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  • Articles  (44)
  • kriging  (23)
  • Nitrification  (21)
  • 1985-1989  (44)
  • 1965-1969
  • Geosciences  (44)
  • Energy, Environment Protection, Nuclear Power Engineering  (1)
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  • Articles  (44)
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  • 1
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    Springer
    Stochastic environmental research and risk assessment 3 (1989), S. 51-67 
    ISSN: 1436-3259
    Keywords: Spatial rainfall estimation ; kriging ; ordinary co-kriging ; disjunctive co-kriging
    Source: Springer Online Journal Archives 1860-2000
    Topics: Architecture, Civil Engineering, Surveying , Energy, Environment Protection, Nuclear Power Engineering , Geography , Geosciences
    Notes: Abstract The feasibility of linear and nonlinear geostatistical estimation techniques for optimal merging of rainfall data from raingage and radar observations is investigated in this study by use of controlled numerical experiments. Synthetic radar and raingage data are generated with their hypothetical error structures that explicitly account for sampling characteristics of the two sensors. Numerically simulated rainfall fields considered to be ground-truth fields on 4×4 km grids are used in the generation of radar and raingage observations. Ground-truth rainfall fields consist of generated rainfall fields with various climatic characteristics that preserve the space-time covariance function of rainfall events in extratropical cyclonic storms. Optimal mean areal precipitation estimates are obtained based on the minimum variance, unbiased property of kriging techniques under the second order homogeneity assumption of rainfall fields. The evaluation of estimated rainfall fields is done based on the refinement of spatial predictability over what would be provided from each sensor individually. Attention is mainly given to removal of measurement error and bias that are synthetically introduced to radar measurements. The influence of raingage network density on estimated rainfall fields is also examined.
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  • 2
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    Biology and fertility of soils 8 (1989), S. 335-338 
    ISSN: 1432-0789
    Keywords: Autotrophy ; Lime ; Lolium perenne ; Nitrate reductase ; Nitrification ; Stagnohumic gley
    Source: Springer Online Journal Archives 1860-2000
    Topics: Biology , Geosciences , Agriculture, Forestry, Horticulture, Fishery, Domestic Science, Nutrition
    Notes: Summary Three different nitrification assays (short-term nitrifier activity, assimilatory nitrate reductase activity of Lolium perenne, and nitrate accumulation in the absence of plants) were performed either on soil from a naturally acidic stagnohumic-gley or on leaves from L. perenne grown in this soil. Before the investigation the soil was limed and fertilised in a manner consistent with established agricultural pasture improvement strategies. Short-term nitrifier activity was only detected in soils above pH 5.6. However, nitrate reductase activity and nitrate accumulation both showed a near linear increase between soil pH 3.8 and 6.8. These findings are attributed to the nature of the assays, each of which considers a different component of the soil nitrifier population.
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  • 3
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    Biology and fertility of soils 8 (1989), S. 247-254 
    ISSN: 1432-0789
    Keywords: Nitrification ; Abiotic factors ; Ammonium concentration ; Vmax of nitrification ; Michaelis-Menten constant for ammonium oxidation
    Source: Springer Online Journal Archives 1860-2000
    Topics: Biology , Geosciences , Agriculture, Forestry, Horticulture, Fishery, Domestic Science, Nutrition
    Notes: Summary The effects of temperature, water potential and ammonium concentrations were studied in field and laboratory experiments on arable soil. The two field experiments used different sampling intervals, one at daily (short-term) and the other at monthly (long-term) intervals. In the short-term field experiment, the numbers and activities of nitrifiers were assessed before and after natural rain or irrigation. The nitrifiers were apparently outcompeted by heterotrophs during the first days after wetting the soil. Potential nitrification was affected only slightly by changes in water potential, whereas the numbers of ammonium and nitrite oxidizers appeared more sensitive to these changes. The numbers of ammonium and nitrite oxidizers correlated strongly during the daily samplings. The potential nitrite-oxidation rates correlated with water potentials whereas the potential ammonium oxidation rates did not. Extractable ammonium decreased in proportion to increasing nitrate concentrations in both the rain-fed and the irrigated plots. In the long-term field experiments, the numbers of ammonium oxidizers correlated with water potentials but not with in situ temperature or with ammonium concentrations. The potential ammonium-oxidation rates correlated with water potentials and with ammonium-oxidizer numbers. The potential nitrite-oxidation rates correlated strongly with the potential ammonium-oxidation rates. The field experiments implied that nitrite oxidizers obtained substrate from ammonium oxidizers but also from nitrate reduction. In laboratory experiments nitrate accumulated at a Q 10 of about 2 and the V max for nitrification was observed at a water potential of −0.11 MPa (65% of water-holding capacity). The K m for ammonium oxidation at pH 8.2 was 1.72 mg l−1 soil water.
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  • 4
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    Biology and fertility of soils 5 (1987), S. 195-202 
    ISSN: 1432-0789
    Keywords: Nitrogen mineralization ; Nitrification ; Organic quality ; New Mexico
    Source: Springer Online Journal Archives 1860-2000
    Topics: Biology , Geosciences , Agriculture, Forestry, Horticulture, Fishery, Domestic Science, Nutrition
    Notes: Summary Forest floor and mineral soil from ponderosa-pine, Douglas-fir, aspen and spruce-fir ecosystems located along a rising gradient in New Mexico were tested with laboratory assays for factors controlling N mineralization and nitrification. We concluded that low pH in combination with factors associated with organic quality controlled N mineralization and almost completely limited nitrification in spruce-fir soils, while N mineralization in the forest floor of ponderosa-pine was limited by low nutrient availability (other than N). Organic quality of the substrate and temporal changes in organic quality appeared to control N-mineralization and nitrification processes in forest-floor and mineral soils from all other sites.
