, magmatic, and tectonic history of the Andean Eastern Cordillera.
    Language: English
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  • 91
    Publication Date: 2022-06-09
    Description: Scandium is important in modern technology and is regarded as a strategic metal in many countries. It is highly dispersed in Earth’s crust and rarely forms independent minerals. Clinopyroxene is the most important Sc-bearing mineral in some world-class deposits hosted in mafic–ultramafic intrusions, which are also the major source of laterite-hosted Sc deposits. However, the factors controlling Sc distribution in minerals have been little explored, impeding the understanding of the geochemical behavior of Sc and why it is common in some clinopyroxene grains. The newly discovered Mouding Sc deposit in SW China is hosted in a zoned intrusion composed, from core to rim, of monzogabbro, syenogabbro, gabbro, magnetite clinopyroxenite, and clinopyroxenite. Clinopyroxene in the intrusion is diopsidic in composition with high Sc contents (80–105 ppm). In-situ trace element mappings of diopside crystals reveal homogeneous, zoned, swallow-tailed, and hourglass internal Sc distribution patterns. These patterns can be produced through kinetically controlled incorporation of Sc on different crystal faces. The preferential substitution of Sc can take place on the {1 0 0}, {1 1 0} and {0 1 0} prism faces because of the high flexibility of the octahedral M1 protosites. The fast growth of diopside, which facilitates kinetically controlled crystallization, is dominated by textural coarsening and promoted by the hydrous parental magmas with low viscosities and active convection. The active flow and efficient interstitial communication of the magma can direct compatible elements from the magma into clinopyroxene, thus favoring formation of Sc-rich grains. Our study provides a feasible way to study intra-grain variations of Sc in minerals and emphasizes that kinetic effects may play a critical role in Sc distribution and enrichment in hydrous magmatic Sc deposits. We also show that disequilibrium crystallization may be more pervasive than previously thought, and the hourglass zoning of clinopyroxene can provide valuable information on this process.
    Language: English
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  • 92
    Publication Date: 2022-06-09
    Description: Iron-bearing carbonates play an important role in Earth’s carbon cycle. Owing to their stability at mantle conditions, recently discovered iron carbonates with tetrahedrally coordinated carbon atoms are candidates for carbon storage in the deep Earth. The carbonates’ iron oxidation and spin state at extreme pressure and temperature conditions contribute to the redox conditions and element partitioning in the deep mantle. By laser heating FeCO3 at pressures of about 83 GPa, Fe3+4C3O12 and Fe2+2Fe3+2C4O13 were synthesized and then investigated by x-ray emission spectroscopy to elucidate their spin state, both in situ and temperature quenched. Our experimental results show both phases in a high-spin state at all pressures and over the entire temperature range investigated, i.e., up to 3000 K. The spin state is conserved after temperature quenching. A formation path is favored where Fe3+4C3O12 forms first and then reacts to Fe 2+2Fe3+2C4O13, most likely accompanied by the formation of oxides. Density functional theory calculations of Fe2+2Fe3+2C4O13 at 80 GPa confirm the experimental findings with both ferric and ferrous iron in high-spin state with antiferromagnetic order at 80 GPa. As the intercrystalline cation partitioning between the Fe-bearing carbonates and the surrounding perovskite and ferropericlase depends on the spin state of the iron, an understanding of the redox conditions prevalent in subducted slab regions in the lower mantle has to take the latter into account. Especially, Fe2+2Fe3+2C4O13 may play a key role in subducted material in the lower mantle, potentially with a similar role as silicate perovskite.
    Language: English
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  • 93
    Publication Date: 2022-06-09
    Description: Transnational access (TNA) allows cross‑border, short‑term and frequently free‑of‑charge access to world-class research facilities, to foster collaborations and exchanges of experience. Specifically, TNA aims to encourage open science and innovation and to increase the efficient and effective use of scientific infrastructure. Within EPOS, the European Plate Observing System, the Volcano Observatories and Multi‑scale Laboratories communities have offered TNA to their high‑quality research facilities through national and European funding. This experience has allowed the definition, design, and testing of procedures and activities needed to provide transnational access in the EPOS context. In this paper, the EPOS community describes the main objectives for the provision of transnational access in the EPOS framework, based on previous experiences. It includes practical procedures for managing transnational access from a legal, governance, and financial perspective, and proposes logistical and technical solutions to effectively execute transnational access activities. In addition, it provides an outlook on the inclusion of new thematic communities within the TNA framework, and addresses the challenges of providing market‑driven access to industry.
