ALBERT

Description: The effect of freshwater sources on wintertime sea-ice CO2 processes was studied from the glacier front to the outer Tempelfjorden, Svalbard, in sea ice, glacier ice, brine and snow. March–April 2012 was mild, and the fjord was mainly covered with drift ice, in contrast to the observed thicker fast ice in the colder April 2013. This resulted in different physical and chemical properties of the sea ice and under-ice water. Data from stable oxygen isotopic ratios and salinity showed that the sea ice at the glacier front in April 2012 contained on average 54% of frozen-in glacial meltwater. This was five times higher than in April 2013, where the ice was frozen seawater. In April 2012, the largest excess of sea-ice total alkalinity (AT), carbonate ion ([CO32−]) and bicarbonate ion concentrations ([HCO3−]) relative to salinity was mainly related to dissolved dolomite and calcite incorporated during freezing of mineral-enriched glacial water. In April 2013, the excess of these variables was mainly due to ikaite dissolution as a result of sea-ice processes. Dolomite dissolution increased sea-ice AT twice as much as ikaite and calcite dissolution, implying different buffering capacity and potential for ocean CO2 uptake in a changing climate.

Description: Radiocarbon (14C) ages cannot provide absolutely dated chronologies for archaeological or paleoenvironmental studies directly but must be converted to calendar age equivalents using a calibration curve compensating for fluctuations in atmospheric 14C concentration. Although calibration curves are constructed from independently dated archives, they invariably require revision as new data become available and our understanding of the Earth system improves. In this volume the international 14C calibration curves for both the Northern and Southern Hemispheres, as well as for the ocean surface layer, have been updated to include a wealth of new data and extended to 55,000 cal BP. Based on tree rings, IntCal20 now extends as a fully atmospheric record to ca. 13,900 cal BP. For the older part of the timescale, IntCal20 comprises statistically integrated evidence from floating tree-ring chronologies, lacustrine and marine sediments, speleothems, and corals. We utilized improved evaluation of the timescales and location variable 14C offsets from the atmosphere (reservoir age, dead carbon fraction) for each dataset. New statistical methods have refined the structure of the calibration curves while maintaining a robust treatment of uncertainties in the 14C ages, the calendar ages and other corrections. The inclusion of modeled marine reservoir ages derived from a three-dimensional ocean circulation model has allowed us to apply more appropriate reservoir corrections to the marine 14C data rather than the previous use of constant regional offsets from the atmosphere. Here we provide an overview of the new and revised datasets and the associated methods used for the construction of the IntCal20 curve and explore potential regional offsets for tree-ring data. We discuss the main differences with respect to the previous calibration curve, IntCal13, and some of the implications for archaeology and geosciences ranging from the recent past to the time of the extinction of the Neanderthals.

Description: The validity of any glaciological paleo proxy used to interpret climate records is based on the level of understanding of their transfer from the atmosphere into the ice sheet and their recording in the snowpack. Large spatial noise in snow properties is observed, as the wind constantly redistributes the deposited snow at the surface routed by the local topography. To increase the signal-tonoise ratio and getting a representative estimate of snow properties with respect to the high spatial variability, a large number of snow profiles is needed. However, the classical way of obtaining profiles via snow-pits is time and energy-consuming, and thus unfavourable for large surface sampling programs. In response, we present a dual-tube technique to sample the upper metre of the snowpack at a variable depth resolution with high efficiency. The developed device is robust and avoids contact with the samples by exhibiting two tubes attached alongside each other in order to (1) contain the snow core sample and (2) to access the bottom of the sample, respectively. We demonstrate the performance of the technique through two case studies in East Antarctica where we analysed the variability of water isotopes at a 100 m and 5 km spatial scales.

Description: Beyond ~13.9 cal kBP, the IntCal20 radiocarbon (14C) calibration curve is based upon combining data across a range of different archives including corals and planktic foraminifera. In order to reliably incorporate such marine data into an atmospheric curve, we need to resolve these records into their constituent atmospheric signal and marine reservoir age. We present results of marine reservoir age simulations enabling this resolution, applying the LSG ocean general circulation model forced with various climatic background conditions and with atmospheric radiocarbon changes according to the Hulu Cave speleothem record. Simulating the spatiotemporal evolution of reservoir ages between 54,000 and 10,700 cal BP, we find reservoir ages between 500 and 1400 yr in the low- and mid-latitudes, but also more than 3000 yr in the polar seas. Our results are broadly in agreement with available marine radiocarbon reconstructions, with the caveat that continental margins, marginal seas, or tropical lagoons are not properly resolved in our coarse-resolution model.

Description: The concentration of radiocarbon (14C) differs between ocean and atmosphere. Radiocarbon determinations from samples which obtained their 14C in the marine environment therefore need a marine-specific calibration curve and cannot be calibrated directly against the atmospheric-based IntCal20 curve. This paper presents Marine20, an update to the internationally agreed marine radiocarbon age calibration curve that provides a non-polar global-average marine record of radiocarbon from 0–55 cal kBP and serves as a baseline for regional oceanic variation. Marine20 is intended for calibration of marine radiocarbon samples from non-polar regions; it is not suitable for calibration in polar regions where variability in sea ice extent, ocean upwelling and air-sea gas exchange may have caused larger changes to concentrations of marine radiocarbon. The Marine20 curve is based upon 500 simulations with an ocean/atmosphere/biosphere box-model of the global carbon cycle that has been forced by posterior realizations of our Northern Hemispheric atmospheric IntCal20 14C curve and reconstructed changes in CO2 obtained from ice core data. These forcings enable us to incorporate carbon cycle dynamics and temporal changes in the atmospheric 14C level. The box-model simulations of the global-average marine radiocarbon reservoir age are similar to those of a more complex three-dimensional ocean general circulation model. However, simplicity and speed of the box model allow us to use a Monte Carlo approach to rigorously propagate the uncertainty in both the historic concentration of atmospheric 14C and other key parameters of the carbon cycle through to our final Marine20 calibration curve. This robust propagation of uncertainty is fundamental to providing reliable precision for the radiocarbon age calibration of marine based samples. We make a first step towards deconvolving the contributions of different processes to the total uncertainty; discuss the main differences of Marine20 from the previous age calibration curve Marine13; and identify the limitations of our approach together with key areas for further work. The updated values for ΔR, the regional marine radiocarbon reservoir age corrections required to calibrate against Marine20, can be found at the data base http://calib.org/marine/.

