ALBERT

All Library Books, journals and Electronic Records Telegrafenberg

X
feed icon rss

Your email was sent successfully. Check your inbox.

An error occurred while sending the email. Please try again.

Proceed reservation?

Export
Filter
  • Articles  (64)
  • crystal structure  (37)
  • meteor  (15)
  • Superconductivity  (12)
  • Springer  (64)
  • American Geophysical Union
  • American Institute of Physics (AIP)
  • American Physical Society
  • Blackwell Publishing Ltd
  • Institute of Physics
  • Oxford University Press
  • 1995-1999  (64)
  • 1945-1949
  • 1998  (64)
  • Physics  (63)
  • Electrical Engineering, Measurement and Control Technology  (13)
  • Natural Sciences in General
Collection
  • Articles  (64)
Source
Keywords
Publisher
  • Springer  (64)
  • American Geophysical Union
  • American Institute of Physics (AIP)
  • American Physical Society
  • Blackwell Publishing Ltd
    • +
Years
  • 1995-1999  (64)
  • 1945-1949
Year
Topic
  • 1
    Electronic Resource
    Electronic Resource
    Structure of a 1:1 complex between the anthelmintic drug mebendazole and propionic acid (1998)
    Springer
    Journal of chemical crystallography 28 (1998), S. 11-15 
    Details
    ISSN: 1572-8854
    Keywords: Mebendazole–propionic acid complex ; molecular complex ; crystal structure
    Source: Springer Online Journal Archives 1860-2000
    Topics: Geosciences , Physics
    Notes: Abstract Recrystallization of the anthelmintic drug mebendazole from propionic acid yields a 1:1 molecular complex which crystallizes in the triclinic system space group $${P\bar 1}$$ , a = 5.928(2), b = 11.066(2), c = 14.337(6)Å, α = 94.89(3), β = 101.56(3), γ = 96.18(2)°, and Z = 2 complex units in the unit cell. An x-ray diffraction study revealed an R 2 2 (8) hydrogen bonding system in the complex, involving the unprotonated imidazole N and amide N–H function of the drug and the acid carboxylic group. Complex molecules form centrosymmetric dimers by intermolecular N–H···O hydrogen bonding involving the protonated imidazole N atom and the benzoyl O atom of the drug molecule.
    Type of Medium: Electronic Resource
    URL: http://dx.doi.org/10.1023/A:1021766300133
    Location Call Number Expected Availability
    BibTip Others were also interested in ...
    Paper (German National Licenses)
    Fulltext
  • 2
    Electronic Resource
    Electronic Resource
    Crystal structure and EPR spectra of glycilglycilglycinocopper(II)bromide sesquihydrate (1998)
    Springer
    Journal of chemical crystallography 28 (1998), S. 61-68 
    Details
    ISSN: 1572-8854
    Keywords: Cu(II) complex ; crystal structure ; EPR spectra
    Source: Springer Online Journal Archives 1860-2000
    Topics: Geosciences , Physics
    Notes: Abstract The title compound, Cu(glyglygly)Br·1·5H2O, crystallizes in the space group C2/c, with a = 21.468(7), b = 6.716(5), c = 16.166(6) Å, β = 98.39°, and Z = 8. The tripeptide is bonded to one Cu(II) ion through the nitrogen [Cu–N=1.97(1)Å] and oxygen [Cu–O=2.019(8)Å] atoms of the amino end glycine residue and to another Cu(II) through one oxygen atom [Cu–O=1.931(9)Å] of the terminal carboxyl group. This give rise to covalently bonded and infinite ···–Cu–tripeptide–Cu–··· chains. These chains are linked to one another by a network of H-bonds involving the water molecules and bromide ions. The Cu(II) ion is in a distorted tetragonal pyramidal coordination polyhedron. At the corner of the base of the pyramid are the terminal glycine nitrogen and oxygen atoms of one tripeptide, a carboxylic oxygen of another tripeptide and a bromide ion. The fivefold coordination is completed with a water molecule at the top of the pyramid [Cu–Ow=2.286(9)Å]. For all orientations of the applied magnetic field the single crystal EPR spectra display a single anisotropic exchange collapsed resonance without hyperfine structure. Its position was measured in three perpendicular planes and the crystal g-tensor evaluated from the data. This tensor is interpreted in terms of the contributing Cu(II) complexes in the unit cell to deduce the principal values g1 = 2.273, g2 = 2.050 and g3 = 2.131 for the molecular gyromagnetic tensor. We also discuss the magnitude of the exchange interaction between neighboring copper ions in the lattice on the basis of the features in the EPR spectra and the structural information.
    Type of Medium: Electronic Resource
    URL: http://dx.doi.org/10.1023/A:1021734820606
    Location Call Number Expected Availability
    BibTip Others were also interested in ...
    Paper (German National Licenses)
    Fulltext
  • 3
    Electronic Resource
    Electronic Resource
    Reaction of 2-methylnaphthalene with hexachlorocyclopentadiene and structural characterization of a new addition-substitution product (1998)
    Springer
    Journal of chemical crystallography 28 (1998), S. 787-790 
    Details
    ISSN: 1572-8854
    Keywords: 2-Methylnaphthalene ; hexachlorocyclopentadiene ; crystal structure
    Source: Springer Online Journal Archives 1860-2000
    Topics: Geosciences , Physics
    Notes: Abstract 2-Methylnaphthalene undergoes Diels-Alder addition and substitution with hexachlorocyclopentadiene to give two products, 1,2,3,4,5,6,7,8,13,13,14,14-dodecachloro-1,4,4a,4b,5,8,8a,12b-octahydro-10-methyl-1,4;5,8-dimethanotriphenylene 1 and 1,2,3,4,5,6,7,8,13,13,14,14-dodecachloro-1,4,4a,4b,5,8,8a,12b-octahydro-10-(1′,2′,3′,4′,5′-pentachlorocyclopentadienyl)methyl-1,4;5,8-dimethanotriphenylene 2. The molecular structure of 2 has been characterized by X-ray crystallography: C26H9Cl17, monoclinic, space group P21/c, with a = 15.316(3), b = 13.698(3), c = 16.116(3) Å, β = 96.113(3)°, and Z = 4.
    Type of Medium: Electronic Resource
    URL: http://dx.doi.org/10.1023/A:1021819518557
    Location Call Number Expected Availability
    BibTip Others were also interested in ...
    Paper (German National Licenses)
    Fulltext
  • 4
    Electronic Resource
    Electronic Resource
    Synthesis and crystal structure of [(PhenH)(PhenH2)][BiCl6]·2H2O with different o-phenanthroline protonations (1998)
    Springer
    Journal of chemical crystallography 28 (1998), S. 791-796 
    Details
    ISSN: 1572-8854
    Keywords: Halobismuthate(III) ; phenanthroline ; synthesis ; crystal structure
    Source: Springer Online Journal Archives 1860-2000
    Topics: Geosciences , Physics
    Notes: Abstract The reaction between bismuthate oxide and phen (1,10-phenanthroline) in acid medium led to the isolation of the unusual [(PhenH)(PhenH2)][BiCl6]·2H2O derivative, which has been characterized by X-ray analysis and IR spectroscopy. The compound crystallizes in the triclinic space group $$[\text[P\bar 1]]$$ with a = 8.313(2), b = 9.349(2), c = 9.807(3) Å, α = 86.39(3), β = 110.27(3) and γ = 106.48(3)°. The crystal structure is made of [BiCl6]3− anions and [(PhenH)(PhenH2)]3+ cations. A network of hydrogen bond interactions involving the two clathrated water molecules, the phenanthroline moiety and the chlorines characterizes the entire structure.
    Type of Medium: Electronic Resource
    URL: http://dx.doi.org/10.1023/A:1021871502627
    Location Call Number Expected Availability
    BibTip Others were also interested in ...
    Paper (German National Licenses)
    Fulltext
  • 5
    Electronic Resource
    Electronic Resource
    Tris-(thiocyanato)-bis-(hexamethylenetetramine)-nona-(aquo) lanthanum(III): synthesis, crystal structure, IR and Raman characterization (1998)
    Springer
    Journal of chemical crystallography 28 (1998), S. 879-884 
    Details
    ISSN: 1572-8854
    Keywords: Lanthanum complex ; hexamethylenetetramine ; IR spectra ; thiocyanates ; coordination number nine ; tricapped trigonal prism ; crystal structure
    Source: Springer Online Journal Archives 1860-2000
    Topics: Geosciences , Physics
    Notes: Abstract The title compound (LaC15H42N11O9S3) was prepared and characterized by means of X-ray, IR and Raman measurements. The crystals are orthorhombic: Pnma (No. 62), a = 21.117(2), b = 14.736(2), c = 10.082(1) Å, and Z = 4. The structure consists of polyhedra with a La(III) ion in the center of them and hexamethylene molecules, which link these polyhedra. Each La(III) ion coordinates seven molecules of water and two thiocyanate ions via nitrogen atoms. The IR and Raman spectra, which have been obtained and interpreted, are in good agreement with X-ray results.
    Type of Medium: Electronic Resource
    URL: http://dx.doi.org/10.1023/A:1022846402229
    Location Call Number Expected Availability
    BibTip Others were also interested in ...
    Paper (German National Licenses)
    Fulltext
  • 6
    Electronic Resource
    Electronic Resource
    Preparation and crystal structures of the Ce(IV) β-diketonates, [Ce(tmhd)4] and [Ce(pmhd)4] (tmhd =2,2,6,6-tetramethylheptane-3,5-dionate and pmhd = 1-phenyl-5-methylhexane-1,3-dionate) (1998)
    Springer
    Journal of chemical crystallography 28 (1998), S. 267-276 
    Details
    ISSN: 1572-8854
    Keywords: Cerium(IV) ; β-diketonate ; volatility ; crystal structure
    Source: Springer Online Journal Archives 1860-2000
    Topics: Geosciences , Physics
    Notes: Abstract The cerium(IV) β-diketonate compounds [Ce(β-diket)4] [where β-diket = tmhd (2,2,6,6-tetramethylheptane-3,5-dionate) 1, pmhd (1-phenyl-5-methylhexane-1,3-dionate) 2] were prepared by reacting cerium(IV) ammonium nitrate [CAN; Ce(NH4)2(NO3)6] with the respective Na(β-diket) compound in ethanol, and structurally characterized by single crystal X-ray diffraction. Compound 1 crystallizes in the triclinic space group $$P \bar 1$$ with a = 12.472(4), b = 19.972(5), c = 21.436(3) Å, α = 97.05(7), β = 90.16(2), γ = 106.55(3)°, V = 5076(2) Å3, Z = 4, T = 150(2) K. Compound 2 crystallizes in the monoclinic space group P21/n. with a = 14.817(6), b = 17.123(6), c = 19.146(3) Å, β = 105.46(4)°, V = 4682(3) Å3, Z = 4, T = 150(2) K. Crystals of 1 contain two independent [Ce(tmhd)4] molecules, with four chelating tmhd ligands bonded to each metal in a distorted dodecahedral arrangement; the cerium atom in 2 is also bonded to four chelating pmhd ligands but in this case the coordination geometry is closer to square antiprism. Both complexes are air and moisture stable. Sublimation studies reveal that 1 sublimes almost quantitatively, while 2 is comparatively involatile.
    Type of Medium: Electronic Resource
    URL: http://dx.doi.org/10.1023/A:1021897102260
    Location Call Number Expected Availability
    BibTip Others were also interested in ...
    Paper (German National Licenses)
    Fulltext
  • 7
    Electronic Resource
    Electronic Resource
    Molecular structure and spectral characteristics of bis(S-methyl-N-(2-pyridyl)methylendithiocarbazato)nickel(II), (Ni(NNS)2) (1998)
    Springer
    Journal of chemical crystallography 28 (1998), S. 871-874 
    Details
    ISSN: 1572-8854
    Keywords: Nickel(II) complex ; crystal structure ; Schiff base
    Source: Springer Online Journal Archives 1860-2000
    Topics: Geosciences , Physics
    Notes: Abstract A nickel(II) complex of the pyridine-2-aldehyde Schiff base of S-methyldithiocarbazate (HNNS) has been synthesized and characterized by means of elemental analysis, IR and UV-vis spectra. The crystal structure of the complex has been determined by single-crystal X-ray diffraction. The complex crystallizes in the monoclinic, space P21/c, with a = 14.092(2), b = 16.886(2), c = 8.857(2)Å; β = 105.78(3) °, V = 2028.2(6) Å3, and Z = 4. The nickel atom is octahedrally coordinated by two uninegatively charged tridentate Schiff base in a mer-configuration via the pyridine nitrogen atom, azomethine nitrogen atom, and mecaptide sulfur atom.
