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  • Chromatographie, Gas  (67)
  • oxidation  (57)
  • Springer  (124)
  • American Meteorological Society
  • Blackwell Publishing Ltd
  • International Union of Crystallography
  • Springer Nature
  • 1975-1979  (124)
Collection
Publisher
  • Springer  (124)
  • American Meteorological Society
  • Blackwell Publishing Ltd
  • International Union of Crystallography
  • Springer Nature
Years
Year
  • 1
    ISSN: 1573-4889
    Keywords: oxidation ; nickel-chromium alloys ; Group III–V elements ; reactive minor additions
    Source: Springer Online Journal Archives 1860-2000
    Topics: Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics
    Notes: Abstract The corrosion of a number of experimental ternary Ni-15 wt. % Cr-0.5wt. %X alloys (where X= Y, La, Ce, Sm, Th, U, Zr, or V) has been assessed in pure oxygen at 900° C for periods of exposure up to 450 hr, and compared with the behavior of an Ni-15% Cr control alloy. It has been established that while all of the alloys oxidize in accordance with a protective, approximately parabolic regime, considerable differences in oxidation rates are exhibited. In particular, additions of La, Ce, and Th bring about progressively enhanced rates of oxidation relative to the binary alloy, whereas Y, Sm, V, U, and Zr effect increasingly reduced rates of oxidation in the order given. The rate constant for the Th-bearing alloy is about two orders of magnitude larger than that for the alloy containing Zr. Such differences in behavior seem to be associated with subtle variations in the morphology/composition of the corrosion products from alloy to alloy. The observations are considered in the light of earlier published literature concerning the effects of rare-earth and other reactive elements on the oxidation behavior of Ni/Cr alloys.
    Type of Medium: Electronic Resource
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  • 2
    Electronic Resource
    Electronic Resource
    Springer
    Oxidation of metals 10 (1976), S. 189-223 
    ISSN: 1573-4889
    Keywords: oxidation ; platinum ; platinum-aluminum alloys ; alumina (Al2O3) ; oxide-scale adhesion
    Source: Springer Online Journal Archives 1860-2000
    Topics: Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics
    Notes: Abstract The development, growth, and adhesion of α-Al2O3 scales on platinum-aluminum alloys containing between 0.5 and 6 wt.% aluminum have been studied at temperatures in the interval between 1000 and 1450° C. The morphologies and microstructures of the α-Al2O3 scales were found to be influenced by the temperature, oxygen pressure, and the microstructures of the alloys. The oxidation rates of the alloys appeared to be controlled by transport of oxygen along grain boundaries in the α-Al2O3 scales. The α-Al2O3 scales adhered to the platinum-aluminum substrates even after extensive periods of cyclic oxidation. The good adhesion of the α-Al2O3 may result from mechanical keying of the oxide to the alloys due to the development of irregular oxide-alloy interfaces.
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  • 3
    Electronic Resource
    Electronic Resource
    Springer
    Oxidation of metals 10 (1976), S. 277-289 
    ISSN: 1573-4889
    Keywords: alloy ; iron ; aluminum ; silicon ; oxidation
    Source: Springer Online Journal Archives 1860-2000
    Topics: Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics
    Notes: Abstract Silicon or chromium can be used as an oxygen getter in iron-aluminum alloys to prevent the internal oxidation of aluminum. This suppresses the formation of the iron oxide nodules that tend to destroy binary iron-aluminum alloys during high-temperature oxidation. Alloys of iron containing aluminum and silicon in varying proportions were heated in flowing air for 50 hr at 1093°C. Of the alloys tested, one containing 6% aluminum and 1 % silicon was the most resistant to oxidation.
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  • 4
    Electronic Resource
    Electronic Resource
    Springer
    Oxidation of metals 10 (1976), S. 311-327 
    ISSN: 1573-4889
    Keywords: defect structure ; CoO ; oxidation
    Source: Springer Online Journal Archives 1860-2000
    Topics: Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics
    Notes: Abstract The total concentration of point defects and deviation from stoichiometry in Co1-yO have been determined experimentally as functions of temperature and equilibrium oxygen pressure in the temperature range 1000–1250°C and oxygen pressure range 10−3-1 atm. This total concentration of defects has also been calculated from known values of the coefficients of chemical diffusion and tracer self-diffusion of cobalt. The results of the two methods agree well. It has been found in the investigated range of temperature and oxygen pressure that the defect structure of cobaltous oxide is composed not only of defects due to deviation from stoichiometry, singly ionized cation vacancies, and an equivalent amount of electron holes, but also of intrinsic defects, probably of the Frenkel type.
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  • 5
    Electronic Resource
    Electronic Resource
    Springer
    Oxidation of metals 10 (1976), S. 341-345 
    ISSN: 1573-4889
    Keywords: α-Al2O3 ; platinum ; oxidation ; adhesion
    Source: Springer Online Journal Archives 1860-2000
    Topics: Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics
    Notes: Abstract The influence of externally located platinum on the isothermal stability of α-Al2O3 scales formed at high temperatures has been examined. It has been observed that a nickel-base alloy forms an external scale of α-Al2O3 during oxidation at 1200°C, but this scale breaks down isothermally, enabling a faster-growing Cr2O3-rich scale to develop. However, in the presence of platinum metal alongside the specimen in the furnace hot zone, the breakdown of the α-Al2O3 scale is postponed for a substantial period of time. It appears that platinum, as the volatile species PtO2, is incorporated into the growing α-Al2O3 scale where it either influences the stress relief mechanism at temperature or reduces oxidation growth stress generation and thus significantly enhances the isothermal stability of the scale.
