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  • Physics  (5,210)
  • Air-sea interaction
  • Wiley-Blackwell  (5,197)
  • Woods Hole Oceanographic Institution  (29)
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  • 1
    Publication Date: 2022-05-25
    Description: Subduction is the mechanism by which water masses formed in the mixed layer and near the surface of the ocean find their way into the upper thermocline. The subduction process and its underlying mechanisms were studied though a combination of Eulerian and Langrangian measurements of velocity, measurements of tracer distributions and hydrographic properties and modeling. An array of five surface moorings carrying meteorological and oceanographic instrumentation were deployed for a period of two years beginning in June 1991 as part of an Office of Naval Research (ONR) funded Subduction experiment. Three eight month deployments were planned. The moorings were deployed at 18°N 34°W, 18°N 22°W, 25.5°N 29°W, 33°N 22°W and 33°N 34°W. A Vector Averaging Wind Recorder (VAWR) and an Improved Meteorological Recorder (IMET) collected wind speed and wind direction, sea surface temperature, air temperature, short wave radiation, barometric pressure and relative humidity. The IMET also measured precipitation. The moorings were heavily instrumented below the surface with Vector Measuring Current Meters (VMCM) and single point temperature recorders. Expendable bathythermograph (XBT) data were collected and meteorological observations were made while transmitting between mooring locations. This report describes the work that took place during R/V Knorr cruise number 138 leg XV which was the fourth scheduled Subduction mooring cruise. During this cruise the moorings previously deployed for a third and final eight month period were recovered. This report includes a description of the moorings and instrumentation that were recovered, has information about the underway measurements (XBT and meteorological observations) that were made including plots of the data, and presents a chronology of the cruise events.
    Description: Funding provided by the Office of Naval Research under Contract No. N00014-90-J-1490.
    Keywords: Air-sea interaction ; Moored data ; Subduction ; Knorr (Ship : 1970-) Cruise KN138
    Repository Name: Woods Hole Open Access Server
    Type: Technical Report
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  • 2
    Publication Date: 2022-05-25
    Description: Subduction is the mechanism by which water masses formed in the mixed layer and near the surface of the ocean find their way into the upper thermocline. The subduction process and its underlying mechanisms were studied through a combination of Eulerian and Langrangian measurements of velocity, measurements of tracer distrbutions and hydrographic propertes and modeling. An array of five surface moorings carrying meteorological and oceanographic instrumentation were deployed for a period of two years beginning in June 1991 as part of an Office of Naval Research (ONR) funded Subduction experiment. Three eight month deployments were planned. The initial deployment of five surface moorings took place during the third leg of R/V Oceanus cruise number 240. The moorings were deployed at 18°N 34°W, 18°N 22°W, 25.5°N 29°W, 33°N 22°W and 33°N 34°W. A Vector Averaging Wind Recorder (VAWR) and an Improved Meteorological Recorder (IMET) collected wind speed and wind direction, sea surface temperature, air temperature, short wave radiation, barometric pressure and relative humidity. The IMET also measured precipitation. The moorings were heavily instrumented below the surface with Vector Measuring Current Meters (VMCM) and single point temperature recorders. Expendable bathythermograph (XBT) data were collected and meteorological observations were made while transitting between mooring locations. This report describes the work that took place during R/V Oceanus cruise 250 which was the second scheduled Subduction mooring cruise. During this cruise the first setting of the moorings were recovered and redeployed for a second eight month period. This report includes a description of the instrumentation that was deployed and recovered, has information about the underway measurements (XBT and meteorological observations) that were made including plots of the data and presents a chronology of the cruise events.
    Description: Funding was provided by the Office of Naval Research under contract N00014-90-J-1490.
    Keywords: Air-sea interaction ; Moored instruments ; Subduction ; Oceanus (Ship : 1975-) Cruise OC250
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    Type: Technical Report
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  • 3
    Publication Date: 2022-05-25
    Description: A surface mooring was deployed in the eastern tropical Pacific west of northern Chile from the R/V Melville as part of the Eastern Pacific Investigation of Climate (EPIC). EPIC is a CLIVAR study with the goal of investigating links between sea surface temperature variability in the eastern tropical Pacific and climate over the American continents. Important to that goal is an understanding of the role of clouds in the eastern Pacific in modulating atmosphere-ocean coupling. The mooring was deployed near 20°S 85°W, at a location near the western edge of the stratocumulus cloud deck found west of Peru and Chile. This deployment started a three-year occupation of that site by a WHOI surface mooring in order to collect accurate time series of surface forcing and upper ocean variability. The surface mooring was deployed by the Upper Ocean Processes Group of the Woods Hole Oceanographic Institution (WHOI). In collaboration with investigators from the University of Concepcion, Concepcion, Chile, an XBT section was made on the way out to the mooring from Arica, Chile, and an XBT and CTD section was made on the way into Arica. The buoy was equipped with meteorological instrumentation, including two Improved METeorological (IMET) systems. The mooring also carried Vector Measuring Current Meters, single-temperature recorders, and conductivity and temperature recorders located in the upper meters of the mooring line. In addition to the instrumentation noted above, a variety of other instruments, including an acoustic current meter, an acoustic doppler current profiler, a bio-optical instrument package, and an acoustic rain guage, were deployed. This report describes, in a general manner, the work that took place and the data collected during the Cook 2 cruise aboard the R/V Melville. The surface mooring deployed during this cruise will be recovered and re-deployed after approximately 12 months and again after 24 months, with a final recovery planned for 36 months after the first setting. Details of the mooring design and preliminary data from the XBT and CTD sections are included.
    Description: Funding was provided by the National Oceanic and Atmospheric Administration under grant number NA96GP0429.
    Keywords: Stratocumulus clouds ; Air-sea interaction ; Moored data ; Melville (Ship) Cruise Cook 2
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  • 4
    Publication Date: 2022-05-25
    Description: The Ocean Reference Station at 20°S, 85°W under the stratus clouds west of northern Chile and Peru is being maintained to provide ongoing, climate-quality records of surface meteorology, of air-sea fluxes of heat, freshwater, and momentum, and of upper ocean temperature, salinity, and velocity variability. The Stratus Ocean Reference Station, hereafter ORS Stratus, is supported by the National Oceanic and Atmospheric Administrations (NOAA) Climate Observation Program. It is recovered and redeployed annually, with cruises that have come in October or November. During the November 2003 cruise of Scripps Institution of Oceanography's R/V Roger Revelle to the ORS Stratus site, the primary activities where the recovery of the WHOI surface mooring that had been deployed in October 2002, the deployment of a new WHOI surface mooring at that site, the in-situ calibration of the buoy meteorological sensors by comparison with instrumentation put on board by Chris Fairall of the NOAA Environmental Technology Laboratory (ETL), and observations of the stratus clouds and lower atmosphere by NOAA ETL and Jason Tomlinson from Texas A&M. The ORS Stratus buoys are equipped with two Improved Meteorological systems, which provide surface wind speed and direction, air temperature, relative humidity, barometric pressure, incoming shortwave radiation, incoming longwave radiation, precipitation rate, and sea surface temperature. The IMET data are made available in near real time using satellite telemetry. The mooring line carries instruments to measure ocean salinity, temperature, and currents. On some deployments, additional instrumentation is attached to the mooring to measure rainfall and bio-optical variability. The ETL instrumentation used during the 2003 cruise included a cloud radar, radiosonde balloons, and sensors for mean and turbulent surface meteorology. In addition to this work, buoy work was done in support of the Ecuadorian Navy Institute of Oceanography (INOCAR) and of the Chilean Navy Hydrographic and Oceanographic Service (SHOA). The surface buoy, oceanographic instrumentation, and upper 500 m of an INOCAR surface mooring at 2°S, 84°W that had been vandalized were recovered and transferred to the Ecuadorian Navy vessel B. A. E. Calicuchima. A tsunami warning mooring was installed at 75°W, 20°S for SHOA. SHOA personnel onboard were trained during the cruise by staff from the NOAA Pacific Marine Environmental Laboratory (PMEL) and National Data Buoy Center (NDBC). The cruise hosted two teachers participating in NOAA's Teacher at Sea Program, Deb Brice from San Marcos, California and Viviana Zamorano from Arica, Chile.
    Description: Funding was provided by the National Oceanic and Atmospheric Administration uncer Contract Number NA17RJ1223.
    Keywords: Air-sea interaction ; Stratus clouds ; Climate prediction ; Roger Revelle (Ship) Cruise Dana 3
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  • 5
    Publication Date: 2022-05-25
    Description: A surface mooring outfitted for meteorological and oceanographic measurement was deployed near 14°50'N, 51°00'W in the northwest tropical Atlantic on 30 March 2001. This was the initial deployment of the Northwest Tropical Atlantic Station (NTAS) project for air–sea flux measurement. These observations will be used to investigate air–sea interaction processes related to climate variability. The deployment was done on R/V Oceanus Cruise 365, Leg 5 by the Upper Ocean Processes Group (UOP) of the Woods Hole Oceanographic Institution. The 3-meter discus buoy was outfitted with two Air–Sea Interaction Meteorology (ASIMET) systems. Each system measures, records, and transmits via Argos satellite the surface meteorological variables necessary to compute air–sea fluxes of heat, moisture and momentum. The upper 120 m of the mooring line was outfitted with oceanographic sensors for the measurement of temperature and velocity. This report describes the initial deployment of the NTAS mooring (NTAS-1), including some of the pre-cruise buoy preparations and post cruise data comparisons.
    Description: Funding was provided by the National Oceanic and Atmospheric Administration (NOAA) through the Cooperative Institute for Climate and Ocean Research (CICOR) under Grant No. NA87RJ0445.
    Keywords: Air-sea interaction ; Tropical Atlantic ; Moored instrumentation ; Oceanus (Ship : 1975-) Cruise OC365
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  • 6
    Publication Date: 2022-05-25
    Description: During the summer of 2001, several moorings and cruises were used as part of the CBLAST-Low (Coupled Boundary Layer Air-Sea Transfer under low wind conditions) pilot experiment in the North Atlantic, south of Martha’s Vineyard Island, MA, USA. Six subsurface tide gauges were deployed around the study site for a period of approximately 3 months during the summer of 2001. Further, two surface buoys equipped with meteorological instrumentation and subsurface arrays that measured temperature, conductivity and velocity were deployed during the months of July and August 2001. For a short intensive operating period during July 2001, a newly manufactured three-dimensional mooring designed to sample three-dimensional properties of the upper ocean was deployed for a period of 6 days. During the Intensive Operating Period (IOP) along-shelf and across-shelf conductivity-temperature-depth (CTD) sections were completed as well as a drifting array designed to passively collect data from the upper water column released for approximately 24 hours. This report describes the instrumentation and type of moorings deployed by the Woods Hole Oceanographic Institution Upper Ocean Processes (WHOI UOP) group as well as data return and quality from the CBLAST-Low 2001 pilot study. This is summarized in graphical and tabular form in this report.
    Description: Funding provided by the Office of Naval Research under Contract No. N00014-01-1-0029 and from the Secretary of the Navy / CNO Chair Grant No. N00014-99-1-0090.
    Keywords: CBLAST-LOW ; Low wind ; Air-sea interaction ; Nobska (Ship) Cruise
    Repository Name: Woods Hole Open Access Server
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  • 7
    Publication Date: 2022-05-25
    Description: During the summer of 2002, six surface moorings and one subsurface mooring were deployed south of Martha's Vineyard, Cape Cod, Massachusetts. The moorings were deployed from June to September 2002 to collect meteorological and oceanographic data. This was done both to support the Coupled Boundary Layered Air-Sea Transfer Low wind (CBLAST-Low) cooperative experiment and to address the question of regional predictability in the littoral regime under research supported by a Secretary of the Navy/Chief of Naval Operations (CNO) Chair. The aim was to capture the mesoscale development and response of inner shelf waters to local synoptic atmospheric, tidal and larger scale oceanic forcing under predominantly low wind conditions. This report covers the operational aspects of the 2002 experiment, including deployment, recovery, and mooring setups, as well as basic data returns.
    Description: Funding was provided by the Office of Naval Research under Contract Numbers N00014-01-1-0029 and N00014-99-1-0090.
    Keywords: CBLAST-LOW ; Air-sea interaction ; Low wind ; Nobska (Ship) Cruise
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  • 8
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    Woods Hole Oceanographic Institution
    Publication Date: 2022-05-25
    Description: The long-range scientific objective of the Coupled Boundary Layer Air Sea Transfer (CBLAST) project is to observe and understand the temporal and spatial variability of the upper ocean, to identify the processes that determine that variability, and to examine its predictability. Air-sea interaction is of particular interest, but attention is also paid to the coupling of the sub-thermocline ocean to the mixed layer and to both the open ocean and littoral regimes. We seek to do this over a wide range of environmental conditions with the intent of improving our understanding of upper ocean dynamics and of the physical processes that determine the vertical and horizontal structure of the upper ocean. Field work for CBLAST was conducted during the summers of 2001, 2002, and 2003 off the south shore of Martha’s Vineyard, Massachusetts. The 2003 field work was conducted from the following platforms: heavy moorings, light moorings, drifters, F/V Nobska, CIRPAS Pelican aircraft, and an IR Cessna Aircraft. This report documents the 2003 field work and includes field notes, platform descriptions, discussion of data returns, and mooring logs. The 2003 Intensive Operating Period (IOP) was very successful and a high data return was seen.
    Description: Funding was provided by the Office of Naval Research under contract numbers N00014-01-1-0029 and N00014-05-10090.
