Publication Date:
2017-04-04
Description:
Sulphur speciation in volcanic gases acts as a major redox buffer, and H2S/SO2 ratios represent a valuable indicator of magmatic conditions and interactions between magmatic and hydrothermal fluids. However, measurement of H2S/SO2 even by direct sampling techniques, is not straightforward. We report here on application of a small ultraviolet spectrometer for real-time field measurement of H2S and SO2 concentrations, using open-path and extractive configurations. The device was tested at fumaroles on Solfatara and Vulcano, Italy, in November 2002. H2S
concentrations of up to 220ppmm(400 ppmv) were measured directly above the Bocca Grande fumarole at Solfatara, and H2S/SO2 molar ratios of 2 and 2.4, respectively, were determined for the ‘F11’ and ‘F0’ fumaroles at Vulcano. In comparison with other optical techniques capable of multiple
volcanic gas measurements, such as laser and FTIR
spectroscopy, this approach is considerably simpler and cheaper, with the potential for autonomous, sustained hightime resolution operation.
Description:
Published
Description:
1652
Description:
partially_open
Keywords:
Remote monitoring
;
Plume chemistry
;
sulphur species
;
04. Solid Earth::04.08. Volcanology::04.08.01. Gases
;
04. Solid Earth::04.08. Volcanology::04.08.06. Volcano monitoring
;
04. Solid Earth::04.08. Volcanology::04.08.07. Instruments and techniques
Repository Name:
Istituto Nazionale di Geofisica e Vulcanologia (INGV)
Type:
article
Format:
503 bytes
Format:
124998 bytes
Format:
text/html
Format:
application/pdf
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