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  • Mixing  (12)
  • 04. Solid Earth::04.04. Geology::04.04.12. Fluid Geochemistry  (10)
  • American Geophysical Union  (18)
  • Blackwell Publishing Ltd  (4)
  • Annual Reviews
  • Nature Publishing Group
  • 2010-2014  (22)
  • 1980-1984
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  • 1
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    Sudden deep gas eruption nearby Rome's airport of Fiumicino (2014)
    American Geophysical Union
    Details
    Publication Date: 2021-03-24
    Description: On 24 August 2013 a sudden gas eruption from the ground occurred in the Tiber river delta, nearby Rome's international airport of Fiumicino. We assessed that this gas, analogous to other minor vents in the area, is dominantly composed of deep, partially mantle-derived CO2, as in the geothermal gas of the surrounding Roman Comagmatic Province. Increased amounts of thermogenic CH4 are likely sourced from Meso-Cenozoic petroleum systems, overlying the deep magmatic fluids. We hypothesize that the intersection of NE-SW and N-S fault systems, which at regional scale controls the location of the Roman volcanic edifices, favors gas uprising through the impermeable Pliocene and deltaic Holocene covers. Pressurized gas may temporarily be stored below these covers or within shallower sandy, permeable layers. The eruption, regardless the triggering cause—natural or man-made, reveals the potential hazard of gas-charged sediments in the delta, even at distances far from the volcanic edifices.
    Description: Published
    Description: 5632–5636
    Description: 2.2. Laboratorio di paleomagnetismo
    Description: JCR Journal
    Description: restricted
    Keywords: geothermal gas ; deep CO2 ; Tiber river delta ; thermogenic CH4 ; 04. Solid Earth::04.04. Geology::04.04.09. Structural geology ; 04. Solid Earth::04.04. Geology::04.04.12. Fluid Geochemistry
    Repository Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
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  • 2
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    Long term variations of the Campi Flegrei (Italy) volcanic system as revealed by the monitoring of hydrothermal activity (2010)
    American Geophysical Union
    Details
    Publication Date: 2017-04-04
    Description: Long duration time-series of the chemical composition of fumaroles and of soil CO2 flux reveal that important variations in the activity of the Solfatara fumarolic field, the most important hydrothermal site of Campi Flegrei, occurred in the 2000-2008 period. A continuous increase of the CO2 concentrations, and a general decrease of the CH4 concentrations are interpreted as the consequence of the increment of the relative amount of magmatic fluids, rich in CO2 and poor in CH4, hosted by the hydrothermal system. Contemporaneously, the H2O-CO2-He-N2 gas system shows remarkable compositional variations in the samples collected after July 2000 with respect to the previous ones, indicating the progressive arrival at the surface of a magmatic component different from that involved in the 1983-84 episode of volcanic unrest (1983-1984 bradyseism). The change starts in 2000 concurrently with the occurrence of relatively deep, long-period seismic events which were the indicator of the opening of an easy-ascent pathway for the transfer of magmatic fluids towards the shallower, brittle domain hosting the hydrothermal system. Since 2000, this magmatic gas source is active and causes ground deformations, seismicity as well as the expansion of the area affected by soil degassing of deeply derived CO2. Even though the activity will most probably be limited to the expulsion of large amounts of gases and thermal energy, as observed in other volcanoes and in the past activity of Campi Flegrei, the behavior of the system in the future is, at the moment, unpredictable.
    Description: Published
    Description: B03205
    Description: 1.2. TTC - Sorveglianza geochimica delle aree vulcaniche attive
    Description: 2.4. TTC - Laboratori di geochimica dei fluidi
    Description: 4.5. Studi sul degassamento naturale e sui gas petroliferi
    Description: JCR Journal
    Description: reserved
    Keywords: Campi Flegrei ; CO2 ; 03. Hydrosphere::03.04. Chemical and biological::03.04.06. Hydrothermal systems ; 04. Solid Earth::04.04. Geology::04.04.12. Fluid Geochemistry ; 04. Solid Earth::04.08. Volcanology::04.08.01. Gases ; 04. Solid Earth::04.08. Volcanology::04.08.08. Volcanic risk
    Repository Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
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  • 3
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    CO2/CH4 ratio in fumaroles a powerful tool to detect magma degassing episodes at quiescent Volcanoes (2010)
    American Geophysical Union
    Details
    Publication Date: 2017-04-04
    Description: Long time series of fumarolic compositions at Campi Flegrei (Italy), Mammoth Mountain (California), Panarea (Italy) and Nisyros (Greece) show rapid increases, up to orders of magnitude, of the CO2/CH4 ratio systematically with the occurrence of volcanic unrest periods. These easily detected anomalies originate with the arrival of CH4-poor magmatic fluids in the shallower levels of the volcanoes. The data suggest that volcanoes are characterized by magmatic activity at depth also in periods of apparent quiescence. The activity is constituted by the pulsing release of large amount of fluids which either cause unrest periods (seismicity and ground deformation) or possibly could precede volcanic eruption. This type of volcanic activity can be monitored trough the classical geophysical techniques together with the systematic sampling and analysis of fumaroles.
