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  • Chemical Engineering  (1,397)
  • 2015-2019
  • 1990-1994  (638)
  • 1985-1989  (759)
  • 1993  (638)
  • 1989  (759)
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  • 2015-2019
  • 1990-1994  (638)
  • 1985-1989  (759)
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  • 1
    Electronic Resource
    Electronic Resource
    Stamford, Conn. [u.a.] : Wiley-Blackwell
    Polymer Engineering and Science 29 (1989) 
    ISSN: 0032-3888
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics , Physics
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  • 2
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    Stamford, Conn. [u.a.] : Wiley-Blackwell
    Polymer Engineering and Science 29 (1989), S. 1-1 
    ISSN: 0032-3888
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics , Physics
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  • 3
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    Stamford, Conn. [u.a.] : Wiley-Blackwell
    Polymer Engineering and Science 29 (1989), S. 29-35 
    ISSN: 0032-3888
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics , Physics
    Notes: A recently developed analytical technique, modulus profiling, conveniently allows the mechanical properties of elastomers to be mapped with spatial resclutions approaching 0.05 mm. Thus, spatial heterogeneities in modulus caused by processing and aging phenomena can be easily monitored. This paper describes some typical results from polymer aging studies, which Indicate the insights available from this technique. These include application of modulus profiling to understanding (1) mechanical property deterioration of Viton in an elevated temperature, gamma-radiation environment, (2) recent continuous stress-relaxation results, and (3) the role of ozone for non mechanically-stressed materials in high energy radiation environments.
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  • 4
    ISSN: 0032-3888
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics , Physics
    Notes: Thermal and mechanical studies on many linear polyesters have revealed their behavior in crystalline, liquid crystalline, and amorphous phases. Their phase behavior in binary compositions has also been studied by a range of additional techniques and in combinations including the polycarbonate of bisphenol-A. Regions of amorphous compatibility and incompatibility have been identified and measures made of transition temperature changes with composition. The conditions for transreaction have also been determined and the properties measured for the resultant new copolymers.
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  • 5
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    Stamford, Conn. [u.a.] : Wiley-Blackwell
    Polymer Engineering and Science 29 (1989) 
    ISSN: 0032-3888
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics , Physics
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  • 6
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    Stamford, Conn. [u.a.] : Wiley-Blackwell
    Polymer Engineering and Science 29 (1989), S. 100-106 
    ISSN: 0032-3888
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics , Physics
    Notes: The present paper describes the evaluation of nonlinear thermally induced residual stresses in the cooling of polymer melt during injection molding of plastic components. The computational methodology adopted is based on the transfinite element approach, which is a hybrid scheme as it combines transform methods and classical Galerkin schemes with finite element formulations to preserve the modeling versatility. The applicability of the proposed formulations for understanding the physics and the nature of the nonlinear thermally induced stresses in the solidifying process of a sample amorphous polystyrene specimen demonstrates the basic capabilities and potential of the methodology. Results obtained agree qualitatively well with earlier research studies and experimental findings relevant to thermally induced residual stresses in the injection molding of plastic components.
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  • 7
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    Stamford, Conn. [u.a.] : Wiley-Blackwell
    Polymer Engineering and Science 29 (1989), S. 127-133 
    ISSN: 0032-3888
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics , Physics
    Notes: A method to obtain microscopic and macroscopic coatings with improved resistance to debonding is described. The procedure, based on polymer-metal complexes, involved the adsorption on inorganic substrates of a poly(vinyl alcohol)-copper II chelate that is also able to catalyze the polymerization of monomers or prepolymers with grafting. The molecular structure of the complex, its adsorption on inorganic surfaces, and the mechanism of the polymerization induced by the supported catalyst are summarized. Much emphasis is placed on application of this technology to the realization of encapsulated filler and pigment and of coatings with improved adherence and solvent resistance. In the field of composite materials, it is demonstrated from several examples that the encapsulation of the filler can be a way to block chemical interactions between filler and matrix, to promote filler dispersion, and to improve mechanical properties.
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  • 8
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    Stamford, Conn. [u.a.] : Wiley-Blackwell
    Polymer Engineering and Science 29 (1989), S. 334-338 
    ISSN: 0032-3888
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics , Physics
    Notes: As a result of increased interest from industry in using dielectric cure monitoring, a need has arisen for simplifying frequency, cure, and temperature dependent data so that control decisions can be readily made. Techniques utilizing data covering several decades of frequency now exist for separating ionic conduction levels from dipole and electrode polarization responses. Ionic conduction levels are particularly useful since they can be correlated to both viscosity and extent of cure. In addition to being a function of extent of cure, dielectric properties are also influenced by temperature. This dependence often makes the dielectric response more difficult to interpret. This paper investigates two methods for overcoming the temperature dependence of the dielectric response during nonisothermal cure. The first method utilizes recent WLF modeling techniques and extends them with the end result of extracting Tg in real time during cure. The second technique involves measuring the temperature dependence of uncured and cured material. Utilizing the correlation between log ionic conductivity and extent of cure, which has been noted by previous researchers, the normalized conductivity can be converted to a cure index. Several examples including epoxy, polyurethane, and a UV cured photoresist are presented, showing data before normalization and after both Tg and cure index determination.
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  • 9
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    Stamford, Conn. [u.a.] : Wiley-Blackwell
    Polymer Engineering and Science 29 (1989), S. 359-365 
    ISSN: 0032-3888
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics , Physics
    Notes: Poly(ethylene terephthalate) (PET) and bisphenol-a-polycarbonate (PC) are known to form a miscible blend whereas ternary blends of PET, PC, and polypropylene (PP) form two phases. This is based on the considerations of various chemical events which may occur in these systems. The role of ester-carbonate interchange reactions during melt mixing and fabricating is found to be unimportant. Differential scanning calorimetric analysis of the ternary blends shows that there appears to occur an exothermic transition in the heating mode of the instrument. This exothermic event was found to be suppressed considerably by incorporating suitable additives into the system. Degradation reactions studied by thermogravimetric analysis and a dilute solution viscometric technique reveal that there exists some kind of interaction among the components even with the immiscible PP component.
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  • 10
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    Stamford, Conn. [u.a.] : Wiley-Blackwell
    Polymer Engineering and Science 29 (1989), S. 397-404 
    ISSN: 0032-3888
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics , Physics
    Notes: Interpenetrating polymer networks of polyurethane and unsaturated polyester were prepared by reaction injection molding (RIM) and transfer molding. The structures of the molded samples were analyzed by electron microscopy and dynamic mechanical analysis. It was found that polymer morphology and dynamic mechanical properties depend strongly on the molding temperature, reaction rate and reaction sequence. Simplified structure models based on Takayanagi's model and sample morphology can predict the storage modulus reasonably well but not the tanδ.
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  • 11
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    Stamford, Conn. [u.a.] : Wiley-Blackwell
    Polymer Engineering and Science 29 (1989), S. 432-432 
    ISSN: 0032-3888
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics , Physics
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  • 12
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    Stamford, Conn. [u.a.] : Wiley-Blackwell
    Polymer Engineering and Science 29 (1989), S. 448-455 
    ISSN: 0032-3888
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics , Physics
    Notes: The plasticating or melting behavior of polymer pellets sliding on a hot metal surface was investigated. An analytical model was developed for predicting the melting rate and the shear stress of an incompletely compacted solid bed of pellets in terms of the rheological and thermodynamic properties of the polymer, the pellet size, the degree of compaction, and the operating conditions. This investigation extends the results of the previous investigators obtained for a fully compacted solid bed of polymers to an incompletely compacted solid bed of polymers, closely representing the initial stage of the plasticating mechanism inside a screw extruder. Experimental verification of the analytical model developed here was made by testing six different commercial polymers.
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  • 13
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    Stamford, Conn. [u.a.] : Wiley-Blackwell
    Polymer Engineering and Science 29 (1989), S. 456-462 
    ISSN: 0032-3888
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics , Physics
    Notes: Vitrification occurs during the reaction injection molding (RIM) of epoxy resin, and the curing reaction rate is reduced as the Tg of the reacting mixture exceeds or approaches the local reaction temperature inside the mold cavity. The effect will be manifested in the distribution of the glass transition temperature across the thickness direction of the molded product. The reaction kinetic equation which includes the vitrification term in the form of the WLF equation is used in the computer simulation of the epoxy RIM process and the effect of the vitrification is shown by comparing with models with no vitrification considerations.
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  • 14
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    Stamford, Conn. [u.a.] : Wiley-Blackwell
    Polymer Engineering and Science 29 (1989), S. 479-487 
    ISSN: 0032-3888
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics , Physics
    Notes: The performance of screws of advanced design in injection molding has been investigated with respect to four different objectives: (1) improvement of distributive mixing; (2) improvement of dispersive mixing; (3) increase of plasticating capacity; and (4) reduction of inhomogeneity of melt temperature.The screws used are three zone screws with different compression ratios, screws with pineapple or Maddock/Egan mixing elements, with one or two channel barrier sections, with static mixers mounted in the valve or in the nozzle, or with combinations of these different elements. The best mixing quality is obtained with multi-channel Maddock sections. The highest plasticating capacity and, consequently, the shortest cycle times are achieved with the barrier screws. Temperature measurements show that these screws improve melt homogeneity considerably with a relatively small loss of plasticating time. In all cases, increasing the back pressure gives inferior results compared with improvement of the screw design.
