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  • 04. Solid Earth::04.04. Geology::04.04.12. Fluid Geochemistry  (7)
  • 04. Solid Earth::04.08. Volcanology::04.08.05. Volcanic rocks  (5)
  • Elsevier  (12)
  • Essen : Verl. Glückauf
  • Krefeld : Geologischer Dienst Nordhein-Westfalen
  • Oxford University Press
  • Springer-Verlag
  • 2005-2009  (12)
  • 2009  (12)
Collection
Publisher
Years
  • 2005-2009  (12)
Year
  • 1
    Publication Date: 2021-06-15
    Description: Public works in progress in the Campanian plain north of Somma-Vesuvius recently encountered the remains of a prehistoric settlement close to the town of Afragola. Rescue excavations brought to light a Bronze Age village partially destroyed and buried by pyroclastic density currents (PDCs) of the Vesuvian Pomici di Avellino eruption (3.8 14C ka BP) and subsequently sealed by alluvial deposits. Volcanological and rockmagnetic investigations supplemented the excavations. Careful comparison between volcanological and archaeological stratigraphies led to an understanding of the timing of the damage the buildings suffered when they were struck by a series of PDCs. The first engulfed the village, located some 14 km to the north of the inferred vent, and penetrated into the dwellings without causing major damage. The buildings were able to withstand the weak dynamic pressure of the currents and deviate their path, as shown by the magnetic fabric analyses. Some later collapsed under the load of the deposits piled up by successive currents. Stepwise demagnetization of the thermal remanent magnetization (TRM) carried by potsherds embedded in the deposits yields deposition temperatures in the order of 260– 320 °C, fully consistent with those derived from pottery and lithic fragments from other distal and proximal sites. The fairly uniform temperature of the deposits is here ascribed to the lack of pervasive air entrainment into the currents. This, in turn, resulted from the lack of major topographical obstacles along the flat plain. The coupling of structural damage and sedimentological analyses indicates that the currents were not destructive in the Afragola area, but TRM data indicate they were still hot enough to cause death or severe injury to humans and animals. The successful escape of the entire population is apparent from the lack of human remains and from thousands of human footprints on the surface of the deposits left by the first PDCs. People were thus able to walk barefoot across the already emplaced deposits and escape the subsequent PDCs. The rapid cooling of the deposits was probably due to both their thinness and heat dissipation due to condensation of water vapour released in the mixture by magma–water interaction.
    Description: Published
    Description: 408–421
    Description: 2.3. TTC - Laboratori di chimica e fisica delle rocce
    Description: 3.5. Geologia e storia dei vulcani ed evoluzione dei magmi
    Description: 3.6. Fisica del vulcanismo
    Description: JCR Journal
    Description: reserved
    Keywords: pyroclastic density current ; Bronze Age ; magnetic fabric ; deposition temperature ; 04. Solid Earth::04.04. Geology::04.04.10. Stratigraphy ; 04. Solid Earth::04.05. Geomagnetism::04.05.07. Rock magnetism ; 04. Solid Earth::04.08. Volcanology::04.08.05. Volcanic rocks
    Repository Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
    Type: article
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  • 2
    Publication Date: 2021-06-25
    Description: We present the first helium isotope data for thermal waters and gas emissions on the islands of Terceira, Graciosa, Faial, Pico and Flores, as well as new data for Sao Miguel. The results allow us to track current mantle degassing associated with the Azores hot spot, to delineate its spatial distribution and to discuss its possible origin. As a general rule, we find that free gases tend to display somewhat higher 3He/4He ratio than groundwaters.We argue that this difference is likely due to radiogenic helium inputs to aquifers duringwater– rock interactions and, therefore, that gas phases are the fluid carriers with the most representative of mantle source signature. The measured 3He/4He ratios (normalized to the air ratio, Ra) range from