ALBERT

Description: The Labrador Sea is important for the modern global thermohaline circulation system through the formation of intermediate Labrador Sea Water (LSW) that has been hypothesized to stabilize the modern mode of North Atlantic deep-water circulation. The rate of LSW formation is controlled by the amount of winter heat loss to the atmosphere, the expanse of freshwater in the convection region and the inflow of saline waters from the Atlantic. The Labrador Sea, today, receives freshwater through the East and West Greenland Currents (EGC, WGC) and the Labrador Current (LC). Several studies have suggested the WGC to be the main supplier of freshwater to the Labrador Sea, but the role of the southward flowing LC in Labrador Sea convection is still debated. At the same time, many paleoceanographic reconstructions from the Labrador Shelf focussed on late Deglacial to early Holocene meltwater run-off from the Laurentide Ice Sheet (LIS), whereas little information exists about LC variability since the final melting of the LIS about 7,000 years ago. In order to enable better assessment of the role of the LC in deep-water formation and its importance for Holocene climate variability in Atlantic Canada, this study presents high-resolution middle to late Holocene records of sea surface and bottom water temperatures, freshening and sea ice cover on the Labrador Shelf during the last 6,000 years. Our records reveal that the LC underwent three major oceanographic phases from the Mid- to Late Holocene. From 6.2 to 5.6 ka BP, the LC experienced a cold episode that was followed by warmer conditions between 5.6 and 2.1 ka BP, possibly associated with the late Holocene Thermal Maximum. Although surface waters on the Labrador Shelf cooled gradually after 3 ka BP in response to the Neoglaciation, Labrador Shelf subsurface/bottom waters show a shift to warmer temperatures after 2.1 ka BP. Although such an inverse stratification by cooling of surface and warming of subsurface waters on the Labrador Shelf would suggest a diminished convection during the last two millennia compared to the mid-Holocene, it remains difficult to assess whether hydrographic conditions in the LC have had a significant impact on Labrador Sea deep-water formation.

Description: We analysed: 1. TOC and CNS contents on sediment core PS69/274-1 and calculated the C/N-ratio and carbonate content of the individual sample depths. 2. a specific biomarker lipid called IPSO25 in sediment core PS69/274-1 from the western Amundsen Sea continental shelf, Antarctica, alongside a phytoplankton biomarker (dinosterol) for reconstructing palaeo-sea ice coverage. We further applied the PIPSO25 approach for semi-quantitative sea ice reconstructions. We analysed a specific biomarker lipid called IPSO25 in sediment core PS69/274-1 from the western Amundsen Sea continental shelf, Antarctica, alongside a phytoplankton biomarker (dinosterol) for reconstructing palaeo sea-ice coverage. We further applied the PIPSO25 approach for semi-quantitative sea-ice reconstructions.

Description: The Indian Monsoon and the westerlies strongly influence the sedimentation in the northeastern Arabian Sea by impacting rainfall and erosion on land and on biogeochemical processes in the ocean. To disentangle the terrestrial and oceanic processes, we analysed mineralogical and bulk geochemical components of a Holocene sediment core offshore Pakistan. Endmember modelling of grain sizes and principal component analyses (PCA) of major and trace elements identify the origin of sediments and their dominant mode of transport. Sedimentation processes during the early Holocene (10.8–8.2 ka BP) were influenced by the post-glacial sea level rise and orbitally forced strengthening of the Indian summer monsoon (ISM) and westerlies. This led to a shift from rather terrestrial-dominated towards a marine-dominated sedimentation, whereas the fluvial source shifted from the Makran rivers to the Hab River near Karachi. During the mid-Holocene (8.2–4.2 ka BP) a combination of weakening ISM and southward displacement of the ITCZ enhanced the influence of the westerlies, together decreasing river discharges and enhancing aeolian input (probably from the Sistan Basin region). This trend continued during the last ca. 4 ka when the increasing aridification of the Hab River catchment further increased the aeolian inputs. Solar and lunar driven short-term variations as well as Bond events known from the North Atlantic Ocean superpose these trends. They lead to a pronounced increase of fluvial inputs between 8.6–8.4 ka BP and at ca. 3 ka BP as well as to dry events around 4.2 ka and 1.2–1 ka BP. Our study highlights the increasing influence of the westerlies on the sedimentation processes in the northeastern Arabian Sea towards the late Holocene.

Description: The Benguela Upwelling System (BUS) is the most productive of all eastern boundary upwelling ecosystems and it hosts a well-developed oxygen minimum zone. As such, the BUS is a potential hotspot for production of N2O, a potent greenhouse gas derived from microbially driven decay of sinking organic matter. Yet, the extent at which near-surface waters emit N2O to the atmosphere in the BUS is highly uncertain. Here we present the first high-resolution surface measurements of N2O across the northern part of the BUS (nBUS).We found strong gradients with a threefold increase in N2O concentrations near the coast as compared with open ocean waters. Our observations show enhanced sea-to-air fluxes of N2O (up to 1.67 nmol m−2 s−1) in association with local upwelling cells. Based on our data we suggest that the nBUS can account for 13% of the total coastal upwelling source of N2O to the atmosphere

Description: Marine heat flow data, sampled by a 22-channel violin bow probe offshore Japan in 2016. Data are unfiltered, that is, they are measured field data, not necessarily refecting geothermal heat flux. The data are correct in a technical way but they are influenced by mud volcanism, gas hydrates and bottom water currents.