Description: The distribution, density and percentage contribution of pack ice seals during ship-board censuses in the marginal sea ice zone beyond the Lazarev Sea in spring 2019 are presented. Adult/juvenile crabeater seals (n = 19), leopard seals (n = 3) and Ross seals (n = 10) were sighted during 582.2 nm of censuses along the ship’s track line in the area bounded by 00°00’–22°E and 56°–60°S. Antarctic fur seals (n = 21) were only encountered on the outer fringes of the pack ice, and Weddell seals were absent due to their primary use of fast ice and inner pack ice habitats close to the coast. Crabeater seal sightings included juveniles (n = 2) and another four groups of 2–3 unclassified crabeater seals, singletons (n = 5), single mothers with pups (n = 3) and a family group (n = 1 triad). Only one leopard seal attended a pup, while no Ross seal pups were located. The survey was likely of insufficient effort, in both extent (north of 60°S) and duration (18 days), to locate seals in considerable numbers this early (late October/early November) in their austral spring breeding season.

Description: Volcanism and metamorphism are the principal geologic processes that drive carbon transfer from the interior of Earth to the surface reservoir.1–4 Input of carbon to the surface reservoir through volcanic degassing is balanced by removal through silicate weathering and the subduction of carbon-bearing marine deposits over million-year timescales. The magnitude of the volcanic carbon flux is thus of fundamental importance for stabilization of atmospheric CO2 and for long-term climate. It is likely that the “deep” carbon reservoir far exceeds the size of the surface reservoir in terms of mass;5,6 more than 99%of Earth’s carbon may reside in the core, mantle, and crust. The relatively high flux of volcanic carbon to the surface reservoir, combined with the reservoir’s small size, results in a short residence time for carbon in the ocean–atmosphere–biosphere system (~200 ka).7 The implication is that changes in the flux of volcanic carbon can affect the climate and ultimately the habitability of the planet on geologic timescales. In order to understand this delicate balance, we must first quantify the current volcanic flux of carbon to the atmosphere and understand the factors that control this flux.

Description: Published

Description: 188-236

Description: 3V. Proprietà chimico-fisiche dei magmi e dei prodotti vulcanici

Description: © The Author(s), 2020. This article is distributed under the terms of the Creative Commons Attribution License. The definitive version was published in Reimer, P. J., Austin, W. E. N., Bard, E., Bayliss, A., Blackwell, P. G., Ramsey, C. B., Butzin, M., Cheng, H., Edwards, R. L., Friedrich, M., Grootes, P. M., Guilderson, T. P., Hajdas, I., Heaton, T. J., Hogg, A. G., Hughen, K. A., Kromer, B., Manning, S. W., Muscheler, R., Palmer, J. G., Pearson, C., van der Plicht, J., Reimer, R. W., Richards, D. A., Scott, E. M., Southon, J. R., Turney, C. S. M., Wacker, L., Adolphi, F., Buentgen, U., Capano, M., Fahrni, S. M., Fogtmann-Schulz, A., Friedrich, R., Koehler, P., Kudsk, S., Miyake, F., Olsen, J., Reinig, F., Sakamoto, M., Sookdeo, A., & Talamo, S. The Intcal20 Northern Hemisphere radiocarbon age calibration curve (0-55 cal kBP). Radiocarbon, 62(4), (2020): 725-757, doi:10.1017/RDC.2020.41.

Description: Radiocarbon (14C) ages cannot provide absolutely dated chronologies for archaeological or paleoenvironmental studies directly but must be converted to calendar age equivalents using a calibration curve compensating for fluctuations in atmospheric 14C concentration. Although calibration curves are constructed from independently dated archives, they invariably require revision as new data become available and our understanding of the Earth system improves. In this volume the international 14C calibration curves for both the Northern and Southern Hemispheres, as well as for the ocean surface layer, have been updated to include a wealth of new data and extended to 55,000 cal BP. Based on tree rings, IntCal20 now extends as a fully atmospheric record to ca. 13,900 cal BP. For the older part of the timescale, IntCal20 comprises statistically integrated evidence from floating tree-ring chronologies, lacustrine and marine sediments, speleothems, and corals. We utilized improved evaluation of the timescales and location variable 14C offsets from the atmosphere (reservoir age, dead carbon fraction) for each dataset. New statistical methods have refined the structure of the calibration curves while maintaining a robust treatment of uncertainties in the 14C ages, the calendar ages and other corrections. The inclusion of modeled marine reservoir ages derived from a three-dimensional ocean circulation model has allowed us to apply more appropriate reservoir corrections to the marine 14C data rather than the previous use of constant regional offsets from the atmosphere. Here we provide an overview of the new and revised datasets and the associated methods used for the construction of the IntCal20 curve and explore potential regional offsets for tree-ring data. We discuss the main differences with respect to the previous calibration curve, IntCal13, and some of the implications for archaeology and geosciences ranging from the recent past to the time of the extinction of the Neanderthals.

Description: We would like to thank the National Natural Science Foundation of China grants NSFC 41888101 and NSFC 41731174, the 111 program of China (D19002), U.S. NSF Grant 1702816, and the Malcolm H. Wiener Foundation for support for research that contributed to the IntCal20 curve. The work on the Swiss and German YD trees was funded by the German Science foundation and the Swiss National Foundation (grant number: 200021L_157187). The operation in Aix-en-Provence is funded by the EQUIPEX ASTER-CEREGE, the Collège de France and the ANR project CARBOTRYDH (to EB). The work on the correlation of tree ring 14C with ice core 10Be was partially supported by the Swedish Research Council and the Knut and Alice Wallenberg foundation. M. Butzin was supported by the German Federal Ministry of Education and Research (BMBF) as Research for Sustainable Development (FONA; http://www.fona.de) through the PalMod project (grant number: 01LP1505B). S. Talamo and M. Friedrich are funded by the European Research Council under the European Union’s Horizon 2020 Research and Innovation Programme (grant agreement No. 803147-RESOLUTION, awarded to ST). CA. Turney would like to acknowledge support of the Australian Research Council (FL100100195 and DP170104665). P. Reimer and W. Austin acknowledge the support of the UKRI Natural Environment Research Council (Grant NE/M004619/1). T.J. Heaton is supported by a Leverhulme Trust Fellowship RF-2019-140\9. Other datasets and the IntCal20 database were created without external support through internal funding by the respective laboratories. We also would like to thank various institutions that provided funding or facilities for meetings.

