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  • thermal conductivity  (21)
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  • Springer  (21)
  • American Geophysical Union
  • American Institute of Physics (AIP)
  • American Physical Society
  • Blackwell Publishing Ltd
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  • 2000-2004  (21)
  • 1995-1999
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  • 1
    Electronic Resource
    Electronic Resource
    Springer
    Journal of superconductivity 13 (2000), S. 617-621 
    ISSN: 1572-9605
    Keywords: thermal conductivity ; (Bi,Pb) 2223 pellet ; thermal conductivity peak ; phonon + electron approach
    Source: Springer Online Journal Archives 1860-2000
    Topics: Electrical Engineering, Measurement and Control Technology , Physics
    Notes: Abstract Thermal conductivity of superconducting (Bi,Pb)2223 pellet in the temperature range 20–170 K is reported. Electronic contribution to thermal conductivity in the normal state is estimated to be ∼25%. Considering both phonon and phonon + electron approach, we attempted to examine the observed nature of the temperature dependence of thermal conductivity. Our analysis strongly supports the role of phonons as well as electrons in the origin of the thermal conductivity peak in the superconducting state. Some of the microscopic quantities evaluated from the best-fit parameters obtained from phonon + electron approach give reasonable values.
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  • 2
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    Journal of nanoparticle research 2 (2000), S. 199-204 
    ISSN: 1572-896X
    Keywords: nanoscale heat transfer ; nanoparticles ; nanowires ; phonons ; superlattices ; thermal conductivity ; thin films ; microscale effects
    Source: Springer Online Journal Archives 1860-2000
    Topics: Physics , Technology
    Notes: Abstract Heat conduction in nanostructures differs significantly from that in macrostructures because the characteristic length scales associated with heat carriers, i.e., the mean free path and the wavelength, are comparable to the characteristic length of nanostructures. In this communication, particularities associated with phonon heat conduction in nanostructures, the applicability of the Fourier law, and the implications of nanoscale heat transfer effects on nanotechnology are discussed.
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  • 3
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    Journal of superconductivity 13 (2000), S. 417-422 
    ISSN: 1572-9605
    Keywords: (Bi,Pb)2223-PEG composites ; thermal conductivity ; polyethylene glycol
    Source: Springer Online Journal Archives 1860-2000
    Topics: Electrical Engineering, Measurement and Control Technology , Physics
    Notes: Abstract Thermal conductivity measurements have been taken between 20 and 300 K on composites prepared from polyethylene glycol (PEG) containing various amounts of superconducting (Bi,Pb)2223 powder. The nature of temperature variation of thermal conductivity (λC) of the composites and its magnitude depend strongly on the volume concentration of the high-temperature superconductor (HTSC) filler present in the material. The results have been discussed in the light of models known for polymer–metal powder composites. It is shown that for composites with 2223 powder content 〈44 vol. %, the measured data can be accounted well with Hamilton–Crosser model, taking the sphericity factor into consideration. Failure of Hamilton–Crosser expression for composites with higher filler concentration is thought to be associated with direct contact between the superconducting grains, which shortcircuits the acoustic mismatch resistance in the composites.
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  • 4
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    International journal of thermophysics 21 (2000), S. 207-215 
    ISSN: 1572-9567
    Keywords: calorific intensity ; hot probe ; organ or tissue of a living body ; specific heat ; thermal conductivity ; thermal diffusivity
    Source: Springer Online Journal Archives 1860-2000
    Topics: Physics
    Notes: Abstract A new method was developed to determine simultaneously the thermal conductivity, thermal diffusivity, specific heat, and calorific intensity of the organ or tissue of a living body either in vivo or in vitro with a thin hot probe. By using the method, the thermophysical properties and calorific intensities of a human palm and in vivo liver and a kidney, heart, brain, and foreleg and hindleg muscles of an anesthetized canine were measured. It is concluded that there are no significant differences in the thermophysical properties of organ or tissue of a living body either in vivo or in vitro. The measured thermophysical properties are in good agreement with those reported in the literature.