    Language: English
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  • 94
    Publication Date: 2022-06-09
    Description: Semi-arid Mongolia is a highly sensitive region to climate changes, but the region’s Holocene paleoclimatic evolution and its underlying forcing mechanisms have been the subject of much recent debate. Here we present a continuous 7.4 ka sediment record from the high-altitude Shireet Naiman Nuur (Nuur = lake) in the central Mongolian Khangai Mountains. We extensively dated the sediments and analyzed elemental composition and bulk isotopes for lake sediment characterization. Our results show that 14C-dating of bulk organic carbon and terrestrial macrofossils provide a robust and precise chronology for the past 7.4 ± 0.3 cal ka BP at Shireet Naiman Nuur and 14C-ages are mostly in stratigraphic order. The 14C-based chronology is confirmed by paleomagnetic secular variations, which resemble the predictions of spherical harmonic geomagnetic field models. The very good chronological control makes paleomagnetic secular variation stratigraphy a powerful tool for evaluating and refining regional 14C-chronologies when compared to the record presented here. The lake sediment proxies TOC, N, log (Ca/Ti) and log (Si/Ti) reveal increased lake primary productivity and high growing season temperatures from 7.4 ± 0.3 to 4.3 ± 0.2 cal ka BP, which is likely the result of stronger summer insolation and pronounced warming. Reduced summer insolation thereafter results in decreased productivity and low growing season temperatures at Shireet Naiman Nuur from 4.3 ± 0.3 cal ka BP until present day. The globally acknowledged 4.2 ka event also appears as a pronounced cooling event at Shireet Naiman Nuur, and additional abrupt cooling events occurred during minima in total solar irradiance at ∼3.4, 2.8 and 2.4 ka BP. Low lake primary productivity and growing season temperatures are likely the result of longer ice cover periods at the high-altitude (2,429 m a.s.l.) Shireet Naiman Nuur. This leads to shorter mixing periods of the lake water which is supported by more positive δ13CTOC because of increased incorporation of dissolved HCO3− by aquatic producers during periods of longer ice cover.
    Language: English
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  • 95
    Publication Date: 2022-06-09
    Language: English
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  • 96
    Publication Date: 2022-06-09
    Description: Soil moisture signatures provide a promising solution to overcome the difficulty of evaluating soil moisture dynamics in hydrologic models. Soil moisture signatures are metrics that quantify the dynamic aspects of soil moisture timeseries and enable process-based model evaluations. To date, soil moisture signatures have been tested only under limited land-use types. In this study, we explore soil moisture signatures' ability to discriminate different dynamics among contrasting land-uses. We applied a set of nine soil moisture signatures to datasets from six in-situ soil moisture networks worldwide. The dataset covered a range of land-use types, including forested and deforested areas, shallow groundwater areas, wetlands, urban areas, grazed areas, and cropland areas. Our set of signatures characterized soil moisture dynamics at three temporal scales: event, season, and a complete timeseries. Statistical assessment of extracted signatures showed that (1) event-based signatures can distinguish different dynamics for all the land-uses, (2) season-based signatures can distinguish different dynamics for some types of land-uses (deforested vs. forested, urban vs. greenspace, and cropped vs. grazed vs. grassland contrasts), (3) timeseries-based signatures can distinguish different dynamics for some types of land-uses (deforested vs. forested, urban vs. greenspace, shallow vs. deep groundwater, wetland vs. non-wetland, and cropped vs. grazed vs. grassland contrasts). Further, we compared signature-based process interpretations against literature knowledge; event-based and timeseries-based signatures generally matched well with previous process understandings from literature, but season-based signatures did not. This study will be a useful guideline for understanding how catchment-scale soil moisture dynamics in various land-uses can be described using a standardized set of hydrologically relevant metrics.
    Language: English
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  • 97
    Publication Date: 2022-06-09
    Description: Apatite is a ubiquitous accessory mineral in crustal rocks. The Sr-isotope record of apatite has a wide range of applications in earth science studies. However, apatite has been documented to be easily altered by certain fluids. Currently, the impact of metasomatic alteration on Sr-isotopic abundances in apatite is not well known. In order to better understand this issue, well-characterized fluorapatite grains have been metasomatized experimentally at a temperature of 800 or 600 °C and a pressure of 200 MPa. Fluids used included a CO2-H2O mixture and NaF-, CaCl2-, and HCl-bearing solutions, all of which were doped with a standard solution with a known 87Sr/86Sr ratio. In the fluorapatite + CO2-H2O experiments, the fluorapatite grains were not altered by the fluids; thus, their Sr isotope compositions were generally kept unchanged. However, the other fluids induced partial to complete alteration of fluorapatite. In experiments involving the NaF- or HCl-bearing solutions, the Sr content remained constant or was increased in altered areas of the fluorapatite, and the Sr isotopes underwent changes with partial isotopic signature of the reacting solutions. In experiments involving CaCl2, the Sr content was decreased in the altered fluorapatite because high Ca activity in the solution caused Ca to replace Sr on the Ca site. Notably, the Sr isotopic ratios are still changed, although to a relatively small extent. The efficient Sr isotopic exchange between fluid and apatite is attributed to the rapid transport rate of Sr between the reaction-interface fluid and bulk fluid surrounding the apatite. This experimental study demonstrates that the response of apatite Sr isotopes to metasomatic alteration is mainly controlled by the chemistry of fluids. Overall, Sr isotopes become susceptible to hydrothermal alteration once the apatite is chemically reactive with the fluids. Therefore, it is important to evaluate the fluid-rock history, especially the conjectured fluid composition before using Sr isotopes from apatite as a geochemical tracer.
