ALBERT

Notes: Book reviewed in this article: SOILpak for Cotton Growers. Third edition 1998. Edited by David C. McKenzie.

Notes: Abstract. Preferential flow has been increasingly recognised as a major component of water movement in many soils, particularly clays. This paper reviews problems in the measurement of solute fluxes in these soils, and discusses the solutions that have been adopted in UK studies of cracking clay soils. The estimation of solute fluxes is subject to many sources of error, which are best reduced by replicated measurements, such as those available in multi-plot experiments.

Notes: Abstract. Soil cores from river marginal wetlands from three sites in the UK (Torridge and Severn catchments), sampled and restrained in PVC piping, were flooded with dilute aqueous potassium nitrate. Half of the cores were sterilized prior to flooding to destroy the denitrifying bacteria. The change in nitrate concentration in the flood-water was measured over time. It is argued that the observed nitrate depletion rates (from 1.2 to 4.7 kg ha−1 d−1) is the result of microbially-mediated denitrification. The results show the method to be a simple and direct procedure for the assessment of spatial variation in nitrate-sink capacity. The depth of the denitrifying layer at the soil–water interface was confirmed to be of the order of a few mm only. A one-dimensional model for the diffusive flux in the flooded soil was developed which, on differentiation, gave a predictive expression for denitrification rate in terms of the effective soil diffusion coefficient for nitrate, the flood-water depth and concentration, and the thickness of the microbially active zone.

Notes: Book reviewed in this article: The Soils and Land Use Potential of the Southern and Eastern Slopes of Kilimanjaro, Tanzania.

Notes: Abstract. A database of 1065 fields in all parts of Finland, two soil profiles (augerhole borings) per field, was screened for acid sulfate (a.s.) soils. Each field represented 2100 14;ha of cultivated land. Soil pH and redox potential were determined in the field, at intervals of 10 14;cm, to a depth of 200 14;cm. Of the maximum of 124 profiles considered as a.s. soils according to the Soil Taxonomy and ILRI (International Institute of Land Reclamation and Improvement) systems, 46 profiles exhibited pH 〈3.5. These represented 48 14;000 14;ha of land. More than half of these severely acidic soils were associated with reduced subsoils and probably contained actively oxidizing sulfidic materials within 150 14;cm of the soil surface, while the remaining profiles were oxidized at least down to 150 14;cm. Using Soil Taxonomy criteria, the total area of cultivated a.s. soils was 67 14;000–130 14;000 14;ha. The minimum estimates exclude soils that may be leached or too low in sulfide to meet the criteria of a.s. soils. Application of the ILRI system produced an estimate of 61 14;000–130 14;000 14;ha. In the maximum estimate, 27% of the profiles were raw, 61% ripe and 12% potential a.s. soils. According to the FAO/UNESCO system, the area of cultivated a.s. soils (pH 〈3.5 or assumed sulfidic materials) is considerably less: 43 14;000–78 14;000 14;ha. All these estimates are only a fraction of the area considered to be covered by a.s. soils by established Finnish criteria. The choice of estimate has important economic implications for liming subsidies and planning regulations for the drainage of a.s. soils.

Notes: Abstract. The effect of increasing rates of nitrogen (N) fertilizer on the yield response of 3 or 4 consecutive winter cereal crops after ploughing out grass was investigated at six field sites on commercial farms in England and Wales. Amounts of N required for an economically optimum yield (〉3 kg of grain for each kg of fertilizer N applied) ranged from 0 to 265 kg ha−1 and were dependent on soil N supply, but not on crop yield. Optimum N rates were large (mean 197 kg N ha−1) at three sites: two sites where cereals followed 2-year grass leys receiving low N inputs (〈200 kg N ha−1), and at one site where a cut and grazed 4-year ley had received c. 315 kg N ha−1 of fertilizer N annually. At the other three sites where 4 and 5-year grass leys had received large regular amounts of organic manures (20–30 t or m3 ha−1) plus fertilizer N (c. 300 kg ha−1 each year), optimum N rates were low (mean 93 kg N ha−1) and consistently over-estimated by the farmer by an average of 107 kg N ha−1. Optimum N rates generally increased in successive years after ploughing as the N supply from the soil declined. Determination of soil C:N ratio and mineral N (NO3N+NH4N) to 90 cm depth in autumn were helpful in assessing fertilizer N need. The results suggest there is scope to improve current fertilizer recommendations for cereals after grass by removing crop yield as a determinant and including an assessment of soil mineralizable N during the growing season.

Notes: Abstract. Soils, of clay texture, were taken from two crop rotations in a long term trial, (i) maize - spring oats - maize, (ii) maize - spring oats - autumn oats - red clover, and from an adjacent uncropped fenceline. Wet sieving was preceded by wetting under vacuum, wetting under tension or by direct immersion. The undisturbed soil was the most stable; the inclusion of clover in the rotation improved aggregate stability. Direct immersion was most disruptive in disintegrating aggregates followed by vacuum and pre-wetting under tension.

Notes: Abstract. A decision support system to predict the plant availability of nitrogen (N) following organic manure applications to land has been developed, drawing together the latest UK research information on factors affecting manure N availability and losses. The ADAS MANure Nitrogen Evaluation Routine (MANNER) accounts for manure N analysis, ammonia volatilization, nitrate leaching and mineralization of manure organic N. Only a few easily available inputs are required to predict the amount of N volatilized or leached, and the fertilizer N value for the next crop grown. Predictions from MANNER have been evaluated by comparison with independently collected data from a range of experimental studies where pig, cattle and poultry manures were applied to arable crops. Good agreement was found (r2 60–79%, P〈0.001), confirming that MANNER can provide a reliable estimate of the fertilizer N value of farm manures spread to arable land under a range of conditions.

Notes: Abstract. A lysimeter study from April 1993 to June 1997 assessed the effects of winter cover crops and unfertilized grass on both the volume of water draining over winter and the amounts of nitrate leached. There were three to five replicates of each treatment in a fully randomized design. The lysimeters were undisturbed monoliths of loamy medium sand, 1.2 m deep and 0.8 m diameter.There were six treatments: sown cover before spring-sown crops (SC), natural regeneration (‘tumbledown’) before spring-sown crops (T), unfertilized grass (UG), bare soil permanent fallow, (PF), winter barley (WB) and conventional overwinter fallow before spring-sown crops (WF). Sugarbeet replaced cereals in 1996 as a disease break, and in consequence no cover was established in SC and T in autumn 1996. Of the four years of the study, two were above-average rainfall, while two were of less than average rainfall. Results are only quoted if statistically significantly different from WB (P=0.10).Over the first winter, NO3―N losses were similar under UG (26 kg ha−1) and PF (29 kg ha−1), due to the slow establishment and growth of the grass. In the following three winters NO3―N losses under UG were small (c. 6 kg ha−1), giving an overall mean of c. 11 kg ha−1. Sown cover crops and T gave means of c. 16 and 22 kg ha−1 respectively, compared with c. 27–31 kg ha−1 under PF, WB and WF.Mean NO3―N concentrations were smallest under UG (4.4 mg l−1) and SC (10.6 mg l−1), although both T (13.7 mg l−1) and PF (12.4 mg l−1) were less than under WB and WF (15.8–18.7 mg l−1). Overwinter drainage was greatest from UG and PF, at 239 and 247 mm respectively. In the three winters that cover crops were grown, drainage was decreased by, on average, 30 mm year−1 compared with WF. However, there were large differences in effects between years, with significant decreases in only one year.We conclude that the widespread adoption of cover crops before spring-sown crops will reduce overwinter drainage in UK Nitrate Vulnerable Zones by no more than c. 2%, compared with no cover before spring-sown crops.

Notes: Abstract. Gross N mineralization and nitrification rates were measured in soils treated with dairy shed effluent (DSE) (i.e. effluent from the dairy milking shed, comprising dung, urine and water) or ammonium fertilizer (NH4Cl) under field conditions, by injecting 15N-solution into intact soil cores. The relationships between gross mineralization rate, microbial biomass C and N and extracellular enzyme activities (protease, deaminase and urease) as affected by the application of DSE and NH4Cl were also determined. During the first 16 days, gross mineralization rate in the DSE treated soil (4.3–6.1 μg N g−1 soil day−1) were significantly (P 14;〈 14;0.05) higher than those in the NH4Cl treated soil (2.6–3.4 μg N g−1 soil day−1). The higher mineralization rate was probably due to the presence of readily mineralizable organic substrates in the DSE, accompanied by stimulated microbial and extracellular enzyme activities. The stable organic N compounds in the DSE were slow to mineralize and contributed little to the mineral N pool during the period of the experiment. Nitrification rates during the first 16 days were higher in the NH4Cl treated soil (1.7–1.2 μg N g−1 soil day−1) compared to the DSE treated soil (0.97–1.5 μg N g−1 soil day−1). Soil microbial biomass C and N and extracellular enzyme activities (protease, deaminase and urease) increased after the application of the DSE due to the organic substrates and nutrients applied, but declined with time, probably because of the exhaustion of the readily available substrates. The NH4Cl application did not result in any significant increases in microbial biomass C, protease or urease activities due to the lack of carbonaceous materials in the ammonium fertilizer. However, it did increase microbial biomass N and deaminase activity. Significant positive correlations were found between gross N mineralization rate and soil microbial biomass, protease, deaminase and urease activities. Nitrification rate was significantly correlated to biomass N but not to the microbial biomass C or the enzyme activities. Stepwise regression analysis showed that the variations of gross N mineralization rate was best described by the microbial biomass C and N.

Notes: Abstract. The efficient use of biologically fixed N in agriculture is important in organic farming and when N fertilizers are either expensive or unavailable. The aim of the study was to determine the effects of cultivation and sowing dates on the efficiency of use of biologically fixed N built up during a period of grass/clover ley by subsequently sown ryegrass. Dates of cultivation in two field experiments conducted in consecutive years (1994/95 and 1995/96) ranged from August to October and sowing was carried out either immediately after cultivation or after a delay of one month. Nitrate-N losses through leaching, herbage yields and N offtake by ryegrass were measured from 1994 to 1996. A laboratory experiment was carried out to assess net N mineralization and nitrification in the soil of the field experiment under different conditions.The utilization of mineralized N ranged from 30 to 100 kg ha−1 in both field experiments. Herbage yield and recovery of mineralized N by ryegrass was greater when sowing was carried out immediately after cultivation than when it was delayed for one month. Cultivation in late October was inferior to cultivation in August or September but the optimum date (August to September) differed between the two years (1994/95 and 1995/96) due to differences in weather, especially rainfall, affecting N leaching during the germination and early growth phases. Indeed the main differences in the efficiency of utilization of mineralized N between treatments could be attributed to differences in NO3–N leaching losses during the autumn establishment period. Decreases in soil temperature during autumn resulted in a modest decrease in net N mineralization but a much more substantial decrease in the rate of nitrification, which has implications for NO3–N leaching. The optimum time for cultivation cannot be refined to a particular calendar date but reasonably accurate long-term rainfall forecasts in conjunction with data on soil moisture deficit would provide the means to set an optimum cultivation date.

