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  • pharmacokinetics  (417)
  • Electron microscopy  (160)
  • 42.60  (90)
  • Springer  (667)
  • American Chemical Society (ACS)
  • 1980-1984  (667)
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Publisher
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Year
  • 1
    Electronic Resource
    Electronic Resource
    Enzymatic and pharmacokinetic studies on the metabolism of branched chain α-keto acids in the rat (1983)
    Springer
    European journal of nutrition 22 (1983), S. 14-26 
    Details
    ISSN: 1436-6215
    Keywords: branched chain α-keto acids ; 4-methyl-2-oxopentanoate, 3-methyl-2-oxopentanoate ; 3-methyl-2-oxobutyrate ; dehydrogenation ; transamination ; pharmacokinetics ; absorption
    Source: Springer Online Journal Archives 1860-2000
    Topics: Agriculture, Forestry, Horticulture, Fishery, Domestic Science, Nutrition , Medicine
    Description / Table of Contents: Zusammenfassung Michaelis-Konstanten und Aktivitäten von Dehydrogenasen und Transaminasen der drei verzweigten α-Ketosäuren Keto-Valin, Keto-Leucin und Keto-Isoleucin in Leber, Niere, Skeletmuskel und Gehirn von Ratten werden mitgeteilt. Nach oraler Zufuhr passieren nur 11–22% der Ketosäuren unverändert die Leber. Aus pharmakokinetischen und Resorptions-Untersuchungen erhaltene Blutspiegel an Ketosäuren werden zu den Michaelis-Konstanten in Beziehung gesetzt. Bei den geringen Konzentrationen an Ketosäuren nach oraler Zufuhr kann angenommen werden, daß die oxidativen Prozesse in den nichthepatischen Geweben über die Transaminierung überwiegen. Daten über die Wachstumseffizienz von verzweigtkettigen α-Ketosäuren im Vergleich zu den entsprechenden Aminosäuren stimmen mit dieser Vorstellung überein. Bei intravenöser Verabreichung müßten die Voraussetzungen für Transaminierung besser sein als nach oraler Zufuhr. Auf der Basis von Daten aus der Literatur werden die Übertragbarkeit unserer Befunde auf den Menschen und die verschiedenen Faktoren, welche die Effizienz der verzweigten α-Ketosäuren durch Einwirkung auf ihren Stoffwechsel beeinflussen können, diskutiert.
    Notes: Summary Miehaelis-constants and enzyme activities for dehydrogenation and transamination of the three branched chainα-keto acids in liver, kidney, skeletal muscle, and brain of rats are reported. After oral load only 11–22 % of the keto acids pass the liver unchanged. Blood levels in pharmacokinetic and absorption studies are related to the Michaelis-constants. At the low keto-acid concentrations after oral application, dehydrogenation in the non-hepatic tissues is supposed to prevail over transamination. Data on feed efficiency of branched chain α-keto acids reported in the literature support this view. The chance for transamination is better after intravenous administration. The transferability of our data to humans, and various factors influencing the efficiency of branched chain α-keto acids are discussed in connection with data reported in the literature.