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  • 5
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    Biology and fertility of soils 2 (1986), S. 65-70 
    ISSN: 1432-0789
    Keywords: Fertilized soil ; Nitrification ; Denitrification ; N2O production ; C2H2 blockage
    Source: Springer Online Journal Archives 1860-2000
    Topics: Biology , Geosciences , Agriculture, Forestry, Horticulture, Fishery, Domestic Science, Nutrition
    Notes: Summary A sandy soil amended with different forms and amounts of fertilizer nitrogen (urea, ammonium sulphate and potassium nitrate) was investigated in model experiments for N2O emission, which may be evolved during both oxidation of ammonia to nitrate and anaerobic respiration of nitrate. Since C2H2 inhibits both nitrification and the reduction of N2O to N2 during denitrification, the amount of N2O evolved in the presence and absence of C2H2 represents the nitrogen released through nitrification and denitrification. Results show that amounts of N2O-N lost from soils incubated anaerobically with 0.1% C2H2 and treated with potassium nitrate (23.1 µg N-NO 3 − /g dry soil) exceeded those from soils incubated in the presence of 20% oxygen and treated with even larger amounts of nitrogen as urea and ammonium sulphate. This indicates that nitrogen losses by denitrification may potentially be higher than those occurring through nitrification.
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  • 6
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    Biology and fertility of soils 2 (1986), S. 77-82 
    ISSN: 1432-0789
    Keywords: Ecosystem production ; Mineralization ; Nitrification ; Ion exchange resin bag method
    Source: Springer Online Journal Archives 1860-2000
    Topics: Biology , Geosciences , Agriculture, Forestry, Horticulture, Fishery, Domestic Science, Nutrition
    Notes: Summary Estimates of ammonium and nitrate availability in conifer and hardwood forests using an ion exchange resin (IER) bag method and with on-site incubations of soil cores in buried bags were compared. Correlations between the two methods were generally high. Correlation coefficients (r) between IER nitrate and buried-bag mineralized nitrate ranged from 0.87 to 0.92. Both methods also correlated well with aboveground net primary production, litter fall N content, and fine root biomass. The major differences between the methods related to the relative importances of ammonium and nitrate forms of available N. The IER method indicated that both ammonium and nitrate were important on all sites, with nitrate predominating in most soils. The buried-bag results indicated that available N was primarily in the form of nitrate (all ammonium was oxidized), but that nitrate was insignificant on infertile sites.
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  • 7
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    Biology and fertility of soils 2 (1986), S. 97-104 
    ISSN: 1432-0789
    Keywords: Nitrogen mineralization ; Nitrification ; Water-soluble inhibitors ; Allelochemic control
    Source: Springer Online Journal Archives 1860-2000
    Topics: Biology , Geosciences , Agriculture, Forestry, Horticulture, Fishery, Domestic Science, Nutrition
    Notes: Summary Bioassay experiments were performed to test for inhibition of the processes of nitrogen mineralization and nitrification by organics in the forest floor of a ponderosa pine ecosystem. Water-extractable organics in the forest floor were tested by applying filtered extracts to the assay soil. The extract decreased nitrate production by 17.0% and decreased net mineralization by 4.1%. Inhibition by volatile organics was tested by placing vials containing forest floor or selected terpenoids of ponderosa pine in sealed jars containing the assay soil. Nitrate production was inhibited by 87.4% and 100%, and net nitrogen mineralization was inhibited by 73.3% and 67.7% in the jars with forest floor and terpenoids, respectively. Organics which are partially water-soluble and are volatile (such as terpenoids) would be very effective inhibitors of nitrogen cycling processes.
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  • 8
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    Biology and fertility of soils 2 (1986), S. 87-95 
    ISSN: 1432-0789
    Keywords: Fire effects on mineralization ; Ammonification ; Nitrification ; Ponderosa pine soils
    Source: Springer Online Journal Archives 1860-2000
    Topics: Biology , Geosciences , Agriculture, Forestry, Horticulture, Fishery, Domestic Science, Nutrition
    Notes: Summary The effects of a prescribed fire in a ponderosa pine ecosystem on the rates of decomposition and nitrogen mineralization (including ammonification and nitrification) in the forest floor and mineral soil horizons were evaluated. The prescribed fire immediately increased the rates of nitrogen mineralization and nitrification in the forest floor of all burned plots and in the mineral soil of one plot. The rates of decomposition, as measured by CO2 evolution, in both the forest floor and mineral soil were not significantly different immediately after the burn when expressed on an organic matter basis. The rates of nitrogen mineralization in the forest floor and mineral soil were higher 6 and 10 months after the burn. The rate of decomposition (as measured by respiration) was lower in the forest floor but not in the mineral soil 6 and 10 months after the burn. Volatile organics that may inhibit rates of nitrogen mineralization may have been consumed by prescribed fire.
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  • 9
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    Biology and fertility of soils 6 (1988), S. 33-38 
    ISSN: 1432-0789
    Keywords: Microbial activity ; Nitrification ; Taiga ; Tillage system ; Crop residue management
    Source: Springer Online Journal Archives 1860-2000
    Topics: Biology , Geosciences , Agriculture, Forestry, Horticulture, Fishery, Domestic Science, Nutrition
    Notes: Summary C and N mineralization potentials were determined, in a 12-week laboratory incubation study, on soil samples obtained from recently cleared land which had been cropped to barley for 4 years (field soils) and from nearby undisturbed taiga (forest soils). Treatments for the cropped soils were conventional and no-tillage with and without crop residues removed. An average of about 3% of the total C was evolved as CO2 from the field soils compared with 〉 10% and 4% for the upper (Oie) and lower (Oa) forest-floor horizons, respectively. Significantly more C was mineralized from the Ap of the no-till treatment with residue left on the surface than from the other field Ap horizons. Both forest-floor horizons showed rather long lag periods for net mineralization compared with the field soils, but at the end of the incubation, more mineral N was recovered from the forest Oie despite a rather wide C:N ratio, than from the field soils. After 12 weeks about 115, 200 and 20 μg mineral N/g soil were recovered from the field Ap, the forest Oie and the forest Oa horizons, respectively. Very little C or N was mineralized from the B horizon of the forest or the field soils. Nitrification was rapid and virtually complete for the field soils but was negligible for both forest-floor O horizons.