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  • 15
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    Stamford, Conn. [u.a.] : Wiley-Blackwell
    Polymer Engineering and Science 29 (1989), S. 505-512 
    ISSN: 0032-3888
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics , Physics
    Notes: The impact fracture energy (Gc) for a polypropylene homopolymer and a copolymer with and without calcium carbonate fillers was measured over a range of temperatures between -40°C and 40°C using fracture mechanics principles. The fillers studied were Omyacarb (∼2.7 μm) and Winnofil (∼75 nm) and 10% by weight was added to the matrix material. These fillers did not have any appreciable effect on Gc of the copolymer-based composites. However, the Omyacarb fillers improved Gc of the homopolymer at low temperatures (≤20°C) due to enhanced microplastic flow as observed on the fracture surfaces. The fillers increased the stiffness of both the homopolymer and copolymer. It would appear that up to 10% of cheap calcium carbonate fillers could be added to the more expensive polypropylene to reduce the production cost without any significant loss of impact fracture energy.
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  • 16
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    Stamford, Conn. [u.a.] : Wiley-Blackwell
    Polymer Engineering and Science 29 (1989), S. 499-504 
    ISSN: 0032-3888
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics , Physics
    Notes: A novel sliding plate rheometer has been developed that is suitable for use with molten plastics, concentrated polymer solutions, raw elastomers, and other viscoelastic or thixotropic materials. It can generate steady shear rates from 0.05 to 500 s-1 and can also be used to measure linear viscoelastic properties. In addition, it can be used to measure a broad spectrum of nonlinear viscoelastic properties such as the nonlinear relaxation modulus and the shear stress growth coefficient. In order to measure these nonlinear properties it is necessary to generate large, uniform, transient deformations Involving high strain rates. Rotational and capillary melt rheometers are not capable of generating this type of deformation, and until now it was not convenient to use sliding plate rheometers for this type of application. However, the recent development of a reliable and robust shear stress transducer makes it very convenient to use the sliding plate geometry to carry out all of these tests. The new rheometer is described, and examples of the types of data it can generate are shown.
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  • 17
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    Stamford, Conn. [u.a.] : Wiley-Blackwell
    Polymer Engineering and Science 29 (1989), S. 308-314 
    ISSN: 0032-3888
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics , Physics
    Notes: During the sheet molding compound (SMC) compression molding process, a premeasured polymer charge is placed between the heated halves of a mold which are then brought together to squeeze the polymer and fill the mold, after which pressure is maintained while the part cures. The cure stage constitutes the larger part of the molding cycle and thus affords the largest potential for cycle time reduction. In general, cure times in SMC processing are set longer than necessary, since the inherent material and process variation make it difficult to predict cure times with more than 10 to 20% accuracy. Accurate methods to detect the end of cure would be very beneficial and would permit opening the mold as soon as the material has cured, avoiding unnecessary waste of time. In this paper, several techniques that show promise for monitoring the state of cure are reviewed and experimental results given. Their relative advantages and accuracies are compared. In particular, the use of linear variable displacement transducers, pressure transducers, and thermocouples is discussed. We also show how the measurements compare to theoretical predictions of the state of cure.
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  • 18
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    Stamford, Conn. [u.a.] : Wiley-Blackwell
    Polymer Engineering and Science 29 (1989), S. 339-346 
    ISSN: 0032-3888
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics , Physics
    Notes: The parallel-plate test fixture on a Rheometrics viscometer was electrically isolated so that the rheological and dielectric properties of a thermoset polymer system could be simultaneously measured. This enabled the relationship between the dielectric properties and the rheological properties to be directly examined. A close relationship was established between the dielectric properties (dipole relaxation time and specific conductivity) and the pre-gelation bulk viscosity. This relationship suggested that models similar in form to those used to describe the change in viscosity might be used to describe the changing dielectric properties. The limitations and advantages of two such models, which attempt to describe the time-temperature behavior of the dielectric properties, were then tested for use with a typical aerospace epoxy resin system.
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  • 19
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    Stamford, Conn. [u.a.] : Wiley-Blackwell
    Polymer Engineering and Science 29 (1989) 
    ISSN: 0032-3888
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics , Physics
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  • 20
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    Stamford, Conn. [u.a.] : Wiley-Blackwell
    Polymer Engineering and Science 29 (1989), S. 586-592 
    ISSN: 0032-3888
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics , Physics
    Notes: We investigated the miscibility of polybutadienes with butadiene-styrene copolymers of varying styrene content. The methods of optical microscopy, differential scanning calorimetry, and small angle light scattering (SALS) were used. All polymers/copolymers used in this study have equivalent butadiene microstructures. Copolymers with high styrene levels are immiscible with polybutadiene. The tendency to miscibility increases with decreasing styrene content. An upper critical solution temperature is observed with the 23 percent styrene copolymer.
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  • 21
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    Stamford, Conn. [u.a.] : Wiley-Blackwell
    Polymer Engineering and Science 29 (1989), S. 405-414 
    ISSN: 0032-3888
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics , Physics
    Notes: Poly(ether-ether-ketone) (PEEK) is a newly developed engineering thermoplastic with potentially vast application in advanced composites due to its exceptional performance. It is thus desired to understand the relationship between physical processing, microstructure and fracture in this semicrystalline polymer. Both oriented and unoriented PEEK were mechanically characterized using static test of three-point bend specimens. The molecular chain orientation was imposed using a rolltrusion technique. The effects of thickness, strain rate, Initial crack length ratio, and orientation on fracture toughness (Kc) are investigated. The crystallinity is also examined by density measurement. The degree of orientation is determined qualitatively by wide-angle X-ray scattering diffraction patterns and quantitatively by further measurement using an image analysis system. Fractographic analysis, using scanning electron microscopy, provides precise information about the mode of fracture, Results indicate that both the modulus and the fracture toughness are remarkedly increased in the direction of drawing (T-type) as opposed to the transverse direction (L-type).
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  • 22
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    Stamford, Conn. [u.a.] : Wiley-Blackwell
    Polymer Engineering and Science 29 (1989), S. 420-425 
    ISSN: 0032-3888
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics , Physics
    Notes: Herein is more detail to microscopic aspects of electron transport through a conductor-filled polymer than has yet been considered in the literature (irrespective of quantum mechanical tunneling and thermal expansion). Some of these details only clarify earlier theories, but others lead to new discoveries such as the cubic conduction path coordination number z = 18 (contrasted with the classical geometric coordination number of z = 6). New also are simplified derivations of the high and low fill asymptotes of the master equation for conductance as a function of fill fraction in the effective medium theory of conductor-filled polymers.
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  • 23
    ISSN: 0032-3888
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics , Physics
    Notes: Several recent calculations of the stress field around crazes in glassy polymers have been based on experimentally obtained craze opening displacements. Although various techniques for performing these calculations have been presented (i.e., Fourier transform, boundary integral, and finite element methods), all are based on the solution of the same ill-conditioned boundary value problem. Specific boundary conditions required to calculate the stresses around a craze lead to a large change in the stress field with small changes in the craze profile which are within the reported experimental tolerance.
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  • 24
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    Polymer Engineering and Science 29 (1989), S. 433-440 
    ISSN: 0032-3888
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics , Physics
    Notes: The flow of Newtonian and non-Newtonian fluids which obeys a power law relationship between shear stress and shear rate has been modeled in the melt conveying section of a self-wiping co-rotating twin-screw extruder using a finite element analysis of an unwound channel section. Predictions of throughput against pressure gradient are compared with experimentally obtained results for maize grits which is represented as a power law material. Rheological data applicable to extrusion simulation were obtained from capillary rheometry. Comparisons are reasonable with predicted characteristic showing similar behavior.
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  • 25
    ISSN: 0032-3888
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics , Physics
    Notes: The emulsifying activity of a poly(hydrogenated butadiene-b-methyl methacrylate) (HPB-b-PMMA) copolymer is investigated in incompatible blends of a low density polyethylene and poly(styrene-co-acrylonitrile) resins (mainly ABS) prepared in the melt state on a two-roll mill. Optical and scanning electron microscopy observations clearly demonstrate that a moderate amount of copolymer (5 wt %) very significantly decreases the particle size and enhances interfacial adhesion. The block copolymer is also responsible for a strong improvement in both the ductility and Charpy impact resistance of PE/ABS blends.
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  • 26
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    Polymer Engineering and Science 29 (1989), S. 564-572 
    ISSN: 0032-3888
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics , Physics
    Notes: To improve the powder processing behavior of ultrahigh-molecular-weight polyethylene, a conductive iron filler was distributed within the polymer in a segregated network. The filler level was kept at a minimum of 10 volume percent, which was sufficient to coat completely all the polymer particle surfaces. This filler level was low enough to avoid modifying the resin properties to a significant extent. Compaction of these filled samples showed a slower densification, under pressure, similar level of final densification at 80% densification parameter, and a doubling of plateau pressure value to 200 MPa in comparison with the unfilled polymer. The filler was found to reduce drastically the postcompaction relaxation time from 24 h to 6 h. The magnitude of the axial (compaction direction) relaxation was unchanged, but the radial relaxation was one quarter of that for the unfilled polymer. Sintering behavior showed improved densification because of lower dimensional changes during sintering resulting in 80% relative sintered density, higher than the 75% percent value for the unfilled polymer, but yielded a 20% lower sintered strength, An alternative process of rapid sintering by induction heating was explored, its feasibility demonstrated, and a recommendation is made to make powder processing of this polymer commercially attractive.