    Keywords: Air-sea interaction ; Upper ocean dynamics ; Mixed layer
    Repository Name: Woods Hole Open Access Server
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  • 9
    Publication Date: 2022-05-25
    Description: Two surface moorings were recovered during R/V Melville cruise PACS03MV in the eastern equatorial Pacific as part of the Pan American Climate Study (PACS). PACS is a NOAA-funded study with the goal of investigating links between sea-surface temperature variability in the tropical oceans near the Americas and climate over the American continents. The two moorings were deployed near 125°W, spanning the strong meridional sea-surface temperature gradient associated with the cold tongue south of the equator and the warmer ocean north of the equator, near the northernmost, summer location of the Inter-tropical Convergence Zone. The moored array was deployed to improve the understanding of air-sea fluxes and of the processes that control the evolution of the sea surface temperature field in the region. Two surface mooring, located at 3°S, 125°W and 10°N, 125°W, belonging to the Upper Ocean Proccess (UOP) Group at the Woods Hole Oceanographic Institution (WHOI), were recovered after being on station for eight months. This was the second setting of the two moorings that had been redeployed from the University of Washington's R/V Thomas Thompson cruise number 73. The buoys of the two WHOI moorings were each equipped with meteorological instrumentation, including a Vector Averaging Wind Recorder (VAWR), and an Improved METeorological (IMET) system. The WHOI moorings also carried Vector Measuring Current Meters, single point temperature recorders, and conductivity and temperature recorders located in the upper 200 meters of the mooring line. In addition to the instrumentation noted above, a variety of other instruments, including an acoustic current meter, acoustic doppler meters, bio-optical instrument packages and an acoustic rain gauge, were deployed during the PACS field program.
    Description: Funding was provided by the National Oceanic and Atmospheric Administration under contract number NA66GPO130.
    Keywords: Air-sea interaction ; Moored instrument measurements ; PACS ; Pan American Climate Study ; Eastern tropical Pacific ; Ocean temperature ; Melville (Ship) Cruise PACS03MV
    Repository Name: Woods Hole Open Access Server
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  • 10
    Publication Date: 2022-05-25
    Description: Three surface moorings were recovered and redeployed during R/V Thomas Thompson cruise number 73 in the eastern equatorial Pacific as pan of the Pan American Climate Study (PACS). PACS is a NOAA-funded study with the goal of investigating links between sea-surface temperature variability in the tropical oceans near the Americas and climate over the American continents. The three moorings were deployed near 125°W, spanning the strong meridional sea-surface temperature gradient associated with the cold tongue south of the equator and the warmer ocean north of the equator, near the northernmost, summer location of the Intertopical Convergence Zone. The moored array was deployed to improve the understanding of air-sea fluxes and of the processes that control the evolution of the sea surface temperature field in the region. Two surface moorings, located at 3°S, 125°W and lO°N, 125°W, belonging to the Upper Ocean Processes (UOP) Group at the Woods Hole Oceanographic Institution (WHOI), were recovered after being on station for eight months and redeployed. Two eight-month deployments were planned. A third mooring deployed at the equator and 128°W by the Ocean Circulation Group at the University of South Florida (USF) was also recovered and redeployed. The USF mooring, unfortunately, had to be recovered immediately following redeployment due to a problem with the buoy and instrumentation. The buoys of the two WHOI moorings were each equipped with meteorological instrumentation, including a Vector Averaging Wind Recorder (VAWR), and an Improved Meteorological (IMET) system. The WHOI moorings also carried Vector Measuring Current Meters, single point temperature recorders, and conductivity and temperature recorders located in the upper 200 meters of the mooring line. In addition to the instrumentation noted above, a variety of other instruments, including an acoustic current meter, acoustic doppler current meters, bio-optical instrument packages and an acoustic rain gauge, were deployed during the PACS field program. The USF mooring had an IMET system on the surface buoy and for oceanographic instrumentation, two RD Instruments acoustic doppler current profilers (ADCPs), single-point temperature recorders, and conductivity and temperature recorders. Conductivity-temperature-depth (CTD) profiles were made at each mooring site and during the transit between mooring locations. This report describes, in a general manner, the work that took place during R/V Thomas Thompson cruise number 73. A description of the WHOI moored array and instrumentation is provided. Details of the mooring designs and preliminary data from the CTD profies are included.
    Description: Funding was provided by the National Oceanic and Atmospheric Administration under Contract No. NA66GPO130.
    Keywords: Air-sea interaction ; Moored instrument measurements ; PACS: eastern tropical Pacific ; Thomas G. Thompson (Ship) Cruise TN73
    Repository Name: Woods Hole Open Access Server
    Type: Technical Report
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  • 11
    Publication Date: 2022-05-25
    Description: Subduction is the mechanism by which water masses formed in the mixed layer and near the surface of the ocean find their way into the upper thermocline. The subduction process and its underlying mechanisms were studied through a combination of Eulerian and Langrangian measurements of velocity, measurements of tracer distributions and hydrographic properties and modeling. An array of five surface moorings carrying meteorological and oceanographic instrumentation were deployed for a period of two years beginning in June 1991 as part of an Office of Naval Research (ONR) funded Subduction experiment. Three eight month deployments were planned. The initial deployment of five surface moorings took place during the third leg of R/V Oceanus cruise number 240. The moorings were deployed at 18°N 34°W, 18°N 22°W, 25.5°N 29°W, 33°N 22°W and 33°N 34°W. A Vector Averaging Wind Recorder (VAWR) and an Improved Meteorological Recorder (IMET) collected wind speed and wind direction, sea surface temperature, air temperature, short wave radiation, long wave radiation, barometric pressure and relative humidity. The IMET also measured precipitation. The moorings were heavily instrumented below the surface with Vector Measuring Current Meters (VMCM) and single point temperature recorders. Expendable bathythermograph (XBT) data were collected and meteorological observations were made while transitting between moonng locations. This report describes the work that took place during R/V Oceanus cruise 240 leg 3. It includes a description of the instrumentation that was deployed,information about the XBT data collected and plots of the data as well as a chronology of the cruise events.
    Description: Funding was provided by the Office of Naval Research under contract N00014-90-J-1490.
    Keywords: Air-sea interaction ; Moored instruments ; Subduction ; Oceanus (Ship : 1975-) Cruise OC240-3
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    Type: Technical Report
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  • 12
    Publication Date: 2022-05-25
    Description: The Ocean Reference Station at 20°S, 85°W under the stratus clouds west of northern Chile is being maintained to provide ongoing, climate-quality records of surface meteorology, of air-sea fluxes of heat, freshwater, and momentum, and of upper ocean temperature, salinity, and velocity variability. The Stratus Ocean Reference Station (ORS Stratus) is supported by the National Oceanic and Atmospheric Administrations (NOAA) Climate Observation Program. It is recovered and redeployed annually, with cruises that have come between October and December. During the October 2006 cruise of NOAA's R/V Ronald H. Brown to the ORS Stratus site, the primary activities where recovery of the Stratus 6 WHOI surface mooring that had been deployed in October 2005, deployment of a new (Stratus 7) WHOI surface mooring at that site, in-situ calibration of the buoy meteorological sensors by comparison with instrumentation pub on board by staff of the NOAA Earth System Research Laboratory (ESRL, formerly ETL), and observations of the stratus clouds and lower atmosphere by NOAA ESRL. A buoy for the Pacific tsunami warning system was also serviced in collaboration with the Hydrographic and Oceanographic Service of the Chilean Navy (SHOA). The old DART (Deep-Ocean Assessment and Reporting of Tsunami) buoy was recovered and a new one deployed which carried IMET sensors and subsurface oceanographic instruments. Argo floats and drifters were also launched and CTD casts carried out during the cruise. The ORS Stratus buoys are equipped with two Improved Meteorological (IMET) systems, which provide surface wind speed and direction, air temperature, relative humidity, barometric pressure, incoming shortwave radiation, incoming longwave radiation, precipitation rate, and sea surface temperature. The IMET data are made available in near real time using satellite telemetry. The mooring line carries instruments to measure ocean salinity, temperature, and currents. The ESRL instrumentation used during the 2006 cruise included cloud radar, radiosonde balloons, and sensors for mean and turbulent surface meteorology. Stratus 7 also received a new addition to its set of sensors: a partial CO2 detector from the Pacific Marine Environmental Laboratory (PMEL). Aerosol measurements were also carried out onboard RHB by personnel of the University of Hawaii. Finally, the cruise hosted a teacher participating in NOAA's Teacher at Sea Program.
    Description: Funding was provided by the National Oceanic and Atmospheric Administration under Grant No. NA17RJ1223.
    Keywords: STRATUS ; Upper ocean ; Air-sea interaction ; Ronald H. Brown (Ship) Cruise RB06-07
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  • 13
    Publication Date: 2022-05-25
    Description: An array of five surface moorings carrying meteorological and oceanographic instrumentation was deployed for a period of two years beginning in June 1991 as part of an Office of Naval Research (ONR) funded Subduction experiment. Three eight month deployments were carried out. The five mooring locations were 18°N 34°W, 18°N 22°W, 25.5°N 29°W, 33°N 22°W and 33°N 34°W. Two Woods Hole Oceanographic Institution (WHOI) and three Scripps Institution of Oceanography (SIO) moorings collected oceanographic and meteorological data, using a 3-meter discus or 2-meter toroid buoy and multiple Vector Measuring Current Meters (VMCMs), an Acoustic Doppler Current Profiler (ADCP) and Brancker temperature recorders (tpods). The surface buoys carried a Vector Averaging Wind Recorder (VAWR) and, on four of the five moorings, an Improved Meteorological Recorder (IMET) which measured wind speed and wind direction, sea surface temperature, air temperature, short wave radiation, barometric pressure and relative humidity. The IMET also measured precipitation. The VMCMs, ADCP and tpods, placed at depths 1 m to 3500 m, measured oceanic velocities and temperatures. This report presents meteorological and oceanographic data from the WHOI Upper Ocean Processes Group (UOP) and the SIO Instrument and Development Group (lDG) instruments and contains summaries of the instruments used, their depths, mooring positions, mooring deployment and recovery times, and data return. Appendices contain information on supplementary Subduction data sets.
    Description: Funding provided by the Office of Naval Research under Contract No. N00014-90-J-1490.
    Keywords: Air-sea interaction ; Moored data ; Subduction ; Oceanus (Ship : 1975-) Cruise OC240 ; Oceanus (Ship : 1975-) Cruise OC250 ; Charles Darwin (Ship) Cruise CD73 ; Knorr (Ship : 1970-) Cruise KN138
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  • 14
    Publication Date: 2022-05-25
    Description: This report describes in a general manner the work that took place during the R/V Thomas Thompson cruise number 46 which was the mooring turnaround cruise for the moored array program. A detailed description of the WHOI surface mooring and its instrumentation is provided. Information about the XBT and CTD data and near-surface temperature data collected during the cruise is also included.
    Description: Funding was provided by the Office of Naval Research through Grant No. NOOOl4-94-1-0161.
    Keywords: Air-sea interaction ; Moored instruments ; Arabian Sea ; Thomas G. Thompson (Ship) Cruise TN46
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  • 15
    Publication Date: 2022-05-26
    Description: Three surface moorings were deployed in the eastern equatorial Pacifc from the R/V Roger Revelle as part of the Pan American Climate Study (PACS). PACS is a NOAA-funded study with the goal of investigating links between sea surface temperature varabilty in the tropical oceans near the Americas and climate over the American continents. The three moorings were deployed near 125°W, spanning the strong meridional sea surface temperature gradient associated with the cold tongue south of the equator and the warmer ocean north of the equator, near the northernmost, summer location of the Intertropical Convergence Zone. The mooring deployment was done to improve understading of the air-sea fluxes and of the processes that control the evolution of the sea surface temperature field in the region. Two surface moorings of the Upper Ocean Processes Group at the Woods Hole Oceanographic Institution (WHOI) were deployed-one at 3°S, 125°W and the other at lO°N, 125°W. One mooring from the Ocean Circulation Group (R. Weisberg) at the University of South Florida (USP) was deployed on the equator at 128°W. The buoys of the two WHOI moorings were each equipped with meteorological instrmentation, including a Vector Averaging Wind Recorder, and an Improved Meteorological (IMET) system. The WHOI moorings also carried Vector Measurng Current Meters, single-point temperature recorders, and conductivity and temperature recorders located in the upper 200 meters of the mooring line. In addition to the instrumentation noted above, a variety of other instruments, including an acoustic current meter, acoustic doppler current meters, bio-optical instrument packages and an acoustic rain gauge, were deployed during the PACS field program. The USF mooring had an IMET system on the surface buoy and for oceanographic instrumentation, two RD Instruments acoustic doppler current profilers, single-point temperature recorders, and conductivity and temperature recorders. Conductivity-temperature-depth (CTD) profiles were made at each mooring site and during the transit between mooring locations. This report describes, in a general manner, the work that took place durig the Genesis 4 cruise aboard the R/V Roger Revelle. The three surface moorings deployed during this cruise will be recovered and re-deployed after approximately nine months, with a final recovery planned for 17 months after the first setting. Details of the mooring designs and preliminary data from the CT profies are included.
    Description: Funding was provided by the National Oceanic and Atmospheric Administration under Contract No. NA66GP0130.
    Keywords: Air-sea interaction ; Moored instrument measurements ; PACS: eastern tropical Pacific ; Roger Revelle (Ship) Cruise Genesis 4
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  • 16
    Publication Date: 2022-05-26
    Description: An array of surface and subsurface moorings was deployed in the Arabian Sea to provide high quality time series of local forcing and upper ocean currents, temperature, and conductivity in order to investigate the dynamics of the ocean's response to the monsoonal forcing characteristic of the area. The moored array was first deployed during R/V Thomas Thompson cruise number 40; recovered and redeployed during R/V Thomas Thompson cruise number 46 and recovered to conclude the deployment during R/V Thomas Thompson cruise number 52. The array was part of the Office of Naval Research (ONR) funded Arabian Sea experiment. This report describes, in a general manner, the work that took place during the R/V Thomas Thompson cruise number 52. A detailed description of the Woods Hole Oceanographic Institution (WHOI) surface mooring and its instrumentation is provided. Information about the XBT and CTD data and near surface temperature data collected during the cruise is also included.