    Type of Medium: Electronic Resource
    URL: http://dx.doi.org/10.1023/A:1022842301321
    Location Call Number Expected Availability
    BibTip Others were also interested in ...
    Paper (German National Licenses)
    Fulltext
  • 8
    Electronic Resource
    Electronic Resource
    Benztropine mesylate: crystal structure and kinetics of dehydration (1998)
    Springer
    Journal of chemical crystallography 28 (1998), S. 885-892 
    Details
    ISSN: 1572-8854
    Keywords: Benztropine mesylate ; crystal structure ; thermal analysis ; dehydration kinetics
    Source: Springer Online Journal Archives 1860-2000
    Topics: Geosciences , Physics
    Notes: Abstract The crystal structure of benztropine mesylate has been determined. It is orthorhombic, Pbca, with a = 12. 885(8)Å, b = 32.012(9)Å, and c = 10.027(3) Å. It exhibits similar packing to that seen in the previously reported crystal structure of benztropine mesylate monhydrate. X-ray powder diffraction patterns have been used to identify the anhydrous and monohydrate forms. The dehydration of the monohydrate follows a first-order reaction mechanism with activation energy of 92(8) kJ mol−1.
    Type of Medium: Electronic Resource
    URL: http://dx.doi.org/10.1023/A:1022898419067
    Location Call Number Expected Availability
    BibTip Others were also interested in ...
    Paper (German National Licenses)
    Fulltext
  • 9
    Electronic Resource
    Electronic Resource
    Synthesis and X-ray crystallographic characterization of [Cd(NO3)2(15-Crown-5)] and [Cd(NO3)2(18-Crown-6)] (1998)
    Springer
    Journal of chemical crystallography 28 (1998), S. 521-527 
    Details
    ISSN: 1572-8854
    Keywords: Cadmium ; crown ether ; 15-crown-5 ; 18-crown-6 ; crystal structure
    Source: Springer Online Journal Archives 1860-2000
    Topics: Geosciences , Physics
    Notes: Abstract Reaction of 15-crown-5 or 18-crown-6 in 3:1 (v/v) CH3CN:CH3OH with Cd(NO3)2·4H2O followed by slow evaporation produces [Cd(NO3)2(15-crown-5)] or [Cd(NO3)2(18-crown-6)]. Crystals of [Cd(NO3)2(15-crown-5)] are orthorhombic with space group Pbca and cell parameters a = 13.562(5), b = 15.941(9), and c = 15.011(7) Å at 295 K. [Cd(NO3)2(18-crown-6)] crystallizes in the monoclinic space group C2/c with a = 11.235(2), b = 11.196(5), c = 15.385(3) Å, and β = 99.89(2)° at 295 K. The metal center in [Cd(NO3)2(15-crown-5)] rests atop the macrocyclic donor array with two cis-bound nitrate anions and adopts a distorted tricapped trigonal prismatic geometry. [Cd(NO3)2(18-crown-6)] resides on an equatorial two-fold rotation axis with Cd2+ coordinated in the 18-crown-6 cavity and the nitrate anions oriented in twisted trans positions.
    Type of Medium: Electronic Resource
    URL: http://dx.doi.org/10.1023/A:1023239921542
    Location Call Number Expected Availability
    BibTip Others were also interested in ...
    Paper (German National Licenses)
    Fulltext
  • 10
    Electronic Resource
    Electronic Resource
    The crystal and molecular structure of (−)—Crinine (C16H17NO3) (1998)
    Springer
    Journal of chemical crystallography 28 (1998), S. 577-579 
    Details
    ISSN: 1572-8854
    Keywords: (−)—Crinine ; Pancratium ; alkaloid ; Amaryllidaceae ; crystal structure
    Source: Springer Online Journal Archives 1860-2000
    Topics: Geosciences , Physics
    Notes: Abstract (−)—Crinine, C16H17NO3, is an alkaloid extracted from the bulbs of Pancratium maritimum L. (Amaryllidaceae). The compound crystallizes in the space group P212121 with cell dimensions a = 6.040(1), b = 12.382(1), c = 17.861(2) Å, with Z = 4. The molecule has five rings and an OH group. The N-containing, five-membered ring and the D ring have envelope conformations. The A and B rings have distorted chair and half-chair conformations, respectively.
    Type of Medium: Electronic Resource
    URL: http://dx.doi.org/10.1023/A:1023256425176
    Location Call Number Expected Availability
    BibTip Others were also interested in ...
    Paper (German National Licenses)
    Fulltext
  • 11
    Electronic Resource
    Electronic Resource
    Crystal structure of 2,2,4,7,7-pentamethyl-3,6-dithiaoctane tetracarbonyl tungsten(0) (1998)
    Springer
    Journal of chemical crystallography 28 (1998), S. 217-220 
    Details
    ISSN: 1572-8854
    Keywords: Metal carbonyl complexes ; chelate complexes ; crystal structure
    Source: Springer Online Journal Archives 1860-2000
    Topics: Geosciences , Physics
    Notes: Abstract The x-ray crystal structure of the complex η2-PDOW(CO)4 (five-membered ring, PDO = 2, 2, 4, 7, 7-pentamethyl-3,6-dithiaoctane) is reported. The complex crystallizes in the monoclinic crystal system, space group P21/c, [#14] with unit cell parameters a = 14.002(14) Å, b = 9.340(10) Å, c = 15.094(12) Å, β = 92.67(4)°, V = 1972(3) Å3; Z = 4. The arrangement of the ligands around the metal atom is distorted from octahedral geometry. Large C–O bond distances and short W–C bond distances of the carbonyl groups located at a trans position with respect to PDO is indicative of a trans influence. The W–S(1) and W–S(2) bond distances of 2.545(3) and 2.545(2) Å, respectively, are shorter than observed for closely related complexes.
    Type of Medium: Electronic Resource
    URL: http://dx.doi.org/10.1023/A:1022478528825
    Location Call Number Expected Availability
    BibTip Others were also interested in ...
    Paper (German National Licenses)
    Fulltext
  • 12
    Electronic Resource
    Electronic Resource
    Crystal structure of tris(triphenylsiloxy)borane·triphenylsilanol (1:1) adduct (1998)
    Springer
    Journal of chemical crystallography 28 (1998), S. 277-281 
    Details
    ISSN: 1572-8854
    Keywords: Triphenylsiloxy ; silanol ; borane ; crystal structure ; adduct
    Source: Springer Online Journal Archives 1860-2000
    Topics: Geosciences , Physics
    Notes: Abstract The title compound crystallizes in the triclinic space group $$P \bar 1$$ , with a = 14.458(6), b = 14.630(5), c = 14.721(8) Å, α = 79.75(2), β = 80.11(3), γ = 80.50(3)°, and Z = 2. The crystal structure consists of molecules of (Ph3SiO)3B and Ph3SiOH linked by an weak B···(silanol) acceptor-donor bond, additionally stabilized by OH(silanol)···O(siloxy) hydrogen bonds. The average B–O, Si–O distances and B–O–Si angle are 1.369, 1.649 Å and 137.2°, respectively.
    Type of Medium: Electronic Resource
    URL: http://dx.doi.org/10.1023/A:1021849219098
    Location Call Number Expected Availability
    BibTip Others were also interested in ...
    Paper (German National Licenses)
    Fulltext
  • 13
    Electronic Resource
    Electronic Resource
    17α-acetoxy-17β-methyl-16β-phenyl-D-homo-4,6-pregnadiene-3,17a-dione: synthesis and crystal structure determination of a new rearranged pregnane derivative (1998)
    Springer
    Journal of chemical crystallography 28 (1998), S. 487-491 
    Details
    ISSN: 1572-8854
    Keywords: Steroid ; pregnadiene ; x-ray diffraction ; crystal structure
    Source: Springer Online Journal Archives 1860-2000
    Topics: Geosciences , Physics
    Notes: Abstract The title compound is C29H34O4, tetragonal, P43, a = b = 10.310(1), c = 23.871(2)Å. The A, B, C, and D rings adopt envelope, half-chair, chair, and distorted chair conformations, respectively. The phenyl ring is planar. The methyl substituents at the A/B, C/D, and at C(17) are axial; and the –OCOCH3 group at C(17) and phenyl ring at C(16) are equatorial. The molecules in the crystal are held together by van der Waals forces and several C–H···O hydrogen bond interactions.
    Type of Medium: Electronic Resource
    URL: http://dx.doi.org/10.1023/A:1021729007943
    Location Call Number Expected Availability
    BibTip Others were also interested in ...
    Paper (German National Licenses)
    Fulltext
  • 14
    Electronic Resource
    Electronic Resource
    Structure, absolute configuration, and conformation of the antimalarial compound, Artemisinin (1998)
    Springer
    Journal of chemical crystallography 28 (1998), S. 539-543 
    Details
    ISSN: 1572-8854
    Keywords: Antimalarial ; crystal structure ; peroxy bridge
    Source: Springer Online Journal Archives 1860-2000
    Topics: Geosciences , Physics
    Notes: Abstract The crystal and molecular structure of the antimalarial compound Artemisinin (formerly known as Qinghaosu), C15H22O5 has been determined by direct methods. Crystals are orthorhombic colorless needles, space group P212121, Z = 4. D c = 1.299 g cm −3, with unit cell parameters a = 6.3543(9), b = 9.439(3), c= 24.066(4) Å. The molecule incorporates a fused ring system containing a six-membered ring C which includes an oxygen bridge and a peroxy-bridge. The ring C has a distorted boat conformation and the C - O - O - C torsion angle is 47.8(2)°. Rings A and D have symmetrical chair and distorted chair conformations, repectively. Ring junctions A/B, A/D, and C/D are cis, junction B/D is trans. All inter-molecular contacts are van der Waals. The absolute configuration of Artemisinin was determined from the refined value of the Flack x parameter. [The atomic coordinates given in a previous structure analysis, “Crystal Structure and Absolute Configuration of Qinghaosu,” Qinghaosu Research Group, Institute of Biophysics, Academica Sinica, Scientia Sinica, Vol. XXIII No. 3, 380 (1980), do not display the molecule in its absolute configuration.]
    Type of Medium: Electronic Resource
    URL: http://dx.doi.org/10.1023/A:1023244122450
    Location Call Number Expected Availability
    BibTip Others were also interested in ...
    Paper (German National Licenses)
    Fulltext
  • 15
    Electronic Resource
    Electronic Resource
    Cluster Complexes of Polythioether Macrocycles: The Synthesis and Molecular Structures of Ru6(CO)13(cis-SCH2 CHMe(CH2SCH2CHMe)2CH2)(μ6-C) and Ru6(CO)13(trans-SCH2 CHMe(CH2SCH2CHMe)2CH2)(μ6-C) (1998)
    Springer
    Journal of cluster science 9 (1998), S. 93-105 
    Details
    ISSN: 1572-8862
    Keywords: Ruthenium ; thioether macrocycle ; crystal structure
    Source: Springer Online Journal Archives 1860-2000
    Topics: Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics , Physics
    Notes: Abstract The reaction of a mixture of cis-3,7,11-trimethyl-1,5,9-trithiacyclododecane, cis-Me312S3, 1 and trans-3,7,11-trimethyl-l,5,9-trithiacyclododecane, trans-Me312S3, 2, with Ru6(CO)17(μ 6-C), 3, yielded three new cluster compounds Ru6(CO)13(μ-η3-cis-SCH2CHMe(CH2SCH2CHMe)2CH2)(μ 6-C) 4, and two isomers of Ru6(CO)13(μ-η3-cis-SCH2CHMe(CH2SCH2CHMe)2CH2)(μ 6-C) 5a and 5b. The molecular structures of 4 and 5b were established by single crystal X-ray diffraction analyses. In both complexes, the macrocycles have adopted tridentate coordination with one of the sulfur atoms in a bridging position. Two carbonyl ligands occupy bridging positions in each compound. Crystal Data for 4·Me2CO: space group=P21/n, a=11.295(1) Å, b=17.547(3) Å, c=20.318(3) Å, β=93.71(1)°, Z=4, 2900 reflections, R=0.025. Crystal Data for 5b·1.5 C6H6: space group=Pbca, a=31.8900(8) Å, b=23.4330(6) Å, c=21.6240(4) Å, Z=16, 12163 reflections, R=0.040.
    Type of Medium: Electronic Resource
    URL: http://dx.doi.org/10.1023/A:1022681523508
    Location Call Number Expected Availability
    BibTip Others were also interested in ...