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  • 27
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    Polymer Engineering and Science 29 (1989), S. 874-877 
    ISSN: 0032-3888
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics , Physics
    Notes: The application of X-Ray lithography in mass production of devices is only economically viable if resist materials of highest sensitivity can be provided. Chemical amplification is the key concept to achieve such performance. It is outlined for a highly sensitive three component positive tone X-Ray resist, consisting of a Novolak binder matrix, a starter compound, which - on X-Ray exposure - yields an acid, which catalytically decomposes a dissolution inhibitor. Resist performance is discussed in terms of reaction kinetics and their implications on resist response, simulation, and handling procedures.
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  • 28
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    Polymer Engineering and Science 29 (1989) 
    ISSN: 0032-3888
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics , Physics
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  • 29
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    Polymer Engineering and Science 29 (1989), S. 898-901 
    ISSN: 0032-3888
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics , Physics
    Notes: Many styrylpyridinium compounds (SPC), which are very stable in the dark, were prepared and evaluated as photobleachable dyes for contrast enhanced lithography (CEL). The photobleaching characteristics of water-soluble contrast enhancing materials composed of SPC and water-soluble polymer depend on the structure of the SPC and the kind of polymers used. The technique using SPC-based CEL proved to be very effective for the resist pattern profiles.
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    Polymer Engineering and Science 29 (1989), S. 916-919 
    ISSN: 0032-3888
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics , Physics
    Notes: Dissolution inhibition mechanisms of naphthoquinone diazides in novolak based positive photoresists were investigated from three different aspects: • Dipolar interaction.• Interfacial chemical reactions.• Chemical structures of naphthoquinone diazides.The results suggest that there exists a hydrogen bonding interaction between the compounds with the matrix novolak resin and that naphthoquinone diazides would crosslink the resin in contact with an alkaline developer, both of which contribute to dissolution inhibition mechanisms. However, there seems to exist another dissolution inhibition mechanism; namely, 1,2-naphthoquinone diazide does not inhibit dissolution of the matrix novolak resin at all while a clear dissolution inhibition effect Is observed for its derivatives containing sulfonyl groups. In the present paper, three dissolution inhibition mechanisms of naphthoquinone diazides will be proposed.
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  • 31
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    Polymer Engineering and Science 29 (1989), S. 625-631 
    ISSN: 0032-3888
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics , Physics
    Notes: A commercial liquid crystalline polymer (LCP) sample was characterized both in shear and in nonisothermal elongational flow over a wide range of temperatures (240-350°C). The LCP sample employed was a copolyesteramide of 2,6 hydroxynaphthoic acid, terephthalic acid, and aminophenol manufactured by Celanese and commercially known as Vectra B950. The viscosity decreases dramatically at temperatures above the crystal-nematic transition of the polymer. At lower temperatures, the extrusion of the sample is mainly due to plastic flow. Die-swell values are very small and contraction of the extrudate is also revealed, but the sample shows high elasticity. The polymer is not spinnable at very low temperatures, and the melt strength rapidly decreases with increasing temperature.
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  • 32
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    Polymer Engineering and Science 29 (1989), S. 639-644 
    ISSN: 0032-3888
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics , Physics
    Notes: Calculation of gas permeation in food packaging structures can be done using a steady-state analysis employing the permeability coefficient. While this approach is adequate for some applications, for many others a time-dependent transport analysis must be considered to make quantitative predictions of shelf life. The limitation of the simple permeability analysis for multilayer structures is illustrated for Saran-coated polycarbonate and poly(ethylene terephthalate) soda cans. These more detailed calculations on package structures can be done using standard computer library routines to include both the effect of gas sorption and diffusion.
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  • 33
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    Polymer Engineering and Science 29 (1989), S. 1097-1102 
    ISSN: 0032-3888
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics , Physics
    Notes: Nonisothermal differential scanning calorimetry (DSC) measurements were used to estimate the kinetic parameters for the curing reaction of a commercial unsaturated polyester resin. The reaction rate expression was derived from a mechanistic kinetic model based on the concept of free radical polymerization, accounting also for the diffusion controlled reaction. The total heat of reaction was evaluated in experiments run at very low scan speeds and using high amount of initiator. The kinetic parameters were found to show no dependency on the heating rate nor on the initiator concentration. Dynamic DSC measurements provide reliable kinetic data over a broad range of temperatures that is mostly significant for process simulations.
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    Polymer Engineering and Science 29 (1989), S. 1103-1106 
    ISSN: 0032-3888
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics , Physics
    Notes: The solid state hydrolysis of a copolyester based on a mixture of 1,4-cyclohexanedimethanol and ethylene glycol condensed with terephthalic acid was studied at 100°C and 57 to 96 kPa water vapor partial pressure (55% to 95% relative humidity). The equilibrium water sorption in weight percent (C∞) was found to be \documentclass{article}\pagestyle{empty}\begin{document}$$ C_\infty = 1.45 \times \,10^{ - 5} (P_{H_2 O} )^{1.2} $$\end{document} where PH2O is the water vapor partial pressure in kPa. For specimens 0.32-cm thick, it took about 24 h to reach 0.9C∞. The intrinsic viscosity (IV) was measured and used to calculate the relative change in molecular weight (M̄w) from the relationship IV ∝ (M̄w)0.7. The decrease in molecular weight was linear with time, and the rate of decrease was found to be proportional to C∞; the empirical correlation is \documentclass{article}\pagestyle{empty}\begin{document}$$ k = 0.026 \times C_\infty $$\end{document} where the rate constant, k, is in day-1. A decrease of 50% in M̄w was observed after 22 days at 95% relative humidity.
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    Polymer Engineering and Science 29 (1989) 
    ISSN: 0032-3888
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics , Physics
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  • 36
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    Polymer Engineering and Science 29 (1989), S. 887-890 
    ISSN: 0032-3888
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics , Physics
    Notes: A new positive-working photosensitive system of silicon polymer, containing silylether groups in the main chain and a photo-induced acid precursor was investigated. The silicon polymer is hydrolized by a photogenerated acid and degraded to low molecular weight compounds. Thus the effect of solubility inhibition of the polymer is diminished. The higher photosensitivity of this system as compared with 1,2-quinone diazide compounds is due to the catalytic reaction of the acid on the hydrolysis of the silicon polymer. The chemical structure around silylether groups in the polymer, in particular more hydrophilic and less steric structures, affects the rate of hydrolysis and thus the photosensitivity. Among various types of photo-induced acid precursors examined, e.g., s-triazine and 1,3,4-oxadiazole compounds substituted by trihalomethyl groups were effective.
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  • 37
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    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics , Physics
    Notes: A finite element technique has been developed for coupled reaction and heat transfer analysis in which mass diffusion is negligible. The temperature unknowns are located at nodal points, while the reaction variables (species concentrations, reaction rates) are at the Gauss points in each element. With a mechanistic kinetic model, the SMC (sheet molding compound) cure in 2-D and 3-D geometries was analyzed. The results for plate-and-rib configurations show the progression of cure and heat transfer and the influence of geometry on the progression. The analysis for a flat sheet of SMC in a mold with localized heating using bubblers indicates the thermal interaction between the mold and the curing SMC. Temperature and reaction profiles are given for each case.
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    Polymer Engineering and Science 29 (1989), S. 1309-1309 
    ISSN: 0032-3888
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics , Physics
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  • 39
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    Polymer Engineering and Science 29 (1989), S. 1340-1367 
    ISSN: 0032-3888
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics , Physics
    Notes: Studies of strength development at polymer-polymer interfaces are examined and applications to welding of similar and dissimilar polymers are considered. The fracture properties of the weld, namely, fracture stress, σ, fracture energy, GIc, fatigue crack propagation rate da/dN, and microscopic aspects of the deformation process are determined using compact tension, wedge cleavage, and double cantilever beam healing experiments. The mechanical properties are related to the structure of the interface via microscopic deformation mechanisms involving disentanglement and bond rupture. The time dependent structure of the welding interface is determined in terms of the molecular dynamics of the polymer chains, the chemical compatibility, and the fractal nature of diffuse interfaces. Several experimental methods are used to probe the weld structure and compare with theoretical scaling laws, Results are given for symmetric amorphous welds, incompatible and compatible asymmetric amorphous welds, incompatible semicrystalline and polymer-metal welds. The relevance of interface healing studies to thermal, friction, solvent and ultrasonic welds is discussed.
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    Polymer Engineering and Science 29 (1989), S. 1387-1395 
    ISSN: 0032-3888
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics , Physics
    Notes: The integrity of a pipeline system is determined by its weakest links. Joints may be such places. Heat fusion is the most common joining method for distribution gas piping. There are procedural, thermal, and mechanical aspects of making fusion joints. Procedural aspects, such as heater calibration and cleanliness, can be assured only by rigorous training and certification of the operators. Thermal and mechanical aspects consist of specifying joining conditions such as the heater temperature, heating time, and joining pressure. In the absence of procedural errors, the strength of a fusion joint should depend on the pipe material, pipe dimensions, and the thermal and mechanical joining conditions.The measured parameters that are measures of strength are impact energy and location of failure in the tensile impact test. A parameter, termed the joining parameter, was found to characterize the joining conditions. This parameter is a function of bead volume, melt volume at the end of the heating phase, and pipe wall thickness. Of the mechanical test parameters, the impact energy was found to correlate best with the joining parameter.