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  • 5
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    International journal of thermophysics 21 (2000), S. 319-328 
    ISSN: 1572-9567
    Keywords: correlation ; R125 ; R134a ; R32 ; refrigerant ; ternary mixture ; thermal conductivity ; transient hot-wire method
    Source: Springer Online Journal Archives 1860-2000
    Topics: Physics
    Notes: Abstract The thermal conductivities of ternary refrigerant mixtures of difluoromethane (R32), pentafluoroethane (R125), and 1,1,1,2-tetrafluoroethane (R134a) in the liquid phase have been measured by the transient hot-wire method with one bare platinum wire. The experiments were performed in the temperature range of 233 to 323 K and in the pressure range of 2 to 20 MPa at various compositions. The measured data are correlated as a function of temperature, pressure, and composition. From the correlation, we can calculate the thermal conductivity of pure refrigerants and their binary or ternary refrigerant mixtures. The uncertainty of the measurements is estimated to be ±2%.
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  • 6
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    International journal of thermophysics 21 (2000), S. 367-375 
    ISSN: 1572-9567
    Keywords: correlation ; hard spheres ; liquid ; refrigerants ; thermal conductivity ; viscosity
    Source: Springer Online Journal Archives 1860-2000
    Topics: Physics
    Notes: Abstract The viscosity and thermal conductivity of liquid halogenated ethane refrigerants from about 200 K to near the critical temperature, at saturation and also at pressures up to 50 MPa, are shown to be satisfactorily correlated on the basis of a scheme developed by Dymond and Assael from consideration of hard-sphere theory.
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  • 7
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    International journal of thermophysics 21 (2000), S. 465-478 
    ISSN: 1572-9567
    Keywords: heat radiation ; hot wire ; thermal conductivity ; semitransparent material
    Source: Springer Online Journal Archives 1860-2000
    Topics: Physics
    Notes: Abstract A new simple analytic model applicable to the measurement system of a hot wire and a semitransparent solid material is developed. An experimental study is carried out on a special glass sample, glass K9, in the temperature range of 297 to 1230 K, and the radiation-free thermal conductivity is reported.
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  • 8
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    International journal of thermophysics 21 (2000), S. 571-583 
    ISSN: 1572-9567
    Keywords: CsPbCl3 single crystal ; heat of transition ; phase transition ; pulse transient method ; specific heat ; thermal conductivity ; thermal diffusivity
    Source: Springer Online Journal Archives 1860-2000
    Topics: Physics
    Notes: Abstract The main features of the pulse transient method are presented. The method gives the specific heat c and thermal diffusivity a for a single measurement, while thermal conductivity λ is calculated according to λ=caρ, where ρ is the density. The pulse transient method is a dynamic method based on the measurement of the temperature response to a heat pulse produced within a specimen. An apparatus operating in the temperature range from −40 to 100°C is described. Errors are discussed. The thermophysical properties of a CsPbCl3 single crystal are determined using the pulse transient method for a temperature range between 10 and 65°C in the controlled heating and cooling regimes. The data show anomalies in the thermophysical properties around the phase transition temperature at 47°C. Discrepancies in comparison with previously published data are discussed.
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  • 9
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    International journal of thermophysics 21 (2000), S. 639-650 
    ISSN: 1572-9567
    Keywords: empirical correlation ; n-alkane ; propane ; thermal conductivity ; transport properties
    Source: Springer Online Journal Archives 1860-2000
    Topics: Physics
    Notes: Abstract New experimental data on the thermal conductivity of propane have been reported since the wide-range correlations proposed by Holland et al. and by Younglove and Ely. These new experimental data, covering a temperature range of 110 to 700 K and a pressure range of 0.1 to 70 MPa, are used together with the previously available data to develop an improved empirical equation for the thermal conductivity of gaseous and liquid propane. The quality of the new data is such that the thermal-conductivity correlation for propane is estimated to have an uncertainty of about ±5% at a 95% confidence level, with the exception of state points near the critical point, where the uncertainty of the correlation increases to ±10%.
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  • 10
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    International journal of thermophysics 21 (2000), S. 927-940 
    ISSN: 1572-9567
    Keywords: calorimetry ; emittance ; fused silica ; hemispherical total emissivity ; refractive index ; spectral emissivity ; thermal conductivity ; virtual mode ; Vycor glass
    Source: Springer Online Journal Archives 1860-2000
    Topics: Physics
    Notes: Abstract An attempt to derive the hemispherical total emissivity from the normal emission spectrum is proposed for Vycor and fused silica glasses. The normal emission spectrum from a clear surface has been measured at steady state in the temperature range from 400 to 750 K. The sample is heated on one metal-backed face by thermal radiation from a heater. Temperatures inside the sample were monitored by thermocouples at two points near the surfaces. Evaluation of the hemispherical total emissivity from the normal emission spectrum is determined by means of Kramers–Krönig analysis and virtual mode equations. Assuming a linear temperature distribution within the sample, the thermal conductivities of silicate glasses were obtained at elevated temperatures. The results are comparable with those obtained by previous investigators. The effect of radiation heat transfer in a sample is also discussed.