    Description: Published
    Description: L02302
    Description: 1.2. TTC - Sorveglianza geochimica delle aree vulcaniche attive
    Description: 2.4. TTC - Laboratori di geochimica dei fluidi
    Description: 4.5. Studi sul degassamento naturale e sui gas petroliferi
    Description: JCR Journal
    Description: reserved
    Keywords: CO2/CH4 ; magma degassing ; quiescent volcanoes ; 03. Hydrosphere::03.04. Chemical and biological::03.04.05. Gases ; 03. Hydrosphere::03.04. Chemical and biological::03.04.06. Hydrothermal systems ; 04. Solid Earth::04.04. Geology::04.04.12. Fluid Geochemistry
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  • 4
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    Wind as a main driver of the net ecosystem carbon balance of a semiarid Mediterranean steppe in the South East of Spain (2012)
    Blackwell Publishing Ltd
    Details
    Publication Date: 2017-04-04
    Description: Despite the advance in our understanding of the carbon exchange between terrestrial ecosystems and the atmosphere, semiarid ecosystems have been poorly investigated and little is known about their role in the global carbon balance. We used eddy covariance measurements to determine the exchange of CO2 between a semiarid steppe and the atmosphere over 3 years. The vegetation is a perennial grassland of Stipa tenacissima L. located in the SE of Spain. We examined diurnal, seasonal and interannual variations in the net ecosystem carbon balance (NECB) in relation to biophysical variables. Cumulative NECB was a net source of 65.7, 143.6 and 92.1 g C mˉ2 yrˉ1 for the 3 years studied, respectively. We separated the year into two distinctive periods: dry period and growing season. The ecosystem was a net source of CO2 to the atmosphere, particularly during the dry period when large CO2 positive fluxes of up to 15 μmol mˉ2 sˉ1 were observed in concomitance with large wind speeds. Over the growing season, the ecosystem was a slight sink or neutral with maximum rates of -2.3 μmol mˉ2 sˉ1. Rainfall events caused large fluxes of CO2 to the atmosphere and determined the length of the growing season. In this season, photosynthetic photon flux density controlled day-time NECB just below 1000 μmol mˉ2 sˉ1. The analyses of the diurnal and seasonal data and preliminary geological and gas-geochemical evaluations, including C isotopic analyses, suggest that the CO2 released was not only biogenic but most likely included a component of geothermal origin, presumably related to deep fluids occurring in the area. These results highlight the importance of considering geological carbon sources, as well as the need to carefully interpret the results of eddy covariance partitioning techniques when applied in geologically active areas potentially affected by CO2-rich geofluid circulation.
    Description: Published
    Description: 539–554
    Description: 4.5. Studi sul degassamento naturale e sui gas petroliferi
    Description: JCR Journal
    Description: reserved
    Keywords: alpha grass ; carbon sequestration ; ecosystem respiration ; eddy covariance ; geogas ; geothermal activity ; grasslands ; net ecosystem carbon balance ; 04. Solid Earth::04.04. Geology::04.04.12. Fluid Geochemistry
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  • 5
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    Sulfur isotopic compositions of fumarolic and plume gases at Mount Etna (Italy) and inferences on their magmatic source (2012)
    American Geophysical Union
    Details
    Publication Date: 2017-04-03
    Description: Here we report new data on the sulfur isotopic compositions (d34S) of fumarolic and plume gases collected at Mount Etna volcano during 2008–2009. While low-temperature fumaroles are affected by postmagmatic processes that modify the pristine isotopic signature, high-temperature and plume gases allow establishment of a d34S range of 0 1‰ for magmatic SO2. We compared our data with those from S dissolved in primitive melt inclusions from 2002 lava and in whole rocks that erupted during the past two thousand years. Such a comparison revealed that d34S is systematically lower for magmatic gases than for sulfur dissolved in the melt. We modeled how isotopic fractionation due to magma degassing process may vary d34S value in both the melt and gaseous phases. This modeling required assessment of the fractionation factor (agas-melt). The most recent measurements on the oxidation state of sulfur in basaltic melt inclusions indicate that nearly all S is dissolved as sulfate (S6+), which would be possible in oxidized magmatic systems (DNNO ≥ 1). Under these conditions the exsolved gaseous phase is depleted with respect to the melt and the proposed model fits both gas and melt data, and constrains the Etnean magmatic d34S to 1.0 1.5‰. It is remarkable that the assessed redox conditions—which are significantly more oxidizing than previously thought—are able to explain why the dominant sulfur species measured in the Etnean plume is SO2.
    Description: Published
    Description: Q05015
    Description: 1.2. TTC - Sorveglianza geochimica delle aree vulcaniche attive
    Description: JCR Journal
    Description: restricted
    Keywords: Mount Etna ; SO2 ; degassing ; fumarole ; plume ; sulfur isotope ; 04. Solid Earth::04.04. Geology::04.04.12. Fluid Geochemistry
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  • 6
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    Real-time measurements of the concentration and isotope composition of atmospheric and volcanic CO2 at Mount Etna (Italy) (2014)
    American Geophysical Union
    Details
    Publication Date: 2020-02-24
    Description: We present unprecedented data of real-time measurements of the concentration and isotope composition of CO2 in air and in fumarole-plume gases collected in 2013 during two campaigns at Mount Etna volcano, which were made using a laser-based isotope ratio infrared spectrometer. We performed approximately 360 measurements/h, which allowed calculation of the δ13C values of volcanic CO2. The fumarole gases of Torre del Filosofo (2900mabove sea level) range from 3.24 ± 0.06‰to 3.71 ± 0.09‰, comparable to isotope ratio mass spectrometry (IRMS) measurements of discrete samples collected on the same dates. Plume gases sampled more than 1 km from the craters show a δ13C= 2.2 ± 0.4‰, in agreement with the crater fumarole gases analyzed by IRMS. Measurements performed along ~17km driving track from Catania to Mount Etna show more negative δ13C values when passing through populated centers due to anthropogenic-derived CO2 inputs (e.g., car exhaust). The reported results demonstrate that this technique may represent an important advancement for volcanic and environmental monitoring.