    Description: Funding was provided by the Office of Naval Research through Grant No. NOOOI4-94-1-0161.
    Keywords: Air-sea interaction ; Moored instruments ; Arabian Sea ; Thomas G. Thompson (Ship) Cruise TN52
    Repository Name: Woods Hole Open Access Server
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    Publication Date: 2022-05-26
    Description: An array of surface and subsurface moorings were deployed in the Arabian Sea to provide high quality time series of local forcing and upper ocean currents, temperature, and conductivity in order to investigate the dynamics of the ocean's response to the monsoonal forcing characteristic of the area. The moored array was deployed during R/V Thomas Thompson cruise number 40, One Woods Hole Oceanographic Institution (WHOI) surface mooring, two Scripps Institution of Oceanography (SIO) surface moorings and two University of Washington (UW) Profiling Current Meter moorings were deployed. The moorings were deployed for a period of one year beginning in October 1994 as part of the Office of Naval Research (ONR) funded Arabian Sea experiment. Two six month deployments were planned. The moorings were deployed at 15.5°N 61.5°E (WHOI), 15.7°N 61.3°E (SIO), 15.3°N 61.3°E (SIO), 15.7°N 61.7°E (UW), and 15.3°N 61.7°E (UW). The WHOI surface mooring was outfitted with two meteorological data collection systems. A Vector Averaging Wind Recorder (VAWR) and an IMET system made measurements of wind speed and direction, sea surface temperature, air temperature, short wave radiation, long wave radiation, barometric pressure, relative humidity and precipitation. Subsurface instrumentation included Vector Measuring Current Meters (VMCMs), Multi-Variable Moored Systems (MVMS), conductivity and temperature recorders and single point temperature recorders. Expendable bathythermograph (XBT) data and CTD data were collected while in transit to the site and between mooring locations. This report describes in a general manner the work that took place during R/V Thomas Thompson cruise number 40 which was the initial deployment cruise for this moored array. A detailed description of the WHOI surface mooring and its instrumentation is provided. Information about the XBT and CTD data collected during the cruise is also included.
    Description: Funding was provided by the Office of Naval Research under Grant No. N00014-94-1-0161.
    Keywords: Air-sea interaction ; Moored instruments ; Arabian Sea ; Thomas G. Thompson (Ship) Cruise TN40
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  • 18
    Publication Date: 2022-05-26
    Description: The Northwest Tropical Atlantic Station (NTAS) was established to address the need for accurate air-sea flux estimates and upper ocean measurements in a region with strong sea surface temperature anomalies and the likelihood of significant local air–sea interaction on interannual to decadal timescales. The approach is to maintain a surface mooring outfitted for meteorological and oceanographic measurements at a site near 15°N, 51°W by successive mooring turnarounds. These observations will be used to investigate air–sea interaction processes related to climate variability. Deployment of the first (NTAS-1), second (NTAS-2) and third (NTAS-3) moorings were documented in previous reports (Plueddemann et al., 2001; 2002; 2003). This report documents recovery of the NTAS-3 mooring and deployment of the NTAS-4 mooring at the same site. Both moorings used 3-meter discus buoys as the surface element. These buoys were outfitted with two Air–Sea Interaction Meteorology (ASIMET) systems. Each system measures, records, and transmits via Argos satellite the surface meteorological variables necessary to compute air–sea fluxes of heat, moisture and momentum. The upper 150 m of the mooring line were outfitted with oceanographic sensors for the measurement of temperature and velocity. The mooring turnaround was done on the NOAA ship Ronald H. Brown, Cruise RB-04-01, by the Upper Ocean Processes Group of the Woods Hole Oceanographic Institution. The cruise took place between 12 and 25 February 2004. The NTAS-3 buoy was found adrift and recovered on 19 February at 14°53.7’N, 51°22.8’W. Deployment of the NTAS-4 mooring was on 21 February at approximately 14°44.4’N, 50°56.0’W in 5038 m of water. A 30-hour intercomparison period followed, after which dragging operations to recover the lower portion of the NTAS-3 mooring commenced. This report describes these operations, as well as other work done on the cruise and some of the pre-cruise buoy preparations.
    Description: Funding was provided by the National Oceanic and Atmospheric Administration under Grant No. NA17RJ1223 and the Cooperative Institute for Climate and Ocean Research (CICOR).
    Keywords: Air-sea interaction ; Tropical Atlantic ; Moored instrumentation ; Ronald H. Brown (Ship) Cruise RB04-01
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  • 19
    Publication Date: 2022-05-26
    Description: The Woods Hole Oceanographic Institution (WHOI) Hawaii Ocean Timeseries (HOT) Site (WHOTS), 100 km north of Oahu, Hawaii, is intended to provide long-term, high-quality air-sea fluxes as a coordinated part of the HOT program and contribute to the goals of observing heat, fresh water and chemical fluxes at a site representative of the oligotrophic North Pacific Ocean. This report documents recovery of the WHOTS-1 mooring, deployed in August 2004 near 22.75°N, 158°W, and deployment of the WHOTS-2 mooring at the same site. Both moorings were outfitted with Air-Sea Interaction Meteorology (ASIMET) systems to measure, record, and transmit the surface meteorological variables necessary to compute air-sea fluxes of heat, moisture and momentum. In cooperation with R. Lukas of the University of Hawaii, the upper 155 m of the moorings were outfitted with oceanographic sensors for the measurement of temperature, conductivity and velocity. The WHOTS mooring turnaround was done on the Scripps Institution of Oceanography Ship Melville, Cruise TUIM-10MV. The cruise took place between 23 and 30 July 2005.
    Description: Funding was provided by the National Oceanic and Atmospheric Administration under Grant No. NA17RJ1223 and the Cooperative Institute for Climate and Ocean Research (CICOR).
    Keywords: Air-sea interaction ; Tropical Atlantic ; Moored instrumentation ; Melville (Ship) Cruise TUIM-10MV
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  • 20
    Publication Date: 2022-05-26
    Description: Numerical weather forecasting model products were acquired for use in the Coastal Mixing and Optics (CMO) Experiment to augment in situ observations of meteorological parameters (e.g., wind speed and direction, air temperature and relative humidity) at a moored array of buoys in the Middle Atlantic Bight. In this report, the Eta and Rapid Update Cycle (RUC) regional models are described and the two methods of acquisition via the Internet, the Internet Data Distribution (IDD) system and file transfer (FTP) from the NOAA Information Center's data server, are discussed. Processing and archival of the model data are also addressed. Data from the CMO central mooring and six National Data Buoy Center (NDBC) buoys in the Middle Atlantic bight were used to evaluate the accuracy of the model products. Comparisons between model and in situ wind speed, wind direction, barometrc pressure, air temperature and sea surface temperature were possible for all seven of the buoys. Since no moisture measurement was made from the NDBC buoys, comparisons of relative and specific humidity were only possible at the CMO buoy. Sensible and latent heat fluxes and global (net) radiation from the models were compared to estimates of heat fluxes and net radiation from the CMO central buoy.
    Description: Funding provided by the Office of Naval Research under Contract No. NOO014-95-1-0339.
    Keywords: Air-sea interaction ; Moored data ; Numerical weather forecasting models ; Coastal Mixing and Optics (CMO) Experiment
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  • 21
    Publication Date: 2022-05-26
    Description: Subduction is the mechanism by which water masses formed in the mixed layer and near the surface of the ocean find their way into the upper thermocline. The subduction process and its underlying mechanisms were studied through a combination of Eulerian and Langrangian measurements of velocity, measurements of tracer distrbutions and hydrographic properties and modeling. An array of five surface moorings carrying meteorological and oceanographic instrumentation were deployed for a period of two years beginning in June 1991 as part of an Office of Naval Research (ONR) funded Subduction experiment. Three eight month deployments were planned. The moorings were deployed at 18°N 34°W, 18°N 22°W, 25.5°N 29°W, 33°N 22°W and 33°N 34°W. A Vector Averaging Wind Recorder (VAWR) and an Improved Meteorological Recorder (IMET) collected wind speed and wind direction, sea surface temperature, air temperature, short wave radiation, barometric pressure and relative humidity. The IMET also measured precipitation. The moorings were heavily instrumented below the surface with Vector Measuring Current Meters (VMCM), and single point temperature recorders. Expendable bathythermograph (XBT) data were collected and meteorological observations were made while transitting between mooring locations. In addition a series of 59 cm stations were made and water samples taken to be analyzed for tritium levels, salinity and dissolved oxygen content. This report describes the work that took place during RRS Charles Darwin cruise number 73 which was the third scheduled Subduction mooring cruise. During this cruise the second setting of the moorings were recovered and redeployed for a third eight month period. This report includes a description of the instrumentation that was deployed and recovered, has information about the underway measurements (XBT and meteorological observations) that were made including plots of the data, includes a description of the work conducted in conjunction with the tracer/hydrography program and presents a chronology of the cruise events.
    Description: Funding was provided by the Office of Naval Research under contract N00014-90-J-1490.
    Keywords: Air-sea interaction ; Moored instruments ; Subduction ; Charles Darwin (Ship) Cruise CD73
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  • 22
    Publication Date: 2022-05-26
    Description: The Tropical Ocean - Global Atmosphere Coupled Ocean - Atmosphere Response Experiment (TOGA COARE) was conceived in order to improve understanding of the principal processes responsible for coupling of the ocean and atmosphere in the western Pacific warm pool region. Field work for TOGA COARE was concentrated in an Intensive Flux Array (IFA) and included a variety of atmospheric and oceanic platforms. The Upper Ocean Processes Group (UOPG) was involved in TOGA COARE through the preparation, deployment, and recovery of a heavily instrumented surface mooring for the observation of air-sea fluxes and oceanic temperature, salinity, and currents in the upper 300 m. The mooring was deployed at 1°,45.27'S, 155°,59.73'E on 21 October 1992 in 1744 m of water. An instrument check-out cruise was undertaken in December of 1992 in order to evaluate the meteorological systems on the buoy. The mooring was recovered on 4 March 1993. This report describes mooring deployment operations, the instrument check-out cruise, and the mooring recovery. UOPG personnel also assisted with the deployment and recovery of five other moorings as a part of the COARE IFA and these operations are discussed.
    Description: Funding provided by the National Science Foundation under grants OCE-9110554 and OCE-9110559.
    Keywords: Air-sea interaction ; Moored data ; Western Pacific warm pool ; Wecoma (Ship) Cruise WE92-10A ; Wecoma (Ship) Cruise WE93-02A ; le Noroit (Ship) Cruise
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  • 23
    Publication Date: 2022-05-26
    Description: The Marine Light - Mixed Layer experiment took place in the sub-Arctic North Atlantic ocean, approximately 275 miles south of Reykjavik, Iceland. The field program included a central surface mooring to document the temporal evolution of physical, biological and optical properties. The surface mooring was deployed at approximately 59°N, 21°W on 29 April 1991 and recovered on 6 September 1991. The Upper Ocean Processes Group of the Woods Hole Oceanographic Institution was responsible for design, preparation, deployment, and recovery of the mooring. The Group's contrbution to the field measurements included four different types of sensors: a meteorological observation package on the surface buoy, a string of 15 temperature sensors along the mooring line, an acoustic Doppler current profiler, and four instruments for measuring mooring tension and accelerations. The observations obtained from the mooring are sufficient to describe the air-sea fluxes and the local physical response to surface forcing. The objective in the analysis phase will be to determine the factors controlling this physical response and to work towards an understanding of the links among physical, biological, and optical processes. This report describes the deployment and recovery of the mooring, the meteorological data, and the subsurface temperature and current data.
    Description: Funding was provided by the Office of Naval Research under Contract N00014-89-J-1683.
    Keywords: Air-sea interaction ; Upper ocean structure ; Re-stratification ; Endeavor (Ship: 1976-) Cruise EN224 ; Endeavor (Ship: 1976-) Cruise EN227
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  • 24
    Publication Date: 2022-05-26
    Description: In 2001, the Geophysical Fluid Dynamics Summer Study Program grappled with Conceptual Models of the Climate. Eli Tziperman (Weizman Institute), Paola Cessi (Scripps Institution of Oceanography) and Ray Pierre- Humbert (University of Chicago) provided the principal lectures. This introduction gave us all a glimpse into the complex problem of the climate, both in the present, past and future, and even on other planets. As always, the next weeks of the program were filled with many seminars from the visitors, and culminated in the fellow's reports.
    Keywords: Climatic changes ; Physics
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  • 25
    Publication Date: 2022-05-26
    Description: The surface mooring component of the CLIVAR Long Term Evolution and Coupling of the Boundary Layers in the Stratus Deck Regions study (STRATUS) took place from October 2000 in the eastern tropical Pacific. As part of the Eastern Pacific Investigation of Climate Processes in the Coupled Ocean-Atmosphere System (EPIC), STRATUS is a CLIVAR study with the goal of investigating links between sea surface temperature variability in the eastern tropical Pacific and climate over the American continents. This study started a three-year occupation off Chili in order to collect accurate time series of surface forcing and upper ocean variability. The Upper Ocean Processes (UOP) Group at WHOI deployed one fully instrumented surface mooring near 20°S 85°W in October 2000, at the western edge of the stratocumulus cloud deck found west of Peru and Chile, to achieve a good understanding of the role of clouds in the eastern Pacific in modulating atmosphere-ocean coupling. Data from the moorings will improve our understanding of the air-sea fluxes and be used to examine the processes that control sea surface temperature in the cold tongue/intertropical convergence zone (ITCZ) and in the stratus deck region. The first surface mooring (STRATUS 1) was deployed in October 2000 by the UOP group and replaced by a second mooring one year later with almost identical instrumentation (STRATUS 2). STRATUS 1 was equipped with meteorological instrumentation, including two Improved METeorological (IMET) systems. The mooring also carried Vector Measuring Current Meters (VMCMs), single point temperature, salinity and conductivity recorders, and an acoustic Doppler Current Profiler (ADCP) to monitor the upper 500m of the ocean. In addition to the traditional instruments, several other experimental instruments were deployed with limited success on the mooring line including an acoustic current meter, bio-optical instrumentation packages, and an acoustic rain gauge. This report describes the instrumentation deployed on the first STRATUS surface mooring (STRATUS 1 mooring) from October 2000 to October 2001, along with information on the processing and quality control of the returned data. It presents a detailed overview of the meteorological and physical oceanographic data including time series plots, statistics and spectra of key parameters. It also presents the estimated air-sea heat, moisture and momentum fluxes.