Description: Executive Summary:Observations show that warming of the climate is unequivocal. The global warming observed over the past 50 years is due primarily to human-induced emissions of heat-trapping gases. These emissions come mainly from theburning of fossil fuels (coal, oil, and gas), with important contributions from the clearing of forests, agricultural practices, and other activities.Warming over this century is projected to be considerably greater than over the last century. The global average temperature since 1900 has risen by about 1.5ºF. By 2100, it is projected to rise another 2 to 11.5ºF. The U.S.average temperature has risen by a comparable amount and is very likely to rise more than the global average over this century, with some variation from place to place. Several factors will determine future temperature increases. Increases at the lower end of this range are more likely if global heat-trapping gas emissions are cut substantially. If emissions continue to rise at or near current rates, temperature increases are more likely to be near the upper end of the range. Volcanic eruptions or other natural variations could temporarily counteract some of the human-induced warming, slowing the rise in global temperature, but these effects would only last a few years.Reducing emissions of carbon dioxide would lessen warming over this century and beyond. Sizable early cuts in emissions would significantly reduce the pace and the overall amount of climate change. Earlier cuts in emissions would have a greater effect in reducing climate change than comparable reductions made later. In addition, reducing emissions of some shorter-lived heat-trapping gases, such as methane, and some types of particles, such as soot, would begin to reduce warming within weeks to decades.Climate-related changes have already been observed globally and in the United States. These include increases in air and water temperatures, reduced frost days, increased frequency and intensity of heavy downpours, a rise in sea level, and reduced snow cover, glaciers, permafrost, and seaice. A longer ice-free period on lakes and rivers, lengthening of the growing season, and increased water vapor in the atmosphere have also been observed. Over the past 30 years, temperatures have risen faster in winter than in any other season, with average winter temperatures in the Midwest and northern Great Plains increasing more than 7ºF. Some of the changes have been faster thanprevious assessments had suggested.These climate-related changes are expected to continue while new ones develop. Likely future changes for the United States and surrounding coastal waters include more intense hurricanes with related increases in wind, rain, and storm surges (but not necessarily an increase in the number of these storms that make landfall), as well as drier conditions in the Southwest and Caribbean. Thesechanges will affect human health, water supply, agriculture, coastal areas, and many other aspectsof society and the natural environment.This report synthesizes information from a wide variety of scientific assessments (see page 7) and recently published research to summarize what is known about the observed and projected consequences of climate change on the United States. It combines analysis of impacts on various sectors such as energy, water, and transportation at the national level with an assessment of key impacts on specific regions of the United States. For example, sea-level rise will increase risks of erosion, storm surge damage, and flooding for coastal communities, especially in the Southeast and parts of Alaska. Reduced snowpack and earlier snow melt will alter the timing and amount of water supplies, posingsignificant challenges for water resource managementin the West. (PDF contains 196 pages)

Description: The waters along the West Antarctic Peninsula (WAP) have experienced warming and increased freshwater inputs from melting sea ice and glaciers in recent decades. Challenges exist in understanding the consequences of these changes on the inorganic carbon system in this ecologically important and highly productive ecosystem. Distributions of dissolved inorganic carbon (CT), total alkalinity (AT) and nutrients revealed key physical, biological and biogeochemical controls of the calcium carbonate saturation state (Ωaragonite) in different water masses across the WAP shelf during the summer. Biological production in spring and summer dominated changes in surface water Ωaragonite (ΔΩaragonite up to +1.39; ∼90%) relative to underlying Winter Water. Sea-ice and glacial meltwater constituted a minor source of AT that increased surface water Ωaragonite (ΔΩaragonite up to +0.07; ∼13%). Remineralization of organic matter and an influx of carbon-rich brines led to cross-shelf decreases in Ωaragonite in Winter Water and Circumpolar Deep Water. A strong biological carbon pump over the shelf created Ωaragonite oversaturation in surface waters and suppression of Ωaragonite in subsurface waters. Undersaturation of aragonite occurred at 〈 ∼1000 m. Ongoing changes along the WAP will impact the biologically driven and meltwater-driven processes that influence the vulnerability of shelf waters to calcium carbonate undersaturation in the future.

Description: Pliocene–Quaternary faults are relevant structures with which to constrain the seismotectonic context and contribute to the evaluation of the seismic hazard of a region. Many of these faults, however, do not show clear surface evidence even when releasing earthquakes. For these reasons they can be extremely dangerous as they receive relatively little attention and can be difficult to identify. From among the various surface geology studies and/or palaeoseismological investigations, we focus our attention on the integration of different datasets such as seismic reflection profiles, surface kinematic data and the relocation of seismological data, which make it possible to identify and characterize active faults whose dimension and earthquake potential would otherwise not be large enough to make them identifiable. We take as an example the Montespertoli NE-trending fault in southern Tuscany (central Italy) with which we associate the 2016 M=3.9 Castelfiorentino earthquake. This structure is part of a wider (in the order of 15–20 km) crustal-scale shear zone, which may be responsible for strong historical earthquakes in the area.

Description: Published

Description: 853 - 872

Description: 4T. Sismicità dell'Italia

Description: JCR Journal

Description: © The Author(s), 2020. This article is distributed under the terms of the Creative Commons Attribution License. The definitive version was published in Hughen, K. A., & Heaton, T. J. Updated Cariaco Basin C-14 calibration dataset from 0-60 cal kyr BP. Radiocarbon, 62(4), (2020): 1001-1043, doi:10.1017/RDC.2020.53.

Description: We present new updates to the calendar and radiocarbon (14C) chronologies for the Cariaco Basin, Venezuela. Calendar ages were generated by tuning abrupt climate shifts in Cariaco Basin sediments to those in speleothems from Hulu Cave. After the original Cariaco-Hulu calendar age model was published, Hulu Cave δ18O records have been augmented with increased temporal resolution and a greater number of U/Th dates. These updated Hulu Cave records provide increased accuracy as well as precision in the final Cariaco calendar age model. The depth scale for the Ocean Drilling Program Site 1002D sediment core, the primary source of samples for 14C dating, has been corrected to account for missing sediment from a core break, eliminating age-depth anomalies that afflicted the earlier calendar age models. Individual 14C dates for the Cariaco Basin remain unchanged from previous papers, although detailed comparisons of the Cariaco calibration dataset to those from Hulu Cave and Lake Suigetsu suggest that the Cariaco marine reservoir age may have shifted systematically during the past. We describe these recent changes to the Cariaco datasets and provide the data in a comprehensive format that will facilitate use by the community.