    Paper (German National Licenses)
    Fulltext
  • 16
    Electronic Resource
    Electronic Resource
    The First New Hydrogen-Bonded Heterohexanuclear Complex [(salen)Cu]4[(salen)Fe(H2O)2]2(ClO4)2: Molecular and Crystal Structure and Magnetic Properties (1998)
    Springer
    Journal of cluster science 9 (1998), S. 465-471 
    Details
    ISSN: 1572-8862
    Keywords: Mixed-metal cluster ; crystal structure ; magnetic properties
    Source: Springer Online Journal Archives 1860-2000
    Topics: Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics , Physics
    Notes: Abstract The preparation, magnetic properties, and crystal structure of [(salen)Cu]4[(salen)Fe(H2O)2]2(ClO4)2 via hydrogen bonding are described [salen=N,N′-ethylenebis (salicylideneiminate)]. Crystals are triclinic, of space group $$\rm P\bar 1$$ , with cell constants a=12.853(3), b=13.921(3), c=14.251(3) Å, α=68.68(3)°, β=87.86(3)°, γ=86.82(3)°, and Z=1. The structure was solved and refined to R=0.064 and R′=0.068. The structure comprises the hexanuclear units which result from the linking of four mononuclear fragments [(salen)Cu] and two mononuclear fragment [(salen)Fe(H2O)]+, through Cu -O ⋯ H -O -Fe -O -H ⋯ O -Cu hydrogen bonds of coordinating H2O. In this complex, FeIII ions are in almost square-planar surroundings. The temperature dependences of the magnetic susceptibilities of the complex have been studied in the 4.2–300 K range, indicating the presence of an antiferromagnetic interactions between metal ions.
    Type of Medium: Electronic Resource
    URL: http://dx.doi.org/10.1023/A:1021990516837
    Location Call Number Expected Availability
    BibTip Others were also interested in ...
    Paper (German National Licenses)
    Fulltext
  • 17
    Electronic Resource
    Electronic Resource
    Direct Evidence for Metal Triangle Mobility within a Relatively Rigid Ligand Polytope: Dynamic Disorder in the X-Ray Crystal Structures of Ru3(CO)11(L), L=CN t Bu, PMe3, and Ru3(CO)9{P(OMe)3}3 (1998)
    Springer
    Journal of cluster science 9 (1998), S. 505-528 
    Details
    ISSN: 1572-8862
    Keywords: Dynamic disorder ; crystal structure ; ruthenium cluster
    Source: Springer Online Journal Archives 1860-2000
    Topics: Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics , Physics
    Notes: Abstract The disorder in the X-ray crystal structures of Ru3(CO)11(L), L=CN t Bu 1 and PMe3 3 has been re-examined. Crystallographic data for 1 at 100 K: C16H9NO11Ru3, space group P21/n, a=11.796(5), b=11.748(2), c=16.040(7) Å, β=109.81(3)°, Z=4, 6077 reflections, R=0.028. For 3 at 223 K: C14H9O11PRu3, space group P21/n, a=8.5971(15), b=12.391(7), c=40.345(8) Å, β=94.43(2)°, Z=8, 7966 reflections, R=0.031. The disorder present in 1 and 3 at room temperature disappears reversibly on cooling, showing that it is dynamic in origin. The ligator atoms of the isonitrile and phosphine ligands move by a maximum of ∼0.8 Å, indicating that the whole cluster does not rotate intact within the crystal lattice, but rather that the Ru3 triangle effectively oscillates within a relatively rigid ligand polyhedron. The crystal structure of Ru3(CO)9{P(OMe)3 3} 7, which crystallizes in triclinic (7-t) and monoclinic (7-m) modifications is also reported. Both modifications have two independent molecules in the asymmetric unit, and both modifications display dynamic disorder in the metal framework. Crystalllographic data for 7-t at 173 K: C18H27O18P3Ru3, space group P-1, a=11.8085(18), b=15.915(2), c=17.350(3) Å, α=99.929(14), β=101.811(14), γ=90.630(12)°, Z=4, 11242 reflections, R=0.048. For 7-m at 120 K: C18H27O18P3Ru3, space group P21/c, a=11.708(8), b=15.922(5), c=33.950(10) Å, β=99.29(4), Z=8, 10191 reflections, R=0.027.
    Type of Medium: Electronic Resource
    URL: http://dx.doi.org/10.1023/A:1021946701816
    Location Call Number Expected Availability
    BibTip Others were also interested in ...
    Paper (German National Licenses)
    Fulltext
  • 18
    Electronic Resource
    Electronic Resource
    Electroless deposition of Ni–B, Co–B and Ni–Co–B alloys using dimethylamineborane as a reducing agent (1998)
    Springer
    Journal of applied electrochemistry 28 (1998), S. 559-563 
    Details
    ISSN: 1572-8838
    Keywords: electroless Ni–Co–B alloy ; dimethylamineborane ; complexing agent ; deposition rate ; crystal structure
    Source: Springer Online Journal Archives 1860-2000
    Topics: Chemistry and Pharmacology , Electrical Engineering, Measurement and Control Technology
    Notes: Abstract Fundamental aspects of electroless Ni–B, Co–B and Ni–Co–B alloys have been systematically examined. The composition, crystal structure and deposition rate of the alloys were determined as a function of the concentration of reducing agent (dimethylamineborane) and complexing agents (tartrate, citrate, malonate and succinic acid), bath pH and Ni2+/Co2+ ratio. Changes in the deposition rate and metallurgical features of the alloys induced by the change in plating parameters are discussed, based on electrochemical polarization data and the formation enthalpy of the nickel and cobalt borides.
    Type of Medium: Electronic Resource
    URL: http://dx.doi.org/10.1023/A:1003233715362
    Location Call Number Expected Availability
    BibTip Others were also interested in ...
    Paper (German National Licenses)
    Fulltext
  • 19
    Electronic Resource
    Electronic Resource
    Structural and magnetic properties of a syn-anti carboxylate bridged one-dimensional copper(II) complex with ferromagnetic exchange interaction (1998)
    Springer
    Journal of chemical crystallography 28 (1998), S. 771-777 
    Details
    ISSN: 1572-8854
    Keywords: Copper ; 1,10-phenanthroline ; trifluoroacetate ; crystal structure ; magnetic exchange
    Source: Springer Online Journal Archives 1860-2000
    Topics: Geosciences , Physics
    Notes: Abstract The compound [Cu(phen)(O2CCF3)2]n (phen = 1,10-phenanthroline) has been synthesized and its crystal structure determined. It crystallizes in monoclinic space group C2/c, with a = 19.229(7), b = 11.281(5), c = 7.621(2) Å, β = 104.305(12)°, and Z = 4. The crystal structure is polymeric, being built from infinite zigzag chains of trifluoroacetate bridged copper(II), with the phenanthroline ligands being stacked between the chains. The variable-temperature (13–300 K) magnetic susceptibility and ESR data are reported and a weak ferromagnetic exchange interaction is observed with the exchange parameter estimated as J = 2.9 cm−1.
    Type of Medium: Electronic Resource
    URL: http://dx.doi.org/10.1023/A:1021820729518
    Location Call Number Expected Availability
    BibTip Others were also interested in ...
    Paper (German National Licenses)
    Fulltext
  • 20
    Electronic Resource
    Electronic Resource
    Crystal structure of chloro(dicarbonyl) bis(acetonitrile) (π-2-methallyl) molybdenum(II) (1998)
    Springer
    Journal of chemical crystallography 28 (1998), S. 839-841 
    Details
    ISSN: 1572-8854
    Keywords: π-allyl ; carbonyl ; nitrile ; chloro ; crystal structure
    Source: Springer Online Journal Archives 1860-2000
    Topics: Geosciences , Physics
    Notes: Abstract The title compound crystallizes in the monoclinic spacegroup P21/m with a = 6.796(9), b = 12.145(14), c = 7.749(8)Å, β = 101.86(1)°, and Z = 2. The crystal structure consists of molecules of [MoCl(CO)2(NCMe)2(η3-C3H4Me-2)] with crystallographically imposed Cs symmetry and has a pseudo-octahedral geometry, with the π-allyl group trans- to the chloro group and the two cis-carbonyl and acetonitrile groups occupying the equatorial plane.
    Type of Medium: Electronic Resource
    URL: http://dx.doi.org/10.1023/A:1021836022191
    Location Call Number Expected Availability
    BibTip Others were also interested in ...
    Paper (German National Licenses)
    Fulltext
  • 21
    Electronic Resource
    Electronic Resource
    The true nature of a complex of 1,10-phenanthroline with the ammonium ion; crystal structure of bis-phenanthrolineprotium perchlorate (1998)
    Springer
    Journal of chemical crystallography 28 (1998), S. 611-619 
    Details
    ISSN: 1572-8854
    Keywords: 1,10-Phenanthroline ; bis-phenanthrolineprotium ; adduct ; crystal structure ; hydrogen bonding
    Source: Springer Online Journal Archives 1860-2000
    Topics: Geosciences , Physics
    Notes: Abstract Herzog's reported bis-1,10-phenanthrolineammonium perchlorate, [(phen)2(NH4)](ClO4) is in fact the known 2:1 adduct of l,10-phenanthroline (phen) with perchloric acid, [(phen)2H](CIO4). Its crystal structure, mode of formation, and properties are described. The compound crystallizes in the triclinic space group with $$P\bar 1$$ , a = 7.2510(8), b = 13.120(2), c = 22.083(12) Å, α = 77.4550(12), β = 84.45(2), γ = 82.204(14)°, V = 2026.7(6) Å3, Z = 4, and D c = 1.510 g cm−3. It contains cationic columns of alternating 1,10-phenanthroline and its conjugate acid.
    Type of Medium: Electronic Resource
    URL: http://dx.doi.org/10.1023/A:1022460909589
    Location Call Number Expected Availability
    BibTip Others were also interested in ...
    Paper (German National Licenses)
    Fulltext
  • 22
    Electronic Resource
    Electronic Resource
    Crystal structure of the cytotoxic marine alkaloid 2-bromoleptoclinidinone (1998)
    Springer
    Journal of chemical crystallography 28 (1998), S. 645-648 
    Details
    ISSN: 1572-8854
    Keywords: 2-Bromoleptoclinidinone ; marine alkaloid ; cytotoxic ; crystal structure
    Source: Springer Online Journal Archives 1860-2000
    Topics: Geosciences , Physics
    Notes: Abstract 2-Bromoleptoclinidinone methanol solvate, C18H8BrN3O·CH4O, crystallizes in the orthorhombic space group Pbca with a = 15.7013(2), b = 7.3308(1), and c = 26.9326(1) Å. The molecule is essentially planar, with the largest deviations occurring at bromine (−0.21 Å), carbonyl oxygen O(l) (+0.19 Å) and in ring-A (C(9) −0.15 Å, C(10) −0.15 Å). Methanol occupies the 1,10-phenanthroline-like metal binding site of the title compound.
    Type of Medium: Electronic Resource
    URL: http://dx.doi.org/10.1023/A:1022421328245
    Location Call Number Expected Availability
    BibTip Others were also interested in ...
    Paper (German National Licenses)
    Fulltext
  • 23
    Electronic Resource
    Electronic Resource
    Synthesis and crystal structure of N 12-(7-chloro-4-quinolinyl)-N 1,N 1-diethy1-1,12-diaminododecane (AQ-40) (1998)
    Springer
    Journal of chemical crystallography 28 (1998), S. 925-929 
    Details
    ISSN: 1572-8854
    Keywords: Quinoline ; chloroquine ; antimalarial ; crystal structure
    Source: Springer Online Journal Archives 1860-2000
    Topics: Geosciences , Physics
    Notes: Abstract The preparation of N12-(7-chloro-4-quinolinyl)-N 1,N 1-diethyl-1,12-diaminododecane, AQ-40, was accomplished by a five-step process in 80% overall yield from 12-aminododecanoic acid and 4,7-dichloroquinoline. AQ-40 crystallizes as a monohydrate from reagent grade chloroform/ diethyl ether mixtures in the triclinc space group P-1 with a = 8.667(2), b = 8.9425(10), c = 17.217(3) Å, α = 99.34(1), β = 99.89(2), γ = 91.56(1)°, V = 1295.0 Å3 and Z = 2. The l2-(N 1,N 1-diethylamino)dodecyl side chain is in the fully extended conformation and the water molecule forms hydrogen bonds to the two tertiary nitrogen atoms as well as with the secondary amino group. The nitrogen of the secondary amino group bound to the four-position of the quinoline moiety is virtually planar. This together with the rather short C–N distance of 1.347(3) Å to the quinoline moiety suggests involvement of the lone pair on this nitrogen with the π system of the ring.
