ALBERT

Beschreibung: A. R. McInroy, A. Uhl, T. Lear, T. M. Klapotke, S. Shaikhutdinov et al. A series of five alumina-supported palladium catalysts have previously been prepared and characterised by a combination of CO chemisorption and infrared spectroscopy. The reactive attributes of these catalysts are examined using the hydrogenation of crotonaldehyde as a test reaction, using a modifie ... [J. Chem. Phys. 134, 214704 (2011)] published Tue Jun 7, 2011.

Beschreibung: Kinematics of a mass movement constrained by sparse and inhomogeneous data Natural Hazards and Earth System Science, 11, 1609-1618, 2011 Author(s): M. Karbon, E. Brückl, E. Hegedüs, and A. Preh On 12 February 2008, a landslide occurred along a 50 m high bank of the Danube river near Dunaszekcsö, Hungary. The initial state is only incompletely documented and the geodetic data acquired after the mass movement are sparse. A generalized 3-D topographic model of the landslide and its surrounding area was assembled and a representative longitudinal profile extracted. The reconstruction of the original surface is based on an orthophoto as well as on morphological considerations. Recorded observations include the locations of the outcrops of basal sliding surfaces, displacements at the main scarp and in the lower part of the slide, and a value to describe the total mass transport. Such sparse and inhomogeneous data were insufficient to derive a comprehensive documentation of the landslide or obtain adequate constraints for an accurate numerical analysis. Therefore, slider block models were fitted to the field data, which have only a small number of free parameters. A general view on the morphology of the mass movement justifies its classification as a rotational slide. A double slider block model fits all observational parameters within their error margin and supplies valuable information on the geometry of the slide. Estimates of the residual friction angles were derived and the question of reactivation was addressed. Finite Difference (FD) modelling and the application of conventional stability analysis support the geometry of the slider blocks and the computed average residual friction angles. Generally, the results are assumed to represent preliminary information, which could only be attained by the combination of the thinly distributed geodetic data with qualitative morphological observations and the implementation of a model. This type of information can be gained quickly and may be valuable for preliminary hazard mitigation measures or the planning of a comprehensive exploration and monitoring program.

Beschreibung: Impact of changes in grain size and pore space on the hydraulic conductivity and spectral induced polarization response of sand Hydrology and Earth System Sciences, 15, 1785-1794, 2011 Author(s): K. Koch, A. Kemna, J. Irving, and K. Holliger Understanding the influence of pore space characteristics on the hydraulic conductivity and spectral induced polarization (SIP) response is critical for establishing relationships between the electrical and hydrological properties of surficial unconsolidated sedimentary deposits, which host the bulk of the world's readily accessible groundwater resources. Here, we present the results of laboratory SIP measurements on industrial-grade, saturated quartz samples with granulometric characteristics ranging from fine sand to fine gravel. We altered the pore space characteristics by changing (i) the grain size spectra, (ii) the degree of compaction, and (iii) the level of sorting. We then examined how these changes affect the SIP response, the hydraulic conductivity, and the specific surface area of the considered samples. In general, the results indicate a clear connection between the SIP response and the granulometric as well as pore space characteristics. In particular, we observe a systematic correlation between the hydraulic conductivity and the relaxation time of the Cole-Cole model describing the observed SIP effect for the entire range of considered grain sizes. The results do, however, also indicate that the detailed nature of these relations depends strongly on variations in the pore space characteristics, such as, for example, the degree of compaction. This underlines the complexity of the origin of the SIP signal as well as the difficulty to relate it to a single structural factor of a studied sample, and hence raises some fundamental questions with regard to the practical use of SIP measurements as site- and/or sample-independent predictors of the hydraulic conductivity.

Beschreibung: Publication year: 2011 Source: Quaternary Research, In Press, Corrected Proof, Available online 8 June 2011 David J., Mallinson , Curtis W., Smith , Shannon, Mahan , Stephen J., Culver , Katie, McDowell The Outer Banks barrier islands of North Carolina, USA, contain a geologic record of inlet activity that extends from ca. 2200calyr BP to the present, and can be used as a proxy for storm activity. Optically stimulated luminescence (OSL) dating (26 samples) of inlet-fill and flood tide delta deposits, recognized in cores and geophysical data, provides the basis for understanding the chronology of storm impacts and comparison to other paleoclimate proxy data. OSL ages of historical inlet fill compare favorably to historical documentation of inlet activity, providing confidence in the technique. Comparison suggests that the Medieval Warm Period (MWP) and...

