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  • Organic Chemistry  (6,096)
  • GEOPHYSICS  (3,342)
  • 1995-1999  (2,909)
  • 1980-1984  (6,529)
Collection
Keywords
Publisher
Years
Year
  • 1
    Electronic Resource
    Electronic Resource
    Untersuchungen über den Thermischen Zerfall von n-Dodecylcyclopentan in der Gasphase (1982)
    New York, NY : Wiley-Blackwell
    Journal für Praktische Chemie/Chemiker-Zeitung 324 (1982), S. 964-972 
    Details
    ISSN: 0021-8383
    Keywords: Chemistry ; Organic Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: Investigations on the Thermal Decomposition of n-Dodecylcyclopentane in the Gas PhaseIn the thermal decomposition of n-dodecylcyclopentane at 670 and 750°C in a laboratory tubular reactor mixtures of hydrogen and 57 and 113 hydrocarbons respectively are formed. The mixtures have been analyzed and identified by capillary gas chromatography and by mass spectrometry. The distribution of the reaction products is used for mechanistic discussions.
    Additional Material: 2 Ill.
    Type of Medium: Electronic Resource
    URL: http://dx.doi.org/10.1002/prac.19823240615
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    Paper (German National Licenses)
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  • 2
    Electronic Resource
    Electronic Resource
    Kinetische Untersuchungen zur Pyrolyse von Mono-n-alkyl-cyclohexanen (1983)
    New York, NY : Wiley-Blackwell
    Journal für Praktische Chemie/Chemiker-Zeitung 325 (1983), S. 66-74 
    Details
    ISSN: 0021-8383
    Keywords: Chemistry ; Organic Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: Kinetic Investigations of the Pyrolysis of Mono-n-alkyl-cyclohexanesThe thermal decomposition of cyclohexane and six mono-n-alkylcyclohexanes was studied kinetically in a metallic laboratory tubular reactor at 650 to 850°C and atmospheric pressure.Kinetic parameters were found to be a function of length of the alkylic side chain. A comparison with analogous parameters of n-paraffins and the unsubstituted cyclohexane allowed the conclusion that C—C-scission in the alkylic chain is the initial reaction in pyrolysis of n-alkylcyclohexanes followed by radical attacks to all C—H-bonds of the feed molecules.
    Additional Material: 4 Ill.
    Type of Medium: Electronic Resource
    URL: http://dx.doi.org/10.1002/prac.19833250109
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    Paper (German National Licenses)
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  • 3
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    Plasma entry into the distant tail lobes - ISEE-3 (1984)
    In:  Other Sources
    Details
    Publication Date: 2011-08-19
    Description: ISEE-3 measurements indicate that a broad mantle-like boundary layer plasma often exists within the distant geomagnetic tail lobes at all latitudes, directly adjacent to the tail magnetopause. The presence of this boundary layer at large tail distances indicates that plasma from the magnetosheath often crosses the magnetopause locally along much of the length of the tail, and is evidence that the tail is 'open'.
    Keywords: GEOPHYSICS
    Type: Geophysical Research Letters (ISSN 0094-8276); 11; 1078-108
    Format: text
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    NASA TECHNICAL REPORTS
  • 4
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    Detailed examination of a plasmoid in the distant magnetotail with ISEE 3 (1984)
    In:  Other Sources
    Details
    Publication Date: 2019-06-28
    Description: Details of an investigation of a lone plasmoid encountered by the ISEE-3 spacecraft in February 1983 are reported. ISEE-3 was then at 217 earth radii distance, in the magnetosheath, and had entered the magnetotail. Intense energetic particle, plasma and magnetic field fluctuations were detected, indicating a large electron flux moving tailward, a suprathermal proton flux, a jump in electron temperature, and inverse signatures of an increasing magnetic field. Closed magnetic field lines were also detected as were IMF field lines around the plasmoid and open field lines connecting the earth with space. The hot particles in the plasmoid are concluded to have been magnetically confined in a boundary one earth radius thick. An earthward directed beam was also detected and was found to balance the tailward flux. The origin and characteristics of the beam were not discerned.
    Keywords: GEOPHYSICS
    Type: Geophysical Research Letters (ISSN 0094-8276); 11; 1046-104
    Format: text
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  • 5
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    Correlated dynamical changes in the near-earth and distant magnetotail regions - ISEE 3 (1984)
    In:  Other Sources
    Details
    Publication Date: 2019-06-28
    Description: It is pointed out that the redeployment of ISEE 3 from its continuous monitoring of the solar wind in a large orbit about the upstream Lagrangian point to an extended magnetotail orbit has afforded an opportunity for deep-tail passage of October 1982, and in the radial range from 200 to 220 R(E) during the near-apogee part of the second tail passage in January-February 1983. Attention is given to instrumentation and data sets, spacecraft positions, and observational data.