Description: K.A. Hughen was supported by funds from U.S. NSF grant #OCE-1657191, and by the Investment in Science Fund at WHOI. T.J. Heaton is supported by a Leverhulme Trust Fellowship RF-2019-140\9, “Improving the Measurement of Time Using Radiocarbon”.

Description: © The Author(s), 2021. This article is distributed under the terms of the Creative Commons Attribution License. The definitive version was published in Baker, M. G., Aster, R. C., Wiens, D. A., Nyblade, A., Bromirski, P. D., Gerstoft, P., & Stephen, R. A. Teleseismic earthquake wavefields observed on the Ross Ice Shelf. Journal of Glaciology, 67(261), (2021): 58-74, https://doi.org/10.1017/jog.2020.83.

Description: Observations of teleseismic earthquakes using broadband seismometers on the Ross Ice Shelf (RIS) must contend with environmental and structural processes that do not exist for land-sited seismometers. Important considerations are: (1) a broadband, multi-mode ambient wavefield excited by ocean gravity wave interactions with the ice shelf; (2) body wave reverberations produced by seismic impedance contrasts at the ice/water and water/seafloor interfaces and (3) decoupling of the solid Earth horizontal wavefield by the sub-shelf water column. We analyze seasonal and geographic variations in signal-to-noise ratios for teleseismic P-wave (0.5–2.0 s), S-wave (10–15 s) and surface wave (13–25 s) arrivals relative to the RIS noise field. We use ice and water layer reverberations generated by teleseismic P-waves to accurately estimate the sub-station thicknesses of these layers. We present observations consistent with the theoretically predicted transition of the water column from compressible to incompressible mechanics, relevant for vertically incident solid Earth waves with periods longer than 3 s. Finally, we observe symmetric-mode Lamb waves generated by teleseismic S-waves incident on the grounding zones. Despite their complexity, we conclude that teleseismic coda can be utilized for passive imaging of sub-shelf Earth structure, although longer deployments relative to conventional land-sited seismometers will be necessary to acquire adequate data.

Description: This research was supported by NSF grants PLR-1142518, 1141916, 1142126, 1246151, 1246416 and OPP-1744852 and 1744856.

Description: © The Author(s), 2022. This article is distributed under the terms of the Creative Commons Attribution License. The definitive version was published in McNichol, A., Key, R., & Guilderson, T. Global ocean radiocarbon programs. Radiocarbon, (2022): 1–13, https://doi.org/10.1017/rdc.2022.17.

Description: The importance of studying the radiocarbon content of dissolved inorganic carbon (DI14C) in the oceans has been recognized for decades. Starting with the GEOSECS program in the 1970s, 14C sampling has been a part of most global survey programs. Early results were used to study air-sea gas exchange while the more recent results are critical for helping calibrate ocean general circulation models used to study the effects of climate change. Here we summarize the major programs and discuss some of the important insights the results are starting to provide.

Description: Authors received funding from the National Science Foundation OCE-85865400 (APM) and a Woods Hole Oceanographic Technical Staff Award (APM).

Description: © The Author(s), 2020. This article is distributed under the terms of the Creative Commons Attribution License. The definitive version was published in Ackley, S. F., Perovich, D. K., Maksym, T., Weissling, B., & Xie, H. Surface flooding of Antarctic summer sea ice. Annals of Glaciology, 61(82), (2020): 117-126, doi:10.1017/aog.2020.22.

Description: The surface flooding of Antarctic sea ice in summer covers 50% or more of the sea-ice area in the major summer ice packs, the western Weddell and the Bellingshausen-Amundsen Seas. Two CRREL ice mass-balance buoys were deployed on the Amundsen Sea pack in late December 2010 from the icebreaker Oden, bridging the summer period (January–February 2011). Temperature records from thermistors embedded vertically in the snow and ice showed progressive increases in the depth of the flooded layer (up to 0.3–0.35 m) on the ice cover during January and February. While the snow depth was relatively unchanged from accumulation (〈10 cm), ice thickness decreased by up to a meter from bottom melting during this period. Contemporaneous with the high bottom melting, under-ice water temperatures up to 1°C above the freezing point were found. The high temperature arises from solar heating of the upper mixed layer which can occur when ice concentration in the local area falls and lower albedo ocean water is exposed to radiative heating. The higher proportion of snow ice found in the Amundsen Sea pack ice therefore results from both winter snowfall and summer ice bottom melt found here that can lead to extensive surface flooding.

Description: This work was supported by the National Science Foundation grant to UTSA, ANT-0839053-Sea Ice System in Antarctic Summer (S.F. Ackley, H. Xie and B. Weissling), and to WHOI, ANT-1341513 (T. Maksym), and by the NASA Center for Advanced Measurements in Extreme Environments or NASA-CAMEE at UTSA, NASA #80NSSC19M0194 (S.F. Ackley, H. Xie, B.Weissling).

Description: © The Author(s), 2020. This article is distributed under the terms of the Creative Commons Attribution License. The definitive version was published in Reimer, P. J., Austin, W. E. N., Bard, E., Bayliss, A., Blackwell, P. G., Ramsey, C. B., Butzin, M., Cheng, H., Edwards, R. L., Friedrich, M., Grootes, P. M., Guilderson, T. P., Hajdas, I., Heaton, T. J., Hogg, A. G., Hughen, K. A., Kromer, B., Manning, S. W., Muscheler, R., Palmer, J. G., Pearson, C., van der Plicht, J., Reimer, R. W., Richards, D. A., Scott, E. M., Southon, J. R., Turney, C. S. M., Wacker, L., Adolphi, F., Buentgen, U., Capano, M., Fahrni, S. M., Fogtmann-Schulz, A., Friedrich, R., Koehler, P., Kudsk, S., Miyake, F., Olsen, J., Reinig, F., Sakamoto, M., Sookdeo, A., & Talamo, S. The Intcal20 Northern Hemisphere radiocarbon age calibration curve (0-55 cal kBP). Radiocarbon, 62(4), (2020): 725-757, doi:10.1017/RDC.2020.41.