    Description: Funding was provided by the National Oceanic and Atmospheric Administration under Grant Numbers NA81RJ1223.
    Keywords: STRATUS ; Air-sea interaction ; Data report ; Melville (Ship) Cruise ; Ronald H. Brown (Ship) Cruise RB01-08
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    Publication Date: 2022-05-26
    Description: The Northwest Tropical Atlantic Station (NTAS) was established to address the need for accurate air-sea flux estimates and upper ocean measurements in a region with strong sea surface temperature anomalies and the likelihood of significant local air–sea interaction on interannual to decadal timescales. The approach is to maintain a surface mooring outfitted for meteorological and oceanographic measurements at a site near 15°N, 51°W by successive mooring turnarounds. These observations will be used to investigate air–sea interaction processes related to climate variability. Deployment of the first NTAS mooring (NTAS-1) at 14°50′ N, 51°00′ W on 30 March 2001 was documented in a previous report (Plueddemann et al., 2001). This report documents recovery of the NTAS-1 mooring and deployment of the NTAS-2 mooring at the same site. Both moorings used 3-meter discus buoys as the surface element. These buoys were outfitted with two Air–Sea Interaction Meteorology (ASIMET) systems. Each system measures, records, and transmits via Argos satellite the surface meteorological variables necessary to compute air–sea fluxes of heat, moisture and momentum. The upper 120 m of the NTAS-1 mooring line, and the upper 150 m of the NTAS-2 mooring line, were outfitted with oceanographic sensors for the measurement of temperature and velocity. The mooring turnaround was done on the NOAA Ship Ronald H. Brown, Cruise RB-02-02, by the Upper Ocean Processes Group of the Woods Hole Oceanographic Institution. The cruise took place between 2 and 8 March 2002. A SeaBeam bathymetry survey of the site was done first, followed by deployment of the NTAS-2 mooring on 4 March at approximately 14°44.3′ N, 50°56.8′ W in 5043 m of water. A 24-hour intercomparison period followed, after which the NTAS-1 mooring was recovered. This report describes these operations, as well as some of the pre-cruise buoy preparations.
    Description: Funding was provided by the National Oceanic and Atmospheric Administration and the Cooperative Institute for Climate and Ocean Research (CICOR) under Grant No. NA17RJ1223.
    Keywords: Air-sea interaction ; Tropical Atlantic ; Moored instrumentation ; Ronald H. Brown (Ship) Cruise RB02-02
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  • 27
    Publication Date: 2022-05-26
    Description: The Long Term Evolution and Coupling of the Boundary Layers Study (referred to as the Stratus Project) is an effort to obtain a reliable multi-year dataset of meteorological and subsurface measurements beneath the stratus cloud deck off the coast of Chile and Peru. This data will improve our understanding of the role of clouds in ocean-atmosphere coupling. This project is part of the Eastern Pacific Investigation of Climate (EPIC), a NOAA-funded Climate Variability (CLIVAR) study. During the Stratus 2002 cruise, a surface mooring that had been deployed for one year off the coast of Chile was recovered, and a new surface mooring was deployed in the same location. The 2002 deployment starts the final year of a three-year occupation of the site by a Woods Hole Oceanographic Institution (WHOI) mooring as part of the Enhanced Monitoring element of EPIC. The occupation of the site will be continued under the NOAA Climate Observations Program, with the mooring serving as a Surface Reference Site. The Stratus buoys were equipped with surface meteorological instrumentation, mainly two Improved METeorological (IMET) systems. The moorings also carried subsurface equipment attached to the mooring line, which measured conductivity, temperature, current direction and velocity, chlorophyll-a, and rainfall. The moorings were recovered and deployed by the Upper Ocean Processes Group of WHOI from the Scripps Institution of Oceanography’s R/V Melville. In collaboration with investigators from the Chilean Navy Hydrographic and Oceanographic Service (SHOA) and the University of Concepcion, Chile, conductivity, temperature, and depth (CTD) profiles were obtained at the mooring site and along 20°S while steaming east from the mooring site.
    Description: Funding was provided by the National Oceanic and Atmospheric Administration under Grant Number NA17RJ1223.
    Keywords: STRATUS ; Air-sea interaction ; Moored data ; Melville (Ship) Cruise Vanc03
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    Publication Date: 2022-05-26
    Description: The Northwest Tropical Atlantic Station (NTAS) was established to address the need for accurate air-sea flux estimates and upper ocean measurements in a region with strong sea surface temperature anomalies and the likelihood of significant local air–sea interaction on interannual to decadal timescales. The approach is to maintain a surface mooring outfitted for meteorological and oceanographic measurements at a site near 15°N, 51°W by successive mooring turnarounds. These observations will be used to investigate air–sea interaction processes related to climate variability. Deployment of the first (NTAS-1) and second (NTAS-2) moorings were documented in previous reports (Plueddemann et al., 2001, 2002). This report documents recovery of the NTAS-2 mooring and deployment of the NTAS-3 mooring at the same site. Both moorings used 3-meter discus buoys as the surface element. These buoys were outfitted with two Air–Sea Interaction Meteorology (ASIMET) systems. Each system measures, records, and transmits via Argos satellite the surface meteorological variables necessary to compute air–sea fluxes of heat, moisture and momentum. The upper 150 m of the mooring line were outfitted with oceanographic sensors for the measurement of temperature and velocity. The mooring turnaround was done on the WHOI R/V Oceanus, Cruise OC-385-5, by the Upper Ocean Processes Group of the Woods Hole Oceanographic Institution. The cruise took place between 12 and 23 February 2003. Deployment of the NTAS-3 mooring was on 15 February at approximately 14°49.5¢ N, 51°01.3¢ W in 4977 m of water. A 24- hour intercomparison period followed, after which the NTAS-2 mooring was recovered. This report describes these operations, as well as some of the pre-cruise buoy preparations.
    Description: Funding was provided by the National Oceanic and Atmospheric Administration under Grant Number NA17RJ1223.
    Keywords: Air-sea interaction ; Tropical Atlantic ; Moored instrumentation ; Oceanus (Ship : 1975-) Cruise OC385-5 ; OC385-5
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  • 29
    Publication Date: 2022-05-26
    Description: The Arabian Sea is characterized by strong, large-scale atmospheric forcing during the summer (southwest) and winter (northeast) monsoons. To investigate air-sea interactions related to this unique surface forcing, a moored array was deployed from 15 October 1994 to 19 October 1995 just south of a region that experiences the climatological maximum winds during the summer monsoon. The array consisted of two Scripps Institution of Oceanography surface toroid buoys, two University of Washington subsurface moorings and a surface 3 m discus buoy deployed by the Woods Hole Oceanographic Institution (WHOI). The WHOI buoy carried redundant meteorological packages to measure wind speed and direction, air temperature, relative humidity, barometrc pressure, incoming short- and long-wave radiation and precipitation. Oceanographic instrumentation was deployed on the WHOI buoy's bridle and mooring line to collect time series of temperatue, salinity and velocity at various depths. Four multi-varable moored systems (MVMS) were also deployed along the mooring line by the Lamont-Doherty Earth Observatory and the University of California at Santa Barbara to record both bio-optical and physical parameters. This report describes the instrumentation deployed on the WHOI buoy and the processing and editing of the returned data. The data are then summarized in graphical and tabular formats.
    Description: Funding provided by the Office of Naval Research under Contract No. N00014-94-1-0161.
    Keywords: Air-sea interaction ; Moored data ; Thomas G. Thompson (Ship) Cruise TN40 ; Thomas G. Thompson (Ship) Cruise TN46 ; Thomas G. Thompson (Ship) Cruise TN52
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  • 30
    Electronic Resource
    Electronic Resource
    New York : Wiley-Blackwell
    Journal of Polymer Science: Polymer Physics Edition 13 (1975), S. 127-135 
    ISSN: 0098-1273
    Keywords: Physics ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Physics
    Notes: Fracture surfaces of an oriented polystyrene (by stretching 150% at 280°F) show many of the same features observed in the fracture of ordinary polystyrene: craze formation followed by quasi-viscous separation of the craze layer or by quasi-brittle fracture along the craze boundary. In cleavage fracture along the direction of orientation, advance fractures are initiated in flat areas covered, if at all, by an extremely thin layer of craze: the initiation of the “crazeles” fractures appears to arise from the orientation of the molecules rather than the presence of impurity particles.
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  • 31
    Electronic Resource
    Electronic Resource
    New York : Wiley-Blackwell
    Journal of Polymer Science: Polymer Physics Edition 13 (1975), S. 43-57 
    ISSN: 0098-1273
    Keywords: Physics ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Physics
    Notes: We describe a new technique for producing fibrous crystals from shear-induced crystallization of polymer solutions and polymer melts. Our technique makes use of a modified version of the 4-Roller apparatus originally developed by G. I. Taylor to study the formation of emulsions. This apparatus generates a planar extensional flow field in which macromolecules are extended more easily than in flow fields with transverse velocity gradients.
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  • 32
    Electronic Resource
    Electronic Resource
    New York : Wiley-Blackwell
    Journal of Polymer Science: Polymer Physics Edition 13 (1975), S. 73-86 
    ISSN: 0098-1273
    Keywords: Physics ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Physics
    Notes: Extrudates of solid linear polyethylene prepared under proper pressure and temperature conditions have a high c axis orientation along the extrusion direction, with lamellar crystals and amorphous layers stacked alternately along the extrusion direction. Kink bands were formed by compressing the oriented extrudate at room temperature along the extrusion direction. Inspection of the kink bands by wide-angle and small-angle x-ray diffraction and electron microscopy revealed that the fiber axis was rotated from the original axis direction by 70-75° and that the lamellar crystals were inclined to the fiber axis in the kink band by 55-60° and stacked nearly parallel to the kink boundary. The superstructural change during the formation of the kink band could not be interpreted in terms of uniform c axis shear alone. In addition to such a mechanism, it was necessary to take into account intermicrofibril and/or intercrystallite slip.
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  • 33
    Electronic Resource
    Electronic Resource
    New York : Wiley-Blackwell
    Journal of Polymer Science: Polymer Physics Edition 13 (1975), S. 137-149 
    ISSN: 0098-1273
    Keywords: Physics ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Physics
    Notes: The complex compliance in extension of gels of poly(vinyl chloride) (PVC) in di(2-ethylhexyl) phthalate (DOP) and in tricresyl phosphate (TCP) was measured over the frequency range from 0.6 to 0.006 cps and the temperature range from -66 to 65°C: the weight fractions of DOP and TCP in the gels were 0.32, 0.40, 0.49, and 0.59. Measurements were carried out in an apparatus using forced low-frequency longitudinal osillations. Data for the gels could not be combined by the method of reduced variables, since there were gradual changes with decreasing temperature, attributable to an increase in crystallinity. Application of the reduction method of Ninomiya and Ferry for solutions of crystalline polymers was found to be successful. The apparent melting temperatures (T′m) were obtained from the temperature dependence of the vertical shift factors. An apparent heat of fusion of ca. 120 cal/mole of monomer unit was found. This melting range was in agreement with that of secondary crystallinity in plasticized PVC reported in calorimetric studies by Juijn. With decreasing temperature, two phenomena occurred in the temperature range from Tg + ca. 80°C to Tg: the vitrification of a concentrated amorphous solution and the slight crystallization of the polymeric component. The larger the difference between Tg and T′m the broader the primary dispersion zone on the frequency scale. This broadening effect was explained as due to the difference in dependence of Tg and T′m on plasticizer concentration, without any need to consider any specific interaction between plasticizer and PVC.
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  • 34
    Electronic Resource
    Electronic Resource
    New York : Wiley-Blackwell
    Journal of Polymer Science: Polymer Physics Edition 13 (1975), S. 223-241 
    ISSN: 0098-1273
    Keywords: Physics ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Physics
    Notes: Certain inorganic nitrate salts are quite soluble in the polymers studied, namely, cellulose acetate, poly(vinyl acetate), poly(vinyl alcohol), poly(methyl methacrylate), and poly(methyl acrylate). Large effects upon the glass-transition temperature were observed in those systems where the transition could be readily measured. Large shifts in the infrared spectra of both the inorganic nitrate salts and in the polymer carbonyl and ester ether frequencies have been observed. These observations have been interpreted in terms of complex formation between these polymers and salts in the solid state. The proposed structure of the complex explains the nature of the infrared shifts both for the nitrate salts and the polymers as well as explaining the concentration effects observed. Effects of the solvating environment upon the salt and polymer spectra remain unexplained. The large glass-transition effects are a result of the degree of solubility of the salts in the polymers and the interactions between them. However, the reason why, in some cases, the change in the transition temperature as a function of concentration goes through a maximum is unclear.
