ALBERT

Description: The coagulation of hydrosols was investigated theoretically and experimentally. A reduced form of the particle size distribution function, designated “self-preserving,” was found to satisfy Smoluchowski's equations of coagulation by Brownian motion and shear flow. Brownian motion coagulation experiments with two heterogeneous hydrosols showed that the distributions were self-preserving. The rate of coagulation for heterogeneous systems was found to be second order in total particle concentration, consistent with the self-preserving form of the distribution function. Coagulation experiments were carried out in a simple laminar shear field using a homogeneous Dow polystyrene latex dispersion. Smoluchowski's shear flow theory was confirmed for shear rates ranging from 1 to 80 sec.−1 The shear coagulation of a heterogeneous emulsion was studied at several shear rates, and the size distributions were self-preserving.

Description: Fecal excretion of calcium of endogenous origin has been measured in 52 studies in 33 adult human subjects, under full metabolic balance conditions. Endogenous fecal calcium averaged .130 ± .047 Gm. per day, was positively correlated with both fecal calcium and dietary calcium and was inversely correlated with fractional calcium absorption. The regression line relating endogenous fecal calcium with fractional absorption allowed estimates for total intestinal calcium secretion at both zero and 100 per cent absorption; from these estimates it was calculated that approximately 15 per cent of the total intestinal calcium secretion was nonabsorbable even under conditions when dietary calcium was completely absorbed (presumably because it enters the gut caudad of the absorption sites). Total intestinal calcium secretion, calculated so as to allow for this nonabsorbable fraction, averaged .194 ± .073 Gm. per day, and could not be correlated with age, sex, dietary calcium intake, caloric intake, urine calcium, or plasma calcium. A weak correlation with body size (weight, surface area) was observed. The conditions studied were principally disorders of bone, calcium, and parathyroid metabolism, and in most of them total intestinal calcium secretion appeared identical. The sole exception was seen in two studies on a patient with acromegaly, in which total intestinal calcium secretion was over twice the mean value for the remainder of the group.

Description: Calcium absorbtion was measured in fasting human beings after oral administration of Ca^45 in a solution containing 10 to 500mg stable calcium and an intravenous dose of Ca^47. Absorbtion was determined from the ratio of specific activities of the two isotopes (oral dose/intravenous dose) in calcium of urine collected more than 24 hours later. The accuracy of this calculation was confirmed by comparison with absorbtion calculated from recovery of the oral dose in stools (the completeness of collection being determined from recovery of simultaneously given Cr2O2or Cr^51 labeled protein and a correction for endogenous calcium being made from the fecal recovery of the intravenouse dose of Ca^47). In 20 tests, the average difference between the two calculations of per cent absorbtion was 2.2 and the coefficient of variation, 1.6. The Conditions under which the double isotope procedure gives an accurate result were evaluated and the results of its use with 3 different doses of calcium given to normal subjects are reported

Description: This chapter discusses the Maillard reaction. Results of the many investigations into the mechanism of the Maillard reaction support one of two main theories. The first assumes the formation of glycosylamines that undergo the Amadori (or, for ketoses, the Heyns) rearrangement. The 1-amino-l-deoxyketose derivative (or 2-amino-2-de- oxyaldose derivative) formed may be dehydrated and cyclized to form furan derivatives, or it may enolize. In either case, intermediates that are readily transformed into brown compounds are formed. A third possibility is for the deoxy sugar derivative to react with more amino acid to form colored products. The many workers who have supported this mechanism found also that optimum conditions for occurrence of the Maillard reaction are (1) fairly low water content, (2) a pH of 7 to 10, and (3) a high temperature. Nevertheless, some reaction occurs under conditions far removed from these, but in the absence of moisture there is no reaction. The formation of an acyclic Schiff base as an initial step is not very likely, since replacement of the aldose by salicylaldehyde caused only a very small loss of amino groups. The second theory of the mechanism of the browning reaction is of recent origin and maintains that the browning reaction and the Maillard reaction are separate and distinct. Browning, according to this school of thought, is due to the effect of pH on the sugar and can occur over a wide range of pH, whereas the Maillard reaction proceeds only in alkaline media.

Description: Fourteen instances of whales entangled in submarine cables are reported. Ten entanglements occured off the Pacific coast of Central and South America. Six cases occured in about 500 fathoms, with 620 fathoms the maximum depth reported. Five entanglements occured in the period, Februray-March-April. All whales positively identified were sperm whales. The submarine cable was generally wrapped around jaw and often around the flukes and fins. The cable was rarely broken but always badly mauled. The entanglements often occured near former repairs where there is a chance for extra slack cable on the bottom. Two photographs of a sperm whale entangled in a cable and one photograph of a whale-jaw entangled in a cable are presented. It is concluded that sperm whales often swim alog the sea floor in depths as grat as 620 fathoms. It is suggested that the whales become entangled while swimming along with their jaw plowing through the sediment in search of food. It is possible that the whales attack tangled masses of slack cable mistaking them for items of food.

Description: This paper summarizes the hydrogeology of the thick carbonate-evaporite sequence that extends from land surface to the oil horizons at depths of about 11,500 feet below sea level in southern Florida. It sets forth the few known facts about the hydrology of the deep water-bearing rocks and discusses a hypothesis concerning the cyclic flow of salt water related to geothermal heating in the Floridan aquifer. Meinzer (1923, p. 30) defined an aquifer as a "formation, a group of formations, or part of a formation that is water bearing." The connotation of quantity was included by the statement: "Few if any formations are entirely devoid of gravity ground water, but those that do not contain enough to be of consequence as a source of supply are not rated as water bearing." The quality of the water does not enter the definition, for if it did, a change in quality (as by salt-water encroachment) would correspondingly convert aquifers to nonaquifers. This paper treats permeable water-bearing beds as aquifers even though the contained water might be a brine seven times as salty as sea water and, therefore, normally not considered a source of supply.

Description: Sedimentary iron and heavy-metal deposits of undetermined size have been found in the middle of the Red Sea some 2000 meters below the surface of the sea (Fig. 1). This discovery has been made from the Research Vessel Atlantis II, which is still at sea engaged in a series of oceanographic investigations which ultimately will end in November 1965, after the ship has circumnavigated the globe. The discovery is significant because the environment and the processes controlling deposition of heavy metals are observable and appear to be still active.

Description: This chapter throws the attention on the methods of sampling the benthos, which has been directed mainly to the operation of the gear at sea and to such other factors as may influence sampling methods. This chapter briefly traces the history of benthos investigations, and then considers how far the instruments now available provide with the quantitative samples. It also shows how advances in other fields, such as radio-position finding, sonar and electronic equipment have increased the precision of our sampling methods. Moreover, sorting and sieving on board ship can be considered and brief mention made of methods of soil analysis and biomass determination. This chapter discusses the two possible approaches for the development of satisfactory quantitative collecting methods. First the improvement of the grab-type of instrument, with particular reference to increasing penetration and the perfection of release gear for the open sea, and second; the development of a wide-core sampler, like the Knudsen sampler, which works satisfactorily in the open sea. Moreover, statistics need to be even more fully applied, where collecting methods justify them, to such problems as the degree and scale of dispersion of individuals.