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  • Chemistry  (7,254)
  • ASTROPHYSICS  (709)
  • AERODYNAMICS  (569)
  • ddc:330
  • 2015-2019
  • 1985-1989  (8,532)
  • 1950-1954
  • 1985  (8,532)
Collection
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  • 2015-2019
  • 1985-1989  (8,532)
  • 1950-1954
Year
  • 1
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    Bond order and charge localization in nucleoside phosphorothioates (1985)
    American Association for the Advancement of Science (AAAS)
    Details
    Publication Date: 1985-05-03
    Description: In the recent literature on nucleoside phosphorothioate anions the structural formulas show a double bond between phosphorus and sulfur and a single bond between phosphorus and oxygen with a negative charge localized on oxygen. However, a review of physical data on these compounds shows the reverse to be the case; that is, in phosphorothioate anions the P-S bond is a single bond with a negative charge localized on sulfur, while the P-O bond order for exocyclic and nonbridging oxygens is greater than 1, approaching 2 in O-alkyl phosphorothioate monoanions and O,O-dialkyl phosphorothioates. The P-O bond orders in phosphorothioate dianions and trianions approach 1 1/2 and 1 1/3, respectively, owing to delocalization of negative charge among two or three oxygens. These conclusions are based on bond lengths obtained from x-ray crystallographic data and electron diffraction, the magnitudes of the effects of 18O on the 31P-nuclear magnetic resonance chemical shifts of phosphorus in nucleoside [18O]phosphorothioates, the pH-dependence of 17O-NMR chemical shifts in [17O]phosphate and [17O]thiophosphate, the vibrational spectra of thiophosphate di- and trianions, and the pKa (dissociation constant) values for phosphoric and thiophosphoric acids.〈br /〉〈span class="detail_caption"〉Notes: 〈/span〉Frey, P A -- Sammons, R D -- GM30480/GM/NIGMS NIH HHS/ -- New York, N.Y. -- Science. 1985 May 3;228(4699):541-5.〈br /〉〈span class="detail_caption"〉Record origin:〈/span〉 〈a href="http://www.ncbi.nlm.nih.gov/pubmed/2984773" target="_blank"〉PubMed〈/a〉
    Keywords: Chemical Phenomena ; Chemistry ; Chemistry, Physical ; Cyclic AMP/metabolism ; Magnetic Resonance Spectroscopy ; Phosphates/metabolism ; Phosphoric Acids/metabolism ; Physicochemical Phenomena ; *Thionucleotides/metabolism
    Print ISSN: 0036-8075
    Electronic ISSN: 1095-9203
    Topics: Biology , Chemistry and Pharmacology , Computer Science , Medicine , Natural Sciences in General , Physics
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  • 2
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    Dissociation of antitumor potency from anthracycline cardiotoxicity in a doxorubicin analog (1985)
    American Association for the Advancement of Science (AAAS)
    Details
    Publication Date: 1985-06-28
    Description: The search for new congeners of the leading anticancer drug doxorubicin has led to an analog that is approximately 1000 times more potent, noncardiotoxic at therapeutic dose levels, and non-cross-resistant with doxorubicin. The new anthracycline, 3'-deamino-3'-(3-cyano-4-morpholinyl)doxorubicin (MRA-CN), is produced by incorporation of the 3' amino group of doxorubicin in a new cyanomorpholinyl ring. The marked increase in potency was observed against human ovarian and breast carcinomas in vitro; it was not accompanied by an increase in cardiotoxicity in fetal mouse heart cultures. Doxorubicin and MRA-CN both produced typical cardiac ultrastructural and biochemical changes, but at equimolar concentrations. In addition, MRA-CN was not cross-resistant with doxorubicin in a variant of the human sarcoma cell line MES-SA selected for resistance to doxorubicin. Thus antitumor efficacy was dissociated from both cardiotoxicity and cross-resistance by this modification of anthracycline structure.〈br /〉〈span class="detail_caption"〉Notes: 〈/span〉Sikic, B I -- Ehsan, M N -- Harker, W G -- Friend, N F -- Brown, B W -- Newman, R A -- Hacker, M P -- Acton, E M -- CA 24543/CA/NCI NIH HHS/ -- CA 32250/CA/NCI NIH HHS/ -- CA 33303/CA/NCI NIH HHS/ -- New York, N.Y. -- Science. 1985 Jun 28;228(4707):1544-6.〈br /〉〈span class="detail_caption"〉Record origin:〈/span〉 〈a href="http://www.ncbi.nlm.nih.gov/pubmed/4012308" target="_blank"〉PubMed〈/a〉
    Keywords: Animals ; *Antineoplastic Agents ; Breast Neoplasms/drug therapy ; Cell Line ; Chemical Phenomena ; Chemistry ; Dose-Response Relationship, Drug ; Doxorubicin/adverse effects/*analogs & derivatives/therapeutic use ; Female ; Heart/drug effects ; Humans ; Isoenzymes ; L-Lactate Dehydrogenase/analysis ; Mice ; Myocardium/enzymology ; Ovarian Neoplasms/drug therapy ; Pregnancy
    Print ISSN: 0036-8075
    Electronic ISSN: 1095-9203
    Topics: Biology , Chemistry and Pharmacology , Computer Science , Medicine , Natural Sciences in General , Physics
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  • 3
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    A potent nonpeptide cholecystokinin antagonist selective for peripheral tissues isolated from Aspergillus alliaceus (1985)
    American Association for the Advancement of Science (AAAS)
    Details
    Publication Date: 1985-10-11
    Description: A new, competitive, nonpeptide cholecystokinin (CCK) antagonist, asperlicin, was isolated from the fungus Aspergillus alliaceus. The compound has 300 to 400 times the affinity for pancreatic, ileal, and gallbladder CCK receptors than proglumide, a standard agent of this class. Moreover, asperlicin is highly selective for peripheral CCK receptors relative to brain CCK and gastrin receptors. Since asperlicin also exhibits long-lasting CCK antagonist activity in vivo, it should provide a valuable tool for investigating the physiological and pharmacological actions of CCK.〈br /〉〈span class="detail_caption"〉Notes: 〈/span〉Chang, R S -- Lotti, V J -- Monaghan, R L -- Birnbaum, J -- Stapley, E O -- Goetz, M A -- Albers-Schonberg, G -- Patchett, A A -- Liesch, J M -- Hensens, O D -- New York, N.Y. -- Science. 1985 Oct 11;230(4722):177-9.〈br /〉〈span class="detail_caption"〉Record origin:〈/span〉 〈a href="http://www.ncbi.nlm.nih.gov/pubmed/2994227" target="_blank"〉PubMed〈/a〉
    Keywords: Animals ; Aspergillus/*metabolism ; Benzodiazepinones/*isolation & purification/pharmacology ; Chemical Phenomena ; Chemistry ; Cholecystokinin/*antagonists & inhibitors/pharmacology/physiology ; Dose-Response Relationship, Drug ; Gallbladder/drug effects ; Guinea Pigs ; Ileum/drug effects ; Pancreas/drug effects ; Rats ; Receptors, Cell Surface/drug effects ; Receptors, Cholecystokinin
    Print ISSN: 0036-8075
    Electronic ISSN: 1095-9203
    Topics: Biology , Chemistry and Pharmacology , Computer Science , Medicine , Natural Sciences in General , Physics
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  • 4
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    Three-dimensional structure of poliovirus at 2.9 A resolution (1985)
    American Association for the Advancement of Science (AAAS)
    Details
    Publication Date: 1985-09-27
    Description: The three-dimensional structure of poliovirus has been determined at 2.9 A resolution by x-ray crystallographic methods. Each of the three major capsid proteins (VP1, VP2, and VP3) contains a "core" consisting of an eight-stranded antiparallel beta barrel with two flanking helices. The arrangement of beta strands and helices is structurally similar and topologically identical to the folding pattern of the capsid proteins of several icosahedral plant viruses. In each of the major capsid proteins, the "connecting loops" and NH2- and COOH-terminal extensions are structurally dissimilar. The packing of the subunit "cores" to form the virion shell is reminiscent of the packing in the T = 3 plant viruses, but is significantly different in detail. Differences in the orientations of the subunits cause dissimilar contacts at protein-protein interfaces, and are also responsible for two major surface features of the poliovirion: prominent peaks at the fivefold and threefold axes of the particle. The positions and interactions of the NH2- and COOH-terminal strands of the capsid proteins have important implications for virion assembly. Several of the "connecting loops" and COOH-terminal strands form prominent radial projections which are the antigenic sites of the virion.〈br /〉〈span class="detail_caption"〉Notes: 〈/span〉Hogle, J M -- Chow, M -- Filman, D J -- AI-20566/AI/NIAID NIH HHS/ -- AI-22346/AI/NIAID NIH HHS/ -- NS-07078/NS/NINDS NIH HHS/ -- R01 AI020566/AI/NIAID NIH HHS/ -- etc. -- New York, N.Y. -- Science. 1985 Sep 27;229(4720):1358-65.〈br /〉〈span class="detail_caption"〉Record origin:〈/span〉 〈a href="http://www.ncbi.nlm.nih.gov/pubmed/2994218" target="_blank"〉PubMed〈/a〉
    Keywords: Amino Acid Sequence ; Antigens, Viral/immunology ; Capsid/physiology ; Chemical Phenomena ; Chemistry ; HeLa Cells/microbiology ; Mutation ; Poliovirus/physiology/*ultrastructure ; Protein Conformation ; Virus Replication ; X-Ray Diffraction
    Print ISSN: 0036-8075
    Electronic ISSN: 1095-9203
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  • 5
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    Qinghaosu (artemisinin): an antimalarial drug from China (1985)
    American Association for the Advancement of Science (AAAS)
    Details
    Publication Date: 1985-05-31
    Description: The herb Artemisia annua has been used for many centuries in Chinese traditional medicine as a treatment for fever and malaria. In 1971, Chinese chemists isolated from the leafy portions of the plant the substance responsible for its reputed medicinal action. This compound, called qinghaosu (QHS, artemisinin), is a sesquiterpene lactone that bears a peroxide grouping and, unlike most other antimalarials, lacks a nitrogen-containing heterocyclic ring system. The compound has been used successfully in several thousand malaria patients in China, including those with both chloroquine-sensitive and chloroquine-resistant strains of Plasmodium falciparum. Derivatives of QHS, such as dihydroqinghaosu, artemether, and the water-soluble sodium artesunate, appear to be more potent than QHS itself. Sodium artesunate acts rapidly in restoring to consciousness comatose patients with cerebral malaria. Thus QHS and its derivatives offer promise as a totally new class of antimalarials.〈br /〉〈span class="detail_caption"〉Notes: 〈/span〉Klayman, D L -- New York, N.Y. -- Science. 1985 May 31;228(4703):1049-55.〈br /〉〈span class="detail_caption"〉Record origin:〈/span〉 〈a href="http://www.ncbi.nlm.nih.gov/pubmed/3887571" target="_blank"〉PubMed〈/a〉
    Keywords: Animals ; *Antimalarials ; *Artemisinins ; Brain Diseases/therapy ; Chemical Phenomena ; Chemistry ; Humans ; Liver/metabolism ; Malaria/*drug therapy ; Medicine, Chinese Traditional ; Metabolic Clearance Rate ; Plants, Medicinal/analysis ; Plasmodium berghei ; Plasmodium falciparum ; *Sesquiterpenes/isolation & purification/metabolism/therapeutic use/toxicity
    Print ISSN: 0036-8075
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  • 6
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    Sculpting horizons in organic chemistry (1985)
    American Association for the Advancement of Science (AAAS)
    Details
    Publication Date: 1985-02-22
    Description: Organic chemistry as a discipline derives from and impacts on the biological and abiological world in which we live. Its challenges lie in the areas of structure, reactivity, techniques, and concepts. Powerful structural tools reveal structures from biology that range from control of insect development and behavior to whole new metabolic pathways in humans. Unnatural products create beautiful new molecular shapes whose properties cannot be predicted as well as catalysts that function with enzyme-like control. From structure flows reactivity. Exploration of known reactions points to new directions, and development of new reactions offers the opportunity of streamlined synthetic design. Emerging new techniques offer new dimensions for performing and studying reactions as well as the hope for developing new ones. Merging disparate facts into unified concepts increases predictive capabilities. The extraordinary difficulty of finding the resultant of many small effects may obscure the presence of general theories, creates the art in the practice of the science, and challenges the practitioner. From these general themes derives the quest for selectivity--chemo-, regio-, diastereo-, and enantio-. An examination of the fundamental underpinnings of the applications of organic chemistry reveals that, while impressive strides have been made, the science is best described as being between infancy and childhood. The cross-fertilization between organic chemistry and molecular biology vividly illustrates a merging of chemistry and biology.〈br /〉〈span class="detail_caption"〉Notes: 〈/span〉Trost, B M -- New York, N.Y. -- Science. 1985 Feb 22;227(4689):908-16.〈br /〉〈span class="detail_caption"〉Record origin:〈/span〉 〈a href="http://www.ncbi.nlm.nih.gov/pubmed/3969569" target="_blank"〉PubMed〈/a〉
