ALBERT

Notes: Abstract Specimen thickness is the main experimental factor controlling the results of illite crystallinity (IC) or crystallite size measurements on sedimentation slides. Different values obtained from thick and thin preparations are due to grain-size gradation effects, which may exclude larger and higher ordered grains from contributing to the diffraction. Orientation effects control the measured peak intensity. The change from poor particle orientation in thick slides to high orientation in very thin slides is marked by an increase in specimen density, diminishing non-basal reflections, and by a strong increase in peak intensity. A plateau with constant peak breadths is observed if thin slides of well ordered, platy illites are used. A similar plateau can be recognized for thick preparations of specimens from less ordered materials, but not from well ordered ones. Therefore, it is suggested that IC is determined on very thin sedimentation slides with a thickness of 0.25 mg/cm2 or less. Ultrasonic and H2O2 treatments enhance the degree of particle orientation by destruction of grain aggregates and organic compounds, leading to smaller peak breadths and higher intensities.

Notes: Abstract Five basalt samples from the Point Sal ophiolite, California, were examined using HRTEM and AEM in order to compare observations with interpretations of XRD patterns and microprobe analyses. XRD data from ethylene-glycol-saturated samples indicate the following percentages of chlorite in mixed-layer chlorite–smectite identified for each specimen: (i) L2036 ± 50%, (ii) L2035 ± 70 and 20%, (iii) 1A-13 ± 70%, (iv) 1B-42 ± 70%, and (v) 1B-55 = 100%. Detailed electron microprobe analyses show that ‘chlorite’analyses with high Si, K, Na and Ca contents are the result of interlayering with smectite-like layers. The Fe/(Fe + Mg) ratios of mixed-layer phyllosilicates from Point Sal samples are influenced by the bulk rock composition, not by the percentage of chlorite nor the structure of the phyllosilicate.Measurements of lattice-fringe images indicate that both smectite and chlorite layers are present in the Point Sal samples in abundances similar to those predicted with XRD techniques and that regular alternation of chlorite and smectite occurs at the unit-cell scale. Both 10- and 14-Å layers were recorded with HRTEM and interpreted to be smectite and chlorite, respectively. Regular alternation of chlorite and smectite (24-Å periodicity) occurs in upper lava samples L2036 and 1A-13, and lower lava sample 1B-42 for as many as seven alternations per crystallite with local layer mistakes. Sample L2035 shows disordered alternation of chlorite and smectite, with juxtaposition of smectite-like layers, suggesting that randomly interlayered chlorite (〈0.5)–smectite exists. Images of lower lava sample 1B-55 show predominantly 14-Å layers. Units of 24 Å tend to cluster in what may otherwise appear to be disordered mixtures, suggesting the existence of a corrensite end-member having thermodynamic significance.

Notes: Abstract White mica crystallinity studies have been carried out on 90 samples of mudrocks, six of spotted slate, and five of accretionary lapilli tuff from the area around the Berwyn Hills, North Wales. Strain was measured for some of the spotted slate and tuff samples. The metamorphic grade increases from southeast to northwest, with values of the Kübler index varying from 0.64 to 0.20Δ2θ. Metamorphic zonal boundaries follow the strike of bedding and cleavage, but crystallinity values increase into stratigraphically younger rocks on the northwest side of the Berwyn Dome. This effect is attributed mainly to a rapid increase in the thickness of synmetamorphic overburden to the northwest, comprising exposed Silurian turbidites and inferred Lower Devonian non-marine sediments. Strain variations have a more local influence on crystallinity, and lateral variations in the contemporary geothermal gradient cannot be ruled out. However, only with unrealistically high gradients would the need for a thick Lower Devonian component to the overburden be removed. This reasoning implies that the metamorphic peak was coeval with the Acadian (late Caledonian) event, rather than with an early diastathermal event.

Notes: Abstract Illite crystallinity (IC) measurements, determination of the proportion of 2M mica-polytypes and organic-matter reflectance measurements establish regional diagenetic/low-grade metamorphic trends for the Taconian and Acadian belts of Gaspé Peninsula.IC varies as a function of many factors besides maximum burial temperature and heating time. Correlation between IC and %2M illite polytypes for the Fortin Group and Temiscouata Formation suggests (i) that the amount of high-grade detrital mica in the samples is low, and (ii) that IC can be used with some confidence as an estimator of regional thermal maturation levels. Correlation of these parameters with available organic reflectance values further supports this assumption. The illites of the Temiscouata and western Fortin groups are mostly phengitic in composition, whereas in the eastern outcrop belt they are more Mg- and Fe-rich (celadonitic), but generally also of lower grade and lower 2M content. The d(060) values for illites measured on the unorientated 〈2-μm fraction of samples fall between 1.502 and 1.503 Å (range: 1.500–1.504 Å), indicating relatively low octahedral occupancy by Mg and Fe (between one-fifth and one-third of the available spaces). Pyrophyllite and paragonite were not detected. Chlorites are Fe-rich and ripidolitic.The IC map for the Acadian belt of the peninsula displays general congruence between IC contours (2200 sample points) and structural trends for the 27,000-km2 area. The highest grades (anchimetamorphic) are associated with the oldest rocks (Honorat and Matapedia groups) exposed in the cores of major anticlines. Anchimetamorphic grades associated with the western outcrop belt of the Lower Devonian Fortin Group require 7–8 km of subsidence to accommodate sufficient thickness of overlying younger rocks (on top of 4–5 km of Fortin Group deep-water clastics) to explain the grades in terms of burial metamorphism assuming a geothermal gradient of 30° C km−1. The lowest-grade diagenetic rocks occupy a large area in the northeastern part of the peninsula, smaller areas in the northwestern part of the Acadian belt, in the centre of Chaleurs Bay synclinorium, and in the Ordovician Mictaw Group. The contact between the Taconian and Acadian belt is marked by a distinct maturation discontinuity. The Grand Pabos fault juxtaposes rocks of contrasting maturation levels (Matapedia Group against Fortin Group) in the west, but shows no maturation offset further east in the Honorat Group. The fault zone limiting the Fortin Group in the north is also associated with a major IC jump.

Notes: Abstract The assemblage muscovite-quartz-staurolite-aluminium silicate-biotite-garnet-chlorite with H2O (SABGC assemblage) is invariant in the K2O-FeO-MgO-Al2O3-SiO2-H2O (KFMASH) system. Such five-phase AFM assemblages should be absent in nature, but reported occurrences from at least ten localities suggest that either the assemblage internally controls μH2O or non-KFMASH components stabilize one or more of the phases.Least-squares regression analysis of minerals from South Royalton and Gassetts, Vermont, USA, demonstrates that subsets of the minerals in single SABGC assemblages from both localities are related by balanced reactions involving water. These results are consistent with the interpretation that the subassemblages fixed μH2O at an arbitrary, specified pressure and temperature. Balanced dehydration reactions also may be written between minerals in the SABGC assemblages and four-phase assemblages from the same outcrops interpreted to have equilibrated at the same pressures and temperatures as the five-phase assemblages. These results suggest that different specimens from the same outcrops equilibrated at different values of μH2O, supporting the conclusion that μH2O was not controlled externally. We could not demonstrate internal control of fo2 using measured mineral compositions because oxygen balance occurred in all reactions derived by regression.Regression analysis of published mineral compositions from New Mexico failed to identify balanced reactions involving water or oxygen either among the phases in a single SABGC assemblage or between SABGC and nearby four-phase assemblages. These results demonstrate that neither μH2O nor fo2 were fixed by the SABGC assemblages at these localities, and permit the interpretations that the assemblages were stabilized by the non-KFMASH components Na or Ca and that μH2O and fo2 were controlled externally.

Notes: Abstract Albite porphyroblasts are widely distributed in pelitic and semi-pelitic schists of the Fleur de Lys Supergroup, western Newfoundland. Textures and mineral assemblages indicate that albite grew during nearly isothermal decompression from P-T conditions of about 500° C, 9 kbar, to conditions of 550° C, 6.5 kbar. Three compositional varieties of albite-bearing schists, here termed PMAQ (paragonite-muscovite-albite-quartz), MMAQ (microcline-muscovite-albite-quartz), and PMMQ (paragonite-muscovite-margarite-quartz), can be distinguished on the basis of pre-porphyroblast mineral assemblages. Analysis of these assemblages in terms of the composition of the coexisting fluid [log a(Na+/H+) versus log a(K+/H+)] suggests that, as pressure and temperature changed, the stability field of albite expanded at the expense of coexisting matrix phyllosilicates. This promoted growth of albite on pre-existing or newly formed nuclei. Late oligoclase in PMAQ and PMMQ samples is associated with replacement of matrix garnet by plagioclase + mica ° Chlorite, particularly in strongly sheared samples.

Notes: Abstract Spinel-quartz-cordierite and spinel-quartz are found as relic prograde assemblages in Fe-rich granulites from the Araku area, Eastern Ghats belt, India. Subsequent reactions produced orthopyroxene + sillimanite in the former association and garnet + sillimanite in the latter. The first reaction is univariant in the FMAS system, but is trivariant in the present case because of the presence of Zn and Fe3+ in spinel. The second reaction also has high variance because of Zn and Fe3+, but also because of the presence of Ca in garnet. Thermobarometry shows that the metamorphic conditions were approximately 950° C and 8.5 kbar and the fo2 was near the NNO buffer. In Fe-rich bulk compositions and low-P-high-T conditions of metamorphism, two of the univariant reactions around the invariant point [Sa], namely (Sa, Hy) and (Sa, Cd), change topology due to reverse partitioning of Fe-Mg between coexisting garnet and spinel. An alternative partial petrogenetic grid in the system FMAS is constructed for such conditions and is applied satisfactorily to several sapphirine-free spinel granulites. It is shown that bulk composition (XFe and Zn) exerts greater control on the stability of spinel + quartz than fo2. The effect of the presence of Zn and Fe3+ in spinel on the proposed grid is evaluated. Reaction textures in the Araku spinel granulites can be explained from the petrogenetic grid as due to near-isobaric cooling.

Notes: The impure marbles of the internal Sesia-Lanzo Zone underwent a multi-stage metamorphic evolution of Alpine age and retain early-Alpine eclogitic assemblages, partially recrystallized under blueschist to greenschist facies conditions. These high-P assemblages consist of carbonates, phengite, quartz, omphacite, grossular-rich (locally spessartinic) garnet, zoisite and Al-rich titanite. Retrogressive stages are characterized by the growth of glaucophane, paragonite, phlogopite, tremolite and albite. Halogen-rich biotite and amphibole are also present. P-T estimates of the early-Alpine metamophism have been calculated from these unique high-P assemblages, in order to test the applicability of some calibrations to impure carbonate systems. In particular, some Gt-Cpx calibrations and the phengite geobarometer give results (T= 575 ± 45° C at 15 kbar for the eclogitic climax and T≤ 500° C at PH2O ≤ 9 kbar for early-Alpine retrogressive stages) which are within the range obtained from the surrounding lithologies.Phase relationships in P-T-XCO2 space indicate that mineral assemblages in the impure marbles coexisted with H2O-rich fluids (XCO2 〈0.03) during their entire Alpine evolution.

Notes: Petrographical and mineral chemical data are given for the eclogites which occur in the garnet-kyanite micaschists of the Penninic Dora-Maira Massif between Brossasco, Isasca and Martiniana (Italian Western Alps) and for a sodic whiteschist associated with the pyrope-coesite whiteschists of Martiniana. The Brossasco-Isasca (BI) eclogites are fine grained, foliated and often mica-rich rocks with a strong preferred orientation of omphacite crystals and white micas. Porphyroblasts of hornblende are common in some varieties, whilst zoisite and kyanite occur occasionally in pale green varieties associated with leucocratic layers with quartz, jadeite and garnet. These features differentiate the BI eclogites from the eclogites that occur in other continental units of the Western Alps, which all belong to type C. Garnet, sodic pyroxene and glaucophane are the major minerals in the sodic whiteschist.Sodic pyroxene in the eclogites is an omphacite often close to Jd50Di50, with very little acmite and virtually no AlIV, and impure jadeite in the leucocratic layers and in the sodic whiteschist. Garnet is almandine with 20–30 mol. % for each of the pyrope and grossular components in the eclogites and a pyrope-rich variety in the sodic whiteschist. White mica is a variably substituted phengite, and paragonite apparently only occurs as a replacement product of kyanite. Amphibole is hornblende in the eclogites, but the most magnesian glaucophane yet described in the sodic whiteschist. Quartz pseudomorphs of coesite were found occasionally in a few pyroxenes and garnets.The P-T conditions during the VHP event are constrained in the eclogites by reactions which define a field ranging from 27–28 kbar to 35 kbar and from 680 to 750° C. These temperatures are consistent with the results of garnet-pyroxene and garnet-phengite geothermometry which suggest that the eclogites may have equilibrated at around 700° C. In the sodic whiteschist pressures ranging from 29 to 35 kbar can be deduced from the stability of the jadeite-pyrope garnet-glaucophane compatibility. As in the eclogites water activity must have been low. Such conditions are close to the P-T values estimated for the early Alpine recrystallization of the pyrope-coesite rock and, like petrographical and mineralogical features, set aside the BI eclogites from the other eclogites of the Western Alps, instead indicating a close similarity to some of the eclogite bodies occurring in the Adula nappe of the Central Alps. An important corollary is that glaucophane stability, at least in Na- and Mg-rich compositions and under very high pressures, may extend up to 700° C, in agreement with the HT stability limit suggested by experimental studies.