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    Polymer Engineering and Science 29 (1989), S. 1413-1418 
    ISSN: 0032-3888
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics , Physics
    Notes: A variety of thermoplastic fully imidized poly(imide siloxane) segmented copolymers with useful thermal and mechanical properties have been prepared. Other interesting properties described are the materials' hydrophobic character, surface domination, UV stability, and atomic oxygen plasma resistance.
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    Polymer Engineering and Science 29 (1989), S. 1446-1455 
    ISSN: 0032-3888
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics , Physics
    Notes: This study deals with the cold compaction of polyether-etherketone (PEEK) and nickel powder blends. Four different types of PEEK powders which are commercially available from Imperial Chemical Industries (ICI) were utilized for this investigation. These PEEK powders included fine and coarse size powders of a low viscosity grade (150PF and 150P) and similar powders of a high viscosity grade (450PF and 450P). Each of the four different PEEK powders were blended with about 10 vol-% nickel powder (Novamet) using a dry mixing technique. These PEEK/nickel powder blends were then successfully compacted at room temperature. Green strengths as high as 39.5 MPa and 26.3 MPa were measured on nickel filled 150 grade and 450 grade compacts, respectively. The higher strength values of the nickel filled compacts compared to their respective unfilled ones were attributed to a higher degree of mechanical interlocking and plastic deformation, which was induced in the polymer particles during compaction by the hard nickel filler. These composites also exhibited lower viscoelastic recoveries than their respective unfilled compacts. Electrical resistivities as low as 0.06 ohm-cm were achieved by compacting 150P/nickel powder blends. This resistivity value agreed well with the calculated value predicted from the literature.
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    Polymer Engineering and Science 29 (1989), S. 1456-1465 
    ISSN: 0032-3888
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics , Physics
    Notes: This study deals with the characterization and cold compaction of polyetheretherketone (PEEK) powders. Four different types of PEEK powders which are commercially available from Imperial Chemical Industries (ICI) were characterized for density, crystallinity, particle size, particle size distribution, and particle morphology. Fine and coarse size powders of a low viscosity grade (150PF and 150P) and similar powders of a high viscosity grade (450PF and 450P) were processed. Compaction was successful at room temperature using the 150 grade powders but not with the 450 grade powders. Compressibility curves were obtained at room temperature for the 150 grade powders and their post-compaction viscoelastic recoveries were measured. The coarse and fine size 150 grade powders reached relative plateau densities of 95.8% and 95.1%, respectively, when compacted at pressures exceeding 300 MPa. These high densification values at room temperature were associated with minimal post-compaction viscoelastic recoveries and as-compacted strengths as high as 8.9 MPa. A modified densification parameter (DP*) was developed based on the plastic deformation of the crystalline regions alone. This new dimensionless parameter, DP*, demonstrated a better fit of all the compaction data. The transverse rupture strength and the green density data are presented and explained in terms of this DP*.
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    Polymer Engineering and Science 29 (1989) 
    ISSN: 0032-3888
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics , Physics
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  • 45
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    Polymer Engineering and Science 29 (1989), S. 1528-1533 
    ISSN: 0032-3888
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics , Physics
    Notes: A study was conducted of blends of poly(vinyl chloride) (PVC) with a poly(methyl methacrylate co imide). The latter polymer was found to be miscible in PVC and to raise the glass transition temperature of the blend. Blends of all compositions could be oriented, but the processing temperature increased in proportion with Tg. For a given blend composition, orientation increased with increasing stretch ratio and strain rate and with decreasing stretch temperature. Increasing copolyimide content and increasing orientation generally lead to improved mechanical properties, though the blends containing high levels of copolyimide exhibited low ductilities.
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    Polymer Engineering and Science 29 (1989), S. 1574-1578 
    ISSN: 0032-3888
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics , Physics
    Notes: The optical properties of polyetherimide resin as described by the complex index of refraction, N = n - ik, are derived by Kramers-Kronig analysis of experimental absorption and reflectance data obtained in the range 40 μm ≥ λ ≥105 nm. Potential uses of this polymer as a printed circuit board material and as a packaging medium for microelectronic circuitry and the relevance of optical data in laser-assisted processing schemes used in these and other applications are briefly discussed.
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  • 47
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    Polymer Engineering and Science 29 (1989), S. 214-226 
    ISSN: 0032-3888
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics , Physics
    Notes: Shear modification treatment represents a special shearing history affecting mainly the elastic behavior of polymer melts. This process has been attributed to reversible physical changes in the entanglement structure of the polymer chain network. Shear modification studies were performed for two well-characterized low-density polyethylene (LDPE) grades differing in molecular weight distribution and degree of long chain branching. The shear working of the material was carried out using a specially designed shearing unit producing definable amounts of pure shear in a continuous process. Measurements of the dynamic storage modulus, G′, steady-state shear compliance; Je, extrudate swell, melt flow index, and the extensional behavior (Rheotens test) indicate that primarily properties associated with the elasticity of the melt are reduced in value. The observed reduction is found to correlate with the mean specific energy dissipated during sample preparation. Comparing the two LDPE grades showed that higher degrees of modification can be obtained at lower energy input levels for the more highly branched grade. Reversibility tests were performed and complete recovery of the initial material behavior was observed. Comparison of measurement results for samples prepared using the shearing unit presented here and a Brabender Plasticorder indicates that the degree of modification depends not only on the molecular structure of the polymer but also on the manner in which the shearing history is imposed upon the material.
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    Polymer Engineering and Science 29 (1989) 
    ISSN: 0032-3888
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics , Physics
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    Polymer Engineering and Science 29 (1989), S. 1637-1637 
    ISSN: 0032-3888
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics , Physics
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    Polymer Engineering and Science 29 (1989), S. 1628-1635 
    ISSN: 0032-3888
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics , Physics
    Notes: The compressive and tensile properties of polyester mortar were studied under various curing conditions, temperature, and strain rate. The curing temperature was varied from room temperature to 80°C. The behavior of polyester mortar was studied using a uniform sand with strain rate and temperature varied between 0.01 to 6 percent strain per minute and 22°C and 120°C, respectively. The strength, failure strain, modulus and stress-strain relationships of polyester mortar are influenced by the curing method, testing temperature, and strain rate to varying degrees. The influence of test variables on the mechanical properties of polyester mortar are quantified. Pretreating the aggregates with a silane coupling agent further enhances the compressive and tensile strength of the mortar. The compressive modulus and splitting tensile strength of polyester mortar are related to the compressive strength. A constitutive model is used to predict the compressive stress-strain behavior of polyester mortar.
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    Polymer Engineering and Science 29 (1989), S. 1667-1676 
    ISSN: 0032-3888
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics , Physics
    Notes: Under the right conditions, high strengths are shown to be achievable in vibration welded polycarbonate to polyetherimide Joints. While welding of thermoplastic interfaces of the same material can be understood in terms of interchain diffusion at elevated temperatures, this mechanism is severely limited in the case of dissimilar materials. Scanning electron microscopy is used to show that part of the bond strength in such dissimilar materials results from mechanical interlocking of the two polymers, which is caused by viscous mixing. The effects of the weld parameters on the weld morphology are considered in detail.
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    Polymer Engineering and Science 29 (1989), S. 1689-1698 
    ISSN: 0032-3888
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics , Physics
    Notes: Ultrasonic welding is one of the most popular techniques for joining thermoplastics because it is fast, economical, and easily automated. In near-field ultrasonic welding, the distance between the horn and the joint interface is 6 mm or less. This study investigated the near-field ultrasonic welding of amorphous (acrylonitrile-butadiene-styrene and polystyrene) and semicrystalline (polyethylene and polypropylene) polymers. High frequency ultrasonic wave propagation and attenuation measurements were made in order to estimate the dynamic mechanical moduli of the polymers. The estimated moduli were entered into a lumped parameter model in order to predict heating rates and energy dissipation. Experimental results showed that variations in the welding pressure had little effect on energy dissipation or joint strength; Increasing the amplitude of vibration increased the energy dissipation and the weld strength. For the semicrystalline polymers, increasing the weld time improved strength up to weld times greater than 1.5 s, where strength leveled off. For the amorphous polymers, the weld strength increased with Increasing weld time up to times of 0.8 s; for longer weld times, the power required was too high, causing overloading of the welder. Monitoring of the energy dissipation and static displacement or collapse provided valuable information on weld quality.
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    Polymer Engineering and Science 29 (1989), S. 1733-1737 
    ISSN: 0032-3888
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics , Physics
    Notes: The hydrolytic stability of a new commercial polycarbonate (Calibre 300, Dow Chemical USA) was investigated and compared with that of other commercial polycarbonates. The tests were conducted between 56% and 95% relative humidity (R. H.) at 100°C. Also performed were water immersion tests at 80 and 100°C. The water diffusivity was found to be 8.7 × 10-7 cm2/s at 100°C with an activation energy of 7.9 kcal/mole. These values are similar to other glassy polymers. The equilibrium water sorption, C∞, was found to increase with temperature and R.H. The isotherm at 100°C was determined to be: C∞ = 0.005945 [R.H.]. When samples immersed in a water bath at 100°C were transferred into room-temperature water, visible aqueous microcavities were formed due to the condition of super-saturation, and under stress may become crack initiation sites. For the polycarbonate investigated here, it was found that the decrease in weight-average molecular weight (M̄)w was a first-order process under a constant R.H. and temperature, and that hydrolytic embrittlement, i. e., (M̄)w 〈34,000, was reached after ca. 188, 143, 99, and 66 days under 56%, 73%, 87%, and 95% R.H., respectively, at 100°C. A comparison with reported hydrolytic stability data for other polycarbonates showed large differences in their stability which are believed to be due to the extent of end-group capping (over 95% in Calibre 300) and resin purity: both phenolic end-groups and some additives (i.e., fire retardants, thermal stabilizers) are known to accelerate hydrolytic degradation.