    Keywords: Alkylation ; Animals ; Chemical Phenomena ; Chemistry ; *Chemistry, Organic ; Enzymes ; Humans ; Insects ; Mammals ; Organic Chemistry Phenomena ; Research ; Stereoisomerism
    Print ISSN: 0036-8075
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  • 7
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    Hernandulcin: an intensely sweet compound discovered by review of ancient literature (1985)
    American Association for the Advancement of Science (AAAS)
    Details
    Publication Date: 1985-01-25
    Description: Ancient Mexican botanical literature was systematically searched for new plant sources of intensely sweet substances. Lippia dulcis Trev., a sweet plant, emerged as a candidate for fractionation studies, and hernandulcin, a sesquiterpene, was isolated and judged by a human taste panel as more than 1000 times sweeter than sucrose. The structure of the sesquiterpene was determined spectroscopically and confirmed by chemical synthesis. Hernandulcin was nontoxic when administered orally to mice, and it did not induce bacterial mutation.〈br /〉〈span class="detail_caption"〉Notes: 〈/span〉Compadre, C M -- Pezzuto, J M -- Kinghorn, A D -- Kamath, S K -- N01-DE-02425/DE/NIDCR NIH HHS/ -- New York, N.Y. -- Science. 1985 Jan 25;227(4685):417-9.〈br /〉〈span class="detail_caption"〉Record origin:〈/span〉 〈a href="http://www.ncbi.nlm.nih.gov/pubmed/3880922" target="_blank"〉PubMed〈/a〉
    Keywords: Animals ; Bibliography as Topic ; Botany/history ; Chemistry ; History, 16th Century ; Humans ; Magnetic Resonance Spectroscopy ; Mexico ; Mice ; Molecular Conformation ; Mutagenicity Tests ; *Plants/analysis ; *Sesquiterpenes/chemical synthesis/isolation & purification/toxicity ; *Sweetening Agents/chemical synthesis/history/isolation & purification/toxicity
    Print ISSN: 0036-8075
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    Topics: Biology , Chemistry and Pharmacology , Computer Science , Medicine , Natural Sciences in General , Physics
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  • 8
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    Computer-assisted analysis in organic synthesis (1985)
    American Association for the Advancement of Science (AAAS)
    Details
    Publication Date: 1985-04-26
    Description: The planning of alternative routes for the synthesis of complex organic molecules has been facilitated by the formulation of guiding strategies that can be applied to a broad range of problems. Analysis of organic synthesis can be carried out in the retrosynthetic direction, opposite to the actual process of chemical synthesis, or bidirectionally, that is, as a combined retrosynthetic and synthetic search. An interactive computer program is described which utilizes the general strategies of retrosynthetic analysis and an appropriate database to generate pathways of chemical intermediates for chemical synthesis of a particular target structure. Computer graphics and standard chemical structures are used for man-machine communication.〈br /〉〈span class="detail_caption"〉Notes: 〈/span〉Corey, E J -- Long, A K -- Rubenstein, S D -- New York, N.Y. -- Science. 1985 Apr 26;228(4698):408-18.〈br /〉〈span class="detail_caption"〉Record origin:〈/span〉 〈a href="http://www.ncbi.nlm.nih.gov/pubmed/3838594" target="_blank"〉PubMed〈/a〉
    Keywords: Chemical Phenomena ; Chemistry ; Chemistry, Organic/*methods ; *Computers ; Forecasting ; Software
    Print ISSN: 0036-8075
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  • 9
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    Dynamics and conformational energetics of a peptide hormone: vasopressin (1985)
    American Association for the Advancement of Science (AAAS)
    Details
    Publication Date: 1985-03-15
    Description: A theoretical methodology for use in conjunction with experiment was applied to the neurohypophyseal hormone lysine vasopressin for elucidation of its accessible molecular conformations and associated flexibility, conformational transitions, and dynamics. Molecular dynamics and energy minimization techniques make possible a description of the conformational properties of a peptide in terms of the precise positions of atoms, their fluctuations in time, and the interatomic forces acting on them. Analysis of the dynamic trajectory of lysine vasopressin shows the ability of a flexible peptide hormone to undergo spontaneous conformational transitions. The excursions of an individual phenylalanine residue exemplify the dynamic flexibility and multiple conformational states available to small peptide hormones and their component residues, even within constraints imposed by a cyclic hexapeptide ring.〈br /〉〈span class="detail_caption"〉Notes: 〈/span〉Hagler, A T -- Osguthorpe, D J -- Dauber-Osguthorpe, P -- Hempel, J C -- New York, N.Y. -- Science. 1985 Mar 15;227(4692):1309-15.〈br /〉〈span class="detail_caption"〉Record origin:〈/span〉 〈a href="http://www.ncbi.nlm.nih.gov/pubmed/3975616" target="_blank"〉PubMed〈/a〉
    Keywords: Chemical Phenomena ; Chemistry ; Chemistry, Physical ; Energy Metabolism ; Hydrogen Bonding ; Lypressin/*metabolism ; Phenylalanine/metabolism ; Physicochemical Phenomena ; Protein Conformation
    Print ISSN: 0036-8075
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  • 10
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    Single-carbon chemistry of acetogenic and methanogenic bacteria (1985)
    American Association for the Advancement of Science (AAAS)
    Details
    Publication Date: 1985-03-08
    Description: Methanogenic and acetogenic bacteria metabolize carbon monoxide, methanol, formate, hydrogen and carbon dioxide gases and, in the case of certain methanogens, acetate, by single-carbon (C1) biochemical mechanisms. Many of these reactions occur while the C1 compounds are linked to pteridine derivatives and tetrapyrrole coenzymes, including corrinoids, which are used to generate, reduce, or carbonylate methyl groups. Several metalloenzymes, including a nickel-containing carbon monoxide dehydrogenase, are used in both catabolic and anabolic oxidoreductase reactions. We propose biochemical models for coupling carbon and electron flow to energy conservation during growth on C1 compounds based on the carbon flow pathways inherent to acetogenic and methanogenic metabolism. Biological catalysts are therefore available which are comparable to those currently in use in the Monsanto process. The potentials and limitations of developing biotechnology based on these organisms or their enzymes and coenzymes are discussed.〈br /〉〈span class="detail_caption"〉Notes: 〈/span〉Zeikus, J G -- Kerby, R -- Krzycki, J A -- 144-T263/PHS HHS/ -- New York, N.Y. -- Science. 1985 Mar 8;227(4691):1167-73.〈br /〉〈span class="detail_caption"〉Record origin:〈/span〉 〈a href="http://www.ncbi.nlm.nih.gov/pubmed/3919443" target="_blank"〉PubMed〈/a〉
    Keywords: Acetates/*metabolism ; Acetobacter/metabolism ; Bacteria/*metabolism ; Carbon Dioxide/metabolism ; Carbon Monoxide/metabolism ; Chemical Phenomena ; Chemistry ; Clostridium/metabolism ; Eubacterium/metabolism ; Euryarchaeota/*metabolism ; Formates/metabolism ; Methane/metabolism ; Methanol/metabolism
    Print ISSN: 0036-8075
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  • 11
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    Trypanothione: a novel bis(glutathionyl)spermidine cofactor for glutathione reductase in trypanosomatids (1985)
    American Association for the Advancement of Science (AAAS)
    Details
    Publication Date: 1985-03-22
    Description: Glutathione reductase from trypanosomes and leishmanias, unlike glutathione reductase from other organisms, requires an unusual low molecular weight cofactor for activity. The cofactor was purified from the insect trypanosomatid Crithidia fasciculata and identified as a novel glutathione-spermidine conjugate, N1,N8-bis(L-gamma-glutamyl-L-hemicystinyl-glycyl)spermidine, for which the trivial name trypanothione is proposed. This discovery may open a new chemotherapeutic approach to trypanosomiasis and leishmaniasis.〈br /〉〈span class="detail_caption"〉Notes: 〈/span〉Fairlamb, A H -- Blackburn, P -- Ulrich, P -- Chait, B T -- Cerami, A -- 1 R01 A127429/PHS HHS/ -- 1 R01 AI19428/AI/NIAID NIH HHS/ -- New York, N.Y. -- Science. 1985 Mar 22;227(4693):1485-7.〈br /〉〈span class="detail_caption"〉Record origin:〈/span〉 〈a href="http://www.ncbi.nlm.nih.gov/pubmed/3883489" target="_blank"〉PubMed〈/a〉
    Keywords: Animals ; Chemical Phenomena ; Chemistry ; Coenzymes/analysis/*isolation & purification/metabolism ; Crithidia/*enzymology ; Glutathione/*analogs & derivatives/analysis/isolation & purification/metabolism ; Glutathione Reductase/*metabolism ; Leishmania/*enzymology ; Oxidation-Reduction ; Spermidine/*analogs & derivatives/analysis/isolation & purification/metabolism ; Terminology as Topic ; Trypanosoma/*enzymology ; Trypanosoma brucei brucei/enzymology ; Trypanosoma cruzi/enzymology
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  • 12
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    Mechanisms of coenzyme B12-dependent rearrangements (1985)
    American Association for the Advancement of Science (AAAS)
    Details
    Publication Date: 1985-02-22
    Description: Coenzyme B12 serves as a cofactor in various enzymatic reactions in which a hydrogen atom is interchanged with a substituent on an adjacent carbon atom. Measurement of the dissociation energy of the coenzyme's cobalt-carbon bond and studies of the rearrangement of model free radicals related to those derived from methylmalonyl-coenzyme A suggest that these enzymatic reactions occur through homolytic dissociation of the coenzyme's cobalt-carbon bond, abstraction of a hydrogen atom from the substrate by the coenzyme-derived 5'-deoxyadenosyl radical, and rearrangement of the resulting substrate radical. The only role thus far identified for coenzyme B12 in these reactions--namely, that of a free radical precursor--reflects the weakness, and facile dissociation, of the cobalt-carbon bond.〈br /〉〈span class="detail_caption"〉Notes: 〈/span〉Halpern, J -- New York, N.Y. -- Science. 1985 Feb 22;227(4689):869-75.〈br /〉〈span class="detail_caption"〉Record origin:〈/span〉 〈a href="http://www.ncbi.nlm.nih.gov/pubmed/2857503" target="_blank"〉PubMed〈/a〉
    Keywords: Carbon/metabolism ; Chemical Phenomena ; Chemistry ; Chemistry, Physical ; Cobalt/metabolism ; Cobamides/*metabolism ; Energy Metabolism ; Free Radicals ; Methylmalonyl-CoA Mutase/metabolism ; Physicochemical Phenomena
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  • 13
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    The structure of arthropod hemocyanins (1985)
    American Association for the Advancement of Science (AAAS)
    Details
    Publication Date: 1985-08-09