    Description: Published
    Description: 2382–2389
    Description: 2V. Dinamiche di unrest e scenari pre-eruttivi
    Description: JCR Journal
    Description: restricted
    Keywords: Real-time data of CO2 content and δ13C in atmospheric/volcanic gases ; This study opens new perspective for the community for volcanic surveillance ; 04. Solid Earth::04.04. Geology::04.04.12. Fluid Geochemistry ; 04. Solid Earth::04.08. Volcanology::04.08.01. Gases ; 04. Solid Earth::04.08. Volcanology::04.08.06. Volcano monitoring ; 04. Solid Earth::04.08. Volcanology::04.08.07. Instruments and techniques ; 05. General::05.02. Data dissemination::05.02.01. Geochemical data
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  • 7
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    Diffuse hydrothermal methane output and evidence of methanotrophic activity within the soils at Sousaki (Greece) (2011)
    Blackwell Publishing Ltd
    Details
    Publication Date: 2017-04-04
    Description: Methane soil flux measurements have been made in 38 sites at the geothermal system of Sousaki (Greece) with the closed chamber method. Fluxes range from –47.6 to 29,150 mg m-2 d-1 and the diffuse CH4 output of the system has been estimated at 19 t a-1. Contemporaneous CO2 flux measurements showed a moderate positive correlation between CO2 and CH4 fluxes. Comparison of the CO2/CH4 soil flux ratios with the CO2/CH4 ratio of the gases of the main gas manifestations provided evidence for methanotrophic activity within the soil. Laboratory CH4 consumption experiments confirmed the presence of methanotrophic microorganisms in soil samples collected at Sousaki. Consumption was generally in the range from –4.9 to –38.9 pmolCH4 h-1 g-1 but could sometimes reach extremely high values (–33,000 pmolCH4 h-1 g-1.). These results are consistent with recent studies on other geothermal systems that revealed the existence of thermoacidophilic bacteria exerting methanotrophic activity in hot, acid soils, thereby reducing methane emissions to the atmosphere.
    Description: Published
    Description: 97–107
    Description: 4.5. Studi sul degassamento naturale e sui gas petroliferi
    Description: JCR Journal
    Description: reserved
    Keywords: Sousaki ; accumulation chamber ; soil degassing ; hydrothermal systems ; methane output ; methanotrophic activity ; 01. Atmosphere::01.01. Atmosphere::01.01.07. Volcanic effects ; 04. Solid Earth::04.04. Geology::04.04.12. Fluid Geochemistry ; 04. Solid Earth::04.08. Volcanology::04.08.01. Gases
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  • 8
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    Geochemical insight into differences in the physical structures and dynamics of two adjacent maar lakes at Mt. Vulture volcano (southern Italy) (2013)
    American Geophysical Union
    Details
    Publication Date: 2017-04-04
    Description: We report on the first geochemical investigation of the Monticchio maar lakes (Mt. Vulture volcano, southern Italy) covering an annual cycle that aimed at understanding the characteristic features of the physical structures and dynamics of the two lakes. We provide the first detailed description of the lakes based on high-resolution CTD profiles, chemical and isotopic (H and O) compositions of the water, and the amounts of dissolved gases (e.g., He, Ar, CH4 and CO2). The combined data set reveals that the two lakes, which are separated by less than 200 m, exhibit different dynamics: one is a meromictic lake, where the waters are rich in biogenic and mantle-derived gases, while the other is a monomictic lake, which exhibits complete turnover of the water in winter and the release of dissolved gases. Our data strongly suggest that the differences in the dynamics of the two lakes are due to different density profiles affected by dissolved solutes, mainly Fe, which is strongly enriched in the deep water of the meromictic lake. A conceptual model of water balance was constructed based on the correlation between the chemical composition of the water and the hydrogen isotopic signature. Gas-rich groundwaters that feed both of the lakes and evaporation processes subsequently modify the water chemistry of the lakes. Our data highlight that no further potential hazardous accumulation of lethal gases is expected at the Monticchio lakes. Nevertheless, geochemical monitoring is needed to prevent the possibility of vigorous gas releases that have previously occurred in historical time.
