ALBERT

Description: This paper presents the results of a series of total and spectral solar irradiance measurements made at ground surface (Table Mountain Facility, Calif., altitude 2.18 km). The spectral irradiance data are presented for the 0.3-3.0-micron spectral region for air mass 1.5.

Description: A proposal for a multi-institutional investigation of the processes involved in the growth and maintenance of high level extended clouds is presented. Mapping of variability of the cloud and of its radiative characteristics in terms of the meteorological environment of the cloud; performance of case studies involving observation of the cloud microphysics and radiation characteristics; and investigation of the processes responsible for the generation, maintenance, and dissipation of the cloud system are recommended. Both modeling and monitoring activities are considered. The specific research projects which the author proposes to carry out are described. Suggestions for the administrative organization of the total effort are presented.

Description: The interplay of the various physical processes involved in the formation, maintenance, and decay of middle and upper tropospheric stratiform clouds is discussed. Ice phase fair weather cloud forms are considered. Simulations of cirriform clouds which attempt to incorporate the physical processes in an interactive manner were performed. A two dimensional time dependent Eulerian numerical model, which incorporates all of the important physical processes in a simplified way, is employed to investigate the role of these processes in the evolution of a cloud in an isolated atmospheric layer. Physical parameters considered are the eddy viscosity and the thermal, water vapor, and ice water eddy diffusivities.

Description: Solid rocket booster cavity collapse flight measurements included external pressures on the motor case and aft skirt, internal motor case pressures, accelerometers located in the forward skirt, mid-body area, and aft skirt, as well as strain gages located on the skin of the motor case. This flight data yielded applied pressure longitudinal and circumferential distributions which compare well with model test predictions. The internal motor case ullage pressure, which is below atmospheric due to the rapid cooling of the hot internal gas, was more severe (lower) than anticipated due to the ullage gas being hotter than predicted. The structural dynamic response characteristics were as expected. Structural ring and wall damage are detailed and are considered to be attributable to the direct application of cavity collapse pressure combined with the structurally destabilizing, low internal motor case pressure.

Description: Stratospheric limb radiance profiles versus altitude of closest approach of the line of sight to the Earth's surface have been measured before and after the Mount St. Helens eruptions by means of photographs taken from a Sun-oriented balloon gondola floating above 35 km altitude over France. Preliminary data were reported for flights in October 1979 and in May and June 1980. The radiance integrated along the line of sight as in-situ radiance (R) can be derived taking into account absorption by ozone and air. The onion peeling inversion method was used to derive the vertical radiance (R) profiles respectively. The values of R were determined in the solar azimuth. The solar elevation angles are chosen larger for the backscattering observation than for the forward scattering observation to deal with as similar illumination conditions as possible despite the Earth's sphericity.

Description: Microscopical investigation of volcanic ash collected from ground stations during Mount St. Helens eruptions reveal a distinctive bimodel size distribution with high concentrations of particle ranges at (1) 200-100 microns and (2) 20-0.1 microns. Close examination of individual particles shows that most larger ones are solidified magma particles of porous pumice with numerous gas bubbles in the interior and the smaller ones are all glassy fragments without any detectable gas bubbles. Elemental analysis demonstrates that the fine fragments all have a composition similar to that of the larger pumice particles. Laboratory experiments suggest that the formation of the fine fragments is by bursting of glassy bubbles from a partially solidified surface of a crystallizing molten magma particle. The production of gas bubbles is due to the release of absorbed gases in molten magma particles when solubility decreases during phase transition. Diffusion cloud chamber experiments strongly indicate that sub-micron volcanic fragments are highly hygroscopic and extremely active as cloud condensation nuclei. Ice crystals also are evidently formed on those fragments in a supercooled (-20 C) cloud chamber. It has been reported that charge generation from ocean volcanic eruptions is due to contact of molten lava with sea water. This seems to be insufficient to explain the observed rapid and intense lightning activities over Mount St. Helens eruptions. Therefore, a hypothesis is presented here that highly electrically charged fine solid fragments are ejected by bursting of gas bubbles from the surface of a crystallizing molten magma particles.

Description: The direct solar radiation transmission record at Mauna Loa, dating from 1958 to the present, revealed with remarkable precision the presence of stratospheric aerosol from volcanic activity. This record can be used to quantify the intensity of the stratospheric volcanic aerosol perturbation following a significant eruption in reference to the Agung event in 1963. The Mount St. Helens' stratospheric cloud was first detected by lidar at 18 km over Mauna Loa on 17 July. The atmospheric transmission was seen to decrease slightly after that time, but only a few tenths of 1 percent. Although it is still fairly early to draw a definite conclusion on the ultimate magnitude of the Mount St. Helens stratospheric aerosol from the Mauna Loa results, it can be stated that the stratospheric aerosol optical depth presently observed is comparable with that observed from Fuego which erupted in 1974. At Boulder, Colorado, the atmospheric debris from Mount St. Helens was observed by lidar on a number of occasions. Also, observations of the diffuse, total and direct transmission of solar radiation were made on June 3 and 4. The latter set of observations is useful for deriving information on the scattering properties of the volcanic cloud. The lidar and solar radiation data are presented and some of their special features are discussed.

Description: Samples of stratospheric aerosols collected with U-2 aircraft for several months following the first three major eruptions of Mount St. Helens were analyzed for ash and liquid acid content. Ash grain sizes and compositions vary depending on collection altitude, location within the drifting cloud, and days following their injection. s computers Size distributions of ash particles vary with altitude. Generally small particles are depleted more rapidly at low altitudes (12 km) than at higher altitudes (17-18 km). Although samples collected 1 day after the first eruption of May 18, 1980, were dry, flow marks on the aircraft indicated parts of the cloud contained heavy acid concentrations. Indeed, all other samples obtained within 1 to 4 days after later eruptions (May 25 and June 12, 1980) were covered with copious amounts of liquid acid. Proportions of liquid to ash varied considerably depending on sampling location and cloud age. Because the acid-coated ash globules were large, they rapidly fell from the stratosphere until, by late June 1980, only a residue of acid droplets remained. Size distributions and concentrations of these droplets varied considerably.

Description: The random vibration of the components of the space shuttle causing internal cargo bay acoustic impingement on the payload was investigated. The import factors to be considered in the design of acoustically loaded structures are the prediction of acoustic environment, prediction of structural response to this environment, and to determine the effect of the response on the structural strength requirements. Two basic responses were analyzed. The primary structure response due to random vibration is first analyzed. The output of primary structure response is used as an input to the secondary structure to calculate the component response.