Notes: Abstract. Deterministic leaching models are used to estimate regional losses of nitrate from agricultural land to the environment. The estimated leaching losses are associated with uncertainty arising from uncertainty in the input data used. In the present case study we have assessed this uncertainty by use of Monte Carlo analysis, using the Latin hypercube sampling technique. Input data have preferably been adopted from publicly available data. Data which could not be retrieved from the databases was assessed by guided estimates or based on local data. The estimated annual leaching loss from the study region was around 106 kg N ha−1, which is in agreement with previous findings. The uncertainty in the leaching expressed in terms of coefficients of variation (CV) depended on the agricultural practices. CV's for arable farm rotations, cattle farm rotations, and pig farm rotations were around 20, 30 and 40%, respectively. Breakdown of the total uncertainty into contributions of different error sources did not isolate one single all important source.

Notes: Abstract. The nitrogen (N) conserving effects of Italian ryegrass (Lolium multiflorum L.) undersown as a nitrate catch crop in spring barley (Hordeum vulgare L.) were evaluated over a ten-year period in outdoor lysimeters (1.5 m deep, diam. 1 m) with sandy loam soil. Spring barley grown every year received 11.0 or 16.5 g N m−2 before planting or was kept unfertilized. The N was given either as calcium ammonium nitrate or as ammoniacal N in pig slurry. From 1985 to 1989, ryegrass was undersown in the barley in half of the lysimeters while barley was grown alone in the remaining lysimeters. The grass sward was left uncut after barley harvest and incorporated in late winter/early spring. From 1990 to 1994 all lysimeters were in barley only.Barley dry matter yields and crop N offtakes were not affected by the presence of undersown ryegrass, although grain yields appeared to be slightly reduced. After termination of ryegrass growing, N offtake in barley (grain+straw) was higher in lysimeters in which catch crops had been grown previously.The loss of nitrate by leaching increased with N addition rate. Regardless of N dressing, ryegrass catch crops halved the total nitrate loss during 1985–1989, corresponding to a mean annual reduction in nitrate leaching of 2.0–3.5 g N m−2. From 1990 to 1994, lysimeters previously undersown with ryegrass lost more nitrate than lysimeters with no history of ryegrass. The extra loss of nitrate accounted for 30% of the N retained by ryegrass catch crops during 1985–1989.It is concluded that a substantial proportion of the N saved from leaching by ryegrass catch crops is readily mineralized and available for crop offtake as well as leaching as nitrate. To maximize benefits from ryegrass catch crops, the cropping system must be adjusted to exploit the extra N mineralization derived from the turnover of N incorporated in ryegrass biomass.

Notes: Abstract. Escherichia coli serotype O157 is a virulent human pathogen the global incidence of which has increased. It has been demonstrated that cattle are the primary reservoir of this pathogen. This has serious implications for the land-based disposal of organic wastes such as cattle manure, cattle slurry and abattoir waste. Further, it also has serious ramifications for the protection of surface and groundwater drinking supplies and public access to pasture land. However, while soil and vegetation can be expected to directly influence the survival of this pathogen, there is a paucity of information concerning the behaviour and survival of E. coli O157 in agricultural environments. It appears that E. coli O157 presently contaminates between 1 to 15% of UK cattle herds, depending on region, and that faecal excretion of the bacterium shows a distinct seasonality which also reflects the incidence of human infections. E. coli O157 can remain viable in soil for greater than 4 months and appears to be a highly resilient pathogen possessing the capability to adapt easily to environmental stresses. While most human cases of E. coli O157 related food poisoning have been associated with the consumption of contaminated meat and dairy products, there is also evidence that human infection has occurred through the ingestion of contaminated soil, fruit and vegetables and drinking water. In this review the potential threat to human health posed by the application of contaminated organic wastes to soil and possible strategies for reducing the amount of pathogen entering the food chain are highlighted.

Notes: Book reviewed in this article: Gaseous Nitrogen Emissions from Grasslands Edited by S.C. Jarvis & B.F. Pain.

Notes: Abstract. Growing cover crops during the winter before spring-planted crops is often suggested as an effective method to decrease nitrate leaching. A four-course crop rotation (potatoes-cereal-sugarbeet-cereal) was followed through two rotations on a sandy soil in the English Midlands. Three management systems were imposed on the rotation to test their effects on nitrate loss. The effects of cover crops on nitrate leaching and crop yields were compared with the more conventional practice of over-winter bare fallow before potatoes and sugarbeet.Cover crop N uptake was variable between years, averaging 25 kg ha−1, which is typical of their performance on sandy soils in the UK. The cover crops usually decreased nitrate leaching but their effectiveness depended on good establishment before the start of drainage. Over 7 years, cover crops decreased the average N concentration in the drainage from 24 to 11 mg l−1. Potato yield and tuber N offtake increased after cover crops. Ware tuber yield increased by an average of c. 8%; this was unlikely to be due to additional N mineralization from the cover crop because the potatoes received 220–250 kg fertilizer N ha−1, and non-N effects are therefore implicated. Sugar yield was not increased following a cover crop.After 8 years of nitrate-retentive practices, there were no measurable differences in soil organic matter. However, plots that had received only half of the N fertilizer each year contained, on average, 0.14% less organic matter at the end of the experiment.

Notes: Abstract. The Pilot Nitrate Sensitive Areas Scheme was set up in England in 1990 to test measures aimed at reducing nitrate losses from agricultural land. Ten groundwater catchments were chosen to typify the geology and farming of areas where nitrate concentrations in abstracted water were high. Voluntary and compensated controls on farming, based on recent research, were introduced. Scheme membership was for 5 years from 1990 or 1991, and 86% of the agricultural land entered the Scheme. On all farms entering the Scheme, manure and fertilizer use were restricted and green cover crops were required over winter (Basic Scheme). Additional payments were available for conversion of arable land to zero or low-input grassland (Premium Scheme). Intensive pig and poultry farmers were assisted with the costs of transporting manure for spreading over a wider area. The most effective changes were improved management of livestock manures, especially of the very large local quantities from housed pig or poultry units; conversion of arable land to low-input grassland; and use of cover crops. There were no indications of reduced crop yields but some requirements increased costs and management complexities. Estimates based on both model calculations and measurements indicated that nitrate losses from agricultural land decreased by about 30%, with considerable variation between areas.

Notes: Abstract. The structure of soils in areas of rain forest cleared for pasture is often compacted due to trampling by animals. When pasture is abandoned, regeneration of forest cover may be achieved from natural seed sources nearby.However, the regeneration of soil structure is also important for local hydrology and successful establishment of some plant species. In this study we investigated changes in soil structure and hydraulic properties in a series of plots on volcanic soils in the San Luis Valley, Costa Rica. The plots were current pasture, 15- and 20-year-old regenerating forest, and primary rain forest.Infiltration rate increased with increasing forest age and the water release characteristic reverted gradually from one with greater water retention at all matric potentials in the pasture plot towards that found in the primary forest. Compaction and low porosity were features of both the current pasture and 15-year-old regenerating forest in comparison to the primary forest.

Notes: Abstract. Over 170 countries have ratified the UN Framework Convention on Climate Change (UNFCCC) which aims at ‘the stabilisation of greenhouse gases in the atmosphere at a level that will prevent dangerous anthropogenic interference with the climate system’. The Kyoto Protocol, signed in 1997, commits the developed (‘Annex 1′) countries to a reduction in gaseous emissions. The global increase in atmospheric CO2, the main greenhouse gas, comes mainly from fossil fuels (6.5 Gt C yr−1), together with about 1.6 Gt C yr−1 from deforestation. The atmospheric increase is only 3.4 Gt C yr−1, however, due to a net sink in terrestrial ecosystems of about 2 Gt C yr−1, and another in the oceans. Increasing net carbon sequestration by afforestation of previously non-forested land is one way of reducing net national emissions of CO2 that is permitted under the Kyoto Protocol. Future modifications may also allow the inclusion of carbon sequestration brought about by other forestry and agricultural land management practices. However, associated changes in net fluxes of two other greenhouse gases identified in the Protocol — nitrous oxide (N2O) and methane (CH4) — will have to be taken into account. Growth of biomass crops can increase N2O emissions, and drainage of wetlands for forestry or agriculture also increases them, as well as emissions of CO2, while decreasing those of CH4. The problems of how to quantify these soil sources and sinks, to maximize soil C sequestration, and to minimize soil emissions of CH4 and N2O, will present a major scientific challenge over the next few years — one in which the soil science community will have a significant part to play.

Notes: Abstract. The effectiveness of Festuca ovina and Poa pratensis as contour grass strips for erosion control was examined in a laboratory experiment for an crodible sandy loam soil on 21, 25 and 29% slopes. No significant differences P〈0.05 were observed in runoff between the plots with grass strips and bare soil but significant differences in soil loss were recorded. Both grasses reduced crosion in the early part of the simulated storms by ponding water behind the barrier, filtering sediment and causing deposition within the ponded area. The P. pratensis barrier was less rigid and became flattened under submergence in the later part of the storms. Runoff flowed over the grass strip forming rills on the slope below, which then cut back and undermined the barrier. These barriers resulted in as much soil loss as bare soil towards the end of the storms on all three slopes. The F. ovina was effective in controlling erosion on the 21% and 25% slopes but not on the 29% slope.

Notes: Abstract. The recommended method of reducing the emission of NH3 while spreading manure is to plough or harrow the manure into the soil. This in turn increases the possibility of N2O emission. At two sites in southern Sweden emissions of NH3 and N2O were measured after spreading pig slurry by broadcasting and band spreading. The band spreading technique can be used in growing crops i.e. when nitrogen is most needed, and it is thought that the NH3 emission is smaller with this technique compared to broadcasting. The average NH3 loss was 50% of applied NH4+ during warm/dry conditions and 10% during cold/wet conditions. The N2O emission was always less than 1% of applied NH4+. When the NH3 emission decreased, the direct N2O emission increased. However, when taking into account the indirect N2O emission due to deposition of NH3 outside the field, the spreading techniques all produced similar total N2O emissions. The ammonia emission was not much lower for the band spreading technique compared to broadcasting, when compared on seven occasions.

Notes: Book reviewed in this article: Soil Erosion at Multiple Scales: Principles and Methods for Assessing Causes and Impacts Edited by F. W. T. Penning de Yries, F. Agus & J. Kerr

Notes: Abstract. Solutions collected from lysimeters of acid soils can show pH values close to or even above neutral. Laboratory experiments on an acid soil from Burundi were planned to test if denitrification or CO2 degassing might explain such a paradox. In the first experiment, soil profiles were reconstituted in columns and leached with 55 μm Ca(NO3)2 solutions at 30 °C and 4 °C. Two drainage regimes were applied: intermittent suction or no suction at the bottom of the columns. In the second experiment, pH values were measured in solutions drained from different horizons at 30 °C, before and after equilibration with ambient air. Sterilized soil was also tested in the same way. Results from experiment 1 showed that despite the accumulation of water in the bottom of soil profiles when no suction was applied, aeration still existed so that reduction reactions, namely denitrification, are not expected to affect greatly the percolate composition. Indeed nitrate concentration was similar in both drainage regimes and was close to the input value. The pH values in percolates were close to 7 at 30 °C and they dropped to about 5.5 when the columns were at 4 °C. In experiment 2, equilibration of percolates with ambient air resulted in pH increase which was greater for the top horizon (C-rich) but negligible when the soil was first sterilized. These convergent results illustrate the very important effect of CO2 degassing on pH of drained solutions when microbial activity is stimulated at high temperatures, in C-rich soil. This is of prime importance when interpreting results from lysimeter experiments. By chance, this study also showed that large quantities of nitrate can be produced in soil at low temperatures.