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    Electronic Resource
    Electronic Resource
    New York : Wiley-Blackwell
    Journal of Polymer Science: Polymer Physics Edition 13 (1975), S. 263-274 
    ISSN: 0098-1273
    Keywords: Physics ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Physics
    Notes: The deformational, swelling, and potentiometric behavior of poly(methacrylic acid) gels was measured as a function of the degree of crosslinking, ionic strength, and degree of ionization. The comparison of the stress-strain behavior with theoretical relations derived in the preceding part has shown that the relations are valid only if an increase is assumed in the number of monomeric units in the statistical chain segment with increasing degree of neutralization of the gel. This dependence is affected by the salt content in the swelling solution and is also dependent on the activity coefficient of counterions. The pK0 values for an undissociated gel approach pK0 = 5.0 and increase somewhat with degree of neutralization. The swelling equilibria are in qualitative agreement with theoretical assumptions; their quantitative agreement depends on the activity coefficient of counterions.
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  • 36
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    Journal of Polymer Science: Polymer Physics Edition 13 (1975), S. 333-338 
    ISSN: 0098-1273
    Keywords: Physics ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Physics
    Notes: Samples of n-hexatriacontane irradiated in the crystalline and molten states were compared as regards the GPC chromatograms of the partially crosslinked products. From differences in the elution volumes it could be inferred that there is a greater trend for random linking along the chain in the sample irradiated in the melt as opposed to preference for end-type linking in the samples irradiated as crystals. In the course of this work the applicability of the GPC technique for detecting short (methyl) branches and for distinguishing between the position of these branches along the chain has also become apparent.
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  • 37
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    Keywords: Physics ; Polymer and Materials Science
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    Notes: Partial molar excess free enthalpies (or excess chemical potentials) at infinite dilution were obtained over a large temperature range by gas chromatography. Data on n-alkenes in Apiezon M are interpreted by the Prigogine-Patterson theory; data on normal and branched alkanes in squalane and polydimethylsiloxane (PDMS) are discussed in terms of the Prigogine-Patterson theory and the solution theory of Flory, Orwoll, and Vrij. For the alkane-PDMS systems heats of dilution and partial excess heat capacity data are given.The aim of this work is to get some insight in the applicability of these solution theories to mixtures of fluids, the properties of which may slightly violate the basic assumptions of these theories. It is shown that orientational order in and a large cross-sectional chain diameter of the polymer solvent do not affect their applicability to the partical molar excess free enthalpies of apolar mixtures, whereas large dissimilarities between the force fields around the segments of the mixture components and/or dissimilar chain flexibilities detract from the applicability of these theories (alkanes in PDMS).Special attention has been paid to the effects of dissimilar size and shape of the segments of the mixture compounds on the magnitude of the interchange interaction parameter. It is shown that the multiple-connected segment model after Lichtenthaler et al. does not warrant a reliable combinatorial contribution. Comparison of the interaction parameters obtained for n-alkanes in n-alkanes, Apiezon, squalane, and polyisobutylene and for branched alkanes in squalane reveals that the magnitude of this parameter is affected by small end-effects due to the relative weakness of methyl-methylene interactions.
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  • 38
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    Journal of Polymer Science: Polymer Physics Edition 13 (1975), S. 437-441 
    ISSN: 0098-1273
    Keywords: Physics ; Polymer and Materials Science
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    Topics: Chemistry and Pharmacology , Physics
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  • 39
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    Journal of Polymer Science: Polymer Physics Edition 13 (1975), S. 477-492 
    ISSN: 0098-1273
    Keywords: Physics ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Physics
    Notes: The effect of base stacking interactions on the conformation of poly(9-vinyladenine) (PVAd) was investigated by osmometry, intrinsic viscosity, and light-scattering measurements. At neutral pH, ideal solution behavior (θ conditions) for this polymer was observed at 26 and 40°C. Intrinsic viscosity measurements revealed a conformational transition on heating from 26 to 40°C, while the ultraviolet absorbance of the solution was insensitive to the change. The transition was accompanied by an inversion in sign of the entropy parameter from negative to positive and an increase in the partial specific volume. At 40°, the variation of intrinsic viscosity with molecular weight corresponded to a random coil conformation, but the characteristic ratio, r̄02/nl2 = 8.6 ± 0.2 indicated that the unperturbed dimensions were smaller than usually observed for comparable vinyl polymers. At 26°, a rare macromolecular phenomenon was found, the intrinsic viscosity-molecular weight relation and the estimated r̄02/nl2 of 6.0-6.8 suggested that the PVAd was in a very highly compacted coil conformation, approaching a semirigid sphere. It is proposed that this effect be named the introversion phenomenon. Unlike polyadenylic acid, whose unperturbed dimensions increase with decreasing temperature due to nearest-neighbor base stacking, the results reported here suggest that both nearest-neighbor and long-range intramolecular base stacking occur in PVAd. The different stereochemical arrangements of bases in PVAd and Poly A are probably responsible for the opposite behavior observed.
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  • 40
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    Journal of Polymer Science: Polymer Physics Edition 13 (1975), S. 533-566 
    ISSN: 0098-1273
    Keywords: Physics ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Physics
    Notes: The deformation of polyethylene in terms of structural processes has been investigated by low-and wide-angle x-ray diffraction in the case of low-density and, to a lesser extent, high-density polyethylene. The samples possessed a range of simple textures which enabled the deformation processes to be identified. The results are interpreted in terms of a model of stacks of lamellae which have axes along the original draw direction and which deform by lamellar slip, chain slip, and lamellar separation. In most cases these processes accounted for the macroscopic strain but in some cases discrepancies were observed which could be accounted for by inhomogeneous deformation or by the effects of a distribution of lamellar thicknesses. Attempts were made to identify fibrillar slip, without success. The relative contributions of the various deformation processes are examined as a function of temperature and sample treatment by defining a compliance constant for each process. Below room temperature, the results are consistent with expectations based on the α and β mechanical relaxations, whereas the unusual effects at high temperatures are attributed to gradual melting. The compliance constants are also found to depend on the annealing temperature of the sample, and are used to predict the mechanical anisotropy. The volume changes accompanying lamellar separation are examined. They were less than expected in low-density polyethylene, but satisfactory agreement was obtained in high-density polyethylene. A general relation is suggested between volume changes and the lateral development of the lamellae. Hence in narrow lamellae the interlamellar layer can contract laterally whereas the greater constraints imposed by wide lamellae lead to void formation. Other effects examined include the reversibility of the processes which is most marked in the case of chain slip and which is explained by the presence of restoring forces in the amorphous regions including the fold surface. Finally, the differences between low- and highdensity polyethylene are highlighted, emphasizing the part played in the deformation by the amorphous component.
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  • 41
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    Journal of Polymer Science: Polymer Physics Edition 13 (1975), S. 599-605 
    ISSN: 0098-1273
    Keywords: Physics ; Polymer and Materials Science
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    Topics: Chemistry and Pharmacology , Physics
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  • 42
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    Journal of Polymer Science: Polymer Physics Edition 13 (1975), S. 663-666 
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    Keywords: Physics ; Polymer and Materials Science
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    Topics: Chemistry and Pharmacology , Physics
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  • 43
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    Journal of Polymer Science: Polymer Physics Edition 13 (1975), S. 675-682 
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    Keywords: Physics ; Polymer and Materials Science
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    Topics: Chemistry and Pharmacology , Physics
    Notes: In the preceding paper, general equations were established for the motions of chains confined to a tetrahedral lattice. In the present paper, bond orientation correlation and autocorrelation functions are explicitly calculated for the case where only three-bond elementary motions are considered. Effects due to the chain end are analyzed and the relaxation time distribution function is established. The expressions obtained reflect the influence of the chain structure. Finally, to characterize the dynamic behavior of chains in orientation relaxation experiments, the notion of an independent kinetic segment is proposed.
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  • 44
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    Journal of Polymer Science: Polymer Physics Edition 13 (1975), S. 1167-1176 
    ISSN: 0098-1273
    Keywords: Physics ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Physics
    Notes: A study of the morphology of thermally induced crystallization in poly(N-vinylcarbazole) has shown the formation of folded chain lamellae. Diffraction analysis of multiple and single lamellae indicates a paracrystalline structure with hexagonal symmetry about the chain axis and an interchain spacing of 12.00 Å. No sharp reflections due to chain axis periodicity were observed and the chain axis period was calculated from the crystalline density extrapolated to 100% crystallinity. This gave a chain axis period/monomer unit of 2.16 Å consistent with an isotactic 3/1 screw axis and a basic trigonal structure with a = 12.00 Å and c = 6.47 Å.
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  • 45
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    Journal of Polymer Science: Polymer Physics Edition 13 (1975), S. 1215-1231 
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    Keywords: Physics ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Physics
    Notes: The viscoelastic properties of chain molecules varying in flexibility and length have been calculated by use of the bead-spring model theory of Zimm. In the evaluation of the hydrodynamic interaction parameter, the number of springs in the bead-spring model, N, has been selected from the range in which the properties predicted by the theory are insensitive to the value of N. The results for limiting viscosity number agree with those predicted by the Yamakawa-Fujii theory of the limiting viscosity number of wormlike chains. The theory also fits the experimental data of Johnson on a sample of polystyrene of molecular weight 860,000 in theta solvents at infinite dilution. The viscoelastic properties of some moderate molecular weight deoxyribonucleic acid solutions are predicted to deviate from the non-free-draining behavior toward the free-draining behavior.
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  • 46
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    Journal of Polymer Science: Polymer Physics Edition 13 (1975), S. 1269-1274 
    ISSN: 0098-1273
    Keywords: Physics ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Physics
    Notes: Earlier work showed that heating causes poly(diethylsiloxane) to undergo a first-order transition from a semicrystalline solid to a more mobile viscous - crystalline material. The latter is composed of two phases and analogies between polymer and liquid crystal morphology and behavior have been made. The viscous - crystalline phase in PDES appears to be unique since the literature is devoid of other documented examples. In this study, spin - lattice and spin - spin relaxation times were measured over a wide temperature range. They show a glass transition at 138°K, a crystal - crystal transition at 206°K, and a transition around 250°K which results from translational motion of the polymer chains with respect to each other. This motion is observed in the amorphous phase at a lower temperature than in the crystalline phase. Translational motion in the crystalline phase is observed on melting of the crystallites. The spin - spin data permitted monitoring of the molecular motions in each phase and the data suggest that these phases exert some influence on the molecular motions of each other. The viscous - crystalline phase in PDES may represent a unique model for studying and understanding “precrystalline” behavior and structure in amorphous solids.
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  • 47
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    Journal of Polymer Science: Polymer Physics Edition 13 (1975), S. 1333-1346 
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    Keywords: Physics ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Physics
    Notes: Real and imaginary parts of the dielectric constant of wet and dry polyglycine have been measured for several temperatures over a wide range of frequencies. A simple, rather crude model, proposed earlier for nylon 66, fits the experimental data rather well, but the blocking coefficient p is larger and adsorption effects are more important.
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  • 48
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    Journal of Polymer Science: Polymer Physics Edition 13 (1975), S. 1377-1386 
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    Keywords: Physics ; Polymer and Materials Science
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    Topics: Chemistry and Pharmacology , Physics
    Notes: Measurements of dielectric relaxation have been made for a series of solutions of poly(methyl methacrylate) in toluene. A range of concentrations between 2% and 20% was used for a number of polymers of differing molecular weights. The dispersion was studied over the frequency range 103-106 Hz for temperatures between -90°C and +20°C. It has been found that both the distribution of relaxation times and the activation energy increase with increasing concentration. The magnitudes of the effects vary with molecular weight. A significant observation is that the increase in dielectric constant with concentration is not linear.
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  • 49
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    Journal of Polymer Science: Polymer Physics Edition 13 (1975), S. 1417-1446 
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    Keywords: Physics ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Physics
    Notes: The melting behavior of restrained isotactic polypropylene fibers is examined quantitatively in terms of the influence the anisotropic structural state of the polymer has on the observed properties. Two endotherm peaks are observed to occur in some of the samples. The formation and location of the multiple peaks are determined by the orientation of the noncrystalline chains, and is independent of the fabrication path used to achieve that orientation. Above a certain minimum orientation of the noncrystalline chains, multiple endotherm peak formation occurs. The high-temperature endotherm (T2M) extrapolates to an ultimate melting point for fully oriented noncrystalline chains of 220°C, while the lower-temperature endotherm (T1M) extrapolates to an ultimate melting point of 185°C. Noncrystalline chain orientation influences the endotherm temperature through its changing configurational entropy. It is shown quantitatively that the noncrystalline polymer must be considered as plastically deformed, since rubber elasticity theory is not followed as predicted. The melting behavior of isothermally crystallized samples are also reported to further elucidate the nature of the observed endotherms.
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  • 50
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    Notes: Further stress relaxation experiments, mostly at 50°C, are reported on mixtures of crosslinkable ethylene-propylene terpolymer with saturated ethylene-propylene copolymer (molecular weights 3.6 and 45 × 104) containing up to 50% by weight of copolymer, crosslinked by sulfur to leave the saturated copolymer unattached and free to reptate in the copolymer network. Stress relaxation was measured in small simple elongations (stretch ratio about 1.15) on samples which had been extracted to remove a large part of the unattached copolymer and dried. The relative increase in modulus at long times (104 sec) increased with the proportion extracted; at short times (1 sec), extraction of the lower molecular weight copolymer increased the modulus to about the same extent but extraction of the higher molecular weight copolymer affected it very little. The relaxation modulus of the copolymer extracted from sample 50H (50% copolymer of high molecular weight), obtained by difference, agreed with that for the total copolymer except for a small difference probably attributable to molecular weight selectivity in the extraction. Stress relaxation was measured on sample 50H at six higher elongations up to a stretch ratio of 3. The dependence of stress on time and strain was consistent with an analysis based on the following assumptions: (a) linear additivity of the network and unattached copolymer contributions, (b) strain-time factorization of the stress contributions from the individual components, (c) a strain dependence for the unattached component corresponding to the presence of a Mooney-Rivlin C2 term only, (d) a strain dependence for the network component which does not follow the Mooney-Rivlin equation but is dominated by a simple neo-Hookean term.