Description: Raypaths for decametric wavelength radiation in Jupiter's magnetosphere were calculated. The model-dependent raypaths with the Voyager observations were compared. Characteristics of the source regions and the influence of propagation effects were deduced. A three dimensional ray tracing program was employed to calculate the raypaths. Families of rays were launched at particular angles with respect to the magnetic field lines to generate conical sheets of radiation for various frequencies and various source locations. As the planet's magnetic field rotates, these warped sheets of radiation sweep past the observer, producing signatures in frequency versus time plots. These signatures match some of those found in the Voyager data. The greatest propagation effects occur in and around the source regions in the Io auroral oval.

Description: In the Solar Power Satellite system, the antenna's misalignment will produce well defined grating lobes. These gratings lobe peaks occur every 440 km and are potentially hazardous to the environment. One way to suppress these peaks is to phase control every power module. The cost due to the increase in receiving electronics and processors, however, could prove to be prohibitive. A new design of the antenna involving the addition of two broad gaps, one along the x axis and another along the y axis is proposed. The gap distance is exactly one half of the distance between the center of two neighboring subarrays. Calculation of far field radiation patterns shows that the design reduces grating lobe peaks without sacrificing power in the main lobe.

Description: The elastic membrane equations which describe the deflection of a biaxially tensioned reflective mesh from an idealized surface were developed and solved. The conditions of equilibrium of the forces acting on a membrane element furnish equations which may be used to solve a variety of problems. Configurations considered include continuous, as well as incremental mesh attachment to structural members to form shapes which are approximately parabolic or spherical.

Description: Nineteen stratospheric samples from the eruption plumes of Mount St. Helens were collected in five flight experiments. The plume samples were collected at various altitudes from 13.1 to 20.7 km by using the Ames cryogenic sampling system on board the NASA U-2 aircraft. The enriched, cryogenically collected samples were analyzed by chromatography. The concentrations of aerosols precursor gases (OCS, SO2, and CS2), CH3Cl, N2O, CF2Cl2, and CFCl3 were measured by gas chromatography. Large enhancement of the mixing ratio of SO2 and moderate enhancement of CS2 and OCS were found in the plume samples compared with similar measurement under pre-volcanic conditions. A fast decay rate of the SO2 mixing ratio in the plume was observed. Measurement of Cl(-), SO2(2-), and NO3(-) by ion chromatography was also carried out on water solutions prepared from the plume samples. The results obtained with this technique imply large mixing ratios of HCl, (NO + NO2 + HNO3), and SO2, in which these constituents are the respective sources of the anions. Measurement of the Rn222 concentration in the plume was made. Other stratospheric constituents in the plume samples, such as H2O, CO2, CH4, and CO, were also observed.

Description: Mount St. Helens erupted somewhat less than 0.5 cu km of magma (dense rock equivalent) on May 18, 1980. The May 18 event was usually violent. As much 35% of the volume of the airfall material fell outside of the 2.5 mm isopach, which encloses about 88,000 sq km. This extraordinary dispersive power was transmitted by an eruption column which reached heights of more than 20 km. There was a lateral blast (or surge) of unusually large dimensions associated with the onset of the eruption. The magma is dacitic in composition and had a low ( 500 ppm) sulfur content. Distal ashes contain much nonmagmatic (lithic) material, but smaller ( 50 microns m) particles are mostly finely divided magmatic dacite. The grain size distributions of the ash are multimodal, frequently with peaks at 90, 25, and 10 microns. The finer populations fell out faster than their terminal velocities as simple particles would suggest. It is inferred that large proportions of the fine ash fell out as composite particles. This condition greatly reduces the atmospheric burden of silicate particles. Some of the unusual aspects (violence, intense surges, multimodal grain size distributions, lithic content of the ashes) of the eruption may be due to its phreatomagmatic character. The hydrothermal system above the magma may have infiltrated the magma body at the onset of the eruption. An "overprint" of the geochemistry of this hydrothermal system on the geochemistry of the magmatic gas system is likely. One important feature is that reduced gas species may be much more abundant than in many eruptions. Another is that fine ash may form aggregates more readily.

Description: Disturbances of the atmosphere at heights of 120 to 40 km by penetration of meteroids of meter and decameter dimensions were examined. Unbiased data on atmospheric penetration of large meteroids was acquired, and their supply of gas and dust components to the middle atmosphere and their connection with the noctilucent clouds were determined.

Description: The goals of map/wind (winter in Northern Europe) are to better understand: (1) the interaction of planetary waves of tropospheric origin; (2) the temporal and spatial development of sudden stratospheric warmings; (3) the temporal and spatial development of mesospheric cooling events in conjunction with stratospheric warmings; (4) the vertical and horizontal transport of minor constituents; (5) the effects on the chemistry of neutral and charged species of the large temperature changes occurring during stratospheric warmings and mesospheric cooling; (6) sources of turbulent energy; (7) the temporal and spatial development of turbulent layers; and (8) the contributions of dynamical processes to the heating and cooling of the mesospheric and turbopause region.

Description: Three general areas of study were identified: stratospheric composition; mesospheric and lower ionospheric structure and composition; and middle atmospheric dynamics. The role of chemical reactions and spectroscope in the study of the middle atmosphere is discussed.

Description: Organizations in the United States which are interested in MAP participation were surveyed. Satellites, rockets, balloons, and ground support systems are listed with available experimentation.

Description: The plans for India's participation in the middle Atmosphere Program are outlined.

Description: Contaminated impact crater formations are pertinent to the study of meteoritic contamination at the Cretaceous-Tertiary boundary and other Ir-enriched layers. Target mixing considerations and volumetric estimates of Rochechouart breccias are presently combined with the geochemistry of both major and siderophile trace elements, to evaluate how the chemistry of the preserved target rock-projectile mixture evolved since deposition. Over 99 percent of the mass of extraterrestrial Ir and Os in preserved formations at Rochechouart is located in suevite-like breccias and impact melts. Hydrothermal alteration and/or weathering are the most likely processes to explain both major and trace element redistribution in Rochechouart formations.

Description: Current development activities at JPL for ground mobile vehicle antennas to be used with the Land Mobile Satellite Service (LMSS) system are described. Both low gain and electronically steerable high gain type antennas are discussed in terms of their design concept and RF performance. For the low gain type, three classes of antennas are under various stages of development. These are the crossed-drooping dipole, quadrifilar helix, and microstrip patch designs. The antennas are intended to provide circularly-polarized radiation with a minimum of 3-dB gain in the angular region from 19 degrees to 60 deg from the horizon in elevation plane and with an omnidirectional pattern in azimuthal plane. For the electronically steerable high gain type, circularly-polarized microstrip patch phased arrays formed on a planar surface and on the surface of a truncated cone are under study. The arrays are intended to provide a minimum of 12 dB gain in the same angular region in elevation plane at all azimuthal angles. This coverage is accomplished by scanning the high gain pencil beam in both elevation and azimuthal directions. Both types of antennas are to transmit at 821-831 MHz band and to receive at 866-876 MHz band. They must be of low cost design and reasonably conformal to the vehicle.