    Description: Published
    Description: 1411–1434
    Description: 1.2. TTC - Sorveglianza geochimica delle aree vulcaniche attive
    Description: JCR Journal
    Description: restricted
    Keywords: geochemistry ; noble gases ; maar lake ; lake dynamics ; 04. Solid Earth::04.04. Geology::04.04.12. Fluid Geochemistry
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  • 9
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    Geofluids and natural gas in Romania, and the 10th International Conference on Gas Geochemistry (2010)
    Blackwell Publishing Ltd
    Details
    Publication Date: 2017-04-04
    Description: This thematic issue of Geofluids includes 11 papers representing the three main topics discussed in the 10th edition of the International Conference on Gas Geochemistry (ICGG-10): (i) gas in petroleum systems and seepage, (ii) gas in geothermal systems and volcanoes and (iii) gas, seismicity and geohazards. ICGG-10 was held in 2009 in Romania, a country extraordinarily rich in surface gas manifestations, that offers innumerable opportunities for innovative studies on gas geochemistry. We briefly describe the present knowledge on gases occurring both in petroliferous sedimentary basins and geothermal areas of Romania. The 11 contributions of this special issue, which include data from eight countries, are then summarised. Based on these papers and other works presented at the ICGG-10, we find that significant advances in analytical capabilities, data treating and interpretation have led to innovative insights into the origin, distribution and environmental impact of gases migrating to the Earth’s surface. It is increasingly clear, in particular, that gas geochemistry can be more effective for petroleum exploration, volcano-tectonic, geodynamic and environmental studies, if multiparametric studies are performed and the data are interpreted in the geological context.
    Description: Published
    Description: 457-462
    Description: 4.5. Studi sul degassamento naturale e sui gas petroliferi
    Description: JCR Journal
    Description: restricted
    Keywords: geothermal gas ; international conference on gas geochemistry ; natural gas ; romania ; seeps ; 04. Solid Earth::04.04. Geology::04.04.12. Fluid Geochemistry
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  • 10
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    Storm-driven mixing and potential impact on the Arctic Ocean (2010)
    American Geophysical Union
    Details
    Publication Date: 2022-05-25
    Description: Author Posting. © American Geophysical Union, 2004. This article is posted here by permission of American Geophysical Union for personal use, not for redistribution. The definitive version was published in Journal of Geophysical Research 109 (2004): C04008, doi:10.1029/2001JC001248.
    Description: Observations of the ocean, atmosphere, and ice made by Ice-Ocean Environmental Buoys indicate that mixing events reaching the depth of the halocline have occurred in various regions in the Arctic Ocean. Our analysis suggests that these mixing events were mechanically forced by intense storms moving across the buoy sites. In this study, we analyzed these mixing events in the context of storm developments that occurred in the Beaufort Sea and in the general area just north of Fram Strait, two areas with quite different hydrographic structures. The Beaufort Sea is strongly influenced by inflow of Pacific water through Bering Strait, while the area north of Fram Strait is directly affected by the inflow of warm and salty North Atlantic water. Our analyses of the basin-wide evolution of the surface pressure and geostrophic wind fields indicate that the characteristics of the storms could be very different. The buoy-observed mixing occurred only in the spring and winter seasons when the stratification was relatively weak. This indicates the importance of stratification, although the mixing itself was mechanically driven. We also analyze the distribution of storms, both the long-term climatology and the patterns for each year in the past 2 decades. The frequency of storms is also shown to be correlated (but not strongly) to Arctic Oscillation indices. This study indicates that the formation of new ice that leads to brine rejection is unlikely the mechanism that results in the type of mixing that could overturn the halocline. On the other hand, synoptic-scale storms can force mixing deep enough to the halocline and thermocline layer. Despite a very stable stratification associated with the Arctic halocline, the warm subsurface thermocline water is not always insulated from the mixed layer.
    Description: This study has been supported by the NASA Cryospheric Science Program and the International Arctic Reseach Center. We benefited from discussion with Dr. A. Proshutinsky. D. Walsh wishes to thank the Frontier Research System for Global Change for their support. The IOEB program was supported by ONR High-Latitude Dynamics Program and Japan Marine Science and Technology Center (JAMSTEC).
    Keywords: Arctic Ocean ; Mixing ; Storm ; Upper ocean
    Repository Name: Woods Hole Open Access Server
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  • 11
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    Mixing at the head of a canyon : a laboratory investigation of fluid exchanges in a rotating, stratified basin (2010)
    American Geophysical Union
    Details
    Publication Date: 2022-05-25
    Description: Author Posting. © American Geophysical Union, 2006. This article is posted here by permission of American Geophysical Union for personal use, not for redistribution. The definitive version was published in Journal of Geophysical Research 111 (2006): C12004, doi:10.1029/2006JC003667.
    Description: Observations indicate that oceanic mixing is intensified near the head of submarine canyons. How the presence of canyon walls affects the local production and distribution of mixed fluid is an open question. These dynamics are addressed through rotating tank experiments which impose mixing at middepth at the closed end of a channel open to a larger body of water. Turbulence is generated in a linearly stratified fluid with initial buoyancy frequency N by means of a single bar oscillated with frequency ω. The mixed fluid quickly reaches a steady state height h ∼ (ω/N)1/2 independent of the Coriolis frequency f and collapses into the channel interior. A small percentage of the fluid exported from the turbulent zone enters a boundary current. The bulk forms a cyclonic circulation in front of the bar. As the recirculation cell expands to fill the channel, it restricts horizontal entrainment into the turbulent zone. Mixed fluid flux decays with time as t inline equation and is dependent on the size of the mixing zone and the balance between turbulence, rotation, and stratification. The recirculation cell is confined within the channel, and export of mixed fluid into the basin is restricted to the weak boundary current. As horizontal entrainment is shut down, long-term production of mixed fluid relies more on vertical entrainment. However, the scalings indicate that short-term dynamics are the most applicable to oceanic conditions.
    Description: This work was supported by the Ocean Ventures Fund, the Westcott Fund, and the WHOI Academic Programs Office. Financial support was also provided by the National Science Foundation through grant OCE-9616949.