lower-than-MORB values (5.23–6.07 Ra) on central Sao Miguel, to MORB values on Faial (8.53 Ra) and Flores (8.04 Ra) – located on either side of the Mid-Atlantic Ridge – and to plume-type values on Graciosa (11.2 Ra) and Terceira (13.5 Ra) where free gases also display ten times higher-than-MORB CO2/3He ratios (1.8–2.6×1010). Such a wide He isotopic range and its spatial distribution corroborate with available data for volcanic rocks, indicating that plume's head presently underlies the central part of the archipelago. The plume-type 3He/4He ratios on Terceira and Graciosa agree with geochemical and seismic evidence of a deep-rooted mantle plume feeding the Azores hot spot. Our finding that high 3He/4He ratios correspond to low 3He concentrations and high (arctype) CO2/3He values exclude a simple plume supply of 3He-rich primitive mantle. Instead, the simultaneity of both elevated CO2/3He and 3He/4He ratios is best explained by a 3He-rich contribution from the lower mantle diluted in a CO2-rich feeding plume that contains a recycled altered oceanic plate component. The alternative possibility of an enhanced time-integrated 3He/(U+Th) ratio in the Azores plume due to a greater compatibility of helium relative to U and Th during melting events is difficult to reconcile with the enriched pattern of volcanic rocks from the central islands. In any case, the Azores plume should derive from a mantle reservoir that could escape convective homogenization for a very long period of time, in agreement with subchondritic osmium isotopic ratios in volcanic rocks from the central islands of the archipelago.
    Description: Published
    Description: 70−80
    Description: 1.2. TTC - Sorveglianza geochimica delle aree vulcaniche attive
    Description: JCR Journal
    Description: reserved
    Keywords: hydrothemal fluids ; helium isotopes ; 04. Solid Earth::04.04. Geology::04.04.12. Fluid Geochemistry
    Repository Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
    Type: article
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  • 3
    Publication Date: 2017-04-04
    Description: Quantifying the contribution of volcanism to global mercury (Hg) emissions is important to understand the pathways and the mechanisms of Hg cycling through the Earth's geochemical reservoirs and to assess its environmental impacts. While previous studies have suggested that degassing volcanoes might contribute importantly to the atmospheric budget of mercury, little is known about the amount and behaviour of Hg in volcanic aquifers. Here we report on detailed investigations of both the content and the speciation of mercury in aquifers of active volcanoes in Italy and Guadeloupe Island (Lesser Antilles). In the studied groundwaters, total Hg (THg) concentrations range from 10 to 500 ng/l and are lower than the 1000 ng/l threshold value for human health protection fixed by the World Health Organization [WHO (1993): WHO Guidelines for Drinking Water Quality- http://www.who.int/water_sanitation_health/GDWQ/index.htlm]. Positive co-variations of (THg) with sulphate indicate that Hg-SO4-rich acid groundwaters receive a direct input of magmatic/hydrothermal gases carrying mercury as Hg0 (gas). Increasing THg in a volcanic aquifer could thus be a sensitive tracer of magmatic gas input prior to an eruption. Since the complex behaviour and toxicity of mercury in waters depend on its chemical speciation, we carefully determined the different aqueous forms of this element in our samples.We find that dissolved elemental Hg0 (aq) and particulate-bound Hg (HgP) widely prevail in volcanic aquifers, in proportions that highlight the efficiency of Hg adsorption onto colloidal particles. Moreover, we observe that dissolved Hg0 aq and Hg(II) forms coexist in comparable amount in most of the waters, in stark contrast to the results of thermodynamic equilibrium modelling. Therefore, chemical equilibrium between dissolved mercury species in volcanic waters is either prevented by natural kinetic effects or not preserved in collected waters due to sampling/storage artefacts. Finally, we provide a first quantitative comparison of the relative intensity of aqueous transport and atmospheric emissions of mercury at Mount Etna, a very active basaltic volcano.