Description: The advanced communications technology satellite (ACTS) program of NASA is aimed at the development of high risk technologies that will enable exploiting higher frequency bands and techniques for improving frequency reuse. The technologies under development include multiple beam spacecraft antennas, on-board switching and processing, RF devices and components and advanced earth stations. The program focus is on the Ka-band (30/20 GHz) as the implementing frequency since it has five times the bandwidth of either the C- or Ku-bands. However, the technology being developed is applicable to other frequency bands as well and will support a wide range of future communications systems required by NASA, other Government agencies and the commercial sector. An overview is presented of an operational 30/20 GHz satellite system that may evolve. How the system addresses service requirements is discussed, and the technology required and being developed is considered. Previously announced in STAR as N83-11210

Description: A conceptual design for a Land Mobile Satellite System (LMSS) for the 1990s is presented. LMSS involves small tranceivers accessing satellites directly, with ground reception through small car-top antennas. The satellite would have a large antenna and blanket coverage areas in the UHF. The call may originate from a home, be carried by wire to a gateway, transmitted to satellite on the S-band, converted to UHF on the satellite, and transmitted to the vehicle. The system design is constrained by the number of users in an area during the busiest hours, Shuttle storage, controllability factors, and the total area served. A 55-m antenna has been selected, with 87 spot beams and two 10 MHz UHF bands in the 806-890 MHz band. A 17 dB interbeam isolation level is required, implying that sufficient sub-bands can be generated to assure 8265 total channels. The mobile satellite (MSAT) would have an 83 m mast lower segment, a 34 m upper segment, and a second, 10 m antenna made of a deployable mesh. Various antenna function modes are considered.

Description: The technique outlined in this paper is intended to eliminate the problems of cochannel interference and uniform geographic distribution of user channels which arise in conventional designs for a multiple spot beam communication satellite to serve mobile telephony users across the CONUS. By time multiplexing FM/FDMA signal ensembles so that only those beams operating on distinct frequency subbands are allowed to transmit concurrently, cochannel interference arising from simultaneous frequency subband reuse is precluded. Thus, time disjoint frequency reuse is accomplished over a repetitive sequence of fixed time slots. By assigning different size subbands to each time slot, a market of nonuniform users can be accommodated. The technique results in a greatly simplified antenna feed system design for the satellite, at a cost of imposing the need for time slot synchronization on the mobile FM receivers whose ability for rejecting adjacent channel interference is somewhat diminished.

Description: Several hundred topside ionograms were used to study simulated wave-particle interactions in the ionosphere. The study combined the benefits of high-frequency-resolution Alouette 2 analog sounder data with advanced digital graphics techniques. The study shows that the sounder phase can cause significant plasma heating when the plasma parameter is confined to specific ranges. The observations support the Harris instability generation process and the nonlinear Landau damping maintaining process for long-duration diffuse resonances. The observations also suggest that the so-called Q resonances have characteristics which imply that generation processes in a sounder-stimulated plasma turbulence may be involved.

Description: A technique is presented for computing a set of normal modes from a set of measured complex modes. The number of elements in the modal vectors, which is equal to the number of measurements, can be larger than the number of modes under consideration. It is also shown that the practice of normal mode approximation to complex modes can lead to very large errors when the modes are too complex. A numerical example and a simulated experiment illustrate the concepts discussed and support the theory presented.

Description: The finite element method, modal component synthesis, and the use of fast Fourier transformation were key developments in structural dynamics in the past 15 to 20 years. Current areas requiring additional effort include: (1) the correct calculation of modal shape and natural frequencies for complex structures; (2) the correlation of math models with test data; (3) the establishment of a criteria for "goodness" of the correlation between analysis and test; (4) the selection of the correct displacement functions when using computer programs for modal synthesis; (5) accuracy of response calculations; and (6) the inverse problem of determining the force problem from the response data. Trends identified include the use of distributed computing, greater reliance on analysis, and the possible use of artificial intelligence techniques, or some way of feeding back information, to provide solution guidance to engineers.

Description: The telecommunications system interfaces between the spacecraft and the space shuttle, and between the spacecraft and the Tracking and Data Relay Satellite System (TDRSS) are discussed. The payload/shuttle/ground communications network, principle end-to-end link configurations, and requirements for attached and detached payloads are addressed.

Description: The computer software used for telecommunications performance analysis and monitoring is discussed. The utilization of the TPAP analysis program for the Viking 1975 project and the Voyager 1977 project is described. The functional and design requirements for the successor system, TPAS, are also given.

Description: The bands available for deep-space communications, and the choice of particular mission frequencies are discussed. The more general susceptibility of deep-space Earth stations to various kinds of interference is then presented. An associated topic is the development of protection criteria that specify maximum allowable levels of interference. Next, the prediction of interference from near-Earth satellites is described, with particular emphasis on the problems and uncertainties of such predictions. Finally, a brief description of other activities aimed at the prevention or avoidance of interference to deep-space radio communications is given.

Description: A tutorial description is given for spacecraft antennas used for deep-space-to-Earth communication. Radiation pattern parameters, pointing errors, pointing and polarization loss, and noise characteristics are discussed.

Description: The historical background for the development of the planetary (RFS) is reviewed, and the performance capabilities of the various functional subassemblies are described. The flight radio frequency subsystem is a valid component for the three spacecraft telecommunications functions of tracking, command, and telemetry. It is the radio and the signal processing equipment residing in the spacecraft that interfaces with the control & data subsystem and performs two-way communications with the Earth-based Deep Space Network. The RFS consists of all the elements for RF reception, demodulation, modulation, and transmission, including those for command detection and telemetry modulation.

Description: The Multimission Command (MMC) System is described. The major components within the MMC System are discussed, with the emphasis on the telecommunication-related implementations. Two versions of the spacecraft command detection system (the Viking heritage command detector and the NASA standard command detector) are discussed in detail. The former prevails in the existing flight projects and the latter will likely be adopted by the missions of the near future. The preparation of design control tables for the control of command link performance between deep space stations and the spacecraft is also discussed.

Description: The basic design, principles of operation, and characteristics of deep space communications receivers are examined. In particular, the basic fundamentals of phase-locked loop and Costas loop receivers used for synchronization, tracking, and demodulation of phase-coherent signals in residual carrier and suppressed carrier systems are addressed.

Description: The importance of the bandwidth required for transmitting the chosen signaling or modulation technique in evaluating efficiency of a communication system is noted. The direct relation between bandwidth and the power spectral density (PSD) of the signaling scheme makes efficient analytical methods for calculating the PSD essential to specifying the spectral occupancy of the transmission channel. Several techniques for calculating the PSD of synchronous data pulse streams are reviewed.