Beschreibung: WRF simulation of a precipitation event over the Tibetan Plateau, China – an assessment using remote sensing and ground observations Hydrology and Earth System Sciences, 15, 1795-1817, 2011 Author(s): F. Maussion, D. Scherer, R. Finkelnburg, J. Richters, W. Yang, and T. Yao Meteorological observations over the Tibetan Plateau (TiP) are scarce, and precipitation estimations over this remote region are difficult. The constantly improving capabilities of numerical weather prediction (NWP) models offer the opportunity to reduce this problem by providing precipitation fields and other meteorological variables of high spatial and temporal resolution. Longer time periods of years to decades can be simulated by NWP models by successive model runs of shorter periods, which can be described by the term "regional atmospheric reanalysis". In this paper, we assess the Weather Research and Forecasting (WRF) models capacity in retrieving rain- and snowfall on the TiP in such a configuration using a nested approach: the simulations are conducted with three nested domains at spatial resolutions of 30, 10, and 2 km. A validation study is carried out for a one-month period with a special focus on one-week (22–28 October 2008), during which strong rain- and snowfall was observed on the TiP. The output of the model in each resolution is compared to the Tropical Rainfall Measuring Mission (TRMM) data set for precipitation and to the Moderate Resolution Imaging Spectroradiometer (MODIS) data set for snow extent. TRMM and WRF data are then compared to weather-station measurements. Our results suggest an overall improvement from WRF over TRMM with respect to weather-station measurements. Various configurations of the model with different nesting and forcing strategies, as well as physical parameterisation schemes are compared to propose a suitable design for a regional atmospheric reanalysis over the TiP. The WRF model showed good accuracy in simulating snow- and rainfall on the TiP for a one-month simulation period. Our study reveals that there is nothing like an optimal model strategy applicable for the high-altitude TiP, its fringing high-mountain areas of extremely complex topography and the low-altitude land and sea regions from which much of the precipitation on the TiP is originating. The choice of the physical parameterisation scheme will thus be always a compromise depending on the specific purpose of a model simulation. Our study demonstrates the high importance of orographic precipitation, but the problem of the orographic bias remains unsolved since reliable observational data are still missing. The results are relevant for anyone interested in carrying out a regional atmospheric reanalysis. Many hydrological analyses and applications like rainfall-runoff modelling or the analysis of flood events require precipitation rates at daily or even hourly intervals. Thus, our study offers a process-oriented alternative for retrieving precipitation fields of high spatio-temporal resolution in regions like the TiP, where other data sources are limited.

Beschreibung: Daeyul Baek, Hirokazu Hasegawa, and Yasuhiro Ohshima We experimentally investigate the nonadiabatic rotational excitation process of a symmetric-top molecule, benzene, in the electronic ground state irradiated by intense nonresonant ultrafast laser fields. The initial rotational-state distribution was restricted mostly to the five lowest levels with d ... [J. Chem. Phys. 134, 224302 (2011)] published Fri Jun 10, 2011.

Beschreibung: T. Suemoto, H. Nakao, M. Nakajima, and H. Kitagawa The out-of-phase and in-phase ladder type Br-bridged Pt complexes are investigated by time-resolved luminescence spectroscopy in pico- and femtosecond time regions. The observed luminescence spectra have peaks at 0.87 and 0.94 eV in out-of-phase and in-phase materials, respectively, and are assigned ... [J. Chem. Phys. 134, 224503 (2011)] published Fri Jun 10, 2011.

Beschreibung: Francesco A. Evangelista We report a general implementation of alternative formulations of single-reference coupled cluster theory (extended, unitary, and variational) with arbitrary-order truncation of the cluster operator. These methods are applied to compute the energy of Ne and the equilibrium properties of HF and C. Po ... [J. Chem. Phys. 134, 224102 (2011)] published Fri Jun 10, 2011.

Beschreibung: Prabir K. Mukherjee A model for coupled tilt angle and lattice distortion parameter is proposed to describe the R R transition in n-alkane. The model is treated in the framework of a Landau mean-field theory and renormalization-group theory. The influence of gauche conformations and molecular flexibility on the R R t ... [J. Chem. Phys. 134, 224502 (2011)] published Fri Jun 10, 2011.