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  • 51
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    Journal of Polymer Science: Polymer Physics Edition 13 (1975), S. 1705-1719 
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    Keywords: Physics ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Physics
    Notes: Chain characteristics of a linear sulfonate-containing homopolymer, sodium poly(3-methacryloyloxypropane-1-sulfonate), in aqueous salt solutions (ionic strength, Cs = 0.01N to 5N NaCl) have been investigated by light scattering and intrinsic viscosity. The molecular weight (M̄w)-viscosity relation can be well described by the Mark-Houwink and the Stockmayer-Fixman equations. The coil is highly expanded even in the most concentrated NaCl solution (6N), and no 1:1 electrolyte was found to precipitate this polymer.A linear relation was observed between the viscosity expansion factor, α3η, and (M̄w/Cs)1/2. Examination of the data in terms of theories for excluded volume and hydrodynamic interaction suggests that the coil experiences dominant hydrodynamic interaction, corresponding to a nondraining coil, and the second virial coefficient and coil expansion at high Cs can be correlated by the Flory-Krigbaum-Orofino equation. Results for this polymer are compared with those for other polyelectrolytes, and are discussed in terms of chain structure, flexibility, and hydrophobicity.
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    Journal of Polymer Science: Polymer Physics Edition 13 (1975), S. 1783-1787 
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    Keywords: Physics ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Physics
    Notes: When a mixture of two monodisperse samples of poly-α-methylstyrene is thermally degraded, the components behave independently, as a first approximation, as shown by GPC and rate of volatilization data. The ratio Mw/Mn, before approaching the ultimate value of 2.0, first goes through a minimum at a much lower value.
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    Journal of Polymer Science: Polymer Physics Edition 13 (1975), S. 1809-1817 
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    Keywords: Physics ; Polymer and Materials Science
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    Topics: Chemistry and Pharmacology , Physics
    Notes: The overall rate of crystallization of isotactic polystyrene from dilute solutions, 1% by weight, in trans-decalin and benzyl alcohol was studied as a function of temperature using dilatometry. These solvents were chosen because the dissolution temperatures of crystalline isotactic polystyrene are practically the same in both solvents. The overall rate of crystallization as a function of crystallization temperature showed a maximum in both solvents at about 50°C. At lower crystallization temperatures the rate of crystallization is much lower. The overall rate of crystallization of isotactic polystyrene in benzyl alcohol is far larger than in trans-decalin at the same undercooling throughout the temperature range, which is in apparent contradiction to present crystallization theories. At very large undercooling (Tc lower than about 0°C) the solutions of isotactic polystyrene in both solvents quickly become “rigid” gels. Surface replicas of freeze-etched gels indicate that a fringed micelle type of crystallization takes place at these low temperatures. The transition from folded chain crystallization to fringed micelle crystallization may be due to a stiffening of the polymer chain below about 50°C, with a reduced rotational mobility of the phenyl groups on the chain. If very dilute solutions, below 0.5% by weight, are crystallized at these low temperatures no gels were formed but fibrous crystals are produced which could be observed under the polarizing microscope.
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    Journal of Polymer Science: Polymer Physics Edition 13 (1975), S. 1849-1854 
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    Keywords: Physics ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Physics
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    Journal of Polymer Science: Polymer Physics Edition 13 (1975), S. 1871-1879 
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    Keywords: Physics ; Polymer and Materials Science
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    Topics: Chemistry and Pharmacology , Physics
    Notes: The mechanical properties (Young's modulus, ultimate tensile strength, deformation processes) of extended-chain polydiacetylene crystals are investigated. The properties observed are similar to those of metal and ceramic whiskers. The elastic modulus is strain-dependent and the ultimate tensile strength increases with decreasing crystal size. The maximum tensile strength observed was 1700 Nmm-2. The ultimate tensile strength seems to be controlled by the presence of a small number of defects near the surface at which fracture nucleates. Irreversible deformation of the crystals was observed to occur by crack propagation normal and parallel to the direction of the macromolecules. The observed mechanical behavior corresponds to exceptionally high per-chain properties. The per-chain modulus obtained for these crystals is nearly as high as that of diamond. A chain-aligned polyethylene fiber with the same per-chain mechanical properties would have an ultimate strength as high as 0.9 × 104 Nmm-2.
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  • 56
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    Journal of Polymer Science: Polymer Physics Edition 13 (1975), S. 1913-1923 
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    Keywords: Physics ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Physics
    Notes: Contraction experiments were performed on hot-stretched polystyrene during isothermal annealing and tempering. Activation energy spectra were obtained from the experimental data using the Primak theory. In the case of isothermal annealing the theory of Kimmel et al. with shift factors was used. There is an appreciable difference between this spectrum and that obtained from the tempering experiment by the original theory without shift factors. These two spectra should be the same according to the theory. In order to resolve the conflict, we have included a correlation between activation processes in the fundamental equation of the Primak theory. A new formula for calculating the activation energy spectra was obtained. For isothermal annealing, it can be written the same as that of Kimmel et al. The shift factor is also included in the formula for tempering. The activation energy spectra obtained by the new formula gives good agreement between the two methods.
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    Journal of Polymer Science: Polymer Physics Edition 13 (1975), S. 1939-1944 
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    Topics: Chemistry and Pharmacology , Physics
    Notes: Observations by transmission electron microscopy suggest that surface-controlled recrystallization of polyethylene occurs by the solid state nucleation and growth of new crystals with (110) or (110) planes parallel to the free surface. The nucleation site of these crystals is the free surface. The growth process involves the migration of [002] tilt boundaries suggesting that these boundaries have high mobilities. The migration process may occur by the lateral rearrangement of the macromolecules in the [002] tilt boundary.
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    Journal of Polymer Science: Polymer Physics Edition 13 (1975), S. 2129-2134 
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    Keywords: Physics ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Physics
    Notes: The peel strength found in the trousers-type peeling process is treated for the case in which the adherends, assumed to be flexible but inextensible are bonded by rubbery viscoelastic adhesives.Taking into consideration energy dissipation during deformation of the adhesive, Griffith's criterion is extended to the peeling of viscoelastic materials. For the peeling force per unit width f it is deduced that 2f = Γ + u′h, where T is twice the surface energy, u' is the energy dissipation per unit volume of adhesive, and h is the thickness of the adhesive layer. Values of u' obtained from peeling tests for various thicknesses are compared with those from the tensile tests and found to agree with the above relation. The deduction that the peel strength is independent of the thickness for adhesives with no energy dissipation is also verified experimentally.
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    Journal of Polymer Science: Polymer Physics Edition 13 (1975), S. 2289-2298 
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    Keywords: Physics ; Polymer and Materials Science
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    Topics: Chemistry and Pharmacology , Physics
    Notes: The low-frequency (10-3 to 5 × 10-1 Hz) dynamic mechanical properties were obtained over the temperature range of 25 to 96°C for 1,5-trans-polypentenamer networks prepared in the presence of 0,0.01, 0.02, 0.04, 0.1, 0.2, and 0.4% dicumyl peroxide. For comparison, similar properties of 1,4-polybutadiene crosslinked with 0.02% dicumyl peroxide were also measured. Superimposed curves for the components of the dynamic compliance, Jp′ and Jp″, reduced to 25°C were obtained and the retardation spectra L were calculated over a range of four logarithmic decades deep in the rubberlike region. It was found that networks containing 0.04 and 0.1% DCP have a small loss maximum Jp″ in the reduced frequency region log ωaT between -2 and 0 which can be assigned to relaxations of untrapped entanglements. The values of (Jp′ - 1/ωη) for very lightly crosslinked polypentenamer networks approached equilibrium very slowly compared to 1,4-polybutadiene crosslinked to the same degree, which suggests the participation of very long retardation times of this polymer which is also probably reflected in the comparatively high values of C2 of the Mooney-Rivlin equation.
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    Journal of Polymer Science: Polymer Physics Edition 13 (1975), S. 2331-2343 
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    Keywords: Physics ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Physics
    Notes: The dynamic mechanical properties of a number of ultra-highly drawn polyethylenes have been studied over a wide range of temperature. It is shown that the materials possess low temperature Young's moduli as high as 1.6 Mbar, a figure which approaches the theoretical and experimental values for the c-axis crystalline modulus of this polymer.The α and γ relaxation processes are still clearly discernible even at highest drawn ratios (ca. 35) and a quantitative analysis of the results, using structural data obtained from broad line nuclear magnetic resonance (NMR) measurements, suggests that the data are consistent with a modified series model.
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    Journal of Polymer Science: Polymer Physics Edition 13 (1975), S. 2385-2390 
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    Keywords: Physics ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Physics
    Notes: In the initial stage of the development of transcrystallinity, nuclei appear sporadically on the substrate. The growth rate and melting temperature of the transcrystalline region are found to be the same as those of spherulites nucleated in the bulk of the polymer. Nucleation densities ns at the interface, and nb in bulk, for the crystallization of isotactic polypropylene, poly(ethylene oxide), and poly(butene-1) in contact with various substrates, have been measured by counting the number of spherulites generated. Despite variations in the results from various causes, the quantities ns and ns/nb are useful parameters for characterizing the nucleating ability of various substrates.
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    Journal of Polymer Science: Polymer Physics Edition 13 (1975), S. 2391-2400 
    ISSN: 0098-1273
    Keywords: Physics ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Physics
    Notes: In the melt crystallization of isotactic polypropylene, poly(ethylene oxide) and poly(butene-1) in contact with substrates, the existence of a fixed number of nucleating sites on the substrate surfaces has been established. When these sites become active successively (the transient in the number of nuclei is long) during crystallization, pseudohomogeneous nucleation on the substrate occurs. Nucleation rates for poly(butene-1) and poly(ethylene oxide) on substrates and in bulk have been measured. These data can be used for comparing the nucleating ability of substrates. Estimates of the variation of bulk nucleation rates from one volume element to another as well as for repeated crystallization within a given volume element have been included. Finally, the temperature coefficients of heterogeneous nucleation rates have been combined with the temperature coefficient of spherulitic growth rate of poly(butene-1), to yield values of the interfacial energy parameters appearing in the theory of heterogeneous nucleation. The quantitative characterization of the nucleating ability of substrates by this method is an improvement over the mere use of nucleation densities or nucleation rates.
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  • 63
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    Journal of Polymer Science: Polymer Physics Edition 14 (1976), S. 11-27 
    ISSN: 0098-1273
    Keywords: Physics ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Physics
    Notes: Fluorescence anisotropy decay experiments are described for polystyrene in various ethylacetate-tripropionin mixtures. Decay curve trends agree with the proposed theoretical autocorrelation function. Study of the effects of viscosity shows that the mean relaxation time varies according to a nonlinear law for low viscosities and that the relaxation time θ, reflecting the effects of the possible departures from the motions permitted by an ideal tetrahedral lattice, obeys a law of the type: θ = α + bη. Furthermore, the effects of the direction of the fluorophore transition moment are examined.
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  • 64
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    Journal of Polymer Science: Polymer Physics Edition 14 (1976), S. 1-10 
    ISSN: 0098-1273
    Keywords: Physics ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Physics
    Notes: The scattering law S(k,w) for dilute polymer solutions is obtained from Kirkwood's diffusion equation via the projection operator technique. The width Ω(k) of S(k,w) is obtained for all k without replacing the Oseen tensor by its average (as is done in the Rouse-Zimm model) using the “spring-bead” model ignoring memory effects. For small (ka\documentclass{article}\pagestyle{empty}\begin{document}$ \sqrt N $ \end{document} ≪ 1) and large (ka ≫ 1) values of k we find Ω = 0.195 k2/β α η0 \documentclass{article}\pagestyle{empty}\begin{document}$ \sqrt N $ \end{document} and Ω = k2/βξ, respectively, indicating that the width is governed mainly by the viscosity η0 for small k values and by the friction coefficient ξ for large k values. For intermediate k values which are of importance in neutron scattering we find that in the Rouse limit Ω = k4a2/12βξ. When the hydrodynamic effects are included, Ω(k) becomes 0.055 k3/βη0. Using the Rouse-Zimm model, it is seen that the effect of pre-averaging the Oseen tensor is to underestimate the half-width Ω(k). The implications of the theoretical predictions for scattering experiments are discussed.
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  • 65
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    Journal of Polymer Science: Polymer Physics Edition 14 (1976), S. 437-449 
    ISSN: 0098-1273
    Keywords: Physics ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Physics
    Notes: The luminescence of 1,2-polybutadiene was measured during and following irradiation with 1.4-MeV electrons at 90 °K. Measured under isothermal conditions, the light intensity at first increases sharply on start-up of irradiation, and then reaches a plateau after several seconds. The equilibrium value was found to be linearly dependent on the dose rate employed. The postirradiation luminescence decay measured at 90°K follows second-order kinetics.The light emitted by the irradiated sample during warm-up to room temperature is characterized by the appearance of four intensity maxima at 118, 168, 223, and 261 °K. The first three peaks are attributable to the onset of local motion, whereas the peak at 223 °K is caused by the long-range motion occurring at the glass-to-rubber transition. A preirradiation of the polymer in vacuo causes an increase in these four peaks as well as the formation of a new maximum at 143 °K.Intermittent exposure of the irradiated sample to light of wavelengths λ 〉 450 nm causes the isothermal luminescence decay to be interrupted by a burst of light emitted by the sample during and shortly following the light exposure. This treatment also results in considerably reduced intensity maxima during warm-up to room temperature. An interpretation of the findings reported is given on the basis of reactions involving primary and secondary transient species produced during irradiation and on the molecular parameters of the polybutadiene.