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    Polymer Engineering and Science 29 (1989), S. 1766-1773 
    ISSN: 0032-3888
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics , Physics
    Notes: Moldability and mechanical properties of polyethylene terephthalate (PET) under normal molding conditions were found to improve significantly when it was blended with bisphenol-A-polycarbonate (PC) and polypropylene (PP) to form ternary polymer blend systems. DSC results of these blends revealed that the PET and PC components formed a miscible blend while PP being incompatible with them, formed a separate phase. PP was also found to form a sleeve around the PET-PC miscible phase and, thereby, showed a skin-core type of morphology. Variations of mechanical properties with varying amounts of PP was measured keeping the ratio of PET and PC constant. Tensile and flexural properties of the blends decrease with the amount of PP. Notched impact strength increases up to a certain level of PP and then decreases, while the unnotched values decrease gradually. The effect of annealing on the mechanical properties of these blends have been discussed on the basis of the increased crystallinity of some of the components.
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    Polymer Engineering and Science 29 (1989), S. 1786-1795 
    ISSN: 0032-3888
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics , Physics
    Notes: The possible multimodal sorption mechanisms in glassy amorphous poly-ether-ether-ketone (PEEK) are presented. By varying the penetrant-polymer affinity, experimental temperature, and external solvent activity, a broad range of sorption behaviors from ideal Fickian diffusion to limiting relaxation controlled kinetics is observed. In particular, water, methylene chloride, and n-heptane sorption kinetics are analyzed and interpreted on the basis of the multiple transport mechanisms. Low uptake liquid n-heptane sorption follows ordinary Fickian diffusion. Analogously, water vapor at low activity, is sorbed in small amounts in the same limiting mode while, at higher activities, the moderately higher penetrant uptakes induce slow relaxation coupled with ideal Fickian diffusion. The highly interacting methylene chloride leads to ideal Fickian diffusion only at very low activities, while anomalous non-ideal Fickian diffusion and limiting Case II and diffusion controlled swelling are observed at moderate and at high solvent activities, respectively. Limiting Case II sorption of methylene chloride in PEEK has been observed only at a very low temperature (-32°C). The optical microscopy observations of cryogenically fractured samples contacted with liquid methylene chloride at 5, 20 and 36°C revealed the presence of a sharp front moving linearly with the square root of time. Solvent induced crystallization in methylene chloride swollen samples was detected by means of differential scanning calorimetry (DSC) and wide angle X-ray scattering (WAXS). Finally, sorption from liquid methylene chloride/n-heptane solutions with varying compositions are presented. The progressive increase of the more high sorbing methylene chloride concentration in the solutions, leads to the same wide variety of sorption behavior observed in the methylene chloride vapor sorptions. The gas chromatographic (GC) analysis indicated that the presence of methylene chloride enhanced the n-heptane sorption in the polymer.
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    Polymer Engineering and Science 29 (1989), S. 1649-1654 
    ISSN: 0032-3888
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics , Physics
    Notes: Welding represents one of the key stages in the manufacture of injection molded or blow molded plastics products. One process frequently employed is heated-tool butt welding. However, the high seam quality associated with this process can only be attained through reliable process control and optimized welding parameters. This paper presents a simple new method for determining these parameters. Mathematical and physical descriptions of the individual process stages and a computer-controlled heated-tool butt welding machine serve as the basis for determining the parameters.
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  • 57
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    Polymer Engineering and Science 29 (1989), S. 1661-1666 
    ISSN: 0032-3888
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics , Physics
    Notes: A measuring method is presented for process monitoring and process analysis of linear vibration welding of thermoplastics. The method works by recording and evaluating time-dependent signals that describe the process - such as the frequency-dependent signals of the displacement of the two parts being joined, the tangential force in the welding plane - and the nonperiodic signals of the welding process, i.e. the normal force in the welding plane and the melting or joining displacement of the parts being joined. It is possible to determine the energy input into the welding zone as a function of the selected machine parameters and the process sequence over time.
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    Polymer Engineering and Science 29 (1989), S. 1699-1704 
    ISSN: 0032-3888
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics , Physics
    Notes: In far-field ultrasonic welding of plastic parts the distance between the ultrasonic horn and the joint is greater than 6 mm. This study investigated the farfield ultrasonic welding of amorphous (acrylo butadiene styrene and polystyrene) and semicrystalline (polyethylene and polypropylene) polymers. Far-field welding worked well for amorphous polymers. Weld strength improved substantially with increasing amplitude of vibration at the joint interface. Increasing the weld pressure and/or the weld time also resulted in higher weld strengths. Far-field ultrasonic welding was not successful for semicrystalline polymers. The parts melted and deformed at the horn/part interface with little or no melting at the joint interface. A model for wave propagation in viscoelastic materials, which was developed to predict the vibration amplitude experienced at the joint interface, indicates that increasing the length of the samples to a half a wavelength should improve the far-field welding of semicrystalline polymers by maximizing the amplitude of vibration at the joint interface.
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    Polymer Engineering and Science 29 (1989) 
    ISSN: 0032-3888
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics , Physics
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  • 60
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    Polymer Engineering and Science 29 (1989), S. 1746-1758 
    ISSN: 0032-3888
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics , Physics
    Notes: A methodological survey of preparation of microspheres and microcapsules by suspension cross-linking is presented. Thus, basic features of suspension cross-linking, i.e., the formation of small droplets of a polymer solution (or melt) in an immiscible liquid followed by hardening of these droplets by covalent cross-linking, are discussed. Typical microspherical and microcapsular products manufactured by suspension cross-linking of naturally occurring and preformed synthetic polymers, including agarose and cellulose beads, albumin microspheres and microcapsules, polystyrene beads and epoxy resin microcapsules, are described. Manufacturing parameters controlling microsphere/microcapsule characteristics are also briefly outlined.
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    Polymer Engineering and Science 29 (1989) 
    ISSN: 0032-3888
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics , Physics
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  • 62
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    Polymer Engineering and Science 29 (1989), S. 1325-1331 
    ISSN: 0032-3888
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics , Physics
    Notes: In structures composed of polymer matrix composite materials, components must be joined such that the overall structure retains its structural integrity while it is performing its, intended function which can include both mechanical loads (static and dynamic) and environmental loads (temperature and humidity). The use of composite materials in complex structures almost always reduces the number of components in the structures compared to the use of metallic alloys for the same structure. Thus, using composite materials not only results in great savings in weight, but also through a reduced number of joining operations, results in significant savings in assembly, inspection, parts storage, and movement, resulting in increased reliability and lower cost. Yet joining is still required. Joining metallic structures is a mature technology involving riveting, bolting, welding, glueing, brazing, soldering, and other methods. However, for most polymer matrix composites only adhesive bonding and mechanical fastening can be utilized. Attention has been given recently, however, to localized welding of thermoplastic polymer matrix composites, and this will be discussed briefly later. Inherently, adhesive bonding is preferable to mechanical fastening because of the continuous connection, whereas in drilling holes for bolts or rivets, fibers or other reinforcements are cut, and large stress concentrations occar at each discrete fastener hole. The following is a review of much of the literature dealing with adhesive bonding of polymer matrix composite structures. It is Intended not only to be a review, but also a background for detailed study of the referenced and other documents, and a catalyst for future research.
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    Polymer Engineering and Science 29 (1989), S. 1488-1491 
    ISSN: 0032-3888
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics , Physics
    Notes: Gelation phenomenon in thermoset polymers is an area of extreme importance from the processing point of view. Gel point (GP) has traditionally been detected using rheological and mechanical techniques. We wish to report the use of dielectric and especially calorimetric techniques for detecting GP. Using a particular thermoset system, we have compared the calorimetric, dielectric, and mechanical techniques and shown how to define GP in terms of time and temperature. As a matter of convenience, we have briefly defined the gelation phenomenon in thermosets, its significance and measurement, and a critical evaluation of the techniques for detecting GP.
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    Polymer Engineering and Science 29 (1989), S. 1516-1523 
    ISSN: 0032-3888
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics , Physics
    Notes: A study of orientation development in polystyrene film by biaxial stretching is described. Stretch ratios up to 7.2 × 7.2 were used. Mechanical properties of polystyrene films were correlated with the level of molecular orientation developed by uniaxial or biaxial stretching. Sensitivity of the mechanical properties to change due to development of orientation varied as follows: Yield strength 〈 Young's modulus 〈 Tensile strength 〈 Elongation to break. Brittle to ductile transition phenomena were observed at certain orientation values in the orientation triangle diagram. The transition occurs when f1B × f2B ∼ 0.0025 for biaxially oriented and f1B ∼ 0.015 in the machine direction for uniaxially oriented films. SEM photomicrographs show that the fracture surfaces of ductile failures exhibit many fibrils while brittle failures exhibit no fibrils.