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  • 11
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    International journal of thermophysics 21 (2000), S. 671-679 
    ISSN: 1572-9567
    Keywords: electrolyte solutions ; potassium chloride aqueous solutions ; thermal conductivity ; transient coated-hot-wire technique
    Source: Springer Online Journal Archives 1860-2000
    Topics: Physics
    Notes: Abstract This paper presents new absolute measurements of the thermal conductivity of aqueous potassium chloride solutions using the transient coated-hot-wire technique. The data cover the range from 295 to 360 K at pressures slightly above the vapor pressures and over a concentration range of 0 to 3 mol·kg−1. The instrument can be used to measure the thermal conductivity with a reproducibility of better than 0.2%, and a comparison of the present results with data available in the literature indicates that the uncertainty of the present data is better than 0.5%. An empirical correlation that reproduces the data within the claimed uncertainty is presented.
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  • 12
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    International journal of thermophysics 21 (2000), S. 23-34 
    ISSN: 1572-9567
    Keywords: HFC-32 ; HFC-125 ; HFC-134a ; hard-sphere theory ; mixture ; refrigerant ; thermal conductivity ; viscosity
    Source: Springer Online Journal Archives 1860-2000
    Topics: Physics
    Notes: Abstract A recently developed scheme, based on considerations of hard-sphere theory, is used for the simultaneous prediction of the thermal conductivity and the viscosity of binary and ternary HFC refrigerant mixtures, consisting of HFC-32, HFC-125, and HFC-134a. In this prediction scheme, the hypothetical molecular parameters of HFC refrigerant mixtures were assumed to be the molar average of the pure component values. The close agreement between the predicted values and the experimental results of thermal conductivity and viscosity demonstrate the predictive power of this scheme.
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  • 13
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    International journal of thermophysics 21 (2000), S. 35-44 
    ISSN: 1572-9567
    Keywords: aqueous solution ; diffraction ; laser-induced thermal grating ; magnesium chloride ; thermal conductivity ; thermal diffusivity
    Source: Springer Online Journal Archives 1860-2000
    Topics: Physics
    Notes: Abstract The thermal diffusivity of aqueous solutions of magnesium chloride was determined in the temperature range 294 to 371 K and at atmospheric pressure. Using a noninvasive optical technique—laser-induced thermal grating (LTG)—the measurements were carried out in aqueous solutions of weight fractions of 5, 10, 15, and 20% magnesium chloride. The measurement results for the aqueous solutions are presented as a function of temperature and weight fraction.
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  • 14
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    International journal of thermophysics 21 (2000), S. 445-452 
    ISSN: 1572-9567
    Keywords: evacuated insulations ; opacifier ; powders ; radiative conductivity ; silica powder ; silicon carbide ; thermal conductivity ; thermal radiation
    Source: Springer Online Journal Archives 1860-2000
    Topics: Physics
    Notes: Abstract The thermal conductivity of powder fillings for load-bearing vacuum insulations is investigated. Different opacifiers have been tested in mixtures with perlite powder, precipitated silica, and fumed silica. Using temperature-dependent thermal conductivity measurements, the radiative thermal conductivity and the solid conductivity of the powder samples are separated. Additionally, the influence of the pressure load on the solid conductivity is studied. The thermal conductivities of silica powders with added opacifier powders (carbon black, magnetite, silicon carbide, titanium dioxide) can be as low as 0.003 W·m−1·K−1 if the powder boards are pressed with moderate loads. The use of microporous silica powders as filler materials allows internal gas pressures even beyond 10 hPa with only a moderate increase of the overall conductivity.