    Keywords: GEOPHYSICS
    Type: Journal of Geophysical Research (ISSN 0148-0227); 89; 3855-386
    Format: text
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    NASA TECHNICAL REPORTS
  • 6
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    Application of the MHD energy principle to magnetostatic atmospheres (1984)
    In:  CASI
    Details
    Publication Date: 2019-06-28
    Description: The MHD energy principle is applied to the stability of a magnetized atmosphere which is bounded below by much denser fluid, as is the solar corona. The two fluids are treated as ideal; the approximation is consistent with the energy principle, and the dynamical conditions that must hold at a fluid-fluid interface are used to show that if vertical displacements of the lower boundary are premitted, then the lower atmosphere must be perturbed as well. However, displacements which do not perturb the coronal boundary can be properly treated as isolated perturbations of the corona alone.
    Keywords: GEOPHYSICS
    Type: NASA-CR-175967 , NAS 1.26:175967
    Format: application/pdf
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    NASA TECHNICAL REPORTS
  • 7
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    Surface elevation contours of Greenland and Antarctic ice sheets (1983)
    In:  Other Sources
    Details
    Publication Date: 2011-08-18
    Description: Preliminary results from Seasat radar altimetry over Antarctica north of 72 deg S and Greenland south of 72 deg N are presented. Surface elevations of the ice sheets, obtained from computer retracking of the radar altimeter waveforms, are contoured at 50-m intervals for Greenland and at 100-m intervals for Antarctica. Elevation differences at orbital crossover points are analyzed to obtain a precision of 1.9 m; this figure is partly determined by radial errors of approximately 1.0 m in orbital determination and partly by noise due to ice surface irregularities. Adjustment of the radial components of the orbits to minimize the differences in elevations at crossovers over a small, relatively flat region reduces the rms difference to 0.25 m, which is indicative of the optimum precision obtainable over the ice sheets. However, the precision degrades as the slope of the surface or amplitude of the undulations increases, yielding an overall precision of + or - 1.6 m.
    Keywords: GEOPHYSICS
    Type: Journal of Geophysical Research; 88; Feb. 28
    Format: text
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  • 8
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    Results from an absolute gravity survey in the United States (1983)
    In:  Other Sources
    Details
    Publication Date: 2011-08-18
    Description: Using the recently completed JTLA absolute gravity meter, we made a survey of twelve sites in the United States. Over a period of eight weeks, the instrument was driven a total distance of nearly 20,000 km to sites in California, New Mexico, Colorado, Wyoming, Maryland and Massachusetts. The time spent in carrying out a measurement at a single location was typically one day. We report the results of the measurements in this survey along with earlier measurements made with the instrument, discuss the measurement accuracy and compare our results with other measurements. Previously announced in STAR as N83-20480
    Keywords: GEOPHYSICS
    Type: Journal of Geophysical Research (ISSN 0148-0227); 88; Sept. 10
    Format: text
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  • 9
    Electronic Resource
    Electronic Resource
    Determination of the enantiomeric purity of commercial Jacobsen's catalyst samples (1998)
    New York, NY [u.a.] : Wiley-Blackwell
    Chirality 10 (1998), S. 362-363 
    Details
    ISSN: 0899-0042
    Keywords: Jacobsen's catalyst ; enantiomeric purity determination ; chiral HPLC ; cyclodextrin chiral stationary phases ; enantioseparation ; Chemistry ; Organic Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: A HPLC method is described for the chiral analysis of the commercially available Jacobsen's catalyst. A hydroxypropyl β-cyclodextrin stationary phase was used in conjunction with a nonaqueous, polar-organic mobile phase. The method can be applied to control the enantiomeric purity of the catalyst, which is of great importance for quality control of that product. High accuracy in the determination of trace levels of the unwanted enantiomer in the presence of large amounts of the desired enantiomer is demonstrated. Chirality 10:362-363, 1998. © 1998 Wiley-Liss, Inc.
    Additional Material: 1 Ill.
    Type of Medium: Electronic Resource
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    Paper (German National Licenses)
  • 10
    Electronic Resource
    Electronic Resource
    2, 3-Disubstituted γ-Butyrolactams from the Michael-Additions of Doubly Deprotonated, Optically Active β-Hydroxycarboxylates to Nitroolefins. Preliminary Communication (1980)
    New York, NY : Wiley-Blackwell
    Helvetica Chimica Acta 63 (1980), S. 2005-2009 
    Details
    ISSN: 0018-019X
    Keywords: Chemistry ; Organic Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: The conjugate addition of the chiral, non-racemic alkoxy-enolates 5 and 6 to nitroolefins furnishes the hydroxynitroesters 7-13, which are catalytically hydrogenated to give the lactams 14-18. The configuration of adduct 7 from nitroethylene was elucidated by NMR. analysis of the acetal 20 derived from 7. The assignment establishes that the reaction follows the stereochemical rule of attack depicted in 21 and previously deduced for other electrophiles, i.e. formation of erythro-products of type 3b and 4b. No stereocontrol was found at the newly formed chiral centers in α- and β-position to the NO2 group of 8-12.
    Additional Material: 1 Tab.
    Type of Medium: Electronic Resource
    URL: http://dx.doi.org/10.1002/hlca.19800630727
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