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    Polymer Engineering and Science 29 (1989) 
    ISSN: 0032-3888
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics , Physics
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    Polymer Engineering and Science 29 (1989), S. 1579-1587 
    ISSN: 0032-3888
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics , Physics
    Notes: A general kinetic model was developed to simulate the grafting of monomers such as unsaturated carboxylic acids and silanes to ethylene polymers. The polymers considered were ethylene-co-vinyl acetate (EVA), ethylene-co-butyl acrylate (EBA), and low-density polyethylene (LDPE). Grafting was assumed to proceed by a free-radical mechanism involving chain transfer. Organic peroxides having a strong tendency for hydrogen abstraction were selected as the source of primary radicals. The model simulated the grafting reaction as taking place in a single screw extruder. The residence time distribution in the extruder was experimentally determined by tracer analysis, according to which the extruder was a plug-flow reactor connected to two mixed reactors in parallel. The model is able to predict the extent of grafting in terms of predefined parameters. Comparison of model predictions with available experimental data showed slight deviations, the possible causes of which are discussed. However, the kinetic behavior expected on the basis of the input parameters was observed, and, as such, the model allowed study of the effect of process variables on grafting kinetics and provided insight into the reaction mechanism.
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    Polymer Engineering and Science 29 (1989), S. 1598-1603 
    ISSN: 0032-3888
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics , Physics
    Notes: This paper describes characterizations performed on two types of polyethylene T-Joints as well as the starting resin from which they were manufactured. It was found that the melt flow rate of material taken from the two types of joints differed from that of the starting resin and differed from each other by as much as a factor of two. Investigation of the environmental stress-crack resistance (ESCR) and uniaxial creep behavior of material from the two joints revealed further significant differences in behavior between the two joints. These observations lead to the conclusion that subtle differences in the processing conditions can result in significant differences in the long-term mechanical behavior.
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    Polymer Engineering and Science 29 (1989), S. 1614-1617 
    ISSN: 0032-3888
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics , Physics
    Notes: The tensile strength of solid-filled rubbers is predicted by the statistical model proposed in this paper, by which the maximum area fraction of the solid filler in a representative cube is calculated. The minimum net cross-section area of the rubber matrix is thus obtained, and this is used to calculate the reduction in strength of the compound in comparison to that of the unfilled rubber. The prediction is then tested by experiments using hydroxyl-terminated polybutadiene (HTPB) filled with glass spheres. After curing, tensile specimens were cut from sheets and exposed to humidity-controlled environments so as to debond the filler particles from the rubber matrix, and were tested in tension. The experimental results were found consistent with the predictions.
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    Polymer Engineering and Science 29 (1989), S. 1683-1688 
    ISSN: 0032-3888
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics , Physics
    Notes: In vibration welding of thermoplastics, frictional work done by vibrating two parts under pressure, along their common interface, is used to generate heat to effect a weld. Past work on welding characterized the effects of weld parameters such as the weld frequency, the weld pressure, and the weld time, on the welding process and weld strength, and showed that the most important parameter affecting weld strength Is the weld penetration - the decrease in the distance between the parts being welded that is caused by lateral outflow of material in the molten film. However, those weld studies were based on specimens of constant nominal thickness (6.35 mm, 0.25 in). This paper is concerned with the effects of specimen thickness on the weld process and weld strength.
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    Polymer Engineering and Science 29 (1989), S. 1722-1729 
    ISSN: 0032-3888
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics , Physics
    Notes: A transient two-dimensional thermal model for resistance welding of thermoplastic composites is presented. A parametric study is conducted that yields insight into the welding process enabling some critical process and material parameters to be identified. Time to melt is predicted by the model and is successfully compared to experimental observations. Local heating and meltthrough can also be explained by the transient thermal model in agreement with experimental observations. Mode I fracture toughness of unidirectional graphite reinforced poly(etheretherketone) resistance welded double cantilever beam specimens are conducted under various process conditions. Experimental results indicate that under optimum process conditions, the interlaminar fracture toughness of the bulk compression-molded thermoplastic composite material can be achieved using resistance heating as a joining technique.
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    Topics: Chemistry and Pharmacology , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics , Physics
    Notes: Although fibers are subject to complex deformations during processing and end use, most research has concentrated on tensile properties. We have extended our studies to include the ultimate torsional properties, i.e., the breaking twist angle (BTA), and the flexural fatigue life of single fibers. We now have sufficient data on diverse fiber types that we may compare their mechanical properties. Thus, in this paper we report the mechanical properties of the different starting, untreated, fibers, tested under fiducial conditions. We then develop and consider some interrelationships between these selected single fiber physical properties.
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    Polymer Engineering and Science 29 (1989), S. 1774-1785 
    ISSN: 0032-3888
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics , Physics
    Notes: We have analyzed step growth polymerization in a flat film with finite mass transfer resistance. We have shown rigorously that the molecular weight distribution (MWD) at equilibrium is given by the Flory distribution, and under reaction the form of the MWD does not change if the feed is either pure monomer or in equilibrium initially. Extensive computations have shown that it is possible to split the film into growing interfacial and shrinking bulk regions. It is possible to obtain similarity transformations of concentrations of condensation product, and polymer as time invariant profiles. Based on this finding, we have determined a solution for step growth polymerization with finite mass transfer in films. The results lie within 5% of the “exact” numerical computations, for all possible variations of parameters.
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  • 73
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    Polymer Engineering and Science 33 (1993), S. 393-399 
    ISSN: 0032-3888
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics , Physics
    Notes: The univariant element, Q1 P0, and the multivariant elements, Q1+P0 and R2+ P0, are compared for the numerical simulation of the flow in extrusion dies. The pressure distribution obtained by using the Q1 P0 element was found to be afflicted with the checkerboard pressure mode. On the other hand, the multivariant elements, Q1+ P0 and R2+ P0, gave accurate and physically reasonable velocity and pressure distributions. The computed values of the pressure drop across extrusion dies matched well with the pressure drop determined experimentally.
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    Polymer Engineering and Science 33 (1993), S. 377-382 
    ISSN: 0032-3888
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics , Physics
    Notes: The viscoelastic responses of some molten polymers, and particularly of low density polyethylene (LDPE), are known to vary with processing history. Reasons for the variations include the effects of shear history on morphological states of the polymer, or on its molecular weight parameters. A typical low density polyethylene has been used to test the shear-history dependence concept following a variety of processing steps. The polymer was sheared in single-screw and twin-screw extruders, and in a high speed melter / mixer (Gelimat). Samples also were precipitated from very dilute solutions in trichlorobenzene and in p-xylene. GPC analyses showed that, in general, these procedures did not affect the various moments of molecular weight. An exception was the Gelimat-mixed sample, for which mild reductions in Mn and Mw were noted. In contrast, melt viscosity and elasticity readings, the former from low shear evaluations and the latter from extrudate swelling, were affected by the various procedures. A drop in melt viscosity and in elasticity was observed, being most pronounced for precipitated and twin-screw extruded versions of the LDPE. Reductions also were observed in the specimen sheared in the Gelimat instrument. Following conditioning at the test extrusion temperature (170°C), viscous and elastic responses tended to revert to those of the unsheared control sample, the exception again being the sample sheared in the Gelimat melter / mixer. Of the various mechanisms proposed in the literature to account for transient property changes such as those reported, temporary changes in the degree of chain entanglement appear the most satisfactory explanation. Irreversible alterations in viscoelastic properties may be associated with changes in molecular weights due to processing at high shear.
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    Polymer Engineering and Science 33 (1993), S. 400-409 
    ISSN: 0032-3888
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics , Physics
    Notes: A model for the filling stage of injection molding of viscoelastic thermoplastics in cavities of complex shape is presented. The model considers two-dimensional melt flow, with converging and diverging flow patterns induced by complex boundary shape and by the presence of an obstacle. The model is non-isothermal (with the melt loosing heat to the mold walls as it travels into the cavity) and handles a viscoelastic (following the White-Metzner model) material with properties that vary with temperature, shear rate, and pressure. The numerical method is based on finite differences, with boundary fitted curvilinear coordinates used in the mapping of the flow field (which has an arbitrary shape that evolves with time) into a time invariant rectangle. The numerical results reveal geometry-induced asymmetries in the flow and thermal fields as well as the effect of various process parameters on the pressure and temperature profiles in the cavity. The model admits variable cavity thickness, thus allowing for a treatment of the cavity thickness as a process parameter in the simulations.
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    Polymer Engineering and Science 33 (1993), S. 497-500 
    ISSN: 0032-3888
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics , Physics
    Notes: The use of polymeric materials in building or construction applications is steadily increasing. Therefore, the potential for these materials to be exposed to fire is also increased. The understanding of the pyrolysis characteristics of these materials is thus a necessity. There are many standard tests used to evaluate materials. Unfortunately, the correlation between these tests and large scale fire is less than desirable. A new bench scale rate of heat release apparatus, the Cone Calorimeter, is now being used more frequently in pyrolysis testing of polymeric materials. This apparatus has been shown to correlate much better between room scale testing and large scale fire testing. The cone Calorimeter provides a pyrolysis profile of a material under ambient oxygen conditions. Characteristics such as ignition time, total heat release, maximum rate of heat release, mass loss during pyrolysis, CO2, CO, and smoke production are determined. In this work several almost neat polymers are examined and the general pyrolysis characteristics of these polymers are discussed. The objective of this work is to provide information of basic polymeric pyrolysis properties of these materials. Variations in the material, i.e., molecular weight, polydispersity, and residual catalysis, along with changes in testing procedures, can have dramatic effects on results. Obviously the addition of flame retardant and flame retardant packages to any of these materials will have dramatic effects on results.