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  • 10
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    Biology and fertility of soils 2 (1986), S. 201-204 
    ISSN: 1432-0789
    Keywords: Fertilizer ; Nitrification ; Denitrification ; N2O emission ; Anhydrous ammonia
    Source: Springer Online Journal Archives 1860-2000
    Topics: Biology , Geosciences , Agriculture, Forestry, Horticulture, Fishery, Domestic Science, Nutrition
    Notes: Summary Field studies to determine the effect of different rates of fertilization on emission of nitrous oxide (N2O) from soil fertilized with anhydrous ammonia showed that the fertilizer-induced emission of N2O-N in 116 days increased from 1.22 to 4.09 kg ha−1 as the rate of anhydrous ammonia N application was increased from 75 to 450 kg ha−1. When expressed as a percentage of the N applied, the fertilizer-induced emission of N2O-N in 116 days decreased from 1.6% to 0.9% as the rate of fertilizer N application was increased from 75 to 450 kg N ha−1. The data obtained showed that a 100% increase in the rate of application of anhydrous ammonia led to about a 60% increase in the fertilizer-induced emission of N2O. Field studies to determine the effect of depth of fertilizer injection on emission of N2O from soil fertilized with anhydrous ammonia showed that the emission of N2O-N in 156 days induced by injection of 112 kg anhydrous ammonia N ha−1 at a depth of 30 cm was 107% and 21 % greater than those induced by injection of the same amount of N at depths of 10 cm and 20 cm, respectively. The effect of depth of application of anhydrous ammonia on emission of N2O was less when this fertilizer was applied at a rate of 225 kg N ha−1.
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  • 11
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    Biology and fertility of soils 2 (1986), S. 195-199 
    ISSN: 1432-0789
    Keywords: Fertilizer N ; Nitrification ; Denitrification ; N2O emission ; Anhydrous ammonia
    Source: Springer Online Journal Archives 1860-2000
    Topics: Biology , Geosciences , Agriculture, Forestry, Horticulture, Fishery, Domestic Science, Nutrition
    Notes: Summary Field studies of the effects of different N fertilizers on emission of nitrous oxide (N20) from three Iowa soils showed that the N2O emissions induced by application of 180 kg ha−1 fertilizer N as anhydrous ammonia greatly exceeded those induced by application of the same amount of fertilizer N as aqueous ammonia or urea. On average, the emission of N2O-N induced by anhydrous ammonia was more than 13 times that induced by aqueous ammonia or urea and represented 1.2% of the anhydrous ammonia N applied. Experiments with one soil showed that the N2O emission induced by anhydrous ammonia was more than 17 times that induced by the same amount of N as calcium nitrate. These findings confirm indications from previous work that anhydrous ammonia has a much greater effect on emission of N2O from soils than do other commonly used N fertilizers and merits special attention in research relating to the potential adverse climatic effect of N fertilization of soils. Laboratory studies of the effect of different amounts of NH4OH on emission of N2O from Webster soil showed that the emission of N2O-N induced by addition of 100 μg NH4OH-N g−1 soil represented only 0.18% of the N applied, whereas the emissions induced by additions of 500 and 1 000 μg NH4OH-N g−1 soil represented 1.15% and 1.19%, respectively, of the N applied. This suggests that the exceptionally large emissions of N2O induced by anhydrous ammonia fertilization are due, at least in part, to the fact that the customary method of applying this fertilizer by injection into soil produces highly alkaline soil zones of high ammonium-N concentration that do not occur when urea or aqueous ammonia fertilizers are broadcast and incorporated into soil.
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  • 12
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    Biology and fertility of soils 5 (1988), S. 344-349 
    ISSN: 1432-0789
    Keywords: Nitrification ; Deamination ; Grassland ; N fertilisers ; pH ; Denitrification
    Source: Springer Online Journal Archives 1860-2000
    Topics: Biology , Geosciences , Agriculture, Forestry, Horticulture, Fishery, Domestic Science, Nutrition
    Notes: Summary Soil nitrification was compared in soils from 89-year-old grassland experimental plots with diverse chemical characteristics. Measurements of NaClO3-inhibited short-term nitrifier activity (SNA) and deamination of 1,2-diamino-4-nitrobenzene were used to study nitrification and deamination activities, respectively, in soil from each of 12 plots. Using multiple regression analysis, an expression for the relationship between SNA, soil pH and fertiliser N additions was derived which indicated that both the frequency and the quantity of farmyard manure additions were important in determining the rate of nitrification. SNA was greatest where there were large and frequent additions of farmyard manure. In soil with pH below 5.2 SNA was very low or insignificant. The effect of (NH4)2SO4 additions could not be assessed because they acidified the soil. We suggest that additions of farmyard manure increase the potential for NO3 − leaching or for denitrification. Deaminase assays indicated that soils with a higher pH showed greater N mineralisation than soils with a lower pH, except at the low extreme. There was no obvious relationship between SNA and deaminase activity at higher levels of pH.
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  • 13
    ISSN: 1432-0789
    Keywords: Ammonium ; Nitrate ; N-mineralization ; Nitrification ; Fertilization ; Irrigation ; Forest ecosystems
    Source: Springer Online Journal Archives 1860-2000
    Topics: Biology , Geosciences , Agriculture, Forestry, Horticulture, Fishery, Domestic Science, Nutrition
    Notes: Summary Forest-floor and 0–10 cm depth mineral soil horizons in two stands of Douglas fir were sampled for available NH4 +-N and NO3 −-N, N-mineralization potentials, and nitrification potentials for 2 years. The plots in each stand were sampled for 1 year, treated with either ammonium sulfate, carbohydrate (sawdust-sucrose), irrigation, carbohydrate plus irrigation, or no treatment (control), and then sampled for 1 year following treatment. In general, the direction of change following the treatments was the same for both the forest-floor and the mineral soils. Fertilization increased the NH4 +-N and NO3 −-N pools, nitrification potential, and N-mineralization potential, while treatment with carbohydrate decreased all of these characteristics. Irrigation generally increased NH4 +-N pools, nitrification potential, and N-mineralization potential, but decreased these characteristics in the soil at one site. Irrigation plus carbohydrate gave similar results to those of carbohydrate alone. Treatments altered pool sizes and/or potentials, but did not reduce within-year variance in any of these characteristics. Distinct seasonal patterns occurred in all measurements, suggesting that control of short-term variation in N-transformation processes is by factors which are dynamic in nature.