Description: The general configuration of deep space telecommunication systems is reviewed with regard to the design criteria necessary to insure the integrity of the system's telemetry, command, and tracking functions. The signal to noise spectral density ratios that characterize telecommunications performance are defined in terms of the link parameters. For design control, a statistical approach to predict link performance and to assess its uncertainty is described.

Description: Eight comets were observed with the IUE at various-heliocentric and geocentric distances. Their UV spectra are remarkably similar despite the large differences in the dust to gas ratios. Since all the dominant atomic species (except N) radicals and ions of the coma are detected in this spectral region, the total gaseous output of the nucleus can be estimated. The abundance of the carbon atom-bearing species is still not very well known and there are indications that the CO content of the coma could vary from comet to comet.

Description: The initial phase of the photometry which involved 17 meteor spectra consisting of eight Geminid spectra, six Orionid spectra and three Eta Aquarid spectra is discussed. Among these 17 spectra it is found that the Geminid spectra are of the best quality and are used for the identification of the atomic lines and molecular bands that normally appear on video tape spectra. The data from the Geminid records are used for developing calibration techniques in photometry. The Orionid and Eta Aquarid spectra are chosen for early analysis because of the current interest in all physical and chemical data relating to Comet Halley.

Description: The use of automatic multi-stage substructing analysis is demonstrated for a hypothetical case of a GAS container supported by structural channels with a simulated experimental package inside the container. The GAS program purpose is stated and potential candidate structures to support experimental packages are discussed. The GAS container model and the substructuring analysis capabilities of NASTRAN make it possible to study the experiments inside the container as well as the design constraints resulting from the support structures holding the containers. The use of substructuring in the GAS program could be an important factor in increasing the number of flight opportunities.

Description: The effects of chemical composition of the lava, physical processes of volcanic formation, and lava flow lengths on the morphology of Earth volcanoes were investigated. Difficulties in investigating volcanic morphology are discussed.

Description: The chemistry and evolution of Titan's atmosphere are reviewed, in light of the scientific findings from the Voyager mission. It is argued that the present N2 atmosphere may be Titan's initial atmosphere, rather than one photochemically derived from an original NH3 atmosphere. The escape rate of hydrogen from Titan is controlled by photochemical production from hydrocarbons. CH4 is irreversibly converted to less hydrogen-rich hydrocarbons, which over geologic time accumulate on the surface to a layer thickness of about 0.5 km. Magnetospheric electrons interacting with Titan's exosphere may dissociate enough N2 into hot, escaping N atoms to remove about 0.2 of Titan's present atmosphere over geologic time. The energy dissipation of magnetospheric electrons exceeds solar EUV energy deposition in Titan's atmosphere by an order of magnitude, and is the principal driver of nitrogen photochemistry. The environmental conditions in Titan's upper atmosphere are favorable to building up complex molecules, particularly in the north polar cap region.

Description: Estimates are made showing that, as a consequence of rocket activity in the earth's upper atmosphere in the Shuttle era, average ice nuclei concentrations in the upper atmosphere could increase by a factor of two, and that an aluminum dust layer weighing up to 1000 tons might eventually form in the lower atmosphere. The concentrations of Space Shuttle ice nuclei (SSIN) in the upper troposphere and lower stratosphere were estimated by taking into account the composition of the particles, the extent of surface poisoning, and the size of the particles. Calculated stratospheric size distributions at 20 km with Space Shuttle particulate injection, calculated SSIN concentrations at 10 and 20 km altitude corresponding to different water vapor/ice supersaturations, and predicted SSIN concentrations in the lower stratosphere and upper troposphere are shown.

Description: The first measurements of the production of nitric oxide (NO) by a laboratory discharge in a simulated Venus atmosphere are presented. The average NO yield over a range of energies was found to be 3.7 + or - 0.7 x 10 to the 15th molecules/joule. Simultaneous measurements of carbon monoxide (CO) resulting from the lightning-induced dissociation of carbon dioxide (CO2) indicated a CO yield of about 4 x 10 to the 17th molecules/joule. These measurements suggest that at and below cloud level, a region where solar ultraviolet radiation cannot penetrate, the dissociation of CO2 by lightning may be a significant source of oxygen atoms. Depending on the assumed value for the total energy dissipated by lightning on Venus, the production of NO by lightning may be a significant sink of atmospheric nitrogen over the history of Venus.

Description: (Previously announced in STAR as N82-18106)

Description: The influence of the geographical distribution and the number of the surface stations in the ozone detecting network on changes in global ozone inferred from the surface measurements is investigated by comparison with information obtained from satellite backscattered UV observations on the Nimbus 4 with nearly complete global coverage for the period 1970-1972. Results show that the geographical distribution of the stations does not properly represent different latitudes. While the number of stations in the north temperate zone appears adequate to represent monthly ozone averages to within 0.5% except during the early phase of the Northern Hemisphere spring maximum, the resultant error in the derived change in north temperature zone ozone between 1970-1972 is 0.5%. In the tropical and south temperate zones the smaller number of stations reduces precision, and the ozone averages for use in deriving seasonal variability and trends are uncertain by about 1%. However, in the south temperature zone, the average from the sample may differ as much as 5% in some months from the averages derived from the full set. It is concluded that the resulting uncertainty in the global averages is comparable in size to typical yearly changes.

Description: The current understanding of the manner in which astronomical variations modulate the Martian climate and thereby lead to the occurrence of laminated polar terrain is considered. The seasonal cycles of dust, carbon dioxide and water, and their responses to astronomical variations, are studied. After an assessment of the way in which these cycles presently operate, for which pertinent spacecraft and ground-based observations are extant, attempts to predict how these cycles may differ under conditions of high and low obliquity and eccentricity are discussed. Attention is given not only to those areas in which there is broad agreement, but also to the controversial and speculative. Key questions include the proportion of dust and water ice in the laminae and its variations within individual layers, the relative importance of older laminae and lower-latitude material as sources of new laminae, and the factors responsible for the youth of the laminated terrain.

Description: Photoclinometry is useful for the determination of topography for areas which have a uniform albedo. The technique is applied to early spring Viking images of the Martian north polar cap, taken when the surface was covered by a nearly uniform frost cover. Unlike earlier approaches, the topographic profiling can be used for surfaces with any photometric function, but the strike of the planetary surface relative to the illumination angle must be specified along the profile. The resultant profiles are relatively insensitive to misestimation of the photometric function and slope orientation, but are quite sensitive to the assumed values of the reflectance of an equivalent level surface and the atmospheric opacity (if it is large).