    Description: Published
    Description: 96-106
    Description: 4.5. Studi sul degassamento naturale e sui gas petroliferi
    Description: JCR Journal
    Description: reserved
    Keywords: speciation ; volcanic aquifers ; total and dissolved mercury ; mercury cycling ; volatile budget ; 04. Solid Earth::04.04. Geology::04.04.12. Fluid Geochemistry
    Repository Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
    Type: article
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  • 4
    Publication Date: 2017-04-04
    Description: On 27 February 2007, at 12.49 GMT, a new eruption of Stromboli took place with the effusion of a lava flow from a fracture cutting the flank of the NE cone, which rapidly reached the sea. The eruption had been heralded by an increase in the amplitude of tremor and flank movement since at least the 14th of February. Short-term precursors were an increase in the rate of occurrence of small landslides within the “Sciara del Fuoco” scar on the North-western flank of the volcano. A new effusive vent opened at 18.30 GMT on the Sciara del Fuoco at an height of 400 m asl. The new lava emission caused the sudden termination of the summit flow and initiated a period of non-stationary lava outpouring which ended on 2 April, 2007. The eruption has been characterized by a rapid decrease in the eruption rate after the first days and subsequently by episodic pulse increases. On the 15th of March, the increase in lava outpouring, monitored by a thermal camera, heralded by 9 min the occurrence of a violent paroxysmal explosion with the formation of an impulsive eruption column and the emission of small pumices mingled with black scoriae. The pumice had a bulk composition similar to that of the lava and of the black scoriae, but with a distinct lower content of phenocrysts. A similar feature has been repeatedly observed during the major explosive paroxysms of Stromboli. Short term precursors of the paroxysm were recorded by strainmeter and tiltmeter stations. The volcano monitoring activity has been made by a joint team of researchers from the INGV sections of Catania, Napoli, Palermo and Rome, along with researchers from the Universities of Florence, Pisa, Roma Tre, and Palermo. The scientific activity was coordinated by a Synthesis Group made up by scientists responsible for the different monitoring techniques of INGV and Universities and by the volcanic experts of Commissione Nazionale Grandi Rischi of the Prime Minister Office (Civil Protection Department). The group made a daily evaluation of the state of the volcano and transmitted its recommendations to the Civil Protection Department (DPC). Several prevention measures were adopted by DPC, the main of which were the evacuation of the coast zone when strong acceleration of the Sciara del Fuoco slope motion (occurred twice) could led to a dangerous tsunami by flank collapse (as last occurred on 30 December 2002) and four days before the 15 March paroxysm when access was prohibited to the part of the volcano above 290 m asl.
    Description: Published
    Description: 123–130
    Description: 2.3. TTC - Laboratori di chimica e fisica delle rocce
    Description: JCR Journal
    Description: reserved
    Keywords: Stromboli volcano ; 2007 eruption ; scientific emergency management ; 04. Solid Earth::04.08. Volcanology::04.08.03. Magmas ; 04. Solid Earth::04.08. Volcanology::04.08.05. Volcanic rocks
    Repository Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
    Type: article
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  • 5
    Publication Date: 2017-04-04
    Description: Dynamic accumulation chamber methods have been extensively used to estimate the total output of CO2 released from active volcanic area. In order to asses the performance and reliability of a closed dynamic system several tests were carried out with different soil permeabilities and soil CO2 fluxes. A special device was used to create a constant one-dimensional CO2 flux through a soil column with a known permeability. Three permeabilities were investigated, ranging between 3.6 × 10− 2 and 3.5 × 10 μm2, as were several CO2 fluxes (ranging between 1.1 × 10− 6 and 6.3 × 10− 5 kg m− 2 s− 1). The results highlight that the accuracy of soil CO2 flux measurements strictly depends on the soil gas permeability and the soil CO2 flux regimen. Generally chamber measurements underestimate CO2 fluxes at low soil permeability and low soil CO2 fluxes, whereas appreciable overestimations occur for high permeability soil, especially for high soil CO2 fluxes. Other tests carried out with different settings for the measurement device, such as the chamber volume and the flux of the pump used to recirculate air through the chamber and the gas analyzer (recirculation flux), revealed a strong dependence of the closed dynamic chamber measurements on the recirculation flux. Low recirculation fluxes (0.2–0.4 l min− 1) decreased the performance of the measurement system, causing underestimations of the actual soil CO2 flux, whereas higher values (0.6–1.0 l min− 1) resulted in overestimations, especially for elevated soil CO2 fluxes. An empirical equation was deduced to allow accumulation chamber fluxes to be calculated very accurately based on soil gas permeabilities measured in the field.