Notes: The retrograde P-T trajectory of the eclogitic Fe-Ti-gabbros from the Ligurian Alps is constrained by the appearance of mineral parageneses post-dating the Na-clinopyroxene + garnet eclogitic assemblage and indicating the following sequence of metamorphic events: (1) amphibolitic stage— edenite/katophorite + plagioclase (An33–43) + oxides in symplectitic aggregates; (2) glaucophanic stage— a porphyroblastic glaucophanic amphibole has overgrown the symplectite, winchite also occurs as thin rims around glaucophane and both amphiboles are, sometimes, armoured by atoll garnets; (3) albite-amphibolite stage—barroisite/katophorite + albite + epidote + oxides ± chlorite overprint the glaucophanic stage minerals; (4) greenschist stage—represented by actinolite + albite + epidote + oxide paragenesis.The metamorphic evolution is complex and the decompression path, on a P–T diagram, is significantly different from those defined in the literature for the Voltri eclogites. The main features inferred from the P–T path are the following: (1) the pressure climax does not match the thermal climax, the maximum temperature conditions are in fact achieved during the early stage of uplift; (2) a decrease in temperature, suggested by the appearance of glaucophane after the amphibolitic symplectite; (3) successive uplift, probably accompanied by an increase in temperature. The complexity of the P-T path drawn for the Voltri eclogites can be explained with a mechanism of successive underthrusts propagating from the innermost to the outermost sector of the Ligurian Alps.

Notes: CO2–CH4 fluid inclusions are present in anatectic layer-parallel leucosomes from graphite-bearing metasedimentary rocks in the Skagit migmatite complex, North Cascades, Washington. Petrological evidence and additional fluid inclusion observations indicate, however, that the Skagit Gneiss was infiltrated by a water-rich fluid during high-temperature metamorphism and migmatization.CO2-rich fluid inclusions have not been observed in Skagit metasedimentary mesosomes or melanosomes, meta-igneous migmatites, or unmigmatized rocks, and are absent from subsolidus leucosomes in metasedimentary migmatites. The observation that CO2-rich inclusions are present only in leucosomes interpreted to be anatectic based on independent mineralogical and chemical criteria suggests that their formation is related to migmatization by partial melting. Although some post-entrapment modification of fluid inclusion composition may have occurred during decompression and deformation, the generation of the CO2-rich fluid is attributed to water-saturated partial melting of graphitic metasedimentary rocks by a reaction such as biotite + plagioclase + quartz + graphite ± Al2SiO5+ water-rich fluid = garnet + melt + CO2–CH4. The presence of CO2-rich fluid inclusions in leucosomes may therefore be an indication that these leucosomes formed by anatexis.Based on the inferences that (1) an influx of fluid triggered partial melting, and (2) some episodes of fluid inclusion trapping are related to migmatization by anatexis, it is concluded that a free fluid was present at some time during high-temperature metamorphism. The infiltrating fluid was a water-rich fluid that may have been derived from nearby crystallizing plutons. Because partial melting took place at pressures of at least 5 kbar, abundant free fluid may have been present in the crust during orogenesis at depths of at least 15 km.

Notes: The solid-solid reaction magnesiocarpholite = sudoite + quartz has been bracketed between 350 and 500°C, 6.3 and 7.8 kbar. Because it is impossible to synthesize end-member sudoite, all experiments were carried out using natural minerals as starting materials. Although mineral compositions were very close to those of the end-members, the effect of the fluorine content in carpholite was significant. Particularly in those experiments where sudoite grows at the expense of carpholite, electron microprobe analysis of the run products shows that a more stable F-rich carpholite crystallizes too, and consumes the fluorine released in solution by the breakdown of the original carpholite.Our experimental results are combined, through a thermodynamic analysis, with a previous data set and with previous experimental data concerning the relative stability of chlorite, talc and magnesiocarpholite with excess of quartz and water as a function of P–T and AlAl(SiMg)-1 substitutions in phyllosilicates. This allows us to constrain the feasible thermodynamic parameters (H°f, sud; S° sud) and (H°f,car; S°car) for the Mg end-members. Using the partition coefficients calculated from natural parageneses, we have computed a petrogenetic grid for the system FeO–MgO–Al2O3–SiO2–H2O. It demonstrates that parageneses involving sudoite and carpholite can be used as indicators of P–T conditions, up to 600° C, 8 kbar for sudoite, and at higher pressure for carpholite.

Notes: Regional-scale mapping of index-mineral isograds in mafic units of the early Proterozoic Cape Smith Thrust Belt (northern Québec) has revealed contrasting pressure-temperature regimes associated with two distinct structural domains. In the southern domain, crustal thickening was accomplished by early, piggy-back thrust faults. Isograds cross-cut the thrusts, indicating that thermal-peak mineral growth outlasted deformation associated with early imbrication. Mineral zones are: (1) actinolite (Act) + albite (Alb); (2) hornblende (Hbl) + Act + Alb; (3) Hbl + Act + oligoclase (Oli); (4) Hbl + Oli; and (5) garnet (Grt) or clinopyroxene + Hbl + Oli-andesine. The oligoclase isograd occurs at higher grade than the hornblende isograd, a sequence typical of medium-pressure terranes (5–7 kbar). An Hbl-Alb bathograd. calibrated from mixed-volatile equilibria in the NCMASH-CO2 model system, suggests minimum pressures of about 5.4 kbar.Metamorphism in the northern domain was a consequence of re-imbrication, by means of out-of-sequence thrust faults active during and after peak metamorphic conditions. Mineral growth was coeval with thrusting, as documented by the syn-kinematic garnet porphyroblasts. Compared to the southern domain, a different sequence of isograds in mafic rocks shows that the albite-oligoclase transition takes place in the garnet zone. Based on thermobarometry in garnet-hornblende rocks, the oligoclase isograd occurs in a temperature range of 525–600°C, typical of high-pressure terranes (7–10 kbar). Calibrated bathograds for the Hbl-Ms-Alb and Grt-Alb bathozonal assemblages, respectively in the KNCMASH-CO2 and NCMASH model systems, indicate minimum pressures in the northern domain of 6.7 and 8.5 kbar. Higher-pressure series for this domain are explained by out-of-sequence thrusts exposing deeper crustal levels. For similar structural levels, only minor amounts of syn-deformational uplift (1–2 kbar and 50–75°C) are recorded in metabasites of this domain, compared to results in adjacent metapelites of the area (essentially isothermal uplift of 3–5 kbar).RESUME La bande du Cap Smith (nord du Québec) est une ceinture de chevauchement d'ǎge protérozoique inférieur, dominée par des roches mafiques. La cartographie d'isogrades à minéraux indicateurs dans les unités mafiques de la ceinture a révelé deux régimes contrastes de pression–température, chacun associéà des épisodes distincts d'épaississement crustal. Dans le domaine sud, des failles de chevauchement en-série sont responsables pour l'empilement tectonique. Les isogrades recoupent les failles, indiquant que l'apogée thermale a suivi l'emplacement initial des nappes de charriage. Les zones minérales sont: (1) actinote (Act) + albite (Alb); 2) hornblende (Hbl) + Act + Alb; (3) Hbl + Act + oligoclase (Oli); 4) Hbl + Oli; et (5) grenat (Grt) où clinopyroxene + Hbl + Oli-andésine. L'isograde d'oligoclase apparaǐt à plus haute température que l'isograde d'hornblende, une séquence typique des terrains de pressions moyennes. Un bathograde Hbl–Alb, calibréà partir d'équilibre mixte de volatiles dans le système NCMASH–CO2, suggère des pressions minimales d'environ 5.4 kbar.Le métamorphisme dans le domaine nord de la ceinture a été le résultat d'une réimbrication, causé par des chevauchements hors-série actifs pendant et après l'apogée thermale. La croissance minérale fǔt synchrone au chevauchement, documentée par des porphyroblastes de grenat syn-cinénatique. Comparé au domaine sud, une différente séquence d'isogrades dans les métabasaltes montre que la transition albite–oligoclase se situé dans la zone à grenat. Par la thermobarométrie dans les roches à grenat–hornblende l'isograde d'oligoclase se situe dans un écart de température de 525–600°C, typique des terrains de hautes pressions (7–10 kbar). Des bathogrades calibrés pour les assemblages bathozonales Hbl–Ms–Alb et Grt–Alb, rcspectivement dans les systèmes KNCMASH–CO2 et NCMASH, indique des pression minimales pour le domaine nord de 6.7 et 8.5 kbar. Une zonégraphie à plus haute pression pour ce domaine est expliquée par des chevauchements hors-série exposant des niveaux plus inférieurs de la croǔte imbriqué. Pour des niveaux structuraux similaries, des soulèvements syn-métamorphiques mineurs sont enregistrés dans les métabasaltes (1–2 kbar et 50–75°C), comparés aux métapélites adjacentes avec un soulèvement (essentially isothermal uplift of 3–5 kbar.

Notes: Mid-Cretaceous granulite gneisses crop out in a narrow belt in the Cucamonga region of the south-eastern foothills of the San Gabriel Mountains, southern California. Interlayered mafic granulites and pelitic, carbonate, calc-silicate and quartzofeldspathic metasediments record hornblende granulite subfacies metamorphism at approximately 8 kbar and 700–800°C. Regional deformation and formation of banded gneisses ceased by c. 108 Ma. although mafic-intermediate magmatism and high-grade metamorphism continued locally as late as c. 88 Ma. Garnet zoning in metapelitic gneisses suggests that peak metamorphism was followed locally by a period of near-isobaric cooling, but this interpretation requires diachronous cooling of the granulite belt which cannot be demonstrated without detailed thermo-chronological data. It is more likely that the entire terrane remained at granulite facies P–T conditions until 88 Ma, followed by rapid uplift associated with juxtaposition against adjacent middle and upper crustal arc terranes. Uplift occurred between c. 88 and 78 Ma at rates of approximately 1–2 km Ma-1. The geotectonic evolution of the Cucamonga granulites is similar to mid-Cretaceous high-P granulites in the Sierra Nevada and Salinian block of central California. Late Cretaceous uplift common to these granulites may provide an important tectonic link between dismembered Mesozoic batholithic terranes in the California Cordillera.

Notes: In this paper we analyze the properties of price equilibria in a duopoly market where firms sell vertically differentiated products, consumers being uncertain about which firm sells which quality. Both existence and properties of price equilibria are characterized by the beliefs of the consumers' population about the distribution of quality between firms.

Notes: The survey classifies economic theories of the firm into four categories based on the level of aggregation in economic models: (1) neoclassical, (2) industrial organization, (3) contractual, and (4) organizational incentive. Economic theories of the firm are evaluated on the basis of their potential application to problems of management decision making. The survey suggests that a management perspective can be useful in developing an integrated theoretical analysis of the firm that addresses both competitive strategy and organizational design.

Notes: Commitment: The Dynamic of Strategy, by Pankaj Ghemawat.Ghemawat's Commitment makes recent results in game-theoretic industrial organization accessible and useful to practitioners in the field of strategic management. This book contributes to the management strategy literature on two levels. On a conceptual level, Ghemawat strives to isolate “commitment” as the sole explanation of persistent differences in firm performance. On a more pragmatic level, he provides a framework intended to aid managers in making commitment-intensive decisions. It is with respect to how well he achieves these two distinct goals that I evaluate Ghemawat's contribution. In addition, I review briefly the book's content, and I compare Ghemawat's approach to some alternative approaches familiar to scholars and practitioners of strategic management.

Notes: In the present paper, we relate the extent of job security offered to incumbent managers to the extent of competition among firms in the product market, where the extent of job security is measured by the probability that an incumbent manager continues to be employed by his current firm and the extent of competition is measured by the degree of differentiation between competing brands. We demonstrate that when competition between firms intensifies and “on-the-job training” is relatively more conducive to reducing the variable costs of production, firms tend to offer reduced (increased) job security to incumbent managers, provided that the degree of differentiation between competing products is sufficiently large (small), respectively. If “on-the-job training” is relatively more conducive to reducing the fixed costs of production, however, the previous result is reversed.

Notes: This paper presents a model of strategic product choice when consumer preferences combine features of both horizontal and vertical product differentiation. Consumers disagree on what amount of a “special” characteristic makes for a better product, but those who prefer more of this attribute are willing to pay more for it. Within this demand structure, I examine the advantages of first-mover firms. I find that such firms typically do best in markets where the maximum degree of product differentiation is limited by preferences rather than technology. These are “niche markets”. Follower firms do better in markets in which the range of preferences is broad relative to the span of feasible goods.

Notes: This paper reexamines Grossman and Hart's (1980) insight into how the free-rider problem excludes an external raider from capturing the increase in value it brings to R firm The inability of the raider to capture any of the surplus depends critically on the assumption of equal and indivisible shareholdings–the one-share-per-shareholder model In contrast, we show that once shareholdings are large and potentially unequal, a raider may capture a significant part of the increase in value Specifically, the free-rider problem does not prevent the takeover process when shareholdings are divisible.

Notes: We analyze the implementation problem faced by firms when trying to collude in the face of asymmetric information about costs. Assuming that transfer payments are possible, we examine the incentive compatibility and individual rationality constraints that must be satisfied by any cartel agreement. Two scenarios are considered. Firms may or may not withdraw from the agreement after each firm's costs become known. If no withdrawal is possible, we find that the monopoly rule is implementable when weak types of individual rationality constraints are required. This contrasts with some results in the literature. If withdrawal is possible, we find a potential conflict between different forms of individual rationality constraints, in particular, between interim and ex post constraints. This conflict disappears in industries with a large number of firms.

Notes: This paper offers a general characterization of the optimal product line prices for a monopolist whose quality of products is initially unknown to consumers. In the focal equilibrium, a monopolist signals a high-quality product line by pricing as if quality were known to be high, but costs of production were higher than they truly are. In a rich set of environments, this characterization implies that the prices of all products are initially distorted upward, with the price distortion being largest for products with the most inelastic demands and/or quality-sensitive production costs. These implications yield predictions for the time path of prices flint are broadly consistent with evidence from the marketing literature. The multidimensional signaling problem is made tractable by the satisfaction of a very simple and powerful single crossing property.

Notes: Managerial behavior that is rational and profit-maximizing sometimes will seem to be overly conservative. If the valuation of innovations contains white noise and the status quo would be preferred to random innovation, then any innovation that does not appear substantially better than the status quo should be rejected, for reasons arising from regression toward the mean. The more successful the firm, the higher is the optimal acceptance threshold and conservative bias. Other things equal, more successful firms will spend less on research, adopt fewer innovations, and be less likely to advance the industry's best practice.