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  • 14
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    Biology and fertility of soils 6 (1988), S. 106-111 
    ISSN: 1432-0789
    Keywords: Nitrification ; Denitrification ; Soil water content ; N2O production ; Acetylene ; Ammonium fixation
    Source: Springer Online Journal Archives 1860-2000
    Topics: Biology , Geosciences , Agriculture, Forestry, Horticulture, Fishery, Domestic Science, Nutrition
    Notes: Summary The effect of soil water content [60%–100% water-holding capacity (WHC)] on N2O production during autotrophic nitrification and denitrification in a loam soil was studied in a laboratory experiment by selectively inhibiting nitrification with a low C2H2 concentration (2.1 Pa). Nitrifiers usually produced more N2O than denitrifiers. During an initial experimental period of 0–6 days the nitrifiers produced more N2O than the denitrifiers by a factor ranging from 1.4 to 16.5, depending on the water content and length of incubation. The highest N2O production rate by nitrifiers was observed at 90% WHC, when the soil had become partly anaerobic, as indicated by the high denitrification rate. At 100% WHC there were large gaseous losses from denitrification, while nitrification losses were smaller except for the first period of measurement, when there was still some O2 remaining in the soil. The use of 10 kPa C2H2 to inhibit reduction of N2O to N2 stimulated the denitrification process during prolonged incubation over several days; thus the method is unsuitable for long-term studies.
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  • 15
    ISSN: 1432-0789
    Keywords: Denitrification ; Nitrification ; Selective inhibitors ; Nitrapyrin ; Acetylene ; Nitrous oxide
    Source: Springer Online Journal Archives 1860-2000
    Topics: Biology , Geosciences , Agriculture, Forestry, Horticulture, Fishery, Domestic Science, Nutrition
    Notes: Summary Nitrapyrin and C2H2 were evaluated as nitrification inhibitors in soil to determine the relative contributions of denitrification and nitrification to total N2O production. In laboratory experiments nitrapyrin, or its solvent xylene, stimulated denitrification directly or indirectly and was therefore considered unsuitable. Low partial pressures of C2H2 (2.5–5.0 Pa) inhibited nitrification and had only a small effect on denitrification, which made it possible to estimate the contribution of denitrification. The contribution of nitrification was estimated by subtracting the denitrification value from total N2O production (samples without C2H2). The critical C2H2 concentrations needed to achieve inhibition of nitrification, without affecting the N2O reductase in denitrifiers, must be individually determined for each set of experimental conditions.
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  • 16
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    Biology and fertility of soils 7 (1988), S. 79-87 
    ISSN: 1432-0789
    Keywords: Microbial biomass ; Mineralization ; Nitrification ; Subarctic ; Volcanic ash
    Source: Springer Online Journal Archives 1860-2000
    Topics: Biology , Geosciences , Agriculture, Forestry, Horticulture, Fishery, Domestic Science, Nutrition
    Notes: Summary C and N pool sizes and rates of mineralization were studied in volcanic-ash deposits found in different subarctic habitats in southwestern Alaska. Surface ash samples were taken from white-spruce, alder, and moist- and dry-tundra habitats and were analysed for total and microbial C and N. C and N dynamics were studied using a 28-day aerobic laboratory incubation, with weekly measurement of evolved CO2 and determination of inorganic-N pools initially and after 10 and 28 days. Total and microbial C and N and cumulative respired CO2 all followed a similar pattern among the different habitats, with the moist-tundra habitat having the highest values and the spruce site the lowest. The size of the microbial biomass C and N pool in the spruce habitat was among the lowest reported for any ecosystem. Little net N mineralization occurred in the spruce-forest and dry-tundra ash over 28 days. Ash from the moist-tundra habitat immobilized a significant amount of N during the first 10 days of incubation, yet showed a large net release of N after 28 days. In contrast, the ash from the alder site exhibited net mineralization after both periods, with N production after 28 days being about 3.5 times that after 10 days. In addition, the alder-habitat ash was the only soil that showed net nitrification. Rates of total C and N accretion in the tundra and alder habitats were rapid relative to rates found for primary successions. The results of this study show that habitat has a profound effect on C and N cycling in subarctic environments.
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  • 17
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    Biology and fertility of soils 7 (1989), S. 254-258 
    ISSN: 1432-0789
    Keywords: N-mineralisation ; Nitrification ; Arginine ammonification ; Inorganic pollutants
    Source: Springer Online Journal Archives 1860-2000
    Topics: Biology , Geosciences , Agriculture, Forestry, Horticulture, Fishery, Domestic Science, Nutrition
    Notes: Summary Long-term effects of 12 inorganic pollutants on N transformations were studied in a sandy cambisol. As, Be, Br, Cd, Cr, F, Pb, Hg, Se, Sn, and V were added to the soil as inorganic salts in 1975 and 1976. Soil samples were taken in 1984 to determine total N mineralisation and nitrification. All pollutants except Se and Sn inhibited N mineralisation. The most toxic elements under investigation were Be and Hg. Nitrification was reduced to a lower degree than total N mineralisation. As, Be, Cd, Cr, F, Pb, Se, and Sn failed to inhibit this process at all. It is assumed that nitrifying bacteria became adapted to these pollutants in the course of time. The arginine-ammonification method was less sensitive in detecting the effects of pollutants on N transformation than the N mineralisation test.
