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  • 1
    Publication Date: 2022-05-25
    Description: Author Posting. © American Geophysical Union, 2009. This article is posted here by permission of American Geophysical Union for personal use, not for redistribution. The definitive version was published in Geochemistry Geophysics Geosystems 10 (2009): Q10T07, doi:10.1029/2008GC002354.
    Description: High-resolution side-scan sonar, near-bottom multibeam bathymetry, and deep-sea photo and bathymetry traverses are used to map the axial summit trough (AST) at the East Pacific Rise between 9 and 10°N. We define three ridge axis morphologic types: no AST, narrow AST, and wide AST, which characterize distinct ridge crest domains spanning tens of kilometers along strike. Near-bottom observations, modeling of deformation above intruding dikes, and comparisons to the geologic and geophysical structure of the ridge crest are used to develop a revised model of AST genesis and evolution. This model helps constrain the record of intrusive and extrusive magmatism and styles of lava deposition along the ridge crest at time scales from hundreds to tens of thousands of years. The grabens in the narrow-AST domain (9°43′–53′N) are consistent with deformation above the most recent (〈10) diking events beneath the ridge crest. Frequent high–effusion rate extrusive volcanism in this domain (several eruptions every ∼100 years) overprints near-axis deformation and maintains a consistent AST width. The most recent eruption at the ridge crest occurred in this area and did not significantly modify the physical characteristics of the AST. The grabens in the wide-AST domain (9°23′–43′N) originated with similar dimensions to the narrow AST. Spreading, driven primarily by the intrusion of shallow dikes within a narrow axial zone, causes the initial graben bounding faults to migrate away from the axis. Infrequent extrusive volcanism (several eruptions every ∼1000 years) fills a portion of the subsidence that accumulates over time but does not significantly modify the width of the AST. Outside of these domains, lower–effusion rate constructional volcanism without efficient drain-back fills and erases the signature of the AST. The relative frequency of intrusive versus extrusive magmatic events controls the morphology of the ridge crest and appears to remain constant over millennial time scales within the domains we have identified; however, over longer time scales (∼10–25 ka), domain-specific intrusive-to-extrusive ratios do not appear to be fixed in space, resulting in a fairly consistent volcanic accretion over the length scale of the second-order ridge segment between 9°N and 10°N.
    Description: This work was supported by NSF grants OCE-0525863 to D. Fornari and S. A. Soule; OCE-0732366 to S. A. Soule; and OCE-9819261 to H. Schouten, M. Tivey, and D. Fornari and by CNRS to J. Escartın.
    Keywords: Mid-ocean ridge ; Submarine volcanism ; Diking ; Seafloor morphology ; Magmatism
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  • 2
    Publication Date: 2022-05-25
    Description: Author Posting. © American Geophysical Union, 2009. This article is posted here by permission of American Geophysical Union for personal use, not for redistribution. The definitive version was published in Global Biogeochemical Cycles 23 (2009): GB4028, doi:10.1029/2009GB003519.
    Description: Nitrogen cycle dynamics have the capacity to attenuate the magnitude of global terrestrial carbon sinks and sources driven by CO2 fertilization and changes in climate. In this study, two versions of the terrestrial carbon and nitrogen cycle components of the Integrated Science Assessment Model (ISAM) are used to evaluate how variation in nitrogen availability influences terrestrial carbon sinks and sources in response to changes over the 20th century in global environmental factors including atmospheric CO2 concentration, nitrogen inputs, temperature, precipitation and land use. The two versions of ISAM vary in their treatment of nitrogen availability: ISAM-NC has a terrestrial carbon cycle model coupled to a fully dynamic nitrogen cycle while ISAM-C has an identical carbon cycle model but nitrogen availability is always in sufficient supply. Overall, the two versions of the model estimate approximately the same amount of global mean carbon uptake over the 20th century. However, comparisons of results of ISAM-NC relative to ISAM-C reveal that nitrogen dynamics: (1) reduced the 1990s carbon sink associated with increasing atmospheric CO2 by 0.53 PgC yr−1 (1 Pg = 1015g), (2) reduced the 1990s carbon source associated with changes in temperature and precipitation of 0.34 PgC yr−1 in the 1990s, (3) an enhanced sink associated with nitrogen inputs by 0.26 PgC yr−1, and (4) enhanced the 1990s carbon source associated with changes in land use by 0.08 PgC yr−1 in the 1990s. These effects of nitrogen limitation influenced the spatial distribution of the estimated exchange of CO2 with greater sink activity in high latitudes associated with climate effects and a smaller sink of CO2 in the southeastern United States caused by N limitation associated with both CO2 fertilization and forest regrowth. These results indicate that the dynamics of nitrogen availability are important to consider in assessing the spatial distribution and temporal dynamics of terrestrial carbon sources and sinks.
