ALBERT

Description: Ocean acidification is one of the most dramatic effects of the massive atmospheric release of anthropogenic carbon dioxide (CO2) that has occurred since the Industrial Revolution, although its effects on marine ecosystems are not well understood. Submarine volcanic hydrothermal fields have geochemical conditions that provide opportunities to characterise the effects of elevated levels of seawater CO2 on marine life in the field. Here, we review the geochemical aspects of shallow marine CO2-rich seeps worldwide, focusing on both gas composition and water chemistry. We then describe the geochemical effects of volcanic CO2 seepage on the overlying seawater column. We also present new geochemical data and the first synthesis of marine biological community changes from one of the best-studied marine CO2 seep sites in the world (off Vulcano Island, Sicily). In areas of intense bubbling, extremely high levels of pCO2 ([10,000 latm) result in low seawater pH (\6) and undersaturation of aragonite and calcite in an area devoid of calcified organisms such as shelled molluscs and hard corals. Around 100–400 m away from the Vulcano seeps the geochemistry of the seawater becomes analogous to future ocean acidification conditions with dissolved carbon dioxide levels falling from 900 to 420 latm as seawater pH rises from 7.6 to 8.0. Calcified species such as coralline algae and sea urchins fare increasingly well as sessile communities shift from domination by a few resilient species (such as uncalcified algae and polychaetes) to a diverse and complex community (including abundant calcified algae and sea urchins) as the seawater returns to ambient levels of CO2. Laboratory advances in our understanding of species sensitivity to high CO2 and low pH seawater, reveal how marine organisms react to simulated ocean acidification conditions (e.g., using energetic tradeoffs for calcification, reproduction, growth and survival). Research at volcanic marine seeps, such as those off Vulcano, highlight consistent ecosystem responses to rising levels of seawater CO2, with the simplification of food webs, losses in functional diversity and reduced provisioning of goods and services for humans.

Description: Published

Description: 93–115

Description: 2IT. Laboratori analitici e sperimentali

Description: JCR Journal

Description: The Italian Apennines are among the most important sources of freshwater for several Italian regions. With evidences of deep CO2-rich fluids intruding into aquifers in the nearby central-southern Apennines, a thorough investigation into the geochemistry of groundwater became critical to ensure the water quality in the area. Here, we show the main hydrogeochemical processes occurring in the Matese Massif (MM) aquifer through the investigation of 98 water samples collected from springs and water wells. All waters were classified as HCO3 type with Ca dominance (from 50% up to 97%) and variable amount of Mg (from 1% up to 49%). A multivariate statistical approach through the application of the factor analysis (FA) highlighted three main hydrogeochemical processes: (i) water-carbonate rock interactions mostly enhanced in peripheral areas of the MM by CO2 deep degassing; (ii) addition of NaCl-rich components linked to recharging process and to water mixing processes of the groundwater with a thermal component relatively rich in Cl, Na, and CO2; (iii) anthropogenic activities influencing groundwater composition at the foothills of MM. Furthermore, the first detailed TDIC, pCO2, and δ13C-TDIC distribution maps of the MM area have been created, which track chemical and isotopic anomalies in several peripheral areas (Pratella, Ailano, and Telese) throughout the region. These maps systematically highlight that the greater the amount of dissolved carbon occurs the heavier the C isotope enrichment, especially in the peripheral areas. Conversely, spring waters emerging at higher altitudes within MM are only slightly mineralized and associated with δ13C-TDIC values mainly characterized by recharging processes with the addition of biogenic carbon during the infiltration process through the soil.

Description: Published

Description: 46614–46626

Description: 6A. Geochimica per l'ambiente e geologia medica

Description: 2IT. Laboratori analitici e sperimentali

Description: JCR Journal

Description: Public concern about anthropogenic seismic- ity in Italy first arose in the aftermath of the deadly M ≈ 6 earthquakes that hit the Emilia-Romagna region (northern Italy) in May 2012. As these events occurred in a (tectonically active) region of oil and gas production and storage, the question was raised, whether stress perturbations due to underground industrial activities could have induced or triggered the shocks. Following expert recommendations, in 2014, the Italian Oil & Gas Safety Authority (DGS-UNMIG, Ministry of Economic Development) published guidelines (ILG - Indirizzi e linee guida per il monitoraggio della sismicità, delle deformazioni del suolo e delle pressioni di poro nell’ambito delle attività antropiche), describing regula- tions regarding hydrocarbon extraction, waste-water in- jection and gas storage that could also be adapted to other technologies, such as dams, geothermal systems, CO2 storage, and mining. The ILG describe the frame- work for the different actors involved in monitoring activities, their relationship and responsibilities, the procedure to be followed in case of variations of mon- itored parameters, the need for in-depth scientific anal- yses, the definition of different alert levels, their mean- ing and the parameters to be used to activate such alerts. Four alert levels are defined, the transition among which follows a decision to be taken jointly by relevant au- thorities and industrial operator on the basis of evalua- tion of several monitored parameters (micro-seismicity, ground deformation, pore pressure) carried on by a scientific-technical agency. Only in the case of liquid reinjection, the alert levels are automatically activated on the basis of exceedance of thresholds for earthquake magnitude and ground shaking – in what is generally known as a Traffic Light System (TLS). Istituto Nazionale di Geofisica e Vulcanologia has been charged by the Italian oil and gas safety authority (DGS- UNMIG) to apply the ILG in three test cases (two oil extraction and one gas storage plants). The ILG indeed represent a very important and positive innovation, as they constitute official guidelines to coherently regulate monitoring activity on a national scale. While pilot studies are still mostly under way, we may point out merits of the whole framework, and a few possible critical issues, requiring special care in the implementa- tion. Attention areas of adjacent reservoirs, possibly licenced to different operators, may overlap, hence mak- ing the point for joint monitoring, also in view of the possible interaction between stress changes related to the different reservoirs. The prescribed initial blank- level monitoring stage, aimed at assessing background seismicity, may lose significance in case of nearby ac- tive production. Magnitude – a critical parameter used to define a possible step-up in activation levels – has inherent uncertainty and can be evaluated using differ- ent scales. A final comment considers the fact that relevance of TLS, most frequently used in hydraulic fracturing operations, may not be high in case of trig- gered tectonic events.

Description: Published

Description: 1015–1028

Description: 1IT. Reti di monitoraggio e sorveglianza

Description: JCR Journal

Description: RAD7 and BigBottle system has been developed, using large glass bottles, but these are fragile and awkward to carry around. In searching for a better solution, we tested polyethylene terephthalate (PET) bottles for water samples storage to estimate radon loss over time. Two sets of experiments with 0.355 and 1.75 L bottles demonstrated that PET is a suitable material for storage. If correction for 226Ra content in water is applied, we can also calculate the rate of radon loss (0.03 ± 0.08 % day-1).

Description: Published

Description: 2277-2280

Description: 2IT. Laboratori analitici e sperimentali

Description: JCR Journal