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  • 15
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    International journal of thermophysics 21 (2000), S. 1255-1278 
    ISSN: 1572-9567
    Keywords: standard uncertainty ; thermal conductivity ; thermal diffusivity ; transient hot strip method ; transient hot wire method
    Source: Springer Online Journal Archives 1860-2000
    Topics: Physics
    Notes: Abstract The standard method for measuring thermal transport properties of dielectric solids such as ceramics and refractories is the transient hot wire (THW) technique. In its simplest arrangement, a thin wire is embedded between two sample halves, where it acts simultaneously as a resistive heat source and a thermometer. From its temperature signal, the thermal conductivity and the thermal diffusivity of the dielectric can be derived. Up to now, there is no uncertainty assessment for this technique strictly following the ISO Guide to the Expression of Uncertainty in Measurement. Here we analyze the ISO standard uncertainty of the THW technique in the same way as in a previous paper on the uncertainty of the closely related transient hot strip (THS) technique. The two papers provide a comprehensive comparison of the most important advantages and disadvantages of these two transient techniques. The results obtained here for the uncertainty (5.8% for the thermal conductivity and 30% for the thermal diffusivity) are nearly the same as those for the THS method. Experiments on a Pyrex standard-reference sample confirm the results.
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  • 16
    ISSN: 1572-9567
    Keywords: R134a ; dilute gas ; refrigerant ; saturation properties ; 1,1,1,2-tetrafluoroethane ; thermal conductivity ; transport properties ; viscosity
    Source: Springer Online Journal Archives 1860-2000
    Topics: Physics
    Notes: Abstract This paper reports the results of an international project coordinated by the Subcommittee on Transport Properties of Commission I.2 of the International Union of Pure and Applied Chemistry. The project has been conducted to investigate the large discrepancies between the results reported by various authors for the transport properties of R134a and culminates the effort which was initially described in 1995. The project has involved the remeasurement of the transport properties of a single sample of R134a in nine laboratories throughout the world in order to test the hypothesis that at least part of the discrepancy could be attributed to the purity of the samples. This paper provides an intercomparison of the new experimental results obtained for the viscosity and thermal conductivity in the vapor, liquid, and supercritical gas phases. The viscosity measurements were made with a variety of techniques including the vibrating wire, oscillating disk, capillary flow, and falling body. Thermal conductivity was measured using transient bare and anodized hot wires, steady-state anodized hot wires, and light scattering. Agreement between a variety of experimental techniques using the standard round-robin sample is necessary to demonstrate that some of the discrepancies in earlier results were due to sample impurities. Identification of disagreement between data using one experimental technique relative to other techniques may suggest modifications that would lead to more accurate measurements on these highly polar refrigerant materials. It is anticipated that the new data which have been measured on this IUPAC round-robin sample will aid in the identification of the reliable data sets in the literature and ultimately allow the refinement of the IUPAC reference-data correlations for the transport properties of R134a.
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  • 17
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    International journal of thermophysics 21 (2000), S. 71-84 
    ISSN: 1572-9567
    Keywords: molten carbonates ; molten nitrate ; thermal conductivity ; thermal diffusivity ; transient short-hot-wire technique
    Source: Springer Online Journal Archives 1860-2000
    Topics: Physics
    Notes: Abstract A transient short-hot-wire technique has been successfully used to measure the thermal conductivity and thermal diffusivity of molten salts (NaNO3, Li2CO3/K2CO3, and Li2CO3/Na2CO3) which are highly corrosive. This method was developed from the hot-wire technique and is based on two-dimensional numerical solutions of unsteady heat conduction from a short wire with the same length-to-diameter ratio and boundary conditions as those used in the actual experiments. In the present study, the wires are coated with a pure Al2O3 thin film by using a sputtering apparatus. The length and radius of the hot wire and the resistance ratio of the lead terminals and the entire probe are calibrated using water and toluene with known thermophysical properties. Using such a calibrated probe, the thermal conductivity and thermal diffusivity of molten nitrate are measured within errors of 3 and 20%, respectively. Also, the thermal conductivity of the molten carbonates can be measured within an error of 5%, although the thermal diffusivity can be measured within an error of 50%.
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  • 18
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    International journal of thermophysics 21 (2000), S. 217-248 
    ISSN: 1572-9567
    Keywords: linear working equation ; nonlinear working equation ; standard uncertainty ; thermal conductivity ; thermal diffusivity ; transient hot strip method
    Source: Springer Online Journal Archives 1860-2000
    Topics: Physics
    Notes: Abstract The transient hot strip (THS) method can be used to measure simultaneously the thermal conductivity λ and diffusivity a of dielectrics within a few minutes. However, although the method has been known for 20 years, there is no complete assessment of its uncertainty. First, the underlying complex mathematical model makes any error analysis a tedious and complicated task. Secondly, the ISO Guide to the Expression of Uncertainty in Measurement does not apply directly because of the classical model's implicit character. In the present paper, the combined standard uncertainty u of the THS method has been determined by applying two different models. First, we start from the classical nonlinear model. The major sources of errors are analyzed, namely, the ideal model errors, the evaluation errors, and the measurement errors. Next, a newly developed numerical procedure combines all the components in a way that the resultant standard uncertainties of the nonlinear model, u(λ)/λ=2.6% and u(a)/a=11%, comply as closely as possible with the principles of the ISO Guide. Second, we start from the recently presented linear expression of the THS mathematical model that is briefly discussed. Since this approximation is explicit in both measurands, the uncertainties, u(λ)/λ=2.5% and u(a)/a=11%, are determined in full accordance with the ISO guide. The uncertainty in thermal conductivity is experimentally assessed against the standard reference CRM 039 (Pyrex). The results obtained are in excellent agreement with the theoretical values.