Notes: Abstract. As leaching of nutrients and agrochemicals can occur readily in cracking clay soils, which are important to UK agriculture, it is essential to identify management systems for them that can minimize the risk of contaminants reaching surface waters. The long-term Brimstone Farm study has provided considerable evidence on the movement of water and solutes through such soils and offers a unique opportunity to determine the factors influencing these processes. Management procedures, such as subsurface drainage and tillage, which are widely used for the production of cereals in these soil types, greatly influence the risk of contamination. At Brimstone Farm, tillage has been shown to change the hydrology in terms of both water table control and the route of water movement, and to increase the mineralization of nitrogen and the consequent risk of nitrate leaching. Drainage, essential in these soils, also creates a risk of solute losses, especially pesticides. Ways to retain effective drainage yet decrease losses to surface waters are discussed.

Notes: Abstract. Sustaining soil fertility under agricultural intensification and expansion onto marginal lands is a significant challenge in the Nepalese Middle Mountains. In a detailed watershed study it was shown that the overall soil fertility is poor, forest soils display the poorest conditions as a result of biomass removal, and sustaining agriculture is questionable due to the transformation from traditional to multiple cropping systems. Parent material is a significant factor influencing low phosphorus status while insufficient inputs create deficiencies in total carbon, nitrogen and bases. A nutrient budget model was developed to assess inputs, redistribution and losses relative to soil fertility. Yield, input and management data obtained from farm interviews, and soil analysis data were used in the calculation of nutrient budgets. Results from modelling indicate declining soil fertility under rainfed agriculture, forest and rangelands, and marginal conditions under irrigated agriculture subject to intensive cultivation. Nutrient deficits were relatively low for irrigated rice-wheat systems, which benefit from nutrient inputs via sediments and irrigation waters, but the introduction of triple cropping showed greater deficits. Nutrient balances were most critical under rainfed maize production where 94% of the farms were in deficit. Current shortages of organic matter make elimination of nutrient deficits problematic but improvement of composting, biological N-fixation and fertilizer efficiency and reducing erosion were found to be potential options.

Notes: Abstract. During three consecutive years (1993–1995) a split-plot design with three replications was used to study the biological and physical role of mulch in the improvement of crusted soil water balance and its productivity in the north of Burkina Faso. The main treatment was the use of an insecticide, to obtain plots with and without soil fauna (SF and NSF). The subsidiary treatment consisted of four mulch types randomly applied on subplots. These were straw of Pennisetum pedicellatum applied at 3 t ha−1, woody material of Pterocarpus lucens applied at 6 t ha−1 and composite (woody material and straw) treatments applied at 4 t ha−1. In addition there was a control, with no mulch (bare plot). Data on soil faunal activity, runoff, sediment accumulation from wind blown soil, vegetation cover and vegetation dry matter yield were collected on all plots.The biological activity (mainly termites) in mulched plots was the key element in the efficacy of mulching to rehabilitate crusted soil. Water infiltration and dry matter yield were statistically lower on NSF plots than on SF plots and runoff and dry matter yield were not different from the values obtained on bare plots. A significant correlation was found between runoff, all vegetation data and termite-voids. Sediment accumulation due to the physical barrier of the mulch was not found to be a significant factor in the improvement of vegetation performance and the reduction of runoff.

Notes: Abstract. Ammonia volatilization with and without gypsum incorporation was measured in Gujranwala soil (Udic Haplustalf) in an incubation study using different nitrogen fertilizers e.g. urea, ammonium sulphate (AS), calcium ammonium nitrate (CAN), and urea nitrophos (UNP). Nitrogen from different fertilizers was applied at the rate of 200 mg N kg−1 to two sets of soils in plastic bags (1.0 kg soil) and plastic jars (0.5 kg soil). Soil moisture was maintained at field capacity. Application of urea increased soil pH to 9, three hours after its addition. Ammonium sulphate and calcium ammonium nitrate had little effect on soil pH. Ammonium volatilization losses from fertilizers were related to the increase in soil pH caused by the fertilizers. Consequently maximum losses were recorded due to application of urea. Losses through ammonia volatilization were significantly lower with AS, CAN and UNP in descending order. Gypsum incorporation significantly reduced the losses. Therefore, application of gypsum to soil before urea may substantially improve N use efficiency for crop production by reducing N losses.

Notes: Abstract. Precision farming is the process of adjusting husbandry practices within a field according to measured spatial variability. In this review, we explore the prospects for precision farming using the principles that underly conventional soil management and agronomy.The cost-effectiveness of precision farming is determined by the cost of defining zones within fields, the stability of zones through time, the difference in treatment between zones in terms of cost, and the responsiveness of the crop in terms of yield and quality to changes in treatment. Cost-effective precision farming is most likely where prior knowledge indicates large heterogeneity and where treatment zones can be predicted, for example from soil type or field history.Soil related factors are likely to provide the main basis for precision farming because they tend to be stable through time and influence crop performance. In particular, soil mapping may usefully indicate the moisture available for crop growth, organic matter maps may be utilized for precision application of fertilizers and soil acting herbicides, and variation in soil pH can be mapped and used as a basis for variable lime application. However, comprehensive nutrient mapping is less likely to be economic with existing techniques of chemical analysis. The value of yield mapping lies in identifying zones which are sufficiently stable to be of use in determining future practices. Maps of grain quality and nutrient content would significantly augment the value of yield maps in guiding marketing decisions and future agronomy. Interactions between soil differences and seasonal weather are large, so yield maps show considerable differences from season to season. Interpretation of such maps needs to follow a careful, informed, analytical process.Extensive and thorough field experimentation by crop scientists over many years has shown that yield variation arises as a result of a large and complex range of factors. It is highly improbable that simple explanations will be appropriate for much in-field yield variation. However, the capacity to sense yield variability within fields as opposed to between fields, where there are many confounding differences, provides an opportunity for the industry to improve its understanding of soil-based effects on crop performance. This should support its decision taking, whether through precision farming or through field-by-field agronomy.The main obstacle to the adoption of precision farming is the lack of appropriate sensors. Optimal sensor configurations that will measure the specific needs identified by end-users need to be developed.The conclusions reached in this paper probably apply to farming throughout northern Europe.

Notes: Abstract. A lysimeter experiment showed a decrease in maximum concentrations and total losses of the herbicide isoproturon leached from a heavy clay soil where the topsoil had a finer, deeper tilth than with a standard agricultural tilth. Volumes of leachate for the first flow event of the season were also smaller and leaching of bromide was slower. The isoproturon was radiolabelled so that its movement could be assessed using a novel radio-scanning technique. Bypass flow began close to the surface as a scan at 8 cm depth showed that only 0.5% of the total soil area had an activity more than four times the nominal background level. At depths of 10–20 cm, isoproturon was preferentially retained within areas of very fine aggregates. No radioactivity was detected in the scans below 20 cm depth, suggesting little or no retention of isoproturon during transport through the subsoil to the bottom of the lysimeter. Rhodamine-B dye injected to the base of the topsoil (approximately 20 cm depth) was also used to assess flow pathways through the subsoil. The dye spread laterally across the interface between topsoil and subsoil and then penetrated the subsoil through cracks and fissures. Even within cracks, transport of dye frequently occurred through only a very small proportion of the total crack area. The macropore flow model MACRO 4.0 was used to simulate results from the lysimeter experiment. The fourfold decrease in maximum concentrations of herbicide from the finer tilth lysimeter could be predicted by varying only a parameter describing aggregate sizes at depths of 6–24 cm, suggesting that transfer of herbicide between macropore and micropore regions was faster in the finer tilth. Differences in concentrations of bromide could be simulated only by adjusting the soil hydraulic parameters for the fine tilth to reflect a slight decrease in the predominance of bypass flow relative to matrix flow.

Notes: Abstract. Degradation of isoproturon in a heavy clay soil followed first-order reaction kinetics with half-lives at 15 °C of 27 and 208 days in the topsoil and subsoil, respectively. Adsorption when shaken with 3 mm sieved samples of the soil fitted the empirical Freundlich relationship with k values of 3.25 in the topsoil and 1.06 in the subsoil. Adsorption in a static system with different sized aggregates of soil did not reach equilibrium, even after 24 hours contact, and the rate of adsorption was slower with larger aggregates. Following an adsorption period of 24 hours, desorption equilibrium was reached more rapidly with larger (6–10 mm) than with smaller (〈3 mm) aggregates. Adsorption isotherms measured in a static system with a soil:water ratio typical of field conditions in winter also indicated less adsorption than that measured in shaken, laboratory systems with low soil:water ratios. The rate of change in water extractable residues of the herbicide was more rapid than that of total extract-able residues following application of isoproturon to the heavy clay soil in the field. The implications of the results for isoproturon leaching under field conditions are discussed.

Notes: Book reviewed in this article: Land Resources: Now and for the future By A. Young.

Notes: Abstract. In order to optimize the management of the N-fertilizer inputs with drip fertigation on sandy-silt soil under apple tree orchard cultivation, we observed in situ: (i) the N and water soil transfers, (ii) the N levels in all leaves, fruits and annual shoots, and (iii) the root distribution. Then we used a mechanistic one-dimensional model (WAVE, Vanclooster et al., 1994) to quantify the annual parameters of the water and nitrogen balance on a daily basis. The horizontal heterogeneity along the row of the tree-soil-dripper system has been treated with two adjacent compartments: one under the dripper and receiving fertigation and the other outside this zone. N transfers in the tree make it impossible to estimate directly N uptake by roots over time.The simulated N losses were due to equal amounts of N leaching below 0.9 m deep (9 g N tree−1year−1 and denitrification (7 g N tree−1year−1. The simulated losses of gaseous N were localized predominantly in the compartment under the dripper and showed a higher rate of leaching during the period of N input when the wet conditions and the high NO3− concentrations were favourable to denitrification. The N-leaching at 0.9 m depth was greatest outside the growing season and was caused by the extension of the N-inputs after the harvest date. This practice, based on the objective to store nitrogen before the period of dormancy does not seem to be justified.

Notes: Abstract. People in the Southern Highlands of Papua New Guinea cultivate some land semi-continuously within a regime of shifting cultivation; the staple crop is sweet potato (Ipomoea batatas). The fertility of Tropepts, variably affected by falls of volcanic ash, was investigated to give further understanding of how subsistence farmers avoid the soil constraints that commonly prompt abandonment. While organic matter, N and K all decrease significantly with time under cultivation, they do not reach critical levels. Phosphorus also decreases significantly over time, although contents are small throughout. Other nutrients show no significant variation with period of use or abandonment. These findings comply with the diversity of crops cultivated early in the life of ‘gardens’, followed by sweet potato, cultivated as a virtual monocrop in long established ‘gardens’. It continues yielding adequately regardless of decrease in nutrient availabilities, notably because nutrient ratios remain favourable for tuberisation and because of sweet potato's tolerance of small phosphorus concentrations. It appears that burning of vegetation significantly increases available minerals and helps maintain a supply which is adequate for longterm sweet potato monoculture. Similar situations are postulated for other areas of less-weathered soils within the tropics.