    Type of Medium: Electronic Resource
    URL: http://dx.doi.org/10.1023/A:1022810821793
    Location Call Number Expected Availability
    BibTip Others were also interested in ...
    Paper (German National Licenses)
    Fulltext
  • 24
    Electronic Resource
    Electronic Resource
    Molecular structure of trans-[Co(NH3)4(NH2CH3)Cl](ClO4)2 (1998)
    Springer
    Journal of chemical crystallography 28 (1998), S. 69-72 
    Details
    ISSN: 1572-8854
    Keywords: Co(III) complex ; crystal structure ; kinetics ; steric effects
    Source: Springer Online Journal Archives 1860-2000
    Topics: Geosciences , Physics
    Notes: Abstract The title compound crystallizes in the orthorhombic space group Pnma, with a = 7.9209(5), b = 9.818(1), c = 16.867(2) Å, and Z = 4. The structure was solved employing 1864 independent x-ray reflections with I〉2σ(I) by Patterson and difference Fourier techniques and refined by full-matrix least-squares to R = 0.036. The trans-[CO(NH3)4(NH2CH3)Cl](ClO4)2 molecule is on a crystallographic mirror plane. The cobalt ion is in an elongated octahedral coordination with four equatorial ammonia ligands [average Co–N distance equal to 1.966(2) Å], an axial methylamine [Co–N=1.965(3)Å], and an axial chlorine ion [Co–Cl=2.2771(9)Å]. Kinetic steric effects of the complex are interpreted in terms of structural results.
    Type of Medium: Electronic Resource
    URL: http://dx.doi.org/10.1023/A:1021786804676
    Location Call Number Expected Availability
    BibTip Others were also interested in ...
    Paper (German National Licenses)
    Fulltext
  • 25
    Electronic Resource
    Electronic Resource
    Crystal structure of NH3(CH2)2NH3BiCl5·2H2O (1998)
    Springer
    Journal of chemical crystallography 28 (1998), S. 209-212 
    Details
    ISSN: 1572-8854
    Keywords: Bismuth ; crystal structure ; inorganic polymer
    Source: Springer Online Journal Archives 1860-2000
    Topics: Geosciences , Physics
    Notes: Abstract The ethylenediammonium pentachlorobismuthate(III) dihydrate salt is monoclinic with the following unit cell dimensions: a = 10.902(8)Å, b = 7.926(6)Å, c = 15.199(6)Å, β = 96.40(1)°, space group P21/n with Z = 4. The structure shows a layer arrangement parallel to the $$\vec a$$ axis: planes of the [Bi2Cl10]4− bioctahedra alternate with planes of [NH3(CH2)2NH3]2+ dications. The [Bi2Cl10]4− bioctahedra are connected through O(W)–H··· Cl hydrogen bonds, so that infinite unidimensional chains of composition [Bi2Cl10(H2O)2] n 4n− are formed in the structure parallel to the $$\vec a$$ axis. These chains are themselves interconnected by means of the N–H···Cl bonds originating from the [NH3(CH2)2NH3]2+ entities, forming a three-dimensional network.
    Type of Medium: Electronic Resource
    URL: http://dx.doi.org/10.1023/A:1022474327917
    Location Call Number Expected Availability
    BibTip Others were also interested in ...
    Paper (German National Licenses)
    Fulltext
  • 26
    Electronic Resource
    Electronic Resource
    The synthesis and X-ray structure of [Sr2(OSiPh3)4(NH3)5]·0.5C7H8 (1998)
    Springer
    Journal of chemical crystallography 28 (1998), S. 221-226 
    Details
    ISSN: 1572-8854
    Keywords: Strontium ; triphenylsiloxy ; crystal structure ; ammonia
    Source: Springer Online Journal Archives 1860-2000
    Topics: Geosciences , Physics
    Notes: Abstract The title complex [Sr2(OSiPh3)4(NH3)5]·0.5C7H8 was prepared by the reaction of strontium metal granules with triphenylsilanol in an ammoniacal-toluene solution at −40°C. It crystallizes in monoclinic space group P21/n with a = 14.465(3), b = 20.715 (6), c = 25.199(6) Å, β = 95.98(2)°, and Z = 4. The complex has a dimeric structure with one terminal and three bridging triphenylsiloxy ligands, the remaining coordination sites being occupied by five ammonia molecules. The central Sr2O4N5 moiety adopts a distorted M2X9 face-sharing bioctahedral arrangement.
    Type of Medium: Electronic Resource
    URL: http://dx.doi.org/10.1023/A:1022430612896
    Location Call Number Expected Availability
    BibTip Others were also interested in ...
    Paper (German National Licenses)
    Fulltext
  • 27
    Electronic Resource
    Electronic Resource
    Crystal structure of mixed rubidium–ammonium hydrogen sulfate Rb0.7(NH4)0.3HSO4 at room temperature (1998)
    Springer
    Journal of chemical crystallography 28 (1998), S. 335-338 
    Details
    ISSN: 1572-8854
    Keywords: Mixed rubidium–ammonium acid sulfate ; crystal structure
    Source: Springer Online Journal Archives 1860-2000
    Topics: Geosciences , Physics
    Notes: Abstract The structure of Rb0.7(NH4)0.3HSO4 has been determined by X-ray analysis. The mixed compound crystallizes in the monoclinic space group P21/n with unit cell parameters a = 14.374(6) Å, b = 4.618(6) Å, c = 14.412(2) Å, β = 118.03(2)°, V = 844.4(4) Å3, and D cal = 1.536 g cm−3 for Z = 8. The mixed compound Rb0.7(NH4)0.3HSO4 is a chain-based structure. The Rb+ and NH4 + cations are intercalated between chains, formed of HSO4 - groups linked with OH⋯O hydrogen-bonding. Rb0.7(NH4)0.3HSO4 presents a new type of structural arrangement different from those of pure RbHSO4 and NH4HSO4.
    Type of Medium: Electronic Resource
    URL: http://dx.doi.org/10.1023/A:1022451822967
    Location Call Number Expected Availability
    BibTip Others were also interested in ...
    Paper (German National Licenses)
    Fulltext
  • 28
    Electronic Resource
    Electronic Resource
    The crystal and molecular structures of isoperezone, aminoperezone, and isoaminoperezone: a comparative study of their crystal packing (1998)
    Springer
    Journal of chemical crystallography 28 (1998), S. 529-537 
    Details
    ISSN: 1572-8854
    Keywords: 2-[1,5-Dimethyl-4-hexenyl]-6-hydroxy-5-methyl-1,4-benzoquinone ; 2-[1,5-dimethyl-4-hexenyl]-6-amino-3-hydroxy-5-methyl-1,4-benzoquinone ; 2-[1,5-dimethyl-4-hexenyl]-3-amino-6-hydroxy-5-methyl-1,4-benzoquinone ; crystal structure
    Source: Springer Online Journal Archives 1860-2000
    Topics: Geosciences , Physics
    Notes: Abstract The crystal structures of isoperezone (1), aminoperezone (2), and isoaminoperezone (3) have been determined by single-crystal X-ray diffraction. Compound (1) yields orange crystals, orthorhombic space group P212121 with unit cell dimensions a = 6.271(6), b = 30.373(7), c = 7.257(1) Å, and Z = 4; compound (2) yields purple crystals, orthorhombic space group P212121 with unit cell dimensions a = 6.498(3), b = 7.500(1) c = 29.200(6) Å, and Z = 4; compound (3) yields purple crystals, monoclinic space group P21 with unit cell dimensions a = 7.354(1), b = 7.511(1), c = 13.283(1) Å, β = 102,07(1)°, and Z = 2. The side chains in (1)–(3) are oriented out of the plane of the quinone ring at an angle of 124, 144, and 97°, respectively. The molecules in the crystal are held together by hydrogen-bonding networks and van der Waals interactions.
    Type of Medium: Electronic Resource
    URL: http://dx.doi.org/10.1023/A:1023292005612
    Location Call Number Expected Availability
    BibTip Others were also interested in ...
    Paper (German National Licenses)
    Fulltext
  • 29
    Electronic Resource
    Electronic Resource
    Crystal structure of [WI2(CO)3{P(OMe)3}2] (1998)
    Springer
    Journal of chemical crystallography 28 (1998), S. 639-643 
    Details
    ISSN: 1572-8854
    Keywords: Tungsten(II) ; diiodo ; carbonyl ; trimethylphosphite ; crystal structure
    Source: Springer Online Journal Archives 1860-2000
    Topics: Geosciences , Physics
    Notes: Abstract [WI2(CO)3{P(OMe)3}2]crystallizes in the orthorhombic space group Pca21, with a = 26.924(5), b = 10.726(2), c = 14.136(3) Å, and Z = 8. There are two molecules in the asymmetric unit, the metal atoms in each case being seven-coordinate with a capped fac-(CO)3 octahedral geometry. The molecular dimensions in the two molecules are nearly identical. The W–P distance to the capping atom 2.397 Å (average) is significantly shorter than the other W–P distance, 2.525 Å (average).
    Type of Medium: Electronic Resource
    URL: http://dx.doi.org/10.1023/A:1022469211406
    Location Call Number Expected Availability
    BibTip Others were also interested in ...
    Paper (German National Licenses)
    Fulltext
  • 30
    Electronic Resource
    Electronic Resource
    Asymmetric hetero-Diels-Alder reactions: X-ray structures of three novel chiral dihydropyrimidines (1998)
    Springer
    Journal of chemical crystallography 28 (1998), S. 663-671 
    Details
    ISSN: 1572-8854
    Keywords: Pyrimidine ; carboxamide ; sulfonyl ; chiral ; crystal structure
    Source: Springer Online Journal Archives 1860-2000
    Topics: Geosciences , Physics
    Notes: Abstract Three novel dihydropyrimidine compounds N8,6-di(4-nitrophenyl)-(3R)-ethyl-(7R)-methyl-5-oxo-2,3,6,7-tetrahydrooxazolo[3,2,c] pyrimidine-8-carboxamide (2), N8,6-di((4-methylphenyl)-sulfonyl)-(3R)-ethyl-5-oxo-(7R)-phenyl-2,3,6,7-tetrahydrooxazolo [3,2,c]pyrimidine-8-carboxamide (3) and N8,6-di ((4-methylphenyl)sulfonyl)-(3R)-ethyl-(7R)-methyl-5-oxo-2,3,6,7-tetrahydrooxazolo[3,2,c] pyrimidine-8-carboxamide (4) have been prepared (from 2-amino-1-butanol of 64.4% e.e.) and structurally characterized by X-ray crystallography. All three compounds contain stereogenic centers, but the crystal of (2) chosen was found to be racemic whilst those of (3) and (4) were found to be homochiral. Compound (2) crystallizes in the monoclinic space group P21/c, with a = 17.958(4), b = 12.431(2), c = 9.653(2) Å, β = 96.20(3)°, U = 2142.3(7) Å3, Z = 4, and D c = 1.449 g cm−3. Compounds (3) and (4) both crystallize in the monoclinic space group P21, with a = 9.349(2), b = 5.824(5), c = 26.513(8) Å, β = 99.43(2)°, U = 1424.1(13) Å3, Z = 2 and D c = 1.389 g cm−3 for (3), and a = 5.9526(9), b = 16.3521(10), c = 13.2263(11) Å, β = 92.81(12)°, U = 1285.9(2) Å3, Z = 2 and D c = 1.378 g cm−3 for (4).
    Type of Medium: Electronic Resource
    URL: http://dx.doi.org/10.1023/A:1021791832534
    Location Call Number Expected Availability
    BibTip Others were also interested in ...
    Paper (German National Licenses)
    Fulltext
  • 31
    Electronic Resource
    Electronic Resource
    The synthesis and crystallographic characterization of the heterotrimetallic linear complex [Et4N][(Ph3P)2{CuS2MoS2Fe}Br2] (1998)
    Springer
    Journal of chemical crystallography 28 (1998), S. 713-716 
    Details
    ISSN: 1572-8854
    Keywords: Heterotrimetallic sulfido cluster ; linear ; synthesis ; crystal structure
    Source: Springer Online Journal Archives 1860-2000
    Topics: Geosciences , Physics
    Notes: Abstract The complex Cu(PPh3)3I reacts with [Et4N]2MoS4 and FeBr2 to give the heterotrimetallic complexes [Et4N][(Ph3P)2{CuS2MoS2Fe}Br2] (1). [Et4N][(Ph3P)2{CuS2MoS2Fe}Br2] (1) crystallizes in the triclinic space group P-1, a = 13.537(4), b = 15.316(4), c = 12.381(4) Å, α = 105.16(2), β = 93.27(3), γ = 101.18(2)°, and V = 2415.0(12) Å3 for Z = 2. The three metal atoms of the structure [Et4N][(Ph3P)2{CuS2MoS2Fe}Br2] (1) are nearly distributed along a line, where three metal atoms (Mo, Cu, Fe) are each in an approximate tetrahedral coordination, the lengths Mo-Fe and Mo-Cu distances are 2.772(2) and 2.798(2) Å, respectively.