    Description: We also acknowledge the financial support of the National Aeronautics and Space Administration Land Cover and Land Use Change Program (NNX08AK75G).
    Keywords: Nitrogen cycle ; Carbon cycle ; ISAM
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  • 3
    Publication Date: 2022-05-25
    Description: Author Posting. © American Geophysical Union, 2004. This article is posted here by permission of American Geophysical Union for personal use, not for redistribution. The definitive version was published in Journal of Geophysical Research 109 (2004): B01101, doi:10.1029/2003JB002499.
    Description: Ocean bottom seismic networks deployed following the 1998 eruption of Axial seamount reveal an evolving pattern of microearthquake activity associated with subsurface magmatism and thermal strain. Seismicity rates decay steadily over 15 months of observation (February 8, 1998, to April 30, 1999), consistent with a trend toward thermal and mechanical equilibrium in the shallow crust after the magmatic event. Immediately after the eruption, seismicity rates were high for about 60 days in the southeast corner of the caldera where lava flows from the 1998 eruption were mapped. A small burst of seismic activity was observed on the southeast shoulder of the volcano from 100 to 150 days after the eruption. These events, which are characterized by slip on nearly vertical faults in the shallow crust, extend about 6 km from the southeast corner of the caldera and overlie a mid-crustal low-velocity zone. After this episode, seismicity rates remain low until the end of the observation period, 455 days after the eruption. Shallow (~0.7 km depth) events, consistent with thermal contraction and volume changes of ~2 × 10−3 m3 in ~5 m3 sources, are observed in individual clusters beneath hydrothermal vents within the 1998 lava flow at the southeast edge of the caldera. Microearthquakes observed during the last 70 days of observation are distributed around the central caldera, most likely representing small amounts of subsidence on caldera faults during the final stages of equilibration following melt withdrawal associated with the 1998 eruption.
    Description: Sohn, Webb, and the field program were supported by NSF grant OCE 97- 11700. Barclay was supported in part by the Woods Hole Oceanographic Institution.
    Keywords: Microearthquakes ; Hydrothermal ; Magmatism
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  • 4
    Publication Date: 2022-05-25
    Description: Author Posting. © American Geophysical Union, 2008. This article is posted here by permission of American Geophysical Union for personal use, not for redistribution. The definitive version was published in Geochemistry Geophysics Geosystems 9 (2008): Q08O10, doi:10.1029/2008GC001965.
    Description: We use 2-D numerical models to explore the thermal and mechanical effects of magma intrusion on fault initiation and growth at slow and intermediate spreading ridges. Magma intrusion is simulated by widening a vertical column of model elements located within the lithosphere at a rate equal to a fraction, M, of the total spreading rate (i.e., M = 1 for fully magmatic spreading). Heat is added in proportion to the rate of intrusion to simulate the thermal effects of magma crystallization and the injection of hot magma into the crust. We examine a range of intrusion rates and axial thermal structures by varying M, spreading rate, and the efficiency of crustal cooling by conduction and hydrothermal circulation. Fault development proceeds in a sequential manner, with deformation focused on a single active normal fault whose location alternates between the two sides of the ridge axis. Fault spacing and heave are primarily sensitive to M and secondarily sensitive to axial lithosphere thickness and the rate that the lithosphere thickens with distance from the axis. Contrary to what is often cited in the literature, but consistent with prior results of mechanical modeling, we find that thicker axial lithosphere tends to reduce fault spacing and heave. In addition, fault spacing and heave are predicted to increase with decreasing rates of off-axis lithospheric thickening. The combination of low M, particularly when M approaches 0.5, as well as a reduced rate of off-axis lithospheric thickening produces long-lived, large-offset faults, similar to oceanic core complexes. Such long-lived faults produce a highly asymmetric axial thermal structure, with thinner lithosphere on the side with the active fault. This across-axis variation in thermal structure may tend to stabilize the active fault for longer periods of time and could concentrate hydrothermal circulation in the footwall of oceanic core complexes.