Notes: Abstract. The mean extractable sulphur (S) concentration in 315 upland topsoil samples collected in 1988/89 from beneath pasture in NE Scotland was 13 μg S g−1 (range 2–77 μg S g−1). More than two thirds of the samples had S concentrations less than that acceptable for productive soils. Continued decreases in atmospheric S inputs may have increased this proportion subsequently. The analysis of herbage S also indicated that two-thirds of the samples were below 0.2% S. A ‘respirometric index’, namely CO2 produced during cellulose decomposition without added S as a percentage of that produced with added S, was significantly less than 100% in a quarter of the soils. Results of three different extraction procedures suggested that sulphate in the soils was present mainly as free plus adsorbed rather than precipitated forms. Soil extraction identified a significant non-sulphate S fraction, presumably organic S. The variability in extractable S stemmed from a combination of geographical, depositional and local site and soil factors. Extractable S was significantly correlated with soil organic matter content and inversely with soil pH and together these factors explained 37% of the variability. While significant differences in mean concentrations between geographical area, soil association and drainage status were evident, no trends could be observed between the major soil subgroups or with altitude.

Notes: Abstract. We investigated whether a polyacrylate polymer could be used to remediate a soil which had been contaminated with copper for many years. Perennial ryegrass was grown in a loamy sand containing 230 mg ammonium-acetate-EDTA extractable Cu kg−1 and amended with 0, 0.1 and 0.2% of polymer. Growth of perennial ryegrass was stimulated in the polymer-amended soil, especially in the soil with 0.1% of polymer. After plant growth for 177 days, the amount of water extractable copper present in the unamended soil was 17 times that of the original soil. In the soil amended with 0.1% of polymer the level of copper after plant growth was only 0.11 times the amount present in the unamended soil. When the soil was incubated with polymer in the absence of plants, the level of water extractable copper was not reduced. The polymer seems to compete with plants for copper, and to prevent the increase of copper in soil solution brought about by root exudates.

Notes: Abstract. Soils developed on volcanic parent materials have many intrinsic qualities favourable to cropping. However, fertility decreases dramatically when they are badly managed. A short review and case studies from Réunion and Guadeloupe highlight the special characteristics of these soils, and their response to management.The interplay of cropping systems and physical characteristics of Andisols is first considered through the example of Pelargonium and food crop systems in Réunion. Progressive decrease in production and cropping potential shows in falling yields as well as in the overall decline of the system. The example of banana production in Guadeloupe highlights the increase in inputs needed to realise the land's potential and to maintain yields, in particular more tillage and pest treatment.In both cases, these trends are connected to the co-evolution of soil characteristics and cropping systems. They lead to an increase of risks with less security and less scope in the choice of cropping systems. Technical solutions in the form of erosion-control measures, rotation and planting techniques have been developed and prove to be relevant and consistent in their benefit.

Notes: Abstract. Soil classification is a tool for stratifying and generalizing information on soil resources but most systems are tailored to handle only slightly disturbed soil. We tested the applicability of the legend of the FAO-Unesco Soil Map of the World and the new World Reference Base for Soil Resources by classifying at the highest order 831 profiles from a nationwide 7 km grid survey in Denmark, where soils are developed in Quaternary glacial and marine sediments and intensively farmed. Comparison of the variability of pH and % clay +% silt of the master horizons (A, E, B, and C) within and between the major well-drained soil groupings shows that liming, fertilizing and ploughing have produced significantly deeper A-horizons with higher pH, lower % humus and C:N ratios on the two-thirds of the country that is cultivated. ‘Anthropogenic’ mollic and umbric horizons are a common result but the liming causes a random final classification of these surface horizons and, hence, random allocation of the soils in both systems. It separates cultivated soils and their undisturbed equivalents, and results in considerable within-group variation in soil texture. Grouping of cultivated and undisturbed soils, on the other hand, results in wide within-horizon pH ranges for most groups, again compromising the advantage of making useful general statements on the basis of classification.We propose that anthropogenic mollic and umbric horizons should be allowed in any soil group and that ‘anthric properties’ should be used to distinguish between profoundly changed cultivated soils and largely undisturbed soils, hereby constructing a two-tier system within each highest-order soil group. We classified the soils according to this proposal. The results show generally narrower ranges for both pH and % clay +% silt. We evaluated the within-group homogeneity by multivariate analysis of variance of pH, % clay +% silt, % clay, % humus, C:N ratio, exchangeable cations, and CEC. The results (Wilks's Lamda) show a higher degree of group compactness compared to the original FAO and World Reference Base systems.

Notes: Abstract. In dairy farming systems the risk of nitrate leaching is increased by mixed rotations (pasture/arable) and the use of organic manure. We investigated the effect of four organic farming systems with different livestock densities and different types of organic manure on crop yields, nitrate leaching and N balance in an organic dairy/crop rotation (barley–grass-clover–grass-clover–barley/pea–winter wheat–fodder beet) from 1994 to 1998. Nitrate concentrations in soil water extracted by ceramic suction cups ranged from below 1 mg NO3-N l−1 in 1st year grass-clover to 20–50 mg NO3-N l−1 in the winter following barley/pea and winter wheat. Peaks of high nitrate concentrations were observed in 2nd year grass-clover, probably due to urination by grazing cattle. Nitrate leaching was affected by climatic conditions (drainage volume), livestock density and time since ploughing in of grass-clover. No difference in nitrate leaching was observed between the use of slurry alone and farmyard manure from deep litter housing in combination with slurry. Increasing the total-N input to the rotation by 40 kg N ha−1 year−1 (from 0.9 to 1.4 livestock units ha−1) only increased leaching by 6 kg NO3-N ha−1. Nitrate leaching was highest in the second winter (after winter wheat) following ploughing in of the grass-clover (61 kg NO3-N ha−1). Leaching losses were lowest in 1st year grass-clover (20 kg NO3-N ha−1). Averaged over the four years, nitrate concentration in drainage water was 57 mg l−1. Minimizing leaching losses requires improved utilization of organic N accumulated in grazed grass-clover pastures. The N balance for the crop rotation as a whole indicated that accumulation of N in soil organic matter in the fields of these systems was small.

Notes: Abstract. Eight lysimeters, each with a surface area of 0.5 m2 and a length of 60 cm, were taken over mole drains from a Denchworth soil and divided into two groups with either a standard agricultural tilth or a finer, deeper topsoil tilth. They were variously instrumented to measure soil moisture content at three depths and losses of nitrate, a bromide tracer and radiolabelled isoproturon, all of which were followed over a year. Leaching of isoproturon was initiated by artificial irrigation either 1 or 39 days after application. The finer tilth seemed to increase the water-holding capacity of the topsoil, and this resulted in slower wetting of the subsoil, decreased flow volumes from the first events of the season and a delay of approximately four weeks in the time to the maximum concentration of the bromide tracer in leachate. The finer topsoil tilth also decreased maximum concentrations of isoproturon from 29 to 15 μg l−1 following irrigation 1 day after treatment and from 43 to 9 μg l−1 following irrigation 39 days after treatment. Total losses of isoproturon were three times larger with the standard agricultural tilth. Differences were attributed to a decrease in bypass flow through the topsoil with the finer tilth, particularly during events early in the season. There was a small decrease in total losses of nitrate in leachate from the finer tilth compared to that from the standard tilth.

Notes: Abstract. The effects of afforestation on potential nitrification, nitrification and ammonification rates were studied at an experimental site in NE Scotland 4½ years after afforestation of former arable land. The site had been planted with three tree species (Sitka spruce, sycamore and hybrid larch) at three different planting densities, with half the plots treated with inorganic NPK fertilizer. Laboratory measurements of potential nitrification, nitrification and ammonification rates, measured using a perfusion system, were compared between the unforested control and combinations of the various treatments. Differences in soil pH and soil moisture content were also investigated.Potential nitrification rates measured in plantation soils were significantly lower than in the unplanted control soil. Nitrification and ammonification rates were also consistently lower, although these differences were only significant in a few of the treatments. Soils planted with a normal tree density had a tendency to show higher nitrification rates compared to soils planted with a high tree density.The results suggest that afforestation of former agricultural soils may cause changes in important parts of the soil N cycle soon after planting. At this early stage in the life of the plantation this appears to be unrelated to changes in soil pH or moisture content, even though soils beneath the trees are drier. The apparent change may be the result of differences in the soil microbial community associated with the type of organic matter substrate present in the unplanted and planted soils.

Notes: Abstract. Increasing concerns for the financial and environmental impact of the use of broadcast fertilizer by the UK horticultural industry is leading to the development of alternative application techniques, which aim to reduce inputs through improved efficiency. One such technique, ‘starter’ fertilizer, was investigated with drilled and transplanted crisp lettuce (Lactuca sativa) on two fertile peaty soils. Starter fertilizers injected below the seed of the drilled crop, or as spot applications around the planting module, were tested alone and in various combinations with different rates of broadcast fertilizer. The work extended previous findings, based largely on mineral soils, and demonstrated that high yields of iceberg quality lettuce can be achieved with reduced inputs of broadcast fertilizer, and that there can be additional benefits of earlier maturity and improved quality. It is concluded that starter fertilizer can contribute to the development of environmentally beneficial farming practices whilst maintaining the productivity and competitiveness of the horticultural industry.

Notes: Abstract. Ancient forests which have never been under agriculture often have larger ecological and pedological value than later established forests. We made a reconstruction of the land use history of the Meerdaal forest complex in central Belgium since 1759. Soil profiles of 33 recent forest sites and of contiguous forest parcels were examined morphologically by augering to 120 cm depth. pHKC1 was determined on samples from every horizon. The data were analysed by Principal Component Analysis, and the axes were used as a basis for derivation of horizon parameters. Former agricultural land use since 1759 can still be recognized in three soil morphological characteristics: colour of the eluviation horizon, intactness of the horizon containing illuviated clay and thickness of the organic layer. These parameters were combined into a ‘naturalness index’, which differs significantly between ancient and recent forest and can be easily and cost-effectively obtained to assess the degree of man-made disturbance of forests on loess-derived soils.

Notes: Abstract. A long-term lysimeter experiment with undisturbed monoliths studied leaching behaviour and balances of phosphorus (P), potassium (K) and nitrogen (N) during a seven year crop rotation on four types of soil receiving inorganic fertilizers, manure and grass compost respectively. It was shown that application of manure did not lead to any direct change in nutrient leaching, unlike the application of fertilizers to soils of normal fertility. However, soil type considerably affected the nutrient concentrations in the drainage water.Manure applied in amounts equal to the maximum animal density allowed by Swedish legislation slightly oversupplied P and N (0.5–3.5 and 18–38 kg ha−1 y−1 respectively) compared to the crop requirement and leaching losses for most of the soils. The relationship between lactate-soluble P in the topsoil and the concentrations of dissolved P in the drainage water was very strong. However the strength of this relationship was dependent on just one or two soils. P losses from a fertile sandy soil were large (1–11 kg ha−1 y−1) throughout the crop rotation and average crop removal (13 kg ha−1 y−1) plus the leaching losses were not balanced (average deficit 3–6 kg ha−1 y−1) by the addition of fertilizer, manure or grass compost. No decreasing trend was found in the P losses during seven years. However, the K deficit (average 26 kg ha−1 y−1) led to a significant reduction in the leaching trend from this soil. The other soils that had a smaller K deficit showed no significant reduction in the leaching of K.

Notes: Abstract. Guizhou province has one of the most severe soil erosion problems in China, with 44% of its total area affected. Within the province, Bijie prefecture is the most severely eroded with 63% of the total area affected. In recent decades this erosion is mainly caused by man's agricultural and industrial development. Not only is erosion restricting crop production, it is the cause of disastrous floods which recur with a frequency far greater than in the past. Reduced infiltration of rain has led to a third of the wells and a fifth of the streams running dry, depriving people and livestock of drinking water.This unsustainable use of land can only be corrected by a combination of population control, prevention of slash and burn cultivation and return of steeply sloping land to forest and grassland. Greater appreciation of the need for soil and water conservation is an essential part of this process.

