ISSN:
1612-1112
Keywords:
Gas chromatography
;
Stationary phases
;
Porous polymer beads
;
Polarity
;
Adsorbents
;
Breakthrough volume
Source:
Springer Online Journal Archives 1860-2000
Topics:
Chemistry and Pharmacology
Notes:
Summary The breakthrough volume of ådsorbent traps made with porous polymer beads Porapak N, P. Q, R, S was evaluated by analysis of polarity reference substances proposed by Rohrschneider (ethanol, methyl ethyl ketone, nitrometane, benzene, pyridine) by McReynolds (butanol, methyl propyl ketone) and of the first term of some homologous series: alcohols, aldehides, carboxilic acids, nitrocompounds, iodoalkanes and nitriles. Adjusted retention times of the compounds were measured at 200°C and correlated with the physical properties and with polarity class according to Ewell. Trapping efficiency of the various Porapak types was evaluated and the theoretical breakthrough volumes at 25°C was calculated for the used test substances.
Type of Medium:
Electronic Resource
URL:
http://dx.doi.org/10.1007/BF02311410
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