Notes: Identical cases of wine are often auctioned one immediately after another. Ashenfelter (1989) reports that on average, the later lots fetch less. Such a systematic price difference seems anomalous, the more so because it is shown here that rational expectations imply not equal, but rising, prices. Risk aversion is an obvious way of reconciling the evidence with rational behavior. There is an alternative explanation. The auctions observed by Ashenfelter involved a buyer's option, whereby the first-round winner could purchase further cases at the same price. It is shown that this feature may both account for the observed price trajectory and raise seller revenue.

Notes: This paper examines the incentives for integration when the market for consumer durables (hardware) is oligopolistic and the market for complementary services (software) is monopolistically competitive. We find that the equilibrium industry structure will depend on the magnitude of the fixed costs of software development. If the software development costs are relatively large, the equilibrium industry structure is unintegrated, that is, neither hardware firm integrates; if the software development costs are relatively small, the equilibrium industry structure is integrated, that is, both hardware firms integrate. Under the integrated industry structure, hardware profits are lower, less varieties are provided, and hardware prices are lower than under the unintegrated industry structure. The game has a prisoners' dilemma structure when the software development costs are relatively small because of a foreclosure effect. Strategically increasing the number of software varieties provides an avenue for an integrated hardware firm to increase its market share and profits by reducing the number of software varieties available for an unintegrated rival technology. Although consumer surplus is higher under an integrated industry structure, the total surplus associated with the unintegrated industry structure exceeds that of the integrated industry structure.

Notes: Price setting by firms and search by customers is analyzed, relaxing two basic attributes of most search models: price precommitment and agent heterogeneity. Customers are characterized by individual demand functions for a homogeneous good and can choose to employ a threat to search. Firms noncooperatively make pricing decisions by using the individual demand curves under conditions of constant marginal cost. Firms adopt pricing rules that optimally respond to customer search histories. Bargaining power is endogenously assigned. Firms know their common marginal cost; customers, the cost distribution. The unique separating equilibrium is characterized by a lumpy distribution of prices and by heterogeneous shopping behavior by customers giving rise to “shoppers” and “nonshoppers”

Notes: Most research on product positioning supports the idea of differentiation. Product standardization (i.e., minimum differentiation) occurs only under very limiting assumptions. Yet, similar products are often observed in the marketplace. We attempt to restore the case for standardization by using more realistic assumptions than in previous work. We assume that consumers consider not only observable attributes in brand choice, but also attributes that are unobservable by the firms. We find that standardization is an equilibrium when consumers exhibit sufficient heterogeneity along the unobservable attributes under both positioning with exogenously given prices and price competition, We also show that, under insufficient heterogeneity along the unobservable attribute, our results coincide with past research that argues in favor of differentiation.

Notes: This paper proposes an empirical methodology for studying various (implicit or explicit) collusive behaviors on two strategic variables, which are price and advertising, in a differentiated market dominated by a duopoly. In addition to Nash or Stackelberg behaviors, we consider collusion on both variables, collusion on one variable and competition on the other, etc. Using data on the Coca-Cola and Pepsi-Cola markets from 1968 to 1986, full information maximum likelihood estimation of cost and demand functions are obtained allowing for various collusive behaviors. The collusive hypothesis is not rejected, and the best form of collusive behavior is selected via nonnested testing procedures. Using the best model, Lerner indices are computed for both duopolists to provide summary measures of market power. Finally, our approach is contrasted with the conjectural variation approach and is shown to give superior results.

Notes: The microstructures in the Erro-Tobbio peridotite indicate several stages of recrystallization of olivine + titanian clinohumite-bearing assemblages. The development of these assemblages is closely associated with serpentinite mylonites, in which they occur in shear bands and foliations and are inferred to have grown synkinematically, in veins, and as post-kinematic radial aggregates. In the peridotite wall-rock adjacent to these mylonites, the same assemblages have recrystallized statically at the expense of original olivine and pyroxenes, mesh-textured chrysolite and antigorite veins. In addition, the olivine-bearing assemblage occurs in widespread vein systems. The brittle deformation of the peridotite resulting in the development of these vein systems is closely related to ductile deformation of metagabbroic dykes in the peridotite. Although early metasomatism resulted in extensive rodingitization of the gabbros, some dykes show an eclogitic assemblage of Na-clinopyroxene + garnet + chloritoid + chlorite ± talc. These observations, the microstructures and the mineral chemistry all suggest that the assemblages in the ultramafic rocks and metagabbros developed during a prograde evolution towards high pressures (〉13–16 kbar, 450–550° C), and during subsequent decompression. This metamorphic evolution is considered to be related to Late Cretaceous intraoceanic subduction in the Alps-Apennine system and closure of the Piedmont-Ligurian basin.

Notes: Abstract In well NJ-15 of the Nesjavellir geothermal field, Iceland, the transition of discrete smectite into discrete chlorite has been studied from drill cuttings recovered at depths of less than 1714 m and over a continuous range of temperatures between 60 and 300° C. At temperatures below 180° C, the clay fractions contain mixtures of di- and trioctahedral smectites, whose layer charge increases with depth. Between 200 and 240° C, discrete smectites have transformed into smectite-rich, randomly interstratified chlorite and smecite (R0 C/S). Because the abundance of chlorite interlayers in this C/S is generally 〈20%, its presence can be detected only by electron microprobe techniques and not by X-ray diffraction. Between 245 and 265° C, both regularly (R1) and randomly interstratified C/S are the predominant layer silicates. Discrete chlorite first appears at approximately 270° C and coexists with minor amounts of R0 C/S at higher temperatures. R0 and R1 C/S form a nearly complete compositional series between trioctahedral saponite and discrete chlorite end-members. The interlayer cation and Si content of smectites and C/S decrease with increasing temperature. The Mg/(Mg + Fe) content of smectite, C/S, and chlorite is unrelated to temperature. The percentage of chlorite in C/S, as determined by electron microprobe analyses, increases continuously with increasing temperature, except for occurrences of smectite-rich C/S in fresh basaltic dykes which have not thermally equilibrated with the higher grade country rocks.

Notes: Abstract Fairly strong (r= 0.75–0.85) positive linear correlations were found between crystallinity indices (peak widths) measured on the first two basal reflections of chlorite and those of illite–muscovite in 〈2-μm fractions of a representative shale–slate–phyllite series from Palaeozoic and Mesozoic formations of northeast Hungary. The metamorphic grade ranges from late or deep diagenesis through anchizone to epizone conditions. Chlorite crystallinity values measured on air-dried and ethylene-glycol-solvated samples suggest that the effects of expandable interlayers are negligable, especially in the higher grade (∼temperature) part of the series. However, the greater scattering of crystallinity values for the chlorite 001 reflection compared to those of the 002 reflection may be related to the effects of minor amounts of interlayered and/or discrete smectite and/or vermiculite. With increasing metamorphic grade and advancing equilibrium recrystallization, the chlorite compositions in different samples become more homogenous. No correlation exists between crystallinity and changes in chlorite composition as estimated from the intensity ratios of basal reflections. Hence an increase of domain size and a decrease of lattice distortion with increasing grade (∼temperature) may be decisive factors affecting chlorite crystallinity.Chlorite crystallinity can be applied as a reliable regional, statistical technique complementary with, or instead of, the illite crystallinity method. The illite and chlorite crystallinity scales used here are related to Kübler's epi-, anchi- and diagenetic zones and correlated with coal rank, conodont colour alteration and mineral facies data. As the effects of the detrital white mica can be observed even in the 〈2-μm fractions of anchizonal metapelites, the anchizone boundaries determined solely on the base of ‘fixed’illite crystallinity values may vary with amounts of detrital and newly formed muscovite–illite. Hence a complex approach utilizing more than one method for determination of grade is preferred for petrogenetic purposes, even if relationships between crystallinity scales, coal rank and mineral facies also vary strongly in different tectonic settings and lithologies.

Notes: Abstract Illite crystallinity (IC) and other indicators of the grade of very-low-grade metamorphism associated with the appearance of various stages of slaty cleavage in phyllosilicate-rich rocks have been compiled from a wide variety of terranes. IC values have been converted to a Kübler-equivalent standard scale, but the diverse characterizations of the cleavage fabrics in published descriptions do not always allow an unequivocal identification of equivalent stages of cleavage development.Nevertheless, there exists a distinct relationship between grade and the appearance of various stages of cleavage development.(1) Indications of incipient slaty cleavage, such as S0–S1 pencil structure, appearance of primary (S1) crenulation cleavage and of closely-spaced cleavage without parallel fabric in the microlithons, is associated with a wide range of mostly medium- and high-grade diagenetic IC values.(2) The appearance of smooth cleavage with a strong parallel fabric in the microlithons and/or quartz–mica ‘beards’and the chlorite–mica stacks shortened at a high angle to (001), and of irregular cleavage in sandy beds is associated with a much narrower range of predominantly low- and medium-grade anchimetamorphic grades (rarely high-grade diagenetic). The first appearance of these stages of cleavage development with higher grades can often be related to post-kinematic magmatic heating, polymetamorphism (pre-cleavage metamorphism), or ‘static’recrystallization without cleavage formation, for example in low-strain zones.There exists a relationship between finite strain, fabric and metamorphic grade in mudstones and slates; in coarser clastic rocks the same finite strain–fabric relationship occurs at appreciably higher grades. A relationship between finite strain in carbonate rocks and IC in the nearby rocks has been reported from the Helvetic zone of the Swiss Alps.The earlier stages of cleavage formation are associated with little improvement in IC; the narrow range of IC associated with smooth cleavage is concluded to represent recrystallization and grain growth concurrent with cleavage formation.

Notes: Distinctive lithological associations and geological relationships, and initial geochronological results indicate the presence of an areally extensive region of reworked Archaean basement containing polymetamorphic granulites in the Rauer Group, East Antarctica.Structurally early metapelites from within this reworked region preserve complex and varied metamorphic histories which largely pre-date and bear no relation to a Late Proterozoic metamorphism generally recognized in this part of East Antarctica. In particular, magnesian metapelite rafts from Long Point record extreme peak P–T conditions of 10–12 kbar and 100–1050°C, and an initial decompression to 8 kbar at temperatures of greater than 900°C. Initial garnet–orthopyroxene–sillimanite assemblages contain the most magnesian (and pyrope-rich) garnets (XMg= 0.71) yet found in granulite facies rocks. A high-temperature decompressional P–T history is consistent with reaction textures in which the phase assemblages produced through garnet breakdown vary systematically with the initial garnet XMg composition, reflecting the intersection of different divariant reactions in rocks of varied composition as pressures decreased. This history is thought to relate to Archaean events, whereas a lower-temperature (c. 750–800°C) decompression to 5 kbar reflects Late Proterozoic reworking of these relict assemblages.The major Late Proterozoic (c. 1000 Ma) granulite facies metamorphism is recorded in a suite of younger Fe-rich metapelites and associated paragneisses in which syn- to post-deformational decompression, through 2–4 kbar from maximum recorded P–T conditions of 7–9 kbar and 800–850°C, is constrained by geothermobarometry and reaction textures. This P–T evolution is thought to reflect rapid tectonic collapse of crust previously thickened through collision.

Notes: In the southeastern Reynolds Range, central Australia, a low-P granulite facies metamorphism affected two sedimentary sequences: the Lander Rock Beds and the Reynolds Range Group. In the context of the whole of the Reynolds Range and the adjacent Anmatjira Range, this metamorphism is M3 in a sequence M1–4 that occurred over a period of 250 Ma. In particular, M1 affected the Lander Rock Beds prior to the deposition of the Reynolds Group. M3 has an areally restricted, high-grade area in the southeastern Reynolds Range, affecting both the Reynolds Range Group and the underlying Lander Rock Beds. The effects of M3 are characterized by spinel + quartz-bearing peak metamorphic assemblages in metapelites, which imply peak conditions of ≥750°C and 4.5 ± 1 kbar, and involved isobaric cooling or compression with cooling. It is concluded that one of a series of thermal perturbations caused by thinning of mantle lithosphere contemporaneous with crustal thickening was responsible for M3. In the southeastern Reynolds Range, evidence of both the unconformity between the two rock groups and previous metamorphism/deformation has been completely erased by recrystallization during M3–D3.

Notes: On the basis of fluid inclusion evidence, pervasive influx of deep-seated CO2-rich fluids has been invoked to account for mid- to upper amphibolite facies (M2B) metamorphism on the island of Naxos (Cyclades, Greece). In this paper, mineral devolatilization and melt equilibria are used to constrain the composition of both syn- and post-peak-M2B fluids in the deepest exposed levels of the metamorphic complex. The results indicate that peak-M2B fluids were spatially and compositionally heterogeneous throughout the high-grade core of the complex, whereas post-peak-M2B fluids were generally water-rich. The observed heterogeneities in syn-M2B fluid composition are inconsistent with pervasive CO2-flushing models invoked by previous workers on the basis of fluid inclusion evidence. It is likely that few CO2-rich fluid inclusions on Naxos preserve fluids trapped under peak metamorphic conditions. It is suggested that many of these inclusions have behaved as chemically open systems during the intense deformation that accompanied the uplift of the metamorphic complex. A similar process may explain the occurrence of some CO2-rich fluid inclusions in granulite facies rocks.

Notes: A detailed high-pressure experimental study of two mafic xenoliths, in which coexisting garnet and clinopyroxene (± plagioclase, spinel and olivine) were crystallized over a P–T range of 10–30 kbar and 950–1200°C, has revealed significant differences in temperatures from those estimated for coexisting garnets and clinopyroxenes using the Ellis & Green Fe–Mg exchange thermometer. The results show perfect matching at 30 kbar, 1150–1200°C, but increasing deviation at lower pressure and lower temperature, with the Ellis & Green calibration reaching a ΔT (overestimate) of c. 145°C at 10–12 kbar and 950°C. The grossular content of the garnet increases from c. 21 mol.% at 10 kbar to 26–31 mol.% at 30 kbar. These results confirm other recent experimental studies that show that the pressure correction, and possibly to a lesser extent the correction for grossular content, applied by Ellis & Green, are not appropriate for lower pressure conditions, and give estimated temperatures that are significantly high when applied to granulitic terranes formed at c. 10 kbar. The new reconnaissance results allow a graphical interpolation of a garnet–clinopyroxene geothermometer based on the Fe–Mg exchange reaction which should be applicable to assemblages formed under lower crustal conditions.