    Description: Funding for this research was provided by NSF grants OCE-0327018 (M.D.B.), OCE-0548672 (M.D.B.), OCE- 0327051 (G.I.), and OCE-03-51234 (G.I.).
    Keywords: Mid-ocean ridges ; Faulting ; Magmatism ; Numerical modeling
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  • 5
    Publication Date: 2022-05-25
    Description: Author Posting. © American Geophysical Union, 2007. This article is posted here by permission of American Geophysical Union for personal use, not for redistribution. The definitive version was published in Global Biogeochemical Cycles 21 (2007): GB2026, doi:10.1029/2006GB002900.
    Description: We investigate the interannual variability in the flux of CO2 between the atmosphere and the Southern Ocean on the basis of hindcast simulations with a coupled physical-biogeochemical-ecological model with particular emphasis on the role of the Southern Annular Mode (SAM). The simulations are run under either pre-industrial or historical CO2 concentrations, permitting us to separately investigate natural, anthropogenic, and contemporary CO2 flux variability. We find large interannual variability (±0.19 PgC yr−1) in the contemporary air-sea CO2 flux from the Southern Ocean (〈35°S). Forty-three percent of the contemporary air-sea CO2 flux variance is coherent with SAM, mostly driven by variations in the flux of natural CO2, for which SAM explains 48%. Positive phases of the SAM are associated with anomalous outgassing of natural CO2 at a rate of 0.1 PgC yr−1 per standard deviation of the SAM. In contrast, we find an anomalous uptake of anthropogenic CO2 at a rate of 0.01 PgC yr−1 during positive phases of the SAM. This uptake of anthropogenic CO2 only slightly mitigates the outgassing of natural CO2, so that a positive SAM is associated with anomalous outgassing in contemporaneous times. The primary cause of the natural CO2 outgassing is anomalously high oceanic partial pressures of CO2 caused by elevated dissolved inorganic carbon (DIC) concentrations. These anomalies in DIC are primarily a result of the circulation changes associated with the southward shift and strengthening of the zonal winds during positive phases of the SAM. The secular, positive trend in the SAM has led to a reduction in the rate of increase of the uptake of CO2 by the Southern Ocean over the past 50 years.
    Description: This work was supported by NASA headquarters under the Earth System Science Fellowship Grant NNG05GP78H to N. S. L. and grants NAG5-12528 and NNG04GH53G to N. G. Both S. C. D. and I. D. L. were supported by NSF/ONR NOPP (N000140210370) and NASA (NNG05GG30G).
    Keywords: Southern Ocean ; Carbon cycle ; Southern Annular Mode
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  • 6
    Publication Date: 2022-05-25
    Description: Author Posting. © American Geophysical Union, 2010. This article is posted here by permission of American Geophysical Union for personal use, not for redistribution. The definitive version was published in Journal of Geophysical Research 115 (2010): C11015, doi:10.1029/2010JC006152.
    Description: The concentration of inert gases and their isotopes in the deep ocean are useful as tracers of air-sea gas exchange during deepwater formation. ΔKr/Ar, ΔN2/Ar, and δ40Ar were measured in deep profiles of samples collected in the northwest Pacific, subtropical North Pacific and tropical Atlantic oceans. For the ocean below 2000 m, we determined a mean ΔKr/Ar composition of −0.96% ± 0.16%, a mean ΔN2/Ar of 1.29% ± 0.21% relative to equilibrium saturation, and for δ40Ar a value of 1.188‰ ± 0.055‰ relative to air. These data are used to constrain high-latitude ventilation processes in the framework of three-box and seven-box ocean models. For the three-box model tracer data, we constrain the appropriate surface area of the high-latitude region in both models to be 3.6% (+2.5%, −1.7%) of ocean surface area and the bubble air injection rate to be 22.7 (+8.8, −7.3) mol air m−2 yr−1. Results for the seven-box model were similar, with a high-latitude area of 3.3% (+2.2%, −1.3%). Our results provide geochemical support for suggestions that the effective area of high-latitude ventilation is much smaller than the region of elevated preformed nutrients and demonstrate that noble gases strongly constrain the ocean solubility pump. Reducing high-latitude surface area weakens the CO2 solubility pump in the box models and limits communication between the atmosphere and deep ocean. These tracers should be useful constraints on high-latitude ventilation and the strength of the solubility pump in more complex ocean general circulation models.