Description: The boundary between the inner and outer parts of Saturn's B ring is located at the theoretical limit of stability of dust grains with large negative charge to mass ratio. A grain inside of this stability limit will move along magnetic field lines and strike Saturn if given a slight velocity component normal to the ring plane. Outside of this marginal stability radius, a perturbed grain merely oscillates back and forth through the ring plane. The theoretical location of the marginal stability radius is at 1.625 Saturn radius. Observations by Pioneer 11 and Voyager 2 in the infared see the boundary as a prominent change in ring brightness at this radius. The occultation of delta-Scorpii by the rings in the ultraviolet seen by Voyager 2 shows about a factor of two change in optical depth beginning very close to this radius.

Description: The effects of the earth's atmosphere on the Thematic Mapper (TM) measurements are studied with two radiative transfer models. A doubling model is used to compute the effective reflectance of the earth-atmosphere system, as measured by the TM for the reflective bands. An emission-transmission model is used to compute the satellite-received radiance for the thermal band. The influences of the aerosol loading, the amount of water vapor, and the solar illumination angle on the effective reflectance are investigated. The effect of varying atmospheric water vapor on the measurements of the thermal band is studied. The scattering and absorption effects on TM bands are compared with those on Multispectral Scanner System (MSS) bands. While the changes in the aerosol loading introduce comparable variation of the effective reflectance for both sensors, the changes in the water vapor amount give less impact on TM4 than MSS7.

Description: Solar ultraviolet flux data obtained within the atmosphere by using Fastie-Ebert double monochromators carried on a balloon-borne gondola and a rocket payload are analyzed. Both the direct and scattered components of the solar ultraviolet flux at wavelengths from 190 to 320 nm are measured at the balloon float altitude of 40 km. The nearly identical spectrometer carried on the rocket flight measures the direct solar flux from 60 to 38 km during a parachute descent. The ozone column content above 40 km and the temperature profile and ozone density below 40 km are deduced using the scattered and direct solar flux components. It is shown that the Nimbus 7 solar flux data are consistent with the present data and with the ozone absorption cross sections of Inn and Tanake (1959). The calculated and measured values of the scattered solar flux are found to agree fairly closely.

Description: The influence of the choice of the Lagrange multiplier on constrained linear inversions is explored, with reference made to applications in inferring the columnar aerosol size distributions from spectral aerosol optical depth measurements. A range of the Lagrange multiplier is examined to find all positive solutions for the solution vector, which represents modifying factors to the assumed form of the size distribution. An iterative method is devised to constrain the calculations to consideration of only positive quantities and a requirement that the regression fit to data be consistent with measurement errors. The determination of the variances and covariances is formulated and applied to existing data sets for optical depth. Variances in the solution are found to be large for particle radii when the information content of the data is small.

Description: Soil fines exposed on the lunar surface accumulate small metallic iron particles and solar wind-derived carbon. In previous work, it has been suggested that an intimate association exists between one particular carbon phase, hydrolysable carbon, and very fine iron droplets, where the carbon is in solid solution in the iron. The earlier hypothesis of a constant carbon in iron concentration across a broad range of droplet sizes is testable by combining hydrolysable carbon determinations with a variety of magnetic measurements sensitive to different droplet diameters. New measurements of ferromagnetic resonance response on density and magnetic separates from size fractions of soil 12023 are interpreted as evidence that hydrolysable carbon is preferentially associated with the larger, magnetically stable single-domain iron particles rather than with the smaller superparamagnetic droplets. For the former, there is a quite uniform ratio of iron to carbon both within a series of separates from a single soil, and among soils of widely varying FeO content.

Description: New line assignments in the spectrum of the stratospheric submillimeter emission, measured with unapodized resolution of 0.0033/cm, have been made. Positive evidence for the presence of symmetric and asymmetric ozone isotopes, water vapor excited to the (010) level, and HCN is given.

Description: During its April 1979 eruption series, Soufriere Volcano produced two major stratospheric plumes that the SAGE (Stratospheric Aerosol and Gas Experiment) satellite system tracked to West Africa and the North Atlantic Ocean. The total mass of these plumes, whose movement and dispersion are in agreement with those deduced from meteorological data and dispersion theory, was less than 0.5 percent of the global stratospheric aerosol burden; no significant temperature or climate perturbation is therefore expected.

Description: At the time of the Soufriere, St. Vincent, volcanic eruption of April 17, 1979, a NASA P-3 aircraft with an uplooking lidar (light detection and ranging) system onboard was airborne 130 kilometers east of the island. Lidar measurements of the fresh volcanic ash were made approximately 2 hours after the eruption, 120 kilometers to the northeast and east. On the evening of April 18, the airborne lidar, on a southerly flight track, detected significant amounts of stratospheric material in layers at 16, 17, 18, and 19.5 kilometers. These data, and measurements to the north on April 19, indicate that the volcanic plume penetrated the stratosphere to an altitude of about 20 kilometers and moved south during the first 48 hours after the eruption.

Description: The radio occultation technique, as applied to Saturn's rings, is developed as a new method for the study of the physical properties of planetary ring systems. The rings are treated as a Doppler-spread radar target composed of an ensemble of discrete scatterers. The mathematical formulation of the received signal as a random-phasor-sum process is carried out following a conventional radar theory approach, providing a convenient starting point for deriving coherent signal parameters. A classical result is rederived for the equivalent refractive index of the medium. The analysis is generalized to include ringlets of arbitrary width and it is shown that when the width is such that two adjacent rays are differentially perturbed in phase, ray bending that causes focusing of the coherent signal may result. The diffuse component is also treated in detail.

Description: Advances in satellite tracking data accuracy and coverage over the past 15 years have led to major improvements in global geopotential models. But the spacial resolution of the gravity field obtained solely from satellite dynamics sensed by tracking data is still of the order of 1000 km. Attention is given to an approach which will provide information regarding the fine structure of the gravity field on the basis of an application of local corrections to the global field. According to this approach, a basic satellite to satellite tracked (SST) range-rate measurement is constructed from the link between a ground station, a geosynchronous satellite (ATS 6), and a near-earth satellite (Apollo or GEOS 3). Attention is given to a mathematical model, the simulation of SST gravity anomaly estimation accuracies, a gravity anomaly estimation from GEOS 3/ATS 6 and Apollo/ATS 6 SST observations, and an evaluation of the mean gravity anomalies determined from SST.

Description: Data on the thermal structure of the nightside middle atmosphere of Venus, from 84 to 137 km altitude, have been obtained from analysis of deceleration measurements from the third Pioneer Venus small probe, the night probe, which entered the atmosphere near the midnight meridian at 27 deg S latitude. Comparison of the midnight sounding with the morning sounding at 31 deg S latitude indicates that the temperature structure is essentially diurnally invariant up to 100 km, above which the nightside structure diverges sharply from the dayside toward lower temperatures. Very large diurnal pressure differences develop above 100 km with dayside pressure ten times that on the nightside at 126 km altitude. This has major implications for upper atmospheric dynamics. The data are compared with the measurements of Keating et al. (1980) above 140 km, with theoretical thermal structure models of Dickinson, and with data obtained by Russian Venera spacecraft below 100 km. Midnight temperatures are approximately 130 K, somewhat warmer than those reported by Keating et al.

