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  • Organic Chemistry  (3,434)
  • ASTROPHYSICS  (2,970)
  • 2015-2019  (28)
  • 1980-1984  (6,376)
  • 1
    Electronic Resource
    Electronic Resource
    New York, NY : Wiley-Blackwell
    Journal für Praktische Chemie/Chemiker-Zeitung 324 (1982), S. 964-972 
    ISSN: 0021-8383
    Keywords: Chemistry ; Organic Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: Investigations on the Thermal Decomposition of n-Dodecylcyclopentane in the Gas PhaseIn the thermal decomposition of n-dodecylcyclopentane at 670 and 750°C in a laboratory tubular reactor mixtures of hydrogen and 57 and 113 hydrocarbons respectively are formed. The mixtures have been analyzed and identified by capillary gas chromatography and by mass spectrometry. The distribution of the reaction products is used for mechanistic discussions.
    Additional Material: 2 Ill.
    Type of Medium: Electronic Resource
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  • 2
    Electronic Resource
    Electronic Resource
    New York, NY : Wiley-Blackwell
    Journal für Praktische Chemie/Chemiker-Zeitung 325 (1983), S. 66-74 
    ISSN: 0021-8383
    Keywords: Chemistry ; Organic Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: Kinetic Investigations of the Pyrolysis of Mono-n-alkyl-cyclohexanesThe thermal decomposition of cyclohexane and six mono-n-alkylcyclohexanes was studied kinetically in a metallic laboratory tubular reactor at 650 to 850°C and atmospheric pressure.Kinetic parameters were found to be a function of length of the alkylic side chain. A comparison with analogous parameters of n-paraffins and the unsubstituted cyclohexane allowed the conclusion that C—C-scission in the alkylic chain is the initial reaction in pyrolysis of n-alkylcyclohexanes followed by radical attacks to all C—H-bonds of the feed molecules.
    Additional Material: 4 Ill.
    Type of Medium: Electronic Resource
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  • 3
    Publication Date: 2011-08-18
    Description: Previous work on electron heating mechanisms operating at the supercritical earth's bow shock is extended to the generally lower Mach number interplanetary shocks. This is done by studying electron velocity distributions observed both upstream and downstream of interplanetary shocks observed by ISEE 3 between August 1978 and December 1979. It is found that perpendicular heating accompanied by little or no parallel heating occurs at the weaker shocks but that parallel heating is dominant for the stronger shocks. When perpendicular heating is dominant, downstream velocity distributions are for the most part Gaussian at low energies (core) and Lorentzian at high energies (halo). When parallel heating is dominant, however, these distributions are flat-topped at low energies, having power law extensions to higher energies. At the weaker shocks, the observations are consistent with electron heating resulting from conservation of the magnetic moment, whereas at the stronger shocks the heating is quite similar to that observed at the earth's bow shock.
    Keywords: ASTROPHYSICS
    Type: Journal of Geophysical Research (ISSN 0148-0227); 88; 9949-995
    Format: text
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  • 4
    Publication Date: 2019-06-28
    Description: An investigation is conducted regarding the existence of measurable transverse diffusive transport for 0.3- to 0.5 MeV protons. The study focuses on 1-hour averaged proton anisotropy data measured by detectors on board the earth-orbiting IMP 7 and 8 spacecraft. The data is restricted to nonimpulsive energetic particle events which are not explicitly associated with solar flares. It is established to within the limits of the measurements using 1-hour averages, that in nonimpulsive 0.3- to 0.5-MeV proton events as measured in the Newtonian inertial frame of the solar system, the anisotropy is predominantly transverse to the magnetic field and most hourly averages of the transverse component are essentially due to the particles' E x B drift.
    Keywords: ASTROPHYSICS
    Type: Journal of Geophysical Research; 86; July 1
    Format: text
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  • 5
    Publication Date: 2019-07-13
    Description: Long-lived upstream energetic ion events at Jupiter appear to be very similar in nearly all respects to upstream ion events at Earth. A notable difference between the two planetary systems is the enhanced heavy ion compositional signature reported for the Jovian events. This compositional feature has suggested that ions escaping from the Jovian magnetosphere play an important role in forming upstream ion populations at Jupiter. In contrast, models of energetic upstream ions at Earth emphasize in situ acceleration of reflected solar wind ions within the upstream region itself. Using Voyager 1 and 2 energetic ( approximately 30 keV) ion measurements near the magnetopause, in the magnetosheath, and immediately upstream of the bow shock, the compositional patterns are examined together with typical energy spectra in each of these regions. A model involving upstream Fermi acceleration early in events and emphasizing energetic particle escape in the prenoon part of the Jovian magnetosphere late in events is presented to explain many of the features in the upstream region of Jupiter.