Notes: Ground water radon concentrations have been measured in nested piezometers and an open borehole in fractured, metasedimentary aquifers in the Clare Valley, South Australia. The vertical radon concentration profile within the undisturbed, open borehole appears to indicate the locations of hydraulically active fractures. If radon concentrations within the aquifer are uniform, then the highest radon concentration within the borehole will indicate the location of the highest flow rate into the bore. In relatively short screened piezometers, radon concentrations have been measured both before and after purging. The ratio of radon concentration before to after purging normalizes for variations in aquifer mineralogy, and can be used to quantify the ground water flow rate.

Notes: Recession flow has long been considered a composite of exponential terms, where each exponential term represents a different source of water discharged from the watershed. The changing slopes in the semi-logarithmic plot of the discharge have been considered indicative of the decreasing contribution of surface runoff and interflow to the discharge. The results of this analysis show that the changing slope in the recession plot can be the consequence of baseflow drainage. This can invalidate the semi-logarithmic baseflow separation technique when applied to some hydrologic settings.

Notes: Statistical properties of combined Shewhart-CUSUM control charts are examined in terms of the site-wide false positive rate, false negative rate, and average run length (i.e., the average number of sampling events that it takes to detect a significant exceedance). The effects of multiple comparisons (i.e., multiple monitoring wells and constituents), verification resampling, background sample size, and background updating are incorporated into the analysis. The effects of (1) verification resampling plans including no resampling, pass one resample, pass one of two resamples, and pass two of two resamples; (2) background sample sizes (n = 8,12,16,20, and 24); and (3) multiple comparisons (k = 1 to 500 future comparisons) were examined. In addition, various alternative control limit factors (h = SCL= 4.5, 5.0,5.5, and 6.0) were considered, where the control limit is x + hs. Results of simulations revealed that it is possible to balance site-wide false positive and false negative rates at low levels using combined Shewhart-CUSUM control charts. The results revealed that it is important to select the appropriate multiplier, verification resampling plan, number of background samples, and number of intervening samples prior to updating background.

Notes: Flow simulation is difficult to implement in heterogeneous media such as karst aquifers, primarily because the structure of the rock is extremely complex and usually unknown. The aim of this study was to verify the possibility of using inverse modeling and an equivalent porous media to identify transmissivities in a slightly karstified aquifer, the La Rochefoucauld karst (Charente, France). Different simulation scenarios were tested: using two spatial discretizations with different finite-element cell sizes and using measured or interpolated heads. The inverse modeling was performed with the downscaling parameterization procedure, using a finite-element representation of bidimensional ground water flow. The inverse modeling converged satisfactorily with all scenarios: head residuals were small and spring flow rates and the river/aquifer exchanges were adequately simulated. The scenario using small cells and measured heads generated a highly heterogeneous transmissivity field, indicating an overpa-rameterization of the problem. The calibrated transmissivities and simulated heads of this scenario proved less reliable overall than those of the other scenarios. The use of interpolated heads generated more uniform transmissivities as a result of the head smoothing. A rotation of the initial parameter mesh showed that the scenarios using interpolated heads generate the most stable and reliable results. The scenarios with interpolated heads could therefore be used when head measurements are limited or are unevenly distributed over the aquifer. Overall, the calibrated transmissivities reproduced the entire range of transmissivities measured in the field using different methods. The results indicate that inverse modeling and an equivalent porous media can be used to determine transmissivities in a moderately karstified aquifer.

Notes: This paper compares and contrasts stochastic optimization and decision analysis as frameworks for the design of remedial pump-and-treat systems in contaminated aquifers. Both decision-making frameworks (1) seek a least-cost, low-risk remedial design; (2) consider uncertainty due to partial knowledge of field environments, which causes imperfect predictive capability of simulation; (3) target predictive uncertainty due to spatially variable hydraulic conductivities and handle it by invoking geostatistical uncertainty theory, and (4) deal with the design and economic impacts of uncertainty by employing the concept of reliability or its complement the probability of failure. The fundamental difference between the two approaches lies in the fact that decision analysis considers a broad suite of technological strategies from which one of many predetermined design alternatives is selected as the best, while stochastic optimization determines the optimal pump-and-treat design but considers only one technological strategy at a time. The early stochastic optimization formulations sought to quantify the cost of overdesign needed to achieve greater performance reliability. The procedure involved a cost minimization that led to the development of a trade-off curve of cost versus reliability. For each point on the trade-off curve a single-valued optimum was achieved by defining a preset level of desired reliability. Decision analysis has always involved a cost-risk minimization, in which a single-valued optimum is obtained by simultaneously accounting for all costs, including the risk costs associated with the probability of failure. Risk costs are assigned a dollar value based on the level of expected reliability; a trade-off curve is not needed. More-recent formulations using stochastic optimization follow the philosophy of the decision-analysis framework by accounting for risk costs through a penalty cost. Using the latter approach, we show that the objective functions in both frameworks are virtually identical.A decision maker should adopt a decision-analysis framework if he or she (1) wants to minimize total system cost by selecting the best design alternatives from among a specified set, (2) has a known risk-cost preference (utility function), (3) wants to consider a broad suite of technological alternatives, and (4) is willing to accept the numbers, locations, and pumping rates for wells that are the best of those under consideration but are not necessarily optimal. The advantages of decision analysis lie in the ease with which capital costs can be incorporated, and the ability to examine alternative designs that span multiple technologies. The disadvantages revolve around the difficulty in determining a decision maker's utility function, selecting a single-valued design as the best from the predefined set of design alternatives, and the inefficiencies introduced by the need for a full enumeration of the design alternatives. A decision maker should adopt optimization if he or she (1) is interested in a truly optimal selection of well locations and pumping rates, (2) has an unknown or uncertain risk-cost preference, and (3) is comfortable considering a single remedial technology at a time. The advantages of optimization lie in its clever and efficient methodologies for identifying a global optimum. The main disadvantages lie in the difficulties associated with a rigorous consideration of capital costs for nonlinear problems, and the fact that solutions do not typically span multiple technologies. The choice of whether to employ optimization or decision analysis as a design tool is not necessarily an either/or proposition, and we suggest possible avenues for their combined use.

Notes: Spatial and temporal characteristics of the saline springs that emerge along the western shore of the Sea of Galilee (Lake Kinneret) are analyzed. Three groups of onshore springs (Tiberias, Fuliya, and Tabgha) and two groups of offshore springs (Barbutim and Maagan), contribute saline water to the lake with concentrations in the range of 300 to 18,000 mgCl/L, depending on location and season. It is well accepted that water emerging from these springs is a mixture of two endmembers: deep-seated saline ground water and shallow, fresh circulating ground water. Temporal trends of discharge rates and of chloride (representing the deep saline aquifer) and nitrate (representing the shallow fresh water aquifer) concentrations within each group of springs are presented. Results show the proportions of the two water bodies while mixing are time dependent. Discharge and concentration peaks in Tabgha springs precede those in Fuliya and Tiberias springs by approximately two months. An analytical solution shows that in Tabgha, variations of these parameters are mainly controlled by recharge variations in the Galilee, and follow an exponential function. In Fuliya and Tiberias, variations of these parameters are mainly dependent on lake level, and follow a sine-cosine function. The different patterns are attributed to different hydraulic properties of the discharge area.

Notes: Pumping and slug tests are widely used, relatively simple methods for estimating hydraulic conductivity and storage coefficient. This study tested the reproducibility of pumping and slug tests in estimating aquifer parameters in fractured or fractured porous media. The continuum concept is applied to represent the hydraulic properties by the conventional conductivity and storage coefficient. Repeated tests show discrepancies wider than can be attributed to probable measurement errors or incomplete curve fitting. The sources of discrepancy include turbulent head loss in an observation well, pumping well location, data acquisition period (pumping or recovery), selection of analysis method, test initiation mechanism, applied initial displacement, and selection of data segment for analysis. When we employ a specific test practice or choose a specific analysis method or data segment for the analysis, the resulting parameter estimates show characteristic patterns of distribution with respect to the mean value. This study analyzes the patterns and discusses how to improve the reliability of the parameter estimation.

Notes: Benzene, toluene, ethyl benzene and xylene (BTEX) dissolved into ground water and migrated from a light nonaqueous phase liquid (LNAPL) source in a sandy aquifer near a petroleum, oil, and lubricants (POL) facility at Hill Air Force Base (AFB), Utah. Field observations indicated that microbially mediated BTEX degradation using multiple terminal electron-accepting processes including aerobic respiration, denitrification, Fe(III) reduction, sulfate reduction, and methanogenesis has occurred in the aquifer. To study the transport and transformation of dissolved BTEX compounds under natural conditions, a reactive flow and transport model incorporating biochemical multispecies interactions and BTEX was developed. The BTEX, oxygen, nitrate, Fe(II), sulfate, and methane plumes calculated by the model agree reasonably well with field observations. The first-order biodegrada-tion rate constants, estimated based on model calibration are 0.051, 0.031, 0.005, 0.004, and 0.002 day−1 for aerobic respiration, denitrification, Fe(III), sulfate reduction, and methanogenesis, respectively. The results of a sensitivity analysis show that the saturated aquifer thickness, hydraulic conductivity, and reaction rate constants are the most critical parameters controlling the natural attenuation of BTEX at this site. The hydraulic conductivity and aquifer thickness were found to be the key factors affecting the restoration of oxygen, nitrate, and sulfate after their interaction with the BTEX plume. The multispecies reactive transport modeling effort, describing BTEX degradation mediated by multiple electron-accepting processes, represents one of the few attempts to date to quantify a complete sequence of natural attenuation processes with a detailed field data set. Because the case study is representative of many petroleum-product contaminated sites, the results and insights obtained from this study are of general interest and relevance to other fuel-hydrocarbon natural attenuation sites

Notes: Ground water production wells commonly are designed to maximize well yield and, therefore, may be screened over several water-bearing zones. These water-bearing zones usually are identified, and their hydrogeologic characteristics and water quality are inferred, on the basis of indirect data such as geologic and geophysical logs. Production well designs based on these data may result in wells that are drilled deeper than necessary and are screened through zones having low permeability or poor-quality ground water. In this study, we examined the application of flowmeter logging and depth-dependent water quality samples for the improved design of production wells in a complex hydrogeologic setting. As a demonstration of these techniques, a flowmeter log and depth-dependent water quality data were collected from a long-screened production well within a multilayered coastal aquifer system in the Santa Clara-Calleguas Basin, Ventura County, California. Results showed that the well yields most of its water from four zones that constitute 58% of the screened interval. The importance of these zones to well yield was not readily discernible from indirect geologic or geophysical data. The flowmeter logs and downhole water quality data also show that small quantities of poor-quality water could degrade the overall quality of water from the well. The data obtained from one well can be applied to other proposed wells in the same hydrologic basin. The application of flowmeter and depth-dependent water quality data to well design can reduce installation costs and improve the quantity and quality of water produced from wells in complex multiple-aquifer systems.