Description: Radiocarbon (14C) ages cannot provide absolutely dated chronologies for archaeological or paleoenvironmental studies directly but must be converted to calendar age equivalents using a calibration curve compensating for fluctuations in atmospheric 14C concentration. Although calibration curves are constructed from independently dated archives, they invariably require revision as new data become available and our understanding of the Earth system improves. In this volume the international 14C calibration curves for both the Northern and Southern Hemispheres, as well as for the ocean surface layer, have been updated to include a wealth of new data and extended to 55,000 cal BP. Based on tree rings, IntCal20 now extends as a fully atmospheric record to ca. 13,900 cal BP. For the older part of the timescale, IntCal20 comprises statistically integrated evidence from floating tree-ring chronologies, lacustrine and marine sediments, speleothems, and corals. We utilized improved evaluation of the timescales and location variable 14C offsets from the atmosphere (reservoir age, dead carbon fraction) for each dataset. New statistical methods have refined the structure of the calibration curves while maintaining a robust treatment of uncertainties in the 14C ages, the calendar ages and other corrections. The inclusion of modeled marine reservoir ages derived from a three-dimensional ocean circulation model has allowed us to apply more appropriate reservoir corrections to the marine 14C data rather than the previous use of constant regional offsets from the atmosphere. Here we provide an overview of the new and revised datasets and the associated methods used for the construction of the IntCal20 curve and explore potential regional offsets for tree-ring data. We discuss the main differences with respect to the previous calibration curve, IntCal13, and some of the implications for archaeology and geosciences ranging from the recent past to the time of the extinction of the Neanderthals.

Description: We would like to thank the National Natural Science Foundation of China grants NSFC 41888101 and NSFC 41731174, the 111 program of China (D19002), U.S. NSF Grant 1702816, and the Malcolm H. Wiener Foundation for support for research that contributed to the IntCal20 curve. The work on the Swiss and German YD trees was funded by the German Science foundation and the Swiss National Foundation (grant number: 200021L_157187). The operation in Aix-en-Provence is funded by the EQUIPEX ASTER-CEREGE, the Collège de France and the ANR project CARBOTRYDH (to EB). The work on the correlation of tree ring 14C with ice core 10Be was partially supported by the Swedish Research Council and the Knut and Alice Wallenberg foundation. M. Butzin was supported by the German Federal Ministry of Education and Research (BMBF) as Research for Sustainable Development (FONA; http://www.fona.de) through the PalMod project (grant number: 01LP1505B). S. Talamo and M. Friedrich are funded by the European Research Council under the European Union’s Horizon 2020 Research and Innovation Programme (grant agreement No. 803147-RESOLUTION, awarded to ST). CA. Turney would like to acknowledge support of the Australian Research Council (FL100100195 and DP170104665). P. Reimer and W. Austin acknowledge the support of the UKRI Natural Environment Research Council (Grant NE/M004619/1). T.J. Heaton is supported by a Leverhulme Trust Fellowship RF-2019-140\9. Other datasets and the IntCal20 database were created without external support through internal funding by the respective laboratories. We also would like to thank various institutions that provided funding or facilities for meetings.

Description: © The Author(s), 2022. This article is distributed under the terms of the Creative Commons Attribution License. The definitive version was published in Druffel, E., Beaupre, S., Grotheer, H., Lewis, C., McNichol, A., Mollenhauer, G., & Walker, B. Marine organic carbon and radiocarbon – present and future challenges. Radiocarbon, (2022): 1-17, https://doi.org/10.1017/RDC.2021.105.

Description: We discuss present and developing techniques for studying radiocarbon in marine organic carbon (C). Bulk DOC (dissolved organic C) Δ14C measurements reveal information about the cycling time and sources of DOC in the ocean, yet they are time consuming and need to be streamlined. To further elucidate the cycling of DOC, various fractions have been separated from bulk DOC, through solid phase extraction of DOC, and ultrafiltration of high and low molecular weight DOC. Research using 14C of DOC and particulate organic C separated into organic fractions revealed that the acid insoluble fraction is similar in 14C signature to that of the lipid fraction. Plans for utilizing this methodology are described. Studies using compound specific radiocarbon analyses to study the origin of biomarkers in the marine environment are reviewed and plans for the future are outlined. Development of ramped pyrolysis oxidation methods are discussed and scientific questions addressed. A modified elemental analysis (EA) combustion reactor is described that allows high particulate organic C sample throughput by direct coupling with the MIniCArbonDAtingSystem.

Description: © The Author(s), 2021. This article is distributed under the terms of the Creative Commons Attribution License. The definitive version was published in Priscu, J. C., Kalin, J., Winans, J., Campbell, T., Siegfried, M. R., Skidmore, M., Dore, J. E., Leventer, A., Harwood, D. M., Duling, D., Zook, R., Burnett, J., Gibson, D., Krula, E., Mironov, A., McManis, J., Roberts, G., Rosenheim, B. E., Christner, B. C., Kasic, K., Fricker, H. A., Lyons, W. B., Barker, J., Bowling, M., Collins, B., Davis, C., Gagnon, A., Gardner, C., Gustafson, C., Kim, O-S., Li, W., Michaud, A., Patterson, M. O., Tranter, M., Ryan Venturelli, R., Trista Vick-Majors, T., & Elsworth, C. Scientific access into Mercer Subglacial Lake: scientific objectives, drilling operations and initial observations. Annals of Glaciology, 62(85–86), (2021): 340–352, https://doi.org/10.1017/aog.2021.10.

Description: The Subglacial Antarctic Lakes Scientific Access (SALSA) Project accessed Mercer Subglacial Lake using environmentally clean hot-water drilling to examine interactions among ice, water, sediment, rock, microbes and carbon reservoirs within the lake water column and underlying sediments. A ~0.4 m diameter borehole was melted through 1087 m of ice and maintained over ~10 days, allowing observation of ice properties and collection of water and sediment with various tools. Over this period, SALSA collected: 60 L of lake water and 10 L of deep borehole water; microbes 〉0.2 μm in diameter from in situ filtration of ~100 L of lake water; 10 multicores 0.32–0.49 m long; 1.0 and 1.76 m long gravity cores; three conductivity–temperature–depth profiles of borehole and lake water; five discrete depth current meter measurements in the lake and images of ice, the lake water–ice interface and lake sediments. Temperature and conductivity data showed the hydrodynamic character of water mixing between the borehole and lake after entry. Models simulating melting of the ~6 m thick basal accreted ice layer imply that debris fall-out through the ~15 m water column to the lake sediments from borehole melting had little effect on the stratigraphy of surficial sediment cores.