    Description: Hemocyanins are large multi-subunit copper proteins that transport oxygen in many arthropods and molluscs. Comparison of the amino acid sequence data for seven different subunits of arthropod hemocyanins from crustaceans and chelicerates shows many highly conserved residues and extensive regions of near identity. This correspondence can be matched closely with the three domain structure established by x-ray crystallography for spiny lobster hemocyanin. The degree of identity is particularly striking in the second domain of the subunit that contains the six histidines which ligate the two oxygen-binding copper atoms. The polypeptide architecture of spiny lobster hemocyanin appears to be the same in all arthropods. This structure must therefore be at least as old as the estimated time of divergence of crustaceans and chelicerates, about 540 to 600 million years ago.〈br /〉〈span class="detail_caption"〉Notes: 〈/span〉Linzen, B -- Soeter, N M -- Riggs, A F -- Schneider, H J -- Schartau, W -- Moore, M D -- Yokota, E -- Behrens, P Q -- Nakashima, H -- Takagi, T -- GM 21314/GM/NIGMS NIH HHS/ -- GM 28410/GM/NIGMS NIH HHS/ -- New York, N.Y. -- Science. 1985 Aug 9;229(4713):519-24.〈br /〉〈span class="detail_caption"〉Record origin:〈/span〉 〈a href="http://www.ncbi.nlm.nih.gov/pubmed/4023698" target="_blank"〉PubMed〈/a〉
    Keywords: Amino Acid Sequence ; Animals ; Arachnida/genetics ; *Arthropods/genetics ; Binding Sites ; Biological Evolution ; Chemical Phenomena ; Chemistry ; Copper ; Crustacea/genetics ; *Hemocyanin/genetics ; Models, Molecular ; Protein Conformation ; Species Specificity
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  • 14
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    [2 + 2] photocycloadditions in the synthesis of chiral molecules (1985)
    American Association for the Advancement of Science (AAAS)
    Details
    Publication Date: 1985-02-22
    Description: A strategy for the synthesis of chiral molecules that receives growing popularity among organic chemists employs the photochemically mediated [2 + 2] cycloaddition reaction. These reactions can be performed on a multigram scale and often proceed with high yield and with stereocontrol. These features, in combination with the useful properties of the four-membered ring photoproducts in subsequent chemical transformations, make them attractive options in the early stage of a synthesis design. Various combinations of unsaturated functional groups can participate in this reaction process. Accordingly, these chemical reactions can be economical solutions to problems relating to the synthesis of a variety of target molecules.〈br /〉〈span class="detail_caption"〉Notes: 〈/span〉Schreiber, S L -- GM-32527/GM/NIGMS NIH HHS/ -- New York, N.Y. -- Science. 1985 Feb 22;227(4689):857-63.〈br /〉〈span class="detail_caption"〉Record origin:〈/span〉 〈a href="http://www.ncbi.nlm.nih.gov/pubmed/4038558" target="_blank"〉PubMed〈/a〉
    Keywords: Animals ; Anti-Bacterial Agents/chemical synthesis ; Antifungal Agents/chemical synthesis ; Chemical Phenomena ; Chemistry ; Cockroaches ; Female ; Furans/chemical synthesis ; Lactones/chemical synthesis ; Male ; Mycotoxins/chemical synthesis ; *Photochemistry ; Pyrones/chemical synthesis ; Sex Attractants/chemical synthesis/isolation & purification ; Stereoisomerism
    Print ISSN: 0036-8075
    Electronic ISSN: 1095-9203
    Topics: Biology , Chemistry and Pharmacology , Computer Science , Medicine , Natural Sciences in General , Physics
    Published by American Association for the Advancement of Science (AAAS)
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  • 15
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    Computerized pattern recognition: a new technique for the analysis of chemical communication (1985)
    American Association for the Advancement of Science (AAAS)
    Details
    Publication Date: 1985-04-12
    Description: Computerized pattern recognition techniques can be applied to the study of complex chemical communication systems. Analysis of high resolution gas chromatographic concentration patterns of the major volatile components of the scent marks of a South American primate, Saguinus fuscicollis, demonstrates that the concentration patterns can be used to predict the gender and subspecies of unknown donors.〈br /〉〈span class="detail_caption"〉Notes: 〈/span〉Smith, A B 3rd -- Belcher, A M -- Epple, G -- Jurs, P C -- Lavine, B -- 5 T32 NSO7176-03/NS/NINDS NIH HHS/ -- New York, N.Y. -- Science. 1985 Apr 12;228(4696):175-7.〈br /〉〈span class="detail_caption"〉Record origin:〈/span〉 〈a href="http://www.ncbi.nlm.nih.gov/pubmed/3975636" target="_blank"〉PubMed〈/a〉
    Keywords: Animals ; Chemical Phenomena ; Chemistry ; Chromatography, Gas ; *Computers ; Female ; Male ; *Pattern Recognition, Automated ; Pheromones/*physiology ; Saguinus/physiology ; Scent Glands/physiology ; Sex Attractants/*physiology ; Structure-Activity Relationship
    Print ISSN: 0036-8075
    Electronic ISSN: 1095-9203
    Topics: Biology , Chemistry and Pharmacology , Computer Science , Medicine , Natural Sciences in General , Physics
    Published by American Association for the Advancement of Science (AAAS)
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  • 16
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    Interplanetary shock phenomena beyond 1 AU (1985)
    In:  Other Sources
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    Publication Date: 2011-08-19
    Description: Attention is given to spatial dependences exhibited by spacecraft measurements obtained between 1 and 30 AU, together with temporal variations occurring between solar activity cycle maxima and minima. At 1-3 AU radial distances, shocks develop in association with the corotating solar wind streams characterizing solar minimum and accelerate solar wind evolution with distance while heating the solar wind and generating waves and turbulence. At solar maximum, shocks are observed more frequently at 1 AU but still in association with transient solar events; acceleration leading to energetic storm particles is observed both within and beyond 1 AU. The superimposed effect of large numbers of intense shocks may be responsible for the solar cycle modulation of galactic cosmic rays.
    Keywords: ASTROPHYSICS
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  • 17
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    Steady and unsteady incompressible free-wake analysis (1985)
    In:  Other Sources
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    Publication Date: 2011-08-19
    Description: The flows around highly sweptback wings and bodies of revolution at high angle of attack are described, and inviscid model approximations and mathematical formulation of the problem are given to steady and unsteady incompressible flows. A general presentation of the methods of solution is given, with emphasis on current computational techniques. Detailed descriptions of the nonlinear vortex-lattice and vortex-panel techniques are presented to show how the boundary conditions are enforced using iteration. Typical numerical results are compared with the available experimental data.
    Keywords: AERODYNAMICS
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  • 18
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    Finite difference methods for the solution of unsteady potential flows (1985)
    In:  Other Sources
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    Publication Date: 2011-08-19
    Description: A brief review is presented of various problems which are confronted in the development of an unsteady finite difference potential code. This review is conducted mainly in the context of what is done for a typical small disturbance and full potential methods. The issues discussed include choice of equation, linearization and conservation, differencing schemes, and algorithm development. A number of applications including unsteady three-dimensional rotor calculation, are demonstrated.
    Keywords: AERODYNAMICS
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  • 19
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    Unsteady transonic flows - Introduction, current trends, applications (1985)
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    Publication Date: 2011-08-19
    Description: The computational treatment of unsteady transonic flows is discussed, reviewing the historical development and current techniques. The fundamental physical principles are outlined; the governing equations are introduced; three-dimensional linearized and two-dimensional linear-perturbation theories in frequency domain are described in detail; and consideration is given to frequency-domain FEMs and time-domain finite-difference and integral-equation methods. Extensive graphs and diagrams are included.
    Keywords: AERODYNAMICS
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  • 20
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    Unsteady subsonic and supersonic flows - Historical review; state of the art (1985)
    In:  Other Sources
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    Publication Date: 2011-08-19
    Description: This lecture is introductory to the subject of unsteady subsonic and supersonic flows. The primary objective is to present fundamental concepts in order to promote an understanding of the relations between the basic physical problems and their mathematical formulation as well as to establish a common foundation for the more detailed presentations of subsequent lectures in this session. Linearized (small-perturbation) potential flow is emphasized, although needs beyond that limit are indicated. The basic equations, concepts, and procedures common to all the methods are reviewed first, followed by the development, discussion, and status of methods for creating two-dimensional incompressible flow, strip theory, subsonic lifting-surface theory, subsonic/supersonic surface-panel methods, and supersonic lifting-surface theory.
    Keywords: AERODYNAMICS
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  • 21
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    Nucleus studies of Comet Halley (1985)
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    Publication Date: 2011-08-19
    Description: Early results from, and research initiatives warranted by, the earth-based observations of Halley's near-nucleus and related phenomena are reviewed. Where appropriate, this information is combined with spacecraft data obtained by the various flight projects. The basic objective is to gain a greater insight into the nature of the comet's nucleus and its environment.
    Keywords: ASTROPHYSICS
    Type: Advances in Space Research (ISSN 0273-1177); 5; 12, 1; 307-316
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  • 22
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    Preliminary results of the Giotto radio science experiment (1985)
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    Publication Date: 2011-08-19
    Description: Doppler and ranging measurements using the radio signal of the Giotto spacecraft were taken before, during, and after the encounter with Comet Halley on Mar. 13, 14, 1986. The spacecraft velocity was found to decrease by a total of 23.3 cm/s due to impacting gas and (primarily) dust in the cometary atmosphere. A preliminary dust production rate of 1000 kg/s is found to be consistent with this deceleration. Power spectra of the carrier phase fluctuations reveal an increase in level and a flattening of the spectrum just prior to encounter, presumably associated with the enhanced dust impact rate. Finally, simulated Doppler time profiles are computed using the radial dependence of plasma density observed by the Giotto in situ investigations. It is shown that the cometary electron content profile would have been clearly seen if a dual-frequency downlink radio configuration had been available at encounter.
    Keywords: ASTROPHYSICS
    Type: Advances in Space Research (ISSN 0273-1177); 5; 12, 1
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  • 23
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    A preliminary look at the dust in Comet Halley (1985)
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    Publication Date: 2011-08-19
    Description: Highlights of infrared observations of the dust are discussed and compared with first results from the space probes. An emission feature was detected at 3.4 microns; the 10 and 20 micron silicate features were well-observed; and far-infrared data out to 160 micron were obtained. Organic material seems to be abundant in grains and may explain the 3.4 micron emission. Calculations are presented for one example of organic material. A component of the grains may volatize at temperatures around 300 K.