    Keywords: ASTROPHYSICS
    Type: NASA-TM-85179 , NAS 1.15:85179 , DE82-019574 , LA-UR-82-1914 , CONF-82058-3 , Symp. on Giant Planets and Their Satellites; May 17, 1982 - May 27, 1982; Ottawa
    Format: application/pdf
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  • 6
    Publication Date: 2019-06-28
    Description: The damping of long wavelength, hydromagnetic waves in molecular cloud environments is studied with the aim of determining whether the supersonic motions observed in such clouds are likely to be due to the waves. It is found that Alfven waves propagating parallel to the average magnetic field are the longest lived wave modes. Such waves can typically survive for as long as one-million years if the wavelength is as long as a few tenths of a pc and the magnetic field is 0.1-1 milligauss. Nonlinear steepening of the waves followed by ion-neutral friction in the steepened wave profiles appears to be the most effective damping mechanism.
    Keywords: ASTROPHYSICS
    Type: Astrophysical Journal, Part 1 (ISSN 0004-637X); 270; July 15
    Format: text
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  • 7
    Publication Date: 2019-06-28
    Description: Using the MHD energy principle, it is shown that P + B sq/8 x pi = constant is a sufficient condition for the stability of magnetized fluid systems with the following properties: the gravitational acceleration g is uniform, the magnetic field lines lie in parallel planes aligned with g, and all quantities are uniform in the direction perpendicular to the plane of the field lines. An example of a stable system is given, consisting of a vertical sheet of plasma supported against gravity by bowed field lines.
    Keywords: ASTROPHYSICS
    Type: Astrophysical Journal; vol. 258
    Format: text
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  • 8
    Publication Date: 2011-08-18
    Description: Data on solar magnetism that may offer clues for understanding stellar magnetism in general were reviewed. Magnetic phenomena in the photosphere and low chromosphere, where the magnetic structure can be studied in detail, are discussed. Properties of the discrete magnetic elements and their extensions through the chromosphere and transition zone up to the corona are described. The structure and evolution of active regions and other structured aggregates of magnetic elements are considered.
    Keywords: ASTROPHYSICS
    Type: NASA. Goddard Space Flight Center The Sun as a Star; p 163-179
    Format: text
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  • 9
    ISSN: 0018-019X
    Keywords: Chemistry ; Organic Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: The conjugate addition of the chiral, non-racemic alkoxy-enolates 5 and 6 to nitroolefins furnishes the hydroxynitroesters 7-13, which are catalytically hydrogenated to give the lactams 14-18. The configuration of adduct 7 from nitroethylene was elucidated by NMR. analysis of the acetal 20 derived from 7. The assignment establishes that the reaction follows the stereochemical rule of attack depicted in 21 and previously deduced for other electrophiles, i.e. formation of erythro-products of type 3b and 4b. No stereocontrol was found at the newly formed chiral centers in α- and β-position to the NO2 group of 8-12.
    Additional Material: 1 Tab.
    Type of Medium: Electronic Resource
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  • 10
    Publication Date: 2019-06-27
    Description: Several positions near the galactic center (Sgr A) in the J=1-0 rotational transitions of (C-12)O, (C-13)O, and C(O-18) were observed in order to better understand the nature of the 'very cold' molecular gas whose existence was first stressed by Liszt and his colleagues (1975, 1977). It is established that several dips in the (C-12)O spectra are due to optically thick clouds of foreground CO with relatively low excitation temperatures (T sub ex). T sub ex is found to be greater than about 5.3 K for all such (C-12)O clouds in all five observed directions. Such clouds fall at the extreme low end of the measured range of T sub ex for nearby dark clouds, but would, nonetheless, generally be detected in sensitive emission surveys of galactic CO.
    Keywords: ASTROPHYSICS
    Type: Astrophysical Journal; vol. 235
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