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  • 19
    ISSN: 1572-9567
    Keywords: molten materials ; self-adaptive finite-element method ; thermal conductivity ; transient hot-strip
    Source: Springer Online Journal Archives 1860-2000
    Topics: Physics
    Notes: Abstract The transient heating in an unsymmetrical, coated, hot-strip sensor was simulated with a self-adaptive finite-element method (SAFEM). The first tests of this model show that it can be used to determine, with a small error, the thermal conductivity of liquids, from the transient temperature rise in the hot strip, which is deposited in a substrate and coated by an alumina spray.
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  • 20
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    International journal of thermophysics 21 (2000), S. 429-443 
    ISSN: 1572-9567
    Keywords: density ; electrical resistivity ; electrostatic levitator ; hemispherical total emissivity ; molten germanium ; specific heat ; surface tension ; thermal conductivity
    Source: Springer Online Journal Archives 1860-2000
    Topics: Physics
    Notes: Abstract Thermophysical properties of molten germanium have been measured using the high-temperature electrostatic levitator at the Jet Propulsion Laboratory. Measured properties include the density, the thermal expansivity, the hemispherical total emissivity, the constant-pressure specific heat capacity, the surface tension, and the electrical resistivity. The measured density can be expressed by ρ liq=5.67×103−0.542 (T−T m ) kg·m−3 from 1150 to 1400 K with T m=1211.3 K, the volume expansion coefficient by α=0.9656×10−4 K−1, and the hemispherical total emissivity at the melting temperature by ε T, liq(T m)=0.17. Assuming constant ε T, liq(T)=0.17 in the liquid range that has been investigated, the constant-pressure specific heat was evaluated as a function of temperature. The surface tension over the same temperature range can be expressed by σ(T)=583−0.08(T−T m) mN·m−1 and the temperature dependence of the electrical resistivity, when r liq(T m)=60μμΩ·cm is used as a reference point, can be expressed by r e, liq(T)=60+1.18×10−2(T−1211.3)μΩ·cm. The thermal conductivity, which was determined from the resistivity data using the Wiedemann–Franz–Lorenz law, is given by κ liq(T )=49.43+2.90×10−2(T−T m) W·m−1·K−1.
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  • 21
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    International journal of thermophysics 21 (2000), S. 965-980 
    ISSN: 1572-9567
    Keywords: electrical conductivity ; microstructure ; pin fin ; single carbon fiber ; steady-state short-hot-wire method ; thermal conductivity
    Source: Springer Online Journal Archives 1860-2000
    Topics: Physics
    Notes: Abstract In this paper, the thermal conductivity of a single carbon fiber under different manufacturing conditions is measured using the steady-state short-hot-wire method. This method is based on the heat transfer phenomena of a pin fin attached to a short hot wire. The short hot wire is supplied with a constant direct current to generate a uniform heat flux, and both its ends are connected to lead wires and maintained at the initial temperature. The test fiber is attached as a pin fin to the center position of the hot wire at one end and the other end is connected to a heat sink. One-dimensional steady-state heat conduction along the hot wire and test fiber is assumed, and the basic equations are analytically solved. From the solutions, the relations among the average temperature rise of the hot wire, the heat generation rate, the temperature at the attached end of the fiber, and the heat flux from the hot wire to the fiber are accurately obtained. Based on the relations, the thermal conductivity of the single carbon fiber can be easily estimated when the average temperature rise and the heat generation rate of the hot wire are measured for the same system. Further, the electrical conductivity of the single carbon fiber is measured under the same conditions as for the thermal conductivity using a four-point contact method. The relation between the thermal conductivity and electrical conductivity is further discussed, based on the crystal microstructure.
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