Notes: Under certain circumstances, wells in unconfined aquifers can display significant water level fluctuations in response to changes in barometric pressure. This is illustrated by Hare and Morse (1997) at a site where a portion of the unconfined aquifer is isolated by a soil-bentonite cutoff wall and clay cap. A relief well located within the containment system displays water level fluctuations that mirror barometric pressure changes. Water levels fluctuated 0.37 m in response to barometric pressure changes of 2.87 centimeters mercury (cm-Hg), representing a barometric efficiency of 93.6%. As described in this paper, the short-term variability in water level elevations inside the containment system had to be considered to develop a reliable post-enhancement performance monitoring program. The approach that was ultimately selected involves correcting the water level elevations obtained in the relief well within the containment system for the effects of barometric pressure changes prior to comparison with the water level elevations in an observation well in the aquifer outside the system. The reliability of the post-enhancement performance monitoring program is improved further by simply requiring that any decision to enhance the containment system be based on the water level measurements obtained during two consecutive months. Using this approach, the probability that the containment system's performance will erroneously be deemed unacceptable is low. The post-enhancement performance monitoring program also requires no extra field work and does not involve any specialized equipment, which helps to keep operation and maintenance costs to a minimum.

Notes: In this paper, we present a heuristic model of mixing and aerobic degradation based on a conceptual understanding of the mixing process in heterogeneous media, rather than on a rigorous derivation from the stochastic transport equations. The mean-behavior, heuristic approach, with a uniform velocity field, was used to reproduce organic plume behavior from a previously published simulation for random pore water velocity fields. The heuristic model presented herein requires that the mixing coefficient be calibrated to explain field data; therefore, in that sense, the model is not predictive. The numerical model uses a modified form of a particle tracking model to account for multispecies transport. Transport simulation includes a random-walk component, while biodegradation is simulated with Monod kinetics. Numerical simulations are presented for nonreactive transport in homogeneous media, and for reactive transport in heterogeneous media. A sensitivity analysis of the model is performed to determine the effect of the mixing coefficient in the model.

Notes: This paper presents numerical experiments designed to simulate heat transfer in deformed, stratified geologic formations during Frasch thermal mining operations in the Delaware Basin. In such operations, superheated water (163°C) is injected into permeable ore zones to melt and mobilize sulfur. The efficiency of Frasch mining depends largely on various aspects of hydrologic controls and geologic factors, such as directing heat flow toward target areas and minimizing heat dissipation through advection and conduction in ore zones. Numerical modeling techniques were used in the search of an optimum thermal mining strategy for maximum sulfur recovery in various geologic settings present at the Culberson Mine, west Texas. The sample calculations illustrate heat transfer patterns in inclined, folded, and fractured geologic formations. Important results presented include the controls of geologic structures on directions and rates of heat transfer and ground water flow, a display of field evidence for the occurrence of thermal convection in permeable ore zones, and a depiction of heat transfer during a thermal mining operation proceeding down-dip along an inclined geologic unit. Modeling results and field data strongly support the hypothesis that thermal convection occurs and controls the heat transfer process in inclined ore zones. Simulations further suggest that the current thermal mining practice, which proceeds down-slope along an inclined ore zone, may result in lowered ultimate sulfur recovery. In this mining approach most heat migrates up-slope where the rock's permeability is enhanced by previous sulfur extraction, rather than down-dip toward the target area.

Notes: The numerical modeling tool ITOUGH2 was examined to determine its effectiveness in parameter estimation for the small scale seals performance tests (SSSPT) at the Waste Isolation Pilot Plant (WIPP) near Carlsbad, New Mexico. Gas flow injection tests were performed at various distances inward from the wall of Room D to estimate the effects of creeping of the disturbed rock zone (DRZ) since excavation of Room D and boreholes, and to estimate the amount of healing of the DRZ that has taken place due to an emplaced concrete seal. Salt creeping into an excavation is expected to show increased porosity and absolute permeability values compared to undisturbed halite. Healed halite is expected to show porosity and absolute permeability values comparable to that of undisturbed halite. Single-phase flow estimates of absolute permeability were made using ITOUGH2. Estimates of DRZ absolute permeability ranged from 10−11 near Room D to 10−21 m2 at the seal. Simultaneous estimates of absolute permeability and porosity were calculated for the disturbed rock zone in halite, and the effects of salt creep and healing were seen in the estimates of porosity and absolute permeability, as evidenced by the differences in absolute permeability and porosity with distance inward from the rib of Room D. Estimate of porosity were 0.04 near Room D, and the locations near the seal showed porosities of around 0.03. ITOUGH2 proved effective in interpreting test data seen in the SSSPT, especially test data with constant injection pressure.

Notes: Due to extremely slow water recovery rates in aquitards and high contamination potential from sealing materials, installation of piezometers in aquitards for geochemical studies requires specialized construction and careful sampling techniques. Few methods have been demonstrated for obtaining representative ground water samples for geochemical parameters from piezometers in aquitards. Here we implement and evaluate an aquitard piezometer installation and ground water chemistry sampling strategy and show that the use of an inert gas pocket in piezometer construction can be used to delay seal contamination for at least three years and avoid oxygenation and disturbance of downhole redox conditions. Major ion analyses did not change appreciably through the standing water columns in the aquitard piezometers over time; however, reliable measurements of typically unstable geochemical parameters (dissolved oxygen, pH, and oxidation-reduction potential) were best obtained using downhole, in situ instrumentation, provided there was at least 2 to 10 m of standing water in the piezometer.

Notes: Sorption to aquifer sediments can limit the effectiveness of surfactants injected to solubilize residual nonaqueous phase liquid contaminants in the subsurface. The objective of this study was to evaluate the ability of the single-well, push-pull test to characterize sorption of linear alkylbenzene sulfonate (LAS) and hexadecyl diphenyl oxide disulfonate (DOWFAX) surfactants to natural aquifer sediment in situ. Batch sorption isotherms for both surfactants exhibited Langmuir-type sorption behavior with larger apparent sorption maxima for LAS than for DOWFAX. However, numerical transport simulations based on batch sorption isotherms were unable to predict the retardation and chromatographic separation of LAS homologs and conservative transport of DOWFAX observed during laboratory and field push-pull tests, indicating that the single-well, push-pull test method can more accurately describe in situ surfactant sorption and transport behavior than batch sorption isotherms.

Notes: Specific capacity (Q/s) data are usually much more abundant than transmissivity (T) data. Theories which assume uniform transmissivity predict a nearly linear relationship between T and Q/s. However, linear dependence is seldom observed in field studies. Since hydrogeologic studies usually require T data, many hydrogeologists use linear regression analysis of T versus Q/s data to estimate T values where only Q/s data are available. In this paper we use numerical models to investigate the effects of aquifer heterogeneity on the relationship between Q/s and T estimates. The simulations of hydraulic tests in heterogeneous media show that estimates of T derived using Jacob's method tend to their late-time effective value much faster than Q/s values. The latter are found to be more dependent upon local transmissivities near the well. This explains why the regression parameters for T versus Q/s data depend on heterogeneity and the‘lateness’of the test period analyzed. Since this effect is more marked in high T zones than in low T zones, we conclude that natural aquifer heterogeneity can explain the convex deviation from linearity often observed in the field. A further result is that the geometric mean of T estimates, obtained from short and intermediate time pumping tests, seems to systematically underestimate effective T (Teff) of heterogeneous aquifers. In the studied simulation cases, the median of the T values or the arithmetic mean yield better estimates for Teff.

Notes: Most of the cities southeast of Buenos Aires, Argentina, depend heavily on ground water for water supply. Whereas ground water quality is generally good in the region, economic development along the coastal plain has been constrained by high salinities.Fifty-four wells were sampled for major ions in zones of recharge, transport and discharge in an area near La Plata, 50 km southeast of Buenos Aires. The shallow, southwest to northeast coastal flow system is 〉30 km long but is only 50 to 80 m thick. It consists of Plio-Pleistocene fluvial sand overlain by Pleistocene eolian and fluvial silt and Holocene estuarine silty clay.Hydrochemical endmembers include HCO3, SO4, and Cl water. Bicarbonate-type water includes high plain recharge water (Ca-Na-HCO3) that evolves through cation exchange and calcite dissolution to a high pH, pure Na-HCO3 endmember at the southwest edge of the coastal plain. Similar Na-HCO3 water is also found underlying recharge areas of the central coastal plain, and a lens of Ca-HCO3 water is associated with a ridge of shell debris parallel to the coast.Mixed cation-Cl water near the coastline represents intruded sea water that has undergone cation exchange. Chemically similar water underlying the southwest coastal plain, however, can be shown isotopically to have formed from fairly dilute solutions concentrated many times by evapotranspiration.In the central coastal plain, Na-SO4-Cl water (up to 17,000 mg/L SO4) underlies hummocks and, at depth, forms plumes in the subsurface. The chemical controls are dissolution of gypsum precipitated during pyrite oxidation, evapotranspiration, and calcite precipitation.This extreme diversity of water chemistry in a shallow, clastic flow system is uncommon. It is made possible by (1) the presence of oxidized, originally pyritic, but slightly permeable sediments that have been exposed to evolving geochemical and hydro-dynamic conditions, and (2) highly focused recharge that favors the development of fresh water bodies underlying recharge zones and stagnant, evaporated water underlying other areas.

Notes: A release of 1,2-dichloroethane. also known as ethylene dichloride (EDC), resulted in shallow subsurface freephase contamination of a Gulf Coast site in the southern United States. The site stratigraphy consists primarily of a low permeability, surficial peat. silt, and clay zone underlain by fractured clay; a confined 12 in deep sand ground water flow zone; a confined 21 m deep fine sand zone of limited ground water flow, followed by a deep aquitard. The Gumbo clay and sandy clay aquitard below the release area overlies and protects the 61 m deep Upper Chicot Aquifer, which is a confined regional aquifer. An ongoing recovery and hydraulic containment program from the primary impacted and laterally and vertically restricted shallow 40-foot sand zone has effectively recovered dense nonaqueous phase liquid (DNAPL) and contained dissolved phase EDC.Natural attenuation of EDC was demonstrated through (1) a laboratory microcosm study substantiating the ability of the native microbial population in the deeper aquifer lo degrade EDC under anaerobic environmental conditions found at the site. (2) field investigations showing reductions in EDC concentrations over time in many of the wells on site, and (3) an evaluation of the ground water for EDC and its degradation products and oilier geo-chemical parameters such as dissolved oxygen, redox potential, and pH. Degradation products of EDC found in the field investigations included 2-chloroeihanol, ethanol. ethene, and ethane. Dissolved EDC concentrations in selected wells between the first recorded samples and the fourth quarter of 1997 ranged from greater than 4% to 99% reductions. First-order exponential decay half-lives ranged from 0.21 to 4.2 years for wells showing decreases in FDC concentrations over time. Elevated methane concentrations indicated carbon dioxide to be the major terminal electron acceptor.

Notes: The municipal landfill at the Complexe Environnemental de Saint-Michel (CESM) in Montreal, which is the third largest in North America, is located in a former quarry in fractured limestone. Impressive measures are taken to monitor and control biogas and leachate generated at the site. Leachate containment is presently performed with a pumping well completed within the waste. The efficiency of the well in controlling off-site leachate migration is questioned because field observations strongly suggest that the nearby former Francon quarry is diverting local ground water flow. To address this issue, four additional hydraulic control options are considered: (1) increased pumping at the existing waste well; (2) new pumping wells in the rock on the eastern limit of the site; (3) new injection wells in the rock on the eastern limit; and (4) combination of new injection wells at the same location and new water supply wells upgradient of the landfill. We evaluated the four hydraulic control options at the CESM using two coupled models: (1) a decision model based on an objective function weighting the risk, costs, and benefits of each option translated into dollar units; and (2) a numerical ground water flow model to represent the effect of operational conditions and ascertain success. Decision analysis offers a quantitative unbiased tool to evaluate the potential and relative cost of each option, but qualitative considerations and judgment still must be used for a complete evaluation. Our analysis confirms that scenario 4, which was the intuitively favored option, represents the best containment strategy.