Description: This material is based upon work supported by the US National Science Foundation, Section for Antarctic Sciences, Antarctic Integrated System Science program as part of the interdisciplinary (Subglacial Antarctic Lakes Scientific Access (SALSA): Integrated study of carbon cycling in hydrologically-active subglacial environments) project (NSF-OPP 1543537, 1543396, 1543405, 1543453 and 1543441). Ok-Sun Kim was funded by the Korean Polar Research Institute. We are particularly thankful to the SALSA traverse personnel for crucial technical and logistical support. The United States Antarctic Program enabled our fieldwork; the New York Air National Guard and Kenn Borek Air provided air support; UNAVCO provided geodetic instrument support. Hot water drilling activities, including repair and upgrade modifications of the WISSARD hot water drill system, for the SALSA project were supported by a subaward from the Ice Drilling Program of Dartmouth College (NSF-PLR 1327315) to the University of Nebraska-Lincoln. J. Lawrence assisted with manuscript preparation. Finally, we are grateful to C. Dean, the SALSA Project Manager, and R. Ricards, SALSA Project Coordinator at McMurdo Station, for their organizational skills, and B. Huber of Lamont-Doherty Earth Observatory for providing the SBE39 PT sensors and the Nortek Aquadopp current meter and assisting with interpretation of the data. B. Huber also provided helpful input on programing and calibrating the SBE19PlusV2 6112 CTD.

Description: © The Author(s), 2020. This article is distributed under the terms of the Creative Commons Attribution License. The definitive version was published in Tison, J.-L., Maksym, T., Fraser, A. D., Corkill, M., Kimura, N., Nosaka, Y., Nomura, D., Vancoppenolle, M., Ackley, S., Stammerjohn, S., Wauthy, S., Van der Linden, F., Carnat, G., Sapart, C., de Jong, J., Fripiat, F., & Delille, B. Physical and biological properties of early winter Antarctic sea ice in the Ross Sea. Annals of Glaciology, 61(83), (2020): 241–259, https://doi.org/10.1017/aog.2020.43.

Description: This work presents the results of physical and biological investigations at 27 biogeochemical stations of early winter sea ice in the Ross Sea during the 2017 PIPERS cruise. Only two similar cruises occurred in the past, in 1995 and 1998. The year 2017 was a specific year, in that ice growth in the Central Ross Sea was considerably delayed, compared to previous years. These conditions resulted in lower ice thicknesses and Chl-a burdens, as compared to those observed during the previous cruises. It also resulted in a different structure of the sympagic algal community, unusually dominated by Phaeocystis rather than diatoms. Compared to autumn-winter sea ice in the Weddell Sea (AWECS cruise), the 2017 Ross Sea pack ice displayed similar thickness distribution, but much lower snow cover and therefore nearly no flooding conditions. It is shown that contrasted dynamics of autumnal-winter sea-ice growth between the Weddell Sea and the Ross Sea impacted the development of the sympagic community. Mean/median ice Chl-a concentrations were 3–5 times lower at PIPERS, and the community status there appeared to be more mature (decaying?), based on Phaeopigments/Chl-a ratios. These contrasts are discussed in the light of temporal and spatial differences between the two cruises.

Description: S. Stammerjohn was supported by the PIPERS and LTER Programs of the U.S. National Science Foundation, ANT-1341606 (S. Stammerjohn and J. Cassano, U Colorado) and ANT-0823101 (H. Ducklow, LDEO/Columbia University), respectively. Steve Ackley (UTSA) was supported by the PIPERS program of the U.S. National Science Foundation ANT-1341717 and by NASA Grant 80NSSC19M0194 to the Center for Adv. Meas. in Extreme Environments at UTSA.Ted Maksym (WHOI) was supported by the PIPERS program of the U.S. National Science Foundation ANT-1341513. This research was supported by the Belgian F.R.S-FNRS (project ISOGGAP and IODIne, contract T.0268.16 and J.0262.17, respectively). Fanny Van der Linden, Sarah Wauthy, Gauthier Carnat, Célia Sapart and Bruno Delille are PhD students, postdoctoral researchers and research associate, respectively, of the Belgian F.R.S.-FNRS. This work was also supported by the Australian Government's Cooperative Research Centre program through the Antarctic Climate & Ecosystems Cooperative Research Centre, and by the Australian Research Council's Special Research Initiative for Antarctic Gateway Partnership (Project ID SR140300001). Daiki Nomura was supported by grants from the Japan Society for the Promotion of Science (#17H04715) and the National Institute for Polar Research through Project Research KP-303 (ROBOTICA) and #28-14.

Description: © The Author(s), 2022. This article is distributed under the terms of the Creative Commons Attribution License. The definitive version was published in Tan, S., Pratt, L. J., Voet, G., Cusack, J. M., Helfrich, K. R., Alford, M. H., Girton, J. B., & Carter, G. S. Hydraulic control of flow in a multi-passage system connecting two basins. Journal of Fluid Mechanics, 940, (2022): A8, https://doi.org/10.1017/jfm.2022.212.

Description: When a fluid stream in a conduit splits in order to pass around an obstruction, it is possible that one branch will be critically controlled while the other remains not so. This is apparently the situation in Pacific Ocean abyssal circulation, where most of the northward flow of Antarctic bottom water passes through the Samoan Passage, where it is hydraulically controlled, while the remainder is diverted around the Manihiki Plateau and is not controlled. These observations raise a number of questions concerning the dynamics necessary to support such a regime in the steady state, the nature of upstream influence and the usefulness of rotating hydraulic theory to predict the partitioning of volume transport between the two paths, which assumes the controlled branch is inviscid. Through the use of a theory for constant potential vorticity flow and accompanying numerical model, we show that a steady-state regime similar to what is observed is dynamically possible provided that sufficient bottom friction is present in the uncontrolled branch. In this case, the upstream influence that typically exists for rotating channel flow is transformed into influence into how the flow is partitioned. As a result, the partitioning of volume flux can still be reasonably well predicted with an inviscid theory that exploits the lack of upstream influence.

Description: This work was supported by the National Science Foundation under grants OCE-1029268, OCE-1029483, OCE-1657264, OCE-1657795, OCE-1657870 and OCE-1658027.