    Type of Medium: Electronic Resource
    URL: http://dx.doi.org/10.1023/A:1021756319330
    Location Call Number Expected Availability
    BibTip Others were also interested in ...
    Paper (German National Licenses)
    Fulltext
  • 32
    Electronic Resource
    Electronic Resource
    [CaSb2(EDTA)2(H2O)8]n: synthesis, crystal structure, and thermal behavior (1998)
    Springer
    Journal of chemical crystallography 28 (1998), S. 447-452 
    Details
    ISSN: 1572-8854
    Keywords: Bimetallic EDTA complex ; crystal structure ; antimony
    Source: Springer Online Journal Archives 1860-2000
    Topics: Geosciences , Physics
    Notes: Abstract The synthesis and crystal structure of a new EDTA complex, [CaSb2(EDTA)2(H2O)8]n, are reported. This compound crystallizes in the monoclinic space group P21/n, with a = 7.132(1) Å, b = 21.893(3) Å, c = 10.891(2) Å, β = 91.15(2)°. Sb(EDTA) entities are connected through carboxylate bridges to the calcium atoms resulting in layers parallel to the (101) plane. These layers are linked through a weak Sb···O bond (3.171 Å). Pyrolysis of this complex under sulfur vapor, between 400 and 800°C, leads to a mixture of the monometallic sulfides. Pyrolysis in air above 700°C allows the easy preparation of the mixed oxide CaSb2O6.
    Type of Medium: Electronic Resource
    URL: http://dx.doi.org/10.1023/A:1021716605217
    Location Call Number Expected Availability
    BibTip Others were also interested in ...
    Paper (German National Licenses)
    Fulltext
  • 33
    Electronic Resource
    Electronic Resource
    Crystal structure of (3,3′,4,4′-tetramethyl-1,1′-diphosphaferrocen-2-yl) carboxylic acid and its bis-[W(CO)5] complex·0.5C5H12: Conformation of 1,1′-diphosphaferrocenes (1998)
    Springer
    Journal of chemical crystallography 28 (1998), S. 621-628 
    Details
    ISSN: 1572-8854
    Keywords: 1-1′-Diphosphaferrocene conformation ; P···P secondary bonding ; bis-[W(CO)5](l,l′-diphosphaferrocene system) ; crystal structure
    Source: Springer Online Journal Archives 1860-2000
    Topics: Geosciences , Physics
    Notes: Abstract The structures of (3,3′,4,4′-tetramethyl-1,1′-diphosphaferrocen-2-yl)carboxylic acid (1) and its bis-[W(CO)5] pentane solvate complex (2) have been determined by X-ray analysis. The compound 1 crystallizes in the monoclinic P21 /n space group with Z = 4; a = 7.8404(9), b = 14.9441(16), c = 11.7730(14) Å, β = 92.773(10)°, V = 1377.8(3) Å3, and Dcalc = 1.553 g cm−3. The compound 2 crystallizes in the triclinic $$P\bar 1$$ space group with two complex molecules and one pentane molecule in the unit cell. Cell parameters: a = 10.7070(2), b = 12.577(2), c = 13.239(3) Å, α = 84.00(2), β = 77.58(1), γ = 66.06(1)°, V = 1591.0(5) Å3, and Dcalc = 2.100 g cm−3 .The fully eclipsed conformation of the phospholyl rings with P···P secondary bonding of 3.353(1) Å is observed in 1 and a partially eclipsed conformation is found in 2. The 10 possible conformations of 1,1′-diphosphaferrocenes were described as the function of conformational parameter θ and observed geometry of the phospholyl rings.7 We suppose that the earlier conclusions concerning the destabilizing nature of 1,1′-diphosphaferrocene conformations with θ 〈 100° cannot be considered as general. The mode of W – P coordination, the structural changes of 1 by W(CO)5 coordination, the structural effect of phospholyl rings substitution by the –COOH group, and hydrogen bonds are analyzed.
    Type of Medium: Electronic Resource
    URL: http://dx.doi.org/10.1023/A:1022413026427
    Location Call Number Expected Availability
    BibTip Others were also interested in ...
    Paper (German National Licenses)
    Fulltext
  • 34
    Electronic Resource
    Electronic Resource
    Crystal structure of [Co(o-SC6H4NH2){P(OMe)3}3]PF6 (1998)
    Springer
    Journal of chemical crystallography 28 (1998), S. 635-638 
    Details
    ISSN: 1572-8854
    Keywords: Cobalt(II) ; 2-aminobenzenethiol ; trimethylphosphite ; crystal structure
    Source: Springer Online Journal Archives 1860-2000
    Topics: Geosciences , Physics
    Notes: Abstract A cobalt-thiolato-phosphite complex [Co(o-SC6H4NH2){P(OMe)3}3]PF6 has been prepared and characterized by X-ray crystallography. The complex crystallizes in the triclinic space group $$P\bar 1$$ with a = 10.590(4), b = 11.122(3), c = 13.577(5) Å, α = 101.85(1), β = 108.50(1), γ = 101.75(1)°, V = 1420.6(8) Å3, and Z = 2. The structure comprises discrete [Co(o-SC6H4NH2){P(OMe)3}3]+ cations and PF 6 − anions where the metal atom is coordinated in a highly distorted square-pyramidal environment by one chelate o-SC6H4NH 2 − (abt) and two P(OMe)3 ligands in the basal positions, and a third P(OMe)3 in the axial site with Co–N,, 1.847(5), Co–S, 2.166(2), Co–P, 2.157(2), 2.147(2), and 2.125(2) Å.
    Type of Medium: Electronic Resource
    URL: http://dx.doi.org/10.1023/A:1022417127336
    Location Call Number Expected Availability
    BibTip Others were also interested in ...
    Paper (German National Licenses)
    Fulltext
  • 35
    Electronic Resource
    Electronic Resource
    Crystal Structure of the Sought-After Tetrameric [(PDBP)AgCl]4 Cluster (PDBP=5-Phenyldibenzophosphole) (1998)
    Springer
    Journal of cluster science 9 (1998), S. 547-554 
    Details
    ISSN: 1572-8862
    Keywords: Silver cluster ; crystal structure ; tetrameric cluster
    Source: Springer Online Journal Archives 1860-2000
    Topics: Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics , Physics
    Notes: Abstract The sought-after member of the [(PDBP) n AgX] m (n, m=1,4; 2,2; 3,1; PDBP=5-Phenyldibenzophosphole, X=halides) series, the tetrameric [(PDBP)AgCl]4 cluster has been prepared and structurally characterized. The [P4Ag4Cl4] cluster core of [(PDBP)AgCl]4 bears striking similarity to that of [(Ph3P)AgCl]4.
    Type of Medium: Electronic Resource
    URL: http://dx.doi.org/10.1023/A:1021950902725
    Location Call Number Expected Availability
    BibTip Others were also interested in ...
    Paper (German National Licenses)
    Fulltext
  • 36
    Electronic Resource
    Electronic Resource
    Predicting the Strength of Leonid Outbursts (1998)
    Springer
    Earth, moon and planets 82-83 (1998), S. 149-166 
    Details
    ISSN: 1573-0794
    Keywords: Comet ; comet ejection ; Leonids ; meteor ; meteor shower ; meteoroid ; model predictions ; orbital dynamics ; radiation pressure
    Source: Springer Online Journal Archives 1860-2000
    Topics: Geosciences , Physics
    Notes: Abstract A simple model is described that predicts the time of occurrences and peak activity of Leonid shower outbursts. It is assumed that the ejection speeds of escaping particles at each return of the parent comet near perihelion are very small, but solar radiation pressure acting differently on different particles causing a spread of particles into different period orbits. Earlier papers predicted the position of the resulting dust trails. This paper sets forth to better predict the strength of the expected outbursts by considering the role of non-isotropic effects in the interaction with the solar radiation on the dispersion of particles away from the dust trail center. This paper determines the approximate magnitude of the relevant effects. Predictions for the next few years are presented that include such considerations, for reasonable assumptions of particle properties. For example, earlier predictions for the 1999 storm of ZHR = 6,000−7,000 are now reduced by a factor of two, which is in better agreement with the observed ZHR ∼ 4,000. The success of the technique, when applied to historic meteor storms and outbursts without need of additional free parameters, lends confidence to the soundness of the underlying model and to its application for future predictions. We predict that the best encounters of this return of the parent-comet will occur in the years 2001 and 2002.
    Type of Medium: Electronic Resource
    URL: http://dx.doi.org/10.1023/A:1017068618114
    Location Call Number Expected Availability
    BibTip Others were also interested in ...
    Paper (German National Licenses)
    Fulltext
  • 37
    Electronic Resource
    Electronic Resource
    Collected Extraterrestrial Materials: Constraints on Meteor and Fireball Compositions (1998)
    Springer
    Earth, moon and planets 82-83 (1998), S. 325-350 
    Details
    ISSN: 1573-0794
    Keywords: Asteroid ; bolide ; chemistry ; comet ; cosmic dust ; fireball ; interplanetary dust particle (IDP) ; meteorite ; meteor ; mineralogy
    Source: Springer Online Journal Archives 1860-2000
    Topics: Geosciences , Physics
    Notes: Abstract The bulk density and bulk porosity of IDPs and various meteorite classes show that protoplanet accretion and evolution were arrested at different stages as a function of parent body modification. The collected IDPs, micrometeorites and meteorites are aggregates of different structural entities that were inherited from the earliest times of solar system evolution. These structural entities and the extent of parent body lithification will determine the material strength of the meteoroids entering the Earth's atmosphere. There is a need for measurements of the material strength of collected extraterrestrial materials because they will in part determine the nature of the chemical interactions of descending meteors and fireballs in the atmosphere. High—precision determinations of meteor and fireball compositions are required to search for anhydrous, carbon-rich proto-CI material that has survived in the boulders of comet nuclei.
    Type of Medium: Electronic Resource
    URL: http://dx.doi.org/10.1023/A:1017086517630
    Location Call Number Expected Availability
    BibTip Others were also interested in ...
    Paper (German National Licenses)
    Fulltext
  • 38
    Electronic Resource
    Electronic Resource
    Ground-Based Leonid Imaging in the UV (1998)
    Springer
    Earth, moon and planets 82-83 (1998), S. 391-398 
    Details
    ISSN: 1573-0794
    Keywords: Leonids 1999 ; meteor ; meteor physics ; photon counting imager ; ultraviolet
    Source: Springer Online Journal Archives 1860-2000
    Topics: Geosciences , Physics
    Notes: Abstract During the 1999 Leonid meteor storm, a camera with a UV sensitive image intensifier and CCD readout (ICCD), was operated at the Wise Observatory in Mitzpe Ramon, Israel. The photocathode spectral response, together with the transmittance of the atmosphere, limited the sensitivity to a narrow band around 320 nm. The aim was to obtain quantitative information on emitted radiance in this band, for comparison with recordings of the same tracks in other wavelengths. The field of view of 7°.2 × 5°.7 was pointed to the East at about 60° elevation and the video recorded from 21 until 03 UT, Nov. 18, 1999. At least five clear images of meteor tracks were recorded, and compared with the signals from known stars. It was concluded that the brightest track gave an estimated monochromatic magnitude at 320 nm peaking at ∼ −4. Some of the peculiarities of astronomical observation with a photon-counting imager are discussed.
    Type of Medium: Electronic Resource
    URL: http://dx.doi.org/10.1023/A:1017067423082
    Location Call Number Expected Availability
    BibTip Others were also interested in ...