    Language: English
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  • 98
    Publication Date: 2022-06-09
    Description: Thaw consolidation of degrading permafrost is a serious hazard to the safety and operation of infrastructure. Monitoring thermal changes in the active layer (AL), the proportion of the soil above permafrost that thaws and freezes periodically, is critical to understanding the conditions of the top layer above the permafrost and regulating the construction, operation, and maintenance of facilities. However, this is a very challenging task using ground-based methods such as ground-penetrating radar (GPR) or temperature sensors. This study explores the integration of interferometric measurements from high-resolution X-band Synthetic Aperture Radar (SAR) images and volumetric water content (VWC) data from SoilGrids to quantify detailed spatial variations in active layer thickness (ALT) in Iqaluit, the territorial capital of Nunavut in Canada. A total of 21 SAR images from COSMO Sky-Med (CSK) were first analyzed using the freely connected network interferometric synthetic aperture radar (FCNInSAR) method to map spatial and temporal variations in ground surface subsidence in the study area. Subsequently, we built an ALT retrieval model by introducing the thaw settlement coefficient, which takes soil properties and saturation state into account. The subsidence measurements from InSAR were then integrated with VWC extracted from the SoilGrids database to estimate changes in ALT. For validation, we conducted a comparison between estimated ALTs and in situ measurements in the airport sector. The InSAR survey identifies several sites of ground deformation at Iqaluit, subsiding at rates exceeding 80 mm/year. The subsidence rate changes along the runway coincide with frost cracks and ice-wedge furrows. The obtained ALTs, ranging from 0 to 5 m, vary significantly in different sediments. Maximum ALTs are found for rock areas, while shallow ALTs are distributed in the till blanket (Tb), the intertidal (Mi) sediments, and the alluvial flood plain (Afp) sediment units. The intersection of taxiway and runway has an AL thicker than other parts in the glaciomarine deltaic (GMd) sediments. Our study suggests that combining high-resolution SAR imagery with VWC data can provide more comprehensive ALT knowledge for hazard prevention and infrastructure operation in the permafrost zone.
    Language: English
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  • 99
    Publication Date: 2022-06-09
    Description: Cosmic-ray neutron sensing (CRNS) has become an effective method to measure soil moisture at a horizontal scale of hundreds of metres and a depth of decimetres. Recent studies proposed operating CRNS in a network with overlapping footprints in order to cover root-zone water dynamics at the small catchment scale and, at the same time, to represent spatial heterogeneity. In a joint field campaign from September to November 2020 (JFC-2020), five German research institutions deployed 15 CRNS sensors in the 0.4 km2 Wüstebach catchment (Eifel mountains, Germany). The catchment is dominantly forested (but includes a substantial fraction of open vegetation) and features a topographically distinct catchment boundary. In addition to the dense CRNS coverage, the campaign featured a unique combination of additional instruments and techniques: hydro-gravimetry (to detect water storage dynamics also below the root zone); ground-based and, for the first time, airborne CRNS roving; an extensive wireless soil sensor network, supplemented by manual measurements; and six weighable lysimeters. Together with comprehensive data from the long-term local research infrastructure, the published data set (available at https://doi.org/10.23728/b2share.756ca0485800474e9dc7f5949c63b872; Heistermann et al., 2022) will be a valuable asset in various research contexts: to advance the retrieval of landscape water storage from CRNS, wireless soil sensor networks, or hydrogravimetry; to identify scale-specific combinations of sensors and methods to represent soil moisture variability; to improve the understanding and simulation of land–atmosphere exchange as well as hydrological and hydrogeological processes at the hillslope and the catchment scale; and to support the retrieval of soil water content from airborne and spaceborne remote sensing platforms.
    Language: English
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  • 100
    Publication Date: 2022-06-09
    Description: Arctic permafrost landscapes have functioned as a global carbon sink for millennia. These landscapes are very heterogeneous, and the omnipresent water bodies within them act as a carbon source. Yet, few studies have focused on the impact of these water bodies on the landscape carbon budget. We deepen our understanding of carbon emissions from thermokarst ponds and constrain their impact by comparing carbon dioxide and methane fluxes from these ponds to fluxes from the surrounding tundra. We use eddy covariance measurements from a tower located at the border between a large pond and semi-terrestrial tundra. When we take the open-water areas of thermokarst ponds into account, our results show that the estimated summer carbon uptake of the polygonal tundra is 11 % lower. Further, the data show that open-water methane emissions are of a similar magnitude to polygonal tundra emissions. However, some parts of the pond's shoreline exhibit much higher emissions. This finding underlines the high spatial variability in methane emissions. We conclude that gas fluxes from thermokarst ponds can contribute significantly to the carbon budget of Arctic tundra landscapes. Consequently, changes in the water body distribution of tundra landscapes due to permafrost degradation may substantially impact the overall carbon budget of the Arctic.
    Language: English
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