Description: © The Author(s), 2020. This article is distributed under the terms of the Creative Commons Attribution License. The definitive version was published in Heaton, T. J., Koehler, P., Butzin, M., Bard, E., Reimer, R. W., Austin, W. E. N., Ramsey, C. B., Grootes, P. M., Hughen, K. A., Kromer, B., Reimer, P. J., Adkins, J., Burke, A., Cook, M. S., Olsen, J., & Skinner, L. C. Marine20-the marine radiocarbon age calibration curve (0-55,000 cal BP). Radiocarbon, 62(4), (2020): 779-820, doi:10.1017/RDC.2020.68.

Description: The concentration of radiocarbon (14C) differs between ocean and atmosphere. Radiocarbon determinations from samples which obtained their 14C in the marine environment therefore need a marine-specific calibration curve and cannot be calibrated directly against the atmospheric-based IntCal20 curve. This paper presents Marine20, an update to the internationally agreed marine radiocarbon age calibration curve that provides a non-polar global-average marine record of radiocarbon from 0–55 cal kBP and serves as a baseline for regional oceanic variation. Marine20 is intended for calibration of marine radiocarbon samples from non-polar regions; it is not suitable for calibration in polar regions where variability in sea ice extent, ocean upwelling and air-sea gas exchange may have caused larger changes to concentrations of marine radiocarbon. The Marine20 curve is based upon 500 simulations with an ocean/atmosphere/biosphere box-model of the global carbon cycle that has been forced by posterior realizations of our Northern Hemispheric atmospheric IntCal20 14C curve and reconstructed changes in CO2 obtained from ice core data. These forcings enable us to incorporate carbon cycle dynamics and temporal changes in the atmospheric 14C level. The box-model simulations of the global-average marine radiocarbon reservoir age are similar to those of a more complex three-dimensional ocean general circulation model. However, simplicity and speed of the box model allow us to use a Monte Carlo approach to rigorously propagate the uncertainty in both the historic concentration of atmospheric 14C and other key parameters of the carbon cycle through to our final Marine20 calibration curve. This robust propagation of uncertainty is fundamental to providing reliable precision for the radiocarbon age calibration of marine based samples. We make a first step towards deconvolving the contributions of different processes to the total uncertainty; discuss the main differences of Marine20 from the previous age calibration curve Marine13; and identify the limitations of our approach together with key areas for further work. The updated values for ΔR, the regional marine radiocarbon reservoir age corrections required to calibrate against Marine20, can be found at the data base http://calib.org/marine/.

Description: We would like to thank Jeremy Oakley and Richard Bintanja for informative discussions during the development of this work. T.J. Heaton is supported by a Leverhulme Trust Fellowship RF-2019-140\9, “Improving the Measurement of Time Using Radiocarbon”. M Butzin is supported by the German Federal Ministry of Education and Research (BMBF), as Research for Sustainability initiative (FONA); www.fona.de through the PalMod project (grant numbers: 01LP1505B, 01LP1919A). E. Bard is supported by EQUIPEX ASTER-CEREGE and ANR CARBOTRYDH. Meetings of the IntCal Marine Focus group have been supported by Collège de France. Data are available on the PANGAEA database at doi:10.159/ANGAEA.914500.

Description: © The Author(s), 2021. This article is distributed under the terms of the Creative Commons Attribution License. The definitive version was published in [Schiller, C. M., Whitlock, C., Elder, K. L., Iverson, N. A., & Abbott, M. B. Erroneously old radiocarbon ages from terrestrial pollen concentrates in Yellowstone Lake, Wyoming, USA. Radiocarbon, 63(1), (2021): 321-342, https://doi.org/10.1017/RDC.2020.118.

Description: Accelerator mass spectrometry (AMS) dating of pollen concentrates is often used in lake sediment records where large, terrestrial plant remains are unavailable. Ages produced from chemically concentrated pollen as well as manually picked Pinaceae grains in Yellowstone Lake (Wyoming) sediments were consistently 1700–4300 cal years older than ages established by terrestrial plant remains, tephrochronology, and the age of the sediment-water interface. Previous studies have successfully utilized the same laboratory space and methods, suggesting the source of old-carbon contamination is specific to these samples. Manually picking pollen grains precludes admixture of non-pollen materials. Furthermore, no clear source of old pollen grains occurs on the deglaciated landscape, making reworking of old pollen grains unlikely. High volumes of CO2 are degassed in the Yellowstone Caldera, potentially introducing old carbon to pollen. While uptake of old CO2 through photosynthesis is minor (F14C approximately 0.99), old-carbon contamination may still take place in the water column or in surficial lake sediments. It remains unclear, however, what mechanism allows for the erroneous ages of highly refractory pollen grains while terrestrial plant remains were unaffected. In the absence of a satisfactory explanation for erroneously old radiocarbon ages from pollen concentrates, we propose steps for further study.

Description: This research was supported by NSF Grant No. 1515353 to C. Whitlock and sampling in Yellowstone National Park was conducted under permits YELL-SCI-0009 and YELL-SCI-5054.

Description: © The Author(s), 2019. This article is distributed under the terms of the Creative Commons Attribution License. The definitive version was published in Roberts, Mark L., Elder, Kathryn L., Jenkins, William J., Gagnon, Alan R., Xu, Li, Hlavenka, Joshua D., & Longworth, Brett E. C-14 Blank Corrections for 25-100 mu G samples at the National Ocean Sciences AMS Laboratory. Radiocarbon, 61(5), (2019): 1403-1411, Doi: 10.1017/RDC.2019.74.

Description: Replicate radiocarbon (14C) measurements of organic and inorganic control samples, with known Fraction Modern values in the range Fm = 0–1.5 and mass range 6 μg–2 mg carbon, are used to determine both the mass and radiocarbon content of the blank carbon introduced during sample processing and measurement in our laboratory. These data are used to model, separately for organic and inorganic samples, the blank contribution and subsequently “blank correct” measured unknowns in the mass range 25–100 μg. Data, formulas, and an assessment of the precision and accuracy of the blank correction are presented.

Description: This work is supported by a Cooperative Agreement (OCE-1755125) with the U.S. National Science Foundation.

Description: © The Author(s), 2019. This article is distributed under the terms of the Creative Commons Attribution License. The definitive version was published in Baker, M. G., Aster, R. C., Anthony, R. E., Chaput, J., Wiens, D. A., Nyblade, A., Bromirski, P. D., Gerstoft, P., & Stephen, R. A. Seasonal and spatial variations in the ocean-coupled ambient wavefield of the Ross Ice Shelf. Journal of Glaciology, 65(254), (2019): 912-925, doi:10.1017/jog.2019.64.