    Description: Published
    Description: 387-393
    Description: 1.2. TTC - Sorveglianza geochimica delle aree vulcaniche attive
    Description: 4.5. Studi sul degassamento naturale e sui gas petroliferi
    Description: JCR Journal
    Description: reserved
    Keywords: Soil CO2 flux measuraments ; Closed dynamic chamber ; soil gas permeability ; 04. Solid Earth::04.02. Exploration geophysics::04.02.01. Geochemical exploration ; 04. Solid Earth::04.04. Geology::04.04.12. Fluid Geochemistry ; 04. Solid Earth::04.08. Volcanology::04.08.01. Gases ; 04. Solid Earth::04.08. Volcanology::04.08.06. Volcano monitoring ; 04. Solid Earth::04.08. Volcanology::04.08.07. Instruments and techniques
    Repository Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
    Type: article
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  • 6
    Publication Date: 2017-04-04
    Description: Major results of post-intrusive GPS monitoring of the five months encompassing and following the onset of 2002-03 Mt. Etna eruption are presented and discussed here. The overall ground deformation pattern is characterized by a time-dependent relaxation function. We evaluated two different parameterizations of relaxation functions, each one linked to a different relaxation process: i) viscoelastic relaxation and ii) after-slip mechanism. The former indicated that the process occurred within a weak layer characterized by viscosity values ranging between 7.1 • 1014 Pa s and 1.3 • 1015 Pa s. The latter evidenced that frictional processes occurred beneath a layer of velocity-strengthening having a thickness with values ranging between 0.4 km and 1.7 km. Either model may explain the observed time-dependent deformation, both from the statistical point of view and the comparison with geologic and seismic information. Although we are unable to favour one model rather than the other, these results indicate that the mechanism, responsible for the observed post-intrusive deformation, occurs within a sliding “zone” located inside the clayey sedimentary basement.
    Description: This study was undertaken with financial support from the FLANK project (DPC-INGV 2008 - 2010 contract)
    Description: Published
    Description: 300-311
    Description: 1.3. TTC - Sorveglianza geodetica delle aree vulcaniche attive
    Description: JCR Journal
    Description: reserved
    Keywords: 2002-03 Mt. Etna eruption ; Post-intrusive relaxation ; Viscoelastic ; After-slip ; Rheology ; 04. Solid Earth::04.08. Volcanology::04.08.05. Volcanic rocks ; 04. Solid Earth::04.08. Volcanology::04.08.06. Volcano monitoring
    Repository Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
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  • 7
    Publication Date: 2017-04-04
    Description: Methane, the most abundant hydrocarbon in the atmosphere, plays an important role in the Earth’s atmospheric chemistry and radiative balance being the second most important greenhouse gas after CO2. Methane is released to the atmosphere by a wide number of sources, both natural and anthropogenic, with the latter being twice as large as the former (Kvenvolden and Rogers, 2005). It has recently been established that significant amounts of geological methane, produced within the Earth’s crust, are currently released naturally into the atmosphere (Etiope, 2004). Among natural sources the volcanic/geothermal emissions are probably the least constrained. Recent estimations for volcanic and geothermal systems in Europe (Etiope et al. 2007) gave a rather large provisional range (4-16 kt/a) that claims for much more field measurements in order to widen the current database and decrease the present uncertainties. Pantelleria is an active volcanic complex, at present in quiescent status, hosting a high enthalpy geothermal system. Explorative geothermal wells tapped an exploitable water-dominated reservoir at 600-800 m depth with maximum measured temperatures of 250 °C. While some data are available on diffuse CO2 fluxes, data on CH4 are available only for fumarolic fluids. In the present study we measured CH4 fluxes in the area of Favara Grande characterized by intense diffuse degassing and widespread signs of geothermal activity (fumaroles, steaming grounds and large zones devoid of vegetation). Values range from negative (-43 to 0 mgCH4 m2 day), typical of soils with methanotrophic activity, up to 3500 mgCH4 m2 day in the most thermalized area. The preliminary estimate of the methane release from the area of Favara Grande is about 2.5 t/a. Extrapolation to the whole volcanic/geothermal system of Pantelleria gives about 10 t/a.