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    Polymer Engineering and Science 33 (1993) 
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    Keywords: Chemistry ; Chemical Engineering
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    Topics: Chemistry and Pharmacology , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics , Physics
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    Polymer Engineering and Science 33 (1993), S. 513-521 
    ISSN: 0032-3888
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics , Physics
    Notes: The overall isothermal crystallization kinetics for nucleated and non-nucleated isotactic polypropylene (iPP)-dotriacontane systems was investigated. Adipic acid was used as the nucleating agent. Half-time was determined via differential scanning calorimetry as a function of the experimentally controlled variables dilution, crystallization temperature, and the addition of nucleating agent. The influence of these variables on crystallization mechanism and spherulitic structure, as implied by the Avrami analysis, was determined. The influence of these variables on fold surface energy was examined by the Lauritzen and Hoffman analysis.
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    Notes: The overall non-isothermal crystallization kinetics for nucleated and non-nucleated isotactic polypropylene (iPP) in dotriacontane systems was investigated. Adipic acid was used as the nucleating agent. Crystallization peak temperature was determined via differential scanning calorimetry as a function of the experimentally controlled variables iPP concentration, cooling rate, and nucleating agent concentration. The influence of these variables on crystallization mechanism and spherulitic structure as implied by the Ozawa and Ziabicki analyses was determined. The non-isothermal crystallization kinetics presented here are the first for iPP-diluent systems with and without nucleating agent.
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    Polymer Engineering and Science 33 (1993), S. 543-548 
    ISSN: 0032-3888
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics , Physics
    Notes: The static shear strength and static friction of three thermoplastics have been investigated for the case of contact between a bulk plastic sample and a very smooth metallic plate. The minimum tangential force required to shear the interfacial adhesion bonds between the two surfaces was measured and defined as the adhesion component of friction Fa. Experimental results showed that Fa is large when the surface energy is high or the interfacial energy is small and that a correlation may exist between this force and the work of adhesion evaluated from Dupré equation. The real area of contact Ar was also measured using an optical device designed to handle samples and experimental conditions similar to the static friction tests. It was found that Ar is proportional to Pa0.9 where Pa is the apparent pressure of contact and an increase of Fa with Pr was observed. The static shear strength τ has been evaluated as the ratio Fa/Ar, and its relationships with the real contact pressure P approximated by linear functions. It was concluded that τ increases at high P, although it has not been verified for ultra-high-molecular-weight polyethylene. An attempt has been made to explain the observed break in the data. The results indicated that (τ/τb) = κ′(τa/Pa) where b refers to bulk, a to apparent values, and κ′ is a proportionality constant that depends on the plastic material.
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  • 81
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    Polymer Engineering and Science 33 (1993), S. 549-558 
    ISSN: 0032-3888
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics , Physics
    Notes: A variety of different styrene monomers [styrene (S), p-fluorostyrene (p-FS), pentafluorostyrene (PFS), p-chlorostyrene (p-ClS), p-bromostyrene (p-BrS), p-methylstyrene (p-MS), p-tert-butylstyrene (p-tBS), p-methoxystyrene (p-MOS), p-ethoxystyrene (p-EOS), and p-propoxystyrene (p-POS)] have been polymerized by radical and cationic mechanisms. Copolymers of S/PFS, S/p-ClS, S/2-vinyl-naphthalene (2-VN), and S/p-phenylstyrene (p-PhS) were prepared by radical polymerization. All polymers were fully amorphous and transparent and exhibited only one glass transition temperature in the temperature range 77 to 141°C. Thin films of the polymers were subjected to external electrical partial discharges (PD). Typically, 20 PD experiments were conducted for each polymer and the data for the time to breakdown were adapted to the two-parameter Weibull distribution function. The resistance towards PD of the various polymers was found to depend strongly on the monomeric structure. Complementary PD experiments on a series of narrow molecular mass polystyrenes confirmed that the minor variation in molecular mass between the different styrene polymers is of no importance for the PD resistance. The PD resistance of the homopolymers decreased in the following order: PS ≍ P(p-MS) 〉 P(p-tBS) ≍ P(p-BrS) 〉 P(p-POS) 〉 P(p-ClS) ≍ P(p-MOS) 〉 P(p-EOS) ≍ P(p-FS) 〉 P(PFS). The time to breakdown for copolymers of S and PFS decreased monotonously with increasing PFS content. Styrene copolymers with low molar contents of 2- VN and p-PhS exhibited a higher resistance towards PD than PS. The results are discussed with reference to various properties of the studied polymers, such as segmental mobility, ionization potential, resonance stabilization, and reactivity of the radicals formed.
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  • 82
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    Polymer Engineering and Science 33 (1993) 
    ISSN: 0032-3888
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics , Physics
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  • 83
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    Polymer Engineering and Science 33 (1993), S. 614-621 
    ISSN: 0032-3888
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics , Physics
    Notes: The glass transition temperatures in bismaleimide-based resins were investigated using different stoichiometric ratios of 1, 1′-(methylenedi-4, 1-phenylene)bismaleimide (BMI) and 4, 4′-methylenedianiline (MDA). The resin cure involves a low temperature primary amine addition to the maleimide double bonds and a high temperature homopolymerization of the maleimide double bonds. The network topology and the glass transition temperature changes with resin composition and curing conditions were determined using differential scanning calorimetry (DSC). An empirical model was used to relate the glass transition temperature to the extents of the amine addition and the homopolymerization reactions in 1:1 and 2:1 BMI:MDA resins. The changes in thermal properties with resin post-cure were also examined.
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  • 84
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    Polymer Engineering and Science 33 (1993), S. 640-644 
    ISSN: 0032-3888
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics , Physics
    Notes: Dynamic mechanical properties, tensile properties, and scanning electron microscopy of blends of poly(methyl methacrylate) and polycarbonate were investigated after phase separation above their cloud point temperature by annealing in a hot press. The dynamic mechanical properties show that phase separation proceeds more distinctly for the blends annealed at higher temperature and for longer time. The scanning electron micrographs show that the morphology of phase separated blends varies with the conditions of heat treatment. The tensile properties of phase separated blends deteriorate on account of the coarsening of the brittle dispersed phase over the optimum size and the occurrence of voiding during the heat treatment.
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  • 85
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    Polymer Engineering and Science 33 (1993), S. 665-674 
    ISSN: 0032-3888
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics , Physics
    Notes: The packing stage starts at the end of mold filling. During this stage, additional material is forced into the mold to compensate for the shrinkage during subse-quent cooling. Underpacking results in molded parts with dimensional variation. Overpacking causes flash at the parting lines, stick during ejection, and excess residual stresses resulting in warpage. The packing stage is thus extremely important in the determination of the final quality of the product. Despite its importance, analysis of the packing stage has been relatively ignored, particularly the viscoelastic effect. In this work, the analysis of the isothermal packing stage is presented for a Maxwell fluid. A set of governing equations is derived for a two-dimensional mold and solved using the Galerkin finite element method. In addition to the distribution of velocity and pressure, the model predicts the stresses in the planar direction, which could be used for subsequent calculation of the residual stresses.
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  • 86
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    Polymer Engineering and Science 33 (1993), S. 675-685 
    ISSN: 0032-3888
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics , Physics
    Notes: The objective this work was to determine the effects of selected polyester catalysts on the reaction of a polyester with epoxy functional polymers. Polyesters containing various catalyst metals were melt blended with either an ethylene-co-glycidyl methacrylate or a styrene-co-glycidyl methacrylate copolymer. The viscosities of the blends were monitored as a function of mixing time using torque rheometry. In addition, the molecular weight distributions of selected samples were analyzed using gel permeation chromatography. Both the torque rheometry and the gel permeation chromatography results indicate that the polyester reacts with epoxy functional polymers. This reaction occurs under conditions and at processing times which are readily obtainable in conventional melt processing equipment. Furthermore, the reaction kinetics of polyesters with glycidyl methacrylate copolymers are dramatically affected by the nature of the catalyst system used to prepare the polyester. Under the conditions used, antimony catalysts are particularly effective at promoting the reaction between polyesters and the epoxy functionality and the activity of the catalysts studied appears to decrease in the following order: antimony 〉 gallium 〉 tin ≃ titanium 〉 germanium. Manipulation of the polyester catalyst system may offer a method to control the extent of reaction obtained in reactive processing of polyesters with epoxy functional compounds.
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  • 87
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    Polymer Engineering and Science 33 (1993), S. 709-715 
    ISSN: 0032-3888
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics , Physics
    Notes: The flow kinematics of power-law fluids in fishtail dies is studied. A general isothermal three-dimensional finite element code developed by the authors is used for the flow analysis purpose. The basic geometry of the fishtail die is defined by simple super-elliptical curves, which allows a smooth transition from a circle to a slit. The three-dimensional path line and the residence time distribution (RTD) are calculated from the velocity field obtained from the finite element solution of the conservation equations. The effects of the rheological properties and the die geometry on the path line pattern and the residence time distribution are investigated. The results indicate that as both the length of the transition zone and the fishtail angle increases, the residence time distribution becomes more uniform. However, the power-law index does not affect the residence time distribution significantly.
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  • 88
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    Polymer Engineering and Science 33 (1993), S. 736-741 
    ISSN: 0032-3888
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics , Physics
    Notes: The polymers of the aromatic nitrogen compounds N-methyl-pyrrole (P-N-Me-PPY), carbazole (PCarb), and aniline (PANI) have been investigated with electro-optical and surface analytical methods. The in-situ reflection spectra indicate the formation of polarons or bipolarons during electrochemical oxidation, depending on polymer type. The absorption bands can be attributed to changes in the electronic structure with regard to the applied potential. Photocurrent spectra of P-N-Me-PPY and PCarb show a p-type semiconducting behaviour for the polymers in the reduced state. The transition to the oxidized state with quasi-metallic properties is indicated by a significant shift in the Fermi level energy and can be followed with XPS and UPS measurements.