    Paper (German National Licenses)
    Fulltext
  • 39
    Electronic Resource
    Electronic Resource
    Precise Trajectories and Orbits of Meteoroids from the 1999 Leonid Meteor Storm (1998)
    Springer
    Earth, moon and planets 82-83 (1998), S. 277-284 
    Details
    ISSN: 1573-0794
    Keywords: Comet dust trial ; dispersion ; Leonids 1999 ; meteor ; meteor orbit ; meteor trajectory ; orbital dynamics
    Source: Springer Online Journal Archives 1860-2000
    Topics: Geosciences , Physics
    Notes: Abstract Photographic multi-station observations of 47 Leonid meteors are presented that were obtained from two ground locations in Spain during the 1999 meteor storm. We find an unresolved compact cluster of radiants at α = 153.67 ± 0.05 and δ = 21.70 ± 0.05 for a mean solar longitude of 235.282 (J2000). The position is identical to that of the Nov. 17/18 outburst of 1998, which implies that both are due to comet 55P/Tempel-Tuttle's ejecta from 1899. We also find a halo which contains about 28% of all meteors. The spatial distribution of radiant positions appears to be Lorentzian, with a similar fraction of meteors in the profile wings as the meteor storm activity curve.
    Type of Medium: Electronic Resource
    URL: http://dx.doi.org/10.1023/A:1017070313938
    Location Call Number Expected Availability
    BibTip Others were also interested in ...
    Paper (German National Licenses)
    Fulltext
  • 40
    Electronic Resource
    Electronic Resource
    Buoyancy of the "Y2K" Persistent Train and the Trajectory of the 04:00:29 UT Leonid Fireball (1998)
    Springer
    Earth, moon and planets 82-83 (1998), S. 457-470 
    Details
    ISSN: 1573-0794
    Keywords: Fireball ; leonids 1999 ; lower thermosphere ; mesosphere ; meteor ; persistent train ; winds
    Source: Springer Online Journal Archives 1860-2000
    Topics: Geosciences , Physics
    Notes: Abstract The atmospheric trajectory is calculated of a particularly well studied fireball and train during the 1999 Leonid Multi-Instrument Aircraft Campaign. Less than a minute after the meteor's first appearance, the train curves into a "2"-shape, which persisted until at least 13 minutes after the fireball. We conclude that the shape results because of horizontal winds from gravity waves with a scale height of 8.3 km at 79–91 km altitude, as well as a westerly wind gradient with altitude. In addition, there is downward drift that affects the formation of loops in the train early on.
    Type of Medium: Electronic Resource
    URL: http://dx.doi.org/10.1023/A:1017044229442
    Location Call Number Expected Availability
    BibTip Others were also interested in ...
    Paper (German National Licenses)
    Fulltext
  • 41
    Electronic Resource
    Electronic Resource
    The Dynamical Evolution of a Tubular Leonid Persistent Train (1998)
    Springer
    Earth, moon and planets 82-83 (1998), S. 471-488 
    Details
    ISSN: 1573-0794
    Keywords: Airglow ; chemistry ; dynamics ; Leonids 1998 ; lower thermosphere ; mesosphere ; meteor ; persistent train
    Source: Springer Online Journal Archives 1860-2000
    Topics: Geosciences , Physics
    Notes: Abstract The dynamical evolution of the persistent train of a bright Leonid meteor was examined for evidence of the source of the luminosity and the physical conditions in the meteor path. The train consisted of two parallel somewhat diffuse luminous tracks, interpreted as the walls of a tube. A general lack of wind shear along the trail allowed these structures to remain intact for nearly 200 s, from which it was possible to determine that the tubular structure expanded at a near constant 10.5 ms−1, independent of altitude between 86 and 97 km. An initial fast decrease of train intensity below 90 km was followed by an increase in intensity and then a gradual decrease at longer times, whereas at high altitudes the integrated intensity was nearly constant with time. These results are compared to a model that describes the dynamical evolution of the train by diffusion, following an initial rapid expansion of the hot gaseous trail behind the meteoroid. The train luminosity is produced by O (1S) emission at 557 nm, driven by elevated atomic O levels produced by the meteor impact, as well as chemiluminescent reactions of the ablated metals Na and Fe with O3. Ozone is rapidly removed within the train, both by thermal decomposition and catalytic destruction by the metallic species. Hence, the brightest emission occurs at the edge of the train between outwardly diffusing metallic species and inwardly diffusing O3. Although the model is able to account plausibly for a number of characteristic features of the train evolution, significant discrepancies remain that cannot casily be resolved.
    Type of Medium: Electronic Resource
    URL: http://dx.doi.org/10.1023/A:1017000414421
    Location Call Number Expected Availability
    BibTip Others were also interested in ...
    Paper (German National Licenses)
    Fulltext
  • 42
    Electronic Resource
    Electronic Resource
    Coordinated Observations of Leonids in Israel (1998)
    Springer
    Earth, moon and planets 82-83 (1998), S. 47-56 
    Details
    ISSN: 1573-0794
    Keywords: Ground-based observations ; Leonids 1999 ; meteor ; meteor shower ; meteor storm ; Multi-instrument Aircraft Campaign
    Source: Springer Online Journal Archives 1860-2000
    Topics: Geosciences , Physics
    Notes: Abstract Ground-based meteor observations from Israel were coordinated with the 1999 Leonid Multi-Instrument Aircraft Campaign. For the first time, a large concentration of observational means for meteor astronomy was gathered in a small country. Many observations were specifically keyed to the peak of the Leonid activity, when the predictions indicated a possibly strong storm component that would be ideally observable from the Middle East. This unique opportunity allowed us to forge collaborations with the amateur astronomers community and with high-technology industries, who contributed unique observational means. The elaborate preparations led to an unprecedented success, yielding unique observational results. Some of these are included in these proceedings, but their interpretation and incorporation in a coherent picture of the Leonid meteors is still to come.
    Type of Medium: Electronic Resource
    URL: http://dx.doi.org/10.1023/A:1017061527258
    Location Call Number Expected Availability
    BibTip Others were also interested in ...
    Paper (German National Licenses)
    Fulltext
  • 43
    Electronic Resource
    Electronic Resource
    DC Electrical Resistivity Study of Granularity in YBa2CU3O7/Ag Composites (1998)
    Springer
    Journal of superconductivity 11 (1998), S. 641-648 
    Details
    ISSN: 1572-9605
    Keywords: Superconductivity ; Ag composites ; percolation ; granularity ; weak-link resistivity
    Source: Springer Online Journal Archives 1860-2000
    Topics: Electrical Engineering, Measurement and Control Technology , Physics
    Notes: Abstract Temperature-dependent electrical resistivity in a set of YBa2Cu3O7−x /Ag composites, all prepared under an identical sintering schedule, is analyzed to extract granularity information. The weak-link resistivity ρ wl across the grain boundaries and the percolation factor α arising due to current frustration caused by misalignment of anisotropic grains and sample defects such as voids and cracks are estimated from the residual resistivity ρ0 and the temperature coefficient of resistivity dρ/dT. Variation of these parameters with Ag vol.% quantifying the extent of granularity indicates that granularity in the composites decreases and their electrical characteristics tend to be identical to that of Ag-free YBa2Cu3O7−x single crystals and epitaxial thin films as Ag vol.% approaches a value where onset of current percolation occurs through Ag channels. The increased α and decreased ρ wl observed at higher Ag vol.% explains the larger grains in the composites with narrow size distribution.
    Type of Medium: Electronic Resource
    URL: http://dx.doi.org/10.1023/A:1022609432697
    Location Call Number Expected Availability
    BibTip Others were also interested in ...
    Paper (German National Licenses)
    Fulltext
  • 44
    Electronic Resource
    Electronic Resource
    Effect of Ca Substitution on the Superconductivity of La2.5Y0.5CaBa3(Cu0.88Fe0.12)7O z (1998)
    Springer
    Journal of superconductivity 11 (1998), S. 673-676 
    Details
    ISSN: 1572-9605
    Keywords: Superconductivity ; La2.5Y0.5CaBa3(Cu0.88Fe0.12)7O z ; compensated oxide ; magnetic pair breaking
    Source: Springer Online Journal Archives 1860-2000
    Topics: Electrical Engineering, Measurement and Control Technology , Physics
    Notes: Abstract The structural and superconducting properties of single-phase La2.5−y Y0.5Ca1+y Ba3 (Cu0.88Fe0.12)7O z (LYCaBCuFe) (y= 0.0−1.0) compounds with triple perovskite structure are investigated using X-ray diffraction, resistivity, a.c. susceptibility, and oxygen content measurements. Increasing Ca substitution for La resulted in a decrease in unit cell axes and volume. T c R=0 shows a marginal increase from 31 K to 37 K for y = 0.0−0.21 and thereafter it decreases with increasing y leading to zero T c R=0 at y ≥ 0.84. This shows that the suppression of T c from 80 K to 31 K by Fe doping at x = 0.12 La2.5Y0.5CaBa3(Cu1−x Fe x )7O z cannot be compensated by appropriate hole doping with Ca in LaYCaBCuFe.
    Type of Medium: Electronic Resource
    URL: http://dx.doi.org/10.1023/A:1022620518584
    Location Call Number Expected Availability
    BibTip Others were also interested in ...
    Paper (German National Licenses)
    Fulltext
  • 45
    Electronic Resource
    Electronic Resource
    Superconductivity and Antiferromagnetic Order in ErNi2B2C Thin Films (1998)
    Springer
    Journal of superconductivity 11 (1998), S. 707-712 
    Details
    ISSN: 1572-9605
    Keywords: Superconductivity ; antiferromagnetic order ; ErNi2Bi2C
    Source: Springer Online Journal Archives 1860-2000
    Topics: Electrical Engineering, Measurement and Control Technology , Physics
    Notes: Abstract Upper critical field and penetration depth of superconducting ErNi2B2C borocarbide thin films have been investigated and compared with the same properties of SmRh4B4 films. The coexistence of superconductivity and antiferromagnetic order is described through Machida's theory. A fairly satisfactory description of the experimental results is obtained.
    Type of Medium: Electronic Resource
    URL: http://dx.doi.org/10.1023/A:1022632921310
    Location Call Number Expected Availability
    BibTip Others were also interested in ...
    Paper (German National Licenses)
    Fulltext
  • 46
    Electronic Resource
    Electronic Resource
    Duality in Two Capacitively Coupled Layered Arrays of Ultrasmall Josephson Junctions (1998)
    Springer
    Journal of statistical physics 93 (1998), S. 943-964 
    Details
    ISSN: 1572-9613
    Keywords: Superconductivity ; macroscopic quantum phenomena ; mesoscopic systems
    Source: Springer Online Journal Archives 1860-2000
    Topics: Physics
    Notes: Abstract We consider the problem of two capacitively coupled Josephson junction arrays made of ultrasmall junctions. Each one of the arrays can be in the semiclassical or quantum regimes, depending on its physical parameter values. The former case is dominated by a Cooper-pair superfluid, while the quantum case is dominated by dynamic vortices leading to an insulating behavior. We first consider the limit when both arrays are in the semiclassical limit, and next the case when one array is quantum and the other semiclassical. We present WKB and mean-field theory results for the critical temperature of each array when both are in the semiclassical limit. When one array is in the semiclassical regime and the other one is in the quantum-fluctuations-dominated regime, we derive a duality transformation between the charge and vortex-dominated arrays that involves a gauge vector field which is proportional to the site coupling capacitance between the arrays. The system considered here has been fabricated and we make some predictions as to possible experimentally measurable quantities that could be compared with theory.
    Type of Medium: Electronic Resource
    URL: http://dx.doi.org/10.1023/B:JOSS.0000033171.04828.d6
    Location Call Number Expected Availability
    BibTip Others were also interested in ...
    Paper (German National Licenses)
    Fulltext
  • 47
    Electronic Resource
    Electronic Resource
    Cytochrome c Oxidase (Heme aa 3) from Paracoccus denitrificans: Analysis of Mutations in Putative Proton Channels of Subunit I (1998)
    Springer
    Journal of bioenergetics and biomembranes 30 (1998), S. 89-97 
    Details
    ISSN: 1573-6881
    Keywords: Terminal oxidase ; redox coupling ; electrochemical gradient ; electron transport ; energy transduction ; proton translocation ; crystal structure ; site-directed mutagenesis
    Source: Springer Online Journal Archives 1860-2000
    Topics: Biology , Chemistry and Pharmacology , Physics
    Notes: Abstract One of the challenging features of energy-transducing terminal oxidases, like the aa 3 cytochrome c oxidase of Paracoccus denitrificans, is the translocation of protons across the cytoplasmic membrane, which is coupled to the transfer of electrons to oxygen. As a prerequisite for a more advanced examination of the enzymatic properties, several amino acid residues, selected on the basis of recent three-dimensional structure determinations, were exchanged in subunit I of the Paracoccus enzyme by site-directed mutagenesis. The properties of the mutated oxidases were analyzed by different methods to elucidate whether they are involved in the coupled and coordinated transfer of protons via two different pathways either to the site of oxygen reduction or through the enzyme from the cytoplasm to the periplasmic side.