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  • 18
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    Biology and fertility of soils 8 (1989), S. 204-211 
    ISSN: 1432-0789
    Keywords: Nitrification ; Heterocyclic N compounds ; Pyrazoles ; Triazoles ; Pyridines ; Thiadiazoles ; 2-Ethynylpyridine ; Nitrapyrin ; Etridiazole
    Source: Springer Online Journal Archives 1860-2000
    Topics: Biology , Geosciences , Agriculture, Forestry, Horticulture, Fishery, Domestic Science, Nutrition
    Notes: Summary The relationship between the structures of diverse heterocyclic nitrogen (N) compounds and the effectiveness of these compounds for the inhibition of nitrification in soil was studied by determining the effects of different amounts of 12 unsubstituted and 33 substituted heterocyclic N compounds on the production of (NO 2 − +NO 3 − )-N in soils incubated at 25 °C for 21 days after treatment with ammonium sulfate. The results showed that unsubstituted heterocyclic N compounds containing two adjacent ring N atoms inhibit nitrification in soil and that two of these compounds, pyrazole and 1,2,4-triazole, are potent inhibitors. They also showed that several substituted pyrazoles and thiadiazoles are good inhibitors of nitrification in soil (e.g., 3-methylpyrazole and 3,4-dichloro-1,2,5-thiadiazole).
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  • 19
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    Biology and fertility of soils 4 (1987), S. 205-212 
    ISSN: 1432-0789
    Keywords: Nitrate production ; Nitrification ; Humisol ; Methane oxidation ; Methanotrophs
    Source: Springer Online Journal Archives 1860-2000
    Topics: Biology , Geosciences , Agriculture, Forestry, Horticulture, Fishery, Domestic Science, Nutrition
    Notes: Summary The coexistence of chemoautotrophic nitrifiers and methanotrophs in a cultivated humisol was investigated. Under laboratory conditions which supported the growth and activity of methanotrophs, the nitrifiers were partially or completely inhibited. The inhibition was related to a competition for available oxygen and a high assimilatory requirement for inorganic nitrogen by the Methanotrophs. Dissolved methane concentrations as high as 250 μM had no direct effect on the oxidation of ammonium. Simultaneous nitrification and methane oxidation was observed only if relatively high levels of ammonium and oxygen were maintained. Coupled nitrification-assimilatory/dissimilatory nitrate reduction resulted from the high oxygen demand of the actively growing methanotrophs. This study suggests that the potential competitive effects of methanotrophs may influence nitrification by chemoautotrophic nitrifiers in certain environmental systems.
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  • 20
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    Biology and fertility of soils 6 (1988), S. 341-346 
    ISSN: 1432-0789
    Keywords: Nitrification ; Phosphatase ; Dehydrogenase ; Aerosol ; Soil thickness ; Soil enzymes
    Source: Springer Online Journal Archives 1860-2000
    Topics: Biology , Geosciences , Agriculture, Forestry, Horticulture, Fishery, Domestic Science, Nutrition
    Notes: Summary Soil was exposed to red phosphorous/butyl rubber (RP/BR) aerosols at various relative humidities in a recirculating environmental wind tunnel. Soil microbial and enzymatic activities were measured immediately after exposure and periodically thereafter for 56 days. The nitrification potential was significantly reduced in soil amended with ammonium sulfate and exposed to RP/BR smoke, and could be related to a decline in soil pH. The rate of nitrate formation in unamended soil with time was also reduced, but by 57 days postexposure, concentrations were similat to those of unexposed controls in all but the thinnest soil lense. Soil dehydrogenase and phosphatase enzyme activities were sensitive to RP/BR smoke and in some treatments no activity was detected. The measured activities did not recover within the 56-day postexposure period and in some cases declined. Soil lense thickness was the greatest factor controlling the degree of RP/BR effects, indicating that injury to soil microbial and enzymatic activities may be surficial. Deposition of smoke particles increased with increasing relative humidity, which had a significant impact on the activities measured.
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  • 21
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    Biology and fertility of soils 1 (1985), S. 3-7 
    ISSN: 1432-0789
    Keywords: Nitrification ; Denitrification ; Soil profile
    Source: Springer Online Journal Archives 1860-2000
    Topics: Biology , Geosciences , Agriculture, Forestry, Horticulture, Fishery, Domestic Science, Nutrition
    Notes: Summary Nitrous oxide (N2O) fluxes at the soil surface and concentrations at 0.1, 0.2, and 0.3 m were determined in a 40-year-old planted tallgrass (XXX) prairie, a 40-year-old white pine (Pinus strobus) plantation, and field plots treated annually for 18 years either with 33 metric tons of manure ha−1 (330 kg N ha−1) and NH4NO3 (80 kg N ha−1) or with only NH4NO3 (control). Nitrous oxide fluxes from the prairie, forest, manure-amended, and control sites from 13 May to 10 November 1980 ranged from 0.2 to 1.3, 3.5 to 19.5, 3.7 to 79.0, and 1.7 to 24.8 ng N2O-N m−2s−1, respectively. We observed periods when there was no apparent relationship between the N2O flux from the surface and N2O concentrations in the soil profile. This was generally the case in the prairie and in the field sites following the application of N fertilizer. The N2O concentrations in the soil profile increased markedly and coincided with increased soil water content following periods of heavy rainfall for all sites except the prairie. Nitrous oxide concentration gradients indicate that following heavy rainfalls the site of N2O production was moved from the surface deeper into the soil profile. We suggest that the source of N2O production near the surface is nitrification and that N2O is produced by denitrification of NO3 leached into the soil following heavy rainfall.