    Keywords: ASTROPHYSICS
    Type: Advances in Space Research (ISSN 0273-1177); 5; 12, 1; 325-334
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  • 24
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    Cometary kilometric radio waves and plasma waves correlated with ion pick-up effect at Comet Halley (1985)
    In:  Other Sources
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    Publication Date: 2011-08-19
    Description: Bow-shock movements at Comet Halley are inferred from the discrete spectra of the cometary kilometric radiation (30-195 kHz); the observed emissions can be interpreted as being generated and propagating from the moving shock. The shock motion is possibly associated with the time variation of the solar wind and cometary outgassing. It is concluded that these plasma wave phenomena are manifestations of ion pick-up processes, which occur even in a remote region 7 million to 10 million km from the cometary nucleus.
    Keywords: ASTROPHYSICS
    Type: Advances in Space Research (ISSN 0273-1177); 5; 12, 1; 83-88
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  • 25
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    Overview of helicopter wake and airloads technology (1985)
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    Publication Date: 2011-08-19
    Description: An overview of helicopter aerodynamics technology is presented with emphasis on rotor wake and airloads methodology developed at the United Technologies Research Center (UTRC). The evolution over the past twenty years of various levels of computerized wake geometry models at UTRC, such as undistorted wake, prescribed empirical wake, predicted distorted wake, and generalized wake models for the hover and forward flight regimes, is reviewed. The requirement for accurate wake modeling for flow field and airload prediction is demonstrated by comparisons of theoretical and experimental results. These results include blade pressure distributions predicted from a recently developed procedure for including the rotor wake influence in a full potential flow analysis. Predictions of the interactional aerodynamics of various helicopter components (rotor, fuselage, and tail) are also presented. It is concluded that, with advanced computers and the rapidly progressing computational aerodynamics technology, significant progress toward reliable prediction of helicopter airloads is forseeable in the near future.
    Keywords: AERODYNAMICS
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  • 26
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    CNO isotopes in red giant stars (1985)
    In:  Other Sources
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    Publication Date: 2011-08-19
    Description: Observational data on CNO abundance ratios in red giants and the interstellar medium (ISM) are analyzed for the implications for the production and distribution of CNO nuclides. The data included isotope abundance measurements for the atmospheres and recent ejecta of cool giants, e.g., carbon stars, S-type stars, red supergiants and oxygen-rich giants beginning an ascent of the giant branch. The contribution of intermediate-mass stars to galactic nuclear evolution is discussed after comparing red giant abundances with ISM abundances, particularly the isotopes O-16, -17 and -18. The O-12/O-18 ratios of red giants are distinctly different from those in interstellar molecular clouds. The CNO values also vary widely from the values found in the solar system.
    Keywords: ASTROPHYSICS
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  • 27
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    CNO abundances in novae ejecta (1985)
    In:  Other Sources
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    Publication Date: 2011-08-19
    Description: Isotope production, particularly CNO, which are enhanced in novae events and the interstellar medium (ISM) by novae are discussed in terms of emission-line data taken a few weeks after novae events. The emission-line abundances emerge only after the fading of absorption spectrum, and are also detectable in thin shells which sometimes, though rarely, form after novae. CNO abundances in these shells are equivalent to those observed in fading novae, with CNO/H ratios being 100 times solar values. Possible heavy element production pathways in the events and their shrinking are discussed, along with observation techniques for detecting CNO isotopes through absorption data on atomic transitions in novae ejecta and the ISM.
    Keywords: ASTROPHYSICS
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  • 28
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    An analysis of IRAS' solar system dust bands (1985)
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    Publication Date: 2011-08-19
    Description: Measurements of longitudinal variations in the brightness and in the latitude of the solar system dust bands recently discovered by IRAS will determine the orbital elements of the particles involved and may discriminate between cometary and asteroidal models of the origin of these bands. The expected variations for bands of dust particles with common orbital elements and small eccentricity and inclination are calculated as functions of semimajor axis.
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  • 29
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    Mass input into and output from the meteoritic complex (1985)
    In:  Other Sources
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    Publication Date: 2011-08-19
    Description: The consequences which arise from the mutual collisions occurring between interplanetary meteoroids, the Poynting-Robertson (PR) effect and the radiation pressure ejection of small meteoroids are examined. The size distribution and flux of micrometeoroids at 1 AU are derived and the dependence of spatial density on distance from the sun is established. The following conclusions are made: (1) the lifetimes of meteoroids with masses approximately greater than 0.00001 g are dominated by catastrophic collisions; (2) after bering crushed by collisions, 70 to 85 percent of this mass will be in the form of zodiacal light particles (with masses in the range of 10 to the -10th g to 10 to the -5th g) which will in part be transported by the PR effect towards the sun where they will evaporate; (3) the 15 to 30 percent of the collisional fragments which have masses approximately less than 10 to the -10th g will, for the most part, be injected into hyperbolic orbits by radiation pressure.
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  • 30
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    Selection effects against small comets (1985)
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    Publication Date: 2011-08-19
    Description: Everhart's (1967) formulation is used to determine the correlation between the probability of discovering a comet and the size of its nuclear radius. The analysis is concentrated on comets that are not more than two or three hundred meters in diameter; hence, heliocentric variations in cometary brightness can be neglected. The effect of cometary physical decay is also considered, and a strong observational bias against the detection of small active comets is found. The following three factors are involved: (1) small comets must pass closer to the earth than large comets in order to be detected, (2) the resulting higher angular velocity for nearby comets leads to a decrease in the time available to discover a small comet, and (3) small comets physically decay and vanish faster than do large comets.
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  • 31
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    IRAS observations of the interplanetary dust emission (1985)
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    Publication Date: 2011-08-19
    Description: The Infrared Astronomical Satellite (IRAS) has completed a sensitive, highly redundant survey of the full sky in four broad photometric bands at 12, 25, 60, and 100 micrometers wavelength. The survey measured interplanetary dust emission over elongation angle ranging from 60 to 120 degrees. Bright emission from the main cloud is consistent with optically thin blackbody emission. The grains are evidently quite black, with an 'apparent albedo' of about 0.07. The data show clear evidence for deviation of the dust symmetry surface from the ecliptic plane. Surprising bands of emission were discovered near the ecliptic plane and about ten degrees on either side of it. The heliocentric distance of this material, suggested to be asteroidal in origin, is inferred to be about 2.5 AU from both color temperature and parallax measurements.
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  • 32
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    Large and small scale structures of molecular clouds in the Taurus Perseus complex (1985)
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    Publication Date: 2011-08-19
    Description: The gaseous components studied in H I and OH absorption against the extragalactic radiosources 3C123 and 3C111 are found to be the low-density edges of condensations of a few 100 solar masses. The densest part of one of these condensations has a structure similar to that found in other dark clouds: it is fragmented into several cores of a few solar masses, with an orbital velocity dispersion of about 2 km/s. In turn, the extended low-density layer, optically thick in CO (2-1), is not a common feature. It depends on the ambient UV field, but the dust temperature in the core may control its existence. Even more critically; it is found that the lower is the dust temperature, the less massive is the core and the more extended is the envelope around it, for a given total mass in a given external pressure.
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  • 33
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    Cepheid variables as extra-galactic distance indicators (1985)
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    Publication Date: 2011-08-19
    Description: The role of Cepheid variables in establishing the inner distance scale to nearby galaxies is discussed. Emphasis is placed on the necessity for broad wavelength coverage in attempting to account for metallicity differences and reddening internal to the parent galaxies. In addition linear detectors are essential in minimizing the effects of any unresolved background contribution to the photometry. Recent infrared observations of Cepheids in Local Group galaxies are surveyed and all published data on extra galactic Cepheids are presented for convenient access.
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  • 34
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    The 50 millisecond pulsar in the Large Magellanic Cloud and the X-ray pulse emission mechanism (1985)
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    Publication Date: 2011-08-19
    Keywords: ASTROPHYSICS
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  • 35
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    Interstellar clouds - From a dynamical perspective on their chemistry (1985)
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    Publication Date: 2011-08-19
    Description: The possibility is examined that in the course of its dynamical evolution, a single mass of interstellar gas would exhibit properties of diffuse clouds, dense clouds and finally also of clouds perturbed by shocks or intense UV or X-ray radiation generated by a star of its own creation. This concept provides a common thread through the bewildering diversity of physical and chemical compositional properties shown by interstellar clouds. From this perspective, instead of being static objects, interstellar clouds are possibly incessantly evolving from initially diffuse to later dense state and then to star formation which ultimately restructures or disperses the remaining cloud material to begin the whole evolutionary process once again. Based on a simplified study of interstellar chemistry from a dynamical perspective, the ideas are presented as an heuristic: to encourage thought on the future direction of molecular astrophysics and the need to consider the chemical behavior of interstellar clouds in conjunction with, rather than in isolation from, their dynamical behavior. A physical basis must be sought for the semiempirical temperature formula which has been given a critical role in the collapse of diffuse clouds. Self-shielding effects in the chemistry of CO were neglected and this drawback should be removed; the ability of the model to explain the fractional abundances of more complex molecules, such as cyanopolyynes, should be examined.
    Keywords: ASTROPHYSICS
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    Cometary comae (1985)
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    Publication Date: 2011-08-19
    Description: The basis of our knowledge about the structure and composition of a comet nucleus is examined. Such knowledge is inferred from observations of the cometary atmosphere (coma). However, photodissociation, photoionization, and chemistry destroy the mother molecules evaporating from the nucleus. To extract the primary information, the chemical kinetics and the physics of the coma are modeled with a computer and the results are compared with coma observations. The physics and chemistry for a dust free coma are described taking into account energy balance, multi-fluid flow for fast atomic and molecular hydrogen and the bulk fluid, and the transition from a collision dominated inner region to the free molecular flow outer region. Special attention is paid to the molecular data requirements for the current modeld and for extended models which will include solar wind interaction and dust. Such models are an important tool in support of the Giotto mission to Halley's comet, in the analysis and interpretation of coma observations, and in the understanding of the earliest history of the solar system.
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    Application of optical interferometry in compressible flows (1985)
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    Publication Date: 2011-08-19
    Description: Interferometry methods were applied to the investigation of steady and unsteady flows in large scale transonic wind tunnels. Holographic interferometry was demonstrated to provide reliable flow visualization and quantitative results for a number of two-dimensional flows. These conclusions were based on extensive comparisons with results obtained by other means. Data obtained on a NACA 64A010 airfoil with an oscillating flap installed in the Ames 11-foot transonic tunnel are presented. Interferograms were recorded at a free stream Mach number of 0.8, flap frequency of 30 Hertz and chord Reynolds numbers of 6.6 x 10 to the 6th and 12.3 x 10 to the 6th. The interferometric results were reduced to dynamic surface pressures, Mach contours and wake flow profiles. A new interferometry method that is capable of providing real-time interferometry data is also discussed.