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  • 66
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    Journal of Polymer Science: Polymer Physics Edition 14 (1976), S. 401-414 
    ISSN: 0098-1273
    Keywords: Physics ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Physics
    Notes: The dynamic piezoelectric stress constant e*25 of drawn films of poly(γ-methyl D-glutamate) (PMDG) cast from solutions in α-helix-promoting solvents 1,2-dichloroethane (DCE) and chloroform and from the nonhelicogenic solvent dichloroacetic acid (DCA) was measured from -180°C to 200°C at 110 Hz. The drawn and annealed films cast from chloroform show a small peak for the real part of piezoelectric stress constant -e′25 in the temperature range of the mechanical α2-crystalline relaxation, which is caused by the distortion motion of the backbone chain of the α-helix. On the other hand, drawn films cast from DCE show the peak of the real part of the piezoelectric stress constant, whose magnitude decreases in the range of the mechanical α1-crystalline relaxation or the β-relaxation processes, which were previously ascribed, respectively, to mutual slipping of α-helices and to the micro-Brownian motion of disordered regions. Also, -e′25 becomes virtually zero near 180°C where the α2-relaxation is located. These results suggest that the polarization change induced by applied strain is caused by distortion of the backbone chains in the α-helix. Near 0°C, the temperature range of the side-chain mechanical relaxation, -e′25 exhibits a marked peak both for films cast from chloroform and from DCE. The maximum value of -e′25 and the orientation function of the α-helix axis are linearly related and extrapolation of -e′25,max to unit orientation function gives 1.3 × 104 cgs esu which corresponds to 2.4 Debye per residue. This value corresponds reasonably to the value of 3.71 Debye for the permanent dipole moment of NHCO bond if the correction for crystallinity is made. This result also indicates the piezoelectric properties of PMDG arise from distortion of the backbone chain of the α-helix induced by applied strain.
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  • 67
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    Journal of Polymer Science: Polymer Physics Edition 14 (1976), S. 955-957 
    ISSN: 0098-1273
    Keywords: Physics ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Physics
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  • 68
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    Journal of Polymer Science: Polymer Physics Edition 14 (1976), S. 941-954 
    ISSN: 0098-1273
    Keywords: Physics ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Physics
    Notes: A mathematical model developed in an earlier paper describes the experimental x-ray profiles of equatorial nylon-6 reflections in terms of Pearson VII functions. The present paper deals with the physical aspects and interpretations of the interrelations of the parameters obtained and the relation between these parameters and the results of other types of measurements. It was found that the growth of the crystallites perpendicular to the chain axis is not isotropic, the strongest growth being in the direction of the hydrogen bonds. Growth and perfection of the crystallites are found to be highly correlated. Large crystals are related to short distances between the planes containing the hydrogen bonds and so to densely packed, i.e., perfect unit cells. This correlation forms the basis for the observed similarity between our quantification technique and the method of the crystal perfection index introduced by Statton. Curve resolution, however, makes the method better applicable for poorly crystallized samples. Comparison of the results with those of small-angle x-ray scattering gave a high degree of consistency with respect to the determined crystal size. In the literature mention is made of a relation between the dimensions and the melting point of the crystals; this relation is confirmed by comparing the appropriate x-ray parameters with DTA results of methoxymethylated nylon 6-yarns.Information about the γ-phase can be obtained from equatorial and meridional reflections. The expected relationship between the relevant peak areas was established. This reported evidence shows the physical validity of the parameters obtained using the Pearson VII model for the analytical description of x-ray reflections of nylon-6 yarns.
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    Journal of Polymer Science: Polymer Physics Edition 14 (1976), S. 1201-1209 
    ISSN: 0098-1273
    Keywords: Physics ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Physics
    Notes: The glass-transition temperatures of a series of copolymers of ethyl acrylate and acrylic acid neutralized with various cations were investigated. It was found that a plot of Tg as a function of ion content, for every type of ion investigated here, gives an unusual sigmoidal curve, which can be correlated with the onset of the failure of time-temperature superposition in viscoelastic studies, as will be shown in a future publication. Also, all of the Tg versus concentration curves for the various counterions can be superposed if the plots are made against cq/a, where c is the metal acrylate content, q the cation charge, and a the distance between centers of charge. Furthermore, in one region of water content, a linear relation is obtained between the glass transition and the water content (in weight-%) independent of the ion concentration over wide ranges of ion content. Finally, above an ion concentration of 12 mole-%, the rate of change in Tg per water molecule per ion pair at constant ion content, (∂Tg/∂n)c is linear but with different slopes above and below two water molecules per ion pair.
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  • 70
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    Journal of Polymer Science: Polymer Physics Edition 14 (1976), S. 1087-1095 
    ISSN: 0098-1273
    Keywords: Physics ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Physics
    Notes: The changes which take place on annealing rigid PVC in the vicinity of the glass transition have been followed by differential scanning calorimetry. The changes appear as an increase in the glass-transition temperature and a decrease in the enthalpy with time of annealing. For annealing at 75°C, the enthalpy after 50-100 hr approaches the value characteristic of the equilibrium liquid state. The results obtained for annealing at 65°C and 75°C are in accord with those expected for the relaxation of an amorphous material, and are at variance with those expected on the basis of crystallization taking place on annealing. The enthalpy relaxation process is characterized by a distribution of activation energies centered about 18.8 kcal mole-1, and seems to reflect a multiplicity of molecular processes.
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  • 71
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    Journal of Polymer Science: Polymer Physics Edition 14 (1976), S. 1149-1156 
    ISSN: 0098-1273
    Keywords: Physics ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Physics
    Notes: The melt rheological behavior of an anionically polymerized styrene-butadiene-styrene (SBS) block copolymer sample (S: 7 × 103 and B: 43 × 103) was studied using a Weissenberg rheogoniometer. Highly non-Newtonian behavior, high viscosity and high elasticity, which are characteristics of ABA type block copolymers, were observed at 125°C, 140°C, and 150°C. The data at these temperatures superimposed well onto a master curve giving a constant flow activation energy. However, the data at 175°C indicated a marked change in the flow mechanism between 150°C and 175°C. At 175°C, the sample showed Newtonian behavior, negligible elasticity, and deviation from the master curve. These findings may be considered as an indication that the SBS block copolymer sample undergoes a structural change from a multiphase structure at low temperatures into a homogeneous structure at some temperature between 150°C and 175°C.
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    Journal of Polymer Science: Polymer Physics Edition 14 (1976), S. 1161-1167 
    ISSN: 0098-1273
    Keywords: Physics ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Physics
    Notes: A new crystalline form of isotactic poly(pentene-1) was obtained from dilute solution in amyl acetate. We have designated it as form III. The morphology and structure of isothermally crystallized samples were investigated by electron microscopy and electron and x-ray diffraction. This crystalline modification can be indexed on an orthorhombic unit cell (cell dimensions: a = 21.20 ± 0.05 Å, b = 11.48 ± 0.05 Å, c = 14.39 ± 0.05 Å (fiber axis) and probable space group P212121).
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    Journal of Polymer Science: Polymer Physics Edition 14 (1976), S. 1187-1199 
    ISSN: 0098-1273
    Keywords: Physics ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Physics
    Notes: Glass-transition temperatures and phase separation have been studied in amorphous bisphenol-A polycarbonate plasticized with pentaerythritol tetranonanoate (PETN), trimellitic acid, tridecyloctyl ester (TMDO), and tritolyl phosphate. (TTP). Phase separations occur with partially compatible plasticizers like PETN or TMDO. With PETN, for compositions situated in the miscibility gap, the system is composed of a pure plasticizer phase and of a plasticized polymeric phase characterized by a transition temperature of 110°C. In the case of TMDO and additional phase separation occurs below 55°C and two plasticized polycarbonate phases are observed. In compositions falling in the region where the could point curve crosses the glass-transition diagram the phase separation may be delayed by quick cooling. TTP is completely compatible with polycarbonate and the variation of the glass-transition temperature follows a Gordon and Taylor equation.
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  • 74
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    Journal of Polymer Science: Polymer Physics Edition 14 (1976), S. 1235-1240 
    ISSN: 0098-1273
    Keywords: Physics ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Physics
    Notes: An x-ray back-reflection rotating camera has been used to measure the lattice constant, thermal expansion, and compressibility in the polymer chain direction of a polydiacetylene, poly[bis(p-toluene sulfonate) of 2,4-hexadiyne 1,6-diol]. The thermal expansion coefficient of the polymer chain is small and positive (0.9 ± 0.2 × 10-6 °K-) at 300°K, but negative below about 70°K. Application of 3.43 kbar hydrostatic pressure at 299°K changed the unit cell dimension in the polymer chain direction by less than 10 ppm.
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    Journal of Polymer Science: Polymer Physics Edition 14 (1976), S. 1425-1431 
    ISSN: 0098-1273
    Keywords: Physics ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Physics
    Notes: Persistence vectors a ≡ 〈r〉 are calculated for polypropylene, polystyrene, and poly(methyl methacrylate) chains as functions of chain length and stereochemical constitution. Differences between the progressions of a with chain length for these vinyl polymers are related to their conformational characteristics. The preferences of the syndiotactic chains for the tt dyad conformation are manifested most strikingly in the behavior of this vector.
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  • 76
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    Topics: Chemistry and Pharmacology , Physics
    Notes: Solvent-cast films of blends of poly(∊-caprolactone) (PCL) with poly(vinyl chloride) (PVC) were examined by low-angle x-ray scattering and by small-angle light scattering. X-ray scattering from crystalline compositions were analyzed using the Tsvankin-Buchanan technique and led to values of the repeat period of the lamellar structure and the thickness of the crystalline and amorphous layers. With increasing content of PVC, the amorphous layer thickness increased sufficiently to accommodate the PVC, leading to values of the linear crystallinity consistent with macroscopic measurements by density and DSC techniques up to about 50% PVC by weight. Above this concentration, the lamellar structure no longer appeared to be volume filling. At high concentration of PCL, the polymer consisted of volume-filling spherulites containing the lamellar substructure. Spherulite sizes were measured by light scattering and absolute light scattering intensities were consistent with calculations based upon the degree of crystallinity and anisotropy of the spherulites. Compositions containing more than 60% PVC were amorphous. Low-angle x-ray scattering was interpreted in terms of the Debye-Bueche theory which leads to values for a correlation distance lc and the mean-square electron density fluctuation 〈η2〉 (which was also obtained from the invariant). By the method of Porod, the correlation distances were resolved into persistence lengths within the two phases, which were determined as a function of composition. The fluctuation 〈η2〉 was analyzed in terms of a two-phase model to show that its value was somewhat larger than would be obtained if the phases were composed of the pure components. It was not possible to uniquely determine their compositions. The data were consistent with the existence of a transition zone of the order of 30 Å thick between phases.
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  • 77
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    Journal of Polymer Science: Polymer Physics Edition 14 (1976), S. 1485-1493 
    ISSN: 0098-1273
    Keywords: Physics ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Physics
    Notes: The universal calibration for gel permeation chromatography (GPC) has been applied to amylose and dextrans. The molecular weight distribution of amylose has been measured starting from known data on dextrans. The agreement found between the molecular weight averages resulting from GPC and those obtained by other methods justifies the procedure followed. The GPC measurements were performed with dimethylsulfoxide as the elution solvent and deactivated silica gel (Porasil) as the column-filling material.
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    Journal of Polymer Science: Polymer Physics Edition 14 (1976), S. 1495-1512 
    ISSN: 0098-1273
    Keywords: Physics ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Physics
    Notes: Unoriented T-die flat films of nylon 6 and PET films annealed at 90°C were stretched in water at 80°C. Amorphous PET films were stretched in water at 65-75°C. Changes in the light scattering patterns from these samples upon stretching were investigated. One of the observed LS patterns from the stretched samples is the Hv eight-leaf pattern consisting of four lobes and streaks. In the nylon 6 and heat-treated PET showing this pattern, spherulitic patterns can be seen in polarization microscopy. The microscopic spherulitic superstructure may possibly be the factor responsible for producing the lobe-and-streak pattern. On the other hand, many microscopic eight-leaf patterns can be observed in amorphous unannealed PET showing the lobe-and-streak pattern. These microscopic patterns are due to retardation at stress concentrations around impurities and nuclei. The superstructure giving these microscopic patterns must be the origin of the lobe-and-streak pattern from unannealed PET. Another scattering pattern, the Vv cruciform pattern, was observed in both stretched nylon 6 and unannealed PET. This pattern is due to an orientation change across the slip lines observed under a polarizing microscope. It is noted (1) that the appearance of the slip lines in PET coincides with the occurrence of oriented crystallization on stretching, (2) that the lobe-and-streak pattern from PET in which orientation crystallization has taken place is fairly stable to heat treatment and does not disappear until just before melting, and (3) that the superstructures produced at low stretching seem to be deformed on further stretching, in accordance with affine deformation theory.
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    Journal of Polymer Science: Polymer Physics Edition 14 (1976), S. 1567-1573 
    ISSN: 0098-1273
    Keywords: Physics ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Physics
    Notes: An Interesting kinetic effect in the environmental stress cracking (E.S.C.) of polyethylene has been observed, in which the liquid viscosity plays an important role. E.S.C. of a low density, high melt index polyethylene due to silicone oils has been studied using constant load creep experiments. For relatively low stresses, it has been found that the time to fracture is independent of the viscosity of the silicone oil, all other factors being approximately equal. However, at high stresses, the time to fracture increases with increasing viscosity for a given stress. This effect has been shown to be due to the relative ease with which the liquid penetrates a growing crack and thus always be at the crack front. Times to fracture for viscous liquids at high stresses are longer since crack propagation continues partially with and partially without liquid contact, fracture rate being much slower when not in the presence of the liquid.