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  • 6
    Electronic Resource
    Electronic Resource
    Springer
    Oxidation of metals 10 (1976), S. 377-401 
    ISSN: 1573-4889
    Keywords: oxidation ; iron ; Mössbauer ; electron re-emission ; ERM spectroscopy
    Source: Springer Online Journal Archives 1860-2000
    Topics: Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics
    Notes: Abstract The results of an electron re-emission Mössbauer (ERM) spectroscopy study of the oxidation of metallic Fe at temperatures from 150 to 500°C in pure oxygen ( $${\text{p}}_{{\text{O}}_{\text{2}} } \approx {\text{ }}10$$ Torr) are presented. The oxidized samples were prepared from a metallic Fe sample enriched to 70% in the Mössbauer isotope Fe57 and the oxidation kinetics were determined volumetrically. Scanning electron microscopy was employed to characterize the morphology of the oxide films. The hematite, magnetite, and total-oxide thicknesses were determined from the ERM spectra using a theory recently developed in this laboratory, and the results were found to agree well with the measured oxygen content of the oxide films. For Fe and Fe-base alloys it is shown that the ERM technique is most useful in the oxide-thickness range of approximately 20–3000 Å within that range, oxide-phase identifications and thickness determinations are perhaps more readily determined by ERM spectroscopy than by any competing technique. In particular, the ERM measurement is nondestructive, and no supplementary measurements (such as surface-roughness determinations) or special sample preparations (such as oxide-film stripping) are required
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  • 7
    Electronic Resource
    Electronic Resource
    Springer
    Oxidation of metals 11 (1977), S. 57-62 
    ISSN: 1573-4889
    Keywords: oxidation ; scale growth
    Source: Springer Online Journal Archives 1860-2000
    Topics: Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics
    Notes: Abstract Equations are presented to modify the classical theoretical expressions for the parabolic rate constant for the case in which the scale has a large composition range and a large variation in molar volume. The modifications appear as simple averages, together with a factor f.Evaluation of f for some hypothetical cases shows that it is near unity unless the composition gradient has an extreme deviation from linearity.
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  • 8
    Electronic Resource
    Electronic Resource
    Springer
    Oxidation of metals 11 (1977), S. 193-198 
    ISSN: 1573-4889
    Keywords: oxidation ; scaling ; wustite ; magnetite ; iron
    Source: Springer Online Journal Archives 1860-2000
    Topics: Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics
    Notes: Abstract The theory of the growth of two oxide layers by Yurek et al. has been applied to the oxidation of iron at 1100° C. The theoretical parabolic rate constants for the simultaneous growth of the two oxide layers were calculated from radioactive tracer diffusion coefficients for wustite and magnetite. Good agreement was found between the theoretical and experimental values of the ratio of scale thicknesses.
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  • 9
    Electronic Resource
    Electronic Resource
    Springer
    Oxidation of metals 12 (1978), S. 227-245 
    ISSN: 1573-4889
    Keywords: oxidation ; sulfidation ; iron-chromium-nickel alloy ; thermochemical diagram ; parabolic rate constant
    Source: Springer Online Journal Archives 1860-2000
    Topics: Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics
    Notes: Abstract Oxidation-sulfidation studies of Fe-Cr-8Ni alloys with 4, 12, and 22 wt. % Cr were conducted at 750 and 875°C in multicomponent gas mixtures that contained CO, CO2, CH4, H2, and H2S. The reaction processes resulted in parabolic kinetics. A chromium concentration in the range 0–12 wt. % in the alloy had a negligible effect on the parabolic rate constant; however, the rate constant for the alloy with 22 wt. % Cr was significantly lower. For a given sulfur partial pressure, the oxygen partial pressures required for the formation of a continuous oxide layer in an Fe-22Cr-8Ni alloy were ∼102 to 103 times those calculated for Cr-Cr2O3 equilibrium at temperatures of 875 and 750° C, respectively.
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  • 10
    Electronic Resource
    Electronic Resource
    Springer
    Oxidation of metals 12 (1978), S. 451-471 
    ISSN: 1573-4889
    Keywords: HCl gas ; H2O vapor ; Ni-Cr-Al alloy ; oxidation ; hot corrosion
    Source: Springer Online Journal Archives 1860-2000
    Topics: Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics
    Notes: Abstract Moist air containing HCl gas caused the oxide formed on a Ni-Cr-Al alloy at 850°C to crack during the early stages of growth, and extensive blistering and spalling occurred on cooling. In dry air containing HCl gas no oxide cracking was observed at temperature although the oxide blistered and spalled on cooling. In dry or moist air free from HCl an adherent protective oxide formed which did not spall on cooling. The oxide cracking at temperature has been attributed to the production of hydrogen by reaction of Cr and Al in the alloy with water vapor and the removal of NiO as NiCl2 by reaction with HCl gas. Hydrogen produced by reaction of water vapor or HCl with Cr or Al dissolved in the alloy at temperature, but on cooling the hydrogen was released, causing the oxide to blister and spall. Preoxidation of the alloy in HCl-free atmospheres eliminated these effects of HCl gas in short-term isothermal tests.
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