    Keywords: AERODYNAMICS
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    Assisting extrasolar planetary detection through the determination of stellar space orientations (1985)
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    Publication Date: 2011-08-19
    Description: Various methods outlined for indirect planetary detection would greatly benefit (in some cases require) the determination of the planetary orbital plane, which is theoretically equivalent to the stellar equatorial plane. Determining the stellar space orientation, therefore, would greatly benefit extrasolar planetary detection. Stellar rotation periods determined from short-term variations in Ca II H and K sunspot emission are utilized together with both stellar radii measurements and Doppler-broadened spectral line profiles to get the stellar inclination to the line of sight. The clocklike on-the-plane-of-the-sky component determination utilizes the concentration of sunspot-associated plage areas at central stellar latitudes when viewed in Ca II H or K emission. One can perform Ca II H and K emission speckle interferometry to measure the clocklike angle of this stellar Ca II H and K emission band, modeling it as an elliptical intensity distribution. Both components should be determinable to within 10 deg for at least the resolvable fifth magnitude stars.
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    Problems with interpreting the radio emission from hot stars (1985)
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    Publication Date: 2011-08-19
    Description: Problems in hot star radio emission interpretation due to radio flux source and other modeling assumptions are examined. An upper limit constraint on the value of the mass loss rate divided by the constant wind velocity is imposed by assuming that the outflow is due to bremsstrahlung in a spherically symmetric wind with the stationary photosphere visible at 4500 A, and by the need for it to be less than the luminosity divided by c. The constraints are satisfied for the deduced values for OB supergiants, and to some extent for early 0 stars, but not for Wolf-Rayet stars, due to mass loss rates excessive by a factor of 10. It is suggested that the problem can be solved by postulating that part of the radio flux from Wolf-Rayet stars is due to processes in a low-density magnetized plasma.
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    Dynamical evolution of the Oort cloud (1985)
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    Publication Date: 2011-08-19
    Description: New studies of the dynamical evolution of cometary orbits in the Oort cloud are made using a revised version of Weissman's (1982) Monte Carlo simulation model, which more accurately mimics the perturbation of comets by the giant planets. It is shown that perturbations by Saturn and Jupiter provide a substantial barrier to the diffusion of cometary perihelia into the inner solar system. Perturbations by Uranus and Neptune are rarely great enough to remove comets from the Oort cloud, but do serve to scatter the comets in the cloud in initial energy. The new model gives a population of 1.8 to 2.1 x 10 to the 12th comets for the present-day Oort cloud, and a mass of 7 to 8 earth masses. Perturbation of the Oort cloud by giant molecular clouds in the galaxy is discussed, as is evidence for a massive 'inner Oort cloud' internal to the observed one. The possibility of an unseen solar companion orbiting in the Oort cloud and causing periodic comet showers is shown to be dynamically plausible but unlikely, based on the observed cratering rate on the earth and moon.
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    A new emission feature in IRAS spectra and the polycyclic aromatic hydrocarbon spectrum (1985)
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    Publication Date: 2011-08-19
    Description: IRAS spectra of those sources which show strong 7.7 and 11.3 micron emission features also show a plateau of emission extending from 11.3 to about 13.0 microns. Like the 11.3 micron feature, this new feature is attributed to the CH out-of-plane bending mode in polycyclic aromatic hydrocarbons (PAHs). Its discovery reinforces the identification of the 'unidentified infrared emission features' as emission from PAHs. The wavelength of this new feature suggests that interstellar PAHs are not as partially hydrogenated as hitherto thought. It also constrains their molecular structure.
    Keywords: ASTROPHYSICS
    Type: Astrophysical Journal, Part 2 - Letters to the Editor (ISSN 0004-637X); 299; L93-L97
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    Near-infrared mapping of ARP 299 (IC 694-NGC 3690) - Colliding galaxies unveiled (1985)
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    Publication Date: 2011-08-19
    Description: Near-infrared maps and multicolor photometry of the interacting galaxies IC 694 and NGC 3690 which form Arp 299 (= Markarian 171) are presented. These data reveal for the first time the distribution of nuclei and old red stars in a cataclysmically interacting system. The nuclei are considerably offset from the visual centroids of the galaxies but not from the mass centroids. The near-infrared colors of the most active regions are strongly affected by extinction, emission form hot dust, and bremsstrahlung. Near-infrared emission is also identified with secondary regions of star formation, probably resulting from the galaxies' interaction.
    Keywords: ASTROPHYSICS
    Type: Astrophysical Journal, Part 1 (ISSN 0004-637X); 299; 896-904
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    Molecular cloud evolution and star formation (1985)
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    Publication Date: 2011-08-19
    Description: The present state of knowledge of the relationship between molecular clouds and young stars is reviewed. The determination of physical parameters from molecular line observations is summarized, and evidence for fragmentation of molecular clouds is discussed. Hierarchical fragmentation is reviewed, minimum fragment scales are derived, and the stability against fragmentation of both spherically and anisotropically collapsing clouds is discussed. Observational evidence for high-velocity flows in clouds is summarized, and the effects of winds from pre-main sequence stars on molecular gas are discussed. The triggering of cloud collapse by enhanced pressure is addressed, as is the formation of dense shells by spherical outflows and their subsequent breakup. A model for low-mass star formation is presented, and constraints on star formation from the initial mass function are examined. The properties of giant molecular clouds and massive star formation are described. The implications of magnetic fields for cloud evolution and star formation are addressed.
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    Far-infrared and submillimeter photometry of evolved stars (1985)
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    Publication Date: 2011-08-19
    Description: Broad-band photometric observations at far infrared and submillimeter wavelengths (lambda is greater than 30 microns and less than 1) provide a unique probe of circumstellar shells in evolved objects and of the mass loss processes which produce them. The problems which these observations explore include: dust properties and dust-to-gas ratios in the outflowing material, the mass and structure of the circumstellar shell, and the pumping mechanism for maser emission. This contribution reviews the early work in this still largely unexploited field and reports results in each of the areas listed above. The dramatic advances forthcoming in this area from the IRAS satellite are previewed along with further progress which will come from the next generation of infrared and submillimeter telescopes.
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  • 45
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    Mass loss from red giants - Infrared spectroscopy (1985)
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    Publication Date: 2011-08-19
    Description: A discussion is presented of IR spectroscopy, particularly high-resolution spectroscopy in the approximately 1-20 micron band, as it impacts the study of circumstellar envelopes. The molecular bands within this region contain an enormous amount of information, especially when observed with sufficient resolution to obtain kinematic information. In a single spectrum, it is possible to resolve lines from up to 50 different rotational/vibrational levels of a given molecule and to detect several different isotopic variants. When high resolution techniques are combined with mapping techniques and/or time sequence observations of variable stars, the resulting information can paint a very detailed picture of the mass-loss phenomenon. To date, near-IR observations have been made of 20 molecular species. CO is the most widely observed molecule and useful information has been gleaned from the observed rotational excitation, kinematics, time variability and spatial structure of its lines. Examples of different observing techniques are discussed in the following sections.
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  • 46
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    The infrared characteristics of circumstellar silicate grains (1985)
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    Publication Date: 2011-08-19
    Description: A theoretical study of the infrared emission from circumstellar shells around late-type giants is made, with the aim of deriving the infrared characteristics of the silicate grains condensing in these shells. A large grid of models has been compared with observations of optically visible Miras, IRC sources and OH/IR stars. From fitting the observed relation between the color temperature and the strength of the 10-micron feature, it is concluded that the ratio of the 3.5 to 10-micron absorption efficiencies of the dust is about 0.25, a factor of 2 less than a previous determination. Detailed modeling of the 2 to 13-micron spectrum of OH 26.5 + 0.6, IRC + 10011 and R Cas yielded a similar ratio. These detailed models also show that the shape of the 10-micron feature, particularly around 8 and 13 microns, varies from source to source. The derived 10-micron feature is narrower for larger dust column densities. These observed differences in the intrinsic shape of the 10-micron feature are not due to differences in size of the condensing particles. Probably they are related to structural or compositional differences in the condensing silicates.
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  • 47
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    Protostellar angular momentum transport by spiral density waves (1985)
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    Publication Date: 2011-08-19
    Description: The application of rotational stability criteria to a specific model of star formation leads to the conclusion that the growth of stellar angular momentum is limited by its transfer to the disk. Excess accreted angular momentum can be transferred by torques connected with spiral density waves induced by even a slight protostellar triaxiality. In addition, viscous damping of the density waves is likely to cause the excess angular momentum to be deposited within a small region close to the protostar. Thus, it would be appropriate to treat that part of the growing protostellar disk beyond the outer Lindblad resonance as an accretion disk with a torque applied to its inner edge. It is noted that this situation is directly relevant to certain models of the evolution of the protosun and solar nebula.
    Keywords: ASTROPHYSICS
    Type: Icarus (ISSN 0019-1035); 64; 435-447
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  • 48
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    The plasma regime at comet Giacobini-Zinner (1985)
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    Publication Date: 2011-08-19
    Description: The paper reviews results on the plasma regime at Comet Giacobini-Zinner obtained by the International Cometary Explorer. The observations are consistent with the existence of a weak shock which may be pulsating, but do not exclude the suggestion that the shock, though present around the subsolar point, is an the process of decaying to a wave on the flanks. 'The pick-up' of cometary ions leads to ion cyclotron, mirror, beam, and electrostatic instabilities which cause strong turbulence in the inner coma.
    Keywords: ASTROPHYSICS
    Type: Advances in Space Research (ISSN 0273-1177); 5; 12, 1
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  • 49
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    Ammonia in the hot galactic centre cloud G 1.6-0.025 (1985)
    In:  Other Sources
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    Publication Date: 2011-08-19
    Description: As part of an extensive southern survey of interstellar NH3 with the Parkes 64-m radio telescope (with a beamwidth of 81 arcsec), the (1,1), (2,2), and (3,3) transitions have been observed towards the galactic centre molecular cloud Gl.6-0.025. The cloud has an overall size of 10 arcmin, and contains several concentrations with differing velocities. It has several features also observed in other galactic centre clouds, e.g. high optical depths and kinetic temperatures above 50 K.
    Keywords: ASTROPHYSICS
    Type: Astronomical Society of Australia, Proceedings (ISSN 0066-9997); 6; 2, 19
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  • 50
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    The aerodynamics of rotor blades with ice shapes accreted in hover and in level flight (1985)
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    Publication Date: 2011-08-19
    Description: Through a series of flights in artificial clouds, ice accretions on the main rotor of a UH-1H helicopter were documented in detail upon landing by silicone-rubber molds for both hover and level flights. Full scale reproductions of typical accretions in hover were fabricated by means of epoxy castings and used for a wind-tunnel test program. Surface static pressure distributions were recorded and used to evaluate lift and pitching moment increments while drag was determined by wake surveys. For comparison, accreted ice shapes are presented for two level flight cases as well as preliminary analytical predictions.
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  • 51
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    A calculation of the Rosseland mean opacity of dust grains in primordial solar system nebulae (1985)
    In:  Other Sources
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    Publication Date: 2011-08-19
    Description: The Rosseland mean opacity owing to grains was calculated as a function of temperature and density for nebulae having solar elemental abundances. The values of the mean opacity were evaluated with a generalized formulation allowing for anisotropic scattering. The values of the mean opacity do not depend sensitively on the choice of the particle size distribution function, provided that there are few particles having sizes in excess of several tens of microns. The results indicate that thermal convection in primordial nebulae occurs over broader ranges of altitudes at low temperatures than at high temperatures, and for size distributions for which extensive aggregation has not yet occurred.