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    Biology and fertility of soils 1 (1985), S. 131-140 
    ISSN: 1432-0789
    Keywords: Nitrification ; MPN of ammonium oxidizers ; Chlorate inhibition ; Arable soil
    Source: Springer Online Journal Archives 1860-2000
    Topics: Biology , Geosciences , Agriculture, Forestry, Horticulture, Fishery, Domestic Science, Nutrition
    Notes: Summary The number of ammonium-oxidizing bacteria was measured with the most probable number (MPN) method while potential ammonium oxidation rates were determined with a chlorate inhibition technique in two arable soils. A new method for measuring actual in situ ammonium oxidation in soil cores is presented. One soil was cropped for 4 years with one of four crop-fertilizer combinations: Unfertilized lucerne ley, unfertilized barley, nitrate-fertilized grass ley, or nitrate-fertilized barley. The highest ammonium oxidizer numbers and potential rates were found in the grass ley. The unfertilized barley had one-third the number and activity of the grass ley. Actual rates were in general 5–25 times lower than potential rates. The other soil was that undergoing a 27-year-old field trial with a fallow and four different cropping treatments: No addition, nitrate, nitrate + straw, or manure. Ammonium oxidizer numbers were highest in the manure and straw treatments. MPN numbers and potential rates were lowest in the fallow treatment. Typical specific potential rates were 30 ng N oxidized cell−1 h−1. Actual rates were in general 40 times lower than potential rates. Actual ammonium oxidation measurements seem to correspond to actual in situ activity at the moment of sampling, whereas the MPN technique and the potential measurements reflect events that occurred weeks to months before the sampling.
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    Mathematical geology 17 (1985), S. 221-241 
    ISSN: 1573-8868
    Keywords: variograms ; covariance ; positive definite conditions ; kriging ; Modified Mercalli Intensity
    Source: Springer Online Journal Archives 1860-2000
    Topics: Geosciences , Mathematics
    Notes: Abstract Earthquake ground motion is a spatial phenomenon associated with local random behavior and global attenuation away from a source. By this description, ground motion is a regionalized variable. Analyses of directional variograms for earthquake ground motion reveal ansiotropic attenuation. For some earthquakes, a spatial structure exists in all directions and an average variogram can be developed. For other earthquakes, either a spatial structure can be identified only for restricted directions, or a spatial structure cannot be found to exist in any direction. A valid application of regionalized variables theory to the spatial analysis of earthquake ground motion must therefore be predicated on an initial, exhaustive analysis of estimated variograms. To estimate these data, an application of ordinary kriging is preferable to other more complex regionalized variables techniques to simplify the spatial analysis of earthquake ground motion.
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    Mathematical geology 17 (1985), S. 785-796 
    ISSN: 1573-8868
    Keywords: geostatistics ; kriging ; estimation variance
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    Topics: Geosciences , Mathematics
    Notes: Abstract This paper discusses the combination of kriging variances, which have been considered heretofor unfeasible since linearity of the problem and considerable simplifications which follow were overlooked. A simplified expression for global estimation variance is presented and an algorithm discussed with respect to precision and computer cost. A case study is presented, and, finally, an optimum calculation method is recommended.
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    Mathematical geology 18 (1986), S. 53-73 
    ISSN: 1573-8868
    Keywords: kriging ; mapping ; quadratic programming ; isopachs
    Source: Springer Online Journal Archives 1860-2000
    Topics: Geosciences , Mathematics
    Notes: Abstract Common features of models for interpolation, consistent with a finite number of inequality constraints on the range of values of a variablez, are discussed. A method based on constrained quadratic minimization yielding kriging estimates when no constraints exist, is presented. A computationally efficient formulation of quadratic minimization is obtained by using results on duality in quadratic programming. Relevant properties of the optimal interpolator are derived in a simple, self-contained way. The method is applied to mapping of horizon depth and estimation of thickness of an oil-bearing formation.
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    ISSN: 1573-8868
    Keywords: time (spatial) series ; prewhitening ; feedback ; transfer function ; residual variance ; forecasting ; kriging
    Source: Springer Online Journal Archives 1860-2000
    Topics: Geosciences , Mathematics
    Notes: Abstract Parametric time domain time series models for different chemical constituents such as SiO 2,Fe 2 O 3,TiO 2,MnO, and P 2 O 5 of iron ores belonging to banded hematite quartzites in Bicholim Mine (Goa) have been utilized for forecasting Fe 2 O 3 assay values through single/multiple input—single output (Fe 2 O 3 ) transfer function with noise methodology. Statistically significant correlated chemical constituent inputs (say, SiO 2,TiO 2,MnO, P 2 O 5 ) along lateral (horizontal strike direction) and vertical (perpendicular to bedding planes) sections in this mine are useful in modeling as well as forecasting assay values of blocks of ore to be exploited. Parameters of transfer function—noise models are estimated by utilizing time domain methodology, and the usefulness of these models for optimization of mining operations is discussed.
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    Mathematical geology 18 (1986), S. 33-51 
    ISSN: 1573-8868
    Keywords: kriging ; splines ; mapping ; prediction
    Source: Springer Online Journal Archives 1860-2000
    Topics: Geosciences , Mathematics
    Notes: Abstract Several kinds of data can provide information about a variable measured on a one- or two-dimensional space; at some points, the value is known to be equal to a certain number. At other points, the only information may be that the variable is greater or smaller than a given value. The theory of splines provides interpolating functions that can take into account both equality and inequality data. These interpolating functions are presented. The parallel between splines and kriging is reviewed, using the formalism of dual kriging. Coefficients of dual kriging can be obtained directly by minimizing a quadratic form. By adding some inequality constraints to this minimization, an interpolating function may be calculated which takes into account inequality data and is more general than a spline. The method is illustrated by some simple one-dimensional examples.
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    Mathematical geology 18 (1986), S. 653-676 
    ISSN: 1573-8868
    Keywords: approximate analysis ; covariance model ; kriging ; perturbation surface ; sensitivity analysis
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    Topics: Geosciences , Mathematics
    Notes: Abstract Universal kriging is an interpolation method for producing contour maps from irregularly spaced sample points, taking into account the trend (or polynomial drift), which is of known form. It assumes a known covariance model to express correlation of points a short distance apart. A sensitivity analysis examines how the fitted surface will change for given perturbations in the covariance model. We develop a simple approximate analysis in preference to exact analysis and show that it is adequate for small perturbations. For large data sets, a dramatic reduction in computer time is possible using approximate analysis. Possible extensions of this work are noted.
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    Mathematical geology 19 (1987), S. 25-39 
    ISSN: 1573-8868
    Keywords: geostatistics ; kriging ; Bayesian statistics
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    Topics: Geosciences , Mathematics
    Notes: Abstract Frequently a user wants to merge general knowledge of the regionalized variable under study with available observations. Introduction of fake observations is the usual way of doing this. Bayesian kriging allows the user to specify a qualified guess, associated with uncertainty, for the expected surface. The method will provide predictions which are based on both observations and this qualified guess.