Notes: The Main Zone of the Hidaka Metamorphic Belt is an uplifted crustal section of island-arc type. The crust was formed during early Tertiary time, as a result of collision between two arc–trench systems of Cretaceous age. The crustal metamorphic sequence is divided into four metamorphic zones (I–IV), in which zone IV is in the granulite facies.A detailed study of the evolution of the Hidaka Belt, based on a revised P–T–t analysis of the metamorphic rocks, notably a newly found staurolite-bearing granulite, confirms a prograde isobaric heating path, after a supposed event of tectonic thickening of accretionary sedimentary and oceanic crustal rocks. During the peak metamorphic event (c. 53 Ma), the regional geothermal gradient attained 33–40° C km−1, and the highest P–T condition obtained from the lowest part of the granulite unit is 830° C, 7 kbar. In this part, XH2O of Gt–Opx–Cd gneiss is about 0.15 and that of Gt–Cd–Bt gneiss is 0.4. The P–T–XH2O condition of the granulite unit is well within a field where fluid-present partial melting of pelitic and greywacke metamorphic rocks takes place. This is in harmony with the restitic nature of the Gt–Opx–Cd gneiss in the lowest part of the granulite unit.The possibility that partial melting took place in the Main Zone is significant for the genesis of the peraluminous (S-type) granitic rocks within it. The S-type granitic rocks in this zone are Opx–Gt–Bt tonalite in the granulite zone, Gt–Cd–Bt tonalite in the amphibolite zone, and Cd–Bt–Mus tonalite in the Bt–Mus gneiss zone. The mineralogical and chemical nature of these strongly peraluminous tonalitic rocks permit them to be regarded as having been derived from S-type granitic magma generated by crustal anatexis of pelitic metamorphic rocks in deeper crust.

Notes: The Whitestone Anorthosite (WSA), located in southern Ontario, underwent granulite facies metamorphism during the Grenville orogeny at 1.16 Ga. During the waning stages of metamorphism fluids infiltrated the outer portions of the anorthosite and promoted the formation of an envelope comprised of upper amphibolite facies mineral assemblages. Also, this envelope corresponds to portions of the anorthosite that underwent deformation related to movement along a high-grade ductile shear zone. Samples from this portion of the anorthosite (the margin) contain CO2-rich inclusions in plagioclase porphyroclasts (relict igneous phenocrysts), matrix plagioclase and garnet. These inclusions have features which normally are interpreted as indicating that they are texturally primary, but they have relatively low CO2 densities (0.61–0.95 g cm-3). Plagioclase from the anorthosite interior contains texturally secondary inclusions with relatively high CO2 densities (generally from 0.99 to 1.10 g cm-3). The high CO2 densities suggest that the inclusions in the plagioclase of the anorthosite core formed prior to inclusions in porphyroclast minerals of the outer portions of the anorthosite, an interpretation that is apparently inconsistent with inclusion textures. This apparent paradox indicates that most fluid inclusions from the anorthosite margin were formed during, or were modified by, the dynamic recrystallization that affected this portion of the WSA. In either case, late formation or modification, the texturally primary fluid inclusions do not contain pristine samples of the peak metamorphic fluid. Furthermore, because shear-related deformation is apparently associated with entrapment of the lowest fluid densities, some strain localization persisted to relatively low temperatures (e.g. less than approximately 500° C). These results constrain a part of the retrograde P–T path for this portion of the Grenville Orogen to temperatures of approximately 400–500° C at pressures of approximately 1–2 kbar.

Notes: A suite of metapelites, charnockites, calc-silicate rocks, quartzo-feldspathic gneisses and mafic granulites is exposed at Garbham, a part of the Eastern Ghats granulite belt of India. Reaction textures and mineral compositional data have been used to determine the P–T–X evolutionary history of the granulites. In metapelites and charnockites, dehydration melting reactions involving biotite produced quartzofeldspathic segregations during peak metamorphism. However, migration of melt from the site of generation was limited. Subsequent to peak metamorphism at c. 860° C and 8 kbar, the complex evolved through nearly isothermal decompression to 530–650° C and 4–5 kbar. During this phase, coronal garnet grew in the calc-silicates, while garnet in the presence of quartz broke down in charnockite and mafic granulite. Fluid activities during metamorphism were internally buffered in different lithologies in the presence of a melt phase. The P–T path of the granulites at Garbham contrasts sharply with the other parts of the Eastern Ghats granulite belt where the rocks show dominantly near-isobaric cooling subsequent to peak metamorphism.

Notes: Staurolite porphyroblasts, 1.5–8cm in length and 0.3–2cm in width, in the Littleton Schist at Bolton, Connecticut, contain curved quartz inclusion trails which document synkinematic rotations of at least 135°. The orientations of long axes of these staurolite crystals define a weak preferred orientation in a plane approximately parallel to the external foliation. Serial sections of four differently orientated crystals and U-stage measurements of the orientations of their inclusion trails demonstrate that the inflection hinge line and the statistical ‘symmetry axis’ characterizing the foliation within a porphyroblast are unrelated to the orientations of external crenulations and are, in all cases, parallel to the long axis of the porphyroblast. The cumulative rotation reflected in the curvature of the inclusion trails is a maximum in a c-axis section through the initial core of a crystal. The amount of rotation about the c-axis decreases linearly along the length of the crystal away from the nucleation site.The sense and amount of rotation recorded by a porphyroblast is related to its orientation. A tightly constrained transition from clockwise to anticlockwise rotation defines a slip direction that coincides with the preferred orientation of the staurolite c-axes. The total rotation reflected by the inclusion trails increases as a function of the angle between the c-axes of the staurolite crystals and the slip direction.Initially random staurolite porphyroblasts rotated during growth, as a consequence of laminar shear in the surrounding viscous matrix. This interpretation is quantitatively consistent with: the staurolite preferred orientation; its coincidence with the apparent slip direction; the correlation between both the sense and the amount of rotation and the orientation of the long axis of the porphyroblast; and the twisted conical shape of the family of surfaces defined by the inclusion trails.

Notes: Silica-deficient sapphirine-bearing rocks occur as an enclave within granulite facies Proterozoic gneisses and migmatites near Grimstad in the Bamble sector of south-east Norway (Hasleholmen locality). The rocks contain peraluminous sapphirine, orthopyroxene, gedrite, anthophyllite, sillimanite, sapphirine, corundum, cordierite, spinel, quartz and biotite in a variety of assemblages. Feldspar is absent.Fe2+/(Fe2++ Mg) in the analysed minerals varies in the order: spinel 〉 gedrite ≥ anthophyllite ≥ biotite 〉 sapphirine〉orthopyroxene 〉 cordierite.Characteristic pseudomorph textures indicate coexistence of orthopyroxene and sillimanite during early stages of the reaction history. Assemblages containing orthopyroxene-sillimanite-sapphirine-cordierite-corundum developed during a high-pressure phase of metamorphism and are consistent with equilibration pressures of about 9 kbar at temperatures of 750–800°C. Decompression towards medium-pressure granulite facies generated various sapphirine-bearing assemblages. The diagnostic assemblage of this stage is sapphirine-cordierite. Sapphirine occurs in characteristic symplectite textures. The major mineralogical changes can be described by the discontinuous FMAS reaction: orthopyroxene + sillimanite → sapphirine + cordierite + corundum.The disequilibrium textures found in the Hasleholmen rocks are characteristic for reactions which have been in progress but then ceased before they run to completion. Textures such as reaction rims, symplectites, partial replacement, corrosion and dissolution of earlier minerals are characteristic of granulite facies rocks. They indicate that, despite relatively high temperatures (700–800° C), equilibrium domains were small and chemical communication and transport was hampered as a result of dry or H2O-poor conditions.

Notes: The Vredefort dome (2.0 Ga) represents the central uplift of a very large impact structure. This uplift exposed a nearly complete cross-section through the continental crust in the region, which is 25–30 km thick. Two metamorphic events took place at about the same time as the impact. The first event, so-called static metamorphism, is pre-impact and produced lithologies varying from low-grade shale to high-grade hornfels. It resembles contact metamorphism by its lack of schistosity, but is more regional as it extends over a large area and is not associated with large intrusions.The second event, the post-shock metamorphism, is responsible for the recrystallization of the shock features. The investigation of this event has been focused on the degree of alteration of the coesite-stishovite-bearing pseudotachylite veins that formed during the transit of the shock wave. These high-pressure silica polymorphs are only present in the upper part of the stratigraphic sequence; downward they have been converted to fibrous quartz. At the highest grade, the fibrous quartz is in turn replaced by triple-junctioned mosaic quartz. The post-shock metamorphism was generated by the heat of the rock before shock, plus the heat released by the shock wave. The isograds, plotted on a map, can be translated into depth of burial and therefore provide valuable information regarding the geological setting immediately before impact. At the time of impact, the rocks were relatively cool and the static metamorphism had ceased with several tens of millions of years separating the two metamorphic events. The static metamorphism was probably caused by continental crustal extension in a stress-free environment and the lack of deformation is probably due to rapid uplift during the later stages of the impact event.

Notes: The P–T paths for metamorphic complexes from the Precambrian shields and fold belts of different ages may result from advection, i.e. one-cycle convective processes in the lithosphere. This conclusion has been exemplified by the metamorphic evolution of several well-known complexes, for which an advective model can be successfully applied. Numerical simulations of the above processes in terms of Newtonian rheology by using a two-dimensional finite element program have been conducted.Two representative models for intracontinental gravitational ordering initiated presumably by mantle activity are considered: (i) a thermally activated multi-layered rhythmic sequence and (ii) huge rising diapiars causing circulation, in which crustal lithologies underwent high-P metamorphism (above 10–15 kbar) and subsequent ascent toward the Earth's surface.

Notes: The Waterman Metamorphic Complex of the central Mojave Desert was exposed as a consequence of early Miocene detachment-dominated extension. However, it has evidence consistent with a more extensive geological history that involves collision of a crustal fragment(s), tectonic thickening by overthrusting and two periods of extension. The metamorphic complex contains granitoid intrusives and felsic mylonitic gneisses as well as polymetamorphic rocks that include marble, calc-silicate, quartzite. mafic granulite, pyribolite, amphibolite, migmatite and biotite schist. The latter group of rocks was affected by an initial series of high-grade metamorphic events (M1 and M2) and a localized lower grade overprint (M3). The initial metamorphism (M1) can be separated into two stages along its high-grade P–T path: M1a, a granulite facies metamorphism at 800–850° C and 7.5–9 kbar and Mlb, an upper amphibolite facies overprint at 750–800° C and 10–12 kbar. M1a developed mineral assemblages and textures consistent with granulite facies conditions at a reduced activity of H2O and is associated with intense ductile deformation (D1) and minor local partial melting. M1b overprinted the granulite assemblages with a series of hydrous phases under conditions of increasing pressure and H2O activity and is accompanied by little or no deformation. M2 developed at lower pressures and temperatures (650–750° C, 4.5–5.5 kbar) and is distinguished by a second local overprint of hydrous phases that reflects an input of aqueous fluids probably associated with the intrusion of a series of granitic dykes and veins. Effects of M3 are confined to the Mitchel detachment zone, an anastomosing early Miocene detachment fault, and are characterized by local ductile/brittle deformation (D2) of the pre-existing high-grade rocks and granitoid intrusives and by the production of mylonites and mylonitic gneisses under greenschist facies conditions (300–350° C, 3–5 kbar). The initial overprint (M1a) represents metamorphism, devolatilization and minor partial melting of supracrustal rocks under granulite facies conditions as a consequence of tectonic and, possibly, magmatic thickening. The increasing pressure transition of M1a to M1b reflects a period of continued compressional tectonism, thrusting and influx of H2O, in part, locally related to crystallization of partial melts. The near isothermal decompression between M1b and M2 probably represents a pre-112-Ma extensional episode that may have been the result of a decompressional readjustment of a thickened crust. Following the initial extensional event, the metamorphic complex remained at depths of 10–17 km for at least 90 Ma until it was uplifted following Miocene extension. M3 develops locally in response to this second extensional period resulting from the early Miocene detachment faulting.

Notes: The High Himalayan Crystalline Sequence in north-central Nepal is a 15-km-thick pile of metasediments that is bound by the Main Central Thrust to the south and a normal fault to the north. The Langtang section through the metasediments shows an apparent inversion of metamorphic isograds with high-P, kyanite-grade rocks exposed beneath low-P, sillimanite-grade rocks. Textural evidence confirms that the observed inversion is a result of a polyphase metamorphic history and phase equilibria studies indicate that thermal decoupling has occurred within a mechanically coherent section of crust. Rocks now exposed at the base of the High Himalayan thrust sheet underwent Barrovian regional metamorphism (M1) prior to 34 Ma in the early stages of the Himalayan orogeny, recording metamorphic conditions of T= 710 ± 30° C, P= 9 ± 1 kbar. After the activation of the Main Central Thrust, which emplaced these metapelites southwards onto the lower grade Lesser Himalayan formations, the upper part of the thrust sheet was overprinted by a second heating event (M2), resulting in sillimanite-grade metamorphism and anatexis of metapelites at T= 760 ± 30° C, P= 5.8 ± 0.4 kbar between 17 and 20 Ma. Crustally derived, leucogranite magmas have been emplaced into low-grade Tethyan sediments on the hangingwall of the normal fault that bounds the northern limit of the metapelitic sequence.The cause of the selective heating of the upper section of the metasediments during M2 cannot be reconciled with either post-thrusting thermal relaxation or advection models. The cause of M2 remains problematical but it is suggested that heat focusing has occurred at the top of the High Himalayan Crystalline Sequence as a result of movement on the normal fault blanketing metapelites of high heat productivity with low-grade sediments of low thermal conductivity. This model implies that the normal fault was active before M2, consistent with decompression textures that formed during, or shortly after, sillimanite-grade metamorphism.