    Type of Medium: Electronic Resource
    URL: http://dx.doi.org/10.1007/BF02020781
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  • 2
    Electronic Resource
    Electronic Resource
    Application of the short-time staining for the electron microscopic investigation of the crystallization of polyethylene (1983)
    Springer
    Colloid & polymer science 261 (1983), S. 373-374 
    Details
    ISSN: 1435-1536
    Keywords: Electron microscopy ; short-time staining ; nodular structure ; crystallization
    Source: Springer Online Journal Archives 1860-2000
    Topics: Chemistry and Pharmacology , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics
    Type of Medium: Electronic Resource
    URL: http://dx.doi.org/10.1007/BF01413947
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  • 3
    Electronic Resource
    Electronic Resource
    Heat of fusion and lamellar structure of polyethylene single crystal mats (1982)
    Springer
    Colloid & polymer science 260 (1982), S. 564-569 
    Details
    ISSN: 1435-1536
    Keywords: lin. Polyethylene ; Single crystals ; Heat of Fusion ; DSC ; Electron microscopy
    Source: Springer Online Journal Archives 1860-2000
    Topics: Chemistry and Pharmacology , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics
    Notes: Abstract Recently published results for solution crystallized PE single crystals have shown, that the experimental heat of fusionΔH * is higher, if the solvent is exchanged to silicon oil (oil suspension samples) as compared with dried mats. This has been interpreted by the collapse of the original hollow pyramids during drying, inducing lateral defects within the lamellae. The present investigation does not confirm this unexpected result.ΔH * of dried mats (T c 66 to 91 °C) and of the corresponding oil suspension samples agree within the rather small limits of experimental error. The crystallinities as derived fromΔH *, density or WAXS are in excellent agreement. SEM micrographs of cold fractured dried mats show their spongy macromorphology, but TEM micrographs of stained ultra-thin sections reveal the lamellar morphology of the walls, consisting of curved lamellae and stacked hollow pyramides. If a dried mat is sintered at room temperature, a dense transparent film is obtained with a rather regular stacked morphology of large flat lamellae.ΔH * of these films agrees with that of the original mat.
    Type of Medium: Electronic Resource
    URL: http://dx.doi.org/10.1007/BF01422587
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  • 4
    Electronic Resource
    Electronic Resource
    An investigation of laser-induced fluorescence for measuring velocity distributions of neutral atoms using a CW dye laser (1984)
    Springer
    Applied physics 35 (1984), S. 83-93 
    Details
    ISSN: 1432-0649
    Keywords: 32.80 ; 42.60 ; 6.30
    Source: Springer Online Journal Archives 1860-2000
    Topics: Physics
    Notes: Abstract The velocity distribution of evaporated Zr atoms has been measured by means of laser-induced fluorescence using a cw dye laser by scanning the laser line across the Doppler-broadened absorption line profile of the atoms. It is shown that the experimental data can be explained on the basis of an excitation theory for a three-level system developed from basic principles. It was calculated that the probability for an atom to be in the excited state mainly depends on the radiation-power density of the laser and on the residence time of the atom in the exciting laser light. It was found that the laser frequency must be well stabilized in order to meet the assumptions in the excitation calculation. Otherwise deviations to the theoretical predictions appear in the experimental results due to the jitter of the dye laser.
    Type of Medium: Electronic Resource
    URL: http://dx.doi.org/10.1007/BF00697427
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  • 5
    Electronic Resource
    Electronic Resource
    Independently controllable multiline emission from a TEA CO2 laser (1984)
    Springer
    Applied physics 35 (1984), S. 123-126 
    Details
    ISSN: 1432-0649
    Keywords: 42.50 ; 42.60
    Source: Springer Online Journal Archives 1860-2000
    Topics: Physics
    Notes: Abstract Spatial separation of wavelengths in a CO2-laser resonator helps to avoid competitions. We have achieved this by means of a nearly concentric resonator with a grating or prism in its center. Thus, we demonstrated independent multiline emission with a variety of output spectra. The temporal sequence of the lines was conveniently controlled by varying their losses.
    Type of Medium: Electronic Resource
    URL: http://dx.doi.org/10.1007/BF00697699
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  • 6
    Electronic Resource
    Electronic Resource
    Picosecond pulses and applications (1982)
    Springer
    Applied physics 28 (1982), S. 172-179 
    Details
    ISSN: 1432-0649
    Keywords: 42.60 ; 07.65
    Source: Springer Online Journal Archives 1860-2000
    Topics: Physics
    Type of Medium: Electronic Resource
    URL: http://dx.doi.org/10.1007/BF00697843
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  • 7
    Electronic Resource
    Electronic Resource
    Theory of synchronously pumped dye lasers (1983)
    Springer
    Applied physics 30 (1983), S. 135-142 
    Details
    ISSN: 1432-0649
    Keywords: 42.55 ; 42.60 ; 42.80
    Source: Springer Online Journal Archives 1860-2000
    Topics: Physics
    Notes: Abstract An analysis of cw synchronously pumped dye lasers is presented. Under the assumption that the cavity (tuning element) bandwidth is much wider than the bandwidth of the transform limited pulses generated, the pulse forming dynamics is rigorously treated. It is shown that for a finite mismatch between the lengths of the dye and the pump lasers, a steady-state pulse develops in the dye laser cavity with a conserved pulseshape. The characteristics (energy, shape, peak power, duration) of these pulses of ultimate width are quantitatively determined as a function of cavity mismatch. An analytical solution for the pulse envelope is determined, which yieldsI(t)∝Sech2(t/t p ) to a good approximation.