Notes: “Valuable information pertaining to contaminant sources, contaminants, and ground water quality was derived using the state-supplied data.”

Notes: Steam flushing experiments were concluded in a two-dimensional chamber containing two layers of F75 silica sand separated by a layer of finer F10 silica sand. Perchloroelhylene (PCE), which had spilled into the chamber under water-saturated conditions, formed a pool on the F110 sand layer. Steam was injected above the F110 sand layer. Temperatures, moisture content, and PCE concentrations in the chamber were monitored. Samples, taken from the various locations in the sand chamber, indicated that complete removal of PCE from the steam zone was achieved, with an 84% overall recovery. Some downward displacement of PCE-contaminated water through the F110 sand layer was observed and a small amount of gravity override occurred. Channeling of steam was minimal. The experiment indicates that steam flushing may be used successfully for removal of PCE from relatively homogeneous soils. Issues of gravity override and downward mobilization of contaminants must be considered in applying steam flushing at the field scale.

Notes: Site closure for soil vacuum extraction (SVE) application typically requires attainment or specified soil concentration standards based on the premise that mass flux from the vadose zone to ground water not result in levels exceeding maximum contaminant levels (MCLs). Unfortunately, realization of MCLs in ground water may not be attainable at many sites. This results in soil remediation efforts that may be in excess of what is necessary for future protection of ground water and soil remediation goals which often cannot be achieved within a reasonable time period. Soil venting practitioners have attempted to circumvent these problems by basing closure on some predefined percent total mass removal, or an approach to a vapor concentration asymptote. These approaches, however, are subjective and influenced by venting design. We propose an alternative strategy based on evaluation of five components: (1) site characterization, (2) design. (3) performance monitoring, (4) rule-limited vapor transport, and (5) mass flux to and from ground water. Demonstration of closure is dependent on satisfactory assessment of all five components. The focus of this paper is to support mass flux evaluation. We present a plan based on monitoring of three subsurface zones and develop an analytical one-dimensional vertical flux model we term VFLUX. VFLUX is a significant improvement over the well-known numerical one-dimensional model. VLEACH, which is often used for estimation of mass flux to ground water, because it allows for the presence of nonaqueous phase liquids (NAPLs) in soil, degradation, and a lime-dependent boundary condition at the water table inter-face. The time-dependent boundary condition is the center-piece of our mass flux approach because it dynamically links performance of ground water remediation lo SVE closure. Progress or lack of progress in ground water remediation results in either increasingly or decreasingly stringent closure requirements, respectively.

Notes: Use of direct-push sampling tools fur rapid investigations of contaminated sites has proliferated in the past several years. A direct-push device, referred to as a ground water sampling profiler, was recently developed at the University of Waterloo. This tool differs from oilier direct-push tools in that point samples are collected at multiple depths in the same hole without retrieving, decontaminating, and re-driving the tool alter each sampling event. The collection of point samples, rather than samples from a longer screened interval, allows an exceptional level of detail to be generated about the vertical distribution of contamination from each hole. The benefits of acquiring this level of detail arc contingent on minimization of vertical cross contamination of samples caused by drag down from high concentration zones into underlying low concentration zones. In a detailed study of chlorinated solvent plumes in sandy aquifers, we found that drag down using the profiler is minimal or non-detectable even when the tool is driven through high concentration zones of dissolved chlorinated solvent contamination. Chlorinated solvent concentrations, primarily PCE and TCE at or below a detection limit of 1 μg/L, were obtained directly beneath plumes with maximum concentrations up to thousands of μg/L. Minimal drag down, on the order of a few μg/L to 20 μg/L, may have been observed below chlorinated solvent concentrations of several tens of thousands to hundreds of thousands of μg/L. Drag down through DNAPL zones was not evaluated.

Notes: Characterizing mass transfer during in situ air sparging requires knowledge of the size, shape, and interfacial area of air channels. These characteristics were determined by analysis of digital images of air channels passing through submerged glass beads having particle size in the sand range. Pore-scale channeling occurred in all cases. The analysis showed that the air channels were narrower, more tortuous, more closely spaced, and moved nearly vertically through the coarser media. In the finer media, air channels had larger diameter, were spaced further apart, and passed nearly horizontally through the media. The mean diameter of the channels varied between 2.8 and 8.1 mm, and the mean spacing varied between 8.3 and 19.4 mm. Estimates of the area of the air-water interface per unit volume of soil (a0), computed using data from the digital images and an assumed arrangement of channels, ranged from 0.02 to 0.2 mm2/mm3. Larger a0 were obtained for coarser media and uniformly graded media. These estimates of a0 compare well with published values for common packed-column materials and for unsaturated soils.

Notes: Air sparging has proven to be an effective remediation technique for treating saturated soils and ground water contaminated by volatile organic compounds (VOCs). Since little is known about the system variables and mass transfer mechanisms important to air sparging, several researchers have recently performed laboratory investigations to study such issues. This paper presents the results of column experiments performed to investigate the behavior of dense nonaqueous phase liquids (DNAPFs). specifically trichloroethylene (TCE), during air sparging. The specific objectives of the study were (1) to compare the removal of dissolved TCE with the removal of dissolved light nonaqueous phase liquids (LNAPLs). such as benzene or toluene; (2) to determine the effect of injected air-flow rate on dissolved TCE removal; (3) to determine the effect of initial dissolved TCE concentration on removal efficiency; and (4) to determine the differences in removal between dissolved and pure-phase TCE. The test results showed that (1) the removal of dissolved TCE was similar to that of dissolved LNAPL: (2) increased air-injection rates led to increased TCE removal at lower ranges of air injection, but further increases at higher ranges of air injection did not increase the rate of removal, indicating a threshold removal rate had been reached; (3) increased initial concentration of dissolved TCE resulted in similar rates of removal: and (4) the removal of pure-phase TCE was difficult using a low air-injection rate, but higher air-injection rates led to easier removal.

Notes: “The panel provided good, solid, interdisciplinary advice on a variety of challenging, state-of-the-art issues.”

Notes: “Contamination of heating oil with MTBE could result in increasing the environmental impact of subsurface heating oil releases.”

Notes: The compatibility of dense nonaqueous phase liquids (DNAPLs). triehloroelhylene (TCE), methylene chloride (MC), and creosote with commercially available sodium bentonite pellets was evaluated using stainless steel, double ring, falling head permeameters. The hydraulic conductivity (K) of the bentonite clay was measured under three experimental conditions: (1) water soluble constituents of the DNAPLs were used to hydrate and permeate the bentonite: (2) bentonite pellets were submersed in DNAPL prior to hydration and permeation with water: and (3) DNAPLs were pooled on water-hydrated bentonite. Further, the effect of hydraulic head (2.5. 145, and 710 cm) on water-hydrated bentonite permeated with TCE and the effects of TCE exposure time to mixtures of bentonite grout and sand were measured. Solubility concentrations of DNAPL constituents did not effect the hydraulic conductivity of the bentonite pellets relative to baseline (water only) measurements; a competent hydraulic barrier was formed (K 〈 5 × 10−9 cm/s). Bentonite pellets submersed in DNAPLs retained their rigid shape, did not swell, and did not perform as a hydraulic barrier. However, when the DNAPL was removed and replaced with water, the DNAPL-wetted pellets imbibed water to swell and form an adequate hydraulic barrier (K 〈 6 × 10−9 cm/s). Competent hydraulic barriers constructed with bentonite pellets and hydrated with water were subsequently permeated with TCE, MC, or creosote DNAPLs developing desiccation cracks up to 5 mm wide. The intrinsic permeability of water-hydrated bentonite was 46 to 2640 limes greater to DNAPLs relative to water, indicating that the desiccation cracks predominantly facilitated preferential DNAPL transport. The propagation rate of cracks was positively correlated to the hydraulic gradient, bin the formation of cracks is chemically dependent on the contact lime of DNAPL. Silica sand is expansively inert, yet 95, 90, 83, 75, and 50% (wt sand/wt bentonite) mixtures with bentonite grout were insufficient to prevent desiccation cracks and hydraulic failure. The incompatibility between DNAPLs and bentonite observed in this study is important due id the numerous exploratory borings in DNAPL/ones, the increasing dependency on hydraulic containment as a remedial alternative, and the fact that such remedial systems are often designed to be functional for many years.

Notes: The U.S. Environmental Protection Agency (EPA) maximum contaminant level (MCL) of 50 μg/L for arsenic was exceeded in 86 of 2125 water supply wells sampled over a broad geographic range in pails of Drown. Outagamie and Winnebago Counties, Wisconsin. The hydrologic and geochemical properties of the area were examined and the source of arsenic was determined to be natural, Ground water collected from two geologic formations, the St. Peter Sandstone and the overlying Platteville/Galena Dolomite, was found to be the principal source of the elevated arsenic concentrations. These two Formations supply a large portion of eastern Wisconsin private wells with their drinking water.Three wells were found within Outagamie County to have an unusually low pH. Results suggest that the cause of the low pH in these wells is of natural origin induced by the oxidation of iron sulfide minerals. In this reaction iron sulfide minerals are oxidized. forming sulfuric acid causing a low pH and a high concentration of various metals to leach from native rock formations into the water supply.Based on the data gathered from this study, an arsenic advisory area was designated for both Outagamie and Winnebago Counties. Guidelines were developed for well drillers and owners constructing new wells within the advisory area to reduce the likelihood of arsenic presence in the water supply. Fifteen wells containing arsenic exceeding the MCL were successfully reconstructed or new wells were constructed based on the guidelines developed. These constructions substantially reduced arsenic levels in the well water supplies.

Notes: We have developed a rugged, durable platinum wire Eh electrode for application in subsurface environments. The electrode design is described in detail and its performance under aerobic and anaerobic steady-state and transient conditions is assessed. The electrode consists of a 0.5-mm-diameter platinum wire (99.99% purity) cast in a glass fiber-reinforced epoxy jacket. The construction allowed installation through direct insertion into sandy media to depths up to several meters. Data collection was through connection to a datalogger with high impedance input; data points were collected every 10 seconds and averaged and stored once an hour. The electrodes functioned in situ for periods of more than three years and gave reliable readings during oxic, anoxic, and transitional conditions. Performance testing and examination of electrodes recovered after three years in situ indicated that they were not impacted by corrosion, dissolution, or poisoning.

Notes: “It's definitely not a time to become complacent with our current understanding of contaminant fate and transport processes.”“In the coming year, we are going to solicit short one- to two-page field Innovation Notes in GWMR.”

Notes: “The EPA decided that showing the presence of DNAPL would prove that cleanup to non-detect was improbable, and that a new end point could be selected.”“The only thing that really matters is the total mass of from the natural attenuation.”