    Description: Published
    Description: Davos, Switzerland
    Description: 1.2. TTC - Sorveglianza geochimica delle aree vulcaniche attive
    Description: 4.5. Studi sul degassamento naturale e sui gas petroliferi
    Description: open
    Keywords: soil gases ; methane output ; 04. Solid Earth::04.04. Geology::04.04.12. Fluid Geochemistry ; 04. Solid Earth::04.08. Volcanology::04.08.01. Gases
    Repository Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
    Type: Poster session
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  • 8
    Publication Date: 2017-04-04
    Description: The island of Vulcano (Aeolian arc, Southern Italy) has displayed several periods of volcanic unrest since the end of the last eruption (1890). We report here results obtained from a long-term survey concerning variations of both the steam output and the exhaling surface area at the sun~mit crater fumarolic field of La Fossa. The field measurements analysed in a Geographiciil Information System (GIS: show a highly dynamic volcanic system in which deep variations in the geochemishy and the temperature of the released fluids were accompanied by fluctuations in the mass output of steam and the topography of the crater field. The use of a GIS facilitated digitized reconstructions of maps of the crater field in addition to analysis (of the steam flux data. The furnarolic field expanded its surface area from 50 m2 in 1983 to more than 2400 m* in 1995, accompanied by an increase in steam output from 152 to about 1400 tonnes per day. The possibility that the observed phenomena are related to volcano-tectonic activity and to magma uprising is taken into consideration.
    Description: Published
    Description: 253-263
    Description: 1.2. TTC - Sorveglianza geochimica delle aree vulcaniche attive
    Description: JCR Journal
    Description: reserved
    Keywords: volcanic surveillance ; Steam output ; tectonic lines ; flux ; 04. Solid Earth::04.04. Geology::04.04.12. Fluid Geochemistry
    Repository Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
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  • 9
    Publication Date: 2017-04-04
    Description: On February 27, 2007 a new eruption started at Stromboli that lasted until April 2 and included a paroxysmal explosion on March 15. Geochemical monitoring carried out over several years revealed some appreciable variations that preceded both the eruption onset and the explosion. The carbon dioxide (CO2) flux from the soil at Pizzo Sopra La Fossa markedly increased a few days before the eruption onset, and continued during lava effusion to reach its maximum value (at 90,000 g m−2 d−1) a few days before the paroxysm. Almost contemporarily, the δ13CCO2 of the SC5 fumarole located in the summit area increased markedly, peaking just before the explosion (δ13CCO2~−1.8‰). Following the paroxysm, helium (He) isotopes measured in the gases dissolved in the basal thermal aquifer sharply increased. Almost contemporarily, the automatic station of CO2 flux recorded an anomalous degassing rate. Also temperatures and the vertical thermal gradient, which had been measured since November 2006 in the soil at Pizzo Sopra La Fossa, showed appreciable variabilities that lasted until the end of the eruption. The geochemical variations indicated the degassing of a new batch of volatile-rich magma that preceded and probably fed the paroxysm. The anomalous 3He/4He ratio suggested that the ascent of a second batch of volatile-rich magma toward the surface was probably responsible of the resumption of the ordinary activity. A comparison with the geochemical variations observed during the 2002–2003 eruption indicated that the 2007 eruption was less energetic.