Notes: The two major Early to Middle Palaeozoic tectonic/metamorphic events in the northern Appalachians were the Taconian (Middle to Late Ordovician) in central to western areas and the Acadian (Late Silurian to early Middle Devonian) in eastern to west-central areas. This paper presents a model for the Acadian orogenic event which separates the Acadian metamorphic realm into eastern and western belts based on distinctively different styles. We propose that the Acadian metamorphism in the east was the delayed consequence of Taconian back-arc lithospheric modification. East of the Taconian island arc, thick accumulations of Late Ordovician and Silurian sediments, coupled with plutons rising along a magmatic arc, produced crustal thermal conditions appropriate for anomalously high-T, low-P metamorphism accompanied by major crustal anatexis. In this zone, upward melt migration was coupled with subsequent E-W crustal shortening (possibly due to outboard collision with the Avalon terrane) to produce mechanical conditions that favoured formation of fold and thrust nappes and resultant tectonic thickening to the west (and probably to the east as well).The basis for the distinction between the Eastern and Western Acadian events lies in the contrasting styles of metamorphism accompanying each. Evidence for contrasting metamorphic styles consists of (1) estimated metamorphic field gradients (MFGs) based on thermobarometric studies, and (2) petrological evidence for contrasting P–T trajectories. West of the Acadian metamorphic front, the Taconian zone has an MFG in which peak temperatures of 400-600° C were reached at pressures of about 4–6 kbar, with both P and T increasing to the east. Near its western edge, the Western Acadian metamorphic overprint has a similar MFG to the Taconian, and is mainly discriminated by 40Ar/39Ar dating and microtextural evidence. East of this narrow zone, the Western Acadian overprint is characterized by progressively higher temperatures (600–725° C) and pressures (6.5–10 kbar, or more) to the east, yielding an overall MFG that lies along, or slightly above, the kyanite–sillimanite boundary on a P–T diagram. There is little or no plutonism accompanying Western Acadian metamorphism.In contrast, thermobarometry in the Eastern Acadian, east of the Bronson Hill Belt, yields high-T, intermediate-P conditions for the highest grade rocks known in New England: T= 650–750° C, P= 4.5–6.5 kbar for granulite facies assemblages which apparently formed along an ‘anticlockwise’P–T path. The Bronson Hill Belt lies geographically between the Eastern and Western Acadian zones and shows transitional petrological behaviour: anomalously high temperatures at intermediate pressures, but a ‘clockwise’ path with decompression cooling.Radiometric dating indicates peak Taconian conditions may have been achieved as early as 475 Ma in the Taconian hinterland and as late as 445 Ma in the Taconian foreland (including the Taconic allochthons). Eastern Acadian magmatism may have started as early as 425 Ma, and most nappe-stage deformation and metamorphism in the Eastern Acadian zone appears to have ended by about 410 Ma. Tectonic thickening in the Western Acadian (including the western counterparts of the nappe-stage deformation documented in the Eastern Acadian) must pre-date attainment of peak metamorphic conditions dated at 395–385 Ma. Dome-stage deformation clearly post-dates peak metamorphism and deforms metamorphic isograds. The end of Western Acadian deformation is well constrained by 370-375 Ma radiometric ages of late pegmatites and granitoids which cross-cut all structures.

Notes: A suite of migmatites in uppermost amphibolite facies schists of the Koettlitz Group exposed in the Taylor Valley, Antarctica, provides direct evidence of the behaviour of partially molten rock during syn-anatectic deformation. The geometry of the migmatites is directly related to their position relative to the hinge of a kilometre-scale antiform. Migmatitic rocks on the fold limbs are characterized by extensional shears and fractures, filled with leucosome material, that intersect the pervasive foliation and millimetre-thick stromatic leucosomes. Vein- and dyke-like leucosomes become more common and thicker from the limb to the hinge region of the antiform. Rocks characterized by high leucosome-to-rock ratios near the antiform hinge are xenolithic in appearance. Major parasitic folds within the hinge contain leucogranite ‘microplutons’ up to 50 m across beneath refractory ‘cap-rock’ layers.Angular boudinage structures in schists surrounded by leucosomes indicate a relatively low yield strength in the leucosome, which is compatible with a molten rather than solid leucosome. Leucogranite-bearing extensional shears and fractures indicate that repeated extensional fracturing and shearing promoted by high fluid (melt) pressure is an important mechanism of melt segregation. Dilation in the hinges of developing folds aids the migration of melt into fold hinges and the development of 10–50-m-wide ‘microplutons’ of xenolith-rich leucogranite.Lack of vapour-absent melting and consequent low melt-to-rock ratios allowed the Koettlitz Group to maintain its structural coherency on a kilometre scale. Consequently, leucosome ‘microplutons’ did not exceed 50 m in width, and therefore observed leucosomes have not contributed to the development of adjacent plutonic-scale granitoids.

Notes: Systematic mapping of a transect along the well-exposed shores of Georgian Bay, Ontario, combined with the preliminary results of structural analysis, geochronology and metamorphic petrology, places some constraints on the geological setting of high-grade metamorphism in this part of the Central Gneiss Belt. Correlations within and between map units (gneiss associations) have allowed us to recognize five tectonic units that differ in various aspects of their lithology, metamorphic and plutonic history, and structural style. The lowest unit, which forms the footwall to a regional decollement, locally preserves relic pre-Grenvillian granulite facies assemblages reworked under amphibolite facies conditions during the Grenvillian orogeny. Tectonic units above the decollement apparently lack the early granulite facies metamorphism; out-of-sequence thrusting in the south produced a duplex-like structure. Two distinct stages of Grenvillian metamorphism are apparent. The earlier stage (c. 1160–1120 Ma) produced granulite facies assemblages in the Parry Sound domain and upper amphibolite facies assemblages in the Parry Island thrust sheet. The later stage (c. 1040–1020 Ma) involved widespread, dominantly upper amphibolite facies metamorphism within and beneath the duplex. Deformation and metamorphism recently reported from south and east of the Parry Sound domain at c. 1100–1040 Ma have not yet been documented along the Georgian Bay transect. The data suggest that early convergence was followed by a period of crustal thickening in the orogenic core south-east of the transect area, with further advance to the north-west during and after the waning stages of this deformation.

Notes: The Main Zone of the Hidaka metamorphic belt is an imbricate stack of crustal material derived from an island arc in which a sequence of units with increasing metamorphic grade from low to high structural levels is exposed. The basal part of the metamorphic sequence underwent granulite facies metamorphism with peak P–T conditions of 7kbar, 870°C. In this zone pelitic granulite includes leucosomes which consist mainly of orthopyroxene-plagioclase-quartz.To test whether the leucosome was derived by partial melting of the surrounding pelite, melting experiments of the pelitic granulite were carried out for water-saturated and dry systems at 7 kbar and 850°C. The chemical composition of the leucosome produced during these runs shows a peraluminous S-type tonalitic affinity and is located very close to the tie-line between the average melts produced in water-saturated systems and the average composition of the residual orthopyroxene + plagioclase. This therefore suggests that the lecosome in pelitic granulite was formed by incipient anatexis at close to the highest P–T condition of the Main Zone.The age of the crustal anatexis is determined by the Rb-Sr whole rock isochron method for garnet-cordierite-biotite gneiss (host rock), garnet-orthopyroxene-cordierite gneiss (restite) and S-type tonalite (melt). This gives an age of 56.0 Ma with an initial 87Sr/86Sr ratio of 0.705711. The S-type tonalite magmas that form large intrusive masses in the Main Zone were probably generated by crustal anatexis in deeper parts of the crust at the same time (late Palaeocene).

Notes: Caledonian eclogite facies shear zones developed from Grenvillian garnet granulite facies anorthosites and gabbros in the Bergen Arcs of western Norway allow direct investigation of the relations between macroscopic structures and crystallographic preferred orientation (CPO) in lower continental crust. Field relations on the island of Holsnøy show that the eclogites formed locally from granulite facies rocks by progressive development of: (1) eclogite adjacent to fractures; (2) eclogite in discrete shear zones (〉 2 m thick); (3) eclogite breccia consisting of 〉80% well-foliated eclogite that wraps around rotated granulite blocks; and (4) anastomosing, subparallel, eclogite facies shear zones 30–100 m thick continuous over distances 〉 1 km within the granulite terrane. These shear zones deformed under eclogite facies conditions at an estimated temperature of 670 ± 50°C and a minimum pressure of 1460 MPa, which corresponds to depths of 〉55 km in the continental crust. Detailed investigation of the major shear zones shows the development of a strong foliation defined by the shape preferred orientation of omphacite and by alternating segregations of omphacite/garnet-rich and kyanite/zoisite-rich layers. A consistent lineation throughout the shear zones is defined by elongate aggregates of garnet and omphacite. The CPO of omphacite, determined from five-axis universal stage measurements, shows a strong b-axis maximum normal to foliation, and a c-axis girdle within the foliation plane with weak maxima parallel to the lineation direction. These patterns are consistent with deformation of omphacite by slip parallel to [001] and suggest glide along (010). The lineation and CPO data reveal a consistent sense of shear zone movement, although the displacement was small. Localized faulting of high-grade rocks accompanied by fluid infiltration can be an important mode of failure in the lower continental crust. Field relations show that granulite facies rocks can exist in a metastable state under eclogite facies conditions and imply that the lower crust can host differing metamorphic facies at the same depth. Deformation of granulite and partial conversion to eclogite, such as is exposed on Holsnøy Island, may be an orogenic-scale process in the lowermost crust of collisional orogens.

Notes: Mineral composition and quantitative thermobarometric studies indicate that the Teslin-Taylor Mountain and Nisutlin terranes within the Teslin suture zone (TSZ), Yukon, record widespread high-P/T metamorphic conditions consistent with subduction zone dynamothermal metamorphism. The highest P–T conditions (575–750° C and 9–17 kbar) are preserved in tectonites formed during normal dip-slip ductile shear. Dextral strike-slip tectonites record lower P–T conditions (400–550° C and 5–8 kbar), and tectonites which show reverse shear have peak temperatures of c. 420° C and a minimum peak pressure of 3 kbar. Dynamothermal metamorphism took place in a west-dipping B-type subduction zone outboard of western North America in Permo-Triassic time. TSZ tectonites were underplated against the hangingwall plate of the subduction zone. Following subduction of the ocean basin which separated North America from the hangingwall plate, TSZ tectonites were overthrust eastward as a coherent structural package as a result of A-type subduction of Cassiar strata in early Jurassic time.(Par)autochthonous Cassiar tectonites, which comprised the leading edge of the western North American margin, record prograde moderate-P, high-T metamorphism (550–750° C and 7–13 kbar) synchronous with top-to-the-east ductile shear. Metamorphism occurred as a result of subduction of the North American margin into the TSZ subduction zone in early Jurassic time. Following metamorphism Cassiar tectonites cooled slowly from 500 to 300° C during the period middle Jurassic to middle Cretaceous.TSZ and Cassiar tectonites were deformed during changing P–T conditions. Data from each of these tectonite packages indicate that grain-scale strain partitioning may have allowed local recrystallization of individual minerals by the addition of mechanical energy. The composition of the new grains reflects the P–T conditions under which that particular grain was deformed.

Notes: The Al–Mg-rich granulites from the In Ouzzal craton, Algeria, show a great diversity of mineral reactions which correspond to continuous equilibria as predicted by phase relationships in the FeO–MgO–Al2O3–SiO2 system. The sequence of mineral reactions can be subdivided into three distinct stages: (1) a high-P stage characterized by the growth of coarse mineral assemblages involving sapphirine and the disappearance of early corundum and spinel-bearing assemblages; (2) a high-T stage characterized by the development of Sa–Qz-bearing assemblages; and (3) a later stage, in which garnet-bearing assemblages are replaced by more or less fine symplectites involving cordierite.During the course of early mineral reactions, the distribution coefficient, Kd, between the various ferromagnesian phases decreased significantly whereas Al2O3 in pyroxene increased concomitantly. These observations, when combined with topological constraints, clearly indicate that the high-P stage 1 was accompanied by a significant rise in temperature (estimated at 150 ± 50° C) under near isobaric conditions, in agreement with the reaction textures. By stage 2, pressure and temperature were extreme as evidenced by the low Kd value between orthopyroxene and garnet (Kd= 2.06–1.99), the high alumina content in pyroxene (up to 11.8%) and the high magnesium content in garnet [100 Mg/(Mg + Fe) = 60.6]. Mineral thermometry based on Fe–Mg exchange between garnet and pyroxene and on Al-solubility in pyroxene gives temperatures close to 970 ± 70° C at 10 ± 1.5 kbar. These results are in agreement with the development of Sa–Qz assemblages on a local scale.Late mineral reactions have been produced during a decompression stage from about 9 to 6 kbar. Except for local re-equilibration of Mg and Fe at grain boundaries, there is no evidence for further reactions below 700° C.We interpreted the whole set of mineral reactions as due to changes in pressure and temperature during a tectonic episode located at c. 2 Ga. Because of the lack of evidence for further uplift after the thermal relaxation which occurred at c. 6 kbar, it is possible however that the exhumation of this granulitic terrane occurred in a later tectonic event unrelated to its formation.

Notes: Investigation of microstructural relationships in major movement zones in metamorphic rocks, where the sense of displacement is known from regional geological relationships, indicates numerous problems with current concepts of shear-sense criteria and their application. The direction of apparent shearing commonly conflicts from one criterion to another (e.g. from the symmetry of quartz c-axis orientation diagrams to the asymmetry of extensional crenulation cleavages). This implies that interpretations of shear sense along foliations from some mesoscale and microscale criteria have been erroneous.A new approach to interpreting shear sense, involving the use of strain fields, resolves conflicts in mesoscopic and microscopic criteria and provides a method for determining coherent shear-sense histories extending back before the last shearing event for ‘any foliated metamorphic rock’. It also provides a powerful tool for determining the structural/metamorphic path that a rock has followed within an orogen. For determination of the shear sense on the last foliation developed in a rock, this approach uses geometries developed around competent heterogeneities such as quartz pebbles, pegmatite pods, veins, porphyroclasts, porphyroblasts and breccia clasts. A shear-sense history is derived by applying this approach to earlier foliations preserved within the heterogeneities and their strain shadows.