    Description: Funding was provided by NSF‐OCE‐0647979.
    Keywords: Noble gases ; Ventilation ; Carbon cycle ; Solubility pump ; Gas exchange
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  • 7
    Publication Date: 2022-05-25
    Description: Author Posting. © American Geophysical Union, 2004. This article is posted here by permission of American Geophysical Union for personal use, not for redistribution. The definitive version was published in Reviews of Geophysics 42 (2004): RG2001, doi:10.1029/2003RG000127.
    Description: Documenting the mass flux through convergent plate margins is important to the understanding of petrogenesis in arc settings and to the origin of the continental crust, since subduction zones are the only major routes by which material extracted from the mantle can be returned to great depths within the Earth. Despite their significance, there has been a tendency to view subduction zones as areas of net crustal growth. Convergent plate margins are divided into those showing long-term landward retreat of the trench and those dominated by accretion of sediments from the subducting plate. Tectonic erosion is favored in regions where convergence rates exceed 6 ± 0.1 cm yr−1 and where the sedimentary cover is 〈1 km. Accretion preferentially occurs in regions of slow convergence (〈7.6 cm yr−1) and/or trench sediment thicknesses 〉1 km. Large volumes of continental crust are subducted at both erosive and accretionary margins. Average magmatic productivity of arcs must exceed 90 km3 m.y.−1 if the volume of the continental crust is to be maintained. Convergence rate rather than height of the melting column under the arc appears to be the primary control on long-term melt production. Oceanic arcs will not be stable if crustal thicknesses exceed 36 km or trench retreat rates are 〉6 km m.y.−1. Continental arcs undergoing erosion are major sinks of continental crust. This loss requires that oceanic arcs be accreted to the continental margins if the net volume of crust is to be maintained.
    Description: This material is partly based upon work supported by the National Science Foundation (Ocean Sciences) under grant 9907137.
    Keywords: Tectonics ; Subduction ; Magmatism
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  • 8
    Publication Date: 2022-05-25
    Description: Author Posting. © American Geophysical Union, 2008. This article is posted here by permission of American Geophysical Union for personal use, not for redistribution. The definitive version was published in Geochemistry Geophysics Geosystems 9 (2008): Q09O12, doi:10.1029/2008GC001970.
    Description: We investigate the origin of mid-ocean ridge morphology with numerical models that successfully predict axial topographic highs, axial valleys, and the transition between the two. The models are time-dependent, simulating alternating tectonic and magmatic periods where far-field extension is accommodated by faulting and by magmatism, respectively. During tectonic phases, models predict faults to grow on either side of the ridge axis and axial height to decrease. During magmatic phases, models simulate magmatic extension by allowing the axial lithosphere to open freely in response to extension. Results show that fault size and spacing decreases with increasing time fraction spent in the magmatic phase F M . Magmatic phases also simulate the growth of topography in response to local buoyancy forces. The fundamental variable that controls the transition between axial highs and valleys is the “rise-sink ratio,” (F M /F T )(τ T /τ M ), where F M /F T is the ratio of the time spent in the magmatic and tectonic periods and τ T /τ M is the ratio of the characteristic rates for growing topography during magmatic phases (1/τ M ) and for reducing topography during tectonic phases (1/τ T ). Models predict the tallest axial highs when (F M /F T )(τ T /τ M ) ≫ 1, faulted topography without a high or valley when (F M /F T )(τ T /τ M ) ∼ 1, and the deepest median valleys when (F M /F T )(τ M /τ T ) 〈 1. New scaling laws explain a global negative correlation between axial topography and lithosphere thickness as measured by the depths of axial magma lenses and microearthquakes. Exceptions to this trend reveal the importance of other behaviors such as a predicted inverse relation between axial topography and spreading rate as evident along the Lau Spreading Center. Still other factors related to the frequency and spatial pervasiveness of magmatic intrusions and eruptions, as evident at the Mid-Atlantic and Juan de Fuca ridges, influence the rise-sink-ratio (F M /F T )(τ T /τ M ) and thus axial morphology.