    Type of Medium: Electronic Resource
    URL: http://dx.doi.org/10.1023/A:1020515713103
    Location Call Number Expected Availability
    BibTip Others were also interested in ...
    Paper (German National Licenses)
    Fulltext
  • 48
    Electronic Resource
    Electronic Resource
    Comparing Meteor Number Fluxes from Ground-Based and Airplane-Based Video Observations (1998)
    Springer
    Earth, moon and planets 82-83 (1998), S. 209-220 
    Details
    ISSN: 1573-0794
    Keywords: Leonid MAC ; meteor ; meteor flux ; Zenithal Hourly Rate
    Source: Springer Online Journal Archives 1860-2000
    Topics: Geosciences , Physics
    Notes: Abstract We operated identical Low-Light level TV cameras to observe the Leonid 1999 meteor storm, both from a ground-based station in Southern Spain and from the ARIA airplane of the Leonid Multi-Aircraft Campaign. The ground-based camera was pointed to a fixed position about 50° from the zenith, the airborne camera was pointed through a window at 75° from the zenith. During the peak of the Leonid storm, the two cameras were located between 10° and 20° apart in geographical longitude. The recorded meteor numbers differed by a factor 5.3 ± 0.4, the airborne camera recording the higher rates. This is much more than what could be expected from the geographical separation of the cameras. The different elevation angles and altitudes of the cameras can explain this. Pointing the camera low to the horizon results in a much larger volume in the atmosphere which is observed, resulting in higher meteor count rates. However, the meteors are on average much further away than when observing high above the horizon. The atmospheric extinction reduces the brightness of the meteors, effectively reducing the count rates. For two ground-based cameras, these two effects are expected to compensate. Due to the high altitude of the airborne camera, the increasing effect of the count rate dominates. We set up an atmospheric extinction model taking into account Rayleigh scattering that quantitatively explains the number difference. Using the same model, we predict number differences for cameras observing from the same location, but pointed at different elevation angles. For typical observing conditions, neglecting this effect can result in differences up to a factor of 10 in the derived meteor numbers.
    Type of Medium: Electronic Resource
    URL: http://dx.doi.org/10.1023/A:1017078313996
    Location Call Number Expected Availability
    BibTip Others were also interested in ...
    Paper (German National Licenses)
    Fulltext
  • 49
    Electronic Resource
    Electronic Resource
    The Leonid Meteors and Space Shuttle Risk Assessment (1998)
    Springer
    Earth, moon and planets 82-83 (1998), S. 249-256 
    Details
    ISSN: 1573-0794
    Keywords: Flux ; Leonids 1999 ; Liquid Mirror Telescope ; meteor ; meteor shower ; satellite impact hazard
    Source: Springer Online Journal Archives 1860-2000
    Topics: Geosciences , Physics
    Notes: Abstract The November 1999 Leonid meteor shower was videotaped with a low light level camera from the grounds of the National Aeronautics and Space Administration (NASA) Johnson Space Center (JSC) in Houston, Texas. Additionally, observations of the Leonids were recorded both digitally with the Liquid Mirror Telescope (LMT) and with a low light level camera at the JSC Observatory near Cloudcroft, New Mexico. The tapes were analyzed using a computer-automated meteor analysis system developed at JSC. These results were used to form estimates of the Leonid mass-distribution. These estimates were compared to a Leonid mass distribution model used by NASA in risk assessment calculations associated with Space Shuttle missions. The observed data agrees favorably with the NASA model in the 0.002 to 0.02 milligram range (based upon the LMT observations) and in the 0.02 to 0.2 gram range (based upon the low light level camera observations). This comparison supports the continued use of this model.
    Type of Medium: Electronic Resource
    URL: http://dx.doi.org/10.1023/A:1017046802609
    Location Call Number Expected Availability
    BibTip Others were also interested in ...
    Paper (German National Licenses)
    Fulltext
  • 50
    Electronic Resource
    Electronic Resource
    Lorentz Shaped Comet Dust Trail Cross Section from New Hybrid Visual and Video Meteor Counting Technique - Implications for Future Leonid Storm Encounters (1998)
    Springer
    Earth, moon and planets 82-83 (1998), S. 191-208 
    Details
    ISSN: 1573-0794
    Keywords: Comet ; comet: 55P/Tempel-Tuttle ; dust trail ; flux ; Leonids 1999 ; Lorentz profile ; meteor ; meteor storm ; predictions ; satellite impact hazard ; observing techniques
    Source: Springer Online Journal Archives 1860-2000
    Topics: Geosciences , Physics
    Notes: Abstract A new hybrid technique of visual and video meteor observations was developed to provide high precision near real-time flux measurements for satellite operators from airborne platforms. A total of 33,000 Leonids, recorded on video during the 1999 Leonid storm, were watched by a team of visual observers using a video head display and an automatic counting tool. The counts reveal that the activity profile of the Leonid storm is a Lorentz profile. By assuming a radial profile for the dust trail that is also a Lorentzian, we make predictions for future encounters. If that assumption is correct, we passed 0.0003 AU deeper into the 1899 trailet than expected during the storm of 1999 and future encounters with the 1866 trailet will be less intense than predicted elsewhere.
    Type of Medium: Electronic Resource
    URL: http://dx.doi.org/10.1023/A:1017076829926
    Location Call Number Expected Availability
    BibTip Others were also interested in ...
    Paper (German National Licenses)
    Fulltext
  • 51
    Electronic Resource
    Electronic Resource
    Leonid Storm Flux Analysis from One Leonid Mac Video AL50R (1998)
    Springer
    Earth, moon and planets 82-83 (1998), S. 221-247 
    Details
    ISSN: 1573-0794
    Keywords: Clustering ; flux ; fragmentation ; Leonids 1999 ; meteor ; meteoroid ; optimal video pointing ; satellite impact hazard ; simulation
    Source: Springer Online Journal Archives 1860-2000
    Topics: Geosciences , Physics
    Notes: Abstract A detailed meteor flux analysis is presented of a seventeen-minute portion of one videotape, collected on November 18, 1999, during the Leonid Multi-instrument Aircraft Campaign. The data was recorded around the peak of the Leonid meteor storm using an intensified CCD camera pointed towards the low southern horizon. Positions of meteors on the sky were measured. These measured meteor distributions were compared to a Monte Carlo simulation, which is a new approach to parameter estimation for mass ratio and flux. Comparison of simulated flux versus observed flux levels, seen between 1:50:00 and 2:06:41 UT, indicate a magnitude population index of r = 1.8 ± 0.1 and mass ratio of s = 1.64 ± 0.06. The average spatial density of the material contributing to the Leonid storm peak is measured at 0.82 ± 0.19 particles per square kilometer per hour for particles of at least absolute visual magnitude +6.5. Clustering analysis of the arrival times of Leonids impacting the earth's atmosphere over the total observing interval shows no enhancement or clumping down to time scales of the video frame rate. This indicates a uniformly random temporal distribution of particles in the stream encountered during the 1999 epoch. Based on the observed distribution of meteors on the sky and the model distribution, recommendations are made for the optimal pointing directions for video camera meteor counts during future ground and airborne missions.
    Type of Medium: Electronic Resource
    URL: http://dx.doi.org/10.1023/A:1017030431743
    Location Call Number Expected Availability
    BibTip Others were also interested in ...
    Paper (German National Licenses)
    Fulltext
  • 52
    Electronic Resource
    Electronic Resource
    Time Resolved Spectroscopy of a Leonid Fireball Afterglow (1998)
    Springer
    Earth, moon and planets 82-83 (1998), S. 399-428 
    Details
    ISSN: 1573-0794
    Keywords: Afterglow ; debris ; dust ; H ; meteor ; persistent train ; spectroscopy
    Source: Springer Online Journal Archives 1860-2000
    Topics: Geosciences , Physics
    Notes: Abstract Two video spectra of a meteoric afterglow were obtained for the first time during the 1999 Leonid aircraft campaign. The train was produced by a −13 magnitude Leonid fireball at a relatively low height between 91-75 km. The meteor spectrum has a strong hydrogen emission, proportional to 10–20 II atoms per one Fe atom The train spectrum consisted of a red continuum, yellow continuum, and about 50 atomic lines between 3700–9000 Å. The yellow continuum, possibly due to NO2, was also detected in the persistent train. The red continuum is interpreted as a thermal radiation of dust from meteoric debris at about 1400 K. Evidence for secondary ablation is found in the afterglow. The atomic lines decayed within seconds of the meteor. The lines of Fe I, Mg I, Na I, Ca I, Ca II, Cr I, Mn I, K I, and possibly Al I were present in the glow together with the 5577 Å forbidden O I line. The gas temperature in the train was close to 5000 K at the beginning and decayed to 1200 K within two seconds. However, thermal equilibrium was not satisfied for all populated levels.
    Type of Medium: Electronic Resource
    URL: http://dx.doi.org/10.1023/A:1017071524899
    Location Call Number Expected Availability
    BibTip Others were also interested in ...
    Paper (German National Licenses)
    Fulltext
  • 53
    Electronic Resource
    Electronic Resource
    Preliminary Data on Variations of OH Airglow during the Leonid 1999 Meteor Storm (1998)
    Springer
    Earth, moon and planets 82-83 (1998), S. 525-534 
    Details
    ISSN: 1573-0794
    Keywords: Ablation ; airglow ; Leonids 1999 ; lower thermosphere ; O2 ; OH ; mesosphere ; meteor
    Source: Springer Online Journal Archives 1860-2000
    Topics: Geosciences , Physics
    Notes: Abstract As part of the 1999 Leonid MAC Campaign an extensive set of infrared (1.00 – 1.65 µm) airglow spectra and imaging data were collected from onboard the USAF FISTA aircraft. These data will permit a detailed study of the upper atmospheric conditions over a several day period centered on the Leonid meteor storm of 17/18 November, 1999 as well as during the meteor storm itself. We describe initial results of a spectral analysis that indicates a small but significant enhancement in the OH airglow emission during the peak of the storm but we cannot yet be certain of a cause and effect relationship. No similar systematic enhancement was observed in the O2 (1.27 µm) airglow emission recorded with the same instrument.
    Type of Medium: Electronic Resource
    URL: http://dx.doi.org/10.1023/A:1017016918056
    Location Call Number Expected Availability
    BibTip Others were also interested in ...
    Paper (German National Licenses)
    Fulltext
  • 54
    Electronic Resource
    Electronic Resource
    Observations of the Leonid Meteoroid Stream by a Multistation FS Radio System (1998)
    Springer
    Earth, moon and planets 82-83 (1998), S. 265-276 
    Details
    ISSN: 1573-0794
    Keywords: Flux ; Leonids 1999 ; meteor ; meteor shower ; radar ; radio forward ; meteor scatter
    Source: Springer Online Journal Archives 1860-2000
    Topics: Geosciences , Physics
    Notes: Abstract Results of joint campaigns of the Leonid meteoroid stream performed throughout the 1995–1999 years by the BLM (Bologna-Lecce-Modra) forward scatter (FS) radar, are shown and compared with visual observations. In 1998 and 1999 at both the stations of Lecce and Modra, the total reflection time is shown to give a better indication of the Leonid activity. For the two years the trends of the reflection time and of the overdense echoes (T 〉 8 sec duration) exhibit multiple peaks just at the maximum of the shower activity. In 1999, strong evidence of a short and extremely intense activity at the nodal longitude of the parent comet (November 18, 02h UT), is deduced from the radio data. The Leonid display is shown to follow a Gaussian activity profile and the particle density/stream width relationship is found to match observations of IRAS dust trails of comparable short-period comets. The mass distribution exponent shows a representation of an extended component of larger particles (brighter Leonids) in 1996 and especially in 1998. Average mass and population indices of radio and visual data show a similar trend in the 1995–1999 period.
    Type of Medium: Electronic Resource
    URL: http://dx.doi.org/10.1023/A:1017001912121
    Location Call Number Expected Availability
    BibTip Others were also interested in ...
