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  • 05. General::05.09. Miscellaneous::05.09.99. General or miscellaneous
  • American Chemical Society  (1)
  • Elsevier  (1)
  • Annual Reviews
  • Blackwell Publishing Ltd
  • 2005-2009  (2)
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  • 1
    Publication Date: 2017-04-04
    Description: Red Pompeian paintings, very famous for their deep intensity, are currently suffering from darkening. The origins of this darkening degradation are not clearly identified yet and remain a major issue for curators. In the specific case of cinnabar (HgS)-based red pigment, a photoinduced conversion into black metacinnabar is usually suspected. This work is focused on the blackening of red cinnabar paintings coated on a sparry calcite mortar. Different samples exhibiting different levels of degradation were selected upon visual observations and analyzed by synchrotron-based microanalytical techniques. Atomic and molecular compositions of the different debased regions revealed two possible degradation mechanisms. On one hand, micro X-ray fluorescence elemental maps show peculiar distributions of chlorine and sulfur. On the other hand, X-ray absorption spectroscopy performed at both Cl and S K-edges confirms the presence of characteristic degradation products: (i) Hg- Cl compounds (e.g., corderoite, calomel, and terlinguaite), which may result from the reaction with exogenous NaCl, in gray areas; (ii) gypsum, produced by the calcite sulfation, in black coatings. Metacinnabar is never detected. Finally, a cross section was analyzed to map the in-depth alteration gradient. Reduced and oxidized sulfur distributions reveal that the sulfated black coating consists of a 5-ím-thick layer covering intact cinnabar.
    Description: Published
    Description: 7484-7492
    Description: reserved
    Keywords: Microspectroscopy Analysis ; 05. General::05.09. Miscellaneous::05.09.99. General or miscellaneous
    Repository Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
    Type: article
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  • 2
    Publication Date: 2017-04-04
    Description: Tephra fallout constitutes a serious threat to communities around active volcanoes. Reliable short-term 13 forecasts represent a valuable aid for scientists and civil authorities to mitigate the effects of fallout on the 14 surrounding areas during an episode of crisis. We present a platform-independent automatic procedure with Q1 15 the aim to daily forecast transport and deposition of volcanic particles. The procedure builds on a series of 16 programs and interfaces that automate the data flow and the execution and subsequent postprocess of fallout 17 models. Firstly, the procedure downloads regional meteorological forecasts for the area and time interval of 18 interest, filters and converts data from its native format, and runs the CALMET diagnostic model to obtain the 19 wind field and other micro-meteorological variables on a finer local-scale 3-D grid defined by the user. 20 Secondly, it assesses the distribution of mass along the eruptive column, commonly by means of the radial 21 averaged buoyant plume equations depending on the prognostic wind field and on the conditions at the vent 22 (granulometry, mass flow rate, etc). All these data serve as input for the fallout models. The initial version of 23 the procedure includes only two Eulerian models, HAZMAP and FALL3D, the latter available as serial and 24 parallel implementations. However, the procedure is designed to incorporate easily other models in a near 25 future with minor modifications on the model source code. The last step is to postprocess the outcomes of 26 models to obtain maps written in standard file formats. These maps contain plots of relevant quantities such 27 as predicted ground load, expected deposit thickness and, for the case of or 3-D models, concentration on air 28 or flight safety concentration thresholds
    Description: Published
    Description: 767-777
    Description: 3.6. Fisica del vulcanismo
    Description: 4.3. TTC - Scenari di pericolosità vulcanica
    Description: JCR Journal
    Description: reserved
    Keywords: Tephra fallout ; volcanoes ; 04. Solid Earth::04.08. Volcanology::04.08.08. Volcanic risk ; 05. General::05.09. Miscellaneous::05.09.99. General or miscellaneous
    Repository Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
    Type: article
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