    Keywords: ASTROPHYSICS
    Type: Icarus (ISSN 0019-1035); 64; 471-492
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  • 52
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    Three-dimensional inviscid analysis of radial-turbine flow and a limited comparison with experimental data (1985)
    In:  Other Sources
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    Publication Date: 2011-08-19
    Description: The three-dimensional inviscid DENTON code is used to analyze flow through a radial-inflow turbine rotor. Experimental data from the rotor are compared with analytical results obtained by using the code. The experimental data available for comparison are the radial distributions of circumferentially averaged values of absolute flow angle and total pressure downstream of the rotor exit. The computed rotor-exit flow angles are generally underturned relative to the experimental values, which reflect the boundary-layer separation at the trailing edge and the development of wakes downstream of the rotor. The experimental rotor is designed for a higher-than-optimum work factor of 1.126 resulting in a nonoptimum positive incidence and causing a region of rapid flow adjustment and large velocity gradients. For this experimental rotor, the computed radial distribution of rotor-exit to turbine-inlet total pressure ratios are underpredicted due to the errors in the finite-difference approximations in the regions of rapid flow adjustment, and due to using the relatively coarser grids in the middle of the blade region where the flow passage is highly three-dimensional. Additional results obtained from the three-dimensional inviscid computation are also presented, but without comparison due to the lack of experimental data. These include quasi-secondary velocity vectors on cross-channel surfaces, velocity components on the meridional and blade-to-blade surfaces, and blade surface loading diagrams. Computed results show the evolution of a passage vortex and large streamline deviations from the computational streamwise grid lines. Experience gained from applying the code to a radial turbine geometry is also discussed.
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  • 53
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    Finite-difference computations of rotor loads (1985)
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    Publication Date: 2011-08-19
    Description: This paper demonstrates the current and future potential of finite-difference methods for solving real rotor problems which now rely largely on empiricism. The demonstration consists of a simple means of combining existing finite-difference, integral, and comprehensive loads codes to predict real transonic rotor flows. These computations are performed for hover and high-advance-ratio flight. Comparisons are made with experimental pressure data.
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  • 54
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    Diagnostics of solar and astrophysical plasmas - Dependent on autoionization phenomena (1985)
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    Publication Date: 2011-08-19
    Description: The application of autoionization calculations to problems in solar and astrophysical plasma diagnostics is discussed. Attention is given to space plasmas having high spectral resolution, particularly in the wavelength region between about 300 and 1100 A. It is shown that atomic resonance data can be used to calculate many of the spectral line intensities in solar plasmas in order to obtain information concerning the physical properties of the emitting gas, including temperature, density, ionization balance, and atmospheric structure and dynamics. Recent spectral observations of nonsolar plasmas are also discussed. A list of the major high-resolution astrophysical plasma spectrometers and spectrographs is provided.
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  • 55
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    Anatomy of a cosmic-ray neutrino source and the Cygnus X-3 system (1985)
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    Publication Date: 2011-08-19
    Description: The effects of an intense beam of ultra-high energy cosmic rays from a compact object in the Cygnus X-3 binary system hitting the companion star, and of the subsequent production of secondary neutrinos, are examined. A maximum allowable beam luminosity of about 10 to the 42nd erg/s is found for a system containing a 1-10 solar mass main sequence target star. The proton beam must heat a relatively small area of the target star to satisfy observational constraints on the resulting stellar wind. With such a model, the neutrino to gamma-ray flux ratio of about 1000 can result from a combination of gamma-ray absorption and a large neutrino to gamma-ray duty cycle ratio. It is found that the high density of the atmosphere resulting from compression by the beam leads to pion cascading and a neutrino spectrum peaking at 1-10 GeV energies.
    Keywords: ASTROPHYSICS
    Type: Nature (ISSN 0028-0836); 316; 418-420
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  • 56
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    The physical implications of an isothermal model for the hot intracluster medium (1985)
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    Publication Date: 2011-08-19
    Description: HEAO-1 A-2 and Einstein Observatory IPC observations of 15 clusters of galaxies have been used to measure the isothermal beta-model parameters, and the parameters are compared with those derived from model fits to the X-ray images. The physical constraints imposed on this model by existing optical data, the implied gas mass, and the gas contribution to the binding cluster mass are addressed. Values of beta less than unity are obtained, consistent with results from X-ray imaging data. This is interpreted to imply that the gas extends out to 8-10 core radii, about 2-3 Mpc. The isothermal gas mass can be as large as 60 percent of the virial mass for some clusters. This contradicts the fundamental assumption that the cluster potential is determined by an unseen mass which is given by the King approximation to an isothermal sphere, and it is concluded that the isothermal model is a nonphysical model.
    Keywords: ASTROPHYSICS
    Type: Astrophysical Journal, Part 1 (ISSN 0004-637X); 292; 441-446
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  • 57
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    Scale-model tests of airfoils in simulated heavy rain (1985)
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    Publication Date: 2011-08-19
    Keywords: AERODYNAMICS
    Type: Journal of Aircraft (ISSN 0021-8669); 22; 536-540
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  • 58
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    An investigation of the tabbed vortex flap (1985)
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    Publication Date: 2011-08-19
    Keywords: AERODYNAMICS
    Type: Journal of Aircraft (ISSN 0021-8669); 22; 490-497
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  • 59
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    Assessment of preliminary prediction techniques for wing leading-edge vortex flows at supersonic speeds (1985)
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    Publication Date: 2011-08-19
    Description: A theoretical investigation of the aerodynamics of sharp leading-edge delta wings at supersonic speeds has been conducted. The primary objective of this was to determine the applicability of existing theoretical methods to predict wing leading-edge separated-flow characteristics at conditions conductive to high-lift supersonic flight. Predicted results from two modified linear-theory methods (LTSTAR and VORCAM) are compared with experimental data. Comparison of the two methods for uncambered wings revealed that the LTSTAR code is in much better agreement with experimentally measured vortex strength, vortex position, and total lifting characteristics than the VORCAM code. Selected analysis was also performed with an Euler code, SWINT. The results of this study indicated that the SWINT code was not well suited to the analysis of wings with separated flow at high lift and low supersonic speeds.
    Keywords: AERODYNAMICS
    Type: Journal of Aircraft (ISSN 0021-8669); 22; 473-478
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  • 60
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    Comparison of inviscid flow computations with flight data for the Shuttle orbiter (1985)
    In:  Other Sources
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    Publication Date: 2011-08-19
    Keywords: AERODYNAMICS
    Type: Journal of Spacecraft and Rockets (ISSN 0022-4650); 22; 297-303
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  • 61
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    The lateral surface drag coefficient of cylindrical spacecraft in a rarefied finite temperature atmosphere (1985)
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    Publication Date: 2011-08-19
    Description: In the present determination of the free molecule flow drag coefficient for a cylindrical spacecraft flying parallel to its principal axis, the lateral surface effects of thermal motion are explicitly included in terms of the average impact angle of the incident gas momentum vector. Kinetic theory is used to characterize self-shadowing, as well as to obtain an expression for the lateral surface coefficient in terms of the average impact angle of the incident momentum vector and the fractional momentum transfer along the line of impact. It is found that, for a length/diameter ratio of about 5, the lateral surface contribution to the drag coefficient is comparable to that of the front face.
    Keywords: AERODYNAMICS
    Type: AIAA Journal (ISSN 0001-1452); 23; 862-867
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  • 62
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    Axisymmetric bluff-body drag reduction through geometrical modification (1985)
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    Publication Date: 2011-08-19
    Description: The effect of shoulder radiusing and grooving (longitudinally and circumferentially) the afterbodies of bluff bodies to reduce the base drag at low speeds is investigated experimentally. Shoulder radii as large as 2.75 body diameters are examined. Reynolds number (ReD) based on body diameter varied from 20,000 to 200,000. Results indicate that increasing the shoulder radius to 2.00 body diameters can reduce the drag levels to those of a streamline body having 67 percent greater fineness ratio. For the relatively sharp shoulder case, body drag reductions as large as 50 and 33 percent are obtained using circumferential or longitudinal grooves, respectively.
    Keywords: AERODYNAMICS
    Type: Journal of Aircraft (ISSN 0021-8669); 22; 516-522
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  • 63
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    High-energy X-ray observations of the Galactic center region (1985)
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    Publication Date: 2011-08-19
    Description: The region within five degrees of the Galactic center was observed in high-energy X-rays on November 12, 1977, and it is concluded that the emission definitely comes from more than one source. At least five 2-10 keV sources are important: the transient A1743 - 322, the binary GX 1 + 4, the bulge sources GX 3 + 1 and GX 5 - 1, and A1742 - 294. The composite spectrum of all the sources agrees with the continuum measured 12 days earlier by Leventhal, MacCallum, and Stang (1978) in the 70-250 keV range but, if extrapolated to higher energies, would be softer than and weaker than the HEAO 1 continuum observed in September 1977 or HEAO 3 continuum observed in the fall of 1979.
    Keywords: ASTROPHYSICS
    Type: Astrophysical Journal, Part 1 (ISSN 0004-637X); 290; 557-567
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  • 64
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    On fast X-ray rotators with long-term periodicities (1985)
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    Publication Date: 2011-08-19
    Description: The support of previous SAS 3 spacecraft observations by new data gathered by the Monitor Proportional Counter aboard the HEAO 2 spacecraft indicates that the pulse period history of the 13.5 sec-pulsing X-ray source LMC X-4 is consistent with standard accretion and torque models only if LMC X-4 is a fast rotator for which the accretion torques nearly cancel. This result leads to a neutron star magnetic field strength estimate of about 1.2 x 10 to the 13th G. Strong evidence is noted for Her X-1's status as a fast rotator, while SMC X-1 is probably an intermediate-to-fast rotator. In the context of slaved disk models for these objects, it is noted that the precession periods expected for the companion stars are significantly longer than the observed 1-2 month time scales; slaved disk models are thereby undermined.
    Keywords: ASTROPHYSICS
    Type: Astrophysical Journal, Part 1 (ISSN 0004-637X); 290; 487-495
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  • 65
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    Electrosphere of an aligned magnetized neutron star (1985)
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    Publication Date: 2011-08-19
    Description: A fundamentally new self-consistent solution for the electrosphere of an aligned magnetized neutron star is presented. Unlike previous models the electrospheres are finite in extent. This avoids the light cylinder problem. The results may provide a basis for pulsar models.
    Keywords: ASTROPHYSICS
    Type: Royal Astronomical Society, Monthly Notices (ISSN 0035-8711); 213; 43P-49P
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  • 66
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    Measured and calculated airloads on a transport wing model (1985)
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    Publication Date: 2011-08-19
    Keywords: AERODYNAMICS
    Type: Journal of Aircraft (ISSN 0021-8669); 22; 336-342
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  • 67
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    Euler and Navier-Stokes solutions for supersonic shear flow past a circular cylinder (1985)
    In:  Other Sources
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    Publication Date: 2011-08-19
    Keywords: AERODYNAMICS
    Type: AIAA Journal (ISSN 0001-1452); 23; 583-587
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  • 68
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    MgS grain component in circumstellar shells (1985)
    In:  Other Sources
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    Publication Date: 2011-08-19
    Description: In this letter, far-infrared spectrophotometry (30-55 microns) and photometry (53-200 microns) are presented which define, for the first time, the long wavelength limit of the previously unidentified 30 micron emission feature found in certain extreme carbon star spectra. The spectral similarities are sufficiently similar to those of solid MgS that MgS is proposed to be the band carrier. This is interpreted as the first direct evidence that chemical surface reactions occur on dust grains in circumstellar environments. The presence of MgS indicates that either the oxygen abundance is relatively low and/or the sulfur abundance is high in extreme carbon stars.