    Keywords: Mixing ; Canyon ; Laboratory
    Repository Name: Woods Hole Open Access Server
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  • 12
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    Modeling surf zone tracer plumes : 2. Transport and dispersion (2011)
    American Geophysical Union
    Details
    Publication Date: 2022-05-25
    Description: Author Posting. © American Geophysical Union, 2011. This article is posted here by permission of American Geophysical Union for personal use, not for redistribution. The definitive version was published in Journal of Geophysical Research 116 (2011): C11028, doi:10.1029/2011JC007211.
    Description: Five surf zone dye tracer releases from the HB06 experiment are simulated with a tracer advection diffusion model coupled to a Boussinesq surf zone model (funwaveC). Model tracer is transported and stirred by currents and eddies and diffused with a breaking wave eddy diffusivity, set equal to the breaking wave eddy viscosity, and a small (0.01 m2 s−1) background diffusivity. Observed and modeled alongshore parallel tracer plumes, transported by the wave driven alongshore current, have qualitatively similar cross-shore structures. Although the model skill for mean tracer concentration is variable (from negative to 0.73) depending upon release, cross-shore integrated tracer moments (normalized by the cross-shore tracer integral) have consistently high skills (≈0.9). Modeled and observed bulk surf zone cross-shore diffusivity estimates are also similar, with 0.72 squared correlation and skill of 0.4. Similar to the observations, the model bulk (absolute) cross-shore diffusivity is consistent with a mixing length parameterization based on low-frequency (0.001–0.03 Hz) eddies. The model absolute cross-shore dispersion is dominated by stirring from surf zone eddies and does not depend upon the presence of the breaking wave eddy diffusivity. Given only the bathymetry and incident wave field, the coupled Boussinesq-tracer model qualitatively reproduces the observed cross-shore absolute tracer dispersion, suggesting that the model can be used to study surf zone tracer dispersion mechanisms.
    Description: This research was supported by SCCOOS, CA Coastal Conservancy, NOAA, NSF, ONR, and CA Sea Grant.
    Description: 2012-05-18
    Keywords: Dispersion ; Mixing ; Surf zone ; Tracer
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  • 13
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    Modeling surf zone tracer plumes : 1. Waves, mean currents, and low-frequency eddies (2011)
    American Geophysical Union
    Details
    Publication Date: 2022-05-25
    Description: Author Posting. © American Geophysical Union, 2011. This article is posted here by permission of American Geophysical Union for personal use, not for redistribution. The definitive version was published in Journal of Geophysical Research 116 (2011): C11027, doi:10.1029/2011JC007210.
    Description: A model that accurately simulates surf zone waves, mean currents, and low-frequency eddies is required to diagnose the mechanisms of surf zone tracer transport and dispersion. In this paper, a wave-resolving time-dependent Boussinesq model is compared with waves and currents observed during five surf zone dye release experiments. In a companion paper, Clark et al. (2011) compare a coupled tracer model to the dye plume observations. The Boussinesq model uses observed bathymetry and incident random, directionally spread waves. For all five releases, the model generally reproduces the observed cross-shore evolution of significant wave height, mean wave angle, bulk directional spread, mean alongshore current, and the frequency-dependent sea surface elevation spectra and directional moments. The largest errors are near the shoreline where the bathymetry is most uncertain. The model also reproduces the observed cross-shore structure of rotational velocities in the infragravity (0.004 〈 f 〈 0.03 Hz) and very low frequency (VLF) (0.001 〈 f 〈 0.004 Hz) bands, although the modeled VLF energy is 2–3 times too large. Similar to the observations, the dominant contributions to the modeled eddy-induced momentum flux are in the VLF band. These eddies are elliptical near the shoreline and circular in the mid surf zone. The model-data agreement for sea swell waves, low-frequency eddies, and mean currents suggests that the model is appropriate for simulating surf zone tracer transport and dispersion.
    Description: This research was supported by SCCOOS, CA Coastal Conservancy, NOAA, NSF, ONR, and CA Sea Grant.
    Description: 2012-05-18
    Keywords: Mixing ; Surf zone ; Tracer dispersion
    Repository Name: Woods Hole Open Access Server
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  • 14
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    The spatial distribution and annual cycle of upper ocean thermohaline structure (2012)
    American Geophysical Union
    Details
    Publication Date: 2022-05-25
    Description: Author Posting. © American Geophysical Union, 2012. This article is posted here by permission of American Geophysical Union for personal use, not for redistribution. The definitive version was published in Journal of Geophysical Research 117 (2012): C02027, doi:10.1029/2011JC007033.
    Description: Observations of the spatial distribution and persistence of thermohaline structure are presented, and show how advection and diffusion affect a passive tracer. More than two years of underwater glider observations in the central subtropical North Pacific showed thermohaline variability over horizontal scales from 5 to 1300 km. Thermohaline fluctuations along isopycnals (spice fluctuations) were elevated in layers throughout the water column with the largest fluctuations near the surface and subtropical frontal regions. Fluctuations were uncorrelated between the layers but stirred by the same velocity field. Spice variance had local extrema in the vertical because of differences in source water properties and the influence of neighboring water masses. Spice variance spanned about three orders of magnitude along deeper isopycnals with larger variance where different water masses met and where velocity and vorticity variance were elevated. Horizontal wave number spectra of spice had slopes of −2 everywhere in the upper 1000 m. Submesoscale spice fluctuations had slopes in physical space near the ratio of the Coriolis parameter to the buoyancy frequency (f/N), consistent with predictions of quasi-geostrophic theory. In the mixed layer, thermohaline structure had a significant annual cycle with smaller interannual differences. Thermohaline fluctuations left behind during restratification and isolated from the mixed layer decayed with time because of diffusion along isopycnals. Horizontal diffusivity estimates in the remnant mixed layer were 0.4 m2 s−1 at 15–28 km wavelengths and 0.9 m2 s−1 at 35–45 km wavelengths.