    Description: Funding for this research was provided by NSF grants OCE-0327018 (MDB), OCE-0548672 (MDB), OCE-0327051 (GI), and OCE-0351234 (GI).
    Keywords: Mid-ocean ridge ; Magmatism ; Seafloor spreading ; Faulting ; Rifting
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  • 9
    Publication Date: 2022-05-25
    Description: Author Posting. © American Geophysical Union, 2006. This article is posted here by permission of American Geophysical Union for personal use, not for redistribution. The definitive version was published in Tectonics 25 (2006): TC4004, doi:10.1029/2005TC001789.
    Description: The Lloyds River Fault Zone is a 10–15 km wide amphibolite-grade shear zone that formed during the Ordovician Taconic Orogeny. It separates ophiolites and arc–back-arc complexes formed in Iapetus from a peri-Laurentian microcontinent (Dashwoods microcontinent). The Lloyds River Fault Zone comprises three high-strain zones, dominantly composed of mylonitic amphibolites, separated by less deformed plutonic rocks. Structural, age and metamorphic data suggest the Lloyds River Fault Zone accommodated sinistral-oblique underthrusting of ophiolites underneath the Dashwoods microcontinent prior to 471 ± 5 Ma at 800°C and 6 kbar. Plutonic rocks within the Lloyds River Fault Zone comprise two suites dated at 464 ± 2 plus 462 ± 2 and 459 ± 3 Ma, respectively. The younger age of the plutons with respect to some of the amphibolites, evidence for magmatic deformation, and the elongate nature of the plutons parallel to the Lloyds River Fault Zone suggest they were emplaced within the fault zone during deformation. Both intrusive episodes triggered renewed deformation at high temperatures (770–750°C), illustrating the positive feedback between deformation and magmatism. Offshoots of the plutons intruded undeformed ophiolitic gabbros outside the Lloyds River Fault Zone. Deformation localized within the intrusive sheets, coeval with static contact metamorphism of the host gabbros, leading to the development of new, small-scale shear zones. This illustrates that channeling of plutons into shear zones and nucleation of shear zones in melt-rich zones may occur simultaneously within the same fault system.
    Description: This research is funded by a scholarship from the Faculty of Graduate and Postdoctoral Studies, University of Ottawa, to C.J.L. and a NSERC grant to C.v.S in his position as Adjunct Professor at the University of Ottawa.
    Keywords: Shear zones ; Magmatism ; Appalachians
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  • 10
    Publication Date: 2022-05-26
    Description: Author Posting. © American Geophysical Union, 2008. This article is posted here by permission of American Geophysical Union for personal use, not for redistribution. The definitive version was published in Journal of Geophysical Research 113 (2008): C07032, doi:10.1029/2007JC004598.
    Description: This paper examines the sensitivity of atmospheric pCO2 to changes in ocean biology that result in drawdown of nutrients at the ocean surface. We show that the global inventory of preformed nutrients is the key determinant of atmospheric pCO2 and the oceanic carbon storage due to the soft-tissue pump (OCS soft ). We develop a new theory showing that under conditions of perfect equilibrium between atmosphere and ocean, atmospheric pCO2 can be written as a sum of exponential functions of OCS soft . The theory also demonstrates how the sensitivity of atmospheric pCO2 to changes in the soft-tissue pump depends on the preformed nutrient inventory and on surface buffer chemistry. We validate our theory against simulations of nutrient depletion in a suite of realistic general circulation models (GCMs). The decrease in atmospheric pCO2 following surface nutrient depletion depends on the oceanic circulation in the models. Increasing deep ocean ventilation by increasing vertical mixing or Southern Ocean winds increases the atmospheric pCO2 sensitivity to surface nutrient forcing. Conversely, stratifying the Southern Ocean decreases the atmospheric CO2 sensitivity to surface nutrient depletion. Surface CO2 disequilibrium due to the slow gas exchange with the atmosphere acts to make atmospheric pCO2 more sensitive to nutrient depletion in high-ventilation models and less sensitive to nutrient depletion in low-ventilation models. Our findings have potentially important implications for both past and future climates.