Description: Gravitational sinking of photosynthetically fixed particulate organic carbon (POC) constitutes a key component of the biological carbon pump. The fraction of POC leaving the surface ocean depends on POC sinking velocity (SV) and remineralization rate (Cremin), both of which depend on plankton community structure. However, the key drivers in plankton communities controlling SV and Cremin are poorly constrained. In fall 2014, we conducted a 6 weeks mesocosm experiment in the subtropical NE Atlantic Ocean to study the influence of plankton community structure on SV and Cremin. Oligotrophic conditions prevailed for the first 3 weeks, until nutrient‐rich deep water injected into all mesocosms stimulated diatom blooms. SV declined steadily over the course of the experiment due to decreasing CaCO3 ballast and – according to an optical proxy proposed herein – due to increasing aggregate porosity mostly during an aggregation event after the diatom bloom. Furthermore, SV was positively correlated with the contribution of picophytoplankton to the total phytoplankton biomass. Cremin was highest during a Synechococcus bloom under oligotrophic conditions and in some mesocosms during the diatom bloom after the deep‐water addition while it was particularly low during harmful algal blooms. The temporal changes were considerably larger in Cremin (max. 15‐fold) than in SV (max. 3‐fold). Accordingly, estimated POC transfer efficiency to 1000 m was mainly dependent on how the plankton community structure affected Cremin. Our approach revealed key players and interactions in the plankton food web influencing POC export efficiency thereby improving our mechanistic understanding of the biological carbon pump.

Description: The western tropical Atlantic (WTA) supplies warm and saline waters to the upper-limb of the Atlantic Meridional Overturning Circulation (AMOC) and may store excess heat and salinity during periods of AMOC slowdown. Since previous sea surface temperature (SST) reconstructions from the WTA typically focus on the Last Glacial Maximum and the last deglaciation, additional long-term records spanning several glacial-interglacial transitions are needed in order to elucidate the drivers of long-term WTA SST variability. We performed stable isotope and Mg/Ca analyses on the surface-dwelling planktonic foraminifera Globigerinoides ruber(pink) on a sediment core from the southern WTA to reconstruct surface-ocean changes over the past 322 kyr. We evaluate the relative importance of atmospheric pCO2 concentration, AMOC strength, and trade-wind intensity in driving the thermal evolution of the WTA across multiple glacial-interglacial cycles. Our SST record indicates that CO2 is the primary driver of glacial-interglacial SST variations in the southern WTA, however, its influence was strongly diminished during Marine Isotope Stage 6. A relatively stable cross-equatorial heat distribution over the past 322 kyr suggests that glacial-interglacial variations in AMOC strength did not drive past WTA SST changes at these timescales. The zonal SST contrast within the (sub)tropical South Atlantic displayed a clear glacial-interglacial mode of variability, which we attribute to low-frequency fluctuations in the strength of the southeast trade winds. Based on these findings, we hypothesize that increasing the concentration of greenhouse gases derived from anthropogenic activities may cause the southern WTA to become warmer and thermally homogenous, which may subsequently impact continental moisture-availability over tropical South America.

Description: The Surface Ocean CO2 Atlas (SOCAT) is a synthesis activity by the international marine carbon research community (〉100 contributors). SOCATv2019 has 25.7 million quality-controlled, surface ocean fCO2 (fugacity of carbon dioxide) observations from 1957 to 2019 for the global oceans and coastal seas. Calibrated sensor data are also available. Automation allows annual, public releases. SOCAT data is discoverable, accessible and citable. SOCAT enables quantification of the ocean carbon sink and ocean acidification and evaluation of ocean biogeochemical models. SOCAT represents a milestone in biogeochemical and climate research and in informing policy. This publication contains the individual cruise files that are new or updated from SOCATv6, with cruise QC flags A-E and all fCO2 WOCE flags. The synthesis file hosted in NOAA NCEI (see other version) contains A-D cruises and WOCE flag 2 (good) data. To download the SOCATv2019 data product in other formats or subsets, please go to www.socat.info.

Description: This data set contains unpublished measurements of the maximum diameter of shells of the planktic foraminifer Neogloboquadrina pachyderma sin. carried out on surface sediment samples from the Norwegian-Greenland Sea.

Description: Butanetriol and pentanetriol dialkyl glycerol tetraethers (BDGTs and PDGTs) are membrane lipids recently discovered in sedimentary environments and in the methanogenic archaeon Methanomassiliicoccus luminyensis. They possess an unusual structure, which challenges fundamental assumptions in lipid biochemistry. Indeed, they bear a butanetriol or a pentanetriol backbone instead of a glycerol at one end of their core structure. In this study, we unambiguously located the additional methyl group of the BDGT compound on the C3 carbon of the lipid backbone via high-field two-dimensional NMR experiments. We further systematically explored the abundance, distribution and isotopic composition of BDGTs and PDGTs as both intact polar and core lipid forms in marine sediments collected in contrasting environments of the Mediterranean Sea and Black Sea. In addition, relatively 13C-depleted BDGTs from the Rhone delta and from the Black Sea are in agreement with a probable methanogenic source for these lipids. In line with this interpretation, high proportions of intact polar BDGTs and PDGTs were detected in the deeper methane-laden sedimentary layers. However, relatively 13C enriched BDGTs and contrasting headgroup distribution patterns of BDGTs and PDGTs in sediments of the Eastern Mediterranean Sea imply that additional archaeal groups also produce these unique lipids.