Description: Global magnetic component anomaly field maps have been derived from the Magsat vector magnetometer data obtained from November 1979 through May 1980. The amplitude of variations of the components over the maps are between 10 and 15 nT, well above the noise in the data. Averaged data, in 2-by-2 deg blocks, exhibit standard errors of the mean of about 1 nT over most of the X and Z maps, and about 2 nT over most of the Y maps. Errors rise to about twice these amounts near the auroral belts. Most of the anomalies in the component data are consistent with a crustal magnetization model which incorporates dipoles aligned only in the direction of the main field. However, there appear to be some regions which require dipoles aligned in some other direction i.e., remanent magnetization.

Description: Initial results of the Magsat mission are presented, in keeping with the categories of earth core field, the crustal or anomaly field of the earth, and external fields. It is noted that one major advantage of orbital magnetic field surveys is their ability to obtain a global set of magnetic field measurements of uniform precision and accuracy at a single epoch, aiding the derivation of the core field models that are a prerequisite for further data analysis. The ability to isolate fields from crustal sources was unexpected, because of the low amplitudes of such fields by comparison with those of the core and those external to the earth. The most significant external-field finding has been an east-west component variation near the dip equator.

Description: Studies of Birkeland current systems have been conducted primarily with low altitude satellite magnetometer data whereas electrojet current signatures have been usually analyzed with data from ground-based magnetometer chains. However, the Magsat magnetometer data set allows magnetic disturbances due to both field-aligned and electrojet currents to be examined simultaneously. This is mainly due to Magsat's approximately 400 km altitude, thus providing data closer to the electrojet current system than has been previously available from satellite measurements. Of additional importance are the superior accuracy, both in sensitivity and altitude, of the magnetic field measurements obtained by Magsat and last, but not least, the availability of an accurate magnetic field model of the concurrent epoch (based on the Magsat data set) that allows one to obtain a better baseline than previous models. The aforementioned points are emphasized and both Birkeland and electrojet currents have been analyzed in a case study for November 13, 1979.

Description: Transverse magnetic disturbances associated with Birkeland currents have been measured by the Magsat and TRIAD spacecraft, whose orbits were nearly coplanar from November to mid-December, 1979. A comparison of data received when the satellites were over the TRIAD/Chatanika receiving station shows that 75% of magnetic disturbance measurements are similar in shape and magnitude, with TRIAD peak disturbances being on average 7% larger than those of Magsat. This discrepancy is lower than measurement uncertainties due to baselines and calibration. During periods of higher Kp, despite time separations of as much as 45 min, better agreement is found in the large-scale and well-defined field-aligned current signatures.

Description: An analytical method for the analysis of absorption spectra obtained from the interferograms of an interferometer operated in the solar occultation mode, in which an interferogram is smeared with individual interferogram components generated by the passage of rays at different tangent altitudes, is described. The creation of strong sidelobes on absorption lines by the interferogram smearing leads to the recommendation of a strong apodization on the interferogram for the solar occultation experiment. The application of these concepts to the simultaneous retrieval of temperature and pressure from CO2 4.3-micron band stratospheric absorption spectra includes the analysis of the continuum absorptions by the pressure-induced N2 fundamental bands and by far wings of the CO2 v3 band. Agreement is reported between observed and simulated spectra.

Description: The effect of attenuation in precipitation regions of the sea, which must be considered in order to measure the radar backscatter from the ocean with sufficient accuracy to allow determination of the wind vector, can be ascertained from a knowledge of the brightness temperature observed by a microwave radiometer such as the Seasat multifrequency scanning radiometer. Two algorithms relating radiometric measurements and attenuation, and thereby correcting measured scattering coefficient values, were compared with wind vectors reported by surface observers and those determined by the Seasat scatterometer measurements with and without correction for atmospheric attenuation. Although the attenuation correction yields some improvements, it is constrained by both radiometer footprint differences and different scan patterns.

Description: It is found that the difference between the wet tropospheric corrections obtained with the Seasat Multichannel Microwave Radiometer (SMMR) algorithm and corrections based on near-coincident radiosonde meteorological measurements has a standard deviation of 2.79 cm, which is consistent with the independent value for water vapor determination accuracy reported by the SMMR Evaluation Team. Because the difference between the radiosonde corrections and those obtained by means of interpolated surface meteorological data has a standard deviation of 5.73 cm, the SMMR wet tropospheric correction is recommended for investigations sensitive to the wet tropospheric height correction accuracy.

Description: A nominal atmospheric model of Mars is presented, with detailed consideration being given to the various sources of variability in the Martian atmosphere. A basic model for the midlatitude summer is outlined for the northern and southern hemispheres. Attention is given to meteorological variability due to winds, diurnal and seasonal pressure variations, temperature changes, and the effects of dust opacity, particularly on temperature stratification. Viking lander IR thermal mapper data are examined in terms of diurnal and latitudinal temperature variations, and cloud and haze formation and locations are discussed. Mass spectrometry of the atmosphere is used to describe the molecular abundances, and water vapor measurements are reviewed. Finally, radio occultation, UV airglow, and mass spectrometry of the Martian upper atmosphere are investigated, along with the temperature structure of the upper atmosphere.

Description: Data from the Pioneer Venus radar mapper, combined with measurements of wind velocity and atmospheric composition, suggest that surface erosion on Venus varies with altitude. Calcium- and magnesium-rich weathering products are produced at high altitudes by gas-solid reactions with igneous minerals, then removed into the hotter lowlands by surface winds. These fine-grained weathering products may then rereact with the lower atmosphere and buffer the composition of the observed gases carbon dioxide, water vapor, sulfur dioxide, and hydrogen fluoride in some regions of the surface. This process is a plausible mechanism for the establishment in the lowlands of a calcium-rich mineral assemblage, which had previously been found necessary for the buffering of these species.

Description: No evidence was found for an intrinsic magnetic field, nor for the development of a bow shock wave, as the corotating Saturnian magnetoplasma convected past Titan during the Voyager 1 close encounter of November 12, 1980. The observation of a well-developed, induced bipolar magnetic tail is evidence, however, of a strong electrodynamic interaction. Three thin, current-carrying regions were crossed which correspond to the inbound and outbound tail magnetopause and an imbedded tail neutral sheet. The interaction is unique among those observed to date in the solar system, in that it is intermediate with respect to sonic and Alfvenic Mach numbers by comparison with Titan in the solar wind and Io in the Jovian magnetosphere. The draping of the Saturnian magnetic field around the ionosphere of Titan is suggested by results of the analysis of magnetic field data.