    Description: We gratefully acknowledge the National Science Foundation for funding this work under grant number OCE0452574.
    Description: 2012-08-18
    Keywords: Diffusion ; Mixing ; Spice ; Stirring ; Thermohaline structure
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  • 15
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    Influence of mixing on CFC uptake and CFC ages in the North Pacific thermocline (2010)
    American Geophysical Union
    Details
    Publication Date: 2022-05-25
    Description: Author Posting. © American Geophysical Union, 2004. This article is posted here by permission of American Geophysical Union for personal use, not for redistribution. The definitive version was published in Journal of Geophysical Research 109 (2004): C07014, doi:10.1029/2003JC001988.
    Description: A diagnostic, isopycnal advection-diffusion model based on a climatological, geostrophic flow field is used to study the uptake of chlorofluorocarbons (CFCs) into the portion of the thermocline that outcrops in the open North Pacific (σ θ ≤ 26.6 kg m−3). In addition to advection, isopycnal diffusion is required to match the CFC data collected during the World Ocean Circulation Experiment (WOCE) in the early 1990s. Using reduced outcrop saturations of 80–95% for isopycnals outcropping in the northwestern North Pacific (σ θ ≥ 25.4 kg m−3), together with an isopcynal interior diffusivity of 2000 m2 s−1 and enhanced diffusion (5000 m2 s−1) in the Kuroshio Extension region, further improves the model-data agreement. Along-isopycnal diffusion is particularly important for isopycnals with shadow zones/pool regions in the western subtropical North Pacific that are isolated from direct advective ventilation. The isopycnal mixing causes an estimated increase in CFC-12 inventories on these isopycnals, compared to advection only, ranging from 10–20% (σ θ = 25.6 kg m−3) to 50–130% (σ θ = 26.6 kg m−3) over the subtropics in 1993. This contribution has important consequences for subduction rate estimates derived from CFC inventories and for the location of the subsurface CFC maxima. When tracer ages are derived from the modeled CFC distributions, time-evolving mixing biases become apparent that reflect the nonlinearities in the atmospheric CFC time histories. Comparison with model-calculated ideal ages suggests that during the time of WOCE (∼1993), ventilation ages based on CFC-12 were biased young by as much as 16–24 years for pCFC-12 ages of 25 years, underestimating ideal ages by as much as 40–50%.
    Description: Most of this work was performed while S.M. was a graduate student at the University of Washington under the support of NSF grant OCE-9819192. A postdoctoral scholarship for S.M. at the Woods Hole Oceanographic Institution, with funding provided by the Doherty Foundation, helped complete this work. R.E.S. acknowledges support from NSF grant OCE-0136897.
    Keywords: Tracers ; Mixing ; Thermocline
    Repository Name: Woods Hole Open Access Server
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    Tidal and spring-neap variations in horizontal dispersion in a partially mixed estuary (2010)
    American Geophysical Union
    Details
    Publication Date: 2022-05-25
    Description: Author Posting. © American Geophysical Union, 2008. This article is posted here by permission of American Geophysical Union for personal use, not for redistribution. The definitive version was published in Journal of Geophysical Research 113 (2008): C07023, doi:10.1029/2007JC004644.
    Description: A sequence of dye releases in the Hudson River estuary provide a quantitative assessment of horizontal dispersion in a partially mixed estuary. Dye was released in the bottom boundary layer on 4 separate occasions, with varying tidal phase and spring-neap conditions. The three-dimensional distribution of dye was monitored by two vessels with in situ, profiling fluorometers. The three-dimensional spreading of the dye was estimated by calculating the time derivative of the second moment of the dye in the along-estuary, cross-estuary and vertical directions. The average along-estuary dispersion rate was about 100 m2/s, but maximum rates up to 700 m2/s occurred during ebb tides, and minimum rates occurred during flood. Vertical shear dispersion was the principal mechanism during neap tides, but transverse shear dispersion became more important during springs. Suppression of mixing across the pycnocline limited the vertical extent of the patch in all but the maximum spring-tide conditions, with vertical diffusivities in the pycnocline estimated at 4 × 10−5 m2/s during neaps. The limited vertical extent of the dye patch limited the dispersion of the dye relative to the overall estuarine dispersion rate, which was an order of magnitude greater than that of the dye. This study indicates that the effective dispersion of waterborne material in an estuary depends sensitively on its vertical distribution as well as the phase of the spring-neap cycle.
    Description: This research was supported by National Science Foundation Grant OCE04-52054 (W. Geyer), OCE00-99310 (R. Houghton), and OCE00-95913 (R. Chant).
    Keywords: Dispersion ; Mixing ; Spring-neap variations
    Repository Name: Woods Hole Open Access Server
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    Eddy stirring in the Southern Ocean (2011)
    American Geophysical Union
    Details
    Publication Date: 2022-05-25
    Description: Author Posting. © American Geophysical Union, 2011. This article is posted here by permission of American Geophysical Union for personal use, not for redistribution. The definitive version was published in Journal of Geophysical Research 116 (2011): C09019, doi:10.1029/2010JC006818.