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    Mathematical geology 19 (1987), S. 91-98 
    ISSN: 1573-8868
    Keywords: geostatistics ; kriging ; conditional simulation ; fast Fourier transform
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    Topics: Geosciences , Mathematics
    Notes: Abstract This paper reviews the turning band method and fast Fourier transform method of producing a nonconditional simulation of a multinormal random function with a given covariance structure. A review of the two common methods of conditioning the simulation to honor the data shows that they are formally equivalent. Another method for directly pondering a conditional simulation based on the LU triangular decomposition of the covariance matrix is presented. Computational and implementation difficulties are discussed.
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    Mathematical geology 20 (1988), S. 145-165 
    ISSN: 1573-8868
    Keywords: interval-valued data ; random function ; kriging
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    Topics: Geosciences , Mathematics
    Notes: Abstract Estimation procedures using data that include some “values” known to lie within certain intervals are usually regarded as problems of constrained optimization. A different approach is used here. Intervals are treated as elements of a positive cone, obeying the arithmetic of interval analysis, and positive interval-valued random functions are discussed. A kriging formalism for interval-valued data is developed. It provides estimates that are themselves intervals. In this context, the condition that kriging weights be positive is seen to arise in a natural way. A numerical example is given, and the extension to universal kriging is sketched.
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    Mathematical geology 20 (1988), S. 405-421 
    ISSN: 1573-8868
    Keywords: kriging ; nugget effect ; range ; sill ; variogram
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    Topics: Geosciences , Mathematics
    Notes: Abstract Suppose data {Z(s i ):i=1, ..., n} are observed at spatial locations {s i :i=1, ..., n}. From these data, an unknownZ(s 0) is to be predicted at a known locations 0c, or, ifZ(s0) has a component of measurement error, then a smooth versionS(s 0) should be predicted. This article considers the assumptions needed to carry out the spatial prediction using ordinary kriging, and looks at how nugget effect, range, and sill of the variogram affect the predictor. It is concluded that certain commonly held interpretations of these variogram parameters should be modified.
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    Mathematical geology 20 (1988), S. 459-475 
    ISSN: 1573-8868
    Keywords: Projection theorem ; kriging ; scalar product ; heteroscedasticity ; outlier resistance ; variogram ; distance measure
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    Topics: Geosciences , Mathematics
    Notes: Abstract The projection or minimum error norm algorithm does not require that the distance measure be a variogram. In non-Gaussian cases, the traditional variogram distance measure leading to minimization of an error variance offers no definite advantage. Other distance measures, more outlierresistant than the variogram, are proposed which fulfill the condition of the projection theorem. The resulting minimum error norms provide the same data configurations ranking as traditionally obtained from kriging variances. A case study based on actual digital terrain data is presented.
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    Mathematical geology 20 (1988), S. 699-715 
    ISSN: 1573-8868
    Keywords: Regionalized variables ; kriging ; interpolation ; sample reuse ; nonparametric error estimates ; confidence intervals
    Source: Springer Online Journal Archives 1860-2000
    Topics: Geosciences , Mathematics
    Notes: Abstract Use of intrinsic random function stochastic models as a basis for estimation in geostatistical work requires the identification of the generalized covariance function of the underlying process. The fact that this function has to be estimated from data introduces an additional source of error into predictions based on the model. This paper develops the sample reuse procedure called the “bootstrap” in the context of intrinsic random functions to obtain realistic estimates of these errors. Simulation results support the conclusion that bootstrap distributions of functionals of the process, as well as their “kriging variance,” provide a reasonable picture of variability introduced by imperfect estimation of the generalized covariance function.
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    Mathematical geology 17 (1985), S. 563-586 
    ISSN: 1573-8868
    Keywords: generalized least squares ; kriging ; median polish ; robustness ; stationarity
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    Topics: Geosciences , Mathematics
    Notes: Abstract The method of weighted least squares is shown to be an appropriate way of fitting variogram models. The weighting scheme automatically gives most weight to early lags and down-weights those lags with a small number of pairs. Although weights are derived assuming the data are Gaussian (normal), they are shown to be still appropriate in the setting where data are a (smooth) transform of the Gaussian case. The method of (iterated) generalized least squares, which takes into account correlation between variogram estimators at different lags, offer more statistical efficiency at the price of more complexity. Weighted least squares for the robust estimator, based on square root differences, is less of a compromise.
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    Mathematical geology 18 (1986), S. 529-537 
    ISSN: 1573-8868
    Keywords: geostatistics ; kriging ; nugget effect ; soil sampling ; support
    Source: Springer Online Journal Archives 1860-2000
    Topics: Geosciences , Mathematics
    Notes: Abstract Short-range variation of measurements of a soil characteristic is a function of the support (i.e., size, shape, and orientation of the physical sample taken at a sample point) of the soil samples. This short-range variance often shows up as a substantial component of the “nugget effect” in experimental semivariograms or estimated generalized covariance functions. Proper choice of support may substantially reduce short-range variance (or nugget) of measurements made at sample points and thereby reduce estimation variance in point or block kriging based on these measurements. Appropriate variance formulas and an example are given for determination of support when support is an array of vertical cores (or bucket auger samples) of equal depth and diameter.