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  • 89
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    Polymer Engineering and Science 33 (1993), S. 838-844 
    ISSN: 0032-3888
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics , Physics
    Notes: Extruded films of liquid crystalline polymer (LCP)/fluoropolymer blends were melt drawn to develop uniaxial orientation of a microfibrillar dispersed LCP phase. The anisotropy of the films increased with increasing draw and LCP content in the blend. Laminated composite plates were prepared using the extruded sheets as prepreg. The mechanical properties and coefficient of thermal expansion (CTE) of the prepreg and laminates agreed well with predictions from composite lamination theories. The potential for replacing glass fiber reinforced fluoropolymers with LCP/fluoropolymer blends in applications such as microwave circuit boards is discussed.
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  • 90
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    Polymer Engineering and Science 33 (1993) 
    ISSN: 0032-3888
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics , Physics
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  • 91
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    Polymer Engineering and Science 33 (1993), S. 865-876 
    ISSN: 0032-3888
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics , Physics
    Notes: This review presents a general picture of suspension, dispersion, and interfacial polycondensation processes employed for the preparation of beaded resins, dry powders, and high solid dispersions. The polymer systems covered include polyamides, polyesters, polycarbonates, polyurethanes, and phenol-formaldehyde and urea-formaldehyde resins. Basic features of heterogeneous polycondensation processes are outlined, and different mechanisms of particle formation in suspension, dispersion, and interfacial polycondensation are discussed. Effects of manufacturing parameters such as feed ratio, droplet/particle stabilizer, and stirrer speed on product characteristics are also briefly covered.
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  • 92
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    Polymer Engineering and Science 33 (1993), S. 781-788 
    ISSN: 0032-3888
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics , Physics
    Notes: The extrudate swell and the dynamic rheological properties of poly(butylene terephthalate) (PBT) and polyamide 6 (PA6) binary blends were investigated at 240°C. The extrudate swell of the blend varies with the viscosity ratio and composition of constituents, and it is several times larger than that of homopolymers when the viscosity ratio of constituents is around unity. The dynamic oscillatory data could be interpreted by Oldroyd's emulsion model proposed by Graebling, et al. These results suggest that the extrudate swell is caused by the shape recovery of the dispersed particles. A semi-empirical method to estimate the terminal relaxation time with experimental data was introduced, and a clear correlation between the extrudate swell and the terminal relaxation time was obtained.
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  • 93
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    Polymer Engineering and Science 33 (1993), S. 819-826 
    ISSN: 0032-3888
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics , Physics
    Notes: Much work in recent years had focused on the improvements of the impact properties of engineering thermoplastics by the addition of a low modulus modifier that contains polar moieties as a result of polymerization or that has been modified to contain polar moieties as a result of various grafting techniques. Styrenic block copolymers (styrene-ethylene/butylene-styrene) functionalized with maleic anhydride have proved useful as impact modifiers and compatibilizers in blends with engineering thermoplastics. This paper focuses on the use of these functionalized elastomers to modify nylon 6. In such compositions, a nylon material with unique mechanical performance may be achieved using the functionalized elastomer either alone or in combination with an unfunctionalized styrenic block copolymer. The optimization of performance in these rubber toughened polyamide blends using various types of styrenic block copolymers is discussed. The morphology as it pertains to performance is also reviewed. The information contained herein may prove useful in obtaining a better understanding of the mechanisms of compatibilization and modification of nylon 6 systems.
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  • 94
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    Polymer Engineering and Science 33 (1993), S. 827-837 
    ISSN: 0032-3888
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics , Physics
    Notes: Oriented blends of poly(ethylene terephthalate) (PET) and high density polyethylene (HDPE) with and without compatibilizing agent have been studied with regard to orientation temperature, stretch rate, extension ratio, mode of orientation, and blend composition. These oriented blends have been characterized using infrared spectroscopy and differential scanning calorimetry. The tensile and tensile impact properties were also investigated. The results show that blends with compatibilizer show strain hardening upon orientation, whereas the blend without compatibilizer does not strain harden upon orientation. The blends with less PET content have been difficult to orient. The morphology of these blends show fibril structure, highly oriented in the direction of stretch. Infrared measurements show that PET within the blend has undergone strain induced crystallization upon orientation. It has also been observed that the mechanical properties, such as the modulus and ultimate stress, show improvement upon orientation. Simultaneously stretched blends show better physical properties than sequentially oriented blends.
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  • 95
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    Polymer Engineering and Science 33 (1993), S. 895-900 
    ISSN: 0032-3888
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics , Physics
    Notes: This paper illustrates the factors that control brittle failure under fatigue loading for test specimens cut from medium-density polyethylene pipes for gas distribution. A square bar specimen cut from a pipe with a notch was made and a fatigue test was conducted to cause a brittle failure. To obtain the correlation among stress range, frequency, temperature, and cycles to failure in this fatigue test, Coffin-Manson's frequency-modified fatigue life equation was adopted and the material constants were determined. By gradually lowering the frequency, the resistance to creep can be estimated because cycles to failure - indicating the fatigue damage - decreased, and the actual loading time - indicating the creep damage - increased.
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  • 96
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    Polymer Engineering and Science 33 (1993), S. 923-930 
    ISSN: 0032-3888
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics , Physics
    Notes: The interfacial tension, phase morphology, and phase growth was determined for four polymer blend systems: polyethylene/polystyrene, polyethylene/polyamide-6, polystyrene/polyamide-6, and polystyrene/poly(ethylene terephthalate). Generally, high interfacial tension correlates with coarse phase morphology and rapid phase coalescence. The addition of various potential compatibilizing agents to these binary blend systems results in lowered interfacial tension, finer and stabilized phase morphologies. The characteristics of different compatibilizing agents were compared for several of the blend systems. We also look at the influences of compatibilizing agents on mechanical properties of the blend systems. Some compatibilizing agents are able to produce substantial improvements in ultimate properties.
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  • 97
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    Polymer Engineering and Science 33 (1993), S. 937-943 
    ISSN: 0032-3888
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics , Physics
    Notes: Unidirectional sheets were extruded of an in-situ composite of thermotropic liquid crystalline Vectra B950 in a matrix of polyphenylene-ether and polystyrene. Three important processing parameters were systematically varied: draw-ratio, slit opening and extruder throughput. Morphology and mechanical properties of these films were determined, and qualitatively related to the processing conditions.
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  • 98
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    Polymer Engineering and Science 33 (1993), S. 959-970 
    ISSN: 0032-3888
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics , Physics
    Notes: It is of great importance to accurately measure or predict the Residence Time Distribution (RTD) in designing extruders and/or in setting up a proper operating condition, because chemical reactions depend significantly on the RTD and temperature when chemical reactions take place during the extrusion process. A previous method to predict the RTD can analytically determine RTD, Residence Time Distribution Function f(t) and Cumulative Residence Time Distribution Function F(t), based on a simplified two-dimensional velocity field in an extruder. However, this previous method cannot accurately take into account the three-dimensional circulatory flow inside the extruder. The present paper suggests a new method to accurately determine the RTD taking into account the three-dimensional circulatory flow and presents a new formula derived to calculate f(t). In order to demonstrate the applicability of the new method including the circulatory flow effect, RTD, f(t) and F(t) were calculated based on a three-dimensional velocity field obtained via a quasi-three-dimensional finite element analysis. It was found that the previous method has a tendency to underestimate the RTD, owing to the neglect of the three-dimensional circulatory flow in comparison with the new method.
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  • 99
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    Polymer Engineering and Science 33 (1993), S. 980-988 
    ISSN: 0032-3888
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics , Physics
    Notes: Experimental data confirm the utility of the following simple equation in predicting the spin coating behavior of polyimide precursor solutions: \documentclass{article}\pagestyle{empty}\begin{document}$$ {\rm h} = {\rm c\beta }_{\rm 0} {\rm k}^{{\rm \beta }_{\rm 1} } {\rm \omega }^{{\rm \beta }_{\rm 2} } {\rm t}^{{\rm \beta }_{\rm 3} } \quad\quad\quad\quad{\rm (1)} $$\end{document} in which \documentclass{article}\pagestyle{empty}\begin{document}$$ \begin{array}{*{20}c} {c = {\rm polymer\, solution\, solid\, weight\, fraction;}} \\ {\beta _i = {\rm fitted\, coefficient\, (Greek\, letter\, beta)};} \\ \quad{h = {\rm film\, thickness\, after\, cure\, or\, solvent\, removal};} \\ \quad{k = {\rm polymer\, solution\, kinematic\, viscosity, centistokes};} \\ {t = {\rm time},{\rm and;}} \\ \quad{\omega = {\rm wafer\, spin\, speed, rpm (Greek\, letter\, omega)}.} \\ \end{array} $$\end{document}.
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  • 100
    ISSN: 0032-3888
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics , Physics
    Notes: Ternary systems consisting of polypropylene (PP), ethylene-propylene-dieneterpolymer (EPDM) and different types of inorganic fillers (kaolin, BaSO4) have been investigated with respect to their mechanical behavior. On the basis of an Interphase model, it was possible using the modified van der Poel equation to describe the temperature dependence of the storage modulus G′(T) and the loss modulus G″(T). The interphase properties G′(T) and G″(T) could be calculated.
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