    Paper (German National Licenses)
    Fulltext
  • 55
    Electronic Resource
    Electronic Resource
    Temporal Variation in the Orbital Element Distribution of the 1998 Leonid Outburst (1998)
    Springer
    Earth, moon and planets 82-83 (1998), S. 295-304 
    Details
    ISSN: 1573-0794
    Keywords: Leonids 1998 ; meteor ; meteor shower ; meteoroid ; orbits ; video
    Source: Springer Online Journal Archives 1860-2000
    Topics: Geosciences , Physics
    Notes: Abstract Double-station video observations of the 1998 Leonid shower from China resulted in 55 trajectories and orbits of meteoroids in the visual magnitude range from +0 to +6 magn. The 1998 Leonid outburst consisted of a relatively long duration shower that was rich in large meteoroids and peaked in the night of November 16/17, and an outburst of shorter duration that was rich in smaller meteoroids and peaked in the next night. The average orbit obtained during the first night agrees well with that from photographic observations. During the second night, the combined set of video and photographic observations shows temporal variation in the radiant distribution. This adds to the earlier discovery of an unusual asymmetric flux profile. In addition, the radiant distribution is shown to be mass dependent. The data suggest the presence of at least two merged dust components or a single dust component perturbed by planetary encounters.
    Type of Medium: Electronic Resource
    URL: http://dx.doi.org/10.1023/A:1017082731685
    Location Call Number Expected Availability
    BibTip Others were also interested in ...
    Paper (German National Licenses)
    Fulltext
  • 56
    Electronic Resource
    Electronic Resource
    Rare-Earths as Probes of High-Temperature Superconductivity (1998)
    Springer
    Journal of superconductivity 11 (1998), S. 615-639 
    Details
    ISSN: 1572-9605
    Keywords: Superconductivity ; rare-earths
    Source: Springer Online Journal Archives 1860-2000
    Topics: Electrical Engineering, Measurement and Control Technology , Physics
    Notes: Abstract Using only two principles: (i) high-temperature superconductivity requires hypercharged oxygen, and (ii) the superconducting condensates are located in those parts of the crystal structures where they are unaffected by magnetic pair breaking, we are able to explain why certain rare-earth ions R are compatible with superconductivity and others are not, in the compounds RBa2Cu3O7, RBa2Cu4O8, RBa2Cu2NbO8, R2 − z Ce z CuO4, and R2 − z Ce z Sr2Cu2NbO10. Various defects are proposed as having central roles in the superconductivity or the suppression of superconductivity in these compounds. Many experiments for testing this physical picture are suggested.
    Type of Medium: Electronic Resource
    URL: http://dx.doi.org/10.1023/A:1022643531034
    Location Call Number Expected Availability
    BibTip Others were also interested in ...
    Paper (German National Licenses)
    Fulltext
  • 57
    Electronic Resource
    Electronic Resource
    Navy Programs in Superconducting Technology (1998)
    Springer
    Journal of superconductivity 11 (1998), S. 1-4 
    Details
    ISSN: 1572-9605
    Keywords: Superconductivity ; magnets ; cryogenics
    Source: Springer Online Journal Archives 1860-2000
    Topics: Electrical Engineering, Measurement and Control Technology , Physics
    Notes: Abstract A review of U.S. Navy efforts in superconducting technology is given. Programs include development of superconducting magnets for motors in ship propulsion systems and to generate magnetic moments in mine sweeping systems. A program to develop superconducting quantum interference devices (SQUIDs) for detection of mines and buried ordnance has successfully been demonstrated. In electronic applications, superconducting filters, resonators, and antennae are being developed for radar, communication, and space systems. Concurrent with these superconductivity programs are efforts to improve the efficiency, reliability, and affordability of refrigeration systems.
    Type of Medium: Electronic Resource
    URL: http://dx.doi.org/10.1023/A:1022656620516
    Location Call Number Expected Availability
    BibTip Others were also interested in ...
    Paper (German National Licenses)
    Fulltext
  • 58
    Electronic Resource
    Electronic Resource
    Effect of M and M-Ca Substitution on the Structure and Superconductivity of GdBa2Cu3O7−δ [M = Mo, Hf ] (1998)
    Springer
    Journal of superconductivity 11 (1998), S. 285-290 
    Details
    ISSN: 1572-9605
    Keywords: GdBa2Cu3O7−δ ; Ca substitution ; Mo substitution ; Hf substitution ; crystal structure
    Source: Springer Online Journal Archives 1860-2000
    Topics: Electrical Engineering, Measurement and Control Technology , Physics
    Notes: Abstract The structural and superconducting properties of (Gd1−x−y Ca y M x )Ba2Cu3O z with M = Mo, Hf are investigated using X-ray diffraction, electrical resistivity, and oxygen content measurements. The effect of increasing the Mo concentration in (Gd1−x Mo x )Ba2Cu3O z changes the structure from orthorhombic to tetragonal accompanied by a large increase in resistivity and a fast decrease in T c at the rate of 1.9 K per at.% of Mo, unlike that of Hf substitution in (Gd1−x Hf x )Ba2Cu3O z , which maintains the orthorhombic structure and decreases T c very slowly at the rate of 0.6 K per atm.% of Hf with nearly no change in resistivity. The suppression of T c by M = Mo, Hf can be counterbalanced by hole doping by Ca which increases T c with increasing Ca content showing maximum compensation for Mo. A comparative study of M = Mo, Hf doped samples in (Gd1−x−y Ca y M x )Ba2Cu3O z indicates that the valence of the dopant M = Mo4+,6+, Hf4+ and its ionic radius play an important role in controlling the structural and superconducting properties of the systems.
    Type of Medium: Electronic Resource
    URL: http://dx.doi.org/10.1023/A:1022644203794
    Location Call Number Expected Availability
    BibTip Others were also interested in ...
    Paper (German National Licenses)
    Fulltext
  • 59
    Electronic Resource
    Electronic Resource
    Superconductivity and Critical Coupling in Non-Fermi Liquids (1998)
    Springer
    Journal of superconductivity 11 (1998), S. 339-345 
    Details
    ISSN: 1572-9605
    Keywords: Superconductivity ; non-Fermi liquid
    Source: Springer Online Journal Archives 1860-2000
    Topics: Electrical Engineering, Measurement and Control Technology , Physics
    Notes: Abstract The critical temperature of a superconductor with a non-Fermi liquid ground state has been calculated. The density of states has two different forms and is energy dependent. The critical values of the coupling factor λ were calculated. The constant density of states results are obtained as particular cases. These results are an extension of the work done by Grosu et al. [Phys. Rev. B 56, 8298 (1997)].
    Type of Medium: Electronic Resource
    URL: http://dx.doi.org/10.1023/A:1022694629696
    Location Call Number Expected Availability
    BibTip Others were also interested in ...
    Paper (German National Licenses)
    Fulltext
  • 60
    Electronic Resource
    Electronic Resource
    The Effect of Nitrates on Thallium Based Oxycarbonate Superconductors (1998)
    Springer
    Journal of superconductivity 11 (1998), S. 123-124 
    Details
    ISSN: 1572-9605
    Keywords: Superconductivity ; Nitrates ; Oxycarbonates
    Source: Springer Online Journal Archives 1860-2000
    Topics: Electrical Engineering, Measurement and Control Technology , Physics
    Notes: Abstract We have synthesised a series of compounds in both the (PbTl)Sr4Cu2O7(CO3)1−y(NO3)y (0.1≤y≤0.5) and TlSr2Ba2Cu2O7(CO3)1−y(NO3)y (0.1≤y≤0.2) systems. We report the synthesis conditions of these materials, an X-ray diffraction analysis of their structure and the changes induced in superconducting behaviour produced by the introduction of nitrate groups into the starting composition.
    Type of Medium: Electronic Resource
    URL: http://dx.doi.org/10.1023/A:1022627222759
    Location Call Number Expected Availability
    BibTip Others were also interested in ...
    Paper (German National Licenses)
    Fulltext
  • 61
    Electronic Resource
    Electronic Resource
    Full Wafer In Situ Deposition of Thallium Lead Superconductors (1998)
    Springer
    Journal of superconductivity 11 (1998), S. 129-132 
    Details
    ISSN: 1572-9605
    Keywords: Superconductivity ; TIPbSrCaCuO ; thin films
    Source: Springer Online Journal Archives 1860-2000
    Topics: Electrical Engineering, Measurement and Control Technology , Physics
    Notes: Abstract Thin films of (Tl,Pb)Sr2Ca0.8Y0.2Cu2O7, and (Tl,Pb)Sr2CuO5 can be grown in a single step process which involves sputter deposition from a mixed oxide target and simultaneous thermal evaporation of Tl2O. The use of a radiant heater has allowed extension of this in situ deposition process to full LaAlO3 and NdGaO3 wafers. Variations in the composition of the deposited film is 〈 4% across a 50 mm wafer while the thickness uniformity is ≍ 8%. The highest transition temperature for a (Tl,Pb)Sr2Ca0.8Y0.2 Cu2O7 film thus far is 83 K. The RMS surface roughness of (Tl,Pb)Sr2CuO5 films is uniform across the wafer and approximately 1% of the film thickness for films 20 to 100 nm thick.
    Type of Medium: Electronic Resource
    URL: http://dx.doi.org/10.1023/A:1022683307738
    Location Call Number Expected Availability
    BibTip Others were also interested in ...
    Paper (German National Licenses)
    Fulltext
  • 62
    Electronic Resource
    Electronic Resource
    Synthesis and Structure of Hg1−xCrxSr2CuO4+δ Mercurocuprates (1998)
    Springer
    Journal of superconductivity 11 (1998), S. 141-142 
    Details
    ISSN: 1572-9605
    Keywords: Superconductivity ; mercury ; chromium ; synthesis ; structure
    Source: Springer Online Journal Archives 1860-2000
    Topics: Electrical Engineering, Measurement and Control Technology , Physics
    Notes: Abstract We report preliminary results concerning the synthesis and structural characterisation of the chromium stabilised 1201 phases: Hg1−xCrxSr2CuO4+δ. A systematic study of the formation of phases in this system has been undertaken, together with a combined powder neutron and synchrotron x-ray diffraction study, to address the issue of chromium clustering and ordering in this system.
    Type of Medium: Electronic Resource
    URL: http://dx.doi.org/10.1023/A:1022691509555
    Location Call Number Expected Availability
    BibTip Others were also interested in ...
    Paper (German National Licenses)
    Fulltext
  • 63
    Electronic Resource
    Electronic Resource
    Superconductivity in Lithium- and Sodium-Doped Mercury-Based Cuprates (1998)
    Springer
    Journal of superconductivity 11 (1998), S. 169-171 
    Details
    ISSN: 1572-9605
    Keywords: Superconductivity ; Alkali-doping ; Hg-based Cuprates
    Source: Springer Online Journal Archives 1860-2000
    Topics: Electrical Engineering, Measurement and Control Technology , Physics
    Notes: Abstract The effect of Na- and Li-doping in Hg-based cuprates has been studied. It has been found that superconductivity can be achieved in samples containing small amount of Na or Li. While little change is found in the crystalline structure, the formed superconducting phase have the onset Tc typically above 140 K and zero-resistance Tc up to 136K. More interestingly, the processing temperature for the doped Hg-1223 can be reduced significantly to near 700 °C which is promising for thin films growth on many technologically compatible substrates.
    Type of Medium: Electronic Resource
    URL: http://dx.doi.org/10.1023/A:1022608113189
    Location Call Number Expected Availability
    BibTip Others were also interested in ...
    Paper (German National Licenses)
    Fulltext
  • 64
    Electronic Resource
    Electronic Resource
    Mixed-State Hall Effect in HgBa2CaCu2O6+δ Thin Films with Columnar Defects (1998)
    Springer
    Journal of superconductivity 11 (1998), S. 163-167 
    Details
    ISSN: 1572-9605
    Keywords: Superconductivity ; thin film ; columnar defect ; pinning
    Source: Springer Online Journal Archives 1860-2000
    Topics: Electrical Engineering, Measurement and Control Technology , Physics
    Notes: Abstract The mixed state Hall effect has been studied in high quality HgBa2CaCu2O6+δ thin films while the pinning strength is modified by the irraddition of columnar defects. It has been shown that the pinning strength can be significantly improved by columnar defects. The sign reversal in Hall resistivity is found to be nearly independent of pinning while the scaling behavior between Hall resistivity (ρxy) and longitudinal resistivity (ρxx) is influenced by pinning. The exponent β in the scaling law β xy ∼ β xy β decrease from 1.8 ± 0.1 to 1.5 ± 0.1 as pinning is enhanced. This results suggest that the sign reversal and the scaling are unrelated, and pinning is not the mechanism of the sign reversal.
    Type of Medium: Electronic Resource
    URL: http://dx.doi.org/10.1023/A:1022656029119
    Location Call Number Expected Availability
    BibTip Others were also interested in ...
    Paper (German National Licenses)
    Fulltext
Close ⊗
This website uses cookies and the analysis tool Matomo. More information can be found here...