    Description: There is an ongoing debate concerning the distribution of eddy stirring across the Antarctic Circumpolar Current (ACC) and the nature of its controlling processes. The problem is addressed here by estimating the isentropic eddy diffusivity κ from a collection of hydrographic and altimetric observations, analyzed in a mixing length theoretical framework. It is shown that, typically, κ is suppressed by an order of magnitude in the upper kilometer of the ACC frontal jets relative to their surroundings, primarily as a result of a local reduction of the mixing length. This observation is reproduced by a quasi-geostrophic theory of eddy stirring across a broad barotropic jet based on the scaling law derived by Ferrari and Nikurashin (2010). The theory interprets the observed widespread suppression of the mixing length and κ in the upper layers of frontal jets as the kinematic consequence of eddy propagation relative to the mean flow within jet cores. Deviations from the prevalent regime of mixing suppression in the core of upper-ocean jets are encountered in a few special sites. Such ‘leaky jet’ segments appear to be associated with sharp stationary meanders of the mean flow that are generated by the interaction of the ACC with major topographic features. It is contended that the characteristic thermohaline structure of the Southern Ocean, consisting of multiple upper-ocean thermohaline fronts separated and underlaid by regions of homogenized properties, is largely a result of the widespread suppression of eddy stirring by parallel jets.
    Description: This study was conducted during A.C.N. G.’s stay at MIT, which was supported jointly by MIT and the U.K. Natural Environment Research Council (NERC) through a NERC Advanced Research Fellowship (NE/C517633/1). R.F. acknowledges the support of NSFaward OCE‐0825376. K.P.’s participation in this work was supported by WHOI bridge support funds.
    Keywords: Antarctic Circumpolar Current ; Eddy stirring ; Mixing
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    Vorticity generation by short-crested wave breaking (2013)
    American Geophysical Union
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    Publication Date: 2022-05-25
    Description: Author Posting. © American Geophysical Union, 2012. This article is posted here by permission of American Geophysical Union for personal use, not for redistribution. The definitive version was published in Geophysical Research Letters 39 (2012): L24604, doi:10.1029/2012GL054034.
    Description: Eddies and vortices associated with breaking waves rapidly disperse pollution, nutrients, and terrestrial material along the coast. Although theory and numerical models suggest that vorticity is generated near the ends of a breaking wave crest, this hypothesis has not been tested in the field. Here we report the first observations of wave-generated vertical vorticity (e.g., horizontal eddies), and find that individual short-crested breaking waves generate significant vorticity [O(0.01 s−1)] in the surfzone. Left- and right-handed wave ends generate vorticity of opposite sign, consistent with theory. In contrast to theory, the observed vorticity also increases inside the breaking crest, possibly owing to onshore advection of vorticity generated at previous stages of breaking or from the shape of the breaking region. Short-crested breaking transferred energy from incident waves to lower frequency rotational motions that are a primary mechanism for dispersion near the shoreline.
    Description: Funding was provided by a National Security Science and Engineering Faculty Fellowship, the Office of Naval Research, and a Woods Hole Oceanographic Institution Postdoctoral Fellowship.
    Description: 2013-06-21
    Keywords: Mixing ; Nearshore ; Turbulence ; Vorticity ; Waves
    Repository Name: Woods Hole Open Access Server
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    Mixing by shear instability at high Reynolds number (2010)
    American Geophysical Union
    Details
    Publication Date: 2022-05-25
    Description: Author Posting. © American Geophysical Union, 2010. This article is posted here by permission of American Geophysical Union for personal use, not for redistribution. The definitive version was published in Geophysical Research Letters 37 (2010): L22607, doi:10.1029/2010GL045272.
    Description: Shear instability is the dominant mechanism for converting fluid motion to mixing in the stratified ocean and atmosphere. The transition to turbulence has been well characterized in laboratory settings and numerical simulations at moderate Reynolds number—it involves “rolling up”, i.e., overturning of the density structure within the cores of the instabilities. In contrast, measurements in an energetic estuarine shear zone reveal that the mixing induced by shear instability at high Reynolds number does not primarily occur by overturning in the cores; rather it results from secondary shear instabilities within the zones of intensified shear separating the cores. This regime is not likely to be observed in the relatively low Reynolds number flows of the laboratory or in direct numerical simulations, but it is likely a common occurrence in the ocean and atmosphere.
    Description: This research was supported by NSF grant OCE‐0824871 and ONR grant N00014‐0810495.
    Keywords: Stratification ; Turbulence ; Mixing
    Repository Name: Woods Hole Open Access Server
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    Turbulent mixing in a strongly forced salt wedge estuary (2011)
    American Geophysical Union
    Details
    Publication Date: 2022-05-25
    Description: Author Posting. © American Geophysical Union, 2010. This article is posted here by permission of American Geophysical Union for personal use, not for redistribution. The definitive version was published in Journal of Geophysical Research 115 (2010): C12024, doi:10.1029/2009JC006061.