Description: Rapid intensity fluctuations in the optical emission, N2/+/ (4278 A), H-beta (4861 A), and OI (5577 A) have been observed with rocket-borne photometers during a passage through a homogeneous auroral arc. The measurements indicate that relatively weak (2-5%) intensity fluctuations of random nature, with dominant frequencies in the 2-20 Hz range, do exist in the optical emissions of quiet-form auroras. These variations have well-defined averaged spectral characteristics and apparently differ from the strong quasi-periodic type of variations seen during pulsing auroras. It is argued that the observed fluctuations, which are usually composed of weak short-lived microbursts, reflect the temporal and spatial microstructure which apparently exists always within auroral arcs.

Description: A closed-form expression for the steady-state output signal-to-noise ratio (SNR) of an n-element adaptive array excited by one desired narrow-band signal and K - 1 narrow-band jammers is obtained. This is facilitated by representing each excitation by a complex n-dimensional vector - the excitation vector. It is shown that the important system parameters are functions of scalar products of pairs of these excitation vectors. In particular, the normalized output SNR of the array is shown to be the ratio of determinants whose elements involve these scaler products. Such determinants are also shown to be involved in the expressions for the optimal array weights.

Description: An eight node curved thin shell slement was tested. The element is based on the degenerate solid concept and the mixed formulation with the independent inplane and transverse shear strains. The number of unknown parameters in the assumed strains is chosen to alleviate the spurious constaining or locking effect. It is indicated that for a pinched cylindrical shell with diaphragmed ends and fixed ends the present element shows good performance.

Description: During dynamic torsion of beam elements, consideration of nonuniform warping effects involves a more general technical formulation then that of Saint-Venant. Nonclassical torsion constants appear in addition to the well known torsional rigidity. The adaptation of the boundary integral element method to the calculation of these constants for general section shapes is described. The suitability of the formulation is investigated with some examples of thick as well as thin walled cross sections.

Description: An effort to apply the reduced basis method to nonlinear transient thermal analysis is described. The method combines the classical Rayleigh-Ritz and modal superposition techniques with contemporary finite element methods to retain modeling versatility as the degrees of freedom in a problem are reduced. The essence of the method is to use a few thermal modes from eigenvalue analyses as basis vectors to represent the temperature response for a given thermal problem similar to the use of vibration modes to represent displacements in a dynamic response problem. Approximate temperature distributions were obtained using the reduced basis method for a small section of the Shuttle Orbiter lower wing undergoing reentry heating. Good agreement was obtained between the reduced basis method solutions and full system solutions with reductions in the degrees of freedom of up to a factor of four. The good agreement indicates the reduced basis method has the potential for significant reduction in computing effort for thermal analysis; however, considerable work remains to determine techniques for selecting the type and number of basis vectors needed for approximate solutions to more complex transient thermal problems.

Description: The Allan Hills icefield is described by as a limited icefield that has large concentrations of meteorites. The meteorites appear to be concentrated on the lower limb of an ice monocline with other finds scattered throughout the field. In an attempt to understand the mechanisms of meteorite concentration, a triangulation chain was established across the icefield. This chain is composed of 20 stations, two of which are on bedrock, and extends westward from the Allan Hills a distance of 15 kilometers. The triangulation chain and its relationship to the meteorite concentrations is shown.

Description: The selection of preferred frequency bands for deep space telecommunications in the 20 to 120 GHz range is discussed. The performance of links between Earth stations and stations in deep space is affected by the atmosphere of the Earth. Attenuation and emission by the atmosphere generally limits deep space telecommunications to frequencies below 20 GHz. There are, however, certain frequency bands in the 20 to 120 GHz range where atmospheric attenuation is low enough to permit links between Earth stations and deep space stations. Additionally there are certain other bands in the 20 to 120 GHz range that would be particularly suitable for links between an Earth orbiting relay station and deep space stations.

Description: Structural deformations primarily occur as functions of antenna elevation angle due to gravity loading. For a Cassegrain antenna, one of the major effects of structural deformation on measured VLBI time delays are those delay changes associated with axial subreflector displacement from its nominal position. Two types of time delay changes that occur when the subreflector is axially defocused are: a change which is a linear function of subreflector defocus position; and a cyclical change caused by multipath. Test results show that for the 64-m DSN antenna, the linear change is 1.8 times the subreflector defocus position, while the peak-to-peak change in cyclical variation is about + or - 3 cm when a spanned bandwidth of 38 MHz at 2290 MHz is used.

Description: The chemistry of Jupiter's atmosphere is reviewed. The various molecules that were discovered on Jupiter are summarized. The compounds: methane, ammonia water, ethane, acetylene, carbon monoxide, phosphine, and germane.

Description: The spectroscopy of the species H2O, H2O2, and HO2 are discussed. Their vibration rotation transitions are emphasized, but the pure rotational transitions in the vibrational ground state of H2O are also considered since they contribute to opacity in the middle infrared region.

Description: A review of recent progress in the theory of collisional line broadening, particularly the impact of recent advances in collision dynamics calculations is presented. Some new approaches to the interpretation of experimentally measured linewidths and their impact on planetary atmosphere research are discussed. Experimental techniques which may have some advantage in providing pressure broadening data at very low temperatures are also mentioned.

Description: Examples of the role which molecular spectroscopy played in the interpretation of the thermal emission spectra of Earth, Mars, and Jupiter are given. Some advantages of molecular spectroscopy from a spacecraft passing close to a planet, or from an orbiter, over ground based techniques are discussed. Specifically the possibility of obtaining spectra over a wide spectral range (1) without the obscuring effect of Earth's atmosphere, (2) at much higher spatial resolution, and (3) from directions and with phase angles inaccessible from Earth.

Description: A semiempirical physical model of the Jovian subnebula was developed by analogy with the primitive solar nebula itself. The chemical aspects of this model are developed according to the principles developed in the study of the thermochemistry and gas kinetic behavior of the solar nebula, but with important modifications to take into account the higher pressures and densities in the Jovian subnebula. The bulk compositions and densities of the inner satellites of Jupiter are calculated. It is proposed that Europa differs from Io chiefly in that in has suffered a less severe thermal history. The general features of this model are applicable with minor modification to the systems of Saturn and Uranus.