Notes: A pilot-scale nutrient injection will (NIW) (4 m by 4 m by 1 m) was installed in the Borden Aquifer lo serve as a pulsed injection source of a potassium acetate solution for the stimulation of anaerobic microbial activity. The success of the flushing procedure was evaluated by monitoring the breakthrough of the acetate solution at several multilevel piezometers installed in the wall. Although some variation in the ground water velocity was observed with depth, the wall was flushed with reasonable uniformity after about six hours of injection and withdrawal, representing about one pore volume, Calculations bused on head level data collected during the flush, and on the solute breakthrough curves, indicated that about 90% of the flow induced by the pumping and injecting was confined to the permeable wall. These results show that a permeable wall injection system is a viable method of introducing solutes uniformly to a cross section of aquifer, with minimal perturbation of the natural flow system. In addition lo its importance for the biostimulation system tested in this project the flushing of permeable walls may have applications in other semi-passive remedial systems, such as the rejuvenation of reactive barriers.

Notes: The funnel and gate remediation concept (Star and Cherry 1993) represents a promising, yet relatively under-developed, technology for the passive control and in situ remediation of contaminated ground water. Effective design and implementation of such a system may, however, prove difficult under conditions of large or unpredictable variations in contaminant migration or ground water flow.Numerical modeling of two-dimensional ground water flow has been used to predict the hydraulic performance of passive, straight, or winged funnel and gate configurations over a range of hydrogeologic and ambient ground water flow conditions. The results of these analyses were used to construct generic correlation diagrams relating upstream capture zone or gale through put to the barrier, gale, and aquifer characteristics. These diagrams serve as useful screening tools to (1) quantitatively estimate the capture zone of pre-determined funnel and gale configurations, or (2) develop preliminary funnel and gale designs that will yield a desired capture zone, independent of aquifer characteristics.

Notes: The importance of obtaining depth-specific ground water samples is now well recognized among practitioners and scientists alike. Many methods and technologies are available for level discrete or depth-specific ground water sampling in consolidated aquifers. All methods have their associated advantages and drawbacks, however. One common disadvantage is that they are expensive. A large number of point discrete ground water samples were required for a UK research project aimed at quantifying natural attenuation processes in ground water contaminated by a former coal carbonization plant. Based on experience from a previous project to develop novel level accurate sampling methodologies for use in existing boreholes, the Ground Water Protection and Restoration Research Unit (GWPRRU) produced and tested a low-cost design multiport sock sampler for ground water monitoring. The sock sampler design allowed the recovery of multiple depth-specific ground water samples from depths of 150 feel (45 m) from individual boreholes in the sandstone aquifer at the field site. Because of their use of inexpensive materials, simple design, installation and use that does not require gravel packs, packers, or grouting, sock samplers were found to be the most cost effective, convenient, and reliable method of obtaining multiple depth-specific ground water samples at the project field site.

Notes: The regional atmospheric climate model HIRHAM has been applied to the Arctic. Simulations for the whole year 1990 and for an ensemble of winter months (January of 1985-1995) have been performed. The comparison of the simulations with observational data analyses shows that the general spatial patterns are in good agreement with the data, in both the vertical structure and the annual cycle. For an additional validation of the model results, a multivariate classification of large-scale circulation patterns has been applied to the January ensemble model simulations.

Notes: We investigate the response of the Nordic seas-Arctic Ocean system to surface freshwater flux anomalies that we regard as typical for long-term atmospheric variability. We employ response experiments with a coupled sea ice-ocean model where we introduce a surface freshwater flux anomaly (A) over the Norwegian Sea and (B) in the Laptev Sea. Case A offers an explanation for the intermediate depth salinity changes observed in the Amundsen Basin. The signal observed there belongs to an original perturbation that, according to the model, occurred around a decade earlier. Salinity fluctuations in the Laptev Sea could play a role in changes in the near surface salinity in the Amundsen Basin.

Notes: Observation of the retreat and disintegration of ice shelves around the Antarctic Peninsula during the last three decades and associated changes in air temperature, measured at various meteorological stations on the Antarctic Peninsula, are reviewed. The climatically induced retreat of the northern Larsen Ice Shelf on the east coast and of the Wordie, George VI, and Wilkins ice shelves on the west coast amounted to about 10 000 km2 since the mid-1960s. A summary is presented on the recession history of the Larsen Ice Shelf and on the collapse of those sections north of Robertson Island in early 1995. The area changes were derived from images of various satellites, dating back to a late 1963 image from the recently declassified US Argon space missions. This photograph reveals a previously unknown, minor advance of the northern Larsen Ice Shelf before 1975. During the period of retreat a consistent and pronounced warming trend was observed at the stations on both east and west coasts of the Antarctic Peninsula, but a major cause of the fast retreat and final collapse of the northernmost sections of the Larsen Ice Shelf were several unusually warm summers. Temperature records from the nearby station Marambio show that a positive mean summer temperature was reached for the first time in 1992-93. Recent observations indicate that the process of ice shelf disintegration is proceeding further south on both sides of the Antarctic Peninsula.

Notes: To determine the factors restricting plant reproduction in front of a glacier, the gender expression and seed production of Dryas octopetala L. (Rosaceae) were observed, as well as the grazing pattern of reindeer on flowers, near Brøggerbreen (Brøgger Glacier), which is near Ny-Ålesund (78° 55'N, 11° 56'E), Svalbard. Three hundred shoots with flowers and flower buds were randomly tagged in early July 1996. Between then and the end of flowering in late July, 100 (33%) flowers and buds were grazed by reindeer. Out of the surviving flowers, 145 (76%) shoots had hermaphrodite flowers, while 45 (24%) shoots had male flowers without a developed gynocium. Male flowers, which appeared later than hermaphrodite flowers in the population, were significantly smaller than hermaphrodite flowers in dry weight. In the hermaphrodite flowers, moreover, smaller flowers showed lower dry-weight allocation to the gynoecium as compared to larger flowers. During the observation, hermaphrodite flowers did not produce any developed seeds under a natural condition (0% seed-set). Cross-pollinated flowers showed 8% seed-set. On the other hand, flowers which were artificially warmed in small greenhouses during the flowering period showed 60% seed-set, regardless of cross-pollination or autodeposition of pollen from anthers to stigma (self-pollination). Thus, it was found that grazing, gender variation in relation to the length of the growing season and the flower size, and - in the floweriing period - low temperature rather than pollinator limitation strongly affected the seed production of D. octopetala in the population studied.

Notes: In the near coastal regions of Dronning Maud Land, Antarctica, below-surface ice-melt in blue-ice areas has been observed. The low scattering coefficients of the large-grained blue-ice allow penetration of solar radiation, thus providing an energy source below the ice surface. The sub-surface meltwater is significant enough to show up on remote-sensing imagery in the form of ice-covered lakes. Adjacent snow-accumulation areas have much higher scattering coefficients and consequently limit solar radiation penetration in these regions. These snow and ice surfaces are generally below freezing, and little surface melting occurs. To assess the response of these melt features to changes in atmospheric forcings such as cloudiness, air temperature, and snow accumulation, a physically-based model of the coupled atmosphere, radiation, snow, and blue-ice system has been developed. The model consists of a heat transfer equation with a spectrally-dependent solar-radiation source term. The penetration of radiation into the snow and blue-ice depends on the surface albedo, and the snow and blue-ice grain size and density. Model simulations show that ice melt occurring in this area is sensitive to potential variations in atmospheric forcing. Under certain conditions more traditional surface melting occurs and, under other conditions, the existing melt processes can be shut down completely. In light of the sensitivity of this system to variations in atmospheric forcing, and the ability to view melt-related features using remote sensing, a tool exists to efficiently monitor variations in Antarctic coastal climate.

Notes: The Holocene glacial and climatic development in Antarctica differed considerably from that in the Northern Hemisphere. Initial deglaciation of inner shelf and adjacent land areas in Antarctica dates back to between 10-8 Kya, when most Northern Hemisphere ice sheets had already disappeared or diminished considerably. The continued deglaciation of currently ice-free land in Antarctica occurred gradually between ca. 8-5 Kya. A large southern portion of the marine-based Ross Ice Sheet disintegrated during this late deglaciation phase. Some currently ice-free areas were deglaciated as late as 3 Kya. Between 8-5 Kya, global glacio-eustatically driven sea level rose by 10-17m, with 4-8 m of this increase occurring after 7 Kya. Since the Northern Hemisphere ice sheets had practically disappeared by 8-7 Kya, we suggest that Antarctic deglaciation caused a considerable part of the global sea level rise between 8-7 Kya, and most of it between 7-5 Kya. The global mid-Holocene sea level high stand, broadly dated to between 8-4 Kya, and the Littorina-Tapes transgressions in Scandinavia and simultaneous transgressions recorded from sites e.g. in Svalbard and Greenland, dated to 7-5 Kya, probably reflect input of meltwater from the Antarctic deglaciation.

Notes: UV-B tolerance and susceptibility of high Arctic morphotypes of the Daphnia pulexl D. tenebrosa complex were assessed by in situ experiments at Ny-Ålesund, Svalbard (79°N). Animals from local ponds were exposed to ambient light plus additional UV-B from lamps in a greenhouse facility. Taxonomic affinities did not appear as major determinants of UV susceptibility, but a major difference in UV-B tolerance was seen between morphotypes with pigmented carapaces and those without, the latter being far more susceptible. Assays on levels of carotene and the anti-oxidant enzymes catalase and superoxide dismutase did not reveal clear-cut differences between populations, and could not account for the higher tolerance in pigmented populations. Levels of glutathione transferase were higher in the transparent population, however. In the absence of blue light and UV, laboratory reared animals did not reconstitute their carapace melanization after moulting, indicating that short-wave light is the cue for melanin synthesis. Tests on melanized individuals and individuals of the same population reared indoors through 1-2 moults supported the major role of melanin for UV protection. Periods with high UV exposure during hatching of ephippia could induce shifts in morphotype or clonal dominance.

Notes: During the 17th and 18th centuries, tens of thousands of Greenland right whales were killed as a result of extensive European whaling in the coastal waters of the Svalbard archipelago. The author reconstructed these whaling activities, examined how the changing climate affected whaling productivity, and considered the consequences of climate and whaling on the species and on the North Atlantic ecosystem. Annual catch records made it possible to calculate the original size of the whale population; its natural migration pattern in the Greenland Sea could be reconstructed using shipping logs and itineraries. Other written sources revealed that besides human hunting activities, climate change played an important role in the elimination of the Greenland right whale from the Arctic marine ecosystem. This elimination made millions of plankton available for other marine mammals, polar cod and planktonfeeding birds. This has caused a major shift in the food web. changing the marine ecosystem in Svalbard.

Notes: Responses to global change impacts require the specification of mitigation and adaptation options. Integrated regional impact studies provide some of the information needed for rational decision making. In order to carry out a comprehensive impact study, the involvement of stakeholders in the planning and execution of the study is seen as a necessary prerequisite for an acceptance of its conclusions by the broad public. One way to pursue such an involvement is through a scientist-stakeholder collaborative. Such a collaborative, for instance institutionalized through a joint scientist-stakeholder steering committee addressing issues related to mutual communication and the integration of individual study results, offers a number of additional advantages. The experience of local residents and the utilization of traditional knowledge may provide insight and expertise inaccessible to scientific investigations. Within the Barents Sea Impact Study, the involvement of stakeholders has been given significant weight early on. One of the main instruments employed in the stakeholder collaborative is the BASIS Information Office. However, given the diversity of backgrounds and interests of stakeholders from four different countries, scientist-stakeholder collaboration represents a significant challenge within BASIS. This notwithstanding, we consider the advantages gained worth the extra effort.