    Description: Published
    Description: 246-254
    Description: 1.2. TTC - Sorveglianza geochimica delle aree vulcaniche attive
    Description: JCR Journal
    Description: reserved
    Keywords: geochemistry ; eruption ; dissolved gases ; Stromboli ; volcanic activity ; 03. Hydrosphere::03.02. Hydrology::03.02.03. Groundwater processes ; 03. Hydrosphere::03.04. Chemical and biological::03.04.03. Chemistry of waters ; 03. Hydrosphere::03.04. Chemical and biological::03.04.05. Gases ; 03. Hydrosphere::03.04. Chemical and biological::03.04.06. Hydrothermal systems ; 04. Solid Earth::04.04. Geology::04.04.12. Fluid Geochemistry ; 04. Solid Earth::04.08. Volcanology::04.08.01. Gases ; 04. Solid Earth::04.08. Volcanology::04.08.06. Volcano monitoring ; 05. General::05.02. Data dissemination::05.02.01. Geochemical data ; 05. General::05.02. Data dissemination::05.02.03. Volcanic eruptions
    Repository Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
    Type: article
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  • 10
    Publication Date: 2017-04-04
    Description: The Campi Flegrei caldera is an active and restless volcano in the densely inhabited Neapolitan area of southern Italy. Because of the very high value (lives, properties, infrastructures, etc.) exposed to potential volcanic hazards, it is one of the areas at highest volcanic risk on Earth. In such a situation we have made an attempt to contribute to assessment of its volcanic hazards by providing a quantitative probabilistic longterm forecast of style and size of the next eruption. We have evaluated the most relevant physical parameters of the 22 explosive eruptions of the Campi Flegrei caldera over the past 5 ka. This time span has been taken as the reference period for volcanic hazards assessment on the basis of the volcanic and deformation history of the caldera. The evaluated parameters include dispersal, volume and density of the pyroclastic deposits, volume of erupted magma, total erupted mass, and eruption magnitude. The obtained results permit a size classification of the explosive eruptions, which are grouped into three sizes: small, medium, and large. On the basis of the reconstructed eruption dynamics, we have considered a type event(s) representative of each size class and hypothesized the style of the next event. An effusive eruption will likely generate a dome or very small lava flows, while an explosive event of any size very probably will produce particles fallout and flowage of pyroclastic density currents. Using a Bayesian inference procedure, we have assigned a conditional probability of occurrence to each of the eruption size classes. A small-size explosive eruption is the most likely event with a probability of about 60%; a large-size explosive eruption is the least likely event with a probability of about 4%; a medium-size explosive eruption has a probability of occurrence of about 25%; an effusive eruption has about 11% probability of occurrence.
    Description: Published
    Description: 265–276
    Description: 3.5. Geologia e storia dei vulcani ed evoluzione dei magmi
    Description: 4.3. TTC - Scenari di pericolosità vulcanica
    Description: JCR Journal
    Description: reserved
    Keywords: volcanic hazards assessment ; eruption size ; eruption style ; Campi Flegrei caldera ; 04. Solid Earth::04.08. Volcanology::04.08.05. Volcanic rocks ; 04. Solid Earth::04.08. Volcanology::04.08.08. Volcanic risk
    Repository Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
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  • 11
    Publication Date: 2017-04-04
    Description: Chemical and isotopic analyses of the main gas manifestations of the island of Pantelleria (Italy) were used to gain insight on the origin of the released methane. Results indicate that the most probable origin is through abiogenic reactions within the hydrothermal system. Methane and CO2 flux measurements from the soils were made with the accumulation chamber method in an area of about 0.015 km2 within the main fumarolic area of the island (Favara Grande). The 23 measurements range from –34 to 3550 mg m-2 d-1 for CH4 and from 0.6 to 379 g m-2 d-1 for CO2. The relationships between CH4 and CO2 fluxes and the CH4/CO2 ratios in the gases collected between 25 and 100 cm depth provide evidence for methanotrophic processes within the soils. Methane output for the surveyed area was calculated in 2.5 t a-1 and extrapolated to about 5-10 t a-1 for the entire volcanic/hydrothermal system of the island. Previous higher estimates of the CH4 output at Pantelleria (Etiope et al., 2007 - J. Volcanol. Geotherm. Res., 165, 76 – 86) were based on soil CO2 output and CH4/CO2 ratios in fumarolic gases; the present work provides the first direct CH4 flux data and it suggests that methanotrophic activity in the soil could be substantial in reducing the CH4 emission to the atmosphere.