Notes: Graphitization and coarsening of organic material in carbonate-bearing metasedimentary rocks is accompanied by carbon isotope exchange which is the basis of a refractory, pressure-independent geothermometer. Comparison of observed isotopic fractionations between calcite and graphite (δ13CCal–Gr) with independent petrological thermometers provides the following empirical calibration over the range 400–800°C: δ13CCal–Gr= 5.81 times 106×T–2(K) - 2.61. This system has its greatest potential in marbles where calcite + graphite is a common assemblage and other geothermometers are often unavailable. The temperature dependency of this empirical calibration differs from theoretical calibrations; reasons for this are unclear but the new empirical calibration yields temperature estimates in better agreement with independent thermometry from several terranes and is preferred for geological applications.Both calcite-graphite isotopic thermometry and calcite-dolomite solvus thermometry are applied to marble adjacent to the Tudor gabbro in the Grenville Province of Ontario, Canada. The marble has undergone two metamorphic episodes, early contact metamorphism and later regional metamorphism. Values of δ13CCal–Gr decrease regularly from c. 8‰ in samples over 2 km from the pluton to values of 3–4‰ within 200 m of the contact. These samples appear to preserve fractionations from the early thermal aureole with the empirical geothermometer, and indicate temperatures of 450–500° C away from the intrusion and 700–750°C near the gabbro. This thermal profile around the gabbro is consistent with conductive heat flow models. In contrast, the distribution of Mg between calcite and dolomite has been completely reset during later regional metamorphism and yields uniform temperatures of c. 500°C, even at the contact.Graphite textures are important for interpreting the results of the calcite–graphite thermometer. Coarsening of graphite approaching the Tudor gabbro correlates with the decrease in isotopic fractionations and provides textural evidence that graphite crystallization took place at the time of intrusion. In contrast to isotopic exchange during prograde metamorphism, which is facilitated by graphitization, retrogressive carbon isotopic exchange appears to require recrystallization of graphite which is sluggish and easily recognized texturally. Resistance of the calcite–graphite system to resetting permits thermometry in polymetamorphic settings to see through later events that have disturbed other systems.

Notes: In order to illustrate different applications of the amphibole-albite-chlorite-epidote-quartz geothermobarometer, pressure-temperature-time (P–T–t) ± space (P–T–t–s) ± deformation (P–T–t–d) paths have been established from literature data. They are discussed as a function of the chemical, equilibrium and microstructural data available in each case, and compared with the conclusions already established by other methods. It is clear that it is necessary to know the relative chronology of the events (directions of zoning of minerals in successive microstructural positions) to establish precise P–T paths; this enables reconstruction of complex geodynamic histories. From this point of view, it is necessary to analyse the maximum possible number of minerals in a few well-chosen metabasic rocks showing different generations of blastesis. The rocks should belong to different tectonic units to obtain the best overall picture of a metamorphic complex.

Notes: In a number of recent papers, the theory has been postulated that porphyroblasts as a rule do not rotate with respect to geographical coordinates, and can be used to determine the original orientation of older foliations. Complex inclusion patterns in spiral garnets have even been used to advocate a new model of orogenesis, involving several alternating phases of horizontal shortening and extension. Critical assessment of the assumptions and data used to support the theory of irrotational porphyroblasts reveals numerous flaws. Millipede structures, used as proof for flow partitioning, can also form by other flow geometries. Evidence quoted to support irrotational behaviour of porphyroblasts is unsound. Porphyroblasts do occur in sets with a preferred orientation of the internal foliation trace, but these cannot be shown to represent original orientations. Microstructures which resemble truncation planes in spiral garnets are used as evidence that these structures developed by several phases of deformation and as proof for periodic extension and horizontal shortening in orogenesis. They can, however, also be explained by intermittent growth of a rotating porphyroblast during a single phase of deformation. Finally, porphyroblast sets in which orientation is a function of aspect ratio indicate that porphyroblast rotation with respect to kinematic axes does occur in at least some situations.

Notes: In the Hazeldene area, situated in the Mount Isa Inlier, Queensland, the metamorphic grade changes from chlorite zone, through biotite and cordierite zones, to sillimanite/K-feldspar zone.Microstructural studies of rocks near the sillimanite isograd demonstrate that cordierite grew early during the development of a steep foliation (S2), was replaced by biotite, andalusite and sillimanite at the metamorphic peak late in S2, and in turn by kyanite + chlorite adjacent to localized small post-D2 shear zones. Although the anticlockwise P–T–t path is well defined, the precise P–T conditions are uncertain because of problems with experimental and thermodynamic data. The best estimate for the metamorphic peak for rocks close to the sillimanite isograd is around 600° C at 4 kbar.The metamorphism has been dated at 1544 Ma, and was synchronous with a major crustal shortening event. Because proposed extensional events occurred more than 60 Ma earlier, their contribution to the peak metamorphic thermal perturbation would have been insignificant. The syn-metamorphic Mica Creek Pegmatites, the abundance of high heat-producing elements in the nearby pre-D2 Sybella Granite, and advective heat by fluids which caused considerable metasomatism in the Hazeldene area, may have each contributed to the thermal budget. However, the metamorphic thermal gradient may be 80°C km-1 or higher, strongly suggesting a local magmatic control. As none are known in the area, such syn-metamorphic plutons would have to lie beneath the exposed high-grade rocks.

Notes: Charnockitic alteration (arrested orthopyroxene formation in biotite- and amphibole-bearing rocks) occurs in high-grade terranes of all ages. Three criteria are used to show that this alteration was produced in many locations by a migrating fluid phase: (i) diffuseness of the alteration—the alteration zones are often quite unlike discrete migmatitic veins; (ii) relation to deformation—most occurrences show alteration closely associated with warping of foliation or dilation cracks; (iii) open-system alteration—whilst some occurrences represent nearly isochemical alteration, slight changes in bulk composition, often loss of mafic constituents and gain of Na and Si, are evident in detailed mass-balance analysis. Y and sometimes Rb are characteristically depleted. Partial melting sometimes accompanied volatile infiltration, as evidenced by more discrete veins and euhedral orthopyroxene. It is quite unlikely, however, that open-system alteration was produced by escape of viscous quartzo-feldspathic melts. Pervasive migration of low-T lamprophyric (mafic–alkaline, CO2-charged) interstitial liquids is a possibility by virtue of their extreme fluidity, but CO2 infiltration was needed to generate these liquids. Vapour-deficient dehydration melting is another feasible mechanism of orthopyroxene formation which may have operated in conjunction with CO2 infiltration.Characteristic development of charnockitic alteration in some prograde amphibolite to granulite facies transitions, as in the Dharwar Craton of South India, suggests that the alteration is a fundamental feature of the granulite facies metamorphism, implying active and causal participation of migrating fluids. In other high-grade terranes like the Adirondack Mountains of New York, this kind of alteration is rare, and fluid action does not seem to have been important in the metamorphism.A vapour phase participating in charnockitic metamorphism was necessarily one of relatively low H2O, therefore presumably rich in CO2. Consideration of possible large CO2 sources leads to the conclusion that emanations from volatile-rich basalts emplaced in the lower crust are the most probable source of charnockitizing fluids. The ultimate source would therefore be enriched subcontinental lithosphere or asthenosphere. The Rb-depleted pyroxene gneiss (charnockitic) terranes may be characteristic of zones of large-scale transcurrent or oblique-motion faults which tap such great depths.

Notes: Quartz veins are developed in a wide range of metasediment types in the upper amphibolite facies rocks of Connemara, and attest to considerable migration of silica. Contrary to common assumptions, there is clear evidence that these veins do not primarily result from movement of fluid to regions of lower P–T down the regional geothermal gradient. Under amphibolite facies conditions, a dilute chloride fluid moving down temperature has the potential to alter 60g of plagioclase to muscovite for each gram of vein quartz precipitated, while cooling over the temperature interval from 650 to 500° C. The absence of significant metasomatic effects in the vein walls effectively precludes a simple origin from such through-flowing, externally derived fluids. The oxygen isotopic composition of matrix quartz shows considerable differences between different rock types (quartzite, pelite and marble), with a range of δ18OSMOW from c.+ 11.5% (quartzite) to + 18.5% (marble). In each rock type, vein quartz compositions closely match those of the matrix quartz. These results demonstrate the importance of local segregation processes in the formation of veins, and suggest that fluid convection cells were not developed during metamorphism on a scale larger than the individual sedimentary formations, if at all.Both oxygen isotope data and the absence of metasomatism indicate that veins form primarily by segregation of quartz from the host lithologies, with only a relatively minor component of through flow of externally derived fluid. Veins are clearly not the major pathways of metamorphic dewatering.It is proposed that abundant veins in the predominantly pelitic Ballynakill Formation formed during peak metamorphic D3 folding because the formation was embrittled by high fluid pressures but was capped by impermeable marble. Hence the pelitic formation fractured repeatedly and the pore fluid drained through the fractures to form veins, while irreversible loss through the rest of the succession was a much less important process.In the central mountains of Connemara, rather pure, unreactive quartzites are cut by widely spaced, laterally extensive quartz veins that are axial planar to D3 folds. These veins may mark pathways whereby metamorphic fluid made its way through the massive impermeable quartzite from lower parts of the nappe pile, but here too, oxygen isotope data indicate considerable segregation of locally derived quartz, reflecting the importance of pumping of fluid between wail rocks and fractures relative to the component of through flow.

Notes: Geothermometry and geobarometry of 10 garnet–oligoclase zone schists in the Franz Josef–Fox Glacier area, Southern Alps, New Zealand, give temperatures ranging from 415 to 625°C and pressures from 5.2 to 9.2 kbar, indicating a T–P array of about 50°C/kbar and inferred peak temperature conditions over a c. 15-km-thick section at depths between c. 20 and 34 km. The present-day distribution of the schist samples implies that only about one-third of the original crustal section is now exposed.The garnet–oligoclase zone schists represent the deeper part of a metamorphosed and deformed accretionary complex that was associated with late Palaeozoic–early Mesozoic subduction along the Gondwana continental margin. Partial uplift (c. 0.2 m/Ma) and erosion of the complex during Jurassic–Cretaceous times (Rangitata uplift) was synchronous with D2 deformation and recrystallization, as recorded by the P–T array. Cenozoic (Kaikoura) uplift and exhumation of the schist since c. 30 Ma to form the Southern Alps was associated with oblique-slip movement on the Alpine Fault. The present-day position and steep eastward dip of isograds and D2 structures suggest considerable clockwise rotation during uplift associated with ductile attenuation and tectonic thinning by over two-thirds of the original schist sequence, largely due to simple shear along schistosity planes. As the schist generally shows only incipient greenschist facies retrograde recrystallization, an apparently complete (although contracted) prograde mineral sequence has been preserved by rapid uplift (〉5 km/Ma) of hot rock and the effects of limited shear heating near the Alpine Fault.

Notes: The Smartville Complex is a late Jurassic, rifted volcanic arc in the northern Sierra Nevada, California. Near Auburn, California, it consists of a lower volcanic unit, dominated by basaltic flows, and an upper volcanic unit of andesitic volcaniclastic rocks, both of which have been intruded by dykes and irregular bodies of diabase. These rocks contain relict igneous minerals, and the metamorphic minerals albite, chlorite, quartz, pumpellyite, prehnite, epidote, amphibole, titanite, garnet, biotite, K-feldspar, white mica, calcite, and sulphide and oxide minerals.Prehnite–pumpellyite (PrP), prehnite–actinolite (PrA), and greenschist (GS) zones have been identified. The pumpellyite-out isograd separates the PrP and PrA zones, and the prehnite-out isograd separates the PrA and GS zones. The minerals Ab + Qtz + Mt + Tn are common to most assemblages in all three zones. The MgO/(MgO + FeO) ratio of the effective bulk composition has an important and systematic effect on the observed mineral assemblages in the PrP zone. Prehnite-bearing assemblages contain the additional minerals, Pmp + Amp + Ep + Chl in MgO-rich rocks, and either Pmp + Ep + Chl or Amp + Ep + Chl in less magnesian rocks. Subcalcic to calcic amphibole is common in the PrP zone. The mineral assemblage Prh + Act + Ep + Chl, without Pmp, characterizes the PrA zone, and the mineral assemblage Act + Ep + Chl, without Prh or Pmp, characterizes the GS zone. The disappearance of pumpellyite and prehnite occurred by continuous reactions.The sequence of mineral assemblages was produced by burial metamorphism at P–T conditions of 300° 50°C at approximately 2.5 ± 0.5 kbar. During metamorphism, the composition of the fluid phase was nearly 100% H2O and the oxygen fugacity was between the hematite–magnetite and quartz–fayalite–magnetite buffers.

Notes: Garnet-bearing mineral assemblages are commonly observed in pelitic schists regionally metamorphosed to upper greenschist and amphibolite facies conditions. Modelling of thermodynamic data for minerals in the system Na2O–K2O–FeO–MgO–Al2O3–SiO2–H2O, however, predicts that garnet should be observed only in rocks of a narrow range of very high Fe/Mg bulk compositions. Traditionally, the nearly ubiquitous presence of garnet in medium- to high-grade pelitic schists is attributed qualitatively to the stabilizing effect of MnO, based on the observed strong partitioning of MnO into garnet relative to other minerals. In order to quantify the dependence of garnet stability on whole-rock MnO content, we have calculated mineral stabilities for pelitic rocks in the system MnO–Na2O–K2O–FeO–MgO–Al2O3–SiO2–H2O for a moderate range of MnO contents from a set of non-linear equations that specify mass balance and chemical equilibrium among minerals and fluid. The model pelitic system includes quartz, muscovite. albite, pyrophyllite, chlorite, chloritoid, biotite, garnet, staurolite, cordierite, andalusite, kyanite. sillimanite, K-feldspar and H2O fluid. In the MnO-free system, garnet is restricted to high Fe/Mg bulk compositions, and commonly observed mineral assemblages such as garnet–chlorite and garnet–kyanite are not predicted at any pressure and temperature. In bulk compositions with XMn= Mn/(Fe + Mg + Mn) 〉 0.01, however, the predicted garnet-bearing mineral assemblages are the same as the sequence of prograde mineral assemblages typically observed in regional metamorphic terranes. Temperatures predicted for the first appearance of garnet in model pelitic schist are also strongly dependent on whole-rock MnO content. The small MnO contents of normal pelitic schists (XMn= 0.01–0.04) are both sufficient and necessary to account for the observed stability of garnet.