    Keywords: ASTROPHYSICS
    Type: Astrophysical Journal, Part 2 - Letters to the Editor (ISSN 0004-637X); 290; L35-L39
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  • 69
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    Implicit Total Variation Diminishing (TVD) schemes for steady-state calculations (1985)
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    Publication Date: 2011-08-19
    Description: The novel implicit and unconditionally stable, high resolution Total Variation Diminishing (TVD) scheme whose application to steady state calculations is presently examined is a member of a one-parameter family of implicit, second-order accurate systems developed by Harten (1983) for the computation of weak solutions for one-dimensional hyperbolic conservation laws. The scheme will not generate spurious oscillations for a nonlinear scalar equation and a constant coefficient system. Numerical experiments for a quasi-one-dimensional nozzle problem show that the experimentally determined stability limit correlates exactly with the theoretical stability limit for the nonlinear scalar hyberbolic conservation laws.
    Keywords: AERODYNAMICS
    Type: Journal of Computational Physics (ISSN 0021-9991); 57; 327-360
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  • 70
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    Laboratory infrared spectra of predicted condensates in carbon-rich stars (1985)
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    Publication Date: 2011-08-19
    Description: Laboratory spectra and mass absorption coefficients of MgS, CaS, FeS, SiS2, FeS2, Fe3C, and a commercial iron carbide are presented over the wavelength range 125-15 microns. These spectra confirm that MgS is the most likely source of the unidentified 30-micron emission in carbon-rich sources and that FeS, Fe3C, and 'iron carbide' cannot be responsible for this feature although they could contribute to the continuum in this region. CaS and FeS2 may contribute to the 30-micron feature; however, both higher resolution and higher precision astronomical observations are needed before their presence can be established. SiS2 has a peak near 22 microns and therefore cannot be a significant component of the dust in such regions.
    Keywords: ASTROPHYSICS
    Type: Astrophysical Journal, Part 2 - Letters to the Editor (ISSN 0004-637X); 290; L41-L43
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  • 71
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    Polycyclic aromatic hydrocarbons and the unidentified infrared emission bands - Auto exhaust along the Milky Way (1985)
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    Publication Date: 2011-08-19
    Description: The unidentified infrared emission features (UIR bands) are attributed to a collection of partially hydrogenated, positively charged polycyclic aromatic hydrocarbons (PAHs). This assignment is based on a spectroscopic analysis of the UIR bands. Comparison of the observed interstellar 6.2 and 7.7-micron bands with the laboratory measured Raman spectrum of a collection of carbon-based particulates (auto exhaust) shows a very good agreement, supporting this identification. The infrared emission is due to relaxation from highly vibrationally and electronically excited states. The excitation is probably caused by UV photon absorption. The infrared fluorescence of one particular, highly vibrationally excited PAH (chrysene) is modeled. In this analysis the species is treated as a molecule rather than bulk material and the non-thermodynamic equilibrium nature of the emission is fully taken into account. From a comparison of the observed ratio of the 3.3 to 11.3-micron UIR bands with the model calculations, the average number of carbon atoms per molecule is estimated to be about 20. The abundance of interstellar PAHs is calculated to be about 2 x 10 to the -7th with respect to hydrogen.
    Keywords: ASTROPHYSICS
    Type: Astrophysical Journal, Part 2 - Letters to the Editor (ISSN 0004-637X); 290; L25-L28
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    The R Aquarii system at optical and radio wavelengths (1985)
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    Publication Date: 2011-08-19
    Description: New continuum observations of all radio components of the R Aquarii system at 2, 6, and 20 cm are reported which allow determination of polarization properties, integrated flux levels, spectral indices, and hence the emission mechanisms of the individual components. Complementary wide-band optical observations are also reported to help determine the nature and structure of the compact double radio source (CDRS) and the R Aquarii radio jet. The results of these observations are discussed in detail with regard to models currently or previously proposed for the R Aquarii system. It is concluded that the compact H II region spectral index is about +0.6, indicative of a thermal and optically thick expanding wind from the long-period variable. The radio jet emission is shown to be optically thin, thermal, cospatial with optical emission, and stable over the last few years. The CDRS is shown to be an extragalactic background object.
    Keywords: ASTROPHYSICS
    Type: Astrophysical Journal, Part 1 (ISSN 0004-637X); 289; 765-767
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  • 73
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    Evaluation of a stalled airfoil analysis program (1985)
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    Publication Date: 2011-08-19
    Description: The Stalled Airfoil Analysis Program (SAAP) is a computer code for predicting the aerodynamic characteristics of an airfoil up to, and beyond, stall. SAAP is presently evaluated through comparisons with experiments and with two other theoretical methods over an extensive range of airfoils and Reynolds number conditions. SAAP modeled drag more accurately than either of the other methods, and at angles of attack below stall yielded a smoother lift variation with angle of attack.
    Keywords: AERODYNAMICS
    Type: Journal of Aircraft (ISSN 0021-8669); 22; 156
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  • 74
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    High-angular resolution observations of stellar binary systems (1985)
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    Publication Date: 2011-08-19
    Description: A long-term program designed to investigate the spatial structure of centimetric radio emission from close binary systems using multistation VLBI array is discussed. Eleven binaries, including eight RS CVn systems, Algol, LSI 61 deg 303, and Cyg X-1, have been detected. The measured brightness temperatures vary from T(B) about 10 exp 8.5 K during periods of low activity to T(B) about 10 exp 10.5 K during flares. Extensive observation of a few sources has shown that the spatial structure is 'core-halo' with linear dimensions of about a stellar radius and the binary system, respectively. The observations are consistent with gyrosynchrotron emission of mildly relativistic electrons in magnetic fields of about 10 exp 1.5 + or - 0.5 gauss. The core sources appear to be optically thick, while the halo component is optically thin.
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  • 75
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    The dynamical history of comet Halley (1985)
    In:  Other Sources
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    Publication Date: 2011-08-19
    Description: The history of the attempts to predict the motion of comet Halley is outlined and the importance of the so-called nongravitational forces acting upon this comet is emphasized. Recent orbital work of the International Halley Watch Astrometry Network is reviewed. Comet Halley's transverse nongravitational parameter is positive and nearly constant with time suggesting that the comet is in direct rotation without precession of the spin pole. The nongravitational effects are consistent with the vaporization of water ice from the comet's nucleus and long term integrations suggest that the comet has been in its present orbit for at least 16,000 years and probably much longer.
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  • 76
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    Morphological and physical characteristics of the Virgo Cluster - First results from the Las Campanas photographic survey (1985)
    In:  Other Sources
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    Publication Date: 2011-08-19
    Description: Preliminary results are presented of a photographic survey of the Virgo cluster to the faintest convenient limit of the Las Campanas du Pont 2.5 m reflector, performed in order to study the complexity of both the surface and velocity distributions within the central 6 degree radius region. The survey is described and the resulting Catalog is discussed, and the frequency of galaxy types found and listed in the Catalog is described. The physical properties of the dwarfs are summarized, and luminosity functions are given separately for each morphological type. The progressive change of (MBT) faintward along the morphological sequence from Sc I through Sm and Im types is shown, leading to a calibration of the de Vaucouleurs Lambda luminosity index and a determination of its intrinsic dispersion. The preliminary results on the distribution of galaxies of all types in the two principal subclustering regions found are summarized, and the velocity distributions over the face of the 6 degree core are discussed for the various galaxy types.
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  • 77
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    Bipolar nebulae and mass loss from red giant stars (1985)
    In:  Other Sources
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    Publication Date: 2011-08-19
    Description: Observations of several bipolar nebulae are used to learn something of the nature of mass loss from the probable red-giant progenitors of these nebulae. Phenomena discussed are: (1) probable GL 2688's optical molecular emissions; (2) newly discovered very high velocity knots along the axis of OH 0739 - 14, which reveal evidence for mass ejections of + or 300 km/s from the M9 III star embedded in this nebula; (3) the bipolar structure of three extreme carbon stars, and the evidence for periodic mass ejection in IRC + 30219, also at high speed (about 80 km/s); and (4) the curious cool TiO-rich region above Parsamian 13, which may represent the very recent shedding of photospheric material from a cool, oxygen-rich giant. Several general key questions about bipolar nebulae that relate to the process of mass loss from their progenitor stars are raised.
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  • 78
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    Infrared studies of the bipolar nebula OHO739 (1985)
    In:  Other Sources
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    Publication Date: 2011-08-19
    Description: Infrared studies have been made of the M9 giant OHO739, which is embedded in a bipolar nebula, in order to study the structure and density distribution of the circumstellar disk, and preliminary results are reported. The degree of polarization across the 3.1 micron ice band in an 8 arcsec beam centered at the 2.2 micron peak is found to increase with extinction in the ice band, as expected for a bipolar scattering nebula. A distance of 2 kpc is inferred from the tilt angle of the bipolar axis and phase lag measurements of the OH maser. Maps made in the K band and in narrow bands at 2.85, 3.1, and 3.5 microns by raster-scanning OHO739 are presented. In all maps, the object is clearly elongated along the bipolar axis. Patterns of increases and decreases in extinction in the object are inferred to indicate that ice particles are widespread through the nebula and not just concentrated in the disk.
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  • 79
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    Hydrogen deficiency and mass loss from AGB stars (1985)
    In:  Other Sources
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    Publication Date: 2011-08-19
    Description: Theoretical studies predict that mass loss from stars should accelerate once stars on the AGB begin thermal pulsations (TP). It has been discovered that the stars on this part of the AGB are apparently hydrogen deficient. This development may be related to the mass loss predicted by theory. Hydrogen deficiency is also supported by the nondetection of H2 in non-Mira stars, S stars, and carbon stars. The possibility that the observed apparent hydrogen deficiency has resulted from a mass loss process is considered. Observations indicate that TP-AGB stars become hydrogen deficient before the Mira phase.
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  • 80
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    Spectral constraints on models of gas in clusters of galaxies (1985)
    In:  Other Sources
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    Publication Date: 2011-08-19
    Description: The HEAO 1A2 spectra of clusters of galaxies are used to determine the temperature profile which characterizes the X-ray emitting gas. Strong evidence of nonisothermality is found for the Coma, A85, and A1795 clusters. Properties of the cluster potential which binds the gas are calculated for a range of model parameters. The typical binding mass, if the gas is adiabatic, is 2-4E14 solar masses and is quite centrally concentrated. In addition, the Fe abundance in Coma is .26 + or - .06 solar, less than the typical value (.5) found for rich clusters. The results for the gas in Coma may imply a physical description of the cluster which is quite different from what was previously believed.
    Keywords: ASTROPHYSICS
    Type: Space Science Reviews (ISSN 0038-6308); 40; 681-688
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  • 81
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    H0323+022 - Classification as a BL Lac and EXOSAT coordinated observations (1985)
    In:  Other Sources
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    Publication Date: 2011-08-19
    Description: The object H0323+022 (Doxsey et al. 1983) has been shown to be a BL Lac object by virtue of a diversity of observational characteristics at radio, optical, and X-ray wavelengths, in agreement with the conclusion of Margon and Jacoby (1984). Multi-frequency coordinated observations of this highly variable object with EXOSAT in September 1984 found it to be in a faint quiescent state (approximately 1/3 micron-Jy at approximately 5 keV and V = 16.55). Preliminary results from the latter observations are presented.