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    Journal of Polymer Science: Polymer Physics Edition 14 (1976), S. 1591-1599 
    ISSN: 0098-1273
    Keywords: Physics ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Physics
    Notes: The dielectric β-relaxation in oriented poly(ethylene terephthalate) was investigated over wide ranges of frequency and temperature, with the electric field applied at inclinations of 0°, 45°, and 90° to the draw direction. Pronounced directional anisotropy is observed over the entire range of temperature and frequency. With the external field parallel to the draw direction the dielectric loss is considerably smaller than the value obtained with the field normal to the draw direction. The value obtained with the electric field at 45° to the draw direction is intermediate between the other two. On the other hand, the activation energy is largest for 0° inclination and smallest for 90° inclination. It is suggested that motions of the dipoles involve localized rocking of the molecular chain backbone, particularly when the external electric field is parallel to the chain direction.
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    Journal of Polymer Science: Polymer Physics Edition 14 (1976), S. 1659-1669 
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    Keywords: Physics ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Physics
    Notes: Dynamic mechanical properties of cold-compacted films of polyethylene prepared by γ-ray-induced polymerization in bulk at 30°C are discussed in connection with the fine structure. The cold-compacted films show a broad α-relaxation at a lower temperature than do single-crystal mats or melt-crystallized polymer. From the effects of annealing and swelling by carbon tetrachloride on the relaxation, it is concluded that the α-relaxation, like the α-relaxation in the single-crystal mats, originates from molecular motions within lamellar crystals. This is consistent with the finding that these films are composed of stacked small irregular lamellar crystals. The γ-relaxation is also similar to that in crystal mats.
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    Journal of Polymer Science: Polymer Physics Edition 14 (1976), S. 1641-1658 
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    Keywords: Physics ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Physics
    Notes: The drawing behavior of a series of linear polyethylene homopolymers with weight-average molecular weight (M̄w) ranging from 67,800 to ∼3,500,000 and variable distribution (M̄w/M̄n = 5.1-20.9) has been studied. Sheets were prepared by two distinct routes: either by quenching the molten polymer into cold water or by slow cooling below the crystallization temperature (∼120°C) followed by quenching into cold water.When the samples (2 cm long) were drawn in air at 75°C using a crosshead speed of 10 cm/min it was found that for low M̄w polymers the initial thermal treatment has a dramatic effect on the rate at which the local deformation proceeds in the necked region. At high M̄w such effects are negligible. An important result was that comparatively high draw ratios (λ 〉 17) and correspondingly high Young's moduli could be obtained for a polymer with M̄w as high as 312,000. It is shown how some of the structural features of the initial materials (mainly studied by optical microscopy, small-angle x-ray scattering and low-frequency laser Raman spectroscopy) can be interpreted in terms of the molecular weight and molecular weight distribution of the polymers. Although crystallization and morphology can be important at low M̄w, it suggested that the concept of a molecular network which embraces both crystalline and noncrystalline material is more helpful in understanding the drawing behavior over the whole range of molecular weights.
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    Journal of Polymer Science: Polymer Physics Edition 14 (1976), S. 1693-1700 
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    Keywords: Physics ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Physics
    Notes: Spin-lattice relaxation times (T1) for methyl, methylene, and methine carbons in an amorphous polypropylene have been measured as a function of temperature from 46 to 138°C. The carbons from isotactic sequences characteristically exhibited the longest T1's of those observed. The T1 differences increased with temperature with the largest difference occuring for methine carbons where a 32% difference was observed. Activation energies were determined for the motional processes affecting T1's for isotactic and syndiotactic sequences with essentially no dependence upon configuration noted.
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    Journal of Polymer Science: Polymer Physics Edition 14 (1976), S. 1903-1907 
    ISSN: 0098-1273
    Keywords: Physics ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Physics
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    Journal of Polymer Science: Polymer Physics Edition 14 (1976), S. 1913-1916 
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    Keywords: Physics ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Physics
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    Journal of Polymer Science: Polymer Physics Edition 14 (1976), S. 1921-1929 
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    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Physics
    Notes: In evaluating molecular orientation by dynamic infrared techniques, it is shown, subject to certain restrictions, that an extensional mechanism plays an important role in the measured orientation. Dichroic measurements can indicate a change in segmental orientation without any change occurring in the chain axis orientation. Extensional orientation was evaluated for a general helical molecule in terms of singular and coupled vibrational modes. Significant orientation changes can occur by the extensional mechanism, the sign and magnitude of which depend on the components of the transition moment vector.
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    Journal of Polymer Science: Polymer Physics Edition 14 (1976), S. 1801-1812 
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    Keywords: Physics ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Physics
    Notes: A method is proposed for calculating the activation energy over the entire temperature range from relaxation measurements at two frequencies as a function of temperature by taking into account the entire experimental curve. The method is independent of the distribution of relaxation times, but assumes the validity of the time-temperature superposition principle.
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  • 88
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    Journal of Polymer Science: Polymer Physics Edition 14 (1976), S. 1871-1875 
    ISSN: 0098-1273
    Keywords: Physics ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Physics
    Notes: The γ and δ relaxations of polystyrene (PS) are rendered more active dielectrically by sorbed oxygen. This effect, coupled with comparative work on molecularly similar systems has led to the assignment of the γ relaxation to a rotational libration of the phenyl ring in PS. Specific interactions of the pendant phenyl ring with molecular oxygen to induce off-axis dipole moments in the phenyl moiety is proposed. It is concluded that this interaction is strong enough to influence the dielectric relaxation strength of other relaxations in PS. It is further concluded that because of the interactions occuring in aromatic polymers containing sorbed oxygen, care must be taken to exclude oxygen or to vary its content, in order that intrinsic motions in the polymer system can be studied.
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  • 89
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    Journal of Polymer Science: Polymer Physics Edition 14 (1976), S. 1909-1912 
    ISSN: 0098-1273
    Keywords: Physics ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Physics
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  • 90
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    Journal of Polymer Science: Polymer Physics Edition 14 (1976), S. 1917-1919 
    ISSN: 0098-1273
    Keywords: Physics ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Physics
    Additional Material: 2 Ill.
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  • 91
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    Journal of Polymer Science: Polymer Physics Edition 14 (1976), S. 2105-2108 
    ISSN: 0098-1273
    Keywords: Physics ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Physics
    Additional Material: 2 Ill.
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  • 92
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    Journal of Polymer Science: Polymer Physics Edition 14 (1976), S. 2109-2112 
    ISSN: 0098-1273
    Keywords: Physics ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Physics
    Additional Material: 4 Ill.
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  • 93
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    Journal of Polymer Science: Polymer Physics Edition 14 (1976), S. 2119-2128 
    ISSN: 0098-1273
    Keywords: Physics ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Physics
    Notes: Polystyrene networks prepared by anionic polymerization have been characterized by small-angle neutron scattering. Two kinds of systems have been examined:(A) networks with labelled branch points allowing characterization of the spatial distribution of crosslinking points; (B) networks containing a low proportion of chains labelled with perdeuterated polystyrene in order to characterize the conformation of individual elastic chains of the polymeric network. The dependence of the results on swelling and uniaxial extension is discussed.
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  • 94
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    Journal of Polymer Science: Polymer Physics Edition 14 (1976), S. 2129-2136 
    ISSN: 0098-1273
    Keywords: Physics ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Physics
    Notes: Relaxation of birefringence and stress in simple extension has been studied for polyisobutylene at -26.0°C and 25.0°C for extension ratios ranging from about 1.2 to 2.0. The dependence of both the stress and birefringence on the extension ratio, for a given time, is well described by equations of the Mooney-Rivlin form. The Mooney-Rivlin treatment of the birefringence experiments was found to reinforce but not add to information available from the stress-relaxation experiments alone. At 25.0°C, the stress-optical coefficient is found to be stress dependent. Possible explanations of this behavior are discussed. An experiment is also reported in which the birefringence is observed under zero stress immediately after cutting a strained sample. The zero stress birefringence is believed to be due to regions of stress-induced crystallization taking a finite time to melt after the stress is removed.
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  • 95
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    Journal of Polymer Science: Polymer Physics Edition 14 (1976), S. 2195-2209 
    ISSN: 0098-1273
    Keywords: Physics ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Physics
    Notes: The lateral swelling, changes in length and tensile stress-strain curve of reconstituted collagen hollow fibers, crosslinked with uv irradiation, were measured as a function of the pH and ionic strength of their aqueous environment. From pH 5 to pH 10 the lateral swelling and length are constant; at lower and higher pH the lateral swelling increases rapidly while the fiber shrinks in length. Corresponding to these changes, a pronounced toe develops in the stress-strain curve and extends to a higher strain in more acid (or basic) media. This toe is attributed to the straightening of a microcrimp in the collagen fibrils; the microcrimp is accentuated by the repulsion between the charged fibrils in acid or basic media. Direct small-angle x-ray evidence of these microcrimp structure changes at low pH is presented. Increasing the ionic strength of an acid solution by adding NaCl decreases the lateral swelling, increases the length, and decreases the extent of the toe on the stress-strain curve. These changes result from an increased screening of the charge on neighboring fibrils at higher ionic strengths thus decreasing the repulsion between fibrils and the resulting microcrimp. Although the zigzag elastica model of the crimp developed by Diamant et al. [Proc. Roy. Soc., Ser. B, 180, 293 (1972)] provides a good empirical fit to the stress-strain data, it is shown to be inappropriate where the crimp results from repulsive forces between fibrils. A new model taking these forces into account is developed and is shown to be in reasonable agreement with the experimental results.
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  • 96
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    Journal of Polymer Science: Polymer Physics Edition 14 (1976), S. 2231-2240 
    ISSN: 0098-1273
    Keywords: Physics ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Physics
    Notes: The mean-square dipole moments of poly(ethylene oxide) and poly(hexamethylene oxide) chains have been determined from dielectric constant measurements on dilute solutions of the polymers in benzene. The values obtained are in good agreement with those predccted using the rotational isomeric state models for these chains. In addition, the unperturbed dimensions of poly(hexamethylene oxide) have been calculated as a function of molecular weight, using the isomeric state theory.
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  • 97
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    Journal of Polymer Science: Polymer Physics Edition 14 (1976), S. 2253-2257 
    ISSN: 0098-1273
    Keywords: Physics ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Physics
    Notes: The kinetics of phase transformation are treated for heterogeneous nucleation, where all nuclei are simultaneously initiated, and where initiation follows first-order kinetcs. The phase transformation curves are sigmoid. For simultaneous initiation in two dimensions, a(t)/(1 - a(t)) ∝ t2. For first-order initiation, we have, approximately, a(t)/(1 - a(t)) ∝ t2.85, and v(t)/(1 - v(t)) ∝ t3.74.
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  • 98
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    Journal of Polymer Science: Polymer Physics Edition 14 (1976), S. 2241-2251 
    ISSN: 0098-1273
    Keywords: Physics ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Physics
    Notes: Cloud-point curves have been determined for aqueous solutions of poly(ethylene oxide) (PEO) at several concentrations for a variety of inorganic salts (sulfates, carbonates, nitrates, and chlorides). From these, theta conditions have been determined. The resulting dependences of the critical temperature θ (mostly between 300 and 360°K) on the molar concentrations (or ionic strengths) of the salts in solution cannot wholly be summarized in sequences of ion effects. The major findings are that sulfates and carbonates are much more effective in reducing θ than the chlorides and nitrates at the same concentrations. The trends found depend on salt concentration, i.e., certain plots of the data cross over, but they broadly agree with those found for comparable systems by other workers. Exceptional are the chlorides of Group II and LiCl which show minima when θ is plotted against molar salt concentration. While interpretations based on solvent structure-breaking are not adequate, there are similarities in behavior with the structure-breaking attributes of the ions based on independent studies (infrared). The results are briefly discussed in terms of current postulates: a more detailed discussion will accompany further experimental studies on these systems.
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  • 99
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    Journal of Polymer Science: Polymer Physics Edition 14 (1976), S. 2273-2284 
    ISSN: 0098-1273
    Keywords: Physics ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Physics
    Notes: Six 6,10-ionenes with different counterions were prepared by ion exchange reactions in aqueous solutions. The counterions were Br, I, CIO4, BF4, SCN, and B(C6H5)4. The dynamic mechanical properties of these polymers were investigated by use of a torsional braid analyser. Three relaxations α (25-140°C), β (-30-0°C), and γ (-140-120°C) were observed at the frequencies of 0.3-0.8 Hz. The temperature of the α and β relaxations were largely dependent on the size of counterions, but those of the γ relaxations had little variation. The effects of electrostatic forces in the polymers on each relaxation was discussed. The influence of absorbed water on the α, β, and γ relaxations was examined. The absorbed water in the polymers greatly depressed the temperature of the α relaxations and this phenomenon was interpreted to be the result of the specific hydration on ionic portions.
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  • 100
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    Journal of Polymer Science: Polymer Physics Edition 14 (1976), S. 2291-2311 
    ISSN: 0098-1273
    Keywords: Physics ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Physics
    Notes: Small-angle and wide-angle x-ray scattering measurements, using a position-sensitive detector, were made during melt-crystallization of linear polyethylenes and PEO-PS-PEO triblock copolymer. The scattering measurements indicated that the triblock copolymer grew by the enlargement of regions in which lamellae are regularly stacked. During primary crystallization at higher temperatures similar behavior is observed in two linear polyethylenes. At lower temperatures, changes in the shape of small-angle scattering curves during the primary stage of crystallization indicate that amorphous gaps within the lamellar stacking become filled in. During secondary crystallization at higher temperatures new crystallites appear to grow between those formed in the primary stage. Concurrent decrease of the overall scattered intensity leads to the conclusion that secondary crystallization has two components: crystallization of new lamellae behind the spherulite growth front and the thickening of existing lamellae.
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