    Type of Medium: Electronic Resource
    URL: http://dx.doi.org/10.1007/BF00695468
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  • 8
    Electronic Resource
    Electronic Resource
    Laser atomic photoionization spectral analysis of element traces (1983)
    Springer
    Applied physics 30 (1983), S. 161-176 
    Details
    ISSN: 1432-0649
    Keywords: 32 ; 42.50 ; 42.60
    Source: Springer Online Journal Archives 1860-2000
    Topics: Physics
    Notes: Abstract A new method for determining trace amounts of elements in a substance has been developed. It is based on thermal evaporation and atomization of a substance in vacuum and detection of the released trace atoms by the laser stepwise photoionization technique. A rather effective way of detecting atoms is their multistep excitation to Rydberg states by the radiation of tunable dye lasers with their subsequent ionization by electric field pulses. The analytical laser spectrometer consisting of several tunable, pulsed dye lasers, a vacuum chamber with an atomizer and a recording system is described. The microimpurities of elements have been detected in pure materials: the contents of Na impurities in CdS crystals (2×10−6%) and Al impurities in germanium (2×10−7%). The detection limit of about 10−9% was determined. A technique for direct determination of the content of elements in natural water and human blood is described. A high sensitivity, universality and other merits of the method enable it to be used in determining traces of many important elements at a level of 10−8 to 10−11% almost in any matrix.
    Type of Medium: Electronic Resource
    URL: http://dx.doi.org/10.1007/BF00688402
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  • 9
    Electronic Resource
    Electronic Resource
    Amplification and measurement of single 1.6–3.5 ps Pulses generated by a distributed feedback dye laser (1983)
    Springer
    Applied physics 31 (1983), S. 1-4 
    Details
    ISSN: 1432-0649
    Keywords: 42.60
    Source: Springer Online Journal Archives 1860-2000
    Topics: Physics
    Notes: Abstract We have shown that distributed feedback dye lasers are capable of generating single transform-limited pulses of 1.6–3.5 ps duration when pumped by a mode-locked Nd: YAG laser. A short-pulse amplifier has been constructed in which the level of amplified spontaneous emission could be kept below 10−3 by properly taking into account the polarization anisotropy of the gain and by precise timing of the pump pulses. A sensitive autocorrelator is described which allows to measure pulse duration in a single shot.
    Type of Medium: Electronic Resource
    URL: http://dx.doi.org/10.1007/BF00693898
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  • 10
    Electronic Resource
    Electronic Resource
    A discussion of the problem of determining multiple lifetimes from picosecond absorption recovery data as encountered in two carbocyanine dyes (1983)
    Springer
    Applied physics 31 (1983), S. 235-247 
    Details
    ISSN: 1432-0649
    Keywords: 42.60 ; 42.65 ; 61.60
    Source: Springer Online Journal Archives 1860-2000
    Topics: Physics
    Notes: Abstract Absorption recovery kinetics data on the picosecond time-scale of a high signalto-noise ratio can be obtained by using continuously operating synchronously modelocked dye lasers. We show that such data make it possible to determine multiple exponential decays with small differences in rate constants. We also show that an absolute prerequisite to accomplish this is that the measurements are performed at a number of different wavelengths, and that the decays are monitored in a time interval corresponding to several lifetimes. These considerations are demonstrated by measurements on two carbocyanine dyes, DQOCI and pinacyanol, respectively.
    Type of Medium: Electronic Resource
    URL: http://dx.doi.org/10.1007/BF00690794
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