    Keywords: ASTROPHYSICS
    Type: Space Science Reviews (ISSN 0038-6308); 40; 613-617
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  • 82
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    The discovery of a 25 min regular modulation in the X-ray flux from 2S0142 + 61 (1985)
    In:  Other Sources
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    Publication Date: 2011-08-19
    Description: A 13 hr observation of 2S0142 + 61 on August 27, 1984 by EXOSAT shows the X-ray flux of 2S0142 + 61 to be modulated with a period of 1456+/-6 s. The 1-10 keV spectrum is two component with an approximately 0.7 keV thermal and 0.0 energy index power law, with 30 percent of the total luminosity in the thermal component. The spectrum is absorbed by about 1 x 10 to the 22nd H per sq cm. Only the hard component is pulsed with a 3 to 10 keV peak to mean amplitude of 35 percent. Below 2 keV the modulation is less than a few percent. The total 1-10 keV luminosity is 3.5 x 10 to the 32nd erg/s for a distance of 100 pc. Possible optical counterparts are discussed.
    Keywords: ASTROPHYSICS
    Type: Space Science Reviews (ISSN 0038-6308); 40; 157-162
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  • 83
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    A wind tunnel inlet flow simulation (1985)
    In:  Other Sources
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    Publication Date: 2011-08-19
    Keywords: AERODYNAMICS
    Type: Journal of Aircraft (ISSN 0021-8669); 22; 927
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  • 84
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    Full potential solutions of three-dimensional supersonic flows (1985)
    In:  Other Sources
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    Publication Date: 2011-08-19
    Keywords: AERODYNAMICS
    Type: Journal of Aircraft (ISSN 0021-8669); 22; 881-887
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  • 85
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    Numerical optimization of circulation control airfoil at high subsonic speed (1985)
    In:  Other Sources
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    Publication Date: 2011-08-19
    Keywords: AERODYNAMICS
    Type: Journal of Aircraft (ISSN 0021-8669); 22; 869-874
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  • 86
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    Inviscid and viscous flows in cascades with an explicit multiple-grid algorithm (1985)
    In:  Other Sources
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    Publication Date: 2011-08-19
    Keywords: AERODYNAMICS
    Type: AIAA Journal (ISSN 0001-1452); 23; 1556-156
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  • 87
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    A computational study of complex three-dimensional compressible turbulent flowfields (1985)
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    Publication Date: 2011-08-19
    Keywords: AERODYNAMICS
    Type: AIAA Journal (ISSN 0001-1452); 23; 1461
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  • 88
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    Flow instabilities in transonic small-disturbance theory (1985)
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    Publication Date: 2011-08-19
    Description: The dynamics of unsteady transonic small disturbance flows about two-dimensional airfoils is examined, with emphasis on the behavior in the region where the steady state flow is nonunique. It is shown that nonuniqueness results from an extremely long time scale instability which occurs in a finite Mach number and angle of attack range. The similarity scaling rules for the instability are presented and the possibility of similar behvior in the Euler equations is discussed.
    Keywords: AERODYNAMICS
    Type: AIAA Journal (ISSN 0001-1452); 23; 1491-149
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  • 89
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    Modeling the effects of latitudinal gradients in stellar winds, with application to the solar wind (1985)
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    Publication Date: 2011-08-19
    Description: A steady, axisymmetric, quasi-radial, global model previously developed for stellar winds with embedded magnetic fields has been extended to include latitudinal gradient effects on the azimuthal velocity and magnetic field. The linear results at large radii are presented for large-amplitude latitudinal variations in the radial magnetic field, mass loss rate, and radial velocity of the wind. The magnetohydrodynamic (MHD) equations predict meridional flows that develop naturally from internal magnetic stresses. The flows open flux tubes in the star's equatorial plane, redistributing mass and magnetic flux as a function of stellar latitude. The plasma spins up to conserve angular momentum in fields and plasma. The results are generally applicable to stellar winds (including radiatively driven winds), provided that the internal structure is not dominated by rotation. The asymptotic solutions do not explicitly depend on the form of the energy equation, although the assumed O(1) state which drives these solutions depends on the deposition of energy and momentum throughout the wind.
    Keywords: ASTROPHYSICS
    Type: Astrophysical Journal, Part 1 (ISSN 0004-637X); 296; 259-267
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  • 90
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    An interpretation of the spectral variations of Theta Coronae Borealis (1985)
    In:  Other Sources
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    Publication Date: 2011-08-19
    Description: Measurements are presented of the strengths and displacements of sharp absorption components of the resonance lines of Si IV, C IV, and Al III in the spectrum of Theta CrB. No evidence is found for mass loss at a detectable rate. A qualitative model of a Be star is developed. It is suggested that the spectral variations of Theta CrB are the result of changes in the rate at which magnetic flux is generated in the envelope of the star and extruded through the photosphere of the star.
    Keywords: ASTROPHYSICS
    Type: Astronomy and Astrophysics (ISSN 0004-6361); 148; 2, Ju
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  • 91
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    Black hole accretion disks - Electrodynamic coupling of accretion-disk coronae and the partitioning of soft and hard X-ray emission (1985)
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    Publication Date: 2011-08-19
    Description: It is demonstrated that the observed large ratio of hard to soft X-ray emission and the bimodel behavior of black hole accreting X-ray sources such as Cygnus X-1 can be described in terms of a magnetically structured accretion disk corona which is electrodynamically coupled to the disk turbulent motions while the disk is thermodynamically coupled to the corona as described by a feedback parameter delta. The observed ratio of hard to soft X-ray emission is independent of the disk thickness, and weakly dependent of the disk parameter alpha relating the disk viscous stresses to the total pressure. Observed values of the luminosity ratio point towards strong differences of the feedback of the low state compared to the high state, in the sense that low state means small feedback (delta less than 0.2) and high state means strong feedback delta of about 0.5.
    Keywords: ASTROPHYSICS
    Type: Astronomy and Astrophysics (ISSN 0004-6361); 148; 2, Ju; 309-311
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  • 92
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    Light variations of Periodic Comet Halley beyond 7 AU (1985)
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    Publication Date: 2011-08-19
    Description: The present examination of brightness data on the Periodic Comet Halley over the October 1982-February 1984 period, for evidence concerning nucleus rotation period and projected cross section area, notes variations of up to 5:1 in intrinsic brightness. Application of a period-determination technique has failed to yield a clear choice for the true rotation period among a large number of peaks in the spectrum, some of which virtually coincide with the sun's rotation period and its submultiples. It is found that rotation periods longer than about 1 day are the most likely; it is suggested that the observed light curve is a composition of periodic and erratic variations.
    Keywords: ASTROPHYSICS
    Type: Astronomy and Astrophysics (ISSN 0004-6361); 148; 2, Ju; 299-308
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  • 93
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    Soft X-ray spectral observations of low-luminosity active galaxies (1985)
    In:  Other Sources
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    Publication Date: 2011-08-19
    Description: The X-ray spectra of a sample of 12 low-luminosity AGNs observed using the solid state spectrometer on the HEAO 2 satellite are investigated. The AGNs discussed here have X-ray luminosities below about 10 to the 44th erg/s, and thus form a sample complementary to the higher luminosity sample discussed by Petre et al. (1984). The spectra are well described by a simple model consisting of a power law, with photon spectral index about 1.7, plus absorption by cold gas. The objects in the sample can be separated into three groups: (1) those whose spectra show no significant absorption; (2) those for which the X-ray source is totally covered by a spatially uniform absorbing medium; and (3) those for which partial covering by 'patchy' absorbers is indicated. Column densities and covered fractions do not correlate systematically with X-ray luminosity. Implications regarding physical conditions in AGNs are discussed.
    Keywords: ASTROPHYSICS
    Type: Astrophysical Journal, Part 1 (ISSN 0004-637X); 296; 69-89
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  • 94
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    VLBI observations of the jet in Cygnus A (1985)
    In:  Other Sources
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    Publication Date: 2011-08-19
    Description: The luminous radio galaxy Cyg A was observed with a five-station US VLBI array at 5 GHz at epoch 1983.25. The jet can be followed from the core to a distance of 9 milliarcsec (mas). Within the limited dynamic range of these observations, it is one-sided (jet:counterjet ratio greater than 12:1). If this one-sidedness is due to Doppler boosting, then (1) the jet must decelerate to a mildly relativistic velocity on a kiloparsec scale, (2) the source cannot lie with 30 deg of the plane of the sky. The jet points directly at the base of the kpc-scale jet seen by Perley, Dreher, and Cowan (1984); the curvature occurs primarily or entirely on a scale of 10-100 kpc. The jet brightness falls off more slowly inside 1 kpc than in other powerful sources. A search for compact structure in the three bright hot spots revealed no structure lower than 3 mas in size with flux greater than 6 mJy.
    Keywords: ASTROPHYSICS
    Type: Astrophysical Journal, Part 1 (ISSN 0004-637X); 295; 463-465
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  • 95
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    Effects of viscosity and modes on transonic aerodynamic and aeroelastic characteristics of wings (1985)
    In:  Other Sources
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    Publication Date: 2011-08-19
    Keywords: AERODYNAMICS
    Type: Journal of Aircraft (ISSN 0021-8669); 22; 756-762
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  • 96
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    Convergence characteristics of a vortex-lattice method for nonlinear configuration aerodynamics (1985)
    In:  Other Sources
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    Publication Date: 2011-08-19
    Keywords: AERODYNAMICS
    Type: Journal of Aircraft (ISSN 0021-8669); 22; 743-749
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  • 97
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    Navier-Stokes computations of projectile base flow with and without mass injection (1985)
    In:  Other Sources
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    Publication Date: 2011-08-19
    Keywords: AERODYNAMICS
    Type: AIAA Journal (ISSN 0001-1452); 23; 1348-135
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  • 98
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    Comparison of supercritical airfoil flow calculations with wind tunnel results (1985)
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    Publication Date: 2011-08-19
    Keywords: AERODYNAMICS
    Type: AIAA Journal (ISSN 0001-1452); 23; 1301-130
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  • 99
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    The C-12/C-13 isotope ratio toward Zeta Ophiuchi (1985)
    In:  Other Sources
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    Publication Date: 2011-08-19
    Description: Observations of interstellar CH(+) toward Zeta Oph were performed to determine the C-12/C-13 isotope ratio in this diffuse cloud. The very high signal-to-noise ratio spectra yield 6 sigma detections of the (C-13)H(+) features at 4232 A and 3957 A; a weighted mean C-12/C-13 ratio of 43 + or - 6 (1 sigma) is obtained. The uncertainty includes the contribution of continuum placement errors, statistical channel-to-channel signal fluctuations, and the error introduced in deconvolving the blended isotopic lines at 4232 A. This result indicates a decrease in the local galactic C-12/C-13 ratio by a factor of 2 during the 4.6 billion yr since the formation of the sun.
    Keywords: ASTROPHYSICS
    Type: Astrophysical Journal, Part 2 - Letters to the Editor (ISSN 0004-637X); 294; L131-L13
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  • 100
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    An optical measurement of the population inversion of the ground state Lambda doublet of interstellar CH (1985)
    In:  Other Sources
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    Publication Date: 2011-08-19
    Keywords: ASTROPHYSICS
    Type: Astrophysical Journal, Part 1 (ISSN 0004-637X); 294; 238-241
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