Notes: The Velay dome (French Massif Central) offers a quasi-continuous section across an anatectic domain comprising low- to high-grade schists, gneisses and granites. Two main tectonometamorphic events, and their related generation of granitic material, were recognized in addition to a major Barrrovian tangential event (D2) attributed to intracontinental collision tectonics: (i) a medium- to low-P, high-T event (D3) which gave rise to migmatites and syntectonic monzonitic granites and granodiorites, and (ii) a widespread melting event (D4) which led to the generation of migmatities, the Velay granite and post-anatectic granites.Thermobarometry on samples collected from both the metamorphic envelope and the granitic core distinguishes two distinct geotherms: (i) a first, associated with the D3 event, characterized by P 〉 5 kbar, T≤ 750° C and water-present melting (biotite remains stable) which led to large-scale migmatization but minor amount of granites; (ii) a second, associated with the D4 event and characterized by vapour-absent melting (P= 4–5 kbar, T= 760–850° C) which gave rise to the Velay granites and late-migmatitic granites. The temperature increase during the D4 event is attributed to the intrusion of hot mafic magmas within the crust.The time-integrated features of the different granitic rocks in the Velay dome can be directly related to aH2O in the source region and illustrate the progressive dehydration of a middle to lower crustal segment over 60 Ma.

Notes: Metabasaltic rocks in the Klamath Mountains of California with ‘komatiitic’ major element concentrations were investigated in order to elucidate the origin of the magnesian signature. Trace-element concentrations preserve relict igneous trends and suggest that the rocks are not komatitic basalts, but immature arc rocks and within-plate alkalic lavas. Correlation of ‘excess’ MgO with the volume per cent hornblende (±clinopyroxene) suggests that the presence of cumulus phases contributes to the MgO-rich compositions. Early submarine alteration produced regional δ18O values of +10±1.5%° and shifts in Al2O3, Na2O, and K2O concentrations. Regional metamorphic grade in the study area varies from biotite-zone greenschist facies (350–550°C, c. 3 kbar) southward to prehnite–actinolite facies (200–400°C, ≤3 kbar), but little isotopic or elemental change occurred during the regional recrystallization. The greenschist facies assemblage is actinolitic hornblende + phengite + epidote + sodic plagioclase + microcline + chlorite + titanite + hematite + quartz in Ti-poor metabasaltic rocks; in addition to these phases biotite is present in Ti-rich analogues. Lower grade greenstones contain prehnite and more nearly stoichiometric actinolite. The moderate to low pressures of regional metamorphism are compatible with P–T conditions in a magmatic arc. Later contact metamorphism at 2–2.9±0.5 kbar and at peak temperatures approaching 600° C around the English Peak and Russian Peak granodiorites produced 3–4–km-wide aureoles typified by gradual, systematic increases in the pargasite content of amphibole, muscovite content of potassic white mica, and anorthite content of plagioclase compositions. Metasomatism during contact metamorphism produced further increases in bulk-rock δ18OSMOW of as much as +6%°. Thus, the unusually MgO-rich nature of the Sawyers Bar rocks may be attributed at least partly to metasomatism and the presence of magnesian cumulus phases.

Notes: Because many durable goods industries are also industries with significant innovative activity, we analyze the relationship between an oligopolistic firm's choice of product durability and cost-reducing innovation in rental and sales markets. We demonstrate the firm's durability may be greater than, equal to, or less than a social planner's, depending upon innovation's impact on the marginal cost of durability. We also show that the firm's innovation level can be maximized for moderate levels of concentration if the output is durable. This provides theoretical support for the empirical observation that innovation is often maximized in markets of moderate concentration.

Notes: In this paper we attempt to disentangle the effects of deregulation on rail costs from those directly attributable to mergers. We estimate that cost reductions obtained from mergers ranged from a high of 33% for the Burlington Northern to a low of a 3% cost increase for the CSX. However, firms not engaged in significant merger activities experienced similar cost differentials indicating that consolidation was not a prerequisite for cost savings. We conclude that although mergers did confer some benefits on the participating firms, they were not a prerequisite for railroads being able to achieve substantial cost savings.

Notes: For a homogeneous product oligopoly market, possibilities for pure strategy Nash equilibria in prices are studied. Consumers, who each nonstrategically purchase one unit up to a common reservation price, are hypothesized to be more concerned with large price differences (and therefore buy from the cheapest firm) than slightly different prices. For the duopoly case, existence, uniqueness, and characterization results are provided. Linear examples are given with 2 and n firms.

Notes: This paper analyzes the ongoing transformation of the soft drink distribution of Coca-Cola and Pepsi-Cola from systems of independent bottlers to captive bottling subsidiaries, A transaction cost-based theory is developed to explain this restructuring. It is postulated that changes in the external environment and the resulting changes in the strategies of Coca-Cola and Pepsi-Cola raised the costs of transacting between them and their independent bottlers. Two types of empirical tests are presented. One exploits the difference in the distribution of Coca-Cola and Pepsi-Cola in the fountain channel. The other consists of statistical analyses of the competitive effects of the move toward captive distribution. Both types of tests support the basic hypothesis.

Notes: Abstract In granulite facies metapelitic rocks in the Musgrave Complex, central Australia, reaction between S1 garnet and sillimanite involves the development in S2 of both garnet + cordierite + hercynitic spinel + biotite and hercynitic spinel + cordierite + sillimanite + biotite. The S2 assemblages occur either in coronas and symplectites, mainly around garnet, or, in rocks in which S2 is more strongly developed, as recrystallized assemblages. Ignoring the presence of biotite and ilmenite, the mineral textures can be accounted for qualitatively by a consideration of the model system FeO-MgO-Al2O3-SiO2 (FMAS); the textural relationships accord with decompression accompanying the change from S1 to S2. However, since biotite and ilmenite are involved in the assemblages, the parageneses are better accounted for in terms of equilibria in the expanded model system K2O-FeO-MgO-Al2O3-SiO2-H2-TiO2-Fe2O3 (KFMASHTO), i.e. AFM + TiO2+ Fe2O3. The coronas reflect the tectonic unroofing of at least part of the Musgrave Complex from peak S1 conditions of about 8 kbar to S2 conditions of about 4 kbar.

Notes: Abstract During the Eocene-Oligocene, the Indian plate collided with the Kohistan arc along the Main Mantle Thrust (MMT) zone. The structure of the Lower Swat rock sequence, on the Indian plate directly south of the MMT, is a dome with a basement of granitic gneiss and quartz-rich schist unconformably overlain by amphibolitic and calcareous schist. The earliest superposed small-scale folds (F1 & F2) represent a progressive F1/F2 deformation that is associated with a single set of WSW-vergent large-scale folds (termed F2). These folds are inferred to have developed during oblique, WSW-directed overthrusting of the MMT suture complex onto the Lower Swat rock sequence. Metamorphism began during F1/F2 as indicated by an S1 foliation that developed during biotite-grade metamorphism. S1 is preserved as a relict texture in porphyroblasts that grew during a subsequent interkinematic phase during garnet- and higher grade metamorphism. The dominant, regional foliation (S2) developed following the interkinematic phase. S2 is associated with transposition of S1 and rotation or dismemberment of porphyroblasts. Annealing recrystallization followed S2 and continued during F3 thereby destroying or masking possible pre-existing stretching fabrics. Superposed F3 folds are upright and open with N-S axial trends. They may correlate with early doming of the Lower Swat rock sequence and with strike-slip displacement in the northern part of the MMT zone, north of the Lower Swat area. F3 was followed by retrograde metamorphism and development of E-W-trending, S-vergent F4 folds. F4 may be associated with a final phase of southward directed thrusting and inactivity in the MMT zone. Correlation of published 40Ar/39Ar ages with the metamorphic fabrics suggests that F1/F2 and F3 occurred in the Eocene, and that F4 developed in the Oligocene. F4 is the earliest indication of southward verging structures on this part of the Indian plate.

Notes: Granulites exposed in the Reinbolt Hills, East Antarctica, are part of the extensive Late Proterozoic granulite complex of East Antarctica, which includes the Rauer Group to the east and the northern Prince Charles Mountains to the west. The deformation history includes three pervasive deformation phases. No chemical or mineralogical distinction between these phases has been detected and this is interpreted to be the result of complete re-equilibration at the end of the third deformation phase. Two late deformation phases post-date the metamorphism and record a medium-temperature cooling path. A short segment of the P–T path of these rocks was inferred from mineral reactions that occurred during these late deformation phases. The path passes from 800°C, 7 kbar to 690°C, 5 kbar, indicating strong decompression, which is typical of a thrust-dominated crustal thickening followed by rapid erosion or extensional collapse.

Notes: Mafic granulite, garnet amphibolite and charnockite occur in the southwest Swedish part of the Baltic Shield. This part is generally considered to be the continuation of the Grenville collisional belt in Canada. The area with granulite facies rocks, the Southwest Swedish Granulite Region (SGR), is considerably larger than previously thought. The SGR is bounded to the east and west by two major tectonic zones. The first quantitative age data and P–T determinations for the high-grade metamorphism in the SGR are presented.Conventional geothermobarometry was applied to mafic granulites from five localities. The estimated P–T conditions for the peak of metamorphism range from 705°C and 8.1 kbar at Hallandsås in the south, to 770°C and 10.5 kbar at Ullared in the north (medium- to high-P granulite facies conditions). Sm–Nd geochronology on minerals from the mafic granulites at Hallandsås and Ullared give late Sveconorwegian (Grenville) ages of 907 ± 12 and 916 ± 11 Ma for the high-grade metamorphism, which is considerably younger than previously thought.Our results stress the hitherto underestimated importance of the late Sveconorwegian high-grade metamorphism in the southwestern part of the Baltic Shield.

Notes: Dark hornblende + garnet-rich, quartz-absent metagabbro boudins from the Seguin subdomain, Ontario Grenville Province, are transected by anastomosing light-coloured veins rich in orthopyroxene, clinopyroxene, plagioclase and sometimes quartz. The veins vary in texture from fine-grained diffuse veins and patches that overprint the metagabbro, to coarse tonalitic leucosomes with sharp borders. The diffuse veins and patches are suggestive of channellized subsolidus dehydration of the metagabbro, while the tonalitic leucosomes are suggestive of local internally-derived anatexis. All vein types grade smoothly into each other, with the tonalitic leucosomes being the latest.Relative to the host metagabbro, the veins have higher Si, Na, Ba & Sr, lower Fe, Mg, Ca & Ti, and similar Al. The coarser veins are enriched in K. Plagioclase becomes steadily enriched in Na in the transition from host metagabbro (An47) to the veins (An35), and in the coarsest veins it is antiperthitic. Differences in composition of the other minerals between host metagabbro and vein are minor. Pressure–temperature estimates are scattered, but indicate a minimum temperature during vein formation of 700°C at about 8 kbar.Mass balance constraints indicate that the veins formed from the metagabbro in an open system. The transecting veins are interpreted to represent pathways of Si + Na + Ba + Sr ± K ± Al-enriched, low aH2O fluids that metasomatized the host metagabbro to form the anhydrous veins. An initial period of localized solid-state dehydration of the metagabbro, represented by the diffuse veins, was followed by a transition to localized anatexis, represented by the tonalitic leucosomes. The change to anatexis may have been due to the addition of K to the infiltrating fluid. The source and delivery mechanism of the fluids is unknown.

Notes: Eclogite facies mineral assemblages are variably preserved in mafic and ultramafic rocks within the Western Gneiss Region (WGR) of Norway. Mineralogical and microstructural data indicate that some Mg–Cr-rich, Alpine-type peridotites have had a complex metamorphic history. The metamorphic evolution of these rocks has been described in terms of a seven-stage evolutionary model; each stage is characterized by a specific mineral assemblage. Stages II and III both comprise garnet-bearing mineral assemblages. Garnet-bearing assemblages are also present in Fe–Ti-rich peridotites which commonly occur as layers in mafic complexes. Sm–Nd isotopic results are reported for mineral and whole rock samples from both of these types of peridotites and related rocks.The partitioning of Sm and Nd between coexisting garnet and clinopyroxene is used to assess chemical equilibrium. One sample of Mg–Cr-type peridotite shows non-disturbed partitioning of Sm and Nd between Stage II garnet and clinopyroxene pairs and yields a garnet–clinopyroxene–whole-rock date of 1703 ± 29 Ma (I= 0.51069, MSWD = 0.04). This is the best estimate for the age of the Stage II high-P assemblage. Other Stage II garnet–clinopyroxene pairs reflect later disturbance of the Sm–Nd system and yield dates in the range 1303 to 1040 Ma. These dates may not have any geological significance. Stage III garnet–clinopyroxene pairs typically have equilibrated Sm–Nd partitioning and two samples yield dates of 437 ± 58 and 511 ± 18 Ma. This suggests that equilibration of the Stage III high-P assemblage is related to the Caledonian orogeny and is more or less contemporaneous with high-P metamorphism of ‘country-rock’eclogites in the surrounding gneisses. The Sm–Nd mineral data for the Fe–Ti-rich garnet peridotites and for a superferrian eclogite, which occurs as a dyke within the Gurskebotn Mg–Cr-type peridotite, are consistent with a Palaeozoic high-P metamorphism.Finally a synoptic P–T–t path is proposed for the Mg–Cr-type peridotites which is consistent with the petrological and geochronological data.

