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  • Last Glacial Maximum  (2)
  • 04. Solid Earth::04.08. Volcanology::04.08.01. Gases
  • American Geophysical Union  (3)
  • Annual Reviews
  • 2005-2009  (3)
  • 1990-1994
  • 1985-1989
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  • 1955-1959
  • 2006  (3)
  • 1
    Publication Date: 2017-04-04
    Description: Sulphur speciation in volcanic gases acts as a major redox buffer, and H2S/SO2 ratios represent a valuable indicator of magmatic conditions and interactions between magmatic and hydrothermal fluids. However, measurement of H2S/SO2 even by direct sampling techniques, is not straightforward. We report here on application of a small ultraviolet spectrometer for real-time field measurement of H2S and SO2 concentrations, using open-path and extractive configurations. The device was tested at fumaroles on Solfatara and Vulcano, Italy, in November 2002. H2S concentrations of up to 220ppmm(400 ppmv) were measured directly above the Bocca Grande fumarole at Solfatara, and H2S/SO2 molar ratios of 2 and 2.4, respectively, were determined for the ‘F11’ and ‘F0’ fumaroles at Vulcano. In comparison with other optical techniques capable of multiple volcanic gas measurements, such as laser and FTIR spectroscopy, this approach is considerably simpler and cheaper, with the potential for autonomous, sustained hightime resolution operation.
    Description: Published
    Description: 1652
    Description: partially_open
    Keywords: Remote monitoring ; Plume chemistry ; sulphur species ; 04. Solid Earth::04.08. Volcanology::04.08.01. Gases ; 04. Solid Earth::04.08. Volcanology::04.08.06. Volcano monitoring ; 04. Solid Earth::04.08. Volcanology::04.08.07. Instruments and techniques
    Repository Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
    Type: article
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  • 2
    Publication Date: 2022-05-25
    Description: Author Posting. © American Geophysical Union, 2006. This article is posted here by permission of American Geophysical Union for personal use, not for redistribution. The definitive version was published in Geochemistry Geophysics Geosystems 7 (2006): Q11N07, doi:10.1029/2006GC001383.
    Description: The vertical profile of meridional transport in the South Atlantic is examined by combining paleoceanographic observations with a geostrophic circulation model using an inverse method. δ18Ocalcite observations along the margins of the South Atlantic show that upper-ocean cross-basin differences were weaker during the Last Glacial Maximum (LGM) than the Holocene. The δ18Ocalcite observations can be explained by a shift of water-mass properties without any change in the overturning circulation. Alternatively, they may indicate a reduced LGM cross-basin density difference and, via the thermal wind relation, a reduced vertical shear. Model inversions of δ18Ocalcite are found to require meridional transports different from the modern only after three assumptions are made: temperature and salinity distributions are spatially smooth, the relationship between salinity and δ18Owater is linear and spatially invariant, and LGM temperatures are known to within 1°C along the margins. The last assumption is necessary because an independent constraint on temperature or salinity is required to determine density from δ18Ocalcite observations. δ18Ocalcite observations are clearly useful, but before any firm constraints can be placed on LGM meridional transport, it appears necessary to better determine the relationship between δ18Ocalcite and density.
    Description: P.H. was funded by the NOAA postdoctoral program in climate and global change, and G.G. was partially funded by NSF paleoclimate program ATM-0502482.
    Keywords: Inverse modeling ; Last Glacial Maximum ; Meridional ocean circulation ; Geostrophy
    Repository Name: Woods Hole Open Access Server
    Type: Article
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  • 3
    Publication Date: 2022-05-25
    Description: Author Posting. © American Geophysical Union, 2006. This article is posted here by permission of American Geophysical Union for personal use, not for redistribution. The definitive version was published in Geochemistry Geophysics Geosystems 7 (2006): Q10N03, doi:10.1029/2005GC001226.
    Description: The geostrophic shear associated with the meridional overturning circulation is reflected in the difference in density between the eastern and western margins of the ocean basin. Here we examine how the density difference across 30°S in the upper 2 km of the Atlantic Ocean (and thus the magnitude of the shear associated with the overturning circulation) has changed between the last glacial maximum and the present. We use oxygen isotope measurements on benthic foraminifera to reconstruct density. Today, the density in upper and intermediate waters along the eastern margin in the South Atlantic is greater than along the western margin, reflecting the vertical shear associated with the northward flow of surface and intermediate waters and the southward flowing North Atlantic Deep Waters below. The greater density along the eastern margin is reflected in the higher δ 18O values for surface sediment benthic foraminifera than those found on the western margin for the upper 2 km. For the last glacial maximum the available data indicate that the eastern margin foraminifera had similar δ 18O to those on the western margin between 1 and 2 km and that the gradient was reversed relative to today with the higher δ 18O values in the western margin benthic foraminifera above 1 km. If this reversal in benthic foraminifera δ 18O gradient reflects a reversal in seawater density gradient, these data are not consistent with a vigorous but shallower overturning cell in which surface waters entering the Atlantic basin are balanced by the southward export of Glacial North Atlantic Intermediate Water.
    Description: This work was supported by NSF award OCE-9984989/OCE-0428803 to J.L.-S., NSF award OCE-9986748 to D.W.O. and W.B.C., NSF OCE-0222111 to C.D.C., and SEGRF fellowship at LLNL to J.M.
    Keywords: Last Glacial Maximum ; South Atlantic ; Meridional overturning circulation ; Oxygen isotopes ; Benthic foraminifera
    Repository Name: Woods Hole Open Access Server
    Type: Article
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