    Description: Turbulent mixing of salt is examined in a shallow salt wedge estuary with strong fluvial and tidal forcing. A numerical model of the Merrimack River estuary is used to quantify turbulent stress, shear production, and buoyancy flux. Little mixing occurs during flood tides despite strong velocities because bottom boundary layer turbulence is dislocated from stratification elevated in the water column. During ebbs, bottom salinity fronts form at a series of bathymetric transitions. At the fronts, near-bottom velocity and shear stress are low, but shear, stress, and buoyancy flux are elevated at the pycnocline. Internal shear layers provide the dominant source of mixing during the early ebb. Later in the ebb, the pycnocline broadens and moves down such that boundary layer turbulence dominates mixing. Mixing occurs primarily during ebbs, with internal shear mixing accounting for about 50% of the total buoyancy flux. Both the relative contribution of internal shear mixing and the mixing efficiency increase with discharge, with bulk mixing efficiencies between 0.02 and 0.07. Buoyancy fluxes in the estuary increase with discharge up to about 400 m3 s−1 above which a majority of the mixing occurs offshore. Observed buoyancy fluxes were more consistent with the k-ɛ turbulence closure than the Mellor-Yamada closure, and more total mixing occurred in the estuary with k-ɛ. Calculated buoyancy fluxes were sensitive to horizontal grid resolution, as a lower resolution grid yielded less integrated buoyancy flux in the estuary and exported lower salinity water but likely had greater numerical mixing.
    Description: This research was funded by National Science Foundation Grant OCE‐0452054. Ralston also received support from The Penzance Endowed Fund in Support of Assistant Scientists and The John F. and Dorothy H. Magee Fund in Support of Scientific Staff at Woods Hole Oceanographic Institution.
    Keywords: Mixing ; Turbulence ; Salt wedge estuary
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    Origin and flux of a gas seep in the Northern Alps (Giswil, Switzerland) (2010)
    Blackwell Publishing Ltd
    Details
    Publication Date: 2017-04-04
    Description: Natural gas seeps in the Alpine region are poorly investigated. However, they can provide useful information regarding the hydrocarbon potential of sedimentary Alpine units and related geofluid migration, typically controlled by pressurized gas accumulations and tectonics. A gas seep located near Giswil, in the Swiss Northern Alps, was investigated, for the first time, for molecular and isotopic gas composition, methane flux to the atmosphere, and gas flux variations over time. The analyses indicated that the gas was thermogenic (CH4 〉 96%; d13C1: )35.5& to )40.2&) and showed evidence of subsurface petroleum biodegradation (13C-enriched CO2, and very low C3+ concentrations). The source rock in the region is marine Type II kerogen, which is likely the same as that providing thermogenic gas in the nearby Wilen shallow well, close to Lake Sarnen. However, the lack of d13CCO2 and d13C3 data for that well prevented us from determining whether the Wilen and Giswil seeps are fed by the same reservoir and seepage system. Gas fluxes from the Giswil seep, measured using a closedchamber system, were significant and mainly from two major vents. However, a substantial gas exhalation from the soil occurs diffusely in an area of at least 115 m2, leading to a total CH4 output conservatively estimated to be at least 16 tonnes per year. Gas flux variations, monitored over a 1-month period by a special tent and flowmeter, showed not only daily meteorological oscillations, but also an intrinsic ‘pulsation’ with periods of enhanced flux that lasted 2–6 h each, occurring every few days. The pulses are likely related to episodes of gas pressure build-up and discharge along the seepage system. However, to date, no relationship to seismicity in the active Sarnen strike-slip fault system has been established.
    Description: Published
    Description: 476-485
    Description: 4.5. Studi sul degassamento naturale e sui gas petroliferi
    Description: JCR Journal
    Description: restricted
    Keywords: Alps ; isotopes ; methane ; organic geochemistry ; seeps ; Switzerland ; 04. Solid Earth::04.04. Geology::04.04.12. Fluid Geochemistry
    Repository Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
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    A box model test of the freshwater forcing hypothesis of abrupt climate change and the physics governing ocean stability (2011)
    American Geophysical Union
    Details
    Publication Date: 2022-05-26
    Description: Author Posting. © American Geophysical Union, 2010. This article is posted here by permission of American Geophysical Union for personal use, not for redistribution. The definitive version was published in Paleoceanography 25 (2010): PA4222, doi:10.1029/2010PA001936.
    Description: Observations and an ocean box model are combined in order to test the adequacy of the freshwater forcing hypothesis to explain abrupt climate change given the uncertainties in the parameterization of vertical buoyancy transport in the ocean. The combination is carried out using Bayesian stochastic inversion, which allows us to infer changes in the mass balance of Northern Hemisphere (NH) ice sheets and in the meridional transports of mass and heat in the Atlantic Ocean that would be required to explain Dansgaard-Oeschger Interstadials (DOIs) from 30 to 39 kyr B.P. The mean sea level changes implied by changes in NH ice sheet mass balance agree in amplitude and timing with reconstructions from the geologic record, which gives some support to the freshwater forcing hypothesis. The inversion suggests that the duration of the DOIs should be directly related to the growth of land ice. Our results are unaffected by uncertainties in the representation of vertical buoyancy transport in the ocean. However, the solutions are sensitive to assumptions about physical processes at polar latitudes.
    Description: This material is based upon work supported by the National Science Foundation under grant OCE‐0402363 and Department of Energy grant DE‐FG02‐08ER64619.
    Keywords: Inversion ; MOC ; Abrupt ; Sea level ; Coral ; Mixing
    Repository Name: Woods Hole Open Access Server
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