Notes: Compositional zoning in biotite–garnet pairs in metamorphic rocks from eastern Finland has been studied. The Mg profiles in the garnet side of biotite–garnet crystal pairs have been interpreted by means of Lasaga's theory (geospeedometry). However, the binary interdiffusion equations are first reformulated by starting from a ternary system and using the lattice fixed frame of reference. This frame of reference gives the fluxes directly by means of the numbers of diffusing ions, which helps to check the 1-dimensionality of the analysis assumed in Lasaga's theory. It is also shown that the recently argued effect of the third cation Ca is negligible in our samples. We were able to investigate satisfactory profiles in three samples from different areas. The values for the cooling rate are a few degrees per million years if the diffusion data obtained by Freer are adopted. The cooling rates are in agreement with recent estimates based on the K–Ar ages on biotite in the same areas.

Notes: In the Caledonide orogen of northern Sweden, the Seve Nappe Complex is dominated by rift facies sedimentary and mafic rocks derived from the Late Proterozoic Baltoscandian miogeocline and offshore-continent–Iapetus transition. Metamorphic breaks and structural inversions characterize the nappe complex. Within the Sarek Mountains, the Sarektjåkkå Nappe is composed of c. 600-Ma-old dolerites with subordinate screens of sedimentary rocks. These lithological elements preserve parageneses which record contact metamorphism at shallow crustal levels. The Sarektjåkkå Nappe is situated between eclogite-bearing nappes (Mikka and Tsäkkok nappes) which underwent high-P metamorphism at c. 500 Ma during westward subduction of the Baltoscandian margin. 40Ar/39Ar mineral ages of c. 520–500 Ma are recorded by hornblende within variably foliated amphibolite derived from mafic dyke protoliths within the Sarektjåkkå Nappe. Plateau ages of 500 Ma are displayed by muscovite within the basal thrust of the nappe and are consistent with metamorphic evidence which indicates that the nappe escaped crustal depression as a result of detachment at an early stage of subduction. Cooling ages recorded by hornblende from variably retrogressed eclogites in the entire region are in the range of c. 510–490 Ma and suggest that imbrication of the subducting miogeocline was followed by differential exhumation of the various imbricate sheets. Hornblende cooling ages of 470–460 Ma are recorded from massive dyke protoliths within the Sarektjåkkå Nappe. These are similar to ages reported from the Seve Nappe Complex in the central Scandinavian Caledonides. Probably these date imbrication and uplift related to Early Ordovician arrival of outboard terranes (e.g. island-arc sequences represented by structurally lower horizons of the Köli Nappes).Metamorphic contrasts and the distinct grouping of mineral cooling ages suggest that the various Seve structural units are themselves internally imbricated, and were individually tectonically uplifted through argon closure temperatures during assembly of the Seve Nappe Complex. The cooling ages of 520–500 Ma recorded within Seve terranes and along terrane boundaries of the Sarek Mountains provide evidence of significant accretionary activity in the northern Scandinavian Caledonides in the Late Cambrian–Early Ordovician.

Notes: Abstract Aegirine–jadeite clinopyroxene (〉60 mol% jadeite) locally occurs within blueschists of the ‘Lower Allochthon’exposed in the Trás-os-Montes region of northern Portugal. Peak conditions attained during blueschist facies metamorphism are estimated to have been c. 420° C and 〉11 kbar. Porphyroblastic white mica (paragonite/phengite) within the blueschist assemblage records a 36Ar/40Ar versus 39Ar/40Ar isotope correlation age of 329.4 ± 1.6 Ma. In view of the relatively low-T nature of the metamorphism, the c. 330-Ma age is interpreted to date closely the high-P recrystallization. This tectonothermal activity is interpreted to have resulted from structural emplacement of a previously assembled crystalline nappe complex (‘Upper Allochthon/Ophiolite Nappe’) onto Iberian protoliths of the Lower Allochthon during terminal stages of the Hercynian orogeny.

Notes: Abstract Standard petrographic, microthermometric and Raman spectroscopic analyses of fluid inclusions from the metamorphosed massive sulphide deposits at Ducktown, Tennessee, indicate that fluids with a wide range of compositions in the C–O–H–N–S–salt system were involved in the syn- to post-metamorphic history of these deposits. Primary fluid inclusions from peak metamorphic clinopyroxene contain low-salinity, H2O–CH4 fluids and calcite, quartz and pyrrhotite daughter crystals. Many of these inclusions exhibit morphologies resembling those produced in laboratory experiments in which confining pressures significantly exceed the internal pressures of the inclusions. Secondary inclusions in metamorphic quartz from veins, pods, and host matrix record a complex uplift history involving a variety of fluids in the C–O–H–N–salt system. Early fluids were generated by local devolatilization reactions while later fluids were derived externally.Isochores calculated for secondary inclusions in addition to the chronology of trapping and morphological features of primary and secondary fluid inclusions suggest an uplift path which was concave toward the temperature axis over the P–T range 6–3 kbar and 550–225° C. Immiscible H2O–CH4–N2–NaCl fluids were trapped under lithostatic to hydrostatic pressure conditions at 3–0.5 kbar and 215 ± 20° C. Entrapment occurred during Alleghanian thrusting, and the fluids may have been derived by tectonically driven expulsion of pore fluids and thermal maturation of organic material in lower-plate sedimentary rocks which are thought to underlie the deposits. Episodic fracturing and concomitant pressure decreases in upper-plate rocks, which host the ore bodies, would have allowed these fluids to move upward and become immiscible. Post-Alleghanian uplift appears to have been temperature-convex.Uplift rates of 0.10–0.05 mm year−1 from middle Ordovician to middle Silurian – late Devonian, and 0.07–0.12 mm year−1 from middle Silurian – late Devonian to late Permian are suggested by our uplift path and available geochronological data.

Notes: Abstract Metapelites in the Altavista area, southwest Virginia Piedmont, USA, underwent allochemical hydrothermal retrograde metamorphism in synmetamorphic shear zones. The metapelites of the Evington Group were metamorphosed in a prograde sequence of chlorite, staurolite, and sillimanite zones. Garnet–biotite geothermometry and phase relations support eastward increasing metamorphic grade, ranging from 570° C in the staurolite zone to 650° C in the sillimanite zone at c. 5.8 kbar. Sillimanite-zone rocks later underwent progressive retrogression around shear zones which acted as fluid conduits. Retrograde assemblages are successively zoned around the shear zones with staurolite-, chloritoid- and kyanite-bearing assemblages. The shear zones commonly contain kyanite or tourmaline veins. Applicable phase equilibria indicate that retrogression occurred during isobaric cooling through c. 200–270° C. Rock compositional changes with retrogression occurred in steps: SiO2 was gained in the early stages of the retrogression but lost in the late stages; Al2O3, K2O, and H2O were increasingly gained through the sequence; CaO was increasingly lost. Addition of H2O and decreasing temperatures resulted in new ferromagnesian minerals (staurolite, chloritoid, chlorite) and changes in H2O, SiO2, Al2O3, K2O, and CaO contents produced muscovite and sodic plagioclase.Subsequent to prograde metamorphism, deeply derived fluids migrated upwards along shear zones, providing fluid and energy for the retrograde reactions. The sheared rocks underwent fluid infiltration with fluid fluxes of 1.8 × 107–4.3 × 107 cm3/cm2 corresponding to minimum estimated fluid-to-rock ratios of 7.5–21 as a function of position within the shear zone. Fluid flow was from high to low temperature early and low to high temperature later in the retrogression.

Notes: The Cordilleran orogen in south-eastern Alaska includes 14 distinct metamorphic belts that make up three major metamorphic complexes, from east to west: the Coast plutonic–metamorphic complex in the Coast Mountains; the Glacier Bay–Chichagof plutonic–metamorphic complex in the central part of the Alexander Archipelago; and the Chugach plutonic–metamorphic complex in the northern outer islands. Each of these complexes is related to a major subduction event. The metamorphic history of the Coast plutonic–metamorphic complex is lengthy and is related to the Late Cretaceous collision of the Alexander and Wrangellia terranes and the Gravina overlap assemblage to the west against the Stikine terrane to the east. The metamorphic history of the Glacier Bay–Chichagof plutonic–metamorphic complex is relatively simple and is related to the roots of a Late Jurassic to late Early Cretaceous island arc. The metamorphic history of the Chugach plutonic–metamorphic complex is complicated and developed during and after the Late Cretaceous collision of the Chugach terrane with the Wrangellia and Alexander terranes.The Coast plutonic–metamorphic complex records both dynamothermal and regional contact metamorphic events related to widespread plutonism within several juxtaposed terranes. Widespread moderate-P/T dynamothermal metamorphism affected most of this complex during the early Late Cretaceous, and local high-P/T metamorphism affected some parts during the middle Late Cretaceous. These events were contemporaneous with low- to moderate-P, high-T metamorphism elsewhere in the complex. Finally, widespread high-P–T conditions affected most of the western part of the complex in a culminating late Late Cretaceous event. The eastern part of the complex contains an older, pre-Late Triassic metamorphic belt that has been locally overprinted by a widespread middle Tertiary thermal event.The Glacier Bay–Chichagof plutonic–metamorphic complex records dominantly regional contact-metamorphic events that affected rocks of the Alexander and Wrangellia terranes. Widespread low-P, high-T assemblages occur adjacent to regionally extensive foliated granitic, dioritic and gabbroic rocks. Two closely related plutonic events are recognized, one of Late Jurassic age and another of late Early and early Late Cretaceous age; the associated metamorphic events are indistinguishable. A small Late Devonian or Early Mississippian dynamothermal belt occurs just north-east of the complex. Two older low-grade regional metamorphic belts on strike with the complex to the south are related to a Cambrian to Ordovician orogeny and to a widespread Middle Silurian to Early Devonian orogeny.The Chugach plutonic–metamorphic complex records a widespread late Late Cretaceous low- to medium/high-P, moderate- T metamorphic event and a local transitional or superposed early Tertiary low-P, high-T regional metamorphic event associated with mesozonal granitic intrusions that affected regionally deformed and metamorphosed rocks of the Chugach terrane. The Chugach complex also includes a post-Late Triassic to pre-Late Jurassic belt with uncertain relations to the younger belts.

Notes: Small pods of silica-undersaturated Al-rich and Mg-rich granulite facies rocks containing sapphirine, pleonastic spinel, kornerupine, cordierite, orthopyroxene, corundum, sillimanite and gedrite are scattered throughout the NE Strangways Range, Central Australia. These are divided into four distinct rock types, namely orthopyroxene-rich aluminous granofels and metapelitic gneisses containing sapphirine, spinel or kornerupine. Two granulite facies metamorphic events are recognized, of which only the first (M1) is considered in this paper.Peak metamorphic mineral parageneses indicate that the M1 thermal maximum occurred at approximately 900–950 °C and 8–9 kbar. All samples are characterized by profuse and diverse coronitic and symplectic reaction textures. These are interpreted as evidence for the sequential crossing of the following reactions in the system FMAS:cordierite + spinel + corundum = sapphirine + sillimanite, cordierite + spinel = orthopyroxene + sapphirine + sillimanite, sapphirine + spinel + sillimanite = orthopyroxene + corundum, sapphirine + sillimanite = cordierite + orthopyroxene + corundum.Phase stability relationships in FMAS and MASH indicate an anticlockwise P–T path terminated by isobaric cooling. Such a path is exemplified by early low-P mineral parageneses containing spinel, corundum and gedrite and the occurrence of both prograde and retrograde corundum. Reaction textures preserve evidence for an increase in aH2O and aB2O3 with progressive isobaric cooling. This hydrous retrogression resulted from crystallization of intimately associated M1 partial melt segregations. There is no evidence for voluminous magmatic accretion giving rise to the high M1 thermal gradient. The M1 P–T path may be the result of either lithospheric thinning after both crustal thickening and burial of the supracrustal terrane, or concomitant crustal thickening and mantle lithosphere thinning.

Notes: The Seve–Köli Nappe Complex is widespread in the Scandinavian Caledonides and is composed of units representing parts of the Baltoscandian margin (Seve Nappes) now overlain by magmatic–sedimentary rocks (Köli Nappes) derived from west of this margin. The metamorphic evolution of Köli and Seve units has been studied in the Handöl area, central Scandinavian Caledonides, where a fragmented ophiolite with cover sequence in the lower Köli units is thrust over the higher grade Seve units. Thermobarometry constrains metamorphic conditions to 490–570° C/950–600 MPa, with a slight downwards increase in grade, for the lower Köli (Bunnerviken lens), 520–620° C/1000–600 MPa for the upper Seve (Täljstensvalen Complex), 630–740° C/750–650 MPa for the middle Seve (Snasahögarna Nappe) and 480–600° C/1150–1000 MPa for the lower Seve (Blåhammarfjället Nappe). P–T paths during garnet growth have been constructed for all units, except the highest grade middle Seve. These paths record heating at the base of the Köli and cooling in the underlying Seve units. Pressure increase during garnet growth is indicated for all units leading to anticlockwise P–T paths in the Seve. The results imply thermal convergence with time for all units and spatial convergence in metamorphic grade in the Köli. It is suggested that the contrasting metamorphic histories on either side of the Seve–Köli boundary resulted from the emplacement of relatively colder Köli rocks on top of relatively hotter Seve rocks and that emplacement of structurally higher units contributed to the increase in pressure.

Notes: Numerical and analytical models of fluid flow that account for fluid production during prograde regional and contact metamorphism show that expulsion of metamorphic fluids dominates the convective flux when crustal permeabilities are less than 0.1–100 μD, depending primarily on the rate of fluid production. When this is the case, fluid circulation is limited or prevented, fluid pressures are elevated above hydrostatic values, and flow throughout most of the model is up and away from the region of maximum fluid production. Fluid circulation is predicted to occur where permeability is high, in dry rocks, or after rates of fluid production decrease as peak temperatures are reached. Large changes in the pattern of flow and influx of externally derived fluids may thus occur in metamorphic terranes when dehydration wanes or ceases and cooling begins. Inclusion of an impermeable horizon in the models further inhibits fluid circulation. Earlier, shallow hydrothermal models and interpretations based on the Rayleigh number may be inappropriate for characterizing fluid flow during prograde metamorphism at depth because they do not account for fluid production.