Description: Efforts to increase the amount of data that can be received from outer planet missions by coherently combining signals from ground antennas in such a way as to increase the total effective aperture of the receiving system are discussed. As these signals become weaker, the baseband arraying technique in current use degrades somewhat due to carrier jitter. One solution to this problem is Sideband-Aided Receiver Arraying (SARA). In SARA, sidebands demodulated to baseband in a master receiver at the largest antenna are used to allow slave receivers in the other antennas to track the sideband power in the signal rather than the carrier power. The already existing receivers can be used in the slaves to track and demodulate the signals in either a residual carrier or a suppressed carrier environment. The resultant baseband signals from all the antennas can then be combined using existing baseband combining equiment. Computer simulations of SARA show increases in throughput (measured in data bits per second) over baseband-only combining 17 percent at Voyager 2 Uranum encounter and 31 percent at Neptune for a four-element antenna array and (7, 1/2) convolutional coding.

Description: The DSN Radio Science System supported the Voyager 2 Saturn encounter radio science experiments in August 1981. Support for these experiments was provided by all the Deep Space Stations of the DSN. However, the critical support for the Saturn occultation and ring scattering experiment was provided at DSS 43 by the medium-band open-loop recording system. The DSN Radio Science System is descried and the recent implementation at DSS 43 is emphasized.

Description: The experimental data and theoretical work on the 7.7 micron band of methane are reviewed. This band is particularly relevant in studies of the atmospheres of Jupiter, Saturn and the other outer planets. Methane spectra taken from the infrared spectrometer (IRIS) aboard Voyager, and a temperature profile derived by inverting those data, both for hydrogen and methane are presented.

Description: Measurements were made of the aerosol size, height and geographical distribution, their composition and optical properties, and their temporal variation with season and following large volcanic eruptions. Sulfur-bearing gases were measured in situ in the stratosphere, and studied of the chemical and physical processes which control gas-to-particle conversion were carried out in the laboratory.

Description: The Instruments are divided into two groups, ground based instruments and satellite-borne instruments. The ground based instruments include a Dobson ozone spectrophotometer, a filter ozonometer, and ozonesondes. The satellite-borne instruments include: a backscatter ultraviolet spectrometer, a high resolution infrared radiation sounder, a infrared interferometer spectrometer, a limb radiance inversion radiometer, and multichannel filter radiometer. A list of investigations using stratospheric satellite data is presented.

Description: The present state of knowledge concerning the absolute magnitude and temporal variability of the solar spectral irradiance is outlined with emphasis on wavelengths relevant to the mesosphere and stratosphere. Reference spectra for the wavelength region 175 to 850 nm are presented including estimates for solar maximum and solar minimum conditions. Values for the Lyman alpha emission are given separately.

Description: A compilation of rate constant data for use in stratospheric modeling is presented. The tabulations are divided into two categories: bimolecular and termolecular. Explanations are given for anomalous pressure and temperature dependences.

Description: Tropospheric and stratospheric source gases and their distribution are reported. A comparison of measurements and model calculations for stratospheric gases is presented.

Description: The capability for obtaining four-dimensional data on stratospheric structure, dynamics, and zone is discussed. Progress in the development of multidimensional models of the stratosphere is reported. The discussion of multidimensional aspects of the stratosphere is divided into four major sections: observations, analysis and interpretation, modeling, and transport of trace species.

Description: Temperatures in the sensible regions of the atmospheres of the outer planets are quite cold. The temperature structures for Jupiter, Saturn, Uranus and Neptune, derived from the equilibrium models are presented in preparation. The vertical temperature profiles for Jupiter and Saturn, the molecular spectroscopic data which form the basis for this type of analysis, and the problems involved with these models for molecular absorption and with the recovery technique in general, are discussed. Results for Jupiter and Saturn from the Pioneer and Voyager infrared experiments are also presented.

Description: Measurements were made of the exact shape of CO2 absorption lines in Mars and Venus to determine the vertical pressure temperature structure using high resolution heterodyne spectroscopy. Accurate measurements of absolute wind velocities in both the mesosphere and stratosphere of Venus were made from Doppler shifts of narrow CO2 lines, and searches were made for minor molecular species of interest in modeling the stratospheric photochemistry for Mars and Venus.

Description: The similarities between the atmospheres of Earth, Venus, and Mars are discussed. The following species are highlighted: NOx, HOx, and COx. The concentrations of the species were examined for all three planets.

Description: About 97% of the Venusian atmosphere is CO2, with the balance comprised of various trace constituents. Species other than CO2 that are found in Venus' atmosphere or are being sought are discussed. The problems connected with the spectrum of CO2 itself are highlighted.

Description: Possibly important sources of infrared opacity in the Venusian atmosphere was identified. It is shown that which is the major atmospheric constituent comprising about 97 percent of the atmosphere, is the dominant infrared opacity source. Not shown is N2 which comprises about 3 percent of the atmosphere. The mixing ratio of water vapor varies considerably with altitude but falls in the range of about 20 to 200 parts per million (ppm). The mixing ratio of SO2 falls in the range of 100-200 ppm. This number is about 5000 times larger than estimates obtained earlier via Earth-based observations. The abundance of some of the other minor constituents is also shown.

Description: The catalog includes molecules of interest in the interstellar medium, in planetary atmospheres and in the Earth's atmosphere. Different units than those on the AFGL tape are used. For citing line frequencies in the microwave region. Either the experimental errors or the propagation of errors from the fit are included on the tape. This gives an estimate of how accurate the frequencies are. The intensity units are defined as follows: the logarithm of the intensity unit is the cross section times the frequency in MHz. This is essentially the same unit as on the AFGL tape, but contains fewer factors of the speed of light. The catalog is available to the scientific community either as a tape or on microfiche (filmed in frequency sorted and molecule sorted format).

Description: The region of planetary atmospheres upward of 1 millimeter is considered. The applications of this region, how microwave, millimeter, and submillimeter spectra (the so called rotational spectra) can fruitfully interact with infrared spectral measurements are described. Both the rotational bands and vibrational bands of molecules are considered. A typical rotational absorption coefficient for a linear molecule in a low J state with a dipole moment of about one Debye is plotted and evaluated. A vibrational case was chosen similarly: the transition dipole moment used for the vibrational case is typical of CO at the peak of its rotational distribution. Information on high altitude parameters that often cannot be obtained from higher frequency spectra, which can be provided by rotational spectra is discussed.

Description: Several Venus cloud condensates, including A12C16 as well as halides, oxides and sulfides of arsenic and antimony, are assessed for their thermodynamic and geochemical plausibility. Aluminum chloride can confidently be ruled out, and condensation of arsenic sulfides on the surface will cause arsenic compounds to be too rare to produce the observed clouds. Antimony may conceivably be sufficiently volatile, but the expected molecular form is gaseous SbS, not the chloride. Arsenic and antimony compounds in the atmosphere will be regulated at very low levels by sulfide precipitation, irrespective of the planetary inventory of As and Sb. Thus the arguments for a volatile-deficient origin for Venus based on the depletion of water and mercury (relative to Earth) cannot be tested by a search for atmospheric arsenic or antimony.