    Description: While at MIT, I.M. was supported by the NOAA Postdoctoral Program in Climate and Global Change, administered by the University Corporation for Atmospheric Research.
    Keywords: Carbon cycle ; Preformed nutrient ; Nutrient depletion
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  • 11
    Publication Date: 2022-05-26
    Description: Author Posting. © American Geophysical Union, 2006. This article is posted here by permission of American Geophysical Union for personal use, not for redistribution. The definitive version was published in Global Biogeochemical Cycles 20 (2006): GB2002, doi:10.1029/2005GB002530.
    Description: Regional air-sea fluxes of anthropogenic CO2 are estimated using a Green's function inversion method that combines data-based estimates of anthropogenic CO2 in the ocean with information about ocean transport and mixing from a suite of Ocean General Circulation Models (OGCMs). In order to quantify the uncertainty associated with the estimated fluxes owing to modeled transport and errors in the data, we employ 10 OGCMs and three scenarios representing biases in the data-based anthropogenic CO2 estimates. On the basis of the prescribed anthropogenic CO2 storage, we find a global uptake of 2.2 ± 0.25 Pg C yr−1, scaled to 1995. This error estimate represents the standard deviation of the models weighted by a CFC-based model skill score, which reduces the error range and emphasizes those models that have been shown to reproduce observed tracer concentrations most accurately. The greatest anthropogenic CO2 uptake occurs in the Southern Ocean and in the tropics. The flux estimates imply vigorous northward transport in the Southern Hemisphere, northward cross-equatorial transport, and equatorward transport at high northern latitudes. Compared with forward simulations, we find substantially more uptake in the Southern Ocean, less uptake in the Pacific Ocean, and less global uptake. The large-scale spatial pattern of the estimated flux is generally insensitive to possible biases in the data and the models employed. However, the global uptake scales approximately linearly with changes in the global anthropogenic CO2 inventory. Considerable uncertainties remain in some regions, particularly the Southern Ocean.
    Description: This research was financially supported by the National Aeronautics and Space Administration under grant NAG5- 12528. N. G. also acknowledges support by the National Science Foundation (OCE-0137274). Climate and Environmental Physics, Bern acknowledges support by the European Union through the Integrated Project CarboOcean and the Swiss National Science Foundation.
    Keywords: Anthropogenic CO2 ; Carbon cycle ; Inverse modeling
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  • 12
    Publication Date: 2022-05-26
    Description: Author Posting. © American Geophysical Union, 2008. This article is posted here by permission of American Geophysical Union for personal use, not for redistribution. The definitive version was published in Global Biogeochemical Cycles 22 (2008): GB3025, doi:10.1029/2007GB003082.
    Description: Interannually varying net carbon exchange fluxes from the TransCom 3 Level 2 Atmospheric Inversion Intercomparison Experiment are presented for the 1980 to 2005 time period. The fluxes represent the model mean, net carbon exchange for 11 land and 11 ocean regions after subtraction of fossil fuel CO2 emissions. Both aggregated regional totals and the individual regional estimates are accompanied by a model uncertainty and model spread. We find that interannual variability is larger on the land than the ocean, with total land exchange correlated to the timing of both El Niño/Southern Oscillation (ENSO) as well as the eruption of Mt. Pinatubo. The post-Pinatubo negative flux anomaly is evident across much of the tropical and northern extratropical land regions. In the oceans, the tropics tend to exhibit the greatest level of interannual variability, while on land, the interannual variability is slightly greater in the tropics and northern extratropics. The interannual variation in carbon flux estimates aggregated by land and ocean across latitudinal bands remains consistent across eight different CO2 observing networks. The interannual variation in carbon flux estimates for individual flux regions remains mostly consistent across the individual observing networks. At all scales, there is considerable consistency in the interannual variations among the 13 participating model groups. Finally, consistent with other studies using different techniques, we find a considerable positive net carbon flux anomaly in the tropical land during the period of the large ENSO in 1997/1998 which is evident in the Tropical Asia, Temperate Asia, Northern African, and Southern Africa land regions. Negative anomalies are estimated for the East Pacific Ocean and South Pacific Ocean regions. Earlier ENSO events of the 1980s are most evident in southern land positive flux anomalies.
    Keywords: Carbon cycle ; Atmospheric inversion ; Interannual variability
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