Description: The Ross Ice Shelf (RIS) is host to a broadband, multimode seismic wavefield that is excited in response to atmospheric, oceanic and solid Earth source processes. A 34-station broadband seismographic network installed on the RIS from late 2014 through early 2017 produced continuous vibrational observations of Earth's largest ice shelf at both floating and grounded locations. We characterize temporal and spatial variations in broadband ambient wavefield power, with a focus on period bands associated with primary (10–20 s) and secondary (5–10 s) microseism signals, and an oceanic source process near the ice front (0.4–4.0 s). Horizontal component signals on floating stations overwhelmingly reflect oceanic excitations year-round due to near-complete isolation from solid Earth shear waves. The spectrum at all periods is shown to be strongly modulated by the concentration of sea ice near the ice shelf front. Contiguous and extensive sea ice damps ocean wave coupling sufficiently so that wintertime background levels can approach or surpass those of land-sited stations in Antarctica.

Description: This research was supported by NSF grants PLR-1142518, 1141916, 1142126, 1246151 and 1246416. JC was additionally supported by Yates funds in the Colorado State University Department of Mathematics. PDB also received support from the California Department of Parks and Recreation, Division of Boating and Waterways under contract 11-106-107. We thank Reinhard Flick and Patrick Shore for their support during field work, Tom Bolmer in locating stations and preparing maps, and the US Antarctic Program for logistical support. The seismic instruments were provided by the Incorporated Research Institutions for Seismology (IRIS) through the PASSCAL Instrument Center at New Mexico Tech. Data collected are available through the IRIS Data Management Center under RIS and DRIS network code XH. The PSD-PDFs presented in this study were processed with the IRIS Noise Tool Kit (Bahavar and others, 2013). The facilities of the IRIS Consortium are supported by the National Science Foundation under Cooperative Agreement EAR-1261681 and the DOE National Nuclear Security Administration. The authors appreciate the support of the University of Wisconsin-Madison Automatic Weather Station Program for the data set, data display and information; funded under NSF grant number ANT-1543305. The Ross Ice Shelf profiles were generated using the Antarctic Mapping Tools (Greene and others, 2017). Regional maps were generated with the Generic Mapping Tools (Wessel and Smith, 1998). Topography and bathymetry data for all maps in this study were sourced from the National Geophysical Data Center ETOPO1 Global Relief Model (doi:10.7289/V5C8276M). We thank two anonymous reviewers for suggestions on the scope and organization of this paper.

Description: © The Author(s), 2022. This article is distributed under the terms of the Creative Commons Attribution License. The definitive version was published in Xu, L., Roberts, M., Elder, K., Hansman, R., Gagnon, A., & Kurz, M. Radiocarbon in dissolved organic carbon by UV oxidation: an update of procedures and blank characterization at NOSAMS. Radiocarbon, 64(1), (2022): 195-199, https://doi.org/10.1017/rdc.2022.4.

Description: This note describes improvements of UV oxidation method that is used to measure carbon isotopes of dissolved organic carbon (DOC) at the National Ocean Sciences Accelerator Mass Spectrometry Facility (NOSAMS). The procedural blank is reduced to 2.6 ± 0.6 μg C, with Fm of 0.42 ± 0.10 and δ13C of –28.43 ± 1.19‰. The throughput is improved from one sample per day to two samples per day.

Description: We gratefully acknowledge support from the U.S. National Science Foundation, via NSF-OCE-1755125.

Description: © The Author(s), 2020. This article is distributed under the terms of the Creative Commons Attribution License. The definitive version was published in Ackley, S. F., Stammerjohn, S., Maksym, T., Smith, M., Cassano, J., Guest, P., Tison, J., Delille, B., Loose, B., Sedwick, P., DePace, L., Roach, L., & Parno, J. Sea-ice production and air/ice/ocean/biogeochemistry interactions in the Ross Sea during the PIPERS 2017 autumn field campaign. Annals of Glaciology, 61(82), (2020): 181-195, doi:10.1017/aog.2020.31.

Description: The Ross Sea is known for showing the greatest sea-ice increase, as observed globally, particularly from 1979 to 2015. However, corresponding changes in sea-ice thickness and production in the Ross Sea are not known, nor how these changes have impacted water masses, carbon fluxes, biogeochemical processes and availability of micronutrients. The PIPERS project sought to address these questions during an autumn ship campaign in 2017 and two spring airborne campaigns in 2016 and 2017. PIPERS used a multidisciplinary approach of manned and autonomous platforms to study the coupled air/ice/ocean/biogeochemical interactions during autumn and related those to spring conditions. Unexpectedly, the Ross Sea experienced record low sea ice in spring 2016 and autumn 2017. The delayed ice advance in 2017 contributed to (1) increased ice production and export in coastal polynyas, (2) thinner snow and ice cover in the central pack, (3) lower sea-ice Chl-a burdens and differences in sympagic communities, (4) sustained ocean heat flux delaying ice thickening and (5) a melting, anomalously southward ice edge persisting into winter. Despite these impacts, airborne observations in spring 2017 suggest that winter ice production over the continental shelf was likely not anomalous.

Description: NSF supported PIPERS award numbers: ANT-1341717 (S.F. Ackley, UTSA); ANT-1341513 (E. Maksym, WHOI); ANT-1341606 (S. Stammerjohn and J. Cassano, U Colorado); ANT-1341725 (P. Guest, NPS). P. Sedwick was supported by NSF ANT-1543483. S.F. Ackley was also supported by NASA Grant 80NSSC19M0194 to the Center for Advanced Measurements in Extreme Environments at UTSA. S. Stammerjohn was also supported by the LTER Program under NFS award number ANT-0823101 (H. Ducklow, LDEO/Columbia University). Additional support was by the Belgian F.R.S-FNRS (project ISOGGAP and IODIne, contract T.0268.16 and J.0262.17, respectively). Bruno Delille is a research associate of the F.R.S.-FNRS. Terra-Sar-X quicklook imagery was coordinated by Kathrin Hoeppner at DLR, and Andy Archer (with the Antarctic Support Contractor) provided selected (cloud-free) MODIS scenes and daily maps of AMSR2 sea-ice concentration.