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    Mathematical geology 18 (1986), S. 93-117 
    ISSN: 1573-8868
    Keywords: deterministic ; “estimation variance” ; interpolation ; geostatistics ; kriging ; least-squares prediction ; ore deposit assessment ; probabilistic ; semivariogram ; statistical inference
    Source: Springer Online Journal Archives 1860-2000
    Topics: Geosciences , Mathematics
    Notes: Abstract Components of geostatistical estimation, developed as a method for ore deposit assessment, are discussed in detail. The assumption that spatial observations can be treated as a stochastic process is judged to be an inappropriate model for natural data. Problems of semivariogram formulation are reviewed, and this method is considered to be inadequate for estimating the function being sought. Characteristics of bivariate interpolation are summarized, highlighting kriging limitations as an interpolation method. Limitations are similar to those of inverse distance weighted observations interpolation. Attention is drawn to the local bias of kriging and misplaced claims that it is an “optimal” interpolation method. The so-called “estimation variance,” interpreted as providing confidence limits for estimation of mining blocks, is shown to be meaningless as an index of local variation. The claim that geostatistics constitutes a “new science” is examined in detail. Such novelties as exist in the method are shown to transgress accepted principles of scientific inference. Stochastic modeling in general is discussed, and purposes of the approach emphasized. For the purpose of detailed quantitative assessment it can provide only prediction qualified by hypothesis at best. Such an approach should play no part in ore deposit assessment where the need is for local detailed inventories; these can only be achieved properly through local deterministic methods, where prediction is purely deductive.
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    Mathematical geology 18 (1986), S. 197-213 
    ISSN: 1573-8868
    Keywords: disjunctive kriging ; nonlinear geostatistics ; kriging ; earthquake ground motion
    Source: Springer Online Journal Archives 1860-2000
    Topics: Geosciences , Mathematics
    Notes: Abstract For earthquake ground motion studies, the actual ground motion distribution should be reproduced as accurately as possible. For optimal estimation of ground motion, kriging has been shown to provide accurate estimates. Although kriging is accurate for this application, some estimates it provides are underestimates. This has dire consequences for subsequent design for earthquake resistance. Kriging does not provide enough information to allow an analysis of each estimate for underestimation. For such an application, disjunctive kriging is better applied. This advanced technique quantifies the probability that an estimate equals or exceeds particular levels of ground motion. Furthermore, disjunctive kriging can provide improved estimation accuracy when applied for local estimation of ground motion.
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    Mathematical geology 18 (1986), S. 477-488 
    ISSN: 1573-8868
    Keywords: kriging ; nugget effect ; range ; semivariogram ; geostatistics
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    Topics: Geosciences , Mathematics
    Notes: Abstract In geostatistics, an estimation of blocks of a deposit is reported along with the variance of error made in their estimation. This calculation is based on the model chosen for the semivariogram of the deposit so that mistakes in its estimation can manifest themselves in the perception of accuracy with which blocks are known. Changes in kriging variance resulting from various amounts of error in modeling the relative nugget effect and range of the semivariogram are investigated for an extensive set of spherical semivariograms.
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    Mathematical geology 19 (1987), S. 467-479 
    ISSN: 1573-8868
    Keywords: random vectors ; spatial analysis ; vector variogram ; kriging ; rock fracture orientation ; structural modeling
    Source: Springer Online Journal Archives 1860-2000
    Topics: Geosciences , Mathematics
    Notes: Abstract Geostatistics is extended to the spatial analysis of vector variables by defining the estimation variance and vector variogram in terms of the magnitude of difference vectors. Many random variables in geotechnology are in vectorial terms rather than scalars, and its structural analysis requires those sample variable interpolations to construct and characterize structural models. A better local estimator will result in greater quality of input models; geostatistics can provide such estimators: kriging estimators. The efficiency of geostatistics for vector variables is demonstrated in a case study of rock joint orientations in geological formations. The positive cross-validation encourages application of geostatistics to spatial analysis of random vectors in geoscience as well as various geotechnical fields including optimum site characterization, rock mechanics for mining and civil structures, cavability analysis of block cavings, petroleum engineering, and hydrologic and hydraulic modelings.
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    Mathematical geology 19 (1987), S. 769-783 
    ISSN: 1573-8868
    Keywords: Cross-validation ; geostatistics ; intrinsic random functions of orderk ; kriging
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    Topics: Geosciences , Mathematics
    Notes: Abstract A procedure is proposed that employs first-moment estimation (kriging), cross-validation, and response surface analysis to estimate parameters of a generalized covariance function. Results from application of this procedure to two data sets are given.
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    Mathematical geology 20 (1988), S. 189-203 
    ISSN: 1573-8868
    Keywords: kriging ; variogram ; robustness ; estimation variance
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    Topics: Geosciences , Mathematics
    Notes: Abstract The robustness of the kriging system with respect to uncertainty of the theoretical variogram is investigated. Inequalities for possible changes of the kriging estimator and the estimation variance are derived. Results of a numerical study show that changes of kriging weights can be predicted partly with the help of the maximal kriging weight.
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    Geotechnical and geological engineering 3 (1985), S. 155-159 
    ISSN: 1573-1529
    Keywords: Estimation variance ; geostatistics ; interpolation ; kriging
    Source: Springer Online Journal Archives 1860-2000
    Topics: Geosciences
    Notes: Conclusions The foregoing discussion indicates that geostatistical estimation of ore deposits is not local; it is not objective; it is not sensitive to local data trends; and it is not unrestrained by the range of data values. Kriging, as an interpolation method, is a variant of IDW least squares linear fit. As such, it suffers from the limitations of all IDW linear interpolation methods that employ only data values. The estimation variance, currently used to calculate the confidence limits of values for individual mining blocks, is hypothetical and globally derived. It is more closely related to sampling density than to local variation in the data set. Geostatistical methods, of course, have a real place in ore deposit assessment, e.g. global, comparative evaluation to assist decisions on development and investment. What is questioned here is the validity of employing a global method to assess detail (mining blocks) within an ore deposit.
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    Transport in porous media 4 (1989), S. 585-598 
    ISSN: 1573-1634
    Keywords: Geostatistics ; kriging ; groundwater ; inverse problem
    Source: Springer Online Journal Archives 1860-2000
    Topics: Geosciences , Technology
    Notes: Abstract Co-kriging equations for log-transmissivity and heads are derived for a two-dimensional stochastic model. The behavior of the weights as a function of the unknown value of mean hydraulic gradient J are discussed and the procedure is illustrated by studying the ‘screening’ effects of adjacent measurements and added head measurements. In addition, the bias of the estimator for head values is studied when J is also estimated.
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