    Description: Published
    Description: 147-157
    Description: 1.2. TTC - Sorveglianza geochimica delle aree vulcaniche attive
    Description: 4.5. Studi sul degassamento naturale e sui gas petroliferi
    Description: JCR Journal
    Description: reserved
    Keywords: hydrothermal systems ; gas geochemistry ; isotope composition ; methane output ; methanotrophic consumption ; 01. Atmosphere::01.01. Atmosphere::01.01.07. Volcanic effects ; 04. Solid Earth::04.04. Geology::04.04.12. Fluid Geochemistry ; 04. Solid Earth::04.08. Volcanology::04.08.01. Gases
    Repository Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
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  • 12
    Publication Date: 2017-04-04
    Description: The Astroni volcano was built through seven eruptions that generated pyroclastic deposits and lava domes within the Campi Flegrei caldera (southern Italy) 4.1–3.8 ka BP. Whole-rock geochemical and B–Sr–Nd isotopic investigations were carried out on representative samples of all seven eruptions. The products vary from tephriphonolites to phonolites, and from latites to trachytes. They show textural, mineralogical and isotopic evidence of disequilibrium, including distinct clinopyroxene populations, rounded and/or resorbed plagioclase and alkali-feldspar, and reverse-zoned phenocrysts of all these mineral phases. The Sr, Nd and B isotopic composition of whole rocks is variable and correlated with the degree of chemical evolution, suggesting open-system processes in addition to fractional crystallisation. Moreover, significant Sr-isotopic disequilibrium between the phenocrysts and glass has been documented for one sample. The chemostratigraphy of the products indicates that Astroni eruptions 1 through 5 were fed by magmas of trachytic to phonolitic composition that were less enriched in radiogenic Sr and 11B up-section. This variability has been interpreted as the result of mingling between at least two distinct magmatic endmembers, one more evolved and the other less evolved. Another heterogeneous batch of magma, resulting from almost complete mixing between the same two end-members, was drained during eruptions 6 and 7. The more evolved end-member, characterised by 87Sr/86Sr≥0.7075, 143Nd/144Nd≤0.51247 and δ11B≥−8‰, was very similar to the magma that fed the final phases of the Agnano–Monte Spina eruption, which occurred a few centuries earlier in the Astroni vent area. The less evolved end-member had 87Sr/ 86Sr≤0.70726, 143Nd/144Nd≥0.51251 and δ11B≤10‰, and was likely derived by fractional crystallisation of a mantle-derived magma. An abrupt decrease in both the Sr isotope ratio and the Th content, detected at the transition between Unit 4 and 5, suggests that another magma with a 87Sr/86Sr ratio intermediate between those of the two identified end-members may have been involved in Astroni activity. The more evolved endmember is interpreted as a residue of the Agnano–Monte Spina eruption that was invaded by either the intermediate or the less evolved magmatic end-member, promoting mingling and triggering Astroni activity. This study of Astroni provides insights for both short- and long-term volcanic hazard assessment, as the Astroni volcano is the best example of a very close sequence of eruptions from the same vent area in the Campi Flegrei caldera.
    Description: Published
    Description: 135–151
    Description: 2.3. TTC - Laboratori di chimica e fisica delle rocce
    Description: 3.5. Geologia e storia dei vulcani ed evoluzione dei magmi
    Description: JCR Journal
    Description: reserved
    Keywords: Campi Flegrei caldera ; B–Sr–Nd isotope geochemistry ; Magma mingling/mixing ; Chemostratigraphy ; 04. Solid Earth::04.08. Volcanology::04.08.03. Magmas ; 04. Solid Earth::04.08. Volcanology::